Page 1
Ma 8"^Your P.O. # :7052Your C.O.C. #: 4099541
Sl lces i Thr cu g i r Scr - * r i ce
Report Date: 2OL4 | O2l 03Report#: R2832502
Version: 1
Attention:Bill WoneWSH Labs38518 - 21 St NECalgary, ABT2E 6T5
CERTI FICATE OF ANALYSISMAilGM JOB #:8411519Received : 2AL4 | 0L | 23, 09 :30
Sample Matrix: Water# Samples Received: 1
AnalysesDate Date
Quantity Extracted Analyzed Laboratory Method ReferenceDiuron, Guthion, TemephosGlyphosateHaloacetic Acids in Water (1)Nitrilotriacetic Acid (NTA)OC Pesticides (Selected) & PCB (2)OC Pesticides Summed ParametersODWS - Semi-VolatilesVOCs (Drinking Water)
L 20L4/0u28L 2014/0L/27L 20L4/01/27L 2014/0L/23L 20L4/AL/241 N/Ar 20r4/0L/241 N/A
EPA 532HPLC in-house methodBased on EPA 552.2EPA 430.1sw846 8081,8082sw846 8081,8082EPA8270 modifiedEPA 8260
2OL4/0t/3020L4/Otl282014/02/0220L4/Otl2420r4l0r/282OL4/0r/2420L4/0u2s2Ot4/Otl29
cAM SOP-00306cAM SOP-00305ATL SOP 00129cAM SOP-00411cAM SOP-00307cAM SOP-00307cAM SOP-00301cAM SOP-00226
* RPDs calculated using raw data. The rounding of final results may result in the apparent difference.(1)This test was performed by Maxxam Bedford(2) Chlordane ( Total ) = Alpha Chlordane + Gamma Chlordane
Validated by :
,r"/- , JamesAspinL f f i -
/4' 04 Feb 2014 13:54:33 -05:00
Rose MacDonaldScienti f ic Special ist (Orga nics)
Total Cover Pages : 1Page 1 of 20
Page 2
,/iMaXXaml/
Maxxam Job #: 84L1519Rep o rt Date: 20t4 / 02 / 03
5lr:cr:gs Thir:r i gh 5ciei lce,
WSH LabsYour P.O. # :7052
HALOACETTC AC|DS By GC-ECD (WATER)
Page 2 of 20
Mlan<am lD uQ5072iampling DateCOC Number A099641
Units 74279 RDL QC Batch
Miscel laneous ParametersMonochloroacetic Acid (MCAA) u8/L ND 5.0 3498093Monobromoacetic Acid (M BAA) uglL ND 5.0 3498093Dichloroacetic Acid (DCAA) ug/L 5 .1 5.0 3498093Irichloroacetic Acid (TCAA) uelL ND 5.0 3498093Bromochloroacetic Acid (BCAA) us/L ND 5.0 3498093)i bromoacetic Acid (DBAA) uglL ND 5.0 3498093lotal haloacetic acids uslL 5.1 5.0 3498093Surrogate Recovery (%)2,3-Dibromopropionic Acid % t04 N/A 3498093RDL = Reportable Detection LimitQC Batch = Quality Control BatchND = Not detectedN/A = Not Applicable
Page 3
,/iMayamMaxxam Job #: 8411519Repo rt D ate : 2014 / 02 / 03
5 iiir:r:i-c Ii ': i ctr g ii $ci*rii:€,i i
WSH LabsYour P.O. #:7052
oRGANOCHLORTNATED PEST|CIDES By GC-ECD (WATER)
Page 3 of 20
Maxxam lD uQ6072Sampling DateCOC Number A099641
Units 74279 RDL QC BatchCalculated ParametersAldrin + Dieldrin uglL ND 0.00634908463hlordane (Total) uglL ND 0.0063490846)DT+ Metabolites uslL ND 0.0063490846Heptachlor + Heptachlor epoxide uglL ND 0.006 3490845c,p-DDD + p,p-DDD uelL ND 0.005 3490846r,p-DDE + p,p-DDE uglL ND 0.005 3490846o,p-DDT + p,p-DDT uelL ND 0.0063490846Total PCB uglL ND 0.05 3490846Pesticides & HerbicidesLindane uglL ND 0.0063492331Heptachlor uglL ND 0.006 349233L\ldrin uglL ND 0.006349233LHeptachlor epoxide uglL ND 0.006349233LCxychlordane uglL ND 0.006349233Lg-Chlordane uglL ND 0.006349233La-Chlordane uglL ND 0.006 349233LDieldrin uglL ND 0.006 3492331c,p-DDE uglL ND 0.006 349233Lc,p-DDE uglL ND 0.006 349233tr,p-DDD uglL ND 0.006 3492337r,p-DDD uelL ND 0.0063492331o,p-DDT uelL ND 0.006 349233Lo,p-DDT UElL ND 0.006 349233LVethoxychlor uglL ND 0.02 3492337Aroclor 1016 uglL ND 0.05 3492337Aroclor 1221 uelL ND 0.05 349233LAroclor 1232 u8/L ND 0.0s 349233r\roclor L242 uelL ND 0.05 349233L{roclor 1-248 uslL ND 0.05 3492337\roclor L254 uelL ND 0.05 349233LAroclor 1-250 uglL ND 0.0s 349233LRDL = Reportable Detection LimitQC Batch = Quality Control BatchND = Not detectedN/A = Not Applicable
Page 4
,/iMaXXaml./
Maxxam Job #: 84LL519Report D are: 2014 / 02 / 03
ii u,:c * g : f h lr:r"r lj [r Sc ie r-.ce,,,,
WSH LabsYour P.O. #:7052
oRGANOCHTORTNATED pESTtCtDES By GC-ECD (WATER)
Page 4 of 20
Manam lD uQ6072Sampling DateCOC Number A099641
Units 74279 RDL Qc Batch2,4,5,6-T etra ch I oro-m-xyle n e % 81 N/A 3492331,)ecachlorobiphenyl % 80 N/A 349233LRDL = Reportable Detection LimitQC Batch = Quality Control BatchN/A = Not Applicable
Page 5
,/iMa#amMaxxam Job #: 8411519Report Date: 20L4 / 02 / 03
5uc:( i$s I hl 'cirgh SciEnceo
WSH LabsYour P.O. # :7052
PESTTCTDES & HERBTCTDES By HPLC (WATERI
Page 5 of 20
Man<am lD uQ6072lampling DateCOC Number A099641
Units 74279 RDt QC BatchPesticides & HerbicidesGlyphosate uglL ND 10 3494706Diuron uelL ND 10 3495563Guthion (Azinphos-methyl)uelL ND 2 3495563Iemephos uglL ND 10 3495563RDL = Reportable Detection LimitQC Batch = Quality Control BatchND = Not detected
Page 6
,/'IMayamMaxxam Job #: 84115L9Re port D ate: 20L4 / 02 / 03
i i i , -c " -s : - t - ; , i , -ug l i Sc ience, '
WSH LabsYour P.O. # :7052
RESULTS OF ANALYSES OF WATER
Miscellaneous ParametersNTA mslLl o.rz lo.osl 34et6e4IDL = Reportable Detection LimitLC Batch = Quality Control Batch
Page 6 of 20
Manam lD uQ6072Sampling DateCOC Number A099641
Units 74279 RDL QC Batch
Page 7
./iMa{/amL/
Maxxam Job #: 8411519Report D ate 2014 / 02 / 03
WSH LabsYour P.O. # :7052
sEMr-voLATtLE ORGANTCS By GC-MS (WATER)
Page 7 of 20
Maxxam lD uQ6072Sampling DateCOC Number A099641
Units 74279 RDL QC Batch
Semivolatile Organics2,3,4,6-T etra ch lo ro p he n o I uglL ND 0.50 34922472,4,5-T uglL ND 1.0 349224I2,4,6-T richlorop h e n o I uelL ND 0.s0 34922412,4-D uglL ND 1.0 349224r2,4-Dichlorophenol uglL ND 0.s0 349224tAlachlor ug/L ND 0.s0 3492247\ldicarb uglL ND 5.0 349224L{trazine uglL ND 0.50 349224LDes-ethyl atrazine uglL ND 0.50 349224LAtrazine + Desethyl-atrazine uelL ND 1.0 349224tBendiocarb uglL ND 2.0 349224L3romoxynil ug/L ND 0.50 34922473arbaryl uelL ND 5.0 349224!Carbofuran uglL ND 5.0 349224LChlorpyri fos (Du rsban) UglL ND 1_.0 349224LCyanazine (Bladex) uelL ND 1.0 3492241Diazinon uglL ND 1.0 349224LDicamba uelL ND L.0 3492241Diclofop-methyl uglL ND 0.90 349224L)imethoate uelL ND 2.5 3492241)inoseb uglL ND 1_.0 3492241Vlalathion uglL ND 5.0 349224LMetolachlor uglL ND 0.s0 349224LMetribuzin (Sencor) uglL ND 5.0 349224tthyl Parathion uglL ND 1.0 3492241
)entachlorophenol ue/L ND 0.50 3492241Phorate uglL ND 0.s0 3492241Picloram uglL ND 5.0 349224LPrometryne uelL ND 0.25 349224tSimazine uglL ND 1.0 3492241Ierbufos uglL ND 0.s0 349224LIria llate uglL ND 1.0 349224Ll-rifluralin uelL ND 1_.0 349224LBenzo(a)pyrene uglL ND 0.0090349224LMethyl parathion uglL ND L.0 3492241RDL = Reportable Detection LimitQC Batch = Quality Control BatchND = Not detected
Page 8
,/iMayamMaxxam Job #: 8411519Report D ate: 2014 / 02 / 03
WSH LabsYour P.O. # :7052
sEMr-voLATrLE ORGANTCS By GC-MS (WATER)
Page 8 of 20
Mlaxxam lD uQ6072iampling DatelOC Number 4099641
Units 74279 RDL QC Batch
Surrogate Recovery (%f2,4,6-Tribromophenol % 94 N/A 349224L2,4-Dichlorophenyl Acetic Acid % 101 N/A 349224L2-Fluorobiphenyl % 85 N/A 349224r)14-Terphenyl (FS) % LLL N/A 3492241D5-Nitrobenzene % 86 N/A 349224IRDL = Reportable Detection LimitQC Batch = Quality Control BatchN/A = Not Applicable
Page 9
,/iMayamMaxxam Job #: 8411519Report D ate : 20L4 / 02 / 03
Srr tcess T l t i , :u1 lh Se ience, , ,
WSH LabsYour P.O. #:7052
VoLATTLE ORGANTCS By GCIMS (WATER)
Page 9 of 20
Malo<am lD uQ6072iampling DateCOC Number A099641
Units 74279 RDL Qc Batch
Volatile OrganicsL,1-Dichloroethylene uelL ND 0.10 34940791,2-Dichlorobenzene uglL ND 0.20 34940791,2-Dichloroethane uglL ND 0.20 34940791,4-Dichlorobenzene ue/L ND 4.20 3494079Jenzene ug/L ND 0.10 3494079lromodichloromethane u8/L 3.4L 0.10 3494079Bromoform us/L ND 4.20 3494079Carbon Tetrachloride ue/L ND 0.10 3494079Chlorobenzene U8/L ND 0.10 34940793hloroform UglL 9.32 0.10 3494079Dibromochloromethane uglL 1.47 0.20 3494079Methylene Chloride(Dichloromethane)uelL ND 0.50 3494079Ethylbenzene uelL ND 0.10 3494079Methyl t-butyl ether (MTBE) uelL ND 0,20 3494079letrachloroethylene uelL ND 0.10 3494079Toluene uglL ND 0.20 3494079Irichloroethylene uelL ND 0.10 3494079/ iny lChlor ide uglL ND 0.20 3494079r-Xylene ue/L ND 0.10 3494079p+m-Xylene uelL ND 0.10 3494079Iotal Trihalomethanes uelL L4.2 0.20 3494079Surrogate Recovery (%|4-Bromofluorobenzene % 93 N/A 3494079) 4-L,2-Dichl o roet ha n e % 87 N/A 3494079D8-Toluene % 95 N/A 3494079RDL= Reportable Detection LimitQC Batch = Quality Control BatchND = Not detectedN/A = Not Applicable
Page 10
./iMayamMaxxam Job #: 8411519Report Date: 20L4 / 02 / 03
WSH LabsYour P.O. #:7052
GENERAL COMMENTSTotal haloacetic acids refers to the total of monochloroacetic acid, dichloroacetic acid, trichloroacetic acid, monobromoacetic acid and dibromoaceticacid.
HAA samples received in the lab above the recommended temperature of 10"C.
Results relate only to the items tested.
Page 10 of 20
Page 11
,/iMayamMaxxam Job #: 8411519Re port D ate: 20L4 / 02 / 03
Iir.r icsss -fhfough
5ct*nce r.,
WSH LabsYour P.O. #:7052
QUALTTY ASSU RANCE REPORT
Page 11 of 20
QA/ACBatch
Date
349L694349L694
349L694
349t6943492241
3492241 WZ Spiked Blank
QC Type ParameterMatrix Spike [UQ6071-04] NTASpiked Blank
Method Blank
RPD [UQ607L-04]Matrix Spike
NTA
NTA
NTA2,4,6-Tribromophenol2,4-Dichlorophenyl Acetic Acid2-FluorobiphenylD14-Terphenyl (FS)D5-Nitrobenzene2,3,4,6-F etra ch loro p h e n ol2,4,5-T2,4,6-T richlo ro p h en ol2,4-D2,4-DichlorophenolAlachlorAldicarbAtrazineDes-ethyl atrazineAtrazine + Desethyl-atrazineBendiocarbBromoxynilCarbarylCarbofuranChlorpyri fos (Dursban)Cyanazine (Bladex)DiazinonDicambaDiclofop-methylDimethoateDinosebMalathionMetolachlorMetribuzin (Sencor)Ethyl ParathionPentachlorophenolPhoratePicloramPrometryneSimazineTerbufosTrial lateTrif lural inBenzo(a)pyreneMethyl parathion2,4,6-Tribromophenol2,4-Dichlorophenyl Acetic Acid2-FluorobiphenylD14-Terphenyl (FS)D5-Nitrobenzene2,3,4,6-T etra c h Iorop he n ol2,4,5-T2,4,6-F richlorop h e n o I2,4-D2,4-DichlorophenolAlachlorAldicarbAtrazineDes-ethyl atrazineAtrazine + Desethyl-atrazineBendiocarbBromoxynilCarbarylCarbofuran
10899
ln i tEAXEAX
EAX
EAXwz
Ana Value
ND,RDL=0.05
NC
Units QC Limits% 75 -125% 75 -L25
mglL
% 2 5% 30 - 130% 3 0 - 1 3 0% 3 0 - 1 3 0o/o 30 - L30% 30 - 1_30% 30 - 130% 30 - 130% 30 - 1_30% 30 - 130% 30 - 130% 40- 130% 70 -L30% 30 - 130% 3 0 - 1 3 0% 30 - 130% 40-130% 4 0 - L 3 0% 40- 130% 40- 130% 40 - 130% 40 - L30% 40 - 130% 30 - 1_30% 40- 130% 40 - L30% 40- 130% 40- 130% 40 - 130% 40 - L30% 4 0 - 1 3 0% 2 5 - 1 3 0% 40 - 130% L0- 130% 30 - 130% 4 0 - 1 3 0% 40 - 130% 40 - L30% 40 - 130% 30 - 130% 30 - 130% 30 - 130% 3 0 - 1 3 0% 30 - 1_30% 3 0 - 1 3 0% 30 - L30% 30 - 130% 30 - 130% 3 0 - 1 3 0% 3 0 - 1 3 0% 3 0 - 1 3 0% 40 - 130% 70 - 130% 3 0 - 1 3 0% 30 - 130o/o 30 - 130% 4 0 - 1 3 0% 40 - 130% 40 - L30% 40 - 130
2014/0L/2420L4/oLl24
20L4/0L/24
20L4/oLl2420L4/0L/24201.4/0L/242014/0L/2420L4/0L/2420!4/01.12420L4/0L12420L4/0L/242014/0t/2420L4/0L12420L4/0L/242074/0L/242014/0L/2420L4/0L/242014/0t12420L4/0L/242074/OLl242014/0L/2420L4/0L/242014/0t/2420L4/0L/2420L4/0L/2420L4/0L/2420L4/0L/242014/0L12420L4lOLl2420t4/01/242oL4/0L/242OL4/0U2420L4/0L/242OL4/0u2420L4/0L/242OL4/0L/242OL4/0L/2420L4/OLl242Ot4/0L12420L4/0L/24zot4/0L/242OL4/0L/242OL4/0L/242OL4/0L/2420L4/0L/242OL4/0L/2420L4/oLl242OL4/0L/242OL4/0L/242OL4/0L/242OL4/0L1242OL4/0L/242OL4/0t/242OL4/OLl242Or4/0L/242Ot4/0L/242OL4/0L/242OL4/0L/242OL4/0L/242OL4/0L/242OL4/0L/242OL4/Orl24
84886393519296779L65967L87396311591LL7L2710580848870478899L9874999L90489289851011.L61039696977510270104r04899981113100844665t22102118L234
Page 12
,/iMayamMaxxam Job #: 8411519Report D ate: 2OL4 / 02 / Og
Succ,::, : Tl:r e;u gh Scisnce{f.,
WSH LabsYour P.O. #:7052
QUALTTY ASSURANCE REPORT(CONT,D)
Page L2 of 2O
QA/qcBatch
DateQCT, Parameter Analvzed Value Units QC Limitsm
% 40- 130% 40- 130% 30 - 130% 40 - 130% 40- 130% 40 - 130% 40- 130% 40 - 130% 40 - 130% 40- 130% 25 - 130% 40- 130% 10 - 130% 30 - 130% 40- 130% 40 - L30% 40 - 130% 40- 130% 30 - L30% 30 - 1303492241 WZ RPD
Chlorpyrifos (Dursba n)Cyanazine (Bladex)DiazinonDicambaDiclofop-methylDimethoateDinosebMalath ionMetolachlorMetribuzin (Sencor)Ethyl ParathionPentachlorophenolPhoratePicloramPrometryneSimazineTerbufosTriallateTrif lural inBenzo{a)pyreneMethyl parathion2,3,4,6-T etra ch lo rop h e n ol2,4,5-T2,4,6-T richloro p h en ol2,4-D2,4-DichlorophenolAlachlorAldicarbAtrazineDes-ethyl atrazineAtrazine + Desethyl-atrazineBendiocarbBromoxynilCarbarylCarbofuranChlorpyrifos (Dursban)Cyanazine (Bladex)DiazinonDicambaDiclofop-methylDimethoateDinosebMalathionMetolachlorMetribuzin (Sencor)Ethyl ParathionPentachlorophenolPhoratePicloramPrometryneSimazineTerbufosTrial lateTrif lural inBenzo(a)pyreneMethyl parathion2,4,6-Tribromophenol2,4-Dichlorophenyl Acetic Acid2-FluorobiphenylD14-Terphenyl (FS)D5-Nitrobenzene
2,3,4,6-T etrach lo rop he nol
201,4/0L1242014/01/2420L4/0u2420L4/0L/2420L4/0L12420L4/01,/242AL4/01/2420L4/0u242At4/0L/2420L4/01/2420L4/01./2420L4/0L/242014/0r/2420L4/0U2420L4/0t12420L4/01,/242014/01/2420L4l0t/2420L4/011242014/0L/2420L4/01/2420L4/0L/2420L4/0L/242014/0u2420L4/0L/2420L4/0L/242014/0u242014/0u2420L4/0r/242At4/0L/24201.4/0L/2420L4/0L12420t4/0L/2420!4/0u2420L4/OLl2420L4/0L/2420L4/01/2420L4/0L124201.4/0L/2420L4/0L/2420L4/0L/2420L4/0L/242014/otl24201,4/0u242OL4/0L/2420L4/0L/242014/0L/2420L4/0L/242OL4/0L/242014/0L/242074/0r/2420L4/01./242OL4/0L/242074/0L/242014/0t/2420L4/OLl2420L4/0L/2420L4/0L/242OL4/Arl242At4/0L12420t4/0L/24201.4/0L/24
11678773961,tLLO7101L1,4110LO2LlL1011032211091971t2t27113L27
349224I WZ Method Blank
4.84.42.74.24.05.86.56.75.76.34.57.O4.25.94.810.57.04.55.16.64.86.94.68.95.08.37.9
34.28.82.88.77.05.14.85.8
% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 A% 3 0 - 1 3 0% 3 0 - 1 3 0% 3 0 - 1 3 0% 30 - 1_30% 3 0 - 1 3 0
UElL
92927210368
ND,RDL=0.50
Page 13
,/iMa{Xamt'/
Maxxam Job #: 84115L9Repo rt D ate : 2014 / 02 / 03
Stter:ess Tfiiir: !l i't 5c ii:lcu-,i
WSH LabsYour P.O. #:7052
QUAUTY ASSU RANCE REPORT(CONT' D)aA/acBatch
DateInit QC Ty Parameter Analvzed Value
ND,RDL=1.0
ND,RDL=0.50
ND,RDL=1.0
ND,RDL=0.50
ND,RDL=0.50
ND,RDL=5.0
ND,RDL=0.50
ND,RDL=0.50
ND,RDL=1.0
ND,RDL=2.0
ND,RDL=0.50
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=1.0
ND,RDL=1-.0
ND,RDL=1.0
ND,RDL=1.0
ND,RDL=0.90
ND,RDL=2.5
ND,RDL=1.0
ND,RDL=5.0
ND,RDL=0.50
ND,RDL=5.0
ND,RDL=1.0
ND,RDL=0.50
Units QC Limits
uslL
uelL
uglL
uglL
uglL
uelL
uglL
u'lL
uelL
2,4,5-T
2,4,6-T richloro p h enol
2,4-D
2,4-Dichlorophenol
Alachlor
Aldicarb
Atrazine
Des-ethyl atrazine
Atrazine + Desethyl-atrazine
Bendiocarb
Bromoxynil
Carbaryl
Carbofuran
Chlorpyrifos (Du rsba n)
Cyanazine (Bladex)
Diazinon
Dicamba
Diclofop-methyl
Dimethoate
Dinoseb
Malath ion
Metolachlor
Metribuzin (Sencor)
Ethyl Parathion
Pentachlorophenol
20L4/0L/24
20L4/OLl24
20L4/0L/24
20L4/0L/24
20L4/0L/24
201.4/0L/24
2014/0L/24
20L4/0L/24
20t4/0L/24
201.4/0r/24
2OL4/0t/24
2AL4/Otl24
2Or4/0L/24
20L4/ALl24
2014/0U24
2Ot4/OLl24
2014/0L/24
2014/oLl24
20L4/01/24
20L4/0L/24
2OL4/01,/24
20L4/Otl24
20L4/0t/24
2OL4/0L/24
20L4/Orl24
uglL
uslL
uelL
uglL
uelL
uglL
uelL
uelL
uelL
uelL
uelL
uslL
uglL
uelL
uglL
uglL
Page 13 of 20
Page 14
r / "MayamMaxxam iob #: 8411519Repo rt D ate: 20L4 / 02 / 03
Success ' i i , , cu , ; i r Sc ience,
WSH LabsYour P.O. #:7052
QUALITY ASSU RANCE REPORT(CONT' D)
Page 14 of 20
QA/acBatch
DateAnalyzed
2074/0L/28
20L4/0L/24
20L4/0L/24
20L4/OLl24
20L4/Otl24
20L4/OLl24
2014/oLl24
2074/OLl24
20t4loLl24
201,4/Otl2420L4/OLl2820t4/otl2820L4/0112820t4/oLl2820t4/oLl2820L4/Orl2820L4/OLl2820L4/0L/28201.4/0t/282AL4/0L/282074/01.12820L4/OLl28201.4/Otl2820L4/0L1282Ot4/OLl282014/oLl282OL4/0L/282014/0r/2820L4/01,/282OL4/0L1282Or4/0L/2820L4/0t/282OL4/0L/282OL4/OLl282014/otl2820t4/0L/282AL4/Au282014/0L/282014/0L/2820L4/0t/282OL4/0r/282ot4l0u282OL4/oLl282OL4/0r/282Or4/0L/282OL4/0u282OL4lALl282Ot4/0r/282OL4/0L1282A!4/0L1282OL4/0L/28
ValueND,
RDL=0,50ND,
RDL=5.0ND,
RDL=0.25ND,
RDL=1.0ND,
RDL=0.50ND,
RDL=1.0ND,
RDL=1.0ND,
RDL=0.0090ND,
RDL=1.0
Units QC Limits
uglL
uglL
uelL
uglL
uglL
uglL
uelL
uglL
uelL
% 30- 130% 30- 130% 30- 130% 30- 130% 30- 130o/o 30 - 130% 30- 130% 30- 130% 30- 130% 30- 130% 30 - 1_30% 30- 130% 30- 130% 30- 130% 3 0 - 1 3 0% 30- 130% 30- 130o/o 30 - 130% 30- 130% 3 0 - 1 3 0% 30- 130% 30- 130% 30- 130% 30- 130% 30- 130% 30- L30% 30- 130% 3 0 - 1 3 0% 3 0 - 1 3 0% 30- 130% 30- 130% 30- 130% 30- L30% 30- 130% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0
Init QC T
349233L FSO Matrix Spike
349233L FSO Spiked Blank
3492331 FSO RPD
Parameter
Phorate
Picloram
Prometryne
Simazine
Terbufos
Trial late
Trif lural in
Benzo(a)pyrene
Methyl parathion
2,4,5,6-T etra ch I oro- m-xyl e n eDecachlorobiphenylL indaneHeptachlorAldrinHeptachlor epoxideOxychlordaneg-Chlordanea-ChlordaneDieldrino,p-DDEP,P-DDEo,p-DDDP,P.DDDo,p-DDTP,P.DDTMethoxychlor2,4,5,6-I etrac h I o ro-m-xyle n eDecachlorobiphenylLindaneHeptachlorAldrinHeptachlor epoxideOxychlordaneg-Chlordanea-ChlordaneDie ldr ino,p-DDEP,P-DDEo,p-DDDP,P-DDDo,p-DDTP,P-DDTMethoxychlorL indaneHeptachlorAldr inHeptachlor epoxideOxychlordaneg-Chlordanea-ChlordaneDieldrin
68838074687868777685768085817474836687797064816978779078838784757382
3.76.97.54.85.55.05.15.4
Page 15
,/iMa(Xaml'/
Maxxam Job #: 8411519Report Date: 2014 / 02 / Og
5u;ces: Tl^;r *r: gf 'r Science,,. '
WSH LabsYour P.O. #:7052
QUALTTY ASSU RANCE REPORT(CONT' D)aA/acBatch lnit QC T Parameter
DateAnalyzed Value
5.02.44.54.73.94.04.8
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.006
ND,RDL=0.005
ND,RDL=0.006
ND,RDL=0.02
ND,RDL=0.05
ND,RDL=0.05
ND,RDL=0.05
ND,RDL=0.05
ND,RDL=0.05
ND,RDL=0.05
ND,RDL=0.05
Units%%%%%%%%o//o
uelL
uglL
uglL
uglL
uglL
uglL
uelL
uglL
uglL
uglL
uelL
uelL
uglL
uelL
uglL
uglL
uglL
uslL
uelL
uglL
UglL
uglL
QC Limits40404040404040
30 - 13030 - 130
o,p-DDEP,P.DDEo,p-DDDP,P.DDDo,p-DDTP,P-DDTMethoxychlor2,4,5,6-T etrach I oro-m-xyle n eDecachlorobiphenyl
L indane
Heptachlor
Aldrin
Heptachlor epoxide
Oxychlordane
g-Chlordane
a-Chlordane
Dieldrin
o,p-DDE
P,P-DDE
o,p-DDD
P,P-DDD
o,p-DDT
P,P.DDT
Methoxychlor
Aroclor 1016
Aroclor t22t
Aroclor 1232
Aroclor 1242
Aroclor 1248
Aroclor 1254
Aroclor 1260
2014/0L12820L4/0L/28
3492331. FSO Method Blank
20L4/0t/282OL4/0L/2820L4/0L/282014/01/282OL4/OLl282Ot4/ALl28201.4/0L/28
201.4/0L/28
20t4/0u28
20L4/0L/28
2014/0t/28
20L4l0L/28
2014/0L/28
2014/0L128
20L4/0L/28
2014/0L/28
2074/0u28
20L4/0t/28
20L4/0L/28
20L4/0L/28
2014/0L/28
20L4/0L/28
2014/aLl28
20L4/0u28
2014/0L/28
2014/0L/28
20L4/0L/28
20L4/0L/28
2014/0L/28
7087
Page 15 of 20
Page 16
./)Ma#amMaxxam Job #: 8411519Re po rt D ate: 20!4 / 02 / 03
.5 uic*s r: Thruru g ir 5c isr,t"-',i
WSH LabsYour P.O. #:7052
QUALTTY ASSU RANCE REPORT(CONT' D)DateaA/ac
Batch34%On
Init QCSLM Matrix Spike [UQ6O7L-071
ParameterffiD4-1,2-Dich loroetha neD8-Toluene1,1-DichloroethyleneL,2-Dichlorobenzene1,2-Dichloroetha ne1,4-DichlorobenzeneBenzeneBromodichloromethaneBromoformCarbon TetrachlorideChlorobenzeneChloroformDibromochloromethaneMethylene Chloride(Dichloromethane)EthylbenzeneMethyl t-butyl ether (MTBE)TetrachloroethyleneTolueneTrichloroethyleneViny lChlor ideo-Xylenep+m-Xylene4-BromofluorobenzeneD4-1,2-Dichloroetha neD8-Toluene1,1-Dichloroethylene1,2-Dichlorobenzene1,2-Dichloroetha ne1,4-DichlorobenzeneBenzeneBromodichloromethaneBromoformCarbon TetrachlorideChlorobenzeneChloroformDibromochloromethaneMethylene Chloride(Dichloromethane)EthylbenzeneMethyl t-butyl ether {MTBE)TetrachloroethyleneTolueneTrichloroethyleneViny lChlor ideo-Xylenep+m-Xylene4-BromofluorobenzeneD4-1,2-Dichloroetha neD8-Toluene
L,L-Dichloroethylene
L,2-Dichlorobenzene
1,2-Dichloroethane
1,4-Dichlorobenzene
Benzene
Bromodichloromethane
Ana Value Recovery Units QC Limits
3494079 SLM Spiked Blank
3494079 SLM Method Blank
20 10L8496L09948890LA792849498NC88TT29086LO494tLzLOz87871038696LL2949290LLI9787961001019711_59 I9110595Lt21068888938794
20t4/oLl2920L4/oLl2s20L4/0L/292oL4/0t12920L4/0L/2920L4/0L/2920L4/0L/2920L4/0u2e2014/0L/2920L4/0L/2920L4/01.12920L4/otl2920L4/0t/2s20L4/0L1292014/0L/2920L4/0L/292074/0L/2920L4/0L1292014/0L/2920L4/ALl2s20L4/0r/2920L4l0t/292AL4/OLl2820L4/0t/2820L4/0L/2820L4/OLl2820L4/Otl2820L4/01/282014/oLl2820L410L12820L4/0u282OL4/0L/28201,4/0L/282OL4/OLl282oL4/0L/282014/0L/282014/0L/2820L4/oLl282oL4/oLl282014/oLl282OL4/0L1282OL4/A1./2820L4/Otl282AL4/OLl282OL4/OLl2820L4/0t/2820L4lOLl282OL4/OLl2820L4/0L/28
2074/0L/28
20L4/0L128
2OL4/0L/28
2OL4/0L/28
2OL4/0t/28
ND,RDL=0.10
ND,RDL=0.20
ND,RDL=0.20
ND,RDL=0.20
ND,RDL=0.10
ND,RDL=0.10
% 70 -130% 70- 130% 70 - 130% 70 - 130% 70 - 130% 70 - 130% 70 - 130% 70- 130% 70 - 130% 70 -130% 70 - 130% 70 - 130% 70 - L30% 70 - 130% 70 - 130% 70 -73A% 70- 130% 70 - 130% 70 - 130% 70 - 130% 70 - 130% 70 - L30% 70 - 130% 70 - 130% 70 - 130% 70- L30% 70 - 130% 70 -730% 70 -730% 70 - t30% 70 - 130% 70 -L30% 70 -130% 70 -130% 70 - 130% 7 0 - 1 3 0% 70 - 130% 70 - 130% 70 -130% 7 0 - 1 3 0% 70 - 130% 7 0 - 1 3 0% 7 0 - 1 3 0% 70 - 130% 7 0 - 1 3 0% 7 0 - 1 3 0% 70 -130% 7 0 - 1 3 0% 7 0 - 1 3 0
uelL
uglL
uelL
uelL
uglL
uglL
Page 16 of 20
Page 17
,/iMayamMaxxam Job #: 841151-9Report D ate : 20t4 / 02 / 03
WSH LabsYour P.O. #:7052
QUALTTY ASSU RANCE REPORT(CONT' D)aA/acBatch Init QC
3494079 SLM RPD [UQ5072-071
Date
HKL Matrix SpikeHKL Spiked Blank
HKL Method Blank
Parameter
Bromoform
Carbon Tetrachloride
Chlorobenzene
Chloroform
Dibromochloromethane
Methylene Chloride(Dichloromethane)
Ethylbenzene
Methyl t-butyl ether (MTBE)
Tetrachloroethylene
Toluene
Trichloroethylene
Viny lChlor ide
o-Xylene
p+m-Xylene
TotalTrihalomethanes
L, l--Dich loroethyleneL,2-Dichlorobenzene1,2-Dichloroetha ne1,4-DichlorobenzeneBenzeneBromodichloromethaneBromoformCarbon TetrachlorideChlorobenzeneChloroformDibromochloromethaneMethylene Chloride(Dichloromethane)EthylbenzeneMethyl t-butyl ether (MTBE)TetrachloroethyleneTolueneTrichloroethyleneViny lChlor ideo-Xylenep+m-XyleneTotal TrihalomethanesGlyphosateGlyphosate
Glyphosate
Glyphosate
Ana
20L4/0u28
20L4/oLl28
20L4/0u28
2014/otl28
20L4/0L/28
2014/0L/28
20L4/0L/28
20L4/0u28
20L4/0L/28
20L4/0L/28
20L4/ALl28
20t4/0L/28
2oL4/0L128
20L4/0L/28
20L4/OL/2820L4/OLl2e20L4/ALl2920L4/0L12920L4/Ou2e20L4/0t/2920L4/0L/2e20L4/OL/2920L4/ALl292oL4/0L/292014/oLl292oL4/oLl2s2oL4/0L/2920t4/oLl2e20L4/OLl2s2OL4/OLl2s20L4/OLl2920L4/OLl292oL4/OLl292OL4/Orl2e20L4/OLl2920L4/0L/2e2OL4/Otl2720L4/OLl2720L4/0t/28
28
ValueND,
RDL=0.20ND,
RDL=0.L0ND,
RDL=0.10ND,
RDL=0.10ND,
RDL=0.20ND,
RDL=0.50ND,
RDL=0.10ND,
RDL=0.20ND,
RDL=0.10ND,
RDL=0,20ND,
RDL=0.10ND,
RDL=0.20ND,
RDL=0.10ND,
RDL=0.L0ND,
RDL=0.20NCNCNCNCNC1.5NCNCNC0.84.8NCNCNCNCNCNCNCNCNCL.4
ND,RDL=10
NC
Units QC Limits
uelL
uslL
uglL
uglL
uglL
uglL
uelL
uglL
uslL
uglL
u8/L
uglL
uelL
uelL
34947063494706
3494706
uglL
% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0% 3 0
77 0/o 50 - 130106 % 50 -130
3494706 HKL RPD
uelL% 40
Page 17 of 20
Page 18
,/iMa{Xamr./Maxxam Job #: 8411519Re port D ate: 20L4 / 02 / 03
5{ri l ( : : 's s Ti-; ; 'cU! l : 5c jgr:r:e,, ,
WSH LabsYour P.O. #:7052
QUAUTY ASSU RANCE REPORT(CONT'D)QA/qcBatch
3495s63
3495563
3495563
349s563
3498093
DateInit QC TJLE Matrix Spike
JLE Spiked Blank
JLE Method Blank
JLE RPD [UQ5071-03]
HIN Matrix Spike
ParameterDi.rr*Guthion (Azinphos-methyl)TemephosDiuronG uthion (Azinphos-methyl)Temephos
Diuron
Guthion (Azinphos-methyl)
Temephos
DiuronGuthion (Azinphos-methyl)Temephos2,3-Di bromopropionic AcidMonochloroacetic Acid (MCAA)Monobromoacetic Acid (M BAA)Dichloroacetic Acid (DCAA)Trichloroacetic Acid (TCAA)Bromochloroacetic Acid (BCAA)Dibromoacetic Acid (DBAA)2,3-Di bromopropionic AcidMonochloroacetic Acid (MCAA)Monobromoacetic Acid (M BAA)Dichloroacetic Acid (DCAA)Trichloroacetic Acid (TCAA)Bromochloroacetic Acid (BCAA)Dibromoacetic Acid (DBAA)2,3-Di bromopropionic Acid
Monochloroacetic Acid (MCAA)
Monobromoacetic Acid (M BAA)
Dichloroacetic Acid {DCAA)
Trichloroacetic Acid (TCAA)
Bromochloroacetic Acid (BCAA)
Dibromoacetic Acid (DBAA)
Total haloacetic acids
Monochloroacetic Acid (MCAA)Monobromoacetic Acid (M BAA)Dichloroacetic Acid (DCAA)Trichloroacetic Acid (TCAA)Bromochloroacetic Acid (BCAA)Dibromoacetic Acid
Ana Value Units QC Limits% 40 - 130% 40- 130% 40 - 130% 40 - 130% 40 - 130% 40 - 130
uglL
uglL
UElL
% 4 0% 4 0% 4 0% 70 -130% 70 -L30% 70 - 130% 70 - 130% 70 - 130% 70 - 130% 70 - 130% 70 - r_30% 70 -L30% 70 - 130% 70 - 130% 70 -L30% 70 - 130% 70 - 130% 70 - 130
uelL
UgIL
uelL
uglL
uglL
uelL
2014/0L/3020t4/0L/3020L4/0L/302014/0L/3020L4/0L/3020L4/ALB020L4/0L/30
20L4/0L/30
20L4/OLl302014/0L/3020t4/0L1302014/0u3020L4/02/01.2014/02/0L2AL4/A2/0t20L4/02/0L20L4/02/0L20L4/02/0r2OL4/02/0t2014/02/0L20L4/02/0L2OL4/A2/0120L4/02/0L20L4/02/A1,20L4/02/0L2AL4/02/01,2OL4/02/0L20t4/02/0L
2OL4/02/0L
201.4/02/0L
2OL4/02/01
20L4/02/AL
20L4/02/0L
2OL4/02/0r2Ot4/02/0L20L4/02/0L2OL4/A2/0L201.4/02/0L2OL4/02/0L
9397889910386
3498093 HIN Spiked Blank
3498093 HIN Method Blank
3498093 HIN RPD
ND,RDL=10
ND,RDL=2
ND,RDL=10
NCNCNC
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=5.0
ND,RDL=5.0
NCNCNCNCNCNC
1r21.LtLOL105NC105L23100to4899310194Lt497
201.
uglL
% 4 0% 4 0% 4 0% 4 0% 4 0% 4 0
Page 18 of 20
Page 19
,/iMa{/amL/
Maxxam Job #: 8411519Report Date: 2014 / 02 / 03
WSH LabsYour P.O. #:7052
QUALrry ASSU RANCE REPORT(CONT'D)aA/qC DateBatch Init Qc Type Parameter Analyzed Value Recovery units ec Limits
Totqf haloacetic acids 20I4/02/OI NC "/" 40Duplicate: Paired analysis of a separate portioh ofthe same sample. Ljsed to evaluate the variance in the measurement.Matrixspike: A sample to which a known amount ofthe analyte of interest has been added. used to evaluate samole matrix interference.spiked Blank: A blank matrix sample to which a known amount ofthe analyte, usually from a second source, has been added. used to evaluate methodaccuracv.Method Blank: A blank matrix containing all reagents used in the analytical procedure. Used to identif,/ laboratory contamination.Surrogate: A pure or isotopically labeled compound whose behavior mirrors the analytes of interest. Used to evaluate extraction efJt'ciency.Nc (Matrix Spike): The recovery in the matrix spike was not calculated. The relative difference between the concentration in the parent sample and thespiked amount was not sufficiently significant to permit a reliable recoverv calculatron.NC (RPD): Ihe RPD was not calculated. The levelofanalWe detected in the parent sample and its duplicate was not sufficiently significantto pefmit areliable calculation.
Page 19 of 20
Page 20
,/iMayamMaxxam Job #: B411519Report D ate : 2014/ 02 / 0E
$uccass Ti;rcr.r. j i r $cience.
WSH LabsYour P.O. # :7052
VALIDATION SIGNATURE PAGEThe analyt ical data and al l QC contained in this report were reviewed and val idated by the fol lowing individual(s).
fu-fi,'* Cont:ot-t
Cristina Carriere, Scientific Services
Rose MacDonald, Scienti f ic Special ist (Organics)
Maxxamhasprocedures inp |ace toguardaga ins t improperuseo f thee |ec t ron ics igna tu reandhave t17025:2005(E),s igningthereports. ForServiceGroupspeci f icval idat ionpleaserefer totheVal idat ionSignaturepage.
Page 20 of 20
