Multiple Choice Questions (MCQ) topic quiz
6.2 Nitrogen compounds, polymers and synthesis
Instructions and answers for teachersThese instructions cover the learner activity section which can be found on page 10. This Lesson Element supports OCR A Level Chemistry A.
When distributing the activity section to the learners either as a printed copy or as a Word file you will need to remove the teacher instructions section.
The Activity This Lesson Element is a teaching and learning resource containing 10 multiple choice questions (MCQs) on the theme of nitrogen compounds, polymers and synthesis. Some questions might require synoptic thinking, using knowledge and ideas from various topics across the full A Level content.
This resource can be used to test and consolidate understanding at the end of a topic or to revisit and refresh knowledge at a later point in the course.
Learning OutcomesThis lesson element relates to the specification learning outcomes 6.2.1(b), 6.2.2(a), 6.2.2(d), 6.2.3(a), 6.2.3(c), 6.2.4(b), 6.2.4(c), 6.2.5(a), 6.2.5(c)
Introduction Multiple choice questions allow rapid coverage of a wide range of sub-topics.
Contrary to a widespread belief among students, multiple choice questions are not necessarily easy – they can be easy, moderate or difficult.
The questions are written so that the incorrect answers are plausible distractors based on common errors or misconceptions.
The questions in this quiz cover topics mainly from specification sections:
6.2 Nitrogen compounds, polymers and synthesis
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Multiple Choice Questions (MCQ) topic quiz – answers
1. What are the correct set of reagents and conditions for the two reactions shown?
CH3CHClCH3 CH3CH(NH2)CH3 C6H5NO2 C6H5NH2
A dilute ethanolic NH3 Sn / conc. H2SO4
B excess ethanolic NH3 Sn / conc. HCl
C nitric acid / 50 °C NaBH4
D nitric acid / <10 °C NaBH4
A Incorrect, dilute ammonia would cause impurities to form.
B Correct answer
C Incorrect, they have possibly identified that the nitro group needs reducing.
D Incorrect, they have possibly identified that the nitro group needs reducing.
Your answer
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B
2. Which compound is an amino acid with the R group –CHO?
A R is CH2COOH in this case.
B Incorrect, learners often mistake CH2OH for CHO.
C Incorrect, the COOH and NH2 are not connected to the same carbon so this is not an amino acid.
D Correct answer
Your answer
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D
3. How many chiral centres does the molecule shown have?
A 2 They have not included any of the ring carbons.
B 7 Correct answer
C 8 Incorrect, learners often think C=O bonds can be chiral.
D 9 Incorrect, as above but the learner has possibly included the carbon with two CH3 groups.
Your answer
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B
4. Which molecule or pairs of molecules below will not undergo condensation polymerisation to form a polyester or polyamide?
A 4-aminohexanoic acid They may have forgotten that single-monomer polymers can be made.
B 4-hydroxybutylamine Correct answer
C 2-methyl-6-hydroxyhexanoyl chloride
They may have forgotten that acyl chlorides can behave like carboxylic acids.
D propane-1,3-diol and hexanedioic acid
The diol and dioic acid will form a polyester.
Your answer
5. Which monomer could form both of the polymer chains shown?
A Incorrect, they have confused the position of the OH group.
B Correct answer
C Incorrect, the condensation polymer would have no side chains.
D Incorrect
Your answer
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B
B
6. Haloalkanes react with CN– to form nitriles, for example:
CH3CH2CHClCH3 + CN– CH3CH2CH(CH3)CN + Cl–
By what mechanism does this reaction proceed?
A electrophillic substitution Incorrect, they may have been confused as the CN– has a negative charge, which relates ‘electro’.
B free radical substitution Incorrect, they may have plumped for a default reaction involving chlorine.
C nucleophilic addition Incorrect, two reactants leading to two products always suggests substitution.
D nucleophilic substitution Correct answer.
Your answer
7. Butanone can undergo addition when mixed with NaCN(aq)/H+(aq), forming product A.
Product A can then undergo hydrolysis when heated with dilute HCl, forming product
B.
What is the systematic name of product B?
A 2-hydroxypentanoic acid They have confused butanone with butanal.
B 2-hydroxypentylamine They have made both mistakes from A and D.
C 2-methyl-2-hydroxybutanoic acid
Correct answer.
D 2-methyl-2-hydroxybutylamine They have confused reduction of CN– with hydrolysis.
Your answer
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D
C
8. What is the correct two-step synthesis to produce 2-hydroxybutanenitrile from propan-1-ol?
A 1) NaCl/H2SO4; 2) NaCN/ethanol
They have tried to create the nitrile via a haloalkane, this however replaces the OH group.
B 1) NaCN/ethanol; 2) NaCl/H2SO4
As above, but they have put the steps in the wrong order.
C 1) NaCN(aq)/H+(aq); 2) K2Cr2O7/H2SO4 under distillation
Incorrect, the CN– group only attacks a carbonyl.
D 1) K2Cr2O7/ H2SO4 under distillation; 2) NaCN(aq)/H+(aq)
Correct answer
Your answer
9. What are the correct reagents and conditions for the organic synthesis shown?
A 1) HNO3/H2SO4; 2) CH3CH3Cl/FeCl3
Incorrect, they have listed reagents for nitration, possibly confused by the NO2 group.
B 1) CH3CH3Cl/FeCl3; 2) NaOH/H2O
Incorrect, The first step would add an ethyl group but the second would have no effect.
C 1) CH3COCl/AlCl3; 2) NaBH4
Correct answer
D 1) Cl2/AlCl3; 2) CH3CH2NH2/ethanol
Incorrect, neither reaction really relates to the synthesis at hand.
Your answer
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D
C
10. Benzoic acid can be produced by protonating sodium benzoate:
C6H5COONa + HCl C6H5COOH + NaCl
The benzoic acid formed can be purified by recrystallisation.
The solubility of benzoic acid in water is shown in the table.
Water solubility Benzoic acid
Solubility at 25 °C / g dm–3 3.4
Solubility at 100 °C / g dm–3 56.3
Which of the following statements applies/apply to the recrystallisation of benzoic acid?
1. Water is an appropriate solvent for the recrystallisation of benzoic acid.
2. The impure product should be dissolved in hot solvent.
3. The recrystallised product should be washed with warm solvent.
A 1, 2 and 3 Cold water must be used to wash the product to reduce the amount lost during washing.
B only 1 and 2 Correct answer: The difference in solubility is important for recrystallisation; the solid must be dissolved at high temperature to maximise the effect of this difference.
C only 2 and 3 Incorrect, they may have discounted option 1, possibly having misunderstood the question or the role of solubility in recrystallisation.
D only 1 Incorrect, see comments above.
Your answer
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B
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Multiple Choice Questions (MCQ) topic quiz
6.2 Nitrogen compounds, polymers and synthesis
Learner Activity
1. What are the correct set of reagents and conditions for the two reactions shown?
CH3CHClCH3 CH3CH(NH2)CH3 C6H5NO2 C6H5NH2
A dilute ethanolic NH3 Sn / conc. H2SO4
B excess ethanolic NH3 Sn / conc. HCl
C nitric acid / 50 °C NaBH4
D nitric acid / <10 °C NaBH4
Your answer
2. Which compound is an amino acid with the R group –CHO?
A B
C D
Your answer
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3. How many chiral centres does the molecule shown have?
A 2
B 7
C 8
D 9
Your answer
4. Which molecule or pairs of molecules below will not undergo condensation polymerisation to form a polyester or polyamide?
A 4-aminohexanoic acid
B 4-hydroxybutylamine
C 2-methyl-6-hydroxyhexanoyl chloride
D propane-1,3-diol and hexanedioic acid
Your answer
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5. Which monomer could form both of the polymer chains shown?
A
B
C
D
Your answer
6. Haloalkanes react with CN– to form nitriles, for example:
CH3CH2CHClCH3 + CN– CH3CH2CH(CH3)CN + Cl–
By what mechanism does this reaction proceed?
A electrophillic substitution
B free radical substitution
C nucleophilic addition
D nucleophilic substitution
Your answer
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7. Butanone can undergo addition when mixed with NaCN(aq)/H+(aq), forming product A.
Product A can then undergo hydrolysis when heated with dilute HCl, forming product
B.
What is the systematic name of product B?
A 2-hydroxypentanoic acid
B 2-hydroxypentylamine
C 2-methyl-2-hydroxybutanoic acid
D 2-methyl-2-hydroxybutylamine
Your answer
8. What is the correct two-step synthesis to produce 2-hydroxybutanenitrile from propan-1-ol?
A 1) NaCl/H2SO4 2) NaCN/ethanol
B 1) NaCN/ethanol2) NaCl/H2SO4
C 1) NaCN(aq)/H+(aq) 2) K2Cr2O7/H2SO4 under distillation
D 1) K2Cr2O7/ H2SO4 under distillation 2) NaCN(aq)/H+(aq)
Your answer
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9. What are the correct reagents and conditions for the organic synthesis shown?
A 1) HNO3/H2SO4 2) CH3CH3Cl/FeCl3
B 1) CH3CH3Cl/FeCl3 2) NaOH/H2O
C 1) CH3COCl/AlCl3 2) NaBH4
D 1) Cl2/AlCl3 2) CH3CH2NH2/ethanol
Your answer
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10. Benzoic acid can be produced by protonating sodium benzoate:
C6H5COONa + HCl C6H5COOH + NaCl
The benzoic acid formed can be purified by recrystallisation.
The solubility of benzoic acid in water is shown in the table.
Water solubility Benzoic acid
Solubility at 25 °C / g dm–3 3.4
Solubility at 100 °C / g dm–3 56.3
Which of the following statements applies/apply to the recrystallisation of benzoic acid?
1. Water is an appropriate solvent for the recrystallisation of benzoic acid.
2. The impure product should be dissolved in hot solvent.
3. The recrystallised product should be washed with warm solvent.
A 1, 2 and 3
B only 1 and 2
C only 2 and 3
D only 1
Your answer
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