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Dr. Andy Sun, Business Manager, HI&I June 24, 2020 Naturally Derived EO-Free Surfactants for Industrial Degreasing
Transcript
PowerPoint PresentationDr. Andy Sun, Business Manager, HI&I June 24, 2020
Naturally Derived EO-Free Surfactants for Industrial Degreasing
Content
• Challenges in Going Green in Industrial Degreasing • Suga®Boost in EO-free heavy-duty degreasing
Oils and greases Drawing compounds Chips and cutting fluids Polish and buffing compounds Rust and scale
Metal & Parts
Transportation Engine oil and greases Traffic films Bird drops and tree saps Dead bugs and insects Break dust and rusts Asphalts and clays Others
Oilfield Heavy oil and paraffin buildup Work-over rigs Coiled tubing units Pumping units Hand tools
Food Processing
Slaughterhouse Smokehouse
Bakery Brewery
• Carcinogenic and reproduction (APEs) • Irritation and sensitization
• Environment Concerns • VOC concern for solvent-based cleaners • Biodegradation and aqua toxicity
• Regulations • CA Prop 65 (1,4-dioxane, DCA, DEA) • NY new regulation on EO in retail products
• Performance • Available green surfactants like APG and amino acid types do not meet performance
requirements • Surfactants do not perform well across petroleum greases and animal greases (e.g. AEO does
well on removing petroleum-based grease, and SLES does well on animal fat)
Suga®Boost – Patent Pending • 100% or close to 100% naturally-derived • Very mild to eyes and skin contact, over harsh sulfates, alkoxylates, coco DEA • No GHS warning labels • Free of Prop 65 components (1,4-Dioxane, DEA, DCA, etc.) • Stable in wide range of pH • Stable in hard water and electrolyte solution without hydrotropes • Great environmental profiles (readily biodegradable, low aqua toxicity, direct release) • Broad regulation approval (EPA Safer Choice, USDA Biobased, EU Detergent Directive) • Compatible with majority of surfactants • Variety of chemistries that meet different formulation and performance demands • Superior Performance Over Traditional Surfactants
8
more to come
biodegradability requirement. This product meets the criteria for a surfactant under the EU Detergents Regulation (EC) 648/2004.
CONFIDENTIAL USE ONLY 9
10
Food Grease Lard (animal fat) Vegetable oil Egg powder (protein)
Test Conditions
Testing method: Immersion cleaning
Test temperature: Room temperature
% Soil Removal at 20 Minutes of Cleaning
Detergent Formula % WT Water q.s.
Sodium Metasilicate 3 Sodium Gluconate 2
EDTA, 40% 1 KOH, 45% 1
Active surfactant 5
SugaBoost 030
Trial 1
NP-9 40 NQ3 46 SugaBoost 030 40 SugaBoost 050 50
Time to 100% Clean, mins
Industrial Degreasing Performance of SugaBoost
Trial 2
NP-9 38 NQ3 28 SugaBoost 030 30 SugaBoost 050 60
Time to 100% Clean, mins.
% Soil Removal
Tergital NP-9 Vitech NQ3 SugaBoost 030 40 45 52.5
Time to Reach 100% Cleaning, mins SugaBoost 030 Vitech NQ3 Tergital NP-9 35 37 39
33 34 35 36 37 38 39
SugaBoost 030
Vitech NQ3
Tergitol NP-9
Greasy Soil: Engine oil / Lithium Grease
Testing method: Immersion cleaning
Test temperature: Room temperature
Sodium Metasilicate 3 Sodium Gluconate 2
EDTA, 40% 1 KOH, 45% 1
Active surfactant 5
Industrial Degreasing (cont.)
SugaBoost 030
Trial 1
NP-9 40 NQ3 46 SugaBoost 030 40 SugaBoost 050 50
Time to 100% Clean, mins
Industrial Degreasing Performance of SugaBoost
Trial 2
NP-9 38 NQ3 28 SugaBoost 030 30 SugaBoost 050 60
Time to 100% Clean, mins.
% Soil Removal
Tergital NP-9 Vitech NQ3 SugaBoost 030 40 45 52.5
Time to Reach 100% Cleaning, mins SugaBoost 030 Vitech NQ3 Tergital NP-9 35 37 39
Suga®Boost 030 in Food Soil Cleaning
0
20
40
60
80
100
Pe rc
ov al
Test Method: Immersion Cleaning Soil: Lard, egg powder, corn oil, red dye Detergent: Water, 0.07% EDTA, 0.006% phosphoric acid, 0.03% IPA, 0.0625% surfactant
CONFIDENTIAL USE ONLY 13
CONFIDENTIAL USE ONLY 15
256 – 26.6 Non-Irritating, Minimal PEG-75 Lanolin, Tween 20
26.5 – 11.8 Mildly Irritating 3% Sodium Dodecyl Sulfate
11.7 – 3.45 Moderate Irritation 5% Triton X-100
< 3.45 Severe, Extreme 5% Benzalkonium Chloride
Results indicate Suga®Boost 030 has a 'non-irritating, minimal' classification ET-50 (mins): >58.2 Non-Irritating, Minimal
Suga®Boost 030 Toxicological Properties Acute Skin Irritation • 48 Hour Occlusive skin patch test on human volunteers - 53 Test Subjects
- 53/53 showed no visible skin reaction - No potential for dermal irritation
Skin Sensitization • Repeat Insult Patch testing (HRIPT)
- Suga®Boost 030 does not indicate a potential for dermal irritation or allergic contact sensitization
CONFIDENTIAL USE ONLY 16
Suga®Boost 030 Applications • Heavy-duty industrial degreasing • Food processing (dairy, bakery,
slaughterhouse, meat packaging, etc.) • Grill and smokehouse • Pot and pans • Dish washing • Toilet bowl cleaning • Floor and tile cleaning • Hospital and senior houses • Hospitality services • General hard surface care
CONFIDENTIAL USE ONLY 17
Suga®Boost 030 Specifications Typical Properties Suga®Boost 030 Color, Gardner ‘98 4 Max. Solids, % 40.0 – 42.5 pH (10% aqueous) 6.0 – 8.0 Appearance, 10% aq. Clear Liquid Ross-Miles Foam Height (1%, 25C, DI water), mm
Immediate 125 1 minute 115 5 minutes 110
Draves Wetting (1% active), seconds 5.8
Surface Tension 1.00% 31.07 0.10% 31.53 CMC, % 0.005
CONFIDENTIAL USE ONLY 18
Suga®Boost 030 Formulations
Grill and Smokehouse Cleaner* (#5029) Compound Weight %
Water qs to 100.00 Sodium Hydroxide 2.0 Sodium Gluconate 0.5 Cola®Teric AP 3.5 Suga®Boost 030 2.0
Heavy Duty Industrial Degreaser* Compound Weight %
Water qs to 100.00 Sodium Gluconate 2.0 Sodium Metasilicate 3.0 Na4EDTA, 40% 1.0 KOH, 45% 1.0 Suga®Boost 030 12.2
CONFIDENTIAL USE ONLY 19
* Ready to use
CONFIDENTIAL USE ONLY 20
Suga®Boost 050 Specifications • DESCRIPTION Functionalized Alkyl Polyglucoside • LISTINGS US (TSCA)
EU (REACH) to come Canada (NDSL) Australia (AICS)
• USDA Bioprefered: 100% rating • Cleaning Gredients: Listed • EPA Safer Choice: Safe for Direct Release • Readily biodegradable per OECD 301 methods. This product meets the criteria for a surfactant
under the EU Detergents Regulation (EC) 648/2004.
CONFIDENTIAL USE ONLY 21
Suga®Boost 050 Hard Surface Cleaning Performance
Test Method: Immersion Cleaning Soil: Lard, egg powder, corn oil, red dye Detergent: Water, 0.07% EDTA, 0.006% phosphoric acid, 0.03% IPA, 0.0625% surfactant
0
20
40
60
80
100
120
Pe rce
nt of
CONFIDENTIAL USE ONLY 22
Suga®Boost 050 Toxicological Properties • MatTek Epi-Ocular: In vitro Acute Ocular Irritation Test
CONFIDENTIAL USE ONLY 23
256 – 26.6 Non-Irritating, Minimal PEG-75 Lanolin, Tween 20
26.5 – 11.8 Mildly Irritating 3% Sodium Dodecyl Sulfate
11.7 – 3.45 Moderate Irritation 5% Triton X-100
< 3.45 Severe, Extreme 5% Benzalkonium Chloride
Results indicate Suga®Boost 050 has a 'non-irritating, minimal' classification >256 mins. (ET-50 score) Non-Irritating
Suga®Boost 050 Toxicological Properties Acute Skin Irritation • 48 Hour Occlusive skin patch test on human volunteers - 53 Test Subjects
- 53/53 showed no visible skin reaction - No potential for dermal irritation
Skin Sensitization • Repeat Insult Patch testing (HRIPT)
- Suga®Boost 050 does not indicate a potential for dermal irritation or allergic contact sensitization
CONFIDENTIAL USE ONLY 24
Suga®Boost 050 Specifications Typical Properties Suga®Boost 050 Color, Gardner ‘98 4 Max. Solids, % 48.0 – 51.0 pH (10% aqueous) 6.0 – 8.0 Appearance, 10% aq. Clear Liquid Ross-Miles Foam Height (1%, 25C, tap water), mm
Immediate 150 1 minute 135 5 minutes 120
Draves Wetting (1% active), seconds 6.0
Surface Tension 1.00% 31.50 0.10% 31.03 CMC, % 0.007
CONFIDENTIAL USE ONLY 25
Compound Weight %
Water qs to 100.00 Sodium Gluconate 5.0 Sodium Citrate 3.0 Suga®Boost 050 20.0 Dilution 4oz/gallon
Green Vehicle Cleaner (For boats, trains, trucks, cars, etc)
Compound Weight %
Water qs to 100.00 Sodium Citrate 5 - 10 Trilon M 3 - 5 Suga®Boost 050 30 - 40 Dilution 30 to 50:1
CONFIDENTIAL USE ONLY 26
Suga®Boost 050 Applications • Green exterior washes (siding, roofs, decks) • Transportation cleaning (DIY carwash,
boats, trains, airplanes) • Laundry (home and commercial) • Hand soaps and hand dish • Food processing • Fire fighting • Agriculture and horticulture
CONFIDENTIAL USE ONLY 27
Suga®Boost for Industrial Cleaning Suga®Boost 030 Great naturally-derived surfactant for heavy-
duty industrial degreasing, transportation cleaning, metal and parts, food processing, machinery and equipment
Suga®Boost 050 Great naturally-derived surfactant qualified for EPA Direct Release. Great for exterior cleaning such as boat, train, airplane, roofs, decks, and exterior wall cleaning, laundry, hand soap, hand dish
More to come…
Content
Oils and greases Drawing compounds Chips and cutting fluids Polish and buffing compounds Rust and scale
Slide Number 4
Slide Number 5
Slide Number 6
Suga®Boost – Patent Pending
Test Conditions
Test Conditions
Immersion Cleaning Test
Suga®Boost 030 Applications
Suga®Boost 030 Specifications
Suga®Boost 030 Formulations
Suga®Boost 050 Toxicological Properties
Suga®Boost 050 Toxicological Properties
Suga®Boost 050 Specifications
Suga®Boost 050 Formulations
Suga®Boost 050 Applications
Slide Number 29

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