LAKME TEKNIA PRODUCTS

Date: 29/10/2019

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MATERIAL SAFETY DATA SHEET

LAKME TEKNIA PRODUCTS

Date: 29/10/2019

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SUMMARY HAIR PREPARATIONS should generally not present a risk to the health and safety of hairdressers or their clients if used sensibly and manufacturers' instructions are followed. Manufacturers are required by law to supply health and safety information on any products used in hairdressing salons (a place of work) that contain potentially hazardous substances. Details must also be provided on the precautions that should be taken to reduce any risks. The information that manufacturers must give their customers (hairdressing salon owners or wholesalers) is given in this booklet. The MSDS tells you how to safely handle a product. It provides information for workers and professionals to help them make decisions and to prevent or deal with emergencies. Use the product lists issued by manufacturers to determine which MSDS applies to a particular haircare product.

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A GUIDE TO THE SAFE USE OF SALON HAIR PRODUCTS The aim of this guide is to provide relevant information on hair products used in Salons for you, the hairdresser to make an assessment of possible health and safety risks associated with storing and handling of these products in the environment in which you work. The guide complies with the requirements of the Health and Safety in Employment Act and related regulation. The guide is not intended to be a complete encyclopaedia of safety information, rather, it is designed to highlight some of the most important points you should be aware of. Your regular training, product's label information, other safety information that is available to you and use of good judgement on the job will help you avoid injury to yourself, your clients and your fellow employees. Are professional cosmetic products safe? A great deal of effort and resources are directed towards product safety on the part of manufacturers and regulators. The Food and Drug Administration (FDA) in the USA, COLIPA (The European federation of the national associations of the perfumery, cosmetics and toiletries industry) in Europe, and other bodies combine to ensure that products offered for sale in the market place are safe. However, poor practice resulting in extended skin contact or respiratory exposure to particular products may cause ill health to some hair and beauty practitioners. Cosmetic products are safe when used according to manufacturer’s instructions and recommendations. Ingredients Listing While responsible manufacturers and suppliers will have ingredients listed there is no legal obligation other than those set out in the Toxic Substances Act Regulations for Scheduled Poisons. If unable to locate this information on the packs you currently use or offer for sale, contact your supplier or distributor and ask that the information be provided to you. Ingredient lists inform about the substances present in the products. If you or some of your clients are allergic to certain ingredients, a look at the list will tell you whether those ingredients are present in the product. This information will help you and your clients avoid unwanted allergic reactions and/or to find products that do not present the potential for that problem. Ingredient names are listed according to a standardised international format

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and therefore should make no difference as to where the products are sourced from. To help you avoid ingredients to which you may be allergic, make sure to find out from your doctor the chemical name or other commonly used names for that ingredient; then compare those names with those on the ingredients list. If you are unsure consult your doctor or the supplier to confirm one way or another. Material safety Data Sheets (MSDS) There is no requirement under the Health and Safety in Employment Act that a material safety data sheet be prepared by the manufacturer or the supplier if the product being supplied is assessed as being a hazardous substance. What can you learn from a Material Safety Data Sheet (MSDS)? The MSDS enables the user to answer some basic questions. a). What is the product I am about to use? b). What do I need to know before and while I use it? c). What do I do if a hazardous situation occurs? d). How can I prevent a hazardous situation from occurring? The MSDS will tell you how to safely handle the product so that you do not place yourself or others at risk. The MSDS provides information to both workers and professionals to help them make decisions and to prevent or deal with emergencies. Such people may include managers, supervisors, transport drivers, the police, fire fighters, occupational hygienists, doctors, poison information centres personnel, government authorities and so on. These people will often need to know additional technical information associated with the product; information which is not often understood by personnel who have not had specialist training in that area. For this reason some of the information on a MSDS may appear too technical and unnecessary, but you are required by Law to make sure all employees know about information pertaining to a hazard and the information is contained on the MSDS is an excellent means of conveying this information and what it means for them.

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Physical description and properties APPEARANCE - In addition to explaining what the products look like (ie. liquid, powder etc) it will also include the likely product colour and product odour. This subsection also contains additional information useful in determining the likely hazards which further characterise the product. BOILING POINT - The temperature at which a liquid boils. VAPOUR PRESSURE - Is a measure of how much of a substance can accumulate as a vapour in the air above a liquid or solid. Useful in determining potential fire hazards and for determining potential respiratory hazard FLAMMABILITY LIMITS - The range of concentrations of flammable vapours in the air which will burn if ignited. SOLUBILITY IN WATER - This information is useful in determining effective fire extinguishing methods and spill clean up procedures. FLASH POINT - Is the lowest temperature at which a liquid will produce enough vapours to ignite if an ignition source is present. SPECIFIC GRAVITY - Less than 1.0 indicates that the product is lighter than water and if not miscible with water then the product could separate. pH - Is a measure of acidity and alkalinity. Low pH means the product is acidic; high pH means the product is alkaline. For example 1 = highly acidic and 14 = highly alkaline Ingredients This subsection provides the chemical name, CAS No (Chemical Abstract No) and proportion within a mixture for each hazardous component. Non hazardous ingredients may also be described. Health Hazards Information This section describes the potential health hazards of short term (acute) and long term (chronic) exposure to the products within the group. The effects are divided into major routes of exposure -- ingestion (swallowing), inhalation (breathing), skin and eye contact.

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Similarly, the first aid instructions for initial treatment of over exposure are divided into routes of exposure. There is also additional advice to doctors in this section. Precautions For Use This is the most important section for users as it details how users can protect themselves and how the manufacturer can advise users of potential harm. One of these standards is the Time Weighted Average (TWA), airborne concentration of a substance over an eight hour working day, for a five day working and over an entire working life. According to current knowledge, this concentration should neither impair the health of, nor cause undue discomfort to users. Exposure standards are guides to be used in the control of occupational health hazards and to evaluate how well equipment is working (i.e. ventilation). Engineering controls detail the mechanical ventilation required during use of the product. “Use in well ventilated areas” explains the need to ensure that the product is not used in areas without ventilation or air flow. Personal protection details the specific equipment (gloves - safety glasses) required to work safely with the product. Disposable gloves use refers to compounds such as nitrile or vinyl and not latex which is a poor chemical barrier. Flammability section details what is needed to prevent a fire or explosion hazard. The advice may include the need to avoid ignition sources and information on whether the substance should be used in well ventilated areas and away from confined spaces. Note: It is not the individual products that are hazardous but excessive exposure of professionals to a cocktail of different chemicals without adequate protection that may cause irritant reactions such as dermatitis. Safe Handling Information - Storage and transport requirements for the product may be found in this section. Some products have special requirements set in regulations (Flammable products and aerosol products) and the MSDS will state the codes and restrictions which may apply. - Spill and disposal will contain advice on how to minimise a spill or leak, a suitable method for cleaning up and how to dispose of collected material.

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- A description of the fire and explosion hazard for the product and the type of extinguisher to be used in case of fire complete this section. Other Information This section can contain any other useful information pertinent to the product.

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THE MATERIAL SAFETY DATA SHEET

RELEVANT SECTION OF MSDS PLAIN LANGUAGE EXPLANATION

Company Name and Address - The name, address and emergency telephone number of the Spanish manufacturer or supplier

Identification Physical description: Properties: Ingredients:

- What is the name of the product? - What does it look like? - Does it smell? - What does it contain?

Health Hazard Information Acute: Swallowed: Chronic: Eye: First Aid: Skin: Inhaled:

- What may happen if too much of the product is:

◼ Breathed in? ◼ Gets into eyes? ◼ Gets into skin? ◼ Swallowed?

- What should I do if someone is over exposed?

Precautions for Use: Exposure standards: Engineering controls: Personal protection: Flammability:

- Are there special handling precautions I should follow?

- Use in well ventilate areas - What protective clothing or

equipment do I need? Gloves, apron, mask?

- What ventilation is required?

Safe Handling Information Storage and transport: Spills and disposal: Fire/explosion hazard:

- How should the material be stored?

- Are there materials this product should not come in contact with?

- How do I clean us s spill? - How do I dispose of it properly? - Will it burn or explode?

Other Information:

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ANNEX I

MSDS No.

DESCRIPTION

1

Shampoos

2

Conditioners, mask and Treatments

3

Hair Care Preparations (hair care liquid or oil products)

4

Refresh shampoos with colorants

5

Refresh mask with colorants

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ANNEX II 1 Shampoo

Teknia color stay shampoo

Teknia deep care shampoo Teknia body maker shampoo

Teknia organic balance shampoo

Teknia perfect cleanse shampoo Teknia full defense shampoo

Teknia frizz control shampoo

2 Conditioners, treatments, mask

Teknia color stay conditioner Teknia color stay treatment Teknia deep care conditioner Teknia deep care treatment Teknia body maker balm

Teknia full defense treatment Teknia frizz control cream Teknia frizz control conditioner Teknia frizz control treatment Teknia organic balance treatment

3. Hair Care Preparations (, hair care liquid products) Teknia full defense serum Teknia full defense mist Teknia body maker mist Teknia frizz control protector Teknia organic balance oil Teknia organic balance hydra oil Teknia deep care drops

4. Refresh Shampoo

Teknia white silver shampoo

Teknia refresh coral red shampoo Teknia refresh saffron copper shampoo

Teknia refresh cocoa Brown shampoo

Teknia refresh violet lavender shampoo

5. Refresh mask

Teknia white silver mask Tekina refresh coral red mask Teknia refresh saffron copper mask Teknia refresh cocoa brown mask Teknia refresh violet lavender mask

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MATERIAL SAFETY DATA SHEET “CATEGORIES”

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MATERIAL SAFETY DATA SHEET nº 1:

TEKNIA SHAMPOO

1. PRODUCT IDENTIFICATION

PRODUCT NAME/CODE: Teknia refresh shampoo PRODUCT USE: To cleanse hair and scalp. MANUFACTURER: Lakmé Cosmetics S.L.U. C/ Narcís Monturiol, 27 08960 Sant Just Desvern Barcelona (SPAIN) Telephone number: + 34 934700155

2. HARZARD INFORMATION

· Hazard description: Not applicable. Information concerning particular hazards for human and environment: Not applicable.

· Classification system:The classification is according to the latest editions of

the EU-lists, and extended by company and literature data.

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3. COMPOSITION /INFORMATION ON INGREDIENTS

INGREDIENTS CAS No. % w/w content

Anionic and amphoteric surfactants such as: DISODIUM LAURETH SULFOSUCCINATE SODIUM LAURYL SULFOACETATE Cocamido propyl betaine Coco Glucoside

39354-45-2 58761-87-8

61789 – 40 – 0 141464 – 42 – 8

5-10 % 5-10 % 1 – 5% 1 – 3 %

Other ingredients determined not to be hazardous to 100

4. FIRST AIDS MEASURES

· After inhalation: Remove individual to fresh air

Seek medical treatment in case of complaints.

· After skin contact: Immediately rinse with water.

Remove contaminated clothing

immediately and launder before re-use. If

irritation develops, seek medical

attention.

· After eye contact: Rinse opened eye for several minutes under running water.

If symptoms persist, consult a doctor.

· After swallowing: Rinse out mouth and then drink plenty of water.

DO NOT give anything by mouth if the person is

unconscious or is having convulsions.

5. FIRE FIGHTING MEASURES

· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.

· Protective equipment: You are recommended to use an approved Self-Contained Breathing Apparatus (SCBA)

· Additional information In case of fire use normal fire fighting equipment

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6. ACCIDENT REALEASE MEASURES

· Person-related safety precautions: Wear protective clothing.

· Measures for environmental protection: Inform all downstream users of possible contamination. Stop source of spill as soon as possible and notify site or duty manager. Do not allow to enter sewers/ surface or ground water

· Measures for cleaning/collecting:

· Spill materials may be absorbed using sand, clay or non-combustible absorbent. Contain all liquid for treatment and or disposal as a hazardous waste. Do not place spill material back into original containers.

7. HANDLING AND STORAGE

Storage: Shelf life: 5 years from the manufacturing date s if

stored under cool, dry, between 15ºC a 30ºC conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

· Respiratory protection: Not necessary if room is well-ventilated.

· Protection of hands: Not necessary

· Eye protection: Not necessary

· Body protection: Not necessary

·

9. PHYSICAL AND CHEMICAL PROPERTIES

APPEARANCE: Viscous liquid BOILING POINT: Approx. 100 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.0 -1.10g/mL FLAMMABILITY LIMITS: Not Combustible pH: 4.5 – 6.5 SOLUBILITY IN WATER: Completely soluble

·

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10. STABILITY AND REACTIVIY

· Stable until: Product is stable at normal room temperature

· Materials to be avoided and dangerous decomposition products: none

·

11. TOXICOLOGICAL INFORMATION

According to the product type, target and package, it is established the

next exposure data:

Exposure:

Area (cm2) 1440

Frequency (daily) 1

Daily amount applied (mg) 10460

Retention factor 0.01

DAp (% absorption) 100%

It is considered the area of the hands and the middle of the head (1440

cm2), the frequency of application is once a day, the estimated daily

amount applied is 10460 mg, and the retention factor is 0.01, so is a

rinse-off product. The absorption is 100%.

DERMAL ABSORPTION Data Applicable SED Value

Per unit area of skin on which is applied:

Skin irritation

YES

0.0726 mg/cm2 per day

Per kilogram of body weight (for 60 Kg body weight):

Widespread

toxicity

YES

1.510 mg / kg bw/day

Bibliographic data:

− SCCS’s Notes of guidance for the testing of cosmetic substances

and their safety evaluation, 10th revision.

− RIVM report 320104001/2006 Cosmetics Fact Sheet

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· Additional toxicological

· on the skin: Not expected to be irritating to the skin

· on the eye: Not expected to be irritating to the eye

· Inhalation: Not expected to be toxic by inhalation

· Ingestion: Not expected to be toxic by ingestion

· Carcinogenicity: This chemical is not known or reported to be carcinogenic

by any reference source including IARC or NTP

· Mutagenicity: Not known to be Mutagenic

· Reproductive &development toxicity: Not known to be reproductive or developmental toxin

12. ECOLOGICAL IMFORMATION

Large quantities should not be discharged into waterways to prevent pollution of the waterways.

13. DISPOSAL CONSIDERATION

Recommendation Care must be taken to prevent environment contamination from

the use of this material. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, national and EU laws, directives and regulations regarding treatment, storage and disposal for hazardous and non-hazardous wastes

14. TRANSPORT INFORMATION

· Land transport ADR/RID (cross-border)

· ADR/RID class: Not regulated

· Maritime transport IMDG:

· IMDG Class: Not regulated

· Marine pollutant: No

· Air transport ICAO-TI and IATA-DGR:

· ICAO/IATA Class: Not regulated

· Transport/Additionalinformation Not dangerous according to the Above specifications.

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15. REGULATORY INFORMATION

Labelling according to he substance is not subject to classification according to EU

lists and other sources of literature known to us. Complies with Regulation (EC) N°

1223/2009 on cosmetic products

16. OTHER INFORMATION

This Material Safety Data Sheet (MSDS) has been prepared in compliance with

the relevant EU directives and regulations. The information in this MSDS should be

provided to all who will use, handle, store, transport, or otherwise be exposed to

this product.

Lakme cosmetics believe this information to be reliable and up to date as of the

date of publication, but makes no warranty that it is. Additionally, if this Material

Safety Data Sheet is more than three years old, you should contact manufacturing

·

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TEKNIA MASK/CONDITIONER /TREATMENT


PRODUCT NAME/CODE: Teknia MASK/CONDITIONER /TREATMENT PRODUCT USE: To conditioner hair MANUFACTURER: Lakmé Cosmetics S.L.U. C/ Narcís Monturiol, 27 08960 Sant Just Desvern Barcelona (SPAIN) Telephone number: + 34 934700155





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Cationic surfactants such as: Certrimonium chloride Behentrimonium chloride

112 - 02 – 7

17301 - 53 – 0

<2.5 <2.5









attention.










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·


APPEARANCE: White cream BOILING POINT: Approx. 100 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:0.9 -1.00g/mL FLAMMABILITY LIMITS: Not Combustible pH: 4.0 – 6.5 SOLUBILITY IN WATER: Completely soluble

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·






next exposure data:

Exposure:

Area (cm2) 1440

Frequency (daily) 1




The surface area is the hair (area hands + ½ area head), the frequency of application is

0.28 times/day, the estimated daily amount applied is 3920 mg, and the

retention factor is 0,1, so is a rinse-off product. The absorption is 100%.

It is used the SCCS´s data for hair conditioner.



Skin irritation

YES

0,2722 mg/cm2 per day

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Widespread toxicity

YES


Bibliographic data:

− SCCS’s Notes of guidance for the testing of cosmetic substances and their

safety evaluation, 10th revision.















Date: 29/10/2019

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·










this product.




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TEKNIA Hair Care Preparations (hair care liquid or oil products)


PRODUCT NAME/CODE: TEKNIA Hair Care Preparations (hair care liquid or

oil products) PRODUCT USE: To conditioner hair MANUFACTURER: Lakmé Cosmetics S.L.U. C/ Narcís Monturiol, 27 08960 Sant Just Desvern Barcelona (SPAIN) Telephone number: + 34 934700155





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INGREDIENTS CAS No. % w/w content Cationic surfactants such as: Certrimonium chloride Silicones as BIS-CETEARYL AMODIMETHICONE

112 - 02 – 7

1126942-72-0

<2.5

Inf 4 %









attention.








· Protective equipment: You are recommended to use an approved Self-

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Contained Breathing Apparatus (SCBA)















·



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·






next exposure data:

Exposure:

Area (cm2) 1440

Frequency (daily) 1









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Skin irritation

YES



Widespread toxicity

YES


Bibliographic data:
















the use of this material. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, national and EU

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laws, directives and regulations regarding treatment, storage and disposal for hazardous and non-hazardous wastes









·










this product.




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TEKNIA REFRESH SHAMPOO


PRODUCT NAME/CODE: Teknia refresh shampoo PRODUCT USE: To cleanse hair and scalp. MANUFACTURER: Lakmé Cosmetics S.L.U. C/ Narcís Monturiol, 27 08960 Sant Just Desvern Barcelona (SPAIN) Telephone number: + 34 934700155





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Anionic and amphoteric surfactants such as: DISODIUM LAURETH SULFOSUCCINATE SODIUM LAURYL SULFOACETATE Cocamido propyl betaine Coco Glucoside May content:

EX D&CVIOLET Nº 2 (CI60730) BASIC RED 513. BASIC BLUE 99

39354-45-2 58761-87-8

61789 – 40 – 0 141464 – 42 – 8

4430-18-6

77061-58-6 68123-13-7

5-10 % 5-10 % 1 – 5% 1 – 3 %

Inf 1%









attention.

This product may cause an allergic reaction. Wash hands thoroughly after use







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Storage:Shelf life: 5 years from the manufacturing date s if







·


APPEARANCE: Viscous liquid BOILING POINT: Approx. 100 ºC FLASH POINT: Not applicable VAPOUR PRESSURE: Not Determined SPECIFIC GRAVITY:1.0 -1.10g/mL FLAMMABILITY LIMITS: Not Combustible pH: 4.5 – 6.5

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SOLUBILITY IN WATER: Completely soluble

·




·



next exposure data:

Exposure:

Area (cm2) 1440

Frequency (daily) 1




It is considered the area of the hands and the middle of the head (1440

cm2), the frequency of application is once a day, the estimated daily

amount applied is 10460 mg, and the retention factor is 0.01, so is a

rinse-off product. The absorption is 100%.



Skin irritation

YES

0.0726 mg/cm2 per day

Per kilogram of body weight (for 60 Kg

body weight):

Widespread

toxicity

YES


Bibliographic data:

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− SCCS’s Notes of guidance for the testing of cosmetic substances

and their safety evaluation, 10th revision.

− RIVM report 320104001/2006 Cosmetics Fact Sheet





















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this product.




·

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TEKNIA REFRESH MASK


PRODUCT NAME/CODE: Teknia REFRESH MASK PRODUCT USE: To conditioner hair MANUFACTURER: Lakmé Cosmetics S.L.U. C/ Narcís Monturiol, 27 08960 Sant Just Desvern Barcelona (SPAIN) Telephone number: + 34 934700155





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Cationic surfactants such as: Certrimonium chloride Behentrimonium chloride May content:

EX D&CVIOLET Nº 2 (CI60730) BASIC RED 51 BASIC BLUE 99

112 - 02 – 7

17301 - 53 – 0

4430-18-6 77061-58-6

68123-13-7

<2.5 <2.5

Inf 1%









attention.

This product may cause an allergic reaction. Wash hands thoroughly after use








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·



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·






next exposure data:

Exposure:

Area (cm2) 1440

Frequency (daily) 1









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Skin irritation

YES



Widespread toxicity

YES


Bibliographic data:
















the use of this material. The user of this material has the responsibility to dispose of unused material, residues and containers in compliance with all relevant local, national and EU

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laws, directives and regulations regarding treatment, storage and disposal for hazardous and non-hazardous wastes









·










this product.




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