: 1 : : : : MEP Manager: HSE Officer: Tech. Manager: QA/QC Manager: Date: Response required by: B - Approved With Comments D - Rejected Comments: Project Director: Date : Received by: Al Khayyat Contracting and Trading LLC Project Director: Date : KCT063-BSI-MS-240 HIRA - 240 - R1 The approval by the Engineer does not relieve contractor/sub-contractor from his obligations/responsibilities under the contract and shall not constitute a departure from the contract. Khayyat Contracting and Trading Tel +974 4429 2211 – 4429 2222 | Fax +974 4429 2223| Email [email protected]PO Box 201184, Doha, Qatar Project Director: Date: FOR THE USE OF CONSULTANT Action: A - Approved C - Revise and Resubmit Details Item Description Sub-Cont Rep's: Received by: Spec./BOQ/Drwg. Reference List of Enclosures Al Khayyat Contracting and Trading LLC Consultant METHOD STATEMENT FOR TROLLEY CORRAL (1ORIGINAL+2COPIES+1SOFT COPY) CONSULTANT KEO MAIN CONTRACTOR SUB CONTRACTOR BLUE STEEL INDUSTY W.L.L AL KHAYYAT CONTRACTING AND TRADING QCS 2010 SECTION 05 5000.13, IFC REF : 7060-AD-F-11-REV 0 KCT063-BSI-ITP-240-R1 Other as mentioned in Appendices MALL OF QATAR Project No.: KCT-63-63-12 METHOD STATEMENT SUBMITTAL METHOD STATEMENT NO. Rev. Date: 15-Feb-15 Discipline: ARCHITECTURAL CLIENT URBACON TRADING AND CONTRACTING LLC Vendors Technical Compliance Statement Mill Certificate Others Risk Assessment KCT-IMS-CM-3301C Rev. 00 31/10/ 2012
Transcript
: 1
:
:
:
:
MEP Manager:
HSE Officer: Tech. Manager:
QA/QC Manager:
Date:
Response required by:
B - Approved With Comments D - Rejected
Comments:
Project Director: Date :
Received by: Al Khayyat Contracting and Trading LLC
Project Director: Date :
KCT063-BSI-MS-240
HIRA - 240 - R1
The approval by the Engineer does not relieve contractor/sub-contractor from his obligations/responsibilities under the contract and shall not constitute a departure from the contract.
Document No.: KCT063-BSI-MS-0240 Rev 01 Date: 15th Feb 2015
Page 1 of 21 KCT P.O.Box 201184
Doha Qatar
Method Statement for the Installation of Trolley Corral
Document Number: KCT063-BSI-MS-0240 Rev 01
01
15th
Febru
ary
2015
Revised
as per
comment
Ojes K Prasannan VK Sanjiv Sharma Nidal Fannoun Mowafaq Kharbat
Rev
Date Reason
for Revision
Prepared By(Bluesteel):
QAQC Engineer
Approved
By(Bluesteel):
Projects Manager
Checked By:
QA/QC Manager
Reviewed By: Technical Manager
Approved By:
Sr. Projects Director
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Document No.: KCT063-BSI-MS-0240 Rev 01 Date: 15th Feb 2015
Page 2 of 21 KCT P.O.Box 201184
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1. INTRODUCTION
2. REFERENCE DOCUMENTS
2.1 PROJECT SPECIFICATION
2.2 CONTRACT DRAWINGS
2.3 SHOP DRAWINGS
2.4 MATERIAL SUBMITTALS
3. ACCESS/EGRESS
3.1 ACCESSIBILITY
4. LOGISTICS
7.1 TRAFFIC MANAGEMENT
5. HEALTH AND SAFETY HAZARDS
6. RESPONSIBILITIES
7. RESOURCES
7.1 MANPOWER
7.2 TOOLS AND EQUIPMENT
7.3 MATERIAL
8. TRAINING
9. WORKING HOURES
10. HOUSE KEEPING
11. MANDATORY PERMITS
12. CONDTRUCTION METHODOLOGY AND PROCEDURES
13. Q.C. APPROVAL AND OTHER DOCUMENTARY REQUIRMENTS
14. DISTRIBUTION
15. SITE SAFETY ENGINEER’S APPROVAL
16. APPENDICES
o RISK ASSESSMENT
o METHOD STATEMENT & RA BRIEFING FORM
o ITP
o METHOD STATEMENT CHECKLIST
o REFERENCE DRAWINGS
o QAQC INSPECTION DOCUMENTS
o OTHER INFORMATION
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1. INTRODUCTION
This method statement is made to provide an overview on the system that Blue steel industry will adapt
to install the Galvanized Painted Trolley corral at Mall of Qatar Project.
This detailed methodology displays the standard approach and may be revised at any time in
accordance with further design development and site coordination requirements.
Where and when required, all the revisions, modifications and additions to this Method statement shall
be submitted to the consultant for information and/or approval.
This method statement describes the sequence of events from the receipt of the order through
to the completion of work.
All procedure and processes will be in accordance with our quality plan and the company
quality management system and in line with KCT UCC Management system and Project Quality
Plan.
All works will be executed in accordance with the Project Specifications, the approved drawings
and the requirements of the contract documentation.
Installation drawings and procedures will be supplied to the site installation team that are
adequate for them to carry out the work.
Installation drawings and ITP will detail all components used to install the Trolley Corral and
clearly show:
o Setting out and control points.
o Cross reference to the identification of all components.
o Details of all the procedure for the installation of all the components.
2. REFERENCE
2.1 DOCUMENTATION
QCS 2010 Spec 05 5000.13 Spec 09 9100.16
PROJECT HSE PLAN
PROJECT QUALITY PLAN
2.2 CONTRACT DRAWINGS
7060-AD-F-11-REV0
2.3 SHOP DRAWINGS
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Document No. Description Status
KCT063-BSI-A-SD-MW-STC-DW-3609 Typical details of TROLLEY CORRAL CODE-B
2.4 MATERIAL SUBMITTAL
Document No. Description Status
KCT063-BSI-A-MAT-0568 Material Submittal for TROLLEY
CORRAL CODE-B
3. ACCESS/EGRESS
3.1 ACCESSIBILITY
o KCT provided access/egress for material transferring and handling
o Access for BSI’s operatives to site will be via a safe pedestrian access route as dictated by main
contractor site management and agreed by KCT Safety manager.
4. LOGISTICS
4.1 TRAFFIC MANAGEMENT
o Storage access for finished goods/ semi-finished materials close to the work place.
o Designated off-loading area where materials will be offloaded by fork lift to the relevant areas.
o Banksman (B) to be deploy in various locations to control traffic.
o Shall follow approved logistic plan
5. HEALTH AND SAFETY HAZRDS
Specific safety measures have to be followed as applicable, and all the safety measures are covered
separately in the project Health & Safety plan.
a) Safety Lighting o Adequate lighting to be provided to work location. o All the electrical accessories will be of industrial type o All the cables will be buried / above head.
b) Task lighting o Connected cables to be secured / tied properly to avoid trip hazards. o In addition to the fixed lightings, Portable lights will be stand by. o All electrical fittings used will confirm to industrial standards.
c) Emergency arrangements o Contact numbers of personnel concerned to be displayed. o Emergency response team to be stand by:
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d) Risks and Controls o Please refer attachment - Risk analysis / Assessment
6. RESPONSIBILITIES
The Project Manager is responsible for the following:
Supervise and coordinate between the project teams.
Attend site meetings on regular basis.
To ensure the effective implementation for the Quality management system, process
Coordination and comply with project work programme.
To ensure the overall progress of project to the agreed programme.
To ensure availability of the required resources on time.
To supervise the Project engineers.
To coordinate with factory manager for production priority.
The Project Engineer will perform the following function:
To act as the main contact for the Construction Manager To ensure the progress of the project to the agreed program To coordinate with the design team dedicated to this project To check all technical details and timely submit of drawing for approval To make decisions for day to day project activities of engineering, design, procurements,
fabrication, delivery and site installation. To supervise the Site Foremen.
The QA/QC Engineer is responsible for following functions:
The QA/QC Engineer is responsible to ensure work has been done as per the specification and drawings, inspections are done as per Quality Control Procedure and the Inspection and Test plan and offer works for KEO inspection.
Prepare all quality documents and procedure as required. Report on project performance according to policy. Perform random site inspections on regular basis. To raise the Material Inspection requests through MDS and witness the inspections. To raise the Inspection Requests for the installed items and witness during the inspections
along with the Main Contractor and Consultant representatives. To raise non-conformances for any deviations in the materials, installation procedures
which are not as per the approved ITP, approved drawings or specifications. To follow up all the non-conformance notices till the closure and maintain a log of all these
items. To ensure that the latest revised approved drawings are used by site personnel.
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The Safety Officer will perform the following functions:
To ensure that all personnel working on MOQ site are having the safety induction.
To ensure all site personnel are wearing the PPE as per the site requirements.
To perform daily checks on the plants and equipment for their current status on test
requirements, calibrations, licenses etc.
To check and report for any abnormal noise in the equipment.
To check all the operators for the equipment are having the valid licenses for operating the
machines.
To give required tool box talks to site personnel as per the schedule on various topics of
Safety.
To ensure that the housekeeping is maintained by all personnel in all the working areas.
To liaise with the KCT Safety Officer for any requirements and observations.
To ensure that the necessary amount of drinking water and or salt tablets are provided
quite often during the summer working hours.
7. RESOURECES
7.1 MANPOWER
o Project Manager
o Project Engineer
o QAQC Engineer
o Safety Officer
o Supervisor
o Foreman
o Qualified welder
o Painter
o Skilled labors
o Unskilled labors
7.2 TOOLS AND EQUIPMENT
o Meter Tape
o Marker
o Spray paint
o Masking Tape
o Sprit Level
o Trolleys
o Drilling Machine
o Welding Machine
o Spanners
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o Hammer
o Chisel ( for chipping off concrete spills)
o Torque Wrench
o Grinding machine
o Painting Tools
o Air blower
7.3 MATERIAL
o Fasteners
o Material as per approved material submittal - KCT063-BSI-A-MAT-0568 (CODE B)
o Spray paint
o Masking Tape
o Touch up Paint
8. TRAINING
o The safety induction shall be provided prior to commence work.
o Daily tool box talk should be conduct by the supervisor. In addition the supervisor has to make special
tool box talk for every new task.
o Training on method statement and risk assessment should be briefed via the Method Statement
Briefing form KCT-QMSP-CM-3301E to all those involved in the activity prior to commencement. All
team members shall sign the briefing form to indicate that they understand the requirements.
o Training for executing the work is not mandatory, since trained technicians (Specialists) are deploying
for this specific job.
9. WORKING HOURES
o Site work will start at 0700 hrs and ends 1700 hrs. However, when work demands, more hours may be
worked as approved by the Construction Manager/ Project Manager
10. HOUSE KEEPING
o The work area will be maintained in a neat and tidy condition at all times.
o All Safety aspects will be continuously monitored by the Senior Safety representative and his team and
necessary corrective actions will be carried out immediately as and when required.
o After completion of works, the wastage will be shifted and stored in designated areas as agreed with
the Main contractor and as per Project management plan.
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11. MANDATORY PERMITS
MANDATORY PERMITS
YES NO
HOT-WORK √
WORK AT HEIGHT √
LIFTING √
SHAFTS (RISER / ELEVATOR) √
OCCUPIED BUILDINGS √
12. CONSTRUCTION METHODOLOGY AND PROCEDURE
12.1 Preliminary Activities/ Approvals
o Ensure that relevant shop drawings are prepared and followed based on the (KCT) provided detailed
drawings with areas and location of Trolley Corral.
o Prepare Material Submittal for TROLLEY CORRAL for Engineer’s approval and ensure that code A or
code B status has been achieved prior to commencing fabrication works.
o Submit Method Statement, Risk Assessment, inspection test Plan, WPS, PQR and welder’s Qualification
to the Engineer for approval.
o Identify quantify and ensure all risk are managed in this Method Statement and residual risks are
acceptable.
o Mock-ups: Before fabrication construct mock-ups for all elements in a location and of size as directed
by the Engineer to demonstrate aesthetic effects and qualities of materials and execution.
1. Build Mock-ups to the satisfaction of the Engineer. If the required standard is not achieved, the
Contractor shall replace (at the contractor’s cost) until the required standard is achieved as judged by
the Engineer
2. Obtain written approval of mock-ups from the engineer before starting fabrication.
3. Maintain mock-ups during construction in an undisturbed condition as a standard for judging the
completed Work.
4. Approved mock-ups shall not become part of the completed Work.
5. Remove and cart away mock-ups as and when directed by the Engineer.
12.2 FABRICATION
o Ensure the delivery of raw m – Mild
Steel) and fasteners(Hilti HST-R) are supplied by approved supplier, required specification as per
approved Material submittal and dimensions etc. approval obtained from BSIQCE.(fm 15-01 Incoming
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Material Inspection Report)
o Marking and Cutting of pipe & plate as per approved drawing.
o
o Tack weld MS pipe to the base plate as per drawing.
o Make cover cap from 1.5mm thick GI sheet as per drawing.
o Fit-up trolley corral in a layout made on a rigid platform as per drawing.
o BSIQCE shall check the fit-up and readings are recorded in stage inspection report (fm 15-05 – stage/fit-
up inspection report) and release for welding.
o The welding process, that’s to be done as per approved WPS, PQR in accordance with AWS D.1.1
Specifications & drawings, carried out by certified welders.
o Weld connections continuously to comply with the following:
o Use materials and methods that minimize distortion and develop strength and Corrosion
resistance of base metals.
o Obtain fusion without undercut or overlap.
o Remove flux immediately.
o After welding, imperfections at weld areas are cleaned, and offer for visual & NDT (From TPI if
applicable) inspection in accordance with the approved ITP and recorded through report (fm 15-06 –
Welding Inspection Report & NDT report from TPI).
o All the materials are subjected to final inspection(dimensional and visual) to assure compliance with the
drawing.(fm 15-08 – Final inspection Report)
o Sandblast the metal surface to prepare for galvanizing.
o Galvanizing will be carried out in accordance with the specification (ASTM A123).
o Readings are noted in Zinc Coating Certificate.
o Upon withdrawal from the zinc bath, sometimes excess zinc is present in small bumps, runs, or
drips. These imperfections will be visible and/or could protrude through the paint coating; and
therefore, must be removed prior to painting the part. Runs, drips, or bumps can be removed by
grinding or filing the surface smooth and flat. Since pure zinc is a soft metal, care must be taken to
remove the excess zinc material and leave a flat surface without removing the underlying zinc coating.
o Clean the surface from grease, oil etc.
o Painting shall be done as per approved painting system and procedure.
o Ensure the weather condition is suitable for the paint application recommended by paint manufacture.
Check temperature, relative humidity, dew point etc. and noted.
o Apply 2 coats (DFT - 2x100µ) of Penguard Special as per manufacturer’s recommended spreading rate
and coating interval.
o Apply 2 final coat (Hardtop XP, not less than 60µ as per approved painting system.
o Painting inspection (DFT) will be carried out for each coat and data will be recorded.(fm 15-07 –
Painting Inspection report).
o Apply succeeding coat only after the completion of recommended curing period of preceding coat
o Ensure all the materials which are ready for dispatch having distinct marking number for easy
identification.
o Protect painted finishes of TROLLEY CORRAL from damage by applying a strippable, temporary
protective covering before shipping.
o Arrange Trolley Corral in a palette for transportation.
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o Final inspection will be carried out by BSIQCE to ensure the compliance with the specification, drawing
and released for Dispatch through Certificate(fm 15-04 Final Release Certificate)
12.3 Delivery, Storage & handling
o The Trolley Corral & anchor bolts shall be delivered from Blue Steel Factory to the site store via trailer.
o Unload the materials using fork lift.
o All materials shall be shifted in due time, to the temporary staging area near to the installation location
with appropriate Equipment, like forklift and /or trolley.
o Delivery sequence of materials and accessories needed to complete the installation shall be on a
continuous basis. The material deliveries shall be scheduled in advance and booked to arrive at a pre-
determined time. Hence, all requests and permits must have been pre-arranged. This will be
coordinated with the Main contractor.
o Site storage and the material handling shall be properly planned by the logistic team. Coordination with
the installation teams and logistics team must go hands in the hands to avoid trouble handling and
minimize unnecessary material transfers and time wastage.
o Main contractor will provide intermediate transport( Forklifts and trolleys ) from the temporary staging
area, to the designated installation area,
12.4 Inspection of Receiving Materials
o All materials received on site shall be inspected by the BSIQCE for any fabrication defects and in-transit
defects such as deep scratches, dents, distortion and irregularities.
o Any visible defects found beyond the agreed tolerances shall be an outright rejection and materials not
complying with the requirements ,damaged or not as per Manufacturer’s recommendation etc., shall be
rejected and removed from site immediately and return to yard for replacement.
o All types of materials shall be checked in accordance with the specification and material approval for
every delivery by the Site BSIQCE through an approved MDS; with the presence of a representative
from the Main Contractor and the Consultant.
12.5 Preparation
o Ensure all required document and material approvals (Approved shop drawings, Schedule of approved
material submissions, Method Statement and Risk assessment, Approved MIR, WPS, PQR & Welder
certificate) have been obtained.
o Ensure the written approval of mockup has obtained from engineer.
o Inspect and ascertain conformance of existing base structures built by others.
o Ensure fabricated materials delivered to site and stored in designated area to allow traceability.
o Ensure work area is clear and safe.
o Ensure all constraints on operations have been identified and precautions are taken.
o Ensure QC and HSE monitoring documents and procedures are established and approved.
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o Arrange all necessary personnel, equipment and services as required for the works and ensure
adequate lighting, task lighting, power and access arrangements are in place.
o Where further information/ clarification in respect of Contract drawings are required shall be referred
to the Engineer, using Request for Information. (RFI)
o Ensure Employee inductions and tool Box talks for discussing risks assessment and identification and
control measures of hazards.
o Verify field measurement dimensions with shop drawing. Any deviations to be incorporated in shop
drawings.
o Ensure all the workmen have worn PPE.
12.6 Survey and Setting Out
o Preliminary inspection of the installation area shall be conducted in coordination with Main
Contractor’s Survey team to re-confirm the stationing & Control Points and the Benchmarks used by the
Main Contractor in locating coordinates and grid lines.
o The installation procedure should be carried out in a proper and safe manner and in compliance with
the below given procedures :
o Bench mark defining gridline and levels will be marked in secure locations in accordance approved
general zone drawing.
o Identify the FFL and mark accurate location of gridlines and levels transfer from the established bench
mark.
12.7 Installation of TROLLEY CORRAL
o Mark the location to drill the holes for anchor.
o Drill holes for Hilti M8 HST-R anchor bolt in required dimension and depth mentioned in Hilti data sheet
and approved drawing.
o Clean the hole with blower and request to BSIQC for inspection & approval.
o Insert anchor with Hammer or machine setting tool.
o Install Trolley corral into the anchors through the holes provided in the base plate
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FIXING DETAIL OF TROLLEY CORRAL
o Set the Trolley corral in accurate level and alignment as per drawing.
o Fit exposed connections accurately together to form hairline joints. Weld connections that are
not to be left as exposed joints but cannot be shop-welded because of shipping size limitations.
o Finish welded surfaces smooth and blended so that no roughness shows after finishing, and
contour of welded surface matches those adjacent.
o Welding should be followed by approved WPS and by qualified welder.
o Tighten the anchor bolt to specified torque (20 Nm) with calibrated torque wrench.
o Paint Touch up & Protection(As per spec 09 9100.16 & 05 5000.13 part 3.03A)
o Immediately after erection, clean bolted connections, and abraded areas. Paint uncoated and
abraded areas with the same material as used for shop paint to comply with SSPC-PA 1 and
approved painting system for touching up shop-painted surfaces.
o Clean and prepare surface to be painted according to manufacturer’s written instructions.
o Apply same paint used in shop for touch up.
o Clean the entire work area by removing, concrete pits, polethene sheets and other unwanted particles
immediately after the completion of the work.
o Return items which cannot be rectified to shop and replace with new units.
3 HST-R M8 Anchor bolts
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o Protect finishes of Bollard from future damages during filling of 20pma concrete.
o Finally crosscheck the Bollard’s installation is as per approved drawings.
o Check and offer for final inspection and approval to the consultant as per approved ITP.
13. Q.C. APPROVAL AND OTHER DOCUMENTARY REQUIRMENTS
o Project Quality Plan will be adhered to at all times.
o Project HSE plan will be adhered to at all times.
o QC approval shall take place as per the ITP
14. DISTRIBUTION
Copies of this MS have been issued to the following for information and necessary action:
o Construction Manager.
o Site Engineer.
o Safety Engineer.
o QA/QC Engineer.
15. SITE SAFETY ENGINEER’S APPROVAL
Approved
Approved with Comments
Not Approved - Reasons
Signed…………………………………………..Dated……………………..
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16. APPENDICES
o RISK ASSESSMENT
o METHOD STATEMENT & RISK ASSESSMENT BRIEFING FORM
o ITP
o METHOD STATEMENT CHECKLIST
o REFERENCE DRAWINGS
o QAQC INSPECTION DOCUMENTS
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APPENDIX 1
RISK ASSESSMENT
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240-R1 AREA / PROJECT:
CLIENT:
REV. / IMPL. DATE: 15/2/2015
No.
Pers.
R
2 R 6 10 8 HIGH 2 5 3 30 LOW
MEDIUM
HIGH Aver rounded up: LOWAverage rounded up:
Environment
Public
Prof. personnel
Std PPE: Overalls, Hard hat, Safety shoes, Reflective Vest, Safety Glasses & Gloves 10
Exposure to decomposition products may cause a health hazard. Serious effects maybe delayed following exposure.
May cause eye irritation.
No known significant effects or critical hazards.
Harmful in contact with skin. May cause skin irritation.
Eyes
Skin
Inhalation
Ingestion
Physical state Liquid.
See toxicological information (Section 11)
WARNING!
FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGHSKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSECANCER, BASED ON ANIMAL DATA.
Flammable liquid. May be harmful if absorbed through skin. Keep away from heat,sparks and flame. Avoid exposure - obtain special instructions before use. Do notbreathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.Contains material which may cause cancer, based on animal data. Risk of cancerdepends on duration and level of exposure. Use only with adequate ventilation. Keepcontainer tightly closed and sealed until ready for use. Wash thoroughly after handling.
:
:
:
:
:
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) byACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven foranimals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].MUTAGENIC EFFECTS: Not available.TERATOGENIC EFFECTS: Not available.
Medical conditionsaggravated by over-exposure
None known.
Potential chronic healtheffects
:
:
Odor : Characteristic.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
2 .
Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard CommunicationStandard).
Composition/information on ingredientsName CAS number % by weight
3 .
Continued on next page
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Hardtop XP - Comp. A Page: 2/8
Wash out mouth with water. Do not induce vomiting unless directed to do so bymedical personnel. Never give anything by mouth to an unconscious person. Getmedical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty ofwater for at least 15 minutes, occasionally lifting the upper and lower eyelids. Getmedical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse.Clean shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.
First aid measuresEye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or weargloves.
4 .
Flammable.
Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxideshalogenated compoundsmetal oxide/oxides
Use dry chemical, CO2, water spray (fog) or foam.
Fire-fighting measuresFlammability of the product
Products of combustion
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.
Flammable liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Runoff to sewer may create fire orexplosion hazard.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 foremergency contact information and section 13 for waste disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
Personal precautions :
Methods for cleaning up :
6 .
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New Stamp
Hardtop XP - Comp. A Page: 3/8
Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabeled containers. Use appropriate containment to avoid environmentalcontamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Remove contaminated clothing and protective equipment before enteringeating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoidbreathing vapor or mist. Use only with adequate ventilation. Wear appropriaterespirator when ventilation is inadequate. Do not enter storage areas and confinedspaces unless adequately ventilated. Keep in the original container or an approvedalternative made from a compatible material, kept tightly closed when not in use.Store and use away from heat, sparks, open flame or any other ignition source. Useexplosion-proof electrical (ventilating, lighting and material handling) equipment.Use non-sparking tools. Take precautionary measures against electrostaticdischarges. To avoid fire or explosion, dissipate static electricity during transfer bygrounding and bonding containers and equipment before transferring material.Empty containers retain product residue and can be hazardous. Do not reusecontainer.
Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001). TWA: 125 mg/m³ 10 hour(s). Form: All forms TWA: 25 ppm 10 hour(s). Form: All formsACGIH TLV (United States, 1/2005). TWA: 123 mg/m³ 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All formsOSHA PEL 1989 (United States, 3/1989). TWA: 125 mg/m³ 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.
Eyes
Skin
Respiratory
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.
Hands :
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
Liquid.
1.2 to 1.4 g/cm3
Insoluble in the following materials: cold water and hot water.
Characteristic.
Various colors.
Physical and chemical propertiesPhysical state
Relative density
Solubility
Odor
Color
384 % (w/w) [ISO % 11890-2]VOC
:
:
:
:
:
:
Flash point : Closed cup: 32°C (89,6°F)
9 .
10.01 to 11.68 pounds/gallon
3.2 pounds/gallon (US)
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New Stamp
Hardtop XP - Comp. A Page: 5/8
The product is stable.
Under normal conditions of storage and use, hazardous polymerization will notoccur.
Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.
Stability and reactivityStability and reactivity
Hazardous decompositionproducts
Hazardous polymerization
:
:
:
10 .
Toxicological information
Specific effects
Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancerdepends on duration and level of exposure.
Mutagenic effects No known significant effects or critical hazards.
Reproduction toxicity No known significant effects or critical hazards.
Chronic effects No known significant effects or critical hazards.
Exposure to component solvent vapor concentrations in excess of the statedoccupational exposure limit may result in adverse health effects such as mucousmembrane and respiratory system irritation and adverse effects on the kidneys, liverand central nervous system. Solvents may cause some of the above effects byabsorption through the skin. Symptoms and signs include headache, dizziness,fatigue, muscular weakness, drowsiness and, in extreme cases, loss ofconsciousness. Repeated or prolonged contact with the preparation may causeremoval of natural fat from the skin, resulting in non-allergic contact dermatitis andabsorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastro-intestinal irritation and chemical pneumonia.
Contains bis(1,2,2,6,6-pentamethyl-4-piperidyl) sebacate. May produce an allergicreaction.
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Provenfor animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].
Chronic effects on humans
Other toxic effects onhumans
:
:
:
:
:
:
11 .
Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2
etc.), halogenated compounds. Some metallic oxides.
ethylbenzene Daphnia magna (EC50)Daphnia magna (EC50)Selenastrum capricornutum(EC50)Oncorhynchus mykiss (LC50)Pimephales promelas (LC50)Poecilia reticulata (LC50)
48 hour(s)48 hour(s)48 hour(s)
96 hour(s)96 hour(s)96 hour(s)
2.93 mg/l2.97 mg/l7.2 mg/l
4.2 mg/l9.09 mg/l9.6 mg/l
Solvent naphtha (petroleum), lightaromatic
Fish (LC50)Daphnia (EC50)Algae (IC50)
96 hour(s)48 hour(s)72 hour(s)
<10 mg/l<10 mg/l<10 mg/l
Species Period ResultProduct/ingredient name
:
Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
12 .
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New Stamp
Hardtop XP - Comp. A Page: 6/8
The generation of waste should be avoided or minimized wherever possible. Significantquantities of waste product residues should not be disposed of via the foul sewer butprocessed in a suitable effluent treatment plant. Dispose of surplus and non-recyclableproducts via a licensed waste disposal contractor. Disposal of this product, solutionsand any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority requirements.Waste packaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible. This material and its container must be disposed of in asafe way. Care should be taken when handling emptied containers that have not beencleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphereinside the container. Do not cut, weld or grind used containers unless they have beencleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contactwith soil, waterways, drains and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations. Localregulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based oncharacteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is theresponsibility of the waste generator to determine the toxicity and physical properties of the material generated todetermine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.
ADR/RID: Viscous substance. Not restricted, ref. chapter 2.2.3.1.5 (applicable to receptacles < 450 litre capacity).IMDG: Viscous substance. Transport in accordance with paragraph 2.3.2.5 (applicable to receptacles < 30 litrecapacity).
14 .
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New Stamp
Hardtop XP - Comp. A Page: 7/8
Flammable liquidCarcinogen
HCS Classification
Regulatory information
U.S. Federal regulations
Connecticut Carcinogen Reporting: None of the components are listed.Connecticut Hazardous Material Survey: None of the components are listed.Florida substances: None of the components are listed.Illinois Chemical Safety Act: None of the components are listed.Illinois Toxic Substances Disclosure to Employee Act: None of the components arelisted.Louisiana Reporting: None of the components are listed.Louisiana Spill: None of the components are listed.Massachusetts Spill: None of the components are listed.Massachusetts Substances: The following components are listed: XYLENE;ethylbenzene; n-butyl acetateMichigan Critical Material: None of the components are listed.Minnesota Hazardous Substances: None of the components are listed.New Jersey Hazardous Substances: The following components are listed: XYLENES;BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetateNew Jersey Spill: None of the components are listed.New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.New York Acutely Hazardous Substances: The following components are listed:Xylene (mixed); Ethylbenzene; Butyl acetateNew York Toxic Chemical Release Reporting: None of the components are listed.Pennsylvania RTK Hazardous Substances: The following components are listed:BENZENE, DIMETHYL-; ethylbenzene; n-butyl acetateRhode Island Hazardous Substances: None of the components are listed.
WARNING: This product contains a chemical known to the State of California to causecancer.
TSCA 8(a) PAIR: 2-methoxy-1-methylethyl acetateTSCA 8(a) IUR Exempt/Partial exemption: Not determinedUnited States inventory (TSCA 8b): Not determined.
Clean Water Act (CWA) 307: c.i. pigment brown 24
Clean Water Act (CWA) 311: formaldehyde
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
State regulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.SARA 302/304 emergency planning and notification: No products were found.SARA 302/304/311/312 hazardous chemicals: ethylbenzene; n-butyl acetate; xyleneSARA 311/312 MSDS distribution - chemical inventory - hazard identification:ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) healthhazard; n-butyl acetate: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)health hazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic)health hazard
:
:
SARA 313
:
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
S23- Do not breathe vapor / spray.S36/37- Wear suitable protective clothing and gloves.S38- In case of insufficient ventilation, wear suitable respiratory equipment.
R10- Flammable.R20/21- Harmful by inhalation and in contact with skin.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
Risk phrases
Safety phrases
:
:
Hazard symbol or symbols :
Harmful
Other information
Hazardous MaterialInformation System (U.S.A.)
0
3
1
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGHSKIN. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSECANCER, BASED ON ANIMAL DATA.
Label requirements :
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.
Date of issue
Version
24.10.2012.
1.02:
:
:
:
16 .
Indicates information that has changed from previously issued version.
Harmful in contact with skin. May cause skin irritation.
Eyes
Skin
Inhalation
Ingestion
Physical state Liquid.
See toxicological information (Section 11)
WARNING!
FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGHSKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE,BASED ON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIALWHICH MAY CAUSE CANCER, BASED ON ANIMAL DATA.
Flammable liquid. May be harmful if absorbed through skin. Keep away from heat,sparks and flame. Avoid exposure - obtain special instructions before use. Do notbreathe vapor or mist. Do not get in eyes. Avoid contact with skin and clothing.Contains material that may cause target organ damage, based on animal data.Contains material which may cause cancer, based on animal data. Risk of cancerdepends on duration and level of exposure. Use only with adequate ventilation. Keepcontainer tightly closed and sealed until ready for use. Wash thoroughly after handling.
:
:
:
:
:
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.) byACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Proven foranimals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
Medical conditionsaggravated by over-exposure
Pre-existing disorders involving any target organs mentioned in this MSDS as being atrisk may be aggravated by over-exposure to this product.
Potential chronic healtheffects
:
:
Odor : Characteristic.
OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard(29 CFR 1910.1200).
2 .
Components not listed are not physical or health hazards as defined in 29 CFR 1910.1200 (Hazard CommunicationStandard).
Wash out mouth with water. Do not induce vomiting unless directed to do so bymedical personnel. Never give anything by mouth to an unconscious person. Getmedical attention immediately.
Check for and remove any contact lenses. Immediately flush eyes with plenty ofwater for at least 15 minutes, occasionally lifting the upper and lower eyelids. Getmedical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minuteswhile removing contaminated clothing and shoes. Wash clothing before reuse.Clean shoes thoroughly before reuse. Get medical attention immediately.
Move exposed person to fresh air. If not breathing, if breathing is irregular or ifrespiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attentionimmediately.
First aid measures
Eye contact
Skin contact
Inhalation
Ingestion
:
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Itmay be dangerous to the person providing aid to give mouth-to-mouth resuscitation.Wash contaminated clothing thoroughly with water before removing it, or weargloves.
4 .
Flammable.
Decomposition products may include the following materials:carbon dioxidecarbon monoxide
Use dry chemical, CO2, water spray (fog) or foam.
Fire-fighting measures
Flammability of the product
Products of combustion
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool.
Flammable liquid. In a fire or if heated, a pressure increase will occur and the containermay burst, with the risk of a subsequent explosion. Runoff to sewer may create fire orexplosion hazard.
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-contained breathingapparatus (SCBA) with a full face-piece operated in positive pressure mode.
:
:
:
5 .
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilled material. Shut off all ignition sources.No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment (see Section 8).
Stop leak if without risk. Move containers from spill area. Approach release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilled product. Note: see section 1 foremergency contact information and section 13 for waste disposal.
Environmental precautions
Accidental release measures
: Avoid dispersal of spilled material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air).
Personal precautions :
Methods for cleaning up :
6 .
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Barrier 80 - Comp. B Page: 3/8
Store in accordance with local regulations. Store in a segregated and approvedarea. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabeled containers. Use appropriate containment to avoid environmentalcontamination.
Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Remove contaminated clothing and protective equipment before enteringeating areas. Do not get in eyes or on skin or clothing. Do not ingest. Avoidbreathing vapor or mist. Use only with adequate ventilation. Wear appropriaterespirator when ventilation is inadequate. Do not enter storage areas and confinedspaces unless adequately ventilated. Keep in the original container or an approvedalternative made from a compatible material, kept tightly closed when not in use.Store and use away from heat, sparks, open flame or any other ignition source. Useexplosion-proof electrical (ventilating, lighting and material handling) equipment.Use non-sparking tools. Take precautionary measures against electrostaticdischarges. To avoid fire or explosion, dissipate static electricity during transfer bygrounding and bonding containers and equipment before transferring material.Empty containers retain product residue and can be hazardous. Do not reusecontainer.
Solvent naphtha (petroleum), light aromatic NIOSH REL (United States, 6/2001). TWA: 125 mg/m³ 10 hour(s). Form: All forms TWA: 25 ppm 10 hour(s). Form: All formsACGIH TLV (United States, 1/2005). TWA: 123 mg/m³ 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All formsOSHA PEL 1989 (United States, 3/1989). TWA: 125 mg/m³ 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection must bebased on known or anticipated exposure levels, the hazards of the product and the safeworking limits of the selected respirator.
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.
Personal protective equipment for the body should be selected based on the task beingperformed and the risks involved and should be approved by a specialist before handlingthis product.
Eyes
Skin
Respiratory
:
:
:
Chemical-resistant, impervious gloves complying with an approved standard should beworn at all times when handling chemical products if a risk assessment indicates this isnecessary.
Hands :
Engineering measures : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation orother engineering controls to keep worker exposure to airborne contaminants below anyrecommended or statutory limits. The engineering controls also need to keep gas, vaporor dust concentrations below any lower explosive limits. Use explosion-proof ventilationequipment.
Hygiene measures : Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period. Appropriatetechniques should be used to remove potentially contaminated clothing. Washcontaminated clothing before reusing. Ensure that eyewash stations and safety showersare close to the workstation location.
Liquid.
0.91 g/cm3
Insoluble in the following materials: cold water and hot water.
Characteristic.
Various
Physical and chemical propertiesPhysical state
Relative density
Solubility
Odor
Color
567 % (w/w) [ISO % 11890-2]VOC
:
:
:
:
:
:
Flash point : Closed cup: 25°C (77°F)
9 .
7.59 pounds/gallon
4.73 pounds/gallon (US)
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New Stamp
Barrier 80 - Comp. B Page: 5/8
The product is stable.
Under normal conditions of storage and use, hazardous polymerization will notoccur.
Under normal conditions of storage and use, hazardous decomposition productsshould not be produced.
Stability and reactivity
Stability and reactivity
Hazardous decompositionproducts
Hazardous polymerization
:
:
:
10 .
Toxicological information
Specific effects
Carcinogenic effects Contains material which may cause cancer, based on animal data. Risk of cancerdepends on duration and level of exposure.
Mutagenic effects No known significant effects or critical hazards.
Reproduction toxicity No known significant effects or critical hazards.
Chronic effects Contains material that may cause target organ damage, based on animal data.
Contains material which may cause damage to the following organs: upperrespiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Target organs
Exposure to component solvent vapor concentrations in excess of the statedoccupational exposure limit may result in adverse health effects such as mucousmembrane and respiratory system irritation and adverse effects on the kidneys, liverand central nervous system. Solvents may cause some of the above effects byabsorption through the skin. Symptoms and signs include headache, dizziness,fatigue, muscular weakness, drowsiness and, in extreme cases, loss ofconsciousness. Repeated or prolonged contact with the preparation may causeremoval of natural fat from the skin, resulting in non-allergic contact dermatitis andabsorption through the skin. If splashed in the eyes, the liquid may cause irritationand reversible damage. Swallowing may cause nausea, diarrhea, vomiting, gastro-intestinal irritation and chemical pneumonia.
Contains 3,6-diazaoctanethylenediamin, 2,2'-iminodiethylamine. May produce anallergic reaction.
CARCINOGENIC EFFECTS: Classified A4 (Not classifiable for humans or animals.)by ACGIH, 3 (Not classifiable for humans.) by IARC [xylene]. Classified A3 (Provenfor animals.) by ACGIH, 2B (Possible for humans.) by IARC [ethylbenzene].Contains material which may cause damage to the following organs: upperrespiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
ethylbenzene Daphnia magna (EC50)Daphnia magna (EC50)Selenastrum capricornutum(EC50)Oncorhynchus mykiss (LC50)Pimephales promelas (LC50)Poecilia reticulata (LC50)
48 hour(s)48 hour(s)48 hour(s)
96 hour(s)96 hour(s)96 hour(s)
2.93 mg/l2.97 mg/l7.2 mg/l
4.2 mg/l9.09 mg/l9.6 mg/l
Solvent naphtha (petroleum), lightaromatic
Fish (LC50)Daphnia (EC50)Algae (IC50)
96 hour(s)48 hour(s)72 hour(s)
<10 mg/l<10 mg/l<10 mg/l
Species Period ResultProduct/ingredient name
12 .
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New Stamp
Barrier 80 - Comp. B Page: 6/8
Ecological information12 .
Products of degradation: carbon oxides (CO, CO2) and water.Products of degradation :
Environmental precautions : Harmful to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
The generation of waste should be avoided or minimized wherever possible. Significantquantities of waste product residues should not be disposed of via the foul sewer butprocessed in a suitable effluent treatment plant. Dispose of surplus and non-recyclableproducts via a licensed waste disposal contractor. Disposal of this product, solutionsand any by-products should at all times comply with the requirements of environmentalprotection and waste disposal legislation and any regional local authority requirements.Waste packaging should be recycled. Incineration or landfill should only be consideredwhen recycling is not feasible. This material and its container must be disposed of in asafe way. Care should be taken when handling emptied containers that have not beencleaned or rinsed out. Empty containers or liners may retain some product residues.Vapor from product residues may create a highly flammable or explosive atmosphereinside the container. Do not cut, weld or grind used containers unless they have beencleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contactwith soil, waterways, drains and sewers.
Waste disposal
Disposal considerations
Disposal should be in accordance with applicable regional, national and local laws and regulations. Localregulations may be more stringent than regional or national requirements.
The information presented below only applies to the material as supplied. The identification based oncharacteristic(s) or listing may not apply if the material has been used or otherwise contaminated. It is theresponsibility of the waste generator to determine the toxicity and physical properties of the material generated todetermine the proper waste identification and disposal methods in compliance with applicable regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTIONfor additional handling information and protection of employees.
Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components arelisted.Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: XYLENE;ethylbenzene; PROPYLENE GLYCOL METHYL ETHERMichigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed: XYLENES;BENZENE, DIMETHYL-; ethylbenzene; PROPYLENE GLYCOL MONOMETHYLETHER; 1-METHOXY-2-PROPANOLNew Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: The following components are listed:Xylene (mixed); EthylbenzeneNew York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:BENZENE, DIMETHYL-; ethylbenzene; 2-PROPANOL, 1-METHOXY-Rhode Island Hazardous Substances: None of the components are listed.
TSCA 8(a) IUR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): Not determined.
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
State regulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: ethylbenzene; xylene; 1-methoxy-2-propanolSARA 311/312 MSDS distribution - chemical inventory - hazard identification:ethylbenzene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) healthhazard; xylene: Fire hazard, Immediate (acute) health hazard, Delayed (chronic) healthhazard; 1-methoxy-2-propanol: Fire hazard, Immediate (acute) health hazard, Delayed(chronic) health hazard
:
:
SARA 313
:
Product name CAS number Concentration
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shallinclude copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
WARNING: This product contains a chemical known to the State of California to causecancer.
ethylbenzene Yes. No. No. No.
Ingredient name Cancer Reproductive No significant risklevel
Maximumacceptable dosagelevel
S23- Do not breathe vapor / spray.S26- In case of contact with eyes, rinse immediately with plenty of water and seekmedical advice.S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.S38- In case of insufficient ventilation, wear suitable respiratory equipment.
R10- Flammable.R20/21- Harmful by inhalation and in contact with skin.R41- Risk of serious damage to eyes.R38- Irritating to skin.R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
Risk phrases
EU regulations
Safety phrases
:
:
Hazard symbol or symbols :
Harmful
Other information
Hazardous MaterialInformation System (U.S.A.)
0
2
3
National Fire ProtectionAssociation (U.S.A.)
Health
Special
Instability
Flammability
FLAMMABLE LIQUID AND VAPOR. MAY BE HARMFUL IF ABSORBED THROUGHSKIN. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASEDON ANIMAL DATA. POSSIBLE CANCER HAZARD - CONTAINS MATERIAL WHICHMAY CAUSE CANCER, BASED ON ANIMAL DATA.
Label requirements :
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-namedsupplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of theinformation contained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may presentunknown hazards and should be used with caution. Although certain hazards are described herein, we cannotguarantee that these are the only hazards that exist.
Date of issue
Version
29.10.2012.
1.02:
:
:
:
16 .
Indicates information that has changed from previously issued version.
Health
Flammability
Physical hazards
GPERSONAL PROTECTION
1
3
0
Health
yoyo
New Stamp
Penguard Special - Comp. A
Identification of the material and supplier
Medical Emergencies 24 hours:Poisons Information Centre (New Zealand) 0800 764 766
Material Safety Data Sheet
Product name
Penguard Special - Comp. A
1 .
Emergency telephonenumber
:
:
Area of application Industrial applications, Used by spraying.
Material uses Solvent-borne.
:
:
Supplier : Polymer Group62 Stonedon Dve, East TamakiAuckland New ZealandPhone: 64 9274 1400Fax: 64 9274 1405
Safety phrases S23- Do not breathe vapour / spray.S36/37- Wear suitable protective clothing and gloves.S38- In case of insufficient ventilation, wear suitable respiratory equipment.S61- Avoid release to the environment. Refer to special instructions/safety data sheet.
Risk phrases R10- Flammable.R20/21- Harmful by inhalation and in contact with skin.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.
:
Statement ofhazardous/dangerous nature
: HAZARDOUS SUBSTANCE. DANGEROUS GOODS.
The preparation is classified in accordance with NOHSC as follows:
Other ingredients, determined not to be hazardous according to Safe Work Australia criteria, and not dangerousaccording to the ADG Code, make up the product concentration to 100%.
See Section 16 for the full text of the R-phrasesdeclared above.
Wash out mouth with water. Remove dentures if any. Remove victim to fresh air andkeep at rest in a position comfortable for breathing. If material has been swallowedand the exposed person is conscious, give small quantities of water to drink. Stop ifthe exposed person feels sick as vomiting may be dangerous. Do not induce vomitingunless directed to do so by medical personnel. If vomiting occurs, the head should bekept low so that vomit does not enter the lungs. Get medical attention if adversehealth effects persist or are severe. Never give anything by mouth to an unconsciousperson. If unconscious, place in recovery position and get medical attentionimmediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, beltor waistband.
Skin contact
Immediately flush eyes with plenty of water, occasionally lifting the upper and lowereyelids. Check for and remove any contact lenses. Continue to rinse for at least 10minutes. Get medical attention.
Flush contaminated skin with plenty of water. Remove contaminated clothing andshoes. Wash contaminated clothing thoroughly with water before removing it, or weargloves. Continue to rinse for at least 10 minutes. Get medical attention. In the eventof any complaints or symptoms, avoid further exposure. Wash clothing before reuse.Clean shoes thoroughly before reuse.
First-aid measures
Remove victim to fresh air and keep at rest in a position comfortable for breathing. Ifit is suspected that fumes are still present, the rescuer should wear an appropriatemask or self-contained breathing apparatus. If not breathing, if breathing is irregularor if respiratory arrest occurs, provide artificial respiration or oxygen by trainedpersonnel. It may be dangerous to the person providing aid to give mouth-to-mouthresuscitation. Get medical attention. If unconscious, place in recovery position andget medical attention immediately. Maintain an open airway. Loosen tight clothingsuch as a collar, tie, belt or waistband.
Ingestion
Inhalation
Eye contact
:
:
:
:
Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It maybe dangerous to the person providing aid to give mouth-to-mouth resuscitation. Washcontaminated clothing thoroughly with water before removing it, or wear gloves.
First-aid measures4 .
Special protectiveequipment for fire-fighters
Fire-fighters should wear appropriate protective equipment and self-containedbreathing apparatus (SCBA) with a full face-piece operated in positive pressuremode.
:
Fire-fighting measures5 .
Hazchem code : 3[Y]
Use dry chemical, CO2, water spray (fog) or foam.
Extinguishing media
Promptly isolate the scene by removing all persons from the vicinity of the incident ifthere is a fire. No action shall be taken involving any personal risk or without suitabletraining. Move containers from fire area if this can be done without risk. Use waterspray to keep fire-exposed containers cool. This material is toxic to aquaticorganisms. Fire water contaminated with this material must be contained andprevented from being discharged to any waterway, sewer or drain.
Flammable liquid. In a fire or if heated, a pressure increase will occur and thecontainer may burst, with the risk of a subsequent explosion. Runoff to sewer maycreate fire or explosion hazard.
Special exposure hazards :
Do not use water jet.
Suitable :
Not suitable :
Date of issue Page: 2/8: 01.11.2012.
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New Stamp
Penguard Special - Comp. A
Environmental precautions
Personal precautions
Avoid dispersal of spilt material and runoff and contact with soil, waterways, drainsand sewers. Inform the relevant authorities if the product has caused environmentalpollution (sewers, waterways, soil or air). Water polluting material. May be harmful tothe environment if released in large quantities.
No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel fromentering. Do not touch or walk through spilt material. Shut off all ignition sources. Noflares, smoking or flames in hazard area. Avoid breathing vapour or mist. Provideadequate ventilation. Wear appropriate respirator when ventilation is inadequate. Puton appropriate personal protective equipment (see Section 8).
:
:
Accidental release measures6 .
Methods for cleaning up : Stop leak if without risk. Move containers from spill area. Approach the release fromupwind. Prevent entry into sewers, water courses, basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows. Contain andcollect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculiteor diatomaceous earth and place in container for disposal according to localregulations (see section 13). Use spark-proof tools and explosion-proof equipment.Dispose of via a licensed waste disposal contractor. Contaminated absorbentmaterial may pose the same hazard as the spilt product. Note: see section 1 foremergency contact information and section 13 for waste disposal.
Contain and collect spillage with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations (seesection 13).
Handling
Storage
Put on appropriate personal protective equipment (see Section 8). Eating, drinkingand smoking should be prohibited in areas where this material is handled, stored andprocessed. Workers should wash hands and face before eating, drinking andsmoking. Remove contaminated clothing and protective equipment before enteringeating areas. Persons with a history of skin sensitization problems should not beemployed in any process in which this product is used. Do not get in eyes or on skinor clothing. Do not ingest. Avoid breathing vapour or mist. Avoid release to theenvironment. Refer to special instructions/safety data sheet. Use only with adequateventilation. Wear appropriate respirator when ventilation is inadequate. Do not enterstorage areas and confined spaces unless adequately ventilated. Keep in the originalcontainer or an approved alternative made from a compatible material, kept tightlyclosed when not in use. Store and use away from heat, sparks, open flame or anyother ignition source. Use explosion-proof electrical (ventilating, lighting and materialhandling) equipment. Use non-sparking tools. Take precautionary measures againstelectrostatic discharges. To avoid fire or explosion, dissipate static electricity duringtransfer by earthing and bonding containers and equipment before transferringmaterial. Empty containers retain product residue and can be hazardous. Do notreuse container.
Store in accordance with local regulations. Store in a segregated and approved area.Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see section 10) and food anddrink. Eliminate all ignition sources. Separate from oxidizing materials. Keepcontainer tightly closed and sealed until ready for use. Containers that have beenopened must be carefully resealed and kept upright to prevent leakage. Do not storein unlabelled containers. Use appropriate containment to avoid environmentalcontamination.
:
:
Handling and storage7 .
The handle provided on the package is for manual handling only. Transport andtransfer should be carried out with appropriate equipment and carriage devices.
butan-1-ol Safe Work Australia (Australia, 8/2005). Absorbedthrough skin. PEAK: 152 mg/m³ 15 minute(s).
Ingredient name Exposure limits
Exposure controls/personal protection8 .
Date of issue Page: 3/8: 01.11.2012.
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New Stamp
Penguard Special - Comp. A
Engineering measures Use only with adequate ventilation. Use process enclosures, local exhaust ventilationor other engineering controls to keep worker exposure to airborne contaminantsbelow any recommended or statutory limits. The engineering controls also need tokeep gas, vapour or dust concentrations below any lower explosive limits. Useexplosion-proof ventilation equipment.
Wash hands, forearms and face thoroughly after handling chemical products, beforeeating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Washcontaminated clothing before reusing. Ensure that eyewash stations and safetyshowers are close to the workstation location.
Hygiene measures
Skin
Personal protection
Use a properly fitted, air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary. Respirator selection mustbe based on known or anticipated exposure levels, the hazards of the product and thesafe working limits of the selected respirator.
Personal protective equipment for the body should be selected based on the taskbeing performed and the risks involved and should be approved by a specialist beforehandling this product.
Chemical-resistant, impervious gloves complying with an approved standard shouldbe worn at all times when handling chemical products if a risk assessment indicatesthis is necessary.
Hands
Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes, mists ordusts.
Eyes
Respiratory
:
:
:
:
:
:
PEAK: 50 ppm 15 minute(s).1-methoxy-2-propanol Safe Work Australia (Australia, 8/2005).
Solvent naphtha (petroleum), light aromatic NOHSC (Australia, 11/2004). Notes: Documentation forthe substances with this footnote can be found in the5th Edition of the ACGIH documentation of the thresholdlimit values and biological exposure indices (1). For allother substances with 'H' in Column 7 thedocumentation can be found in the 6th Edition of theACGIH documentation of the threshold limit values andbiological exposure indices (2). TWA: 123 mg/m³ 8 hour(s). Form: All forms TWA: 25 ppm 8 hour(s). Form: All forms
: Emissions from ventilation or work process equipment should be checked to ensurethey comply with the requirements of environmental protection legislation. In somecases, fume scrubbers, filters or engineering modifications to the process equipmentwill be necessary to reduce emissions to acceptable levels.
Recommended monitoringprocedures
: If this product contains ingredients with exposure limits, personal, workplaceatmosphere or biological monitoring may be required to determine the effectivenessof the ventilation or other control measures and/or the necessity to use respiratoryprotective equipment.
Physical state Liquid.
Characteristic.Odour
Various colours.Colour
Flash point Closed cup: 25°C (77°F)
:
:
:
:
Solubility Insoluble in the following materials: cold water and hot water.:
Physical and chemical properties9 .
Density 1.45 g/cm3:
Date of issue Page: 4/8: 01.11.2012.
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New Stamp
Penguard Special - Comp. A
Materials to avoid/Hazardous Reactions
Conditions to avoid Keep away from heat, sparks and flame.:
Stability and reactivity10 .
:
Stability :
Hazardous decompositionproducts
Stable under recommended storage and handling conditions (see section 7).
Keep away from the following materials to prevent strong exothermic reactions:oxidising agents, strong alkalis, strong acids.
: Decomposition products may include the following materials: carbon monoxide,carbon dioxide, smoke, oxides of nitrogen.
Keep away from the following materials to prevent strong exothermic reactions:oxidising agents, strong alkalis, strong acids.
Acute toxicity
Toxicological information11 .
Potential acute health effects
Inhalation Harmful by inhalation.:
Ingestion Irritating to mouth, throat and stomach.:
Skin contact Harmful in contact with skin. Irritating to skin. May cause sensitisation by skin contact.:
Eye contact Irritating to eyes.:
Toxicity data : Not available.
Potential chronic health effects
Carcinogenicity
Mutagenicity
Reproductive toxicity
No known significant effects or critical hazards.
No known significant effects or critical hazards.
:
:
Skin
Ingestion
Inhalation No known significant effects or critical hazards.
No known significant effects or critical hazards.
No known significant effects or critical hazards.
Over-exposure signs/symptoms
:
:
:
Target organs Contains material which may cause damage to the following organs: mucousmembranes, upper respiratory tract, skin, central nervous system (CNS), ears, eye,lens or cornea.
:
Ingredient name OSHA NIOSH NTP
xylene A4 - - 3 - -ethylbenzene A3 - - 2B - -
ACGIH EPA IARC
There are no data available on the preparation itself. The preparation has been assessed following the conventional methodof the Dangerous Preparations Directive 1999/45/EC and classified for toxicological hazards accordingly. See sections 2 and15 for details.
Exposure to component solvent vapour concentrations in excess of the stated occupational exposure limit may result inadverse health effects such as mucous membrane and respiratory system irritation and adverse effects on the kidneys, liverand central nervous system. Symptoms and signs include headache, dizziness, fatigue, muscular weakness, drowsiness and,in extreme cases, loss of consciousness.Solvents may cause some of the above effects by absorption through the skin. Repeated or prolonged contact with thepreparation may cause removal of natural fat from the skin, resulting in non-allergic contact dermatitis and absorption throughthe skin.If splashed in the eyes, the liquid may cause irritation and reversible damage.Ingestion may cause nausea, diarrhea and vomiting.This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact.
Contains epoxy resin (MW 700-1200). May produce an allergic reaction.
Date of issue Page: 5/8: 01.11.2012.
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New Stamp
Penguard Special - Comp. A
Ecological information12 .
There are no data available on the preparation itself.Do not allow to enter drains or watercourses.
The preparation has been assessed following the conventional method of the Dangerous Preparations Directive1999/45/EC and is classified for eco-toxicological properties accordingly. See Sections 2 and 15 for details.
Ecotoxicity
LogPow BCF Potential
Bioaccumulative potential
Other ecological information
Other adverse effects : No known significant effects or critical hazards.
Product/ingredient name
xylene 3,12 - highbutan-1-ol 0,88 - low
Product/ingredient name Aquatic half-life Photolysis Biodegradability
: Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment. Water polluting material. May be harmful to the environment ifreleased in large quantities.
Methods of disposal : The generation of waste should be avoided or minimised wherever possible. Emptycontainers or liners may retain some product residues. This material and its containermust be disposed of in a safe way. Significant quantities of waste product residuesshould not be disposed of via the foul sewer but processed in a suitable effluenttreatment plant. Dispose of surplus and non-recyclable products via a licensed wastedisposal contractor. Disposal of this product, solutions and any by-products should atall times comply with the requirements of environmental protection and wastedisposal legislation and any regional local authority requirements. Avoid dispersal ofspilt material and runoff and contact with soil, waterways, drains and sewers.
Disposal considerations13 .
Transport information14 .
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure thatpersons transporting the product know what to do in the event of an accident or spillage.
Transport in accordance with ADR/RID, IMDG/IMO and ICAO/IATA and national regulation.
:
:
:
The environmental hazardous / marine pollutant mark is only applicable for packagescontaining more than 5 litres for liquids and 5 kg for solids.
Marking :
Regulatory information15 .
Standard for the Uniform Scheduling of Drugs and Poisons
Control of Scheduled Carcinogenic Substances
Ingredient name Schedule
No listed substance
Australia inventory (AICS) : All ingredients are listed on AICS or are exempt.
EU regulations
National regulations
: The product is classified and labelled for supply in accordance with the Directive1999/45/EC as follows:
:
Harmful
Dangerous for theenvironment
Hazard symbol orsymbols
:Contains epoxy resin (MW 700-1200)xylene
R10- Flammable.R20/21- Harmful by inhalation and in contact with skin.R36/38- Irritating to eyes and skin.R43- May cause sensitisation by skin contact.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
Risk phrases :
S23- Do not breathe vapour / spray.S36/37- Wear suitable protective clothing and gloves.S51- Use only in well-ventilated areas.
Safety phrases :
5
New Zealand Inventory ofChemicals (NZIoC)
: All components listed or exempt from listing on the New Zealand Inventory ofChemicals (NZIoC).
HSNO Classification : 3.1 - FLAMMABLE LIQUIDS - Category C6.1 - ACUTE TOXICITY: ORAL - Category E6.3 - SKIN IRRITATION - Category A8.3 - CORROSIVE TO OCULAR TISSUE - Category A6.5 - SENSITIZATION - Category B (Skin)6.8 - REPRODUCTIVE AND DEVELOPMENTAL TOXICITY [Fertility] - Category B6.8 - REPRODUCTIVE AND DEVELOPMENTAL TOXICITY [Unborn child] -Category B6.9 - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATEDEXPOSURE): ORAL - Category B6.9 - SPECIFIC TARGET ORGAN TOXICITY (SINGLE OR REPEATEDEXPOSURE): INHALATION - Category B9.1 - AQUATIC ECOTOXICITY - Category B
Date of issue Page: 7/8: 01.11.2012.
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Penguard Special - Comp. A
US regulations
HCS Classification : Flammable liquidCarcinogenTarget organ effects
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier,nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the informationcontained herein.Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknownhazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee thatthese are the only hazards that exist.
Disclaimer
Other information16 .
Notice to reader
History
Date of printing
Date of issue :: 01.11.2012.
01.11.2012.
4:Version
Prepared by : Jotun Group Product Safety Department
Full text of R-phrases referredto in sections 2 and 3
: R11- Highly flammable.R10- Flammable.R20- Harmful by inhalation.R22- Harmful if swallowed.R20/21- Harmful by inhalation and in contact with skin.R65- Harmful: may cause lung damage if swallowed.R41- Risk of serious damage to eyes.R37- Irritating to respiratory system.R38- Irritating to skin.R36/38- Irritating to eyes and skin.R37/38- Irritating to respiratory system and skin.R43- May cause sensitisation by skin contact.R66- Repeated exposure may cause skin dryness or cracking.R67- Vapours may cause drowsiness and dizziness.R50/53- Very toxic to aquatic organisms, may cause long-term adverse effects in theaquatic environment.R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquaticenvironment.
