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1 Identification

· Product identifier

· Trade name: GreenSeal

· Article number: DK072· Relevant identified uses of the substance or mixture and uses advised against

No further relevant information available.· Details of the supplier of the safety data sheet· Manufacturer/Supplier:

Company: Omnia Specialities Australia Pty LtdAddress: Tramway RoadMORWELL VIC 3840Telephone Number: +61-3 5133 9118Facsimile Number: +61-3 5133 9114

· Further information obtainable from: Rene.Mommers@omnia.net.au· Emergency telephone number:

+61 3 513 39118+61 408 375135

2 Hazard(s) Identification

· Classification of the substance or mixture

corrosion

Skin Corr. 1B H314 Causes severe skin burns and eye damage.

Eye Dam. 1 H318 Causes serious eye damage.

Acute Tox. 4 H302 Harmful if swallowed.

Skin Sens. 1 H317 May cause an allergic skin reaction.

· Label elements· GHS label elements

The product is classified and labelled according to the Globally Harmonised System (GHS).· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labelling:Teric 200Emulsion DA-101Teric N9

· Hazard statementsHarmful if swallowed.Causes severe skin burns and eye damage.

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May cause an allergic skin reaction.· Precautionary statements

If medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Do not breathe dusts or mists.IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.Immediately call a POISON CENTER/doctor.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

3 Composition and Information on Ingredients

· Chemical characterisation: Mixtures· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components:

Teric 200 Skin Corr. 1B, H314; Eye Dam. 1, H318 Acute Tox. 4, H302; Acute Tox. 4, H312

25-50%

CAS: 9016-45-9NLP: 500-024-6

Teric N9 Eye Dam. 1, H318 Acute Tox. 4, H302; Acute Tox. 4, H312

25-50%

CAS: 24937-78-8 Emulsion DA-101 Skin Sens. 1, H317 2.5-10%

· SVHC

Teric 200

· Additional information: For the wording of the listed hazard phrases refer to section 16.· Other hazards that do not result in classification None

4 First Aid Measures

· Description of first aid measures· General information:

Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48hours after the accident.

· After inhalation:Supply fresh air and to be sure call for a doctor.Remove to fresh air.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact:Immediately wash with water and soap and rinse thoroughly. Remove contaminated clothing. Flush affectedareas with plenty of water and soap.

· After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.· After swallowing:

Call for a doctor immediately. Do not induce vomiting. Rinse mouth with water (only if person is conscious).· Information for doctor: Treat supportive and symptomatically· Most important symptoms and effects, both acute and delayed No further relevant information available.· Indication of any immediate medical attention and special treatment needed

No further relevant information available. AU

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5 Fire Fighting Measures

· Extinguishing media· Suitable extinguishing agents:

Use fire extinguishing methods suitable to surrounding conditions. Water spray jet, foam. Dry fire-extinguishing substance.

· Special hazards arising from the substance or mixtureDuring heating or in case of fire poisonous gases are produced.

· Advice for firefighters· Protective equipment: Mouth respiratory protective device.

6 Accidental Release Measures

· Personal precautions, protective equipment and emergency proceduresMount respiratory protective device.Wear protective equipment. Keep unprotected persons away.

· Environmental precautions:Do not allow product to reach sewage system or any water course.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water. Should not be released into the environment.

· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Transfer into suitablecontainers. To be disposed of in compliance with existing regulations. After cleaning, flush away traces withwater.Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.

· Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

7 Handling and Storage

· Handling:· Precautions for safe handling

Ensure good ventilation/exhaustion at the workplace.Prevent formation of aerosols.

· Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.Protect from heat.Keep respiratory protective device available.

· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:

Observe the rules usually applicable when handling chemicals.· Information about storage in one common storage facility: Not required.· Further information about storage conditions: Protect from heat and direct sunlight.· Specific end use(s) No further relevant information available.

8 Exposure controls and personal protection

· Additional information about design of technical facilities:Ensure eyewash stations and safety showers are close to the workstation location.

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· Control parameters· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.

· Additional information: The lists valid during the making were used as basis.

· Exposure controls· Personal protective equipment:· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Avoid contact with the eyes.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective device.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.

· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to beobserved.

· Eye protection:

Tightly sealed goggles

· Body protection: Protective work clothing

9 Physical and Chemical Properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: FluidColour: Green

· Odour: Characteristic· Odour threshold: Not determined.

· pH-value: Not determined.

· Change in conditionMelting point/freezing point: Undetermined.Initial boiling point and boiling range: Undetermined.

· Flash point: Not applicable.

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· Flammability (solid, gas): Not applicable.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto-ignition temperature: Product is not selfigniting.

· Explosive properties: Product does not present an explosion hazard.

· Explosion limits:Lower: Not determined.Upper: Not determined.

· Vapour pressure: Not determined.

· Density: Not determined.· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.

· Solubility in / Miscibility withwater: Not miscible or difficult to mix.

· Partition coefficient: n-octanol/water: Not determined.

· Viscosity:Dynamic: Not determined.Kinematic: Not determined.

· Solvent content:Organic solvents: 0.2 %VOC (EC) 0.21 %

· Other information No further relevant information available.

10 Stability and Reactivity

· Reactivity No further relevant information available.· Chemical stability· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Possibility of hazardous reactions No dangerous reactions known.· Conditions to avoid No further relevant information available.· Incompatible materials: No further relevant information available.· Hazardous decomposition products: No dangerous decomposition products known.

11 Toxicological Information

· Information on toxicological effects· Acute toxicity

· LD/LC50 values relevant for classification:

Teric 200

Oral LD50 960-3,980 mg/kg (rat)

Dermal LD50 2,000-2,990 mg/kg (rabbit)

107534-96-3 Tebuconazole

Oral LD50 625 mg/kg (Dog)

625 mg/kg (Sheep)

1,615 mg/kg (mouse)

>5,000 mg/kg (rat)(Contd. on page 6)

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>1,000 mg/kg (rabbit)

Dermal LD50 >5,000 mg/kg (rat)

Inhalative LC50 4 h 0.82 mg/l (rat)

Occupational Exposure Limit 0.2 mg/m³ (Worker)

· Primary irritant effect:· Skin corrosion/irritation No irritant effect.· Serious eye damage/irritation Strong irritant with the danger of severe eye injury.· Respiratory or skin sensitisation Sensitisation possible through skin contact.· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:HarmfulIrritant

12 Ecological Information

· Toxicity

· Aquatic toxicity:

Teric 200

LC50 96 hours 3.8-7.7 mg/L (Fish)

107534-96-3 Tebuconazole

EC50 48 h 4 mg/l (Daphnia magnus)

EC50 96 hr (static) 1.45 mg/L (Algae)

EC50 120 hr 0.15 mg/L (Lemna minor (common duckweed))

LC50 96 hours (dynamic) 5.7 mg/L (Lepomis cyanellus (Green Sunfish))

4.4 mg/L (Oncorhynchus mykiss (rainbow trout))

5.9 mg/L (Pimephales promelas (Fathead Minnow))

· Persistence and degradability No further relevant information available.· Behaviour in environmental systems:· Bioaccumulative potential No further relevant information available.· Mobility in soil No further relevant information available.· Ecotoxical effects:· Remark: Toxic for fish· Additional ecological information:· General notes:

Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for waterDo not allow product to reach ground water, water course or sewage system, even in small quantities.Danger to drinking water if even extremely small quantities leak into the ground.Also poisonous for fish and plankton in water bodies.Toxic for aquatic organisms

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· Recommendation

Disposal according to local regulations.Must not be disposed together with household garbage. Do not allow product to reach sewage system.

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· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.

14 Transport information

· UN-Number· ADG, IMDG, IATA UN3082

· UN proper shipping name GreenSeal· ADG, IATA ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

LIQUID, N.O.S. (Teric N9, Teric 200)· IMDG ENVIRONMENTALLY HAZARDOUS SUBSTANCE,

LIQUID, N.O.S. (Teric N9, Teric 200, Tebuconazole),MARINE POLLUTANT

· Transport hazard class(es)

· ADG, IMDG, IATA

· Class 9 Miscellaneous dangerous substances and articles.· Label 9

· Packing group· ADG, IMDG, IATA III

· Environmental hazards: Product contains environmentally hazardoussubstances: Teric 200

· Marine pollutant: Symbol (fish and tree)· Special marking (ADG): Symbol (fish and tree)· Special marking (IATA): Symbol (fish and tree)

· Special precautions for user Warning: Miscellaneous dangerous substances andarticles.

· Danger code (Kemler): 90· EMS Number: F-A,S-F· Stowage Category A · ERG No. None

· Transport in bulk according to Annex II of Marpoland the IBC Code Not applicable.

· Transport/Additional information:

· ADG· Limited quantities (LQ) 5L· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 1000 ml

· Transport category 3

· IMDG· Limited quantities (LQ) 5L· Excepted quantities (EQ) Code: E1

Maximum net quantity per inner packaging: 30 mlMaximum net quantity per outer packaging: 1000 ml

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· UN "Model Regulation": UN 3082 ENVIRONMENTALLY HAZARDOUSSUBSTANCE, LIQUID, N.O.S. (TERIC N9, TERIC200), 9, III

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Australian Inventory of Chemical Substances

Teric 200

9016-45-9 Teric N9

24937-78-8 Emulsion DA-101

111-76-2 Butyl oxitol

57-55-6 MONO PROPYLENE GLYCOL

Tylose H 30000 YP2

· Standard for the Uniform Scheduling of Medicines and Poisons

111-76-2 Butyl oxitol S6

107534-96-3 Tebuconazole S5

· GHS label elementsThe product is classified and labelled according to the Globally Harmonised System (GHS).

· Hazard pictograms

GHS05 GHS07

· Signal word Danger

· Hazard-determining components of labelling:Teric 200Emulsion DA-101Teric N9

· Hazard statementsHarmful if swallowed.Causes severe skin burns and eye damage.May cause an allergic skin reaction.

· Precautionary statementsIf medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Do not breathe dusts or mists.IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.Immediately call a POISON CENTER/doctor.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.· Seveso category E1 Hazardous to the Aquatic Environment· Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t· Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t

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· National regulations:

· Other regulations, limitations and prohibitive regulations

· Substances of very high concern (SVHC) according to REACH, Article 57

Teric 200

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH302 Harmful if swallowed.H312 Harmful in contact with skin.H314 Causes severe skin burns and eye damage.H317 May cause an allergic skin reaction.H318 Causes serious eye damage.

· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationEINECS: European Inventory of Existing Commercial Chemical SubstancesELINCS: European List of Notified Chemical SubstancesCAS: Chemical Abstracts Service (division of the American Chemical Society)VOC: Volatile Organic Compounds (USA, EU)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percentPBT: Persistent, Bioaccumulative and ToxicSVHC: Substances of Very High ConcernvPvB: very Persistent and very BioaccumulativeAcute Tox. 4: Acute toxicity – Category 4Skin Corr. 1B: Skin corrosion/irritation – Category 1BEye Dam. 1: Serious eye damage/eye irritation – Category 1Skin Sens. 1: Skin sensitisation – Category 1

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