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BARTON SOLVENTS Onc.COUNCIL BLUFF* BRANCH ^^JF

tO BOX 456 • 2135 9rhAVENUC • COUNCIL BLUFFS, tOWA 51502* I»HONE (712)3222509

October 27, 1989

Liberty Cleaners1061 25th AvenueColumbus, Nebraska 68601

enclosed Material Safety Data Sheec(s) is being sent to you for yourreference and information on the product(s) you have recently purchased frc-nfcarton Solvents, Inc , either as a new customer or an additional product

information contained in these Material Safety Data Sheet(-») meets require-ments under the OSHA Hazard Communication Standard (29 CFR 1910 12f»0) Youare required by this standard to provide copies of these Material Safety DataSheets to all employees, contractors or agents who may be exposed to thehazards associated with the product(s) Please make certain copies are distributedto the proper personnel or departments within your company

Barton Solvents, Ire will continue to update your company with any naw infor-mation pertaining to this product(s)

If you have any questions, please <ontact your Barton Solvents' representa-tive

Very truly yours,

BARTON SOLVENTS, INCCouncil Bluffs Branch

Richard F, KlementBranch Manager

RFK/kd

DATA SHrETS-Dowper Solvent

0»

M A T E R I A L S A F E T Y D A T A SHEEJDow Cbeaical U.S.A.*. Midland, MI 48674 Emergency Phone: 517-636:4400

"froduct Code. 25202

PRODUCT KAME: DOWPER (R) SOLVENTEffective Date. 07/28/83 Date Printed. 08/0V89 '

Page. 6

-MSDS 000190

9. ADDITIONAL INFORMATION. <CONTINUED)» *

j.* delayed health hazard

CALIFORNIA PROPOSITION 6$: The following statement is made inorder to comply with the California Safe Or inking Water andToxic Enforcement Act of 1986 (see Section 6 above for woredetails): This product contains a chemical (s.) known to theState of California to cause cancer.

SOCIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Handle•with reasonable care and caution Avoid breathing vapors.Vapors of this product are heavier than air and will collect Jn

' low areas such as pits, degreasers, storage tanks, and otherconfined areas Do not enter these areas where vapors of thisproduct are suspected unle< s special breathing apparatus isused and an observer is prtient for assistance

MSDS STATUS Revised Section I 'f

SARA 313 INFORMATIONThis product contains the l o l l owing substances subject toreporting requirements of section }13 of Title 1 I I of theSuper fund Amendments and Rf authorization Act of 1986 andtt> CFR Part 372:

the

CHEMICAL NAME

PERCHlOftOETHYLENE

CAS NUMBER CONCENTRATION

OOOU7-18-4, 99.$

(R) Indicates a Trademark of The Do* Chemical CompanyThe Information Herein Is Given In £ood Faith, But Ho "Warranty,Express Or Implied, Is Made. Consult The Dow ChemicalFor for trier Information. - ' }

K

An Operating Unit «f The Dow Chemical Company

»-

S A f £ T T D A T A S H E TU.S.A.* Midland. MI 48674 Energem? Phont: 517-636-4400

- Product Code: 2^202

PRODUCT HAKE: OOWPER (R) SOLVENT •Effective Date: 07/26789 Date Printed. O8/QV89 .'

Page: 5

' 'K6BS.OOOT90

8. HAWJLINfi PRECAUTIONS: (CONTINUED) " 'ven t i l a t ion may be necessary for some operations.

- . concentrations may exist in areas wvth poort*thal

R£SPIfiATORY PftOTfCTJOW; Ataospheric levels should be maintainedbelow the exposure gu-tdeline. When respiratory protection 'is

', -required for certain operations, use an approved air-pur i f ying'respirator. For emeroency and other conditions where theexposure guideline nay be greatly exceeded,' -use an approved

, positive-pressure se}/ -contained breathing apparatus or positive. v pressure *»H me with auxHHary self-contained air supply. >n

confined or poorly ventilated areas, use an- approved positive"pressure «eJf-*contained air breathing apparatus. ^

i * - \. *SKIN PROTECTION: For brief contact, no precautions other than

clean body-covering clothing should be needed When prolongedor frequently repeated cottact could occur, use protectiveclothing impervious to this material Selection of specific

v> Items such BE gloves, boots, apron, or full body suit w i l ldepend on operation

EYE PROTECTION; Use safety glasses Where contact withis likely, chemical goggljs are recommended because eye contactwith this material may ca j&e dj (comfort, even though it isunlike)/ to cause injury \r

9, ADDITIONAL INFORMATIONR E G U L A T O R / R E Q U I R E M E N T S :

SARA HAZARD C A T E G O R Y . Th i s product has been reviewedaccord ing to the EPA ' H a z i r d Ca tegor ies ' promulgated underSections 31» and 312 of t >e Super fund Amendment *ntff t eau tho - i za t i on Act of 19(6 (SARA T i t l e Ul) and isconsidered, under apphca t le d e f i n i t i o n s , to peet thef o l l o w i n g categories: 5

i

An unmedJate health bazar i ' ;' "\*

(Continued on Page 6)(R) indicates a Trademark of The tow Chemical Conpany f

5*

* An Operating Knit of The Dow Chnicai Company

O

N

1

M AJ E * I A L S_A_FJ TY D A T A S H E E T _

fow CnaBlcal ILSJL* Midland, MI 48674 Erergeno Phone. 517-636-4400"^ , - Product Code 25202 Page- k

PRODUCT fW4E: DOWPER (R) SOLVENT

Effective Date. 07/28/89 Hate Printed: 08/OV89 MSDS:000190

6. WEALTH HAZARD DATA: (CONTINUE))toxic effect* to the mo the . Results of in Vitro (Jtest tube1)

- imjt agent city tests have bean negative.

7. AID:Irrigate immediately with water for at least 5 minutes.

,SK1ti: Wash o£f if\ T lowing w< ter or shower.

JNCEETIDN- Do not Induce vorntmg. Call a physician and/ortransport to emergency facility immediately.

INHALATION- Remove .to fresh air. If not breathing, give*

wouth-to-mouth /esusci tat icn if breathing it difficult, giveoxygen. Cell -a" physician

» t-

-WfiT£ TO PHYSICIAN; Because rapid absorption may occur throughlungs if aspirated and cause systemic effects, the decision ofwhether to induce vomiti-ng or not should be cwde by aphysician. J{ favage is performed, suggest endotr«cheal and/oresophageol control- Danger from lung aspirat ion must beweighed against tox ic i ty when considering emptying the stomachIf burn is -present, treat as any thermal burn, afterdecontamination, txposure nay increase "wyocardielirr i tabi I ifcy". &o not administer sympathomime^c dr<ig6 unlessabsolutely necessary No speci f ic antidote Supportive care.

•> ^reatfflent based on judgment of tfee physician^n response tofr-eactions »f the patunt ( *-\ v '^-; -. : , • '- :/" - -

%. ftAWDLlNS P«EC*TiWS: ' ' ' - f ' X ~,

CUlfif LINENS)' Perch loroethylene OSHJi PEl Is' 25 PP»TWA. ACGIM TVV i.s $0 ppa TM, ST^L is 200 ppm . . ,.

" ". 'VUfTlt.*TION: tontfo' airborn* concentrations l»elow the exposure

BuideUne. Use only Vith alequate vent (lit Ion. local exhaust» « ( 'i, > \ ~ *

• j-l tJI -> ,<, » K " t '

(Continued on Page 5) ' *•" j '"" ^ "-IndJcaxes a Trademark' of The ton Chemical Company' ,. . "

f

.An Operating Unit t>f T^e Dow Chew cal Company

" ' '

RV

M A T E R I A L S A F E T Y D A T A S H E E T~ —— ,— «•»_. — >.. — — . ————— . — . — _ ——— ________ —————— __ — . —— ___. _ _Dow 'Chemical U.S.A.* Midland, MI 48674 Emergency Phone: 517-636-4400

i •* **

Product Code* 25202 Page: 3

PRODUCT NAME. DWPER (R) SOLVEKTDate 07/28/89 Date Printed 08/OV89 MSDS'000190

,j6. «|AITH HAZARD DATA. (CONTINUED)- JSKIN ABSORPTION: A single prolonged exposure is not l i k e l y to

result in the material being absorbed through skin in harmfulf-« amounts. The 1050 for skin absorption in rabbits 4s > 10,COO

mg/kg '

>f»GESTION: Single dose oral toxictty is low. The LD50 for rats--^ _ is >50OO mg/kg. If aspirated (liquid enters the lung), may be"" rapidly absorbed through the lungs and result in injury to

other body systems

INHALATION. In confined or poorly ventilated areas vapors can,' readily accumulate and can cause unconsciousness and death

", Dizziness may occur at 200 ppm, progressively higher levels mayalso cause nasal irritation, nausea, incoordination, drunkeness;and over 1OOO pom, unconsciousness and death A single brief(minutes) inhalation exposure to levels above 6000 ppm may bef immediately dangerous to life. Based on structural analogyand/or equivocal data in animals, excessive exposure maypotent/ally increase sensitivity to epinephrine and increasemyocardial irritability (irregular heartbeats). Alcoholconsumed before or after exposure may increase adverse effects

-- • SYSTEMC £ OTHER EFFECTS Signs and symptoms of excessiveI- SJ ^ - -exposure may be central nervous system effects and anesthetic; ' ' or narcotic effects. Observations in animals include liver «nd'. _ , kidney effects For hazard communication purposes under

OSHA Standard 29 CFR Part 1910 1200, this chemical is listed as| a potential carcinogen ty IARC. Perchloroethylene has been

shown to Increase the rite of spontaneously occurring rralignant' ~ tumors 4n certain laboratory rats and mice. Other long-term[ j inhalation studies in n ts failed to show tumongemc response[ t. Epidemiology .studies arc limited and have not established anSc - " ^ a&cocibtion between perch)oro«thylenc exposure and «c»ncer. <>er-\ ^ ch)oroethylef>« is fx>t believed to pose a measurable carcinogenicI " risk to man when hand lee as recommended Girth defects areI " unlikely. 'Exposures having no effect on the mother should haveL ^ no effect on the fetus Did not cause birth defects in animals,if - * other effects were seen in the fetus only at doses which caused

on(ft) Indicates a Trademark of The Dow Chemical Company

* An Operating Unit of The Dow Chemica l Company*

V. *-*si

^ M A T E R I A L S A F E T Y D A T A S H E E TBow ChealcAl U.S.A.* Midland, MI 48674 Enerjency Phone: 517-636-4400

Product Code: 25202 Page 1

PRODUCT NAME: DOWER (R) SOLVENT -Effective Datet 07/28/89 Date Printed- 08/04/89 nSDS 000190

1. INGREDIENTS: (* w/w. unless otherwise noted). ' TetrachJoroethylene C*S# 000127-18-1. J9 9*

»This document is prepared pursuant to the DSHA HazardComnumcation Standard (29 CFR 1910. J200) . In addition, other

- substances not 'Hazardous1 per this OSHA Standard {&ay belisted. Where proprietary ingredient shows, the identity

- may fce made available as provided in this standard.

2. WiYSICAL DATA:BOILING POINT: 250F (121. 1C)VAP PRESS. 13 mmHg «. 20(VAP DENSITY: 5-?6SOL. IN WATER- 0 015 g/100g 25C

- SP. GRAVITY. I 619 £ 25/25CAPPEARANCE: Colorless liquid.BOOR Ether-like

3. FIRE AND EXPLOSION HAZARD DATA:k FLASH P O I N T - Hone

-KETKOD USED. TCC, TOC, COC

FLAftMABlE L I M I T SiFL. NoneU F L . None

E X T I N G U I S H I N G WED I A. Non - f I aranab I e natenal

F i R E ft IXPLOSION HAZARDS: Mo auto lonil Ion temperature

f I R E - F I G H T I N G EQUIPMENT. Wear positive pressure self-contained- respiratory equipment.

(Continued on Page 2)<ft) Indicates a Trademark of The Dow Chemica l Company

* An Operating U n i t of The Dow (Jienlcal Company

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MATERIAL SAFETY DATA SHEET(ESSENTIALLY SIMILAR TO FORM OSHA-20)

SEE IMPORTANT NOTICE ON BOTTOM OF OTHER SIDE?4 Hour Emergency Phone (316) 524-5751

1 • PRODUCT IDENTIFICATIONMAHUTACTOReTg NAME AND ADOflEW

ViOcn Htr/irialu Gcnpvrt O*»<nili> Dtvixico, P. 0. BOK 7689, XL 35253-0689CHEMICAL NAME CHEMICAL FORMULA

CQ-2 "TMAOC HAME AND 9«MON>«0 OMEMtCAL FA»*LY

Chlorinated HydroDOT OeMTWCAT ION NO

W1897

' f

r>< > -"' ». HAZARDOUS WGREOIEWTSMATEItiAL-OR COMJ>CN» T

. ,-f

100 lO&ffBl

<r III- PHYSICAL DATA

BwKJNQ lippfr (V j icAfraOur

KATOR ffCSSUAE(ran He) (J2Q«C 13

WDftOEMinrtAM-t) 5>g

iBOmMJTYM WATER « flTwrn/lflOfcm B IV1I v * " V*v*-JJCDV A\AJ D C J ^ ^ v

SPECIFIC ORAVmr (HgO-1)

PERCENT VOLATILEBY VOLUME (*)

EVAPOAATON WkTE(etter-1)

APPEARAKZ AND OOOft

1.6

100

0.09Colorless cltmr liquid,taOdly sweet odor.

IV - RRE Ah D EXPLOSION HAZARD DATAPLASH POWT (Meted MM •

Ifaoe OEC)

Not ApplicableS^eCML IVe FIQKTMG PHOCEOUflES

Self-coatalned breadrlag appaxatus should be usedUNUSUAL n*E AND EXPLOSION HAZARDS Cabcentr«tcd vapors

beat source. Tteooapcaition produces ryirogen chin

FLAMW/JLE UMTTS lcM«r UppwNone

in areas where perdaloraettylene IB stoced.«I.ll deconpose on contact «J rh Wgji incaan

ride.Ity

V • REACTIVITY DATA

8T/BU

a womoNS TO MOD

Contact with opea flane, bat surfor electric arcs

Stroqg

chloride, pteBgeoe (gall aaauota)

«C JUK <OLYMEfXZWeN

MAY OCCURCONDITIONS TO AVOID

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r

* i^ !%

VI HEALTH HAZARD DATAOSXA PEAMissiaLE EXPOSURE LIMIT 100 ppn 8 hour THA, 200 ppn celling; 300 ppn peak for

J. S*dn*ss in any 3 hours. (29CPR Part 1910.1000)Jg&Bt

EfPBCTSOF OVENE»"08UBE,

route cf opoeure - Acute ovezexposutea above 800 ppn range can cause li£it-headednaaa,headache, vertigo, droolnesft, narcosis, tnoonBdLousneas and even death In

*ln exposure can cause burning sensation. Repeatedj,JgTltatSag and aay cauae sli^tt daaatltia and defattiqg cf akin.

are alldly

WOESTONcf ikpoaure* Inges clan of aoall quarciti B is not likely to be

Liquid la alldly Irritating to tire eves. Ooneal injury is vnlikely.

FIRST AID PROCEDURES

cootacLnaced clothing and flush exposed areas with water for 5 to 15 nLnutes.NfrtALATtQNlaaove to fresh air. If breatMqi has stopped, administer respiration or oxygen if available.MQESTONtk> not Induce vanttirg. Call phyi Idan and obtain aedlcal attectloa.________________

VII - S >tLL OR LEAK PROCEDURESSTEPS TO BE TAKEN Hi CASE MATERIAL IS RELEASEC OR SPILLED

Evacuate tie area, ventilate, wad breathing vapors, contain spill, dean up area (tearprotective clothing) by napping o with absorbent mart-rial, transfer to closed container.

WASTE DISPOSAL MET noo Recovered liquid usay be sent to a licensed reclaimer or Incinerated^ Con-tandnated ibsorbent OBterial aist be disposed cf In a permitted waste nanageoent facility.Consult federal, state or local disposal authoritiuB for approved procedures.____________

VUI - SPE AL PROTECTION INFORMATION

fiPfCffHC PERSONAL f HDTECTfVE EOUPMEWTRESPIRATORY Mone tequtred v^ien u «d with adequateEVE "CbeaLeal safety gaggles. Contact lerHes should not be WJTO.SKINOTHER

Solvent resistant g] yves such as Vltoi, WA or equivalent.Protective headgaar t apron when splashing is a problem.

VEKDLATON REOAHRI MEHTSSuf f ideot to BBintain below PEL.

IX • SPECIAL PRECAUTIONS

*»H6CftUTO*STOBE rAW-Hi* HANDLING AW STOP wa Avoid contact with skin & avoid breathing vapors. Pipevents outdoes 3, Store in cool, dry, mcntiJatad area. Vapors are heavier than air and will collectin low araas.

Prevent aoist al: froa entering st-orage. No annVIng In presence of vaporB.

«KTC 19840«tierte>rTwtioocorB»kiedcrlt« Thei

VMCtL

ctaw of pubtodiion They art not rwceasarfty ilHncLiBive nor fifty adequate m every arcumslancs Ate the!jlouxu rules or insurance raquovmerMORBMXiEO, Of KRCHAMTABUTY, flTMW* OR OTHERWSE B MADE.

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