LAKME PRODUCTS

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MATERIAL SAFETY DATA SHEET

LAKME PRODUCTS

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SUMMARY HAIR PREPARATIONS should generally not present a risk to the health and safety of hairdressers or their clients if used sensibly and manufacturers' instructions are followed. Manufacturers are required by law to supply health and safety information on any products used in hairdressing salons (a place of work) that contain potentially hazardous substances. Details must also be provided on the precautions that should be taken to reduce any risks. The information that manufacturers must give their customers (hairdressing salon owners or wholesalers) is given in this booklet. The MSDS tells you how to safely handle a product. It provides information for workers and professionals to help them make decisions and to prevent or deal with emergencies. Use the product lists issued by manufacturers to determine which MSDS applies to a particular haircare product.

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A GUIDE TO THE SAFE USE OF SALON HAIR PRODUCTS The aim of this guide is to provide relevant information on hair products used in Salons for you, the hairdresser to make an assessment of possible health and safety risks associated with storing and handling of these products in the environment in which you work. The guide complies with the requirements of the Health and Safety in Employment Act and related regulation. The guide is not intended to be a complete encyclopaedia of safety information, rather, it is designed to highlight some of the most important points you should be aware of. Your regular training, product's label information, other safety information that is available to you and use of good judgement on the job will help you avoid injury to yourself, your clients and your fellow employees. Are professional cosmetic products safe? A great deal of effort and resources are directed towards product safety on the part of manufacturers and regulators. The Food and Drug Administration (FDA) in the USA, COLIPA (The European federation of the national associations of the perfumery, cosmetics and toiletries industry) in Europe, and other bodies combine to ensure that products offered for sale in the market place are safe. However, poor practice resulting in extended skin contact or respiratory exposure to particular products may cause ill health to some hair and beauty practitioners. Cosmetic products are safe when used according to manufacturer’s instructions and recommendations. Ingredients Listing While responsible manufacturers and suppliers will have ingredients listed there is no legal obligation other than those set out in the Toxic Substances Act Regulations for Scheduled Poisons. If unable to locate this information on the packs you currently use or offer for sale, contact your supplier or distributor and ask that the information be provided to you. Ingredient lists inform about the substances present in the products. If you or some of your clients are allergic to certain ingredients, a look at the list will tell you whether those ingredients are present in the product. This information will help you and your clients avoid unwanted allergic reactions and/or to find products that do not present the potential for that problem. Ingredient names are listed according to a standardised international format

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and therefore should make no difference as to where the products are sourced from. To help you avoid ingredients to which you may be allergic, make sure to find out from your doctor the chemical name or other commonly used names for that ingredient; then compare those names with those on the ingredients list. If you are unsure consult your doctor or the supplier to confirm one way or another. Material safety Data Sheets (MSDS) There is no requirement under the Health and Safety in Employment Act that a material safety data sheet be prepared by the manufacturer or the supplier if the product being supplied is assessed as being a hazardous substance. What can you learn from a Material Safety Data Sheet (MSDS)? The MSDS enables the user to answer some basic questions. a). What is the product I am about to use? b). What do I need to know before and while I use it? c). What do I do if a hazardous situation occurs? d). How can I prevent a hazardous situation from occurring? The MSDS will tell you how to safely handle the product so that you do not place yourself or others at risk. The MSDS provides information to both workers and professionals to help them make decisions and to prevent or deal with emergencies. Such people may include managers, supervisors, transport drivers, the police, fire fighters, occupational hygienists, doctors, poison information centres personnel, government authorities and so on. These people will often need to know additional technical information associated with the product; information which is not often understood by personnel who have not had specialist training in that area. For this reason some of the information on a MSDS may appear too technical and unnecessary, but you are required by Law to make sure all employees know about information pertaining to a hazard and the information is contained on the MSDS is an excellent means of conveying this information and what it means for them.

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Physical description and properties APPEARANCE - In addition to explaining what the products look like (ie. liquid, powder etc) it will also include the likely product colour and product odour. This subsection also contains additional information useful in determining the likely hazards which further characterise the product. BOILING POINT - The temperature at which a liquid boils. VAPOUR PRESSURE - Is a measure of how much of a substance can accumulate as a vapour in the air above a liquid or solid. Useful in determining potential fire hazards and for determining potential respiratory hazard FLAMMABILITY LIMITS - The range of concentrations of flammable vapours in the air which will burn if ignited. SOLUBILITY IN WATER - This information is useful in determining effective fire extinguishing methods and spill clean up procedures. FLASH POINT - Is the lowest temperature at which a liquid will produce enough vapours to ignite if an ignition source is present. SPECIFIC GRAVITY - Less than 1.0 indicates that the product is lighter than water and if not miscible with water then the product could separate. pH - Is a measure of acidity and alkalinity. Low pH means the product is acidic; high pH means the product is alkaline. For example 1 = highly acidic and 14 = highly alkaline Ingredients This subsection provides the chemical name, CAS No (Chemical Abstract No) and proportion within a mixture for each hazardous component. Non hazardous ingredients may also be described. Health Hazards Information This section describes the potential health hazards of short term (acute) and long term (chronic) exposure to the products within the group. The effects are divided into major routes of exposure -- ingestion (swallowing), inhalation (breathing), skin and eye contact.

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Similarly, the first aid instructions for initial treatment of over exposure are divided into routes of exposure. There is also additional advice to doctors in this section. Precautions For Use This is the most important section for users as it details how users can protect themselves and how the manufacturer can advise users of potential harm. One of these standards is the Time Weighted Average (TWA), airborne concentration of a substance over an eight hour working day, for a five day working and over an entire working life. According to current knowledge, this concentration should neither impair the health of, nor cause undue discomfort to users. Exposure standards are guides to be used in the control of occupational health hazards and to evaluate how well equipment is working (i.e. ventilation). Engineering controls detail the mechanical ventilation required during use of the product. “Use in well ventilated areas” explains the need to ensure that the product is not used in areas without ventilation or air flow. Personal protection details the specific equipment (gloves - safety glasses) required to work safely with the product. Disposable gloves use refers to compounds such as nitrile or vinyl and not latex which is a poor chemical barrier. Flammability section details what is needed to prevent a fire or explosion hazard. The advice may include the need to avoid ignition sources and information on whether the substance should be used in well ventilated areas and away from confined spaces. Note: It is not the individual products that are hazardous but excessive exposure of professionals to a cocktail of different chemicals without adequate protection that may cause irritant reactions such as dermatitis. Safe Handling Information - Storage and transport requirements for the product may be found in this section. Some products have special requirements set in regulations (Flammable products and aerosol products) and the MSDS will state the codes and restrictions which may apply. - Spill and disposal will contain advice on how to minimise a spill or leak, a suitable method for cleaning up and how to dispose of collected material.

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- A description of the fire and explosion hazard for the product and the type of extinguisher to be used in case of fire complete this section. Other Information This section can contain any other useful information pertinent to the product.

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THE MATERIAL SAFETY DATA SHEET

RELEVANT SECTION OF MSDS PLAIN LANGUAGE EXPLANATION

Company Name and Address - The name, address and emergency telephone number of the Spanish manufacturer or supplier

Identification Physical description: Properties: Ingredients:

- What is the name of the product? - What does it look like? - Does it smell? - What does it contain?

Health Hazard Information Acute: Swallowed: Chronic: Eye: First Aid: Skin: Inhaled:

- What may happen if too much of the product is:

Breathed in? Gets into eyes? Gets into skin? Swallowed?

- What should I do if someone is over exposed?

Precautions for Use: Exposure standards: Engineering controls: Personal protection: Flammability:

- Are there special handling precautions I should follow?

- Use in well ventilate areas - What protective clothing or

equipment do I need? Gloves, apron, mask?

- What ventilation is required?

Safe Handling Information Storage and transport: Spills and disposal: Fire/explosion hazard:

- How should the material be stored?

- Are there materials this product should not come in contact with?

- How do I clean us s spill? - How do I dispose of it properly? - Will it burn or explode?

Other Information:

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ANNEX I

MSDS No.

DESCRIPTION

1

Peroxide Solutions 7- 12%

2

Bleach Powder

3

Peroxide Solutions 3 – 6%

4

Alkaline Perms and relaxers

5

Hair colours (Semipermanent Cream)

6

Hair Colours (Permanent Cream)

7

Hairsprays/Lacquers (Aerosol)

8

Aerosol Mousses (Styling and Conditioning)

9

Shampoos

10

Conditioners, mask and Treatments

11

Hair Care Preparations (Styling gel, hair care liquid products)

12

Hair Care Preparations (Styling powder products)

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ANNEX II MSDS DESCRIPTION

1 Peroxide Solutions 7- 12%

Collage Hydrox 30 vol Collage hydrox 40 vol

Chroma developer 28 vol

2 Bleach powders

kblonde dust free

3 Peroxide solution 3-7 %

Gloss emulsion Gloss emulsion long Lasting

Collage Hydrox 20 vol Collage Hydrox 10 vol

Chroma developer 18 vol Masterperm neutralizer

K-straight Neutralizing Balm

4 Alkaline perms and relaxers

Masterperm “0” Masterperm “1”

Masterperm “2”

K-wave “0” K-wave “1”

K-wave “2” K-straight ”0”

K-straight “1”

5 Hair colours (semipermanent cream)

Gloss (all shades) Chroma (all shades)

6 Hair colours (permanent cream)

Collage Hair Color Cream (all shades) Red motion by collage (all shades) Collage mix-tone (all shades) Collage Clair (all shades)

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ANNEX II MSDS DESCRIPTION

7 Hair sprays /lacques (aerosols)

Master Lak

Master lak strong

K-style Hard K-style Pliable

k-style crunchy k-style polish

Ecolak

k-style Brush up

8 Aerosols mousses (styling and conditioning)

k-style power

k-style natural boost

9 Shampoo

Teknia color stay shampoo

Teknia curl up shampoo Teknia deep care shampoo

Teknia body maker shampoo Teknia gentle balance shampoo

Teknia ultra clair shampoo Teknia ultra red shampoo

Teknia ultra copper shampoo

Teknia ultra Brown shampoo Teknia ultra violet shampoo

Teknia ultra gold shampoo Teknia extreme cleanse shampoo

Teknia straight shampoo

Teknia sun care shampoo k-therapy repair shampoo

k-therapy active shampoo k-therapy purifying shampoo

k-therapy peeling oily shampoo

k-therapy peeling dry shampoo k-therapy peeling gel shock

k-therapy sensitive shampoo k-therapy bioargan shampoo

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ANNEX II MSDS DESCRIPTION 10 Conditioners, treatments, mask

Master Restructuring Hair mask

Lak-2 conditioner Teknia color stay conditioner Teknia color stay treatment Teknia curl up conditioner Teknia deep care conditioner Teknia deep care treatmenr Teknia body care treatment Teknia ultra clair treatment Tekina ultra red treatment Teknia ultra copper treatment Teknia ultra brown treatment Teknia ultra violet treatment Teknia ultra gold treatment Teknia straight treatment Teknia sun care treatment

k-therapy repair mask k-therapy repair conditioning fluid k-therapy active mask k-therapy sensitive balm k-therapy purifying maks k-therapy bio-argan mask i.plex keratech i.power i.plex hair perfection

11 Hair Care Preparations (Styling gel, hair care liquid products) Master care oil Master care lotion Master care tonic Master scalp protector Master stain remover Teknia deep care drops Teknia straight gel Teknia sun care serum Teknia sun care protection Teknia straight thermal protector k-therapy repair gel k-therapy active concentrate k-therapy active lotion k-therapy repair concentrate k-therapy sensitive drops k-therapy bio argan oil

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k-stylke i-tool k-style shape k-style fiber paste k.tyle matter k-style ring k-style sea mist k-style curl action k-style smooth k-style lift k-style x-treme k-style water touch

k-style top ten k-style texture putty k-style body shaper i.plex Premium bond

12 Hair Care Preparations (powder) k-style chalk

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MATERIAL SAFETY DATA SHEET “CATEGORIES”

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PEROXIDE SOLUTIONS 7 – 12% MATERIAL SAFETY DATA SHEET NO. 1

PRODUCT IDENTIFICATION

PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 2984 DANGEROUS GOOD CLASS: 5.1 (> 8%) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155

PHYSICAL / CHEMICAL PROPERTIES

APPEARANCE: Low viscosity cream BOILING POINT: >35 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.02 –

1.05g/mL FLAMMABILITY LIMITS: not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble

INGREDIENTS CAS No. % w/w content

Hydrogen peroxide 7722 – 84 – 1 7 to 12 Other ingredients determined not to be hazardous to 100

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HEALTH HAZARD INFORMATION

HEALTH EFFECTS Irritant. Attacks eyes. Protect eyes when using. ACUTE EFFECTS: Swallow: Severe systemic poisoning may cause headache, dizziness,

vomiting, diarrhoea, tremors, numbness, convulsions, pulmonary oedema, unconsciousness and shock.

Eye: Eye contact may cause ulceration of the cornea. The

appearance of the eye damage would be delayed

Skin: Avoid contact. Temporary whitening or bleaching of the skin may occur. Irritation and formation of blisters may also occur.

Inhaled: Exposure to high vapour concentration may cause irritation of nose and throat.

CHRONIC EFFECTS: Long term exposure may cause dermatitis. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a Doctor. Skin: Remove contaminated clothing and wash skin thoroughly

with water.

Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm)

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ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be handling this product. Disposable gloves must not be latex. Eyes: Eye protection must be worn (safety glasses) to avoid accidental

splashes into eyes. Flammability:Product is not flammable, but can start a fire if spilled on combustible materials, eg: paper, wood, cardboard.

SAFE HANDLING INFORMATION

STORAGE AND TRANSPORT:

Store product upright in a cool place away from heat and direct sun light. Store away from corrosive and flammable products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods class 5.

SPILL AND DISPOSAL:

Dilute small spills with water, contain and absorb larger spills in inert material (sand). Dispose in accordance with local regulations.

FIRE / EXPLOSION HAZARD:

Will not burn, but may release oxygen when subjected to heat. At concentration above 10%, hydrogen peroxide may ignite a fire if spilled in combustible materials (ie. wood , paper, cardboard). In case of fire water, water fog, dry chemical CO2 or foam can be caused.

ECOLOGICAL IMFORMATION

Large quantities should not be discharged into waterways to prevent pollution of the waterways.

TOXICOLOGICAL INFORMATION

Medical Conditions Generally Aggravated by Exposure: None known.

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OTHER INFORMATION

Solutions containing hydrogen peroxide and bleach powders may sometimes produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie. aluminium as in glitter sprays or other forms). Should this occur, remove mixture from the hair by rinsing at the basin!

PEROXIDE SOLUTIONS 7 – 12% MATERIAL SAFETY DATA SHEET NO. 1


PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 2984 DANGEROUS GOOD CLASS: 5.1 (> 8%) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155



1.05g/mL FLAMMABILITY LIMITS: not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble



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HEALTH EFFECTS Irritant. Attacks eyes. Protect eyes when using. ACUTE EFFECTS: Swallow: Severe systemic poisoning may cause headache, dizziness,

vomiting, diarrhoea, tremors, numbness, convulsions, pulmonary oedema, unconsciousness and shock.

Eye: Eye contact may cause ulceration of the cornea. The

appearance of the eye damage would be delayed

Skin: Avoid contact. Temporary whitening or bleaching of the skin may occur. Irritation and formation of blisters may also occur.

Inhaled: Exposure to high vapour concentration may cause irritation of nose and throat.

CHRONIC EFFECTS: Long term exposure may cause dermatitis. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a Doctor. Skin: Remove contaminated clothing and wash skin thoroughly

with water.


PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA

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CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be handling this product. Disposable gloves must not be latex. Eyes: Eye protection must be worn (safety glasses) to avoid accidental

splashes into eyes. Flammability:Product is not flammable, but can start a fire if spilled on combustible materials, eg: paper, wood, cardboard.



Store product upright in a cool place away from heat and direct sun light. Store away from corrosive and flammable products. Store in accordance with Dangerous Goods Regulations and transport in accordance with the NZDG Code for Dangerous Goods class 5.

SPILL AND DISPOSAL:



Will not burn, but may release oxygen when subjected to heat. At concentration above 10%, hydrogen peroxide may ignite a fire if spilled in combustible materials (ie. wood , paper, cardboard). In case of fire water, water fog, dry chemical CO2 or foam can be caused.





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OTHER INFORMATION

Solutions containing hydrogen peroxide and bleach powders may sometimes produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie. aluminium as in glitter sprays or other forms). Should this occur, remove mixture from the hair by rinsing at the basin!

BLEACH PRODUCTS MATERIAL SAFETY DATA SHEET NO. 2


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Mixed with solutions containing hydrogen peroxide to

bleach/lighten the colour of the hair. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: Fine to granular powder. BOILING POINT: Not applicable. FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: Not

determined FLAMMABILITY LIMITS: Not determined pH: 9.0 – 10.0 (when mixed) SOLUBILITY IN WATER: Miscible with water.


Potassium persulfate Ammonium persulfate

7727 - 21 -1 7727 - 54 – 0

20 – 45 10 – 20

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Sodium persulfate Silica Sodium metasilicate

7775 - 27 - 1 7631 - 86 – 9

112945 - 52 – 5 6834 - 92 - 0

1 – 5 2 – 10

5 - 10

Other ingredients determined not to be hazardous to 100


HEALTH EFFECTS ACUTE EFFECTS: Swallow: Harmful if swallowed can cause irritation of the

gastrointestinal tract. Eye: Irritating to eyes. Skin: Irritating to skin. May cause sensitisation by skin contact.. Inhaled: Irritating to the respiratory system. May cause sensitisation

by inhalation. CHRONIC EFFECTS: May cause allergic dermatitis. Prolonged or repeated

inhalation may cause sensitisation. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water

and contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a doctor. Skin: Remove contaminated clothing and wash skin thoroughly

with water. Inhaled: Remove person to fresh air and see a doctor. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: Amorphous fumed silica (respirable dust) 2 mg/m3

Persulphate (ACGIH TLV standard) 5 mg/m3

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ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this or

its mixtures with solutions containing hydrogen peroxide. Disposable gloves must not be latex. Eyes: Safety glasses must be worn to avoid product or dust entering the

eye. Flammability:Product is not flammable, but its mixtures with peroxide can start

a fire if spilled on combustible materials, eg: paper, wood, cardboard.



Store product in a cool dry place away from heat and direct sun light. Store away from corrosive and flammable products.

SPILL AND DISPOSAL:

Avoid creating dust. Collect into clean plastic containers and dispose in accordance with local regulations. Wipe area with wet mop/cloth.


When heated product can release oxygen. This can cause other materials to burn. On decomposition can release fumes or ammonia, sulfates and oxides of nitrogen and potassium. Respirators and eye protection is required. In case of fire water, water fog, dry chemical CO2 or foam can be used.





OTHER INFORMATION

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• Mixtures of bleach powders and solutions containing hydrogen peroxide (6, 9 and 12%) may produce heat when applied to hair. This may be further enhanced by the presence of metallic impurities (ie aluminium as in glitter sprays or other forms). Should a reaction occur, remove mixture from the hair by rinsing at the basin! • Do not mix with perm lotions. • Skin sensitivity test: follow manufacturer’s instructions. • Added heat during application: follow manufacturer’s instructions.

PEROXIDE SOLUTIONS 3 - 6% MATERIAL SAFETY DATA SHEET NO. 3


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To mix with hair colours and bleaches MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155



1.05g/mL FLAMMABILITY LIMITS: Not flammable pH: 2.0 – 4.0 SOLUBILITY IN WATER: Completely soluble



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HEALTH EFFECTS Irritant. Attacks eyes. Protect eyes when using. ACUTE EFFECTS: Swallow: Can cause irritation of the gastrointestinal tract. Eye: Eye contact can cause irritation. Skin: Temporary whitening of the skin may occur. Prolonged skin

contact should be avoided. May cause skin irritation. Inhaled: Inhalation of vapours may cause irritation of nose and

throat. CHRONIC EFFECTS: Long term skin contact may cause dermatitis. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water.

Contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least

15 minutes and see a doctor. Skin: Remove contaminated clothing and wash skin thoroughly

with water.


PRECAUTIONS FOR USE


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CHEMICAL NAME: Hydrogen peroxide 1.4 mg/m3 (1ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended when handling this

product. Disposable gloves must not be latex. Eyes: Eye protection (safety glasses) must be worn to avoid accidental

splashes into eyes. Flammability:Product is not flammable.



Store product upright in a cool place away from heat and direct sun light. Store away from corrosive and flammable products.

SPILL AND DISPOSAL:



Will not burn, but may release oxygen when subjected to heat. In case of fire water, water fog, dry chemical CO2 or foam can be caused.





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OTHER INFORMATION

ALKALINE PERMS & RELAXERS MATERIAL SAFETY DATA SHEET NO. 4


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Permanent waving of the hair MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: Liquid with characteristic odour BOILING POINT: Not applicable. FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY: 1.03 –

1.05g/ml FLAMMABILITY LIMITS: Not flammable pH: 8 – 9.5 (when mixed) SOLUBILITY IN WATER: Completely soluble


Ammonia 7664 - 41 – 7 1 – 3

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Tioglicolic acid 68 - 11 - 1 7 - 10 Other ingredients determined not to be hazardous to 100


HEALTH EFFECTS ACUTE EFFECTS: Swallow: Harmful if swallowed. May cause irritation of the

gastrointestinal tract. Eye: Avoid contact. Corrosive in concentrate form. Skin: Avoid contact. May cause skin irritation. Inhaled: Inhalation of vapours may cause irritation of nose and

throat. CHRONIC EFFECTS: Long term or repeated exposure may result in skin irritation

in some individuals. FIRST AID: Swallowed: If swallowed do not induce vomiting, give a glass of water

and contact a doctor. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a doctor. Skin: Do not rub. Rinse with water. Remove contaminated

clothing. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: Ammonia 17 mg/m3 (25 ppm) ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this

product. Disposable gloves must not be latex.

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Eyes: Safety glasses must be worn to avoid product or dust entering the eye.

Flammability:Product is not flammable, but its mixtures with peroxide can start a fire if spilled on combustible materials, eg: paper, wood, cardboard.



Store product in a cool dry place away from heat and direct sun light. Store away from corrosive and flammable products.

SPILL AND DISPOSAL:

Avoid creating dust. Collect into clean plastic containers and dispose in accordance with local regulations. Wipe area with wet mop/cloth.


When heated product can release oxygen. This can cause other materials to burn. On decomposition can release fumes or ammonia, sulfates and oxides of nitrogen and potassium. Respirators and eye protection is required. In case of fire water, water fog, dry chemical CO2 or foam can be used.





OTHER INFORMATION

Do not mix with hydrogen peroxide (3, 6, 9 or 12%) solutions or bleach powders.

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HAIR COLOUR (Semipermanent Cream)

MATERIAL SAFETY DATA SHEET NO. 5


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair Colour MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155


APPEARANCE: Creamy soft mass BOILING POINT: Not Determined FLASH POINT: Not flammable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:0.98-

1.0g/mL FLAMMABILITY LIMITS: Not Applicable pH: 9.0 – 11.0 SOLUBILITY IN WATER: Completely soluble


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Toluene-2,5-Diamine Sulfate Resorcinol Phenylendiamines Aminophenols Ethanolamine

615 – 50 - 9 108 – 46 - 3

141 - 43 - 5

< 5 < 2 < 2 < 2 <10



HEALTH EFFECTS: This product contains ingredients which may cause skin

irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows.

ACUTE EFFECTS: Swallow: Harmful if swallowed. Product may cause irritation of the

gastrointestinal tract. Eye: Corrosive to the eye. Skin: Avoid contact. Prolonged skin contact may cause skin

irritation. Inhaled: CHRONIC EFFECTS: Long term or repeated skin contact may lead to

dermatitis. Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals.

FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water.

Contact a doctor Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a Doctor if pain persists. Skin: Wash affected area with water. If irritation develops seek

medical advice. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA*

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CHEMICAL NAME:

Resorcinol 45mg/m3(10ppm)

Phenylendiamines (refer to pack copy for specific ingredients)

0.1mg/ m3

Ethanolamine 7.5mmg/ m3(3ppm)

ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this

product or the mixture between products and solutions containing hydrogen peroxide. Disposable gloves must not be latex

Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes.

Flammability: Product is not flammable.



Store product in a cool place out of sun and away from food stuffs.

SPILL AND DISPOSAL:

Dilute small spills with water. Contain and absorb in inert material (ie. sand or vermiculate). Dispose of in accordance with local regulations.


The material is not flammable. In case of fire water, water fog, dry chemical, CO2 or foam can be used.





Date: 04/01/2017

33

OTHER INFORMATION

HAIR COLOUR (Permanent Cream)



PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair Colour MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155


APPEARANCE: Creamy soft mass with ammonia odour BOILING POINT: Not Determined FLASH POINT: Not flammable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:0.98-1.0g/mL FLAMMABILITY LIMITS: Not Applicable pH: 10.0 - 11.0 SOLUBILITY IN WATER: Completely soluble


Date: 04/01/2017

34

Ammonia Toluene-2,5-Diamine Sulfate Resorcinol Phenylendiamines Aminophenols

7664 – 41 –7 615 – 50 - 9 108 – 46 - 3

< 5 < 5 < 2 < 2 < 2



HEALTH EFFECTS: This product contains ingredients which may cause skin

irritation and sensitisation to certain individuals (ie. phenylendiamines). A preliminary skin test must be carried out before use. (For test details see product pack copy). Product must not be used for dyeing the eyelashes or eyebrows.

ACUTE EFFECTS: Swallow: Harmful if swallowed. Product may cause irritation of the

gastrointestinal tract. Eye: Corrosive to the eye. Skin: Avoid contact. Prolonged skin contact may cause skin

irritation. Inhaled: Ammonia vapours may cause irritation of the nose and

throat. CHRONIC EFFECTS: Long term or repeated skin contact may lead to dermatitis.

Some aromatic amine dyes may cause contact dermatitis and allergic reactions in some individuals.

FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water.

Contact a doctor Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a Doctor if pain persists. Skin: Wash affected area with water. If irritation develops seek

Date: 04/01/2017

35

medical advice. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE


CHEMICAL NAME:

Ammonia 17mg/m3(25ppm)

Resorcinol 45mg/m3(10ppm)

Phenylendiamines (refer to pack copy for specific ingredients)

0.1mg/ m3

ENGINEERING CONTROLS: Use in well ventilated areas. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) must be worn when handling this

product or the mixture between products and solutions containing hydrogen peroxide. Disposable gloves must not be latex

Eyes: Eye protection should be worn (safety glasses) to avoid product contacting the eyes.

Flammability: Product is not flammable.



Store product in a cool place out of sun and away from food stuffs.

SPILL AND DISPOSAL:

Dilute small spills with water. Contain and absorb in inert material (ie. sand or vermiculate). Dispose of in accordance with local regulations.

Date: 04/01/2017

36


The material is not flammable. In case of fire water, water fog, dry chemical, CO2 or foam can be used.





OTHER INFORMATION

Date: 04/01/2017

37

HAIRSPRAYS/LACQUERS (AEROSOLS) MATERIAL SAFETY DATA SHEET NO. 7


PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 1950 DANGEROUS GOOD CLASS: 2 PRODUCT USE: Hair styling preparation. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: Clear liquid BOILING POINT: Not determined FLASH POINT: Not applicable VAPOUR PRESSURE: 275 – 345 KPa SPECIFIC GRAVITY: 0.86 –

0.90g/ml FLAMMABILITY LIMITS: 1.9 – 9.5 pH: 6.0 – 8.5 SOLUBILITY IN WATER: Completely soluble


Hydrocarbon propellant (LPG)

Date: 04/01/2017

38

- Propane - Isobutane

Dimethyl ether Ethyl alcohol

74 - 98 - 6 75 - 28 -5

115 - 10 - 6 64 - 17 - 5

30 – 50

30 – 40 40 - 65



HEALTH EFFECTS Warning intentional misuse by deliberately concentrating and

inhaling contents can be harmful or fatal. ACUTE EFFECTS: Swallow: Low toxicity by the oral route. May cause irritation of the

gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness.

Eye: Splashes in the eye may cause immediate stinging sensation and tears.

Transient reddening of the eye may also occur. Skin: No appreciable irritation of the skin is expected. Inhaled: At relatively vapour concentrations ethyl and isopropyl

alcohol are irritants to the nose and throat and may cause central nervous system depression.

CHRONIC EFFECTS: Long term exposure to ethyl and isopropyl alcohol may

result in irritation of the nose and mouth, headaches, lack of concentration and drowsiness. Prolonged or repeated skin contact may lead to dermatitis.

FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a doctor if pain persists. Skin: Wash affected area with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically. If in eyes, recheck after one week.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrocarbon propellant (LPG) 1800mg/m3 (1000 ppm) Ethyl alcohol 1880mg/m3 (1000 ppm)

Date: 04/01/2017

39

ENGINEERING CONTROLS: Use in well ventilated areas and away from

ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged skin conduct with the product. Eyes: Protect eyes when using. Flammability:Highly flammable, keep away from heat, flame or ignition source.



Store product in a cool place out of direct sunlight. Store away from corrosive products. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous goods Class 2.

SPILL AND DISPOSAL:

Remove all ignition sources and ventilate area. Remove possible leaking containers. Dilute spills with water. Do no t puncture or incinerate cans even when empty. Dispose of in accordance with local regulations.


Highly flammable. Vapours are heavier than air, distant ignition source possible. Closed containers may rupture when exposed to heat greater than 50ºC. may react with oxidising agents. May produce toxic vapours on decomposition. Fog, fine water spray, carbon dioxide, foam or dry chemical can be used to extinguish fires.





OTHER INFORMATION

Date: 04/01/2017

40

AEROSOLS MOUSSE (STYLING & CONDITIONING) MATERIAL SAFETY DATA SHEET NO. 8


PRODUCT NAME/CODE: Refer to individual company listing (annex II) UN No: 1950 DANGEROUS GOOD CLASS: 9 PRODUCT USE: Hair styling/conditioning preparation. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: White foam BOILING POINT: Not determined FLASH POINT: - 87ºC VAPOUR PRESSURE: 448 – 517 KPa SPECIFIC GRAVITY: 0.88 –

0.74g/ml FLAMMABILITY LIMITS: 1.9 – 9.5% pH: 4.0 – 7.0 SOLUBILITY IN WATER: Completely soluble


Hydrocarbon propellant (LPG) - Propane - Isobutane

Ethyl alcohol

74 - 98 - 6 75 - 28 -5 64 - 17 - 5

1 - 5 1 - 5 <20


Date: 04/01/2017

41


HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. May cause irritation of the

gastrointestinal tract. Depression of the central nervous system may result in headache and dizziness.

Eye: Contact may irritate eye. Skin: Prolonged and repeated skin contact should be avoided. Inhaled: Inhalation of aerosol products may cause irritation to the

nose and throat. CHRONIC EFFECTS: Prolonged or repeated exposure may lead to skin dryness. FIRST AID: Swallowed: If swallowed do not induce vomiting. Give a glass of water. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a doctor if pain persists. Skin: Wash affected area with water. Inhaled: Remove person to fresh air. Advice to Doctor: Treat symptomatically.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: Hydrocarbon propellant (LPG) 1800mg/m3 (1000 ppm) Ethyl alcohol 1880mg/m3 (1000 ppm) ENGINEERING CONTROLS: Use in well ventilated areas and away from

ignition sources. PERSONAL PROTECTION: Skin: Avoid prolonged skin conduct with the product. Eyes: Protect eyes when using. Flammability:Highly flammable, keep away from heat, flame or ignition source.

Date: 04/01/2017

42



Store product in a cool place out of direct sunlight. Store away from corrosive products. Store in accordance with Dangerous Good Regulations and transport in accordance with the NZDG Code for Dangerous goods Class 2.

SPILL AND DISPOSAL:

Remove all ignition sources and ventilate area. Remove possible leaking containers. Dilute spills with water. Do no t puncture or incinerate cans even when empty. Dispose of in accordance with local regulations.


Flammable. Closed containers may rupture when exposed to heat greater than 50ºC. Fog, fine water spray, carbon dioxide, foam or dry chemical can be used to extinguish fires.





OTHER INFORMATION

Date: 04/01/2017

43

SHAMPOOS MATERIAL SAFETY DATA SHEET NO. 9


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To cleanse hair and scalp. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephne number: 34 934700155


APPEARANCE: Viscous liquid BOILING POINT: Approx. 100 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.0 -1.10g/mL FLAMMABILITY LIMITS: Not Combustible pH: 4. – 7.5 SOLUBILITY IN WATER: Completely soluble


Anionic and amphoteric surfactants such as: Sodium laureth sulphate Cocamido propyl betain Coco Glucoside

9004 - 82 - 4 1335 – 72 - 4

61789 – 40 – 0 141464 – 42 - 8

6 –12%

1 – 5% 1 – 3 %


Date: 04/01/2017

44


HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Splashes in the eye may cause stinging sensation and tears.

Transient reddening of the eye may also occur. Skin: Prolonged and repeated skin contact should be avoided. Inhaled: No appreciable irritation is expected by this route. CHRONIC EFFECTS: May produce dermatitis on repeated or prolonged contact

with skin. FIRST AID: Swallowed: If swallowed DO NOT induce vomiting. Give a glass of water

and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a Doctor if pain persists. Skin: Wash affected area with water.

Inhaled: Remove from further exposure. Advice to Doctor: Treat symptomatically.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA ENGINEERING CONTROLS: None required. PERSONAL PROTECTION: Skin: Gloves (vinyl, rubber or plastic) are recommended if prolonged contact with the product is envisaged. Eyes: None Flammability: Product is not flammable.

Date: 04/01/2017

45



Store product in a cool place

SPILL AND DISPOSAL:

Spills are slippery. Remove possible leaking containers. Mop up small pills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations.


Will not burn. Not considered a significant risk.





OTHER INFORMATION

Date: 04/01/2017

46

CONDITIONERS, MASKS & TREATMENTS MATERIAL SAFETY DATA SHEET NO. 10


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: To condition and beautify hair after cleansing. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: Viscous liquid BOILING POINT: Approx. 100ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: 0.88 –

0.74g/ml FLAMMABILITY LIMITS: Not combustible pH: 3.5 – 5.5 SOLUBILITY IN WATER: Miscible


Cationic surfactants such as: Certrimonium chloride Behentrimonium chloride

112 - 02 – 7

17301 - 53 – 0

<3 < 3


Date: 04/01/2017

47


HEALTH EFFECTS ACUTE EFFECTS: Swallow: Low toxicity by the oral route. Eye: Eye contact may cause some stinging and tears. Transient

reddening of the eye may also occur. Skin: No appreciable irritation is expected by this route but

however, prolonged repeated skin contact should be avoided.

Inhaled: No appreciable irritation is expected by this route. CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two

glasses of water and seek medical attention. Eyes: If in eyes, hold eyes open, flood with water for at least 15

minutes and see a doctor if pain persists. Skin: Remove contaminated clothing and wash affected area with water. Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. For prolonged use gloves are advised. Eyes: No protection need. Flammability:Product is not flammable..

Date: 04/01/2017

48



Store product in a cool place.

SPILL AND DISPOSAL:

Spills are slippery. Remove possible leaking containers. Mop up small spills. For larger spills absorb in inert material (sand or vermiculate). Dispose of in accordance with local regulations.







OTHER INFORMATION

Date: 04/01/2017

49

HAIR CARE PREPARATIONS (STYLING GEL, HAIR CARE LIQUID PRODUCTS)



PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair care and styling. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: Viscous liquid, gel or wax. BOILING POINT: Approx. 100ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined SPECIFIC GRAVITY: 0.88 –

0.74g/ml FLAMMABILITY LIMITS: Not combustible pH: 4.0 – 8.0 SOLUBILITY IN WATER: Miscible


Liquids: - Water

Gels and waxes: - Polyquaternium - 11 - Polyquaternium – 46 - Water

7732 - 18 - 5

53633 - 54 – 8 174761 - 16 – 1

7732 - 18 - 5

>50

<3 <3

< 50


Date: 04/01/2017

50





Inhaled: No appreciable irritation is expected by this route. CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two


minutes and see a doctor if pain persists. Skin: Remove contaminated clothing and wash affected area with water. Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA CHEMICAL NAME: ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. Eyes: No protection need. Flammability:Product is not flammable.

Date: 04/01/2017

51




SPILL AND DISPOSAL:








OTHER INFORMATION

Date: 04/01/2017

52

HAIR CARE PREPARATIONS (STYLING POWDER PRODUCTS) MATERIAL SAFETY DATA SHEET NO. 12


PRODUCT NAME/CODE: Refer to individual company listing (annex II) PRODUCT USE: Hair care and styling. MANUFACTURER: Lakmé Cosmetics S.L. C/ Narcís Monturiol, 37 08960 Sant Just Desvern Barcelona (SPAIN) Emergency telephone number: 0034 - 934700155


APPEARANCE: POWDER DENSITY: Approx. 2.2 GR/CM3 FLASH POINT: Not applicable VAPOUR PRESSURE: Not determined BULK DENSITTY:100-300 kg/m3 LAMMABILITY LIMITS: Not combustible pH: 6.0 – 9.0 SOLUBILITY IN WATER: No miscible


Hydrofobic dispersed silica

68909-20-6 100 %

Date: 04/01/2017

53





Inhaled: TLV-GB 6 mg/m3 inhalable dust. Not recommended CHRONIC EFFECTS: FIRST AID: Swallowed: If swallowed do not induce vomiting. Give one or two


minutes and see a doctor if pain persists. Skin: Wash with water and soap an apply a cream Inhaled: If affected, remove from further exposure. Advice to Doctor: Treat symptomatically.

PRECAUTIONS FOR USE

EXPOSURE LIMITS: TWA ENGINEERING CONTROLS: None required PERSONAL PROTECTION: Skin: Not normally required. Eyes: No protection need. Flammability:Product is not flammable.

Date: 04/01/2017

54




SPILL AND DISPOSAL:








OTHER INFORMATION

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