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1 Identification

· Product identifier

· Trade name: Rhizovator A1

· Article number: DK058· Relevant identified uses of the substance or mixture and uses advised against

For use in the agricultural sector.· Technical function Fertilizers (soil amendments)· Details of the supplier of the safety data sheet· Manufacturer/Supplier:

Company: Omnia Specialities Australia Pty LtdAddress: Tramway RoadMORWELL VIC 3840Telephone Number: +61-3 5133 9118Facsimile Number: +61-3 5133 9114

· Further information obtainable from: info@omnia.net.au· Emergency telephone number:

ISS First Response03 8769 3688

2 Hazard(s) Identification

· Classification of the substance or mixture

health hazard

Carc. 1A H350 May cause cancer.

Acute Tox. 4 H302 Harmful if swallowed.

Skin Irrit. 2 H315 Causes skin irritation.

Eye Irrit. 2A H319 Causes serious eye irritation.

· Label elements· GHS label elements

The product is classified and labelled according to the Globally Harmonised System (GHS).· Hazard pictograms

GHS07 GHS08

· Signal word Danger

· Hazard-determining components of labelling:Humic acidZn EDTABoron 20.5Cu EDTA

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· Hazard statementsHarmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause cancer.

· Precautionary statementsIf medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.Specific treatment (see on this label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

· Other hazards· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.

3 Composition and Information on Ingredients

· Chemical characterisation: Mixtures· Description: Mixture of substances listed below with nonhazardous additions.

· Dangerous components:

Humic acid Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319

10-25%

Kelp extract Acute Tox. 4, H302

2.5-10%

EINECS: 237-865-0 Zn EDTA Carc. 1A, H350 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

2.5-10%

CAS: 39208-15-6 Cu EDTA Acute Tox. 2, H300 Carc. 1A, H350 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

2.5-10%

Boron 20.5 Repr. 2, H361 Acute Tox. 4, H332

≤2.5%

EINECS: 239-407-5 Mn EDTA Carc. 2, H351 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

≤2.5%

CAS: 17099-81-9 Fe EDTA Carc. 1A, H350 Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335

≤2.5%

· Additional information: For the wording of the listed hazard phrases refer to section 16.· Other hazards that do not result in classification None

4 First Aid Measures

· Description of first aid measures· General information:

Take affected persons out of danger area and lay down.(Contd. on page 3)

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In case of irregular breathing or respiratory arrest provide artificial respiration.Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48hours after the accident.

· After inhalation:Remove to fresh air.In case of unconsciousness place patient stably in side position for transportation.

· After skin contact:Immediately wash with water and soap and rinse thoroughly. Remove contaminated clothing. Flush affectedareas with plenty of water and soap.

· After eye contact:Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.

· After swallowing: If symptoms persist consult doctor.· Information for doctor:

Check for hyperkalemia and treat ECG changes aggressively (ie Kayexelate)Treat supportive and symptomatically

· Most important symptoms and effects, both acute and delayed No further relevant information available.· Indication of any immediate medical attention and special treatment needed

No further relevant information available.

5 Fire Fighting Measures

· Extinguishing media· Suitable extinguishing agents:

Use fire extinguishing methods suitable to surrounding conditions. Water spray jet, foam. Dry fire-extinguishing substance.

· Special hazards arising from the substance or mixtureIn case of fire, the following can be released:Carbon oxides (COx)Metal oxide fumes

· Advice for firefighters Material not combustable· Protective equipment: Use breathing apparatus with independent air supply (Isolated)

6 Accidental Release Measures

· Personal precautions, protective equipment and emergency proceduresWear protective gear. Do not inhale the material or its combustion products. Go against the wind and keepout of low areas. Evacuate personnel to safe area.

· Environmental precautions:Do not allow product to reach sewage system or any water course.Inform respective authorities in case of seepage into water course or sewage system.Do not allow to enter sewers/ surface or ground water. Should not be released into the environment.

· Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders). Transfer into suitablecontainers. To be disposed of in compliance with existing regulations. After cleaning, flush away traces withwater.Dispose contaminated material as waste according to item 13.Ensure adequate ventilation.

· Reference to other sectionsSee Section 7 for information on safe handling.See Section 8 for information on personal protection equipment.See Section 13 for disposal information.

7 Handling and Storage

· Handling:· Precautions for safe handling

Ensure good ventilation/exhaustion at the workplace.(Contd. on page 4)

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Open and handle receptacle with care.Prevent formation of aerosols.

· Information about fire - and explosion protection: Keep respiratory protective device available.

· Conditions for safe storage, including any incompatibilities· Storage:· Requirements to be met by storerooms and receptacles:

Observe the rules usually applicable when handling chemicals.· Information about storage in one common storage facility:

Do not store together with oxidising and acidic materials.· Further information about storage conditions: Keep container tightly sealed in a dry well-ventilated place.· Specific end use(s) Agricultural

8 Exposure controls and personal protection

· Additional information about design of technical facilities:Ensure eyewash stations and safety showers are close to the workstation location.

· Control parameters· Ingredients with limit values that require monitoring at the workplace:

The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.

· Additional information: The lists valid during the making were used as basis.

· Exposure controls· Personal protective equipment:· General protective and hygienic measures:

Keep away from foodstuffs, beverages and feed.Immediately remove all soiled and contaminated clothingWash hands before breaks and at the end of work.Store protective clothing separately.Avoid contact with the eyes and skin.

· Respiratory protection:In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposureuse self-contained respiratory protective device.

· Protection of hands:

Protective gloves

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation

· Material of glovesThe selection of the suitable gloves does not only depend on the material, but also on further marks of qualityand varies from manufacturer to manufacturer. As the product is a preparation of several substances, theresistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication.

· Penetration time of glove materialThe exact break through time has to be found out by the manufacturer of the protective gloves and has to beobserved.

· Eye protection:

Tightly sealed goggles

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· Body protection: Protective work clothing

9 Physical and Chemical Properties

· Information on basic physical and chemical properties· General Information· Appearance:

Form: LiquidColour: Brown to black

· Odour: Earthy· Odour threshold: Not determined.

· pH-value: Not determined.

· Change in conditionMelting point/freezing point: Undetermined.Initial boiling point and boiling range: 100 °C

· Flash point: Not applicable.

· Flammability (solid, gas): Not applicable.

· Ignition temperature:

Decomposition temperature: Not determined.

· Auto-ignition temperature: Product is not selfigniting.

· Explosive properties: Product does not present an explosion hazard.

· Explosion limits:Lower: Not determined.Upper: Not determined.

· Vapour pressure: Not determined.

· Density at 20 °C: 1.01089 g/cm³· Relative density Not determined.· Vapour density Not determined.· Evaporation rate Not determined.

· Solubility in / Miscibility withwater: Fully miscible.

· Partition coefficient: n-octanol/water: Not determined.

· Viscosity:Dynamic: Not determined.Kinematic: Not determined.

· Solvent content:VOC (EC) 0.00 %

Solids content: 13.5 %· Other information No further relevant information available.

10 Stability and Reactivity

· Reactivity No further relevant information available.· Chemical stability· Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.· Possibility of hazardous reactions

Too dilute to have hazardous reactions, but when dried in a fire may give of irritant fumes and gasses· Conditions to avoid Incompatibles and extreme temperatures

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· Incompatible materials: Strong oxidizing agents· Hazardous decomposition products:

Carbon monoxide and carbon dioxideMetal oxide fumes

11 Toxicological Information

· Information on toxicological effects· Acute toxicity

· LD/LC50 values relevant for classification:

Humic acid

Oral LD50 1,938 mg/kg (rat)ths is an estimated value based on 0.5% KOH in final solution

39208-15-6 Cu EDTA

Oral LD50 30 mg/kg (mouse)

Mn EDTA

Oral LD50 >2,000 mg/kg (rat)

Dermal LD50 >2,000 mg/kg (rat)

Inhalative LC50 4 h >5.16 mg/l (rat)

· Primary irritant effect:· Skin corrosion/irritation Irritant to skin and mucous membranes.· Serious eye damage/irritation Irritating effect.· Respiratory or skin sensitisation No sensitising effects known.· Additional toxicological information:

The product shows the following dangers according to the calculation method of the General EUClassification Guidelines for Preparations as issued in the latest version:IrritantCarcinogenic.

· CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)

Zn EDTA

Carcinogenicity (Not Applicable)Contains Nitrilotriacetic acid as impurity, 1 t0 3%, which is listed by IARC as a possiblecarcinogen

Carc. 1A

12 Ecological Information

· Toxicity

· Aquatic toxicity:

Zn EDTA

LC50 96 hours 685 mg/L (Fish)

39208-15-6 Cu EDTA

EC50 72 h 0.005 mg/l (Algae)

EC50 96 hr 0.033 mg/L (Algae)

LC50 96 hours 0.286 mg/L (Oncorhynchus mykiss (rainbow trout))

Mn EDTA

EC50 72 h 649.3 mg/l (Algae)

17099-81-9 Fe EDTA

LC50 96 hours 12,750 mg/L (Fish)

4,547 mg/L (dap)(Contd. on page 7)

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· Persistence and degradability

Humic acid

Biodegradation (Not Applicable)This substance will only very slowly biodegrade

Zn EDTA

BOD5 0.01 (Not Applicable)

39208-15-6 Cu EDTA

COD 560 (Not Applicable)

Biodegradation (Not Applicable)

Mn EDTA

COD 500 (Not Applicable)

Biodegradation (Not Applicable)

17099-81-9 Fe EDTA

COD 570 (Not Applicable)

Biodegradation (Not Applicable)

· Behaviour in environmental systems:

· Bioaccumulative potential

Humic acid

Bioaccumulate (Not Applicable)This substance is unlikely to bioaccumulate in animals

· Mobility in soil

Humic acid

Koc (Not Applicable)This substance's mobility will be diminished by clay and cations in the soil.

· Additional ecological information:· General notes:

Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for waterDo not allow product to reach ground water, water course or sewage system, even in small quantities.Danger to drinking water if even extremely small quantities leak into the ground.

· Results of PBT and vPvB assessment· PBT: Not applicable.· vPvB: Not applicable.· Other adverse effects No further relevant information available.

13 Disposal considerations

· Waste treatment methods· Recommendation

Contain material in dyke and pump into container for reuse.Must not be disposed together with household garbage. Do not allow product to reach sewage system.

· Uncleaned packaging:· Recommendation: Disposal must be made according to official regulations.

14 Transport information

· UN-Number· ADG, ADN, IMDG, IATA Void

· UN proper shipping name· ADG, ADN, IMDG, IATA Void

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· Transport hazard class(es)

· ADG, ADN, IMDG, IATA· Class Void

· Packing group· ADG, IMDG, IATA Void

· Environmental hazards: Not applicable.

· Special precautions for user Not applicable.· ERG No. None

· Transport in bulk according to Annex II of Marpoland the IBC Code Not applicable.

· UN "Model Regulation": Void

15 Regulatory information

· Safety, health and environmental regulations/legislation specific for the substance or mixture

· Australian Inventory of Chemical Substances

17099-81-9 Fe EDTA

· Standard for the Uniform Scheduling of Medicines and Poisons

None of the ingredients is listed.

· GHS label elementsThe product is classified and labelled according to the Globally Harmonised System (GHS).

· Hazard pictograms

GHS07 GHS08

· Signal word Danger

· Hazard-determining components of labelling:Humic acidZn EDTABoron 20.5Cu EDTA

· Hazard statementsHarmful if swallowed.Causes skin irritation.Causes serious eye irritation.May cause cancer.

· Precautionary statementsIf medical advice is needed, have product container or label at hand.Keep out of reach of children.Read label before use.Wear protective gloves/protective clothing/eye protection/face protection.IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.Specific treatment (see on this label).Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations.

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· Directive 2012/18/EU· Named dangerous substances - ANNEX I None of the ingredients is listed.

· National regulations:

· Information about limitation of use:Workers are not allowed to be exposed to the hazardous carcinogenic materials contained in thispreparation. Exceptions can be made by the authorities in certain cases.

· Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

16 Other informationThis information is based on our present knowledge. However, this shall not constitute a guarantee for anyspecific product features and shall not establish a legally valid contractual relationship.

· Relevant phrasesH300 Fatal if swallowed.H302 Harmful if swallowed.H315 Causes skin irritation.H319 Causes serious eye irritation.H332 Harmful if inhaled.H335 May cause respiratory irritation.H350 May cause cancer.H351 Suspected of causing cancer.H361 Suspected of damaging fertility or the unborn child.

· Abbreviations and acronyms:ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the InternationalCarriage of Dangerous Goods by Road)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationEINECS: European Inventory of Existing Commercial Chemical SubstancesELINCS: European List of Notified Chemical SubstancesCAS: Chemical Abstracts Service (division of the American Chemical Society)VOC: Volatile Organic Compounds (USA, EU)LC50: Lethal concentration, 50 percentLD50: Lethal dose, 50 percentPBT: Persistent, Bioaccumulative and ToxicvPvB: very Persistent and very BioaccumulativeAcute Tox. 2: Acute toxicity – Category 2Acute Tox. 4: Acute toxicity – Category 4Skin Irrit. 2: Skin corrosion/irritation – Category 2Eye Irrit. 2A: Serious eye damage/eye irritation – Category 2ACarc. 1A: Carcinogenicity – Category 1ACarc. 1A: Carcinogenicity – Category 1ACarc. 2: Carcinogenicity – Category 2Repr. 2: Reproductive toxicity – Category 2STOT SE 3: Specific target organ toxicity (single exposure) – Category 3

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