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Nutrient Removal:Costsand Benefits,Degrees of Difficulty, andRegulatory Decision Making

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    How to Participate Today

    How to participate Audio Modes

    Listen using Mic&Speakers

    Or, select Use Telephoneand dial the conference

    Submit your text questionsusing the Questions pane

    A recording will be availablefor replay shortly after thisweb seminar

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    Agenda2:00-2:05 Welcome and Introduction

    Amit Pramanik, WERF2:05-2:30 Finding the Sustainable Balance on Nutrient

    Removal

    Michael Falk, HDR, Inc.

    2:30-3:10 Research on Characterization and Speciationof N and P

    David Stensel, University of Washington

    3:10-3:35 Managing Water Quality Translating Research

    to PracticeDave Clark, HDR, Inc.

    3:35-3:45 Questions and Answers

    3:45 Adjourn

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    Michael Falk, PhD, PE

    Wastewater process engineer at HDR

    Engineering

    Specializes in nutrient removal and

    optimization of wastewater reactors

    Ph.D. from UC Davis with an emphasis onthe microbial ecology of activated sludge

    This work is part of WERFs Nutrient

    Challenge titled Striking a Balance

    between Nutrient Removal andSustainability

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    Tradeoff Between NutrientRemoval and Sustainability

    Michael Falk, PhD; J.B. Neethling, PhD; Dave Reardon, BCEEHDR Engineering, Inc.

    Amit Pramanik, PhD, BCEEM

    Water Environment Research Foundation

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    Acknowledgements

    WERF:

    Amit Pramanik, PhD, BCEEM

    Reviewers:

    Kartik Chandran, PhDMichael Stenstrom, PhD, PE, BCEEHDR:

    JB Neethl ing, PhD, PE, BCEEDave Reardon, PE, BCEE

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    Presentation Outline

    Focus/Objectives

    Background

    Results & Discussion

    Potential Impacts toWastewater Plants

    Summary & Conclusions

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    The Nutrient Storm is aNational Phenomenon

    Long Island Sound

    DO low in half ofsound

    Water quality tradingprogramimplemented

    Gulf of Mexico

    Large dead zone

    Importance ofphosphorus

    SacramentoRegional

    Concern over

    ammonia/nitrateloads in Delta

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    Focus/Objectives

    Determine sustainability impacts of fivelevels of treatment for 10 mgd plant

    Determine if there is a point of

    diminishing returns for sustainabilitywith increased treatment

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    What is Sustainability?

    Energy

    Polish YourGreen Image

    Greenhouse Gas

    Social

    Environmental

    Stewardship

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    Sustainability

    Sustainability is Often Described asAchieving the Triple Bottom Line

    Water Quality

    Greenhouse Gas

    Odors/Air Quality

    Economics/Life-Cycle Cost

    Analysis

    Waste Products Consumables

    Social/Community

    Impacts

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    What Did We Consider for theTriple Bottom Line?

    Economic Pillar:Total Project Cost

    O&M Cost

    Environmental Pillar: GHGs (Energy Demand, Chem

    manufacturing/hauling, N2O, biosolidshauling)

    Water Quality

    Ancillary Benefits of IncreasedTreatmentSocial Pillar:

    Discussion in WERF Report

    Existing metrics (Health)

    Future metrics (Social)

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    Treatment Level Objectives

    LevelBOD

    (mg/L)TSS

    (mg/L)TN

    (mg N/L)TP

    (mg P/L)

    1 30 30 - -

    2

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    Level Primary Ferm.

    Act Sludge

    Relative

    Footprint

    High

    Rate

    Clar. Filter MF/RO

    Return-

    Stream

    Treatment

    Metal

    Salt

    (Chem.)

    Methanol

    (Chem.)

    1

    1X

    2

    2X

    Optional Opt ional

    3

    2-2.5X

    4

    2-2.5X

    Denit.

    5

    2-2.5X

    Denit.

    a

    Treatment Unit Processes

    a RO requires brine management (assumed deep well injection)

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    System Inputs

    (Thicken/Digest/Dewater)

    Wastewater

    CollectionLiquid Stream

    Treatment

    Discharge

    Plant Boundary

    Boundary for this Study

    Biological Solids Treatment

    GHG

    EnergyProduction

    GHG

    Chem Mining,

    Manufacturing,

    & Hauling

    GHG

    GHG

    GHGGHG

    Solids

    Disposal

    GHG

    Deep Well

    Injection

    (Level 5)

    GHG

    Biosolids

    Hauling

    GHGCogen

    GHG

    Tertiary Add-On

    Disinfection

    GHG

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    GHG Distribution

    -2,000

    0

    2,000

    4,000

    6,000

    8,000

    10,000

    12,000

    14,000

    16,000

    18,000 N2OEmissions (w/Data Range as Bars)

    Biosolids Hauling and CH4 Emissions

    DeepWell Injection

    Aeration

    ChemicalsPumping/

    Mixing

    Miscellaneous

    Cogeneration

    CO2 eq mt/yr

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    Incremental GHG per Additional

    lb N or P Removed

    3

    18 23

    338

    0.5

    16

    190

    3,400

    0

    1

    10

    100

    1,000

    10,000

    Level 1 to 2 Level 2 to 3 Level 3 to 4 Level 4 to 5Incremen

    talGHG

    Increase

    perAdditionallb

    NPRemoved(CO2eq

    lb/N

    orPlb)

    Incremental GHG Increase per Change in Treatment Level for N

    Incremental GHG Increase per Change in Treatment Level for P

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    Potential Algae Production

    0

    2,500

    5,000

    7,500

    10,000

    12,500

    15,000

    17,500

    0

    5,000

    10,000

    15,000

    20,000

    25,000

    30,000

    35,000

    Level 1 Level 2 Level 3 Level 4 Level 5

    GHG

    Emissions(CO2

    eqmttons/yr)

    Alg

    aeProductionperTreatmentLevel

    (lbalga

    e/d)

    Algae Production GHG Emiss ions

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    Ancillary Benefits ofNutrient Removal

    Lower BOD and TSS discharge load

    Higher removal of micro-constituentsand metals

    Water more conditioned for filtration,disinfection, and reuse applications

    Fewer algal blooms Greater process stabil ity from the

    anaerobic/anoxic zones serving as

    selectors

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    Whats It Going to Cost Youfor a 10 mgd Plant?

    Treatment Level

    Total ProjectCosts

    ($ Million) i

    OperationsCost

    ($/MG) ii

    Total PresentWorth

    ($ Million) ii i

    1 (No N/P Removal) 93 250 110

    2 (8 mg N/L; 1 mg P/L) 127 350 150

    3 (4-8 mg N/L; 0.1-0.3 mg P/L) 144 640 180

    4 (3 mg N/L N;

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    Summary/Conclusions

    1. GHG impacts from all levels of treatment aredominated by energy consumption

    2. Levels 4 & 5 may have sustainability impacts thatoutweigh potential water quality improvements

    3. Why even discharge Levels 4/5?

    4. Capital and operating costs may make Level 4

    and 5 treatment difficult to implement withratepayers

    5. Use a more holistic approach to watershednutrient management

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    Potential Impacts toDischargers

    Nutrient wave is coming

    Impacts on site constrained plants

    (nutrient removal requires MOREspace)

    More energy and chemicals Additional operators (more skilled)

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    H. David Stensel, PhD, PE, BCEE

    Professor of civil and environmental engineering, University

    of Washington, Seattle, WA

    Principal research activities: biological wastewater

    treatment, biological nutrient removal, biodegradation of

    micropollutants, anaerobic digestion methods, and water

    reuse

    ASCE Rudolf Hering Medal, twice received the WEFHarrison Prescott Eddy Medal, and the Water Environment

    Bradley Gascoigne Medal for research publications

    Registered professional engineer and a diplomat in the American Academy of

    Environmental Engineers

    B.S. degree in Civil Engineering from Union College in Schenectady, N.Y. andM.E. and Ph.D. degrees in environmental engineering from Cornell University.

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    Coconuts and Bananas in BNR Effluents

    Research on Characterization and Speciation

    of Effluent Nitrogen and Phosphorus

    WERF Research

    Webinar

    October 5, 2011

    H. David Stensel, PhD, PE, BCEE

    University of Washington

    Seattle, WA

    36

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    WWTP Effluents are a Source ofNutrients to Surface Waters

    Nitrogen (N) and Phosphorus (P) are removedfrom wastewater effluents to limit nutrientenrichment and eutrophication in surface waters

    Nutrients enrich streams and lakes to promotehigher algae and plant growth

    Eutrophication causes low dissolved oxygen to

    harm aquatic life

    Chesapeake Bay, Long Island Sound, Gulf ofMexico, many coastal estuaries and fresh water

    impoundments are impaired due to nutrients 37

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    WWTPs Are Point Source DischargersRegulated for Effluent N and P

    Effluent permit concentrations typically based on not toexceed total nitrogen (TN) and/or total phosphorus (TP)concentration

    Range of low effluent TN concentration limits

    TN 3.0 mg/L common in Chesapeake and Floridacoast

    TN 2.0 mg/L or 1.0 mg/L applied in a few cases

    Range of low effluent TP concentration limits

    0.10 to 0.20 mg/L is becoming more common

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    The Dissolved Portion of TN and TP is a

    Major Component at Low Effluent Limits

    ~ 0.01 mg/LpOrg N

    DON

    NH3-N

    ~0.81.5 mg/L

    ~ 0.50 mg/L

    NOx-N~ 1.5 mg/L

    TN~3.0 mg/L

    TP~0.10 mg/L

    pP

    DP

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    The Problem with Trying to Reduce

    DON and DP Lower

    Biological processes can bepushed to meet low NH4-Nand Nox

    DON residual observed

    DON can increase withmore aeration time

    BNR effluent DON variesfor different WWTPs

    Increase chemical dose candrive reactive P to lowerconcentration

    But DP is not all reactive P

    0

    3

    6

    9

    12

    15

    Primary

    effluent

    Anaerobic

    effluent

    Anoxic

    effluent

    Aerobic

    effluent

    Concentration,gN/m3

    0.45-1.2 m

    0.1-0.45 m

    < 0.1 m

    Example:

    DON profile across Gdansk, Poland

    BNR WWTP -

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    But effluent DON

    concentration varies for

    different WWTPs

    Meeting TN3.0 mg/L

    can be possible,unreliable,

    or impossible

    0.0

    0.5

    1.0

    1.5

    2.0

    2.5

    3.0

    .01 .1 1 5 10 2030 50 7080 90 95 99 99.999.99

    DON Effluent Concentrations

    from 33 BNR Facilities

    Percent

    DONConc.,mg/L

    41

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    Chemical Analysis

    Total P

    Dissolved P (DP)

    Filtered

    Particulate P (PP)

    Reactive Dissolved P(RDP) Non-Reactive Dissolved P(nRDP)

    Total Reactive P

    (TRP)

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    Non-reactive Dissolved P is very

    significant in BNR tertiary effluents

    with high chemical dose

    0%

    20%

    40%

    60%

    80%

    100%

    NDWRFSDWRF MBR Ruidoso CUMF 1st BW 2nd BW TMF MSWTP Z2E

    Pcomposition

    PP

    DOP

    SRP

    Biological Removal ACTI FiltrationBlue WaterMBR Membrane

    nRDP

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    C d B P l

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    Coconuts and Bananas Postulate

    Bo Li University of Washington

    Some DON and nRDP is readily available

    to algae and some is not

    Reactive P (PO4-3)

    Amino acids

    Inorganic P

    Apatite

    ( Ca3(PO4)2 )

    AlPO4 FePO4

    .

    RecalcitrantsN and P in humic substances

    Organic P Polyphosphate

    Inositol hexakisphophate

    L--phosphatidyl choline

    phosphoenol pyruvate

    Glycerophosphate .

    Bioavailable

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    Readily bioavailable

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    WERF Nutrient Challenge ProgramEvaluate Bioavailability of Effluent DON and DP

    Professor David Sedlak, UC Berkeley

    Protocol for Algae Bioassay for effluent DON

    Evaluate fraction of recalcitrant DON at BNR WWTPs

    Evaluate type of constituents resistant to bioavailability Professor Michael Brett, University of Washington

    Protocol for Algae Bioassay for effluent DP

    Evaluate fraction recalcitrant P at BNR WWTPs and Tertiary

    Treatment with Chemicals

    Develop long term bioassay test

    Evaluate type of constituents resistant to bioavailability

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    Evaluate effect of Tertiary Treatment Processon bioavailable P fraction in effluent

    Identify banana

    Assess relationship between total reactive P,BAP, and total P

    Find a better way to identify banana

    Test Bioavailability of P speciesWhich species of banana will be more

    tasty?

    Or stated another way. . .

    Studies Used Bioassay Methods

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    Selenastrum capricornutumInitial concentration:10,000 cells/ml

    Incubate for 14 days.

    Culturing condition:

    1.Continuous Illumination

    2.Temperature: 24 2C

    3. shake at 110 rpm.

    Studies Used Bioassay Methods

    Cell Counts or Chlorophyll a to

    Measure Algae Production

    Bo Li

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    Highlights of Key Findings for DON

    Developed method to separate coconuts and

    bananas Hydrophobic DON was not bioavailable

    to algae in tests

    Protocol developed to minimize effect ofinorganic N in samples

    20-25% of effluent DON was recalcitrant for

    plants with low effluent TN (

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    Hydrophobic Fractions of

    WWTP Effluent DON

    0.0

    0.5

    1.0

    1.5

    2.0

    TMWRF KWWTP BRWRF SJWTP NDWRF SDWRF NAWTP RVWTP

    Location

    DON

    (mg

    N/L)

    Whole effluent

    Hydrophobic DON

    Hydrophilic DON

    A

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    Highlights of Key Findings for DP

    For tertiary treatment with chemicals the %

    bioavailable (bananas) decreased with

    increasing chemicals and lower effluent DP

    The recalcitrant effluent DP fraction ranged

    from 10 to 80% depending on the degree of

    treatment

    P in humic substance was not bioavailable

    % Bi il bl P i Effl t TP

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    % Bioavailable P in Effluent TP

    Decreases as Effluent P Decreases

    for Tertiary Chemical Treatment

    0

    20

    40

    60

    80

    100

    10100100010000

    BAP%&TP

    Model Predicted

    TP (ug/L)

    BAP%

    City of Spokane

    pilot plant

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    For Other Facilities Tested % BAP Varied

    from 10-50% for TP from 0.02 to 0.20 mg/L

    0

    20

    40

    60

    80

    10100

    Model Predicted

    NDWRF

    SDWRF

    MBR

    CUMF

    1st BW

    TMF

    MSWTP

    TP (ug/L)

    BAP%

    i d h bi i

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    If coconut will turn to banana?

    Investigate Hydrophobic Separation on

    BAP and Long Term BAP Analysis

    Wh i h Si ifi

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    What is the Significance

    of These Results?

    Not all effluent N and P species from nutrient removal

    WWTPs behave the same

    Water quality models do not adequately consider speciation of

    N and P with different bioavailability

    For very low effluent TP and TN goals the fraction of P andN that is recalcitrant is more significant and more difficult

    to remove

    Methods are available to evaluate recalcitrant fractions of

    effluent DON and DP Tool may be used to understand why some facilities have

    much higher effluent DON

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    QUESTIONS?

    Many thanks to Professor David Sedlak, Michael Brett, Scott

    Smith and April Gu and Dr. Haizhou Liu and Joonseon Jeong

    and Bo Li and WERF supporters for making this possible.

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    Dave Clark, P.E.

    HDRs National Director of Wastewater; leads strategicefforts in understanding wastewater market issues as they

    affect HDR clients

    Over 25 years of experience in the wastewater industry

    Works with local offices and business class technical

    leads to outline technical skills needed to assist clients in

    managing wastewater

    Managed a broad range of wastewater projects ranging

    from planning to detailed design and construction

    management, to discharge permit negotiations and TMDL

    Implementation Plans

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    Nutrient Removal

    Managing Water Quality Translating Research

    to PracticeWERF Webinar

    October 5, 2011

    David L. ClarkHDR Engineering

    [email protected]

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    Nutrient Removal

    Managing Water Quality

    Translating Research to Practice Regulatory Trends

    Numeric Nutrient Standards

    Treatment Technology Issues Regulatory Solutions

    Discharge Permitting

    Key Nutrient Management

    Issues

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    Nutrient Removal

    Regulatory TrendsNumeric Nutrient Standards

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    Nutrient Removal

    Acting Assistant Administrator Nancy Stoners March 16, 2011

    Memorandum to EPA Regional Administrators

    Working in Partnership with States to Address Phosphorus and NitrogenPollution through Use of a Framework for State Nutrient Reductions

    place new emphasis on working with states to

    achieve near-term reductions in nutrient loadings."

    nitrogen and phosphorus pollution has the potentialto become one of the costliest and the most

    challenging environmental problems we face

    It has long been EPA's position that numeric nutrient

    criteria targeted at different categories of water bodies

    and informed by scientific understanding of the

    relationship between nutrient loadings and waterquality impairment are ultimately necessary for

    effective state programs.

    EPA will support states that follow the framework but,

    at the same time, will retain all its authorities under

    the Clean Water Act

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    Nutrient Removal

    Challenges in Establishing Nutrient Criteria

    F 150 mg/m2 Chla D 1,250 mg/m2 Chla

    Scientific and Technical Basis for

    Montanas Numeric Nutrient Criteria

    Identifying Threshold of Harmto Beneficial Uses

    Numeric Nutrient Criteria

    Stressor Response

    Response Variables D.O., pH

    Chla, Benthic Algae

    Macroinvertebrates

    Fisheries

    Recreation/PublicPerception

    Translation of In-stream

    Criteria to Effluent Discharge

    Permit Limits

    Typical Concentrations ThatProtect Uses Are Low MikeSuplee, MDEQTotal Phosphorus 0.05 mg/lTotal Nitrogen 0.30 mg/l

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    Nutrient Removal

    Treatment Technology Issues

    Regulatory Solutions

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    Nutrient Removal

    Water Quality and

    Advanced Wastewater Treatment Waterbody Numeric Nutrient Standards

    Based on Natural Conditions Are Very

    Low

    Lower Than Treatment Technologies

    Are Capable of Achieving If AppliedEnd-of-Pipe

    Effectiveness of Advanced Treatment

    for Nutrient Removal

    Variability in Treatment Performance

    Reliability Effluent Speciation

    Bioavailability

    Translation to Discharge Permits

    303(d) Impairment Listings and TMDLs

    Direct Application to Discharge Permits

    Ideal Median Reliable

    Neethling, JB; Stensel, H.D.; Parker, D.S.; Bott, C.B.; Murthy, S.;

    Pramanik, A.; Clark, D. (2009) What is the Limit of Technology

    (LOT)? A Rational and Quantitative Approach. Proceedings of the

    WEF Nutrient Removal Conference, Washington DC, Water

    Environment Federation, Alexandria, Virginia.

    Treatment Performance Statistics

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    Nutrient Removal

    Regulatory Solutions Water Quality Variances,

    Treatment Technology Standards, Affordability Tests

    Key Areas

    Permit Requirements

    Below the Capabilities ofWastewater Treatment

    Technology

    Water Quality Variances

    Treatment TechnologyLimits

    Affordability Tests

    Case Study Examples

    Montana Senate Bill 95 andSenate Bill 367 Affordability Test (1% MHI)

    Limit of Technology

    Treatment Technology Std(TP 1 mg/L, TN 10 mg/L

    Wisconsin Dual Legislation Numeric Nutrient Criteria

    Treatment Technology Standard

    Adaptive Management

    Colorado New Regulation #85 Numeric Nutrient Criteria

    Treatment Technology Standard

    Adaptive Management

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    Nutrient Removal

    Wisconsin

    Midwest Environmental Advocates Notice ofIntent to Sue EPA Nov 23, 2009

    Failure to Perform its Non-discretionary

    Duty to Promulgate Numeric Nutrient

    Criteria

    2010 Rulemaking

    Phosphorus Criteria for Streams

    Streams 0.075 mg/L

    Large Rivers 0.100 mg/L

    Chapter NR217 Effluent Standards and

    Limitations for Phosphorus

    Implementation by AdaptiveManagement

    Watershed Adaptive Management Option

    NPS + Stormwater

    Numerical EffluentLimitations

    1st Permit

    TP 1 mg/L

    Rolling 12 Mo. Ave

    2nd Permit

    TP

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    Nutrient Removal

    Colorado Initial Nutrient Criteria for Rivers and Streams

    February 9, 2010

    Selecting Numeric Nutrient Criteria That Allow

    5% Decrease in Biological Condition

    Multi Metric Macroinvertebrate Index

    Regulation #31 Basic Standards and

    Methodologies for Surface Water

    New Section 31.17 Nutrient Interim Values After May 31, 2017 and Prior to May 31, 2022

    Regulation #85 Nutrients Management

    Control Regulation Establishes Numerical Effluent Limitations

    Existing Plants

    First Level BNR (3-stage)

    TP 1 mg/L

    TIN 10 mg/L

    New Plants

    Enhanced BNR (4 & 5-stage)

    TP 0.7 mg/L

    TIN 7 mg/L

    Running Annual Median

    Rivers and Streams Cold Water Warm Water

    Chl a mg/m2 150 150

    TP, ug/L 110 160

    TIN, ug/L 400 2,000

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    Nutrient Removal

    Montana 150 mg Chla/m2 Considered

    Nuisance Threshold by Public

    Rarely Occurs in Western

    Montana Reference Streams

    Harm-to-Use Threshold for

    Salmonid Streams Salmonid Growth Enhanced by

    Productivity Up to 150 mg Chla/m2

    DO Problems Begin at Higher Levels

    150 mg Chla/m2 More Common

    in Prairie Streams (E. MT)

    2009 Senate Bill 95 Variance Temporary Nutrient

    Standards

    Economic Hardship

    Substantial and Widespread

    Targeted 1% MedianHousehold Income

    Limits of Technology

    2011 Senate Bill 367

    MDEQ TP = 0.100 mg/L TN 5

    mg/L Monthly Average

    League of Cities TP = 1 mg/L

    TN 10 mg/L Seasonal Average

    F 150 mg/m2 Chla D 1,250 mg/m2 Chla

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    Nutrient Removal

    Discharge Permitting

    Key Nutrient Management Issues

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    Nutrient Removal

    Appropriate Discharge

    Permit Guidance for Nutrients Translation water quality criteria to

    NPDES to permit limits

    Critical interpretation of water quality

    issues

    Pre-formulated permit guidance

    from EPA and States often focused

    on toxics

    Appropriate averaging periods Variability in low nutrient plant

    performance

    Over-specifying effluent discharge permit limits will not

    provide significant additional water quality protection

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    Nutrient Removal

    Nutrients Differ from ToxicsNutrients

    No Immediate Impact

    Aside from Ammonia

    Watershed Scale Impacts

    Nutrient Enrichment Leads toAquatic Growth

    Algal Response Over

    Longer Periods

    Longer Averaging Period

    Appropriate for Nutrients

    Seasonal or Annual Averages

    Appropriate

    Treatment Technology

    Variability at Low Levels in the

    Best Technologies

    Toxics

    Acute and Chronic Impacts

    on Aquatic Life

    Chlorine, Metals, Organics

    Near-field (mixing zone) andFar-field (watershed)

    Impacts

    Long Term Response

    Average Limits

    Short Term Response

    Maximum Limits Required

    Treatment Technology

    Available Technology to

    Prevent Excursions

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    Nutrient Removal

    Permit Structure Long Term Seasonal

    Averages, Seasonal Mass LimitsKey Areas Translation of TMDL

    Requirements to Effluent

    Discharge Permits

    Appropriate Averaging Periodsfor Nutrient Limits

    Maximum Day and Maximum

    Week Dilemmas

    Effluent Mixing Zones

    Permit Requirements Below theCapabilities of Wastewater

    Treatment Technology

    Novel NPDES Permit

    Approaches

    Case Study Examples

    Chesapeake Bay TMDL

    Jim Hanlon Memo on Annual Averaging

    Nitrogen and Phosphorus

    Tualatin River Clean Water Services

    Seasonal Median TP Concentration Las Vegas Wash City Las Vegas, CCSD,

    Henderson

    Seasonal Mass TP Loading Shared

    Between 3 Dischargers

    Spokane River DO TMDL

    Seasonal Mass Loading Limits forPhosphorus, NH3N, CBOD

    Coeur dAlene (Region 10 EPA)

    Spokane County (Washington Ecology)

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    Nutrient Removal

    NPDES Permitting Regulations

    40 CFR 122.45(d) requires that all permit limits be

    expressed as average monthly limits and average weekly

    limits for publicly owned treatment works (POTWs) and

    as both average monthly limits and maximum daily limitsfor all others, unless impracticable.

    Individual permit wri ters in every nutr ient limited watershed must interpret these

    NPDES regulations and the definition of impracticable with limited guidance

    Maximum monthly, weekly, and daily limi ts likely to be exceeded by even the best

    designed and operated low nutrient treatment facil ities

    Effluent N and P concentration is h ighly variable for even the best designed andoperated low nutrient treatment facili ties

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    Nutrient Removal

    Case Study: Chesapeake BayDaily Maximum, Weekly Average andMonthly Average Limits Not Mandatory

    Guidance from EPA Headquarters

    Office of Wastewater Management

    Annual Permit Limits for Nitrogen

    and Phosphorus for PermitsDesigned to Protect Chesapeake

    Bay

    permit limits expressed as an

    annual limit are appropriate and

    that it is reasonable in this case

    to conclude that it is

    impracticable to express permit

    effluent limits as daily maximum,

    weekly average, or monthly

    average effluent limitations.

    Jim Hanlon, Office of WastewaterManagement, March 3, 2004

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    Nutrient Removal

    Variety of Successful Permit Structures

    Nationally for NutrientsLocation Total Phosphorus

    LimitsComments

    Clean Water Servicesof Washington

    County, OR

    0.100 mg/l Monthly Median, May 1to Oct 31

    Watershed Permit

    Las Vegas, ClarkCounty, Henderson, NV

    334 lbs/day(130/174/30 lbs/day)

    Mar 1 to Oct 31Cooperative Agreementto Share for Flexibi lity

    Alexandria, VA 0.18 mg/l and 37 kg/day

    0.27 mg/l and 55 kg/day

    Monthly Average

    Weekly Average

    Concentration Only, Mass Only, Both Seasonal Limits

    Mean or Median

    Shared Capacity

    Case Study Example: Spokane River Dischargers

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    Nutrient Removal

    (Washington Ecology, Idaho DEQ, EPA Region 10)

    Dissolved Oxygen TMDL

    Very Restrictive

    Cumulative Anthropogenic

    D.O. Depression

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    Nutrient Removal

    Permit Structure Effluent LimitsMass and Concentration

    Long Averaging Periods

    Preferred

    Maximum monthly, weekly, and

    daily limits likely to beexceeded by even the best

    designed and operated low

    nutrient treatment facilities

    Individual permit writers in

    every nutrient limitedwatershed must interpret these

    NPDES regulations and the

    definition of impracticable

    with limited guidance

    Mass Only

    Mass Limits Provide Greater

    Flexibility

    Supports Effluent Reuse

    Supports Trading/Water QualityOff-sets

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    Nutrient Removal

    Permit Structure Nutrient Speciation

    and BioavailabilityKey Areas

    Low N and P Effluent

    Speciation

    Refractory N and P Not Biodegradable

    Bioavailability?

    Effluent Limits Based on Total

    or Inorganic N and P?

    Inorganic Limits Avoid

    Refractory Constituents

    Case Study Examples

    Onondaga Lake TMDL, Syracuse,NY

    Onondaga County (NYDEC)

    Spokane River DO TMDL Spokane County (Washington

    Ecology)

    Coeur dAlene (Region 10 EPA)

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    Question & Answer Session

    To ask our speakers a question,

    please follow the instructions

    on the next slide.

    Q & A

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    Q & A

    Submit your text questions nowusing your Questions Window

    Closing & Follow Up

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    Closing & Follow-Up

    Thank you for participating!

    As you leave todays session, an online survey

    will follow. We appreciate your feedback.

    This presentation has been recorded. A link to

    the recording will be available at www.werf.org

    later this week.

    For more information, go to www.werf.org

    http://www.werf.org/http://www.werf.org/http://www.werf.org/http://www.werf.org/

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