PELA INC - TECHNICAL MEMORANDUM NO. 3 FOR REMEDIAL ...Min RRF for SPCCMM - 0.300 CO. 250 for...

PELA

TECHNICAL MEMORANDUM NO. 3

FOR REMEDIAL INVESTIGATION/FEASIBILITY STUDY

CITY DISPOSAL CORPORATION LANDFILL

(DUNN LANDFILL)

(PELA Reference No, 495201)

Appendix B.

Results of Analyses off Soil Samples and

Ground-Water Samples - Technical Report A

Volume I of III, Part 2 of 2

CA1365-CA1378

CA1382, CA2013

February, 1990

P. E. I.aMoraies feAtaoditM, Inc. —

ETC

STANDARDS DATA

215

6AUOLATILE ORGANICS INITIAL CALIBRATION DATA

Lab Name:ETC Corp, ' I Labei u l u i j Contract:

Lab Code: Case No.: SAS No.: SDG No.:

Instrument ID:GC/MS C Calibration Date(s) 09/20/89 09/20/89

Mat r ix: Csoi I/water ) LOATER Le^e 1 : C low/med ) LOW Co lumn : (pack/cap ) PACK

Min RRF for SPCCMM - 0.300 CO. 250 for Bromoform) Max SRSO for CCCC*) - 30. OS

I LAB FILE 10: RRF2Q ->C7185 RRF50 ->C7186 IIRRF100->C7187 RRF150->C7188 RRF200->C7189 1

1 II COMPOUND 1

ICh lorn me thane 41 Bromomethane 1lUinul Chloride *1 Ch 1 oroethane II M e t h u l e n e C h l o r i d e 11 Acetone 1ICarbon Disulfide 111,1-Dichloroethene *11,1-Dichloroethane #11,2-Dichlorethene t t o t a l ) _ 1(Chloroform *1 1 r2-Dich loroethane 112-Butanone 111,1,1-Trichloroethane 1ICarbon Tet r a chloride 1l U i n u l Acetate 11 Bromod i ch lorome thane 111,2-Dichloropropane *1 c is-1 , 3-D ich loropropene ___ 1ITrichloroethene 1IDibromochloromethane 111,1,2-Trichloroethane 1IBenzene 1ltrans-l,3-Dich loropropene __ 1IBramoform A!4-Methvl-2-Pentanone 11 2-Hexanone 1iTetrachloroethene 111 ,1 ,2 ,2-Tetrach loroethane _ $IToluene *IChlorobenzene *1 Et hulbenzene *IStvrene 1IXulene t total ) 1.1 To Iuene-d8 1ISromofluorobenrene , 1ll,2-Dichloroethane-d4 1I ~\ * X»ry. VVVA Ai fAliuCtiM'v . 1

13RF2Q 1

.4501

.2911

.3841

.72911.89311.408 14.32511.15912.560 11.34212.91411.9641. 039 1.4791.4651.6581.539 1.4171.5421.4141.481 I.3031

1.0081.4251.3811.4571.3791.5551.5371.9171

1. 1781.5541

1.2521.6981

1.6741.9721

1.8481.31* 1

1RRF50 1

.3871• '.Tjffifr |.332 1.6711

1.6991.7731

4. 13311. 189 12.73111.41013.10612.2361.0311.5071.5101.6971.6021.4531.603 1.459 1.540 1.3261

1. 043 1.481 1.463 1.5821.4221.5711.619 1.9791

1.2611.6071

1.3701.7671

1.6951.9951

1.9531-q«^'

&5-io 19.8*7.11

14.4136.917.718.0*5.4*5.815.4*4.81

14.914.6 16.41

23.414.414.6*4.3 18. 017.719.21

10.9!6.417.3ft9.018.71

11.516.1*6.2*5.6*5.2*4.35.7

1.82.07.5 .

\\.*T l̂ H*FORM YI UOA 1/87 Rev

216

TQTQL I OH CHROMPTOCROMFile >C718S 35.0-268.0 tmu.

280

160000

TIC488

QV70067VS.QV70067,L,

1000

• 4

Data File: >C7185::U2Name :Misc: QU70067US,QU70Q67,L,5 2UL

Id File: IC1042::UST i t l e : PP/UOA, IFB,Last Calibration: 890912 12:35

Operator ID: CA3875Quant Time: 890920 14:07Injected at: 890920 12:56

Quant Output File: 'SC7X85::AQ

217

QUANT REPORT

Operator IDOutput FileData File:Name:

CA3875~C7185::AQ>C7185::U2

Quant Rev: 7 Quant TimeInjected at

Di lut ion Factor

Page 1

890920 14:07890920 12:56

1.00000Name:Misc: QU70067US,Q'J7Q067,I_,5 2UL

ID File: IC1042::USTitle: PP/UOA, IFB,Last Calibration: 890912 12:35

Compound R.T. Scan* Area Cone Uni ts

1)2)2)3)4)5)6)7)8)9)10)11)12)13)14)15)15)16)17)18 'J19)20)21)22)2?)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40 >

"Bromoch lorome thaneMethyl chlorideMethyl chlorideMethyl bromideD i ch lorod ifluoro me thaneUiny 1 chlorideCh loroe thaneMethylene chlorideAero le inAcet oneAcrylon i t r i leCarbon d isu 1 f ideTr ichlorof luoro me thane1,1-Dichloroethylene1 ,1-DichloroethaneTetrahydrofuranTet rahydrofuran1,2-Trans-dich loroe thyl oneCh I oro forml,2-Dichloroethan«-D4 (SURR)1,2-Dich loroe thane

*l,4-DifluorobenzeneMethyl ethyl ketone1 ,1,1-Tr ichloroethaneCarbon tetrachlorideCarbon tetrachlorideU iny 1 acetateDicnlorobromomethane1 ,2-Dich loropropanec is-l,3-DichloropropyleneTr ichloroethyleneCh lorod ibromome thaneb is (Ch loro methyl >e therBenzene1 ,1 ,2-Tr ichloroethanetrans-l,3-Dichloropropylene2-Chloroethylvinyl etherBromo form

*Ch Iorobenzene-d5Methyl-iso-butyl ketone2-Hexanone1,1,2,2-TetrachloroethaneTetrach loroe thy lene

13.2.3 .4.5.6.7.9.10.10.11.11.12.12.14.14.14.14.15.15.16.23.15.17.17.17.17.18.19.19.20,20.20.21.21.21.22.23.28.24.25.25.25.

08381985860152916157346108730101717821900248943737808815658539939701091221606318728896

311475598124128167229247246266273285302335335353355366384387580385422422433435442481486500514515516518519547583713598638642644

8500915293167979892994113067248036476655869478801979014708271119394098703813532490045636990981570966678238987060077463611106725211026308403665097845436456375047198411571894718866321331405948627732150675420335953761568

250323511971757512114583181421159611289

60252181988215963250136841282115829789100967410297809198250829498114

.00

.26

.43

.67

.41

.62

.85

.35

.04

.82

.50

.95

.07

.21

.00

.06

.70

.37

.41

.36

.16

.00

.37

.13

.56

.00

.62

.59

.24

.58

.19

.03

.71

.55

.86

.09

.15

.50

.00

.62

.95

.55

.20

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG218NG

989998999897949999969699959798100100949779989899979296939998969096100968598100997992889698

QUANT REPORT

Operator ID: CA3875Output File: ~C7185::AQData File: >C7185:: U2Name:Misc: QU70Q67iJS,QU70067,L,5


Oi lut ion Factor

Page 2

890920 14:ff7890920 12:56

1. 00000

!UL


Compound R.T. Scan* Area Cone Units

41)42)43)44)45)46)47)48)

Toluene-D8 CSURR)To lueneCh 1 orobenzeneEthy Ibenzenep-Bromof luorobenzene CSURR)Styrenam-Xy 1 eneo+p-Xy lenes

27.27.28.31.35.37.38.39.

2443755721601562

677682716789883945959997

4643511017221306776141326967013888180397154956

24494999623596100200

.12

.74

.90

.48

.00

.73

.75

.57

NGNGNGNGNGNGNGNG

9296988166989991

Compound is ISTD

219

TOTAL ION CHROMflTOCRfiMFile >C7186 35.6-260.0 amu.

... 200.....TIC

QV70067VS,QV70e&7,L

.W.......W-......AW ....

44

Data File: >C7186::U2Name:Misc: QU70Q67iJS,QU70067,L,5 5UL

Id File: IC1042::USTitle: PP/UOA, IFB,Last Calibration: 890912 12:?5


Quant Output File: ^C7186::AQ

220.

Operator ID: CA3875Output File: ~C7186::ftQData File: >C7186::U2Name:Miac: QU7Q067US,QU7QQ67,L,5

QUANT REPORT

Quant Rev: 7 Quant TimeIn jected at

D i lut ion Fac tor

Page 1

890920 14:3-8890920 13:51

1.00000

5UL

ID File: IC1042::USTitle: PP/UOA, IF8,Last Calibration: 890912 12:35

Compound R.T. Scan* Area Cone Un i ts

1)2)2)3)4)5)617)8)9)10)11)12)13)14)15)15 )16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)

*Bromoch loro me thaneMethyl chlorideMethy 1 chlorideMethyl brom i deDich lorodi fluoro me thaneUiny 1 chlorideCh 1 oroe thaneMethylene chlorideAero le i nAcetoneAery 1 on i t r i leCarbon disulfideTrich lorof luoro me thane1,1-Dichloroethylene1 ,1-Dich loroethaneTet rahydrof uranTet rahydrofuran1,2-Trana-dichloroethyleneCh loro f o rml,2-Dichloroethane-D4 (SURR)1 ,2-Dich loroethane

*1 ,4-Dif luorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon tetrachlorideCarbon tetrachlorideUinyl acetateDich lorobromomethane1 ,2-Dich loropropanecis-l,3-DichloropropyleneTr ich loroethyleneChlorodibromomethanebisCChloromethyl JetherBenzene1 ,1 ,2-Tr ichloroethanetrans-l,3-Dichloropropylene2-Chloi:oethylvinyl etherBromo form*Chlorobenzene-d5Methyl-iso-butyl ketone2-Hexanone1,1, 2 , 2- Tetrach loroethaneTet rachloroethylena

13.2.3.4.5.5.7,9.10.10.11.11.12.12.14.14.14.14.15.15.16.23.15.17.17.17.17.18.19.19.20.20.21.21.21.21.22.23.28.24,25.25.26.

1287,1888859751956460306111770404707820900252984141 •798718658442930004081220596321728700

311465498123126166229247246264272285302335335352354365383386580385422422432434442480485500513515516517518546582712598637641644

708622743736123631179532355247548120367140450548045226829287211685284225193542322634659999092201071383881584673209419889

16258023594163764223629193181145262193569147284173320455563346491046291544787495514861922826413275596276141310130391

250.69.91.91.68.163.174.272.4397.437.451.276.189.287.237.

17232.2488.258.219.168.179.250.272.222.32.224.306.230.263.249.277.269.208.265.263.226.250.298.250.262.264.284.293.

004240595350432416785097377042795335594080'00716241950462591665403721576243940095221782

NGNGNG,NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

9798989491969799929896989298981001009?Q-1

80O'i9$oo*M

OQQCL

orQO

*"'-1o •*Op

1 0 r,* ?86Q"11

1009*819?Q29797

221

QUANT REPORT

Operator ID: CA3875 QuantOutput File: AC7186::AQData File: >C7186::U2Name :Misc: QU70067US,QiJ70067,L ;5 5UL

ID File: IC1042: :USTitl«: PPxuOA, IFB,Last Calibration: 890912 12:35

7 Quant TimeIn jec ted at

Di lut ion Factor

Page 2

890920 14:3-8890920 13:51

1.00000

Compound

Toluene-08 C SURR )To luenaCh 1 orobenzeneEthy Ibenzenep-Bromofluorobenzene (SURR)Styrenem-Xy leneo + p-Xy lenes

R.

27.27.28.31.35.37.38.39.

T.

2447795724601465

Scantf

676682716788883944958997

Area

386925223574287758138517227117312691182598350371

Cone

247.252.267.264.240.264.277.550.

1397253945599998

Uni ts

NGNGNGNGNGNGNGNG

q9296998062979890

41)42)43)44)45)46)47)48)

* Compound is ISTD

Ill

026068 :026068

ST6068 :

PI

I . L . I . I _ I . I _ . 1 . 1 . 1 . 1 . I . I . 1 . 1 . 1 . 1 . 1 . 1 . . I

000T 006Oil 0-092-8*S£

NOI

QUANT REPORT Page

Operator ID: CA3875Output File: ^C7187::AQData File: >C7187:: U2Name:Misc: Q"J70Q67US,QY70067,L,5


Di lut ion Factor

890920 15:3?890920 14:47

1. 00000

1 QU-


Compound R.T. Scanft Area Cone Units

1)2)2)3)3)4)5)5)6)7 )8)9)10)11)12)13)14)15)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)22)33)34)35)36)37)38)

*Bromoch loro me thaneMethyl chlorideMethyl chlorideMethyl bromideMethyl bromideDichlorodif luoro me thaneU i ny 1 chloride"Jiny 1 ch lor ideCh loroethaneMethylene chlorideAc r o' 1 e inAcetoneAery Ion i t r i leCarbon disulfideTr ichlorof luoro me thane1 ,1-0 ich loroethylene1 ,1-Dich loroethaneTet rahydrofuranTet rahydrofuran1 ,2-Trans-d ich loroethyleneCh 1 ore forml,2-Dichloroethane-D4 CSURR)1,2-D ich loroethane

*1 ,4-Di f luorobenzeneMethyl ethyl ketone1 ,1 ,1-Tr ich loroethaneCarbon tet rach lor ideCarbon tetrachloride"Jinyl acetateDichlorobromomethane1 ,2-Dich loropropanecis-1, 3-D ich loropropyleneTrich loroethyleneChlorodibromo me thaneb is (Ch loro methyl )etherBenzene1 ,1 ,2-Trichloroethanetrans-1 , 3-D ich loropropylene2-Chloroethylvinyl etherBromoform

*Ch Iorobenzene-d5Methyl- iso-butyl ketone2-Hexanone

13.2.3.4.5.5.6.6.7.9.10.10.11.11.12.12.14.14.14.14.15.15.16.23.15.17.17.17.17.18.19.19.20.20.20.21.21.21.22.23.28.24.25.

12962793319305945695656130611277010571792591024898414180921966854393970109132160601869

311485699109125129151167229247246264272285302334335352354366383386579385422422432435442480485500513514515517518546582711597636

741875881772187716411637352394705239189555221643527740510371094568559523230225155826367968558265109

18944941855415158930497032806719060

2967944294829134149211136280327067636352125704830625182219589824189056295701155172274528234258246545169342

25014217499161290312253344678295791780505356508431

28482260646739817633025051439757

- 391658423480457474465367457465410507540250475452

.00

.15

.46

.31

.32

.05

.01

.98

.83

.58

.64

.31

.29

.43

.37

.42

.16

.16

.59

.94

.86

.20,52,00,21.56.71.50.84.71.49.75.04.69.89.28.91.03.19.21.00.84.84

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

97979997879795949498939996989798961001009597849999999695979196999?959710096859510098819496

224

Operator ID: CA3875Output File: ^C7187::AQData File: >C7187::U2Name:Mi so: QU70067'JS>Q'J70067,L,5

QUANT REPORT


Di lut ion Factor

Page 2

890920 15:3-3890920 14:47

1.00000

10UL



39)40)41)42)43)44)45 )46)47)48)

1,1,2,2-TetrachloroethaneTetrachloroethyleneToluene-08 (SURR)To 1 ueneCh 1 orobenzeneEthy Ibenzenep-Bromofluorobenzene CSURR)Styrenem-Xy 1 eneo +p-Xy lenes

25.25.27.27.28.31.35.37.38.39.

84962044755725611570

640643675681715738883944958998

291248232977405409403961530968257692234904581954336238642406

570.511.252.450.480.479.242.479.498.934.

71563189512733828038

NGNGNGNGNGNGNGNGNGNG

95978896998262979791

* Compound is ISTD

225

TOTQL ION CHROMflTOGRRMFile >C7188 35.0-260.8 »mu . QV70067VS,QV70067 ,L ,

TIC. 200 ,

400080-

368808-

320000-

288000-

240000^

280000^-

160009;

120000^•

80000-

40000-

8_

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I1j

7!l1

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480

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1

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.iiii

r

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600 888 1808. . . i . . . . i . . . . . . . . . . . . i . . . . . . . . i .

31;

;24

2

I1E

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3

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.

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44 « 48

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20 ' 24 ' 28 ' 32 ' 36 ' 40 ' 44

Data File: >C7188::U2Name:Misc: QV70067US,QU7Q067,L,5 15UL

Id File: IC1042::USTitle: PP/UOA, IFB,Last Calibration: 890912 12:35



226

Operator ID: CA3875Output File: ~C7188::AQData File: >C7188::U2Name :Misc: QU70067US,QV70Q67,L,5

QUANT REPORT


Di lut ion Factor

Page 1

890920 16:28890920 15:42

1.00000

15UL

ID File: IC1042::USTitle: PP/"JOA, IFB,Last Calibration: 890912 12:35


1)2)2)3)3)4)5)5)6)7)8)9)10)11)12)13)14)15)1?)15)16.i17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)

*Bromoch lore me thaneMethyl chlorideMethyl chlorideMe thy 1 bromideMethy 1 bromi deDi ch 1 o rod i f luoro me thaneU i ny 1 chlorideUiny 1 ch lor ideCh 1 o roethaneMe thy 1 ene chlorideAc ro le inAcetoneAc ry 1 on i t r i leCarbon d i a u l f i d eTr ich lorof luoro me thane1 ,1-Dich loroethylene1 ,1-Dich loroethaneTetrahydrofuranTet rahydrofuranTetrahydrofuran1 ,2-Trans-dichloroethyleneCh loro form1 ,2-Dichloroethane-D4 (SURR)1 ,2-Dich loroethane

* 1 ,4-Di f luorobenzeneMethyl ethyl ketone1,1,1-Trich loroethaneCarbon tetrachlorideCarbon tetrachloride"Jinyl acetateDichlorobromo me thane1,2-Dich loropropanecis-l,3-DichloropropyleneTrichloroethyleneChlorodibromomethaneb is CCh loro methyl )etherBenzene1 ,1 ,2-Tr ich loroethanetrans-l,3-Dichloropropylene2-Chloroethylvinyl etherBromo form

*Ch Iorobenzene-d5Methyl-iso-butyl ketone

13.2.3.4.5.5.6.7.7.10.10.10.11.11.12.12.14.14.14.15.14.15.15.16.23.16.17.17.17.17.18.19.19.20.20.20.21.21.21.22.23.28.24.

18942591619207005801717136712183071177278127970451004343829017688741959907111523626324

313485699117125129153168231249249266275288304336337354367355367385387580386423423433435442481486500514515517518519547583712599

760849055910946517157614552514720595598

1442013155824306841515141375958435583321682321105531217758079923853

2837286223871615764703073290332637444914865384431950369042551461398695541846377061439877120038828933259854405694218278393819236895348561

250.213.257.231.83.

421.465.36.492.664.

12558.1127.1107.743.501.738.631.

38594.3975.1916.683.578.183.496.250.709.599.87.578.492.642.705.680.693.666.535.640.638.580.711.772.250.665.

00419691064792207077242400013544950382773332139900448860746215663033925477515336670024

NGNGNGNGNGNGNGNGNGNGNGNG .NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGA. _̂

9799999296979980979897989099959798100100100939889999898969495959694959399100908494100968190

227

QUANT REPORT

Operator ID: CA3875Output File: ^C7188::AQData File: >C7188::U2Name :Misc: QU7D067US,Q«J7Q067,L,5

Quant 7 Quant TimeIn jec ted at

Dilution Factor

Page 2

890920 16:2S890920 15:42

1.00000

15UL

ID File: IC1042::USTitle: PP/YOA, IFB,Last Calibration! 890912 12:35

Compound R.T. Scan# Area Cone Units

38)39)40)41)42543)44)45)46)47)48)

2-Hexanone1,1,2,2-TetrachloroethaneTetrachlorocthyleneToluene-08 CSURR)To lueneCh lorobenzeneEthyl benzenep-Bromof luorobenzene (SURR)Styrenem-Xy leneo +p-'Xy 1 enes

25.25.25.27.27.28.31.35.37.38.39.

7586982747786032681869

638641644677682716789885946959998

238462407140323412410614602034779943378919237909862539496985946585

630.788.702.252.656.697.696.242.703.729.

1434.

5892237137978970250634

NGNGNGNGNGNGNGNGNGNGNG

9495979195997964979690

* Compound is ISTD

228

TOT PL ION CHROMOTOGRflMFile >C7189 35.8-260.0 MU . ,. QV70a67VS ,QV7a067 ,L ,

TIC

488009-

440000-

400000-

360000-

32008^

28000&J

240000:

20000^

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80000-

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MLJU11IL_, , , , T_F.,, , _^,_,,,, . , , ,,., , ,,..T-, r , , , ,..,, , . ,_.16 20 24 28 32 36 40 44

Data File: >C7189::U2Name:Miac: QU70067US,QV70067,L,5 20UL

Id File: IC1042::USTit l e : PPxUQA, 1FB,Last Calibration: 890912 12:35



229

QUANT REPORT Page 1

Operator ID: CA3875 Quant Rev:Output File: /SC7189::AQData File: >C7189::U2Name:Misc: QU70Q67US,QU7Q067,L,5 20UL


7 Quant TimeIn jected at

D i lut ion Factor

890920 17:24890920 16:38

1.00000

Compound R.T. Scant Area Cone Units

1)2)2)3)4)5)5)6)7)8)9)10)11)12)13)14)15)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)3D32)33)34)35)36)37)38)39)

*Bromochloro me thaneMethyl ch lor i deMethyl chlorideMethyl bromideDichlorodifluoro me thaneUiny 1 ch lor ideUiny 1 chlorideCh loroe thaneMe thy lene ch lor ideAero le inAcetoneAery Ion i t r i leCarbon disulfideTr ich lorof luoro me thane1,1-Dichloroethylene1 ,1-0 ich loroethaneTetrahydrofuranTetrahydrofuran1 ,2-Trans-d ich loroethy leneCh 1 oro forml,2-Dichloroethane-D4 CSURR)1,2-Dich loroethane

*l,4-DifluorobenzeneMethyl ethyl ketone1 ,1 ,1-Tr ichloroethaneCarbon tetrachlorideCarbon tetrachlorideUinyl acetateDlchlorobromome thane1 ,2-Dich loropropanecis-l,3-Dich loropropy leneTr ich loroe thy leneChlorodibromomethaneb is CChloro methyl )etherBenzene1,1,2-Trichloroethanetrans-l,3-Dich loropropy lene2-Chloroethylvinyl etherBromo form

*Chlorobenzene-d5Methyl-iso-butyl ketone2-Hexanone1,1,2,2-Tetrachloroethane

13.2.3.4.5.6.6.7.9.

10.10.11.11.12.12.14.14.15.14.15.15.16.23.15.17.17.17.17.18.19.19.20.20.20.21.21.21.22.23.28.24.25.25.

17972890900695579666703562168206102679269507499942428193206786449498061014225758197085

313495799125129152168230248249266273287304.336337367355367385388580386423423433436443481486501514515517518519547582711598637641

68906944931265762106625961827257649

1676053805375346551960191758341002194404834274970658522989572908

3391877552621546705871942905683341054599377528519266766259673451477203647653445236531239145067950399307146487681270034492572208440432113297336505236

25024532931423059054632885

1721316101562974674965830

543561597902774193685250

1017825117787

11583889569209279127328318547909961094250937893

1112

.00

.88

.36

.40

.06

.60

.61

.32

.10

.93

.26

.01

.69

.68

.92

.74,79.36.00.89.56.15.00.67.76.63.83.26.02.43.78.06.06.88.92.62.23.53.35.00.29.60.652

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG -NGNG30

9798969896979094999597879996979810010094979?9799989696989296989494981008882941009879949393

QUANT REPORT

Operator ID: CA3875Output File: ~C7189::AQData File: >C7189::U2Name :Misc: Q"J70067"JS,QiJ70067,l_,5


Di lut ion Factor

Page 2

890920 17:24.890920 16:38

l.OOQOO

20UL

ID Filo: IC1042::USTitle: PP/UOA, IFB,Last Calibration: 890912 12:35


40)41)42)43)44)45)46)47)48)

Tet rachloroethyleneToluene-08 CSURR)To lueneCh lorobenzeneEthy Ibenzenep-Bromof luorobenzene CSURR)Styrenem-Xy leneo+p-Xy lenes

25.27.27.28.31.35.37.38.39.

972342745627631768

644676681715788884945959998

36810936426070947092993745193421416910405565964391133746

908.254.879.945.944.248.964.994.1952.

397809806431214046

NGNGNGNGNGNGNGNGNG

978995988064959691

Compound is ISTD

231

7AVOLATILE CONTINUING CALIBRATION CHECK

tf»7- /0/7-X̂Lab Name:ETC Corp., I Lubu^atar/ ' Contract:

Lab Code: Case No.: 5A5 No.: SDG No.:

Instrument ID:GC/MS C Calibration Date: 09/21/89 Time: 1904

Lab File ID: >C7200 Init Calib. Dates(a): 09/20/89 09/20/89

Matrix:(soiI/water) WATER Leve1:(lou/med) LOW Column:(pack/cap) PACK

Min RRF50 for SPCC(*) - 0.300 CO.250 for Bromoform) Max KRSD for CCCC«) -

11 COMPOUND

IChlaramethana _m _._IBrama methanelOinyl ChlorideIChloroethaneIMathylane Chloride1 Aeatana1 Carbon Diaulfida1 1 ,1-Oiehlaraathene1 1 ,1-Dichlorae thane1 1 ,2-Dich lore thane (totaltChlorafarm..,1 1 ,2-Qiehlaraathana12-Butanane1 1 rl P 1-Tr ichloroathane „1 Carbon Tat rachlor ide ._,.,lUinyl AcetateIBromadichl aroma thane1 1 ,2-DichlaroprapaneIc is-1 ,3-Dich loropropene_ITr ich loroethena __iDibromochlerome thane1 1,1 jS-Tr^chloroethane

ItralKkj^OUhloropropan1 RMMB̂ BBHB̂ ».I£#;l4~MbBlCjjdiM£fe»*ntananei o-.tmisBauimi,;' "•"-'• •1 TeMsEkloroathena nm

\\

*1•1111»*

) _ I*1t1111*

111

*11

1 l,l,2/2-T»tpachloroathana___*1 Ta luana , mi_ , , „ *iChlarahanzanalEthylhanzana.,. ,-(StyranaIXylana (total) mi

IToluana-dSIflromrtf luarohanzana _ , iin1 1 ,2-Dich Ioroethane-d41

*«11

1t11

__ 1 1RRF IRRF50 1

.3951

.1561

.3301

.65711.5631.8511

3.91211.08212.51711.30012.86212.0891.0311.4721.4611.6281.5661.4191.5611.4061.4781.2891.9211.4351

.5151

.3711

.5041

.5911

.89311.1571.5571

1.2651.6991

1.71611.00012.0431

1

.4901

.6781

.3251

.68711^5141.4061

3 . 643 11 . 073 12 . 744 11.38912.92712.9671.0301.6081.5931.6341.6961.4001.6141.4151.5581.3391.9821.5311.3911.4981.3831.4461.5161.9591

1.2501.6121

1.4241.7781

1.6951.9621

2.61311

SO 1

24.1*333.51

4.613.11

52.316.91.9*9.0*6.812.3«

42.011.91

28.6128.711.01

22.914.6*9.412.31

16.7117.216.61

22.216.3*3.313.31

11.4112.7*7.3»8.1*9.9»

12.5111.21

1.313.81

27.91

Te+^k/Jt-of-fAM -3?^ .JV7 19.0

">/f*4*i

232

MM- •««

TOTAL ION CHROMBTOCRftMdC70067VS,BV7ae«7,

1000 .

Fill >C7200 35.8-268.8 Wu. 2/Z1 89 C

48 44

Quant Output Fil«: AC7200::AQData File: >C7200::U1Name: 9/21 89 CMisc: QC70067US,QV70067,L:n4,5,, 5UL CAL I*II+XUOA

Id File: IC1042::USTit lei PP/UOA, IFB,Last Calibration: 890920 20:93

Operator ID: PT1575Quant Time: 690921 19:90Injected at: 690921 19:04

233

QUANT REPORT Page

Operator ID: PT1575Output File: ^C72QO::AQData Fi1«: >C7200::U1Name: 9/21 89 CMiac: QC70067v-S,QU70Q67,L!M4J5,,

ID File: IC1042::USTitle: PP/UOA, IFB,Lest Calibration: 890920 20:93

Compound

Quent 7 Quant TimeInjected et

Di lut ion Factor

890921 19:50890921 19:04

1.00000

5UL CAL 1*1 I+XUOA

R.T. Scan* Area Cone Units

1)2)2)3)4)4)5)6)7)8)9)10)11)12)13)14)15)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)

*Bromoch lorome thaneMethyl ch lor ideMethyl chlorideMethyl bromideD ich lo rod if luorome thaneDichlorodif luorome thaneUinyl chlorideChloroethanaMe thy lene ch lor ideAero la inAcetoneAery Ion i t r i leCarbon disulf ideTr ich lorof luorome thane1,1-Dichlo roe thy lene1 ,1-Dicn loroe thaneTet ra hydro furanTat rahydro furan1 ,2-Trana-dichloroethyleneCh lorof orml,2-Dichloroethane-D4 CSURR)1 ,2-Dich loroe thane

*1 ,4-Dif luorobanzeneMethyl ethyl katona1 ,1 ,1-Tr ich loroe thaneCarbon tat rachlor idaCarbon tat raohlor id* .,Uinyl acetat«jl ...'. ...>.Dich lo rob ro«$e*e than*1 ,2-Dich lor̂ lfrdfeBfuic is-1 ,3-Oic^9it^DpropylaneTr ich loroatliyfvM 'VCh 1 o rod ibromo me thanebiaCCh lorome thy 1 )etherBenzene1,1,2-Tr ich loroe thanet rans-1 , 3-D ich loropropylana2-Ch loroethy 1 vinyl etherBromof orm

*Ch Iorobenzene-d5Methyl- iso-butyl ketone2-Hexanona1,1,2,2-Tet rach loroe thane

13.192.993.264.966.006.896.127.6710.0610.7210.6811.4211.7212.1912.8814.1214.1214.7814.8615.3216.0216.0923.6016.0617.4917.4917.8717.9518.2219.7319.9220.5021.0121.0421.1221.1621.2022.3223.6728.7324.2925.8029.96

3134956

100127150130170232249248267275287305337337354356368386388582387424424434436443482487502515516518519520549584713600639643

8930743716455766053631644409128982M61345135224117500362675055032531923005095824245016310098017

124078261372M23338626497842224012739256610311502502932676662938971689422592081753482356677534641475414296822413285373165118307014152786117575158487

250.00 NG310.14 NG323.33 NG1083.76 NG360.17 NG46.56 NG245.91 NG261.44 NG242.23 NG .2822.99 NG119.29 NG r354.02 NG *232.77 NG^*391.90 NG247.81 NG272.53 NG225.07 NG58.19 NG267.08 NG255.68 NG319.86 NG355.03 NG250.00 NG245.13 NG321.58 NG40.03 NG321.64 NG252.51 NG307.24 NG238.49 NG273.53 NG255.75 NG291.82 NG348.03 NG266.51 NG293.05 NG305.40 NG222.48 NG234.37 NG250.00 NG241.73 NGJ>7;258.16 Nff̂218.27 NG

979898989697959896959985989393971001009798939798999699989994969495971009088931009780

1 929497

QUANT REPORT

Operator ID: PT1575Output File: "C7200HAQData Tile: >C7200::U1Name: 9x21 89 Criisc: QC7Q067US,QU7Q067,L:M4,5,,

ID File: IC1042:: USTit la: PP/UOA, IFB,Last Calibration: 890920 20:53

Quant 7 Quant TimeInjected at

Di lut ion Factor

Page 2

890921 19:50890921 19:04

1.00000

5UL CAL I + U*XUOA


Tet rach loroethy leneToluene-08 CSURR)TolueneCh lorobenzeneEthylbenzenep-BromoF luorobenzene (SURR)Styrenem-Xyleneo*p-Xy lenes

26.1027.3327.5728.9231.7435.4237.7838.2839.91

645677683718791886947960

1002

13704952026929434738388918799B295427437151244371477703

221.42 NG246.86 NG268.26 NG270.19 NG274.77 NG240.47 NG281.37 NG272.06 NG556.12 NG -

979295998075979591

40)41)42)43)44)45)46)47)48)

* Compound is ISTD

235

VOLATILE7A

CONTINUING CALIBRATION CHECK

Lab NameiETC Corp. 1 Leaei-etei' iy Con t rac t :

TOTRL ION CHRQHRTOCRPNQC7BB67V5,aV70B67

leaaFile >cr219 35.8-268.8 wu. ?'Z7 89 C

4 * 12 14 20 24 28 32 34 40 44

Quant Output Fila: AC7219i:AQData Fila: >C7219i:UlNama: 9x27 89 CMisc: QC70Q67VS,QU70067,LiM4,5,, fUL CAL I+ll XVOA

Id File: ICX042::USTit la: PP/UOA, IFB,Last Calibration: 890921 21:12

•

Operator ID: GM6356Quant Time: 690927 11:01Injected at: 890927 10:19

237

Operator ID:Output File:Data File:

GM6356-"C7219: : AQ>C7219:iUl

QUANT REPORT

Quant Rev: 7

w i a r i * w . ' w f- * r » - •«•*

Name: 9/27 89 CMisc: QC700670S,0070067,L:M4,5,, 5UL CAL I*


Compound

Quant TimeInjected at

Di lution Factor

I I XOOA

Page 1

890927 11:01890927 10:15

1.00000


1)2)2)3)3)4)5)5)6)7)8)9>10)11)12)13)14)15)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)

•Bromochloro me thaneMethyl chlorideMethyl chlorideMethyl bromideMethyl bromideD ichlo rod if luorome thaneOinyl chlorideOinyl chlorideCh loroethaneMe thy lene ch lor ideAero 1» inAcetoneAcrylonitri leCarbon disulfideTr ichlorof luorome thane1,1-Dichloroe thy lene1,1-D ichlo roe thaneTet rahydrofuranTet rahydrofuran1 , 2-Trans-dichloroe thy leneCh lorof orml,2-Dichloroethane-D4 (SURR)1 ,2-D ichlo roe thane•1,4-Dif luorobenzeneMethyl ethyl ketone1 ,1 ,1-Tr ichlo roe thaneCarbon tetrechLorideCarbon tet rachletr-ide "'Oinyl •c»t*tejJKf ' .V VD i ch 1 o robrowMHlf hane1 ,2-Oich lororf̂ e/paine)c i a- 1 , 3-D i ch to^epropyleneTr ichlo roe thy leneCh 1 o rod ibromo me thanebisCChloromethyl )etherBenzene1 , 1 ,2-Tr ichlo roe thanet rans-1 ,3-Dich loropropylene2-Chloroethyl vinyl etherBromoform

•Ch Iorobenzene-d5Methyl- iso-buty 1 ketone2-Hexanone

13.2.3.5.5.5.6.6.7.10.10.10.11.11.12.12.14.14.14.14.15.16.16.23.16.17.17.17.17.18.19.19.20.21.21.21.21.21.22.23.28.24.25.

20993400789712976703767646731985131782903302105606494988992773935101051317202964683081

3134958101121126130152170231250250268275287304337338355357368386388581387424424434437444482487502515516518519520548583713600639

10844947919540591769437172017934818M6095771841974881363425131747559385956262087114958279748311067415

14752137580427015928505954286013425

300660384243111852681693339431919322959962179662668758438648333215448624757997529194686391112142573105477

25022525460121312474325930038222913092442342462353718824429623822125020422729241194220220222241220217226210214222229250183176

.00

.67

.58

.17

.64

.28

.33

.30

.03

.67

.19

.31

.91

.25

.54

.98

.06

.73

.61

.77

.01

.31

.48

.00

.92

.83

.85

.76

.82

.95

.91

.05

.71

.20

.78

.60

.12

.79

.14

.27

.00

.13

.05

NGNGNGNGNGNGNGNGNGNGNG ,-'NG . :NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG238NG ̂ w

979899967694966299998998899995989710010097979098989497999897979895949910088889410097849595

QUANT REPORT

Operator ID: 6M6356Output Fila: AC7219UAQData Fila: >C7219itUlName: 9x27 S9 CMisc: QC70067US,0070067,L:M4,5,,

ID Fila: IC1042::USTitle: PP/VOA, IFB,Last Calibration: 890921 21:12

Compound

Quant Rev: 7 Quant TimeInjected at'

Dilut ion Factor!

Page 2

990927 11:01'890927 10:15

1.00000

5UL CAL I*I I XUOA


39)40)41)42)43)44)

i\*ri47)48)

1 ,1 ,2,2-TetrachloroethaneTet rach loroethylenaToluene-08 CSURR)Toluene'Ch lorobenzeneEthy Ibenzenep-Bromof luorobenzena CSURR)Styrenem-Xyleneo+p-Xylones

25.26.27.27.28.31.35.37.38.39.

92053352877037813182

6426456786837187918869499621001

184455191842649743347487459481226345373718507454288158553484

228.274.245.231.234.236.248.227.231.454.

40700867892725804175


999894949582709797

. 91

* Compound is ISTD

239


Lab Name:ETC Corp. '-»—LaUui a t6i y Contract:



Lab File ID: >C7231 Init Calib. Detests): 09/20/89 09/20/89

Matrix:CsoiI/water) WATER Le^e1:(low/med) LQLJ Column:I pack/cap) PACK

Min RRF50 for SPCC (*) - 0,300 CO.250 for BromoforrrO Max SRSD for CCC(») -

11 COMPOUND1 ..........................1 Ch loromet hane1 Bromoma than*lUinul Chloride1 Ch 1 oroet hane1 Me thv lene Chloride1 Acet oneICarbon Disulfide\ 1 .1-Dichloroethene1 1 .1-Dichloroethane11,2-Dichlorethene ( tota 1 )_1 Ch lorof arm1 1 .2-Dichloroethane12-Butanone1 1,1,1-TrichloroethaneICarbon TetrachloridelUin v l AcetateIBromod ichloro me thane! 1 .2-Dichloropropanelcis-1 ,3-Dichloropropene! Tr ich loroetheneIDibromochloromethane1 1 . 1 ,2-Tr ichloroethane1 Benzene

11

*1*

111**

_i*111

1

*1

111

1 trans-l,3-Dich loropropene _IBromoform Hk14- Methyl-2- Pa ntanone1 2-HexanoneITetrach loroethene

111

11,1 , 2, 2-Tetrachl oroet hane _ 41 To 1 uene *1 Ch lorobenzene1 Eth-jlbenzene1 S t v r e n e n nIXvlene (total)(..........»...............1 To 1 uene-dSIBromofluorobenzene1 1 T2-Dichloroethane-d41

#*11

1I11

RRF

•m.330.657

1.563.851

3.9121.0822.5171.3002.8622.089.031.472.461.623.566.419.561.406.473.289.921.435.417.515.371.504.591.893

1.157.557

1.265.699

1RRF50 1...... |

.382 1

.586 11.60411.Q58I3.65511.11412.47711.37013.25712.4881. 040 1.5211.5131.5961.600 1.3501.5601.411 1.5101.3261.926 1.4791.4021.4871.370 1.5151.6501.912 1

1.1811.575 1

1.243 1.7141

1.7161 1.62911.0001 .92412.0431 2.296!

1 1

1SD 1

&&*15.7*10.712.6124.3 16.612 . 9*1.6f5.31

13.8*19. 1123.5110.3111.215.015.9116. 5«

. 111.216.61

12.81.51

10.213.6*5.31.21

2.1110.0*2.1*2.1*3.2*1.712.11

..... |5.117.61

12.411

240Tcf r*ly 4n> 4- .41*

FORM UII UOA 1/87 Rev

TCT3L ION CHROMBTOCRPM".;# >C"31 35.0-263.0 *nu. IFP 'VOfl 9

QUANT REPORT Page

Ouant Rev: 7Operator ID: CA3875Output File: ^C7231::AQData File: >C7231::UOName: IFB/VOA 9/28/89 CMisc: QC70070US,QU7007Q,L:M4,5,, 5UL CAL I+II+XUQA

ID File: IC1043::USTitle: PP/UOA, IFB.Last Calibration: 890927 12:40

Compound R.T. Scan*

Ouant TimeInjected at

Di lut ion Factor

891002 19:23891002 18:37

1.00000

Area Cone Units

1)2)213)4)4)5)5)6)7)8)9)

10 >11)12113)14 )15)15 i16)I"7)18)19 )20)21)22)27)23)2-i25)26)27)28)29)30)31)32)33)34)35)36)37)38)

*Bro mo chlorome thaneMethyl ch lor ideMethyl chlorideMethyl bromideDichlorod if luorome thaneDichlorodif luorome thaneiJi n«j 1. chlorideiJiny 1 chlorideCh loroe thaneMe thy lene ch lor ideAero le inAce t oneAc-ylonitrileCarbon disulfideTrichlorof luorome thane1 ,1-Dichloroethylene1 .1-DichloroethaneTetrahydrofuranTetrahvdrofuran1 ,2-Trans-dichloroethyleneCh 1 orof orm1 f2-Dichloroethane-D4 CSURR)1 .2-Dich loroe thane

*1 ,4-Di f luorobenzeneMethyl ethyl ketone1 ,1 ,1-Tr ichloroethaneCarbon tetrachlorideCarbon tetrachlorideU iny 1 acetateDichlorobromomethane1 .2-Dich loropropanec is-1 ,3-Dich loropropyieneTrichloroethyleneChlorod ibromomethaneb is (Ch loromethyl )etherBenzene1 .1 ,2-Trichloroethanetrans-l,3-Dich loropropyiene2-Chloroethylvinyl etherBromoform•Ch Iorobenzene-d5Methyl-iso-butyl ketone2-Hexanone

13.3.3.5.6.6.6.6.7.10.10.10.11.12.12.13.14.14.15.15.15.16.16.24.16.17.17.18.18.18.20.20.20.21.21.21.21.21-22.24.29.24.26.

47053613176829728331969270004716444409176333450537348426346111358943475458627413477530

3215159105132145135146175239256255275283295313346346363365377395398595396434434445447454493499513527528530531532561597735613653

6655026403299642382910845141332540918638390191067191145007043040377

243263148417741411648212781710950911552167541528041655663175841255916549122186162775189385190458111194177933130463161882467112940141035181520126884912765623320111365186318

250.224.254.548.218.285.297.218.205.220.5474.559.553.256.230.262.240.655.258.251.234.230.236.250.399.235.30.

223.301.243.247.256.255.259.236.259.286.262.301.280.250.334.343.

00477565953330089515111340787075037814749843620077224753797257897821559535386720002313

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG ryNG ^ 'NGNGNGNG

9699969899889798969892999799939797

1QU1009597919899889*98969899919592981008988

dp 96•* *• 10096859997

QUANT REPORT

Ooerator ID: CA3875Output File: ^C7231::AQData File: >C7231::UOName: IFB/UOA 9/28/89 CMisc: QC70070US,QU70070rl_:M4,5,

ID File: IC1Q43::USTitle: PP/OOA. IFB,Last Calibration: 890927 12:40

Compound


Di lut ion Factor

Page 2

891002 19:23891002 18:37

1.00000

5UL CAL I+II+XUOA


39140)41142)4?i44)4S )46)47)48)

1 . 1. 2 ,2-Tet rach lor oe thaneTetrachloroethyleneTo luene-D8 CSURR)To lueneCh lorobenzeneEthyl benzenep-Bromof luorobenzene (SURR)Styrenem-Xy 1 eneo*p-Xy lenes

26.26.27.28.29.32.37.39.40.40.

46579316668300753333

657660695701740822930

100110161016

151681120002379827212751275407134120215458289940168002168252

344.262.245.256.251.248.241.239.244.254.

79271171314573564592


959995969481719?9790

* Comoound is ISTD

243

ON Uco O- Tx CD If. IT. ^ Xf CM O-- SJ K*

i -*OO"iOON ir- ' ~ O C D O > T - < U s f SS3 C-l -O iH * 0 TV CO C-* K> ̂•T *O If . ^ lf> -̂ VT CM CN "^ X|

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QUANT REPORT Page

Operator ID: GH6356 Quant Re^:Output File: "C7240::AQData File: >C724Q::UOName: IFBxUOA 10 /?/89 CMisc: 0070070̂ 3,0̂ 70070,1-̂ 4,5,, 5UL SPIKE

ID File: IC1043::USTitle: PP/YOA, IFB,Last Calibration: 891003 09:47

Compound

7 Quant TimeInjected at

Di lut ion Fac tor

891QQ3 11:28891003 10:42

1.00000


1)2)2)3)4)4)5)5)6)7)8)9)10)11)12)13)14)15)15 )16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)32)34)35)36)37)38)

•BromochloromethaneMethyl chlorideMe thy 1 chlorideMethyl bromideDichlorodif luoro me thaneDichlorodif luoro me thaneUinyl chlorideUinyl chlorideCh loroe thaneflethylene chlorideAero le inAce toneAery Ion i t r i leCarbon d isu 1 f ideTrich lorof luoro me thane1,1-Dich loroethylene1 ,1-DichloroethaneTe t rahydro f uranTet rahydrofuran1 , 2-Trans-d ich loroethyleneCh 1 oro f o rml,2-Dichloroethane-D4 CSURR)1 ,2-Dich loroe thane

* 1 ,4-0 i f luorobenzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon tetrachlorideCarbon tetrachlorideUinyl acetateDich lorobromomethane1 ,2-Dich loropropanec is- 1 , 3-D ich loropropyleneTr ich loroethyleneChlorodibromomethanebisCChloromethyl )etherBenzene1,1,2-Trichloroethanetrans-1 ,3-Dich loropropylene2-Chloroethyluinyl etherBromof orm

*Chlorobenzene-d5Methyl- iso-butyl ketone2-Hexanone

13.2.3.5.6.6.6.6.7.

10.10.10.11.11.12.13.14.14.15.15.15.16.16.24.16.17.17.18.18.18.20.20.20.21.21.21.21.21.22.24.29,24.26.

45993008128927858225949164994515384212156231390035828224325910298737415353606811417328

3215058104131151135150175238256255274283295313345346364365377395397594396434434445447454493498513526527530530532560597734613653

10416344338448942259819109m$10665693591636291370386913655275392840259284121484269844265061089314499634531223776826168949350112492264197345492681702666562985861806662736652069332401217390747115914687722770994653173805366536140867109969

250.236.239.151.215.

" 124.339.67.

283.244.3058.156.349.257.279.261.261.695.286.254.254.248.252.250.160.256.34.265.226.252.261.247.255.238.254.257.228.241.221.219.250.197.202.

003531479634390492906579869404725095010746'54460002841505532240441864558227001804001564

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNĈ /-w* °

9898999695869690979695999298969598

100100•593~*8«97«8Qt

*aQt

8̂**"-eo-•**:o-Q-

10088a?9-4

10099829798

QUANT REPORT

Quant Rev: 7Operator ID: GM6356Output File: ~C724Q::AQData File: >C724Q::UOName: IFB/UOA 10 /3/89 CMiac: QC70070US,QU70070,L:M4,5,, 5UL SPIKE

ID File: IC1043::USTitle: PP/YOA, IFB,Last Calibration: 891003 09:47

Compound

Quant TimeIn jected at

Dilut ion Factor

Page 2

891003 11:28891003 10:42

1.00000

R.T. Scan# Area Cone Units

39)40)41)42)43)44)45)46)47)48)

1,1,2,2-TetrachloroethaneTet rach loroethyleneToluene-DB CSURR)To lueneCh lorobenzencEthy Ibenzenep-Bromof luorobenzene CSURR )Styrenem-Xy leneo +p-Xy lenes

26.4026.5227.9128.1429.6132.7736.9539.6540.1940 .-T9

6566596957017398219299991013WJ4-3

19030618973161481933961343777021581734000648530628492430*924

199.56 NG251.48 NG257.46 NG253.90 NG252.83 NG255.94 NG251.00 NG266.23 NG269.75 NG5JO . T*l- NG

96979296978070979889

V2. *?/* Compound is ISTD

247

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0J-•4 8 12 16 29 24 28 32 36 40 44

Quant Output Fi l eData F i l e = >C^253::UOName: 1F8/UQA 10 /4.'89 CMuc: QC.''0070US.0̂ 70070,L:M4,5 . , 5UL SPIKES

Id F! le: IC1043::USTi*.lei PP/UOA, IFB,Last Calibrat ion: 89100? 09:4"

OL'.-rator ID: CA7875Ouant Time: 891004 15s2frIr ^ected at: 891004 14:40

249

QUANT REPORT Page

Operator ID:Output File:Data Fi le:Name:

CA3B75 Quant^C7253::AO>C7253::UO10 X4/89 C

Misc: QC70070US,QU70Q70,L:M4,5, , 5UL SPIKES

7 Quant TimeIn jected at

Di lut ion Fac tor

891004 15:2*'891004 14:40

1. 0 0 0 0 Q

ID Fi le: IC1043: : USTitle: PP/UOA, IFB,Last Calibration: 891003 09:47


1 i2)2 i3)4 ''4)5 i6)7^8)9 •10)r* '12)17 i14)lr: <16)1"18)I* >20)1 1 )

22)21 i23)2« i25)2c i27)28 i29)3 U i31)32 '33)34.35)"* r. '

37)38 '39)4-1 .

*BromochloromethaneMe thy 1 chlorideMe ;. hy 1 chlorideMe thy 1 bromideDich lorodi f luoro me thaneDichlorodifluor ome thaneUi f 'j 1 chlorideCh loroe thaneMe f hy 1 ene chlorideAero le i nAc* t oneAcrylonitri leCa "bon d i su 1 f i deTrichlorof luoro me thane1 .1-Dichloroethylene1 ,1-DichloroethaneTe '• rah1- 'dro f uran1 ,2-Trans-dich loroe thy leneCh loro^orm1 ,2-Dichloroethane-D4 CSURR)1 . 'j-Dichloroethane

*1 ,4-Di f luorobenzeneMet h y l ethyl ketone1 ,1 ,1-TrichloroethaneCarbon tetrachlorideCarbon tetrachlorideUioyl acetateD i ch lo robromome thane1 .2-Dichloropropanecis-1 .3-DichloropropyleneTr ichloroethyleneCh lorod i bromome thanebis(Chioromethvl JetherBenzene1 . 1 ,2-Tnchloroethanetrans-1 ,3-Dichloropropylene2-=rh loroe thy 1 v iny 1 etherBromo f o rm

*Ci-< Iorobenzene-d5Methyl- iso-butyl ketone2- Hexanone1 ,1 ,2 ,2-TetrachloroethaneTetracr loroethvlene

133356667

1010101111121314141515161527161717181818192020212121212122232824252626

.30

. 04

.34

.08

.09

.'*Q

.24

.75

. 18

.83

.79

.53

.88

.34

.00

.23

.27

.00

.43

. 12

.00

.73

.20

.63

.59

.02

.09

.36

.87

.06

.64

. 14

.14

.26

.30

.34

.46

.31

.92

.43

.93

.06

.22

3154957102128149132171234251250269278290307339340359370738359585390427426437439446485490505518518521522523552587719603642645649

96965562566815637244M2656519^0638912M767*81787741921025672941793920591270372122930M24039826215143y0334468522526526772M45223620180257^3637532

26233533285328^5551641252107262117782227327191343662612689322217515437162064349207227350146743141205173307

250.322.390.268.322.279.262.335.287.4605.136.281.649.312.284.250.779.270.272.252.27.

25 U.2S2.277.36.

283.308.266.259.207.284.241.270.260.215.256.39.

222.250.334.283.156.241.

00142818512477954395204433574926406885957400104217485691149299612872216036380071825210

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

NG2NG

9898999g979 '.-••9496999498QW999494931009898'!' • -iu- '-'

9 •'9496969398P '959o979 a1008'J8795100979Os>

r~ 95J 'J 9 'i

97

QUANT REPORT

Operate-* ID: CA1'875 Quant ReOutput File: AC^253=:AQData Fi le: >C7253: :UOName: IFB/UOA 10 /4/S9 CMi*c: QC7007QUS,QU70Q7Q,L:M4,5 , , 5UL SPIKES


Di lut ion Factor

ID Fi le: IC1043: : USTi t l e : PP.--UOA, IFB,Last Calibration: 891003 09:47

Page 2

891004 15:26'391004 14:40

1.00000

41 t42)47 '.44)45 i46)4"' >47)4*148)

Compound

Toluene-08 (SURR)To 1 ueneCh torobenzeneEthy Ibenzenep-Bromo f luorobenzene t SURR )St yrenem- ̂ y lenem-Xy 1 eneo +D-Xy 1 eneso +p-Xy 1 enes

R.

27.27.29.32.35.38.38.40.38.40.

T.

49720801843181478147

Scan ft

6826387237998*8962975

ID 18975

1018

Area

580839315668405082201636328846793^34230422438411230422438411

Cone

255.247.245.250.254.457.228.435 .457.370.

30715699810498672804

U n i t s


q

94


&T»t*}^Lab Name:ETC Corp. '-I—U-abui u l u i y Contract:



Lab File ID: >C7264 I n i t Calib. Dates(s): 09/20/89 09/20/89

Matrix:CsoiI/water) WATER Leye1:C1ow/med) LOW Column:(pack/cap) PACK

Min RRF50 for SPCCCft) - 0.300 CO.250 for Bromoform) Max *RSD for CCCC») •

1 11 COMPOUND 1

IChlorome thane ft1 Bromomethane IlUinol Chloride *1 Ch loroe thane 11 Meth-ulene Chloride 1[Acetone 1ICarban Disulfide 1Il rl-Dichloroethene *1 1 .I'D ich loroethane ft11,2-Dichlorethene (total) _ 1IChloroform *

12-Butanone 111,1.1-Tr ich loroethane 1ICarbon Tetrachloride 1l U i n v l Acetate 1IBromodichloromethane 111,2-Dichloropropane *1cis-l,3-Dich loropropene ____ !ITrichloroethene 1IDibromochloro me thane i11.1.2-Trichloroethane 11 Benzene 11 trans-l,3-Dichlo ropropene _ 11 Bromo form *l4-Meth-jl-2-Pentanone 11 2-Hexanone tITetrach loroethene 111,1,2,2-Tetrach loroethane _ *! To luene *IChlorobenzene ft1 Et hy 1 benzene *IStvrene !IXvlene C total ) 1•

1 Toluene-d8 tIBromofluorobenzene 1ll f2-Dichloroethane-d4 !1 T*>r

TOTQL ION CHROHBTOGRBMFile >C?264 35,8-260.0 anu . IFB/VQH T8/5/89IT QC70078VS,QV73370,Li

TIC

14000*

12080*

10000*

eoooo-J

60000~

40900-J

20000-|

0-

200 600 800 1000

1T2 ", | -,—, , , , -j [—. ; • r • i ̂ T T n i16 20 24 29 32 36 40 44

Quant Output File: ^C7264::AQData File: >C7264Name: IFB/UOA 10/5/89 CHisc: QC70070US,QU70070,L:M4,5,, 5UL CAL I+II+X

Id File: IC1043::USTitle: PP/UQA, IFB,Last Calibration: 891004 17:59

Operator ID: GM6356Quant Time: 891005 16:16Injected at: 891005 15:30

253

QUANT REPORT Page

Operator ID: GM6356 Quant Rev:Output File: ^C7264::AQData File: >C7264::U1Name: IFB/UOA 10/5x89 CMtsc: QC7007QUS,QU7QQ7Q,I_:M4,5,, 5UL CAL I + I I + X


Compound R.T. Scan*


Di lut ion Factor

891005 16:1'6391005 15:30

1.00000

Area Cone Units

1)2)2)3)4)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)20)21)22)23)23)24)25 J26)27)28)29)30)3D32)33)34)35)36)37)38)39)40)41 )

*Bro mo ch loro me thaneMethyl ch lor ideMethyl chlorideMe thy 1 bromi deDich lorod i f luoro me thaneD i c h l o r o d i f luorome thaneUi ny 1 chlorideCh loroethaneMethylene chlorideAc ro le i nAce toneAery 1 on i t r i leCarbon d isu 1 f i deTr ichlorof luoro me thane1 ,1-D ich loroethylene1,1-Dich loroethaneTet rahydrofuran1 ,2-Trans-d ich loroethyleneCh loro forml,2-Dichloroethane-D4 (SURR)

* 1 ,4-Di f luorob«nzeneMethyl ethyl ketone1,1,1-TrichloroethaneCarbon tetrachlorideCarbon tetrachlorideUiny 1 aceta teDich lorobromome thane1 ,2-Dich loropropanec is-1 ; 3- Dich loropropyleneTr ich loroethyleneCh lorod ibro mo me thanebis CCh loro methyl )etherBenzene1 ,1,2-Trich loroethanetrans-l,3-Dich loropropylene2-Chloroethylvinyl etherBromo form

*Ch Iorobenzene-d5Methyl-iso-butyl ketone2-Hexanone1 ,1 ,2 ,2-Tetrach loroethaneTet rach loroethyleneToluene-08 (SURR)

13.3.3.5.6 .7.6.7.10.10.10.11.11.12.12.14.14,14.15.16.23.16.17.17.17.18.18.19.20.20.21.21.21.21.21.22.23.23.24.25.26.26.27.

29033307081223741782785287299922229542076815585897083182015909132125294176833892011644

312465499125152129168231248247266275286304336336355367384581386423423433436442481486501514515517518519548583714599639641645678

81199447686175639098211261 199^Wfer?V626151487441458432799233500367385227601115843201271209421318843029141989693966943988

25009032143232763145192232996132467185571188650200217655713661781137891899824105013945731867Q9203660859101182143989520937

250.237.327.313.320.181.491.244.248.3626.147.386.119.251.281.249.429.273.262.263.250.126.276.34.

252.124.229.-230.250.253.256.259.239.255.243.757.245.250.110.113.194.227.245.

0058734.005634963394231581431339528803669009455353932330398S314870257718825006662936270

NGNGNGNGNG

tfl .NG \Ci\&NGNGNGNGNGNGNGNGNGNGNGNGNGNG ,NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG

NG254NG

959899989999

1 96959893999899959697100979991979097989799999897989810089369610096849897989791

QUANT REPORT Page 2

Operator ID: GM6356 Quant Re^: 7 Quant Time: 891005 16: 1'6Output File: "C7264::AQ Injected at: 891005 15:30Data File: >C7264::U1 Dilution Factor: 1.00000Name: IFB/UOA 10/5/89 CMisc: QC7007QUS,QU70Q7Q,L:r'l4,5,, 5UL CAL I+ I I + X

ID File: IC1Q4?::USTitle: PP/UOA, IFB,Last Calibration: 891004 17:59


42)43)44)45)46)47)48)

To lueneCh lorobenzeneEthy Ibenzenep-Bromof luorobenzene CSURR )Styrenem-Xy leneo +p-Xy lenes

27.29.31.35.38.38.40.

67029270227634

6847197948929579711012

270984356761177916305674374996224208436141

235241241254129266545

.18

.28

.73

.65

.43

.57

.08

NGNGNGNGNGNGNG

96958071979591

* Compound is ISTD

255

6AVOLATILE ORGAN ICS INITIAL CALIBRATION DATA

Lab Name:ETC Corp. I Laboratory Contract:


Instrument ID:GC/MS D Calibration Date(s)

Matrix:CsoiI/water) SOIL Leve1:Clow/med) LOW Column:(pack/cap) PACK

Mm RRF for SPCCC*) - 0.300 CO.250 for Bromoform) Max KRSD for CCCC*) - 30.OS

ILAB FILE ID:IRRF1QO->D7531

RRF20 ->D7529RRF150->D7532

RRF50 ->D7530RRF200->D7533

COMPOUND

Ch1orome thaneBromomethane_

Chloride

Ch1 orideCh loroe thane_Me thy 1eneAce t one________Carbon Disulfide1,1-Dichloroethene1.1-Dichloroethane1.2-Dichlorethene (total)Chloro form______________1,2-Dichloroethane2-Bu t anone__________1,1,1-TrichloroethaneCarbon TetrachlorideUmy 1 AcetateBromodichlorome thane1,2-0ichloropropanec i s- 1,3-DichloropropeneTr ich loroetheneD ibromochlorome thane1,1,2-Tr ichloroethaneBenzene_____________trans-l,3-Dichloropropene_I

I B r o mo for m__________________ft4-Methy1-2-Pentanone

I 2-HexanoneTet rach loroethene11,1,2,2-Tetrachloroethane_*To luene

I Ch lorobenzene^^__________._*EthyIbenzene

I StyreneXylane (total )

/J-tt-fff

TOTQL ION CHPOHPTOISROnFilt >07529 35.0-260.0 amu. IFB'VOfl 9'26''89 D QC70869VS ,QV70069 ,S i

52000-

48000-

44000-

40000-

36000-

32000-.

28000-

240ee-50000-

16000-

12069-

8000-

40136-

0-

200 400 600 800 1000

i I1

• 1 i i I II s 1 R % I

1 I ]i 12 i3 * "I I

t*. f 1U £7 nv *2 3? 1 J,

\3jf Irl ! '*21»1 J* 1 A A **7A•^ vLJuwy .( jyi'y^ ouuLAJ ̂ A/L.4 ' 8 12 ' ie ' 20 24 ' 28 ' 3£ ' 36 ' 40

Data F i l e : >D?529::UOtJfl,-r,e: LR& ",.'CJm 9.̂ '6'"39 0Misc: OC7U069US,QU70069,S:M4,5,, 2UL

Jd r •. le : I01U-16: : UST i t l e : 1FB, PP/UOA, XUO«13Last C a l i b r a t i o n : 8vu9?6 I?:?!1

Operator ID: GM6356Qoar t- Tim^-: SVt!9l'6 1^:3?I n j e c t e d at: 890926 10:24

Quant O u t p u t File: "D?529::AQ

257

Operator ID: GM6356Output F i l e : 0̂7529:: AQData File: >D7529::UOName: IFB/UOA 9/26/89 DHisc : QC

QUANT REPORT

Quant Rev: 7 Quant Time:I n j e c t e d a t :

Di 1 u t ion Fac tor:

Page 1

890926 15:35890926 10:24

1. 00000

:ULID F i l e : ID1046::UST i t l e : 1FB, PP/UOA, XUQfllSLast C a l i b r a t i o n : 890926 15

Compound R.T. Scan* Area Cone Un i ts

1)2)3)-i)5)6 )7)S39)10 )11)1? )13)1 4 ;15 )16)17);£ )1-5 )

1'u )21 J22 )23)23)24)I'1:- i26 J27)28)29 130)31 i32)•3 1 ••J S >

34)1.C-. -,

36)77 )38 J2 9 )40 ).41 )42 )

*Bromoch loro me thaneMethyl chloridetl* t hy 1 brom ideD i c h 1 o r o d i f 1 u o r o me t h a n eU i ny 1 ch 1 or ideCh loroethaneMethylene chlorideAc r o 1 e i nAce toneAc ry 1 on i t r i 1 eCarbon d isu 1 f ideTr ichloroflboro me thane1 ,1-Dichloroethylene1 , 1-Dich loroethaneTet rahydrofuranI t 2 -Trans-d ic h loroethyleneCh loroform1 ,2-Dich lor oe thane -04 : SUfc'R )1 ,2-Dich loroethane

* 1 , 4-D i f 1 uor o benzeneMethyl ethyl ketonei , I fl - T r ; c h 1 o r o e t h a n eCarbon tetrachlorideCarbon tetrachlorideU i ny 1 ace ta teD i ch lor ob r omome t hane1,2-Dichloropropanecis-1 ,3-DichloropropyleneTr ich loroethyleneCh 1 or od ib r omome thanebiaCChloromethyl )etherBenrene1,1,2-Trichloroethanetrans-1 ,3-DichloropropyIene2- Ch I oroe thy 1 vinyl etherBr orriO form

*Chlorob«nzene-d5Ms t h y 1 - 1 «, o - b -j t y 1 Ketone2-Hexanone1 ,1 ,2 , L' -Tet rach loroethaneTet rach loroethyleneTo iuftne-DS f SURR )To 1 uene

12.2.4.5.5.6.9.10.10.10.10.11.12.13.13.14.14.15.15.fl 1,

15.17.17.17.17.17.19.19.20.20.20.20.20.20.20.23.26.'I1 4 .25.25.25.27.27.

659220172930321721839553276270409U647236721111547097487125SO8484959983474209617688U625

27726598487

ii'6191213214230233243267'7023043223353543565533563923924U34074144534

iilllttNT REPORT

Operator ID: GM6356Output F i l e : "-D7529: : «QData F i l e : >D7529::UOName: IFB/UQA 9/-26/S9 DMisc: 007006903,Qv7Q069,S:t14,5, ,

10 F i l e : 1D1046::UST i t l e : IFB, PP/UOA, XOOA13Last C a l i b r a t i o n : 390926 15:32

Compound


D i l u t i o n Fac tor

Page 2

890926 15:35390926 10:24

1. 00000

2UL

R.T. Scan* Area Cone U n i t s

43 )44)45 5i6 )47)4t: ;

Ch 1 o robenzeneEt hy 1 benzenep-Bromof luo robenzene ( SURR)S t y r e n em-Xy 1 eneo +p-Xy 1 enes

28.31.35.37.37.39.

573209459659

68675?85491592897Q

280431414043935236051897441646

112.116.267.118.120.246,

703053690471

NGNGNGNGNGNG

978188949790

Compound is ISTD

259

TOTRL ION CHROflflTOSffPM35.0-260.0 *rau.

see

80000

60800

30000-

£0000

TIC600 800 1000

\ r i i i i i i r r i i i i i i i i i \4 6 12 16 80 £4 £8 32 36 40

Data File: >D7530::UOname: iFB-'UCtt 9/26-'S9 DMisc: QC70Q69

QUftNT REPORT Page

Operator ID: GOutput File: ^07530::AQData File: :D753U::UOName: IFB/UQA 9/26/89 DMisc : QC7iJti69vS,QU70fJ69 ,3: M4 ,5

ID F i l e : ID1046::UST i t l e : 1FB, PP/UOA, XUCW13Last C a 1 i b r a t i o n : 890926 15:32

Compound


D i l u t i o n F a c t o r -

890926 15:37890926 11:18

1. 00000

5UL

R.T. Area Cone Unit*

1)2 )3 J4 I5J6 J7)y J9 i

:u j11 )1 2 '13;'i4 -

15)16 :A ' '

* O '

19 i2U !

21 J22 !23 J23 J24 )2e- i26 )2 " )2812'̂ ^l30 )1 1 ;32 J73 J34)75 )36 J"*. ""* :38 )7v ;40 )-i i42 )

*6romoch lorome t haneMe t hy 1 c h l o r i d eMethyl bromideD i c h l o r c d i f 1 u o r o me thaneUinyl chlorideCh 1 or oe t haneMethylene chlorideAc r G 1 ft i nAce toneAc r y t on i t r i 1 eCarbon d isu 1 f ideT r i c h 1 o r o *•' 1 u o r o me t h a n e1 , 1-Oich loroethylene1 , i - 0 1 c h lore-ethaneTet rahydrofuran1 , 2 - T ,•- a n s - d i c h 1 o r o e t h y 1 e n eCh 1 oro f o rm1 ,2-LMch lor oe thane- 1)4 ( SURR)1 ,2-Dichloroethane

* 1 , 4- D i f 1 u o r o b s n z e n eMethyl ethyl ketone1 ,i , 1 - T r ic h to re-ethaneCarbon tetrachlorideCarbon tetrachlorideU i ny 1 ace ta t eL) i c. h 1 o r o b r o mo me thane1,2-Dich loropropanecis-1 ,3-Cich;oropropyieneTr ichloroethyleneCh 1 o r & d i b r o mo me thanebistChloromethyl )e t herBenzene1 , 1 ,2-Tr ichloroethanet r a n 5 - 1 ,3-Dichloropropylene2-Chloroethylvinyl ether3r orc.o f O rrr,

*Ch Iorobenzene-d5"e- 1 h y 1 - i =, o - & u t y 1 ketone2-Hexanone1 . 1 ,2 ,2-TetrachloroethaneTetrach loroethyleneTo iuene-D3 C SURR 1To 1 uene

12.2.4.5.5.6.9.

;fl .10.10.11.11.12.13.13.14.14.15.15.23.15.17.17,17.17.17.19.19.20.20.20.20.20.20.20.23.28.23.25.25.25.26.27.

71V73330428941263496006232637941966577297713175571934569237777318993854135995470829918

2802964'S9921301952172192-352362522703053083243383^63595533593943954054094164544604744384834394914924905e'6683571611615613648653

39865433S81421355U626709534250415397335729446273571433431062354313010757096355247912232172584716403124029933243510716743934241052413295673U976381313 19^412345105039174282269393901970954539319041891730'-'lj9287119414143047

250.256.288.338.309.262.278.3409.265.330.253.260.253.245 .230.252.254.243.249.250.255.267.37.

261.258.244.243.233.248.238,244.248 .239.236.252.239.25 U.231.304.251.250.243.243.

001245582727831609751090492014241306.950082196967733429324350583249742470ou646706753704

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNUNGNGNG „-O 'p̂ lj/ (j

NGNG

95989399979598929694

• 999591981009098899697929796969697939399ys1009586921009&8U97929o

1 932994

QUHNT REPORT

Operator ID: GM6356Output File: -^07530: : AQData File: >D7530::UOName: 1FB*'UQ« 9x26/89 DMisc: QC70069US,QU70Q69,S:M4,5,, 5UL

ID File: 1D1046::USTit l e : IFB, PP/VQA, XUOA13Last Calibration: 89U926 15:32

Compound

Quant Rev: 7 Quant TimeIn jec ted at

D i 1 u t ion Fac t or

Page 2

890926 15:37390926 11:18

1.00000


43 )44 !45 )-6 J47)-3 )

Ch 1 orobenzeneE t h y l b e n z e n ep-Bro mo f luorobenzene (SURR)S t y r- e n em-Xy 1 oneo+p-Xy lenes

28.31.

- 34.37.37.39.

462286237729

686757851912926965

614753053342913616844050687468

245.250.259.254.254.514.

496564326386

NGNGNGNGNGNG

988190979389

Compound is ISTD

262

£92

80 '.Zl 9C606S :

9 S 6 Q 6 S :

P I

~ I R O T ' ' 5 '6S/93./6OH: :

-,^ , . . - - , | •-] ^T^ 1 "^^1 T I"0631 003 009 0et>

311

HOI

QUANT REPORT Page 1

Operator ID: GM635fo Quant Rev:Output F i l e : AD7531::AQData File: >D7531::UOName: IFB/UOA 9x26x89 DMisc: QC70069US,QU70069,S:M4,5,, 10UL

ID File: ID1046::UST i t l e : IPS, PPXUQA, XUOA13Last Calibration: S9Q926 15:32

~? Quan t T i n-,eInjected at

D i lut ion Fac tor

390926 15:7-9890°26 12:08

1.00000

Compound R.T. Scan* Area Cone Uni ts

1).-1 •,

3)4 )c; y

ft )7 )3;9 )10)11 J12)13)14)15 jlo »17)13)19)2 0 J.-. i ,22 ,'23;23 ,'24)25 ;26)27j28)2g )30)31 i32 J33 )34)35 )36)37)33)39 *40;4l )-*2 )

*Br omoch loro me thaneMe t hy 1 c h l o r i d ehe thy 1 b romideDich lorod i f luoro me thaneUinyl chlorideCh loroe t haneMe t hy 1 ene c h l o r i d eAc ro le inAce toneAc ry Ion i t r i 1 eCarbon d i s u l f i d eTr ich lorof luoro me thane1 ,1-Dich loroethylene1 , 1-Dich loroethaneTe t rah yd ro f ur an1 ,2-Trans-d ich loroethyleneCh 1 oro f o rm1 ,2 -Dich loroe thane-D4 ESURR>1 , 2 - D i c h loroethane

* 1 ., 4-DifrluorobenzeneMethyl ethyl ketone1,1,1-Tr ich loroethaneCarbon t e t r a c h l o r i d eCarbon t e t r a c h l o r i d eUinyl acetateDich lorobr omome thane1 , 2-D i ch loropropanec is-l,7-Dich loropropyleneTr ich loroethyleneCh lorodiDromomethanebisCChloromethyl )etherBenzene1 f 1 /2-Tr ich loroethanet r an 5- 1 , 3-D ich loropropylene2 - Ch 1 o r o e t h y 1 v • i n y 1 etherBromo form

*Cnlorobenzene-d5fie t hy 1 - i so-bu t y 1 ketone2-Hexanone1, 1 ,2 /2-Tetrach loroethaneTet rach loroethyleneTD luene-D3 : SURR)To 1 uene

12.2 .4 .5 .5.6 .9.10.10.11.11.11.12.13.13.14.15.15.15.23.15.17.17.17.17.18.19.19.20.20.20.20.21.21.20.23.28.24.25.25.25.27.27.

77963633409240334103076533748648027234368419196278055275308488380000965245106180380929

2802763889012919321721927523525127030?3083243383563595537593943944054094164544604744834894894924924915576845726116lo6l&64965**

400863561924232874441196&46373392747195331517775658123533520264683464

216334203151009982464133031315241791631b*75

159490210671486788447111662966110723718304774739277472247664042355221214794533364633623173513467796D3&&0111010112io3

250.450.483.534.548.432.619.3473 .459.769.434.494.487.490.432.432.507.272 .528.250.49 Q .45 S.65.

467.•456 .

482.482.

- 496 .479.494.8̂7.472.492.510.•*35 .438.250 .467.4~"7 .46*4 .4o3 .246 .*73.

006389735434142598091594345257770697*350067TO

o1963Ql?99294?70•17330554^Ti

6982008579317894T'i

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGo ^ ANl-/. o 4

93939697969"98949490099490

. 971009199390397gp9393969595999*4

9393100963"91100

QUANT REPORT

Operator ID: GM6356 QuantO u t p u t File: AD7531:iAQData File; >D7531::UOName: IFB/UQA 9x26^89 DMisc: QC70Q69US,QU70069,S:M4,5,, 10UL

ID File: ID1046::USTitle: IFB, PP/UOA, XUOA13La»t Calibration: 890926 15:32

Compound

7 Quan t TimeInjected at

Dilut ion Fac tor

Page 2

890926 1? : 3-9890926 12:08

1.00000

R.T. Scan* Area Cone Uni t 5

43)44)45)46)47)48 )

Ch 1 orobenaeneEthy I benzenep-Bromof luorobenzene tSURR)Styrenem-Xy 1 eneo+p-Xy lenes

28.31.35.37.37.39.

613601333843

638759853914927967

143123633944312013576688981190212

431.476.245 .471.471.944 .

907949976404

NGNGNGNGNGNG

Q7

8189949690

* Compound is ISTD

TOTPL ION CHROMBTOSROnFile >D7532 35.0-260.8 4mu. IFB'VOR 9'£6'8? D QC78?*9V5 ,GtV7?069 ,S i

T IC£00 ( 400 600 _ 800 ( 1000

140009-

130000-

1S0000-

110000-

100600-.

90000-

80080-70000-

60000-

50000-

49800-•

?0000-

•^AdAC^fVWWV"

10000-j

oJ • - , , , , — - .. . -,-r-,— •• -̂ rn-r ---i-r

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^

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4

2i

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9£

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}aiu

QUANT REPORT Page

Operator ID: GM6356 Quant RevO u t p u t F i l e : "D7532::AQData F i l e : >D7532::UOName: IFB-'UOA 9x26/89 Dniac: QC70069US,QU7Q069,S:M4,5,, 15UL

7 Quan t T i meInjected at

D i l u t i o n Fac tor

890926 15:41690926 13:GO

1.00000

ID File: ID1046::UST i t l e : IFB, PP/'JOA, XUOA13Last C a l i b r a t i o n : 390926 1

Compound

32

R.T. Scan* Area Cone Uni ts

111111111122.-i222

222.̂T

3T

?."'TT.

T

33•4

1)

2 J3)4)4)5)5 J6 )7 )3)o )0)1)2)3 )4)5Jo ;7 /8 !9 J0>1 )2 '3 jT, .

4 J5 )6 )"̂ j

3 J9 ,.0)1>2 i3 J4 J5 io )7 j3)9 >0 J

*Bromoch loro me thaneMethyl ch lor ideMethyl bromideDich lorodi f luoromethaneDich lorodi f luoromethaneUinyl chlorideUinyl chlorideCh loroethaneMethylene chlorideAc r o 1 e i nAce t-oneAery 1 on 1 1 r i 1 eCarbon d i su 1 f i deT r ich lorof luoromethane1 , 1-Dich loroethylene1,1-DichloroethaneTe t rahydro f ur an1 , 2-Trans-dich loroethyleneCh 1 o r o f o rm'1 ,2-Dich loroethane- D4 ('SUP.P ti ,2-Dich loroethane

* 1 , * - D i f luorobenzeneMethyl ethyl ke t one1 f 1 , 1-Tr ich IcroethaneCarbon tetrac.hlorideCarbon tetrachlorideU i n y 1 acetateDich lorobromomethane1 , 2-Dichloropropanec is-1 , 7 - D i c h loropropyleneTr ich loroethylen*Ch lorodibromomethanebisCChloromethyl )etherBenzene1 ,1 ,2-Tr ich loroethanet rana- 1 ,3- Dich loropropylene2-Chloroethyl'-'inyl etherBr omo form

*Ch Iorobenzene-d5i'1e t h y 1 - iso-butyl ketone2-Hexanone1 , 1 ,2 ,2-Tet rach loroethaneTftt r ach loroethylene

12.2.4.5.5.c5.6 .Q .

10.10.11.11.11.12.13.13.14.14.15.15.23.15.17.17.17.17.18.19.19.20.20.20.20.21.21.20.23.28.24.25.25.25.

77963633714471954441521006693874864493728036871919 .627805527534848838000396524510617788

28027633398919813019421922223723625227030530332333735635855?36039439440540941645446047543848943949^493491557634572611615613

365331105722991236035240387314190703M3256467595M

2936037324090134

37419-*2431961042582373073185613400930304563553191?S2830538702

203355272901894041318461618429173310090211129110590338339

311325573367457130076638 07M5837990353^836410203584141

250633662242161166456o89*95

1*1767191344696b65668714830702695255-7̂ -1 g25072764493

65173673 9738753709772742721771760750313250"49727774680

.00

.64

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. 13

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.69

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.64

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NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGMGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG267

99o999•jaQ9o0

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'3'3

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698/8oo~30_•*Q

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~*

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QUANT REPORT

O p e r a t o r ID: GM6356Output F i l e : ^07532::AQData File: >D7532::UOName: IFB/UOA 9''26/39 DMisc: QC70069US,QU70069,S:M4,5,

Quant Rev: 7

15UL

ID F i l e : ID1046::UST i t l e : IFB, PP/UOA, XUOA13Last C a l i b r a t i o n : 390926 15 32

Quan t T i meInjected at

Di lut ion Fac tor

Page 2

390926 15:4189Q926 13:00

1. 00000

Compound

To luene-D8 ',SURRJTo 1 ueneChiorobenreneEthylbenzenep-Bromofluorobenzene ( SURR )S t y r e n em-Xy leneo *-p-Xy 1 enes

R.

27.27.28.31.35.37.37.39.

T. J

0929613609459655

3can#

649654683759855916929970

Area

102611544219466917242231731611701249^5

6079

6

Io

Cone

252.729.726.700.238 .686 .t>ar.1373.

9723

14

24303493

Units

NGNGNGNGNGNGNGNG

q8593963288959991

41)42J43)44)45)«6)47)43 )

* Compound is ISTO

268

TOTAL ION CHROnRTOSRflMFile >0?533 35.0-266.6 amu. IFe'VOP 9/2*'8? D QC799S9VS ,QV79869 ,S I

T IC£00 400 609 800 I960

189008-

169000-

.149966-

-

120000-

10000&

89988--

60000-

-40e9fr

.29909-

1.V

5

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7

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.4 S 12 16 £0 £4 £S 3£ 3i 4S

Data Fi lc: ^D75J.7: :UOname: IFE."-'OA 9x26^39 DMisc: QC

Id Fi le: ID1046: : UST i t l e : IFB, PP/UOA, XUGA1?Last Calibration: 890926 1

Operator ID:Quant T i m e : S90926 15:43Injected at: S90926 13:51

Quan t Ou tpu t F i l e

5,,20UL

269

QUANT REPORT Page

Operator ID: GM6356O u t p u t Fi le= 'SD7533: : AQData F i l e : >D7533::UOName: IFB/UQA 9/26/89 DMisc: QC7Q069US,QU70Q69/

ID F i l e : ID1Q46::UST i t l e : IFB, PP/UOA, XUOA13Last C a l i b r a t i o n : 890926 I1

Compound

Quant Rev:7 Ouan t T i rnftInjected at

Di Lut ion Factor

890926 15:4?89Q926 13:51

1. 00000

t14,5,,2QUL

R.T. Scan# Area Cone Un i t s

1)2)3-'4)4)5)5 J6 )7)S ;9)

10 i11)12)13)l*+ ;•15;lo 'i17 )1SJ19 j20 J2 1 >22 )23)23 )24)25 '26 /

23;2 9 ,'30 )M)32)73.'34)35 )36 )37 >38 J39 j40)

*Bromochloro me thaneMethyl ch lor ideMe thy 1 bromi deDich lorod i f 1 u o r o me thaneDichlorodi f luoro me thaneUinyl chlorideUi ny 1 c h l o r i d eCh loroe thaneMethylene chlorideAero le i nAce toneAc ry 1 on i t r i 1 eCarbon disulfideTr ichlorofluoromethane1 , 1-Dichloroethylene1 , 1-DichloroethaneTet fahydrofuran1 ,2-Trans-d ich loroethyleneCh 1 oro f orml,2-Dichloro«thane-D4 ', SUPR )1 ,2-Gichloroethane

* i , 4-D i f luoro benzenehethy 1 ethyl ketone1,1,1-TrichloroethaneCarbon t e t r a c h l o r i d eCarbon tetrachlorideU l ny 1 ace t a t eDich lorobromomethane1 ,2-Dichloropropanec is-1 ,3- Dich loropropyleneTr ich loroethyleneCh 1 o rod ibromo me thanebislChloromethyl ) etherBenzene1,1,2-Tr ichloroethanetrans-1, 3-D ich loropropylene2-Chloroethylvinyl etherBromo form

*Ch Iorobenzene-d5Me t h y 1 - i s o - b u t y 1 ketone2-Hexanone1 , 1 f2 /2-Tet rach loroethaneTetrachloroethylene

12.3.4 .5.R .

5.5 .6 .9.

10.10.11.11.11.12.13.13.14.15.15.15.23.15.17.17.17.17.18.19.19.20.20.20.20.21.21.21.23.28.24.25.25.25.

SI00393371*8~>5954437431006693874904302-yry

8444S32323667809567933QQoo9292040700? 64514653192

231286438939299170194213221237236252270705309724738756759555360395395406409417455461476439490490493494492553684573612ol6619

4095516644446316550 00377034566593879120994100032322793699711130195646897971621633274295314277319920348044931370288?o510155211311

322656-4130530476719988224710614518^161074173163163476535304776343751811S2S545176986567150612176067421145139131880

250.357.914.329.225.204.421.901.653.

17657.783.

1507,937.949.974.953.994,932 .967.270,9^9 .250.307.836.117.857.975.923 .QC;C990 .902.Q ~?p;

927 ,905 .962.98̂ .92 i .95° .250.819.823.89 '3.37S .

00546220673921859353436332443715500165697400oO6267515336711551K n

6512031375360033194748

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG(4GNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGt-JGNGNGNGNGNGNGtiGo i rt!G

QUANT REPORT

Operator ID: GM6356Output File: ^07537::AQData File: >D7533::UOName: IFB/UOA 9/26/-S9 D

Quant Re1

,20UL


D i 1 u t ion Fac tor

Page 2

890926 15:4-7890926 13:51

1. 00000

ID F i l e : ID1046::UST i t l o : IFB, PP-'UOA, XUQA13Last C a l i b r a t i o n : 890926 15:72

Compound R.T. Scantt Area Cone Units

41)42)43)44)45)46 )47)48)

To luene-D3 ( SURR ')To lueneCh 1 orobenzeneEthy 1 benzenep-Bromofluorobenzene tSURR.)St y renem-Xy 1 eneo *p-Xy lenes

27.27.28.71.34.77.37.33.

1033612574035397

649655688756846905918955

12370224690431482515043551706293412192198407385

248952953942

' 238933921

1811

.92

.5?

.39

.07

.61

.40

.52

.01

NGNGNGNGNGNGNGNG

3994987987989691

* Compound is ISTD

271


Lab Name:ETC Corp. 4—Luboi'atery— Contract:


Instrument ID:GC/MS D Calibration Date: 09/26/39 Time: 1625

Lab Fil e ID: >D7535 In i t Calib. Dates(s):

Matrix: (soi I/water) SOIL Leve 1: ( low/mod ) LOU Co lumn : (pack/cap ) PAC:<

Min RRF50 for SPCCC*) - 0.300 (0.250 for Bromoform) Max SRSD for CCC(») - XT. OX

I COMPOUND I RRF IRRF50 I *D

1 Ch loromethane1 Bromo methanelUiny 1 ChlorideICh loroethaneIMethylene Chloride, _1 AcetoneICarbon Disulfida1 1 Pl-Dichloraethene1 1 f 1-Dich loroethane.1 1 ,2-D ich lorethene (total )_(Chloroform ,,,_ „„,,1 1 ,2-Dich loroethane ...1 2-Bu tanone1 1 , 1 , 1-Tr ich loroethane1 Carbon Tat rach lor idelUinol AcetateIBromod ich loromethane1 1 ,2-Dich loropropaneIc i»-l ,3-0 ich loropropene __1 Tr ieh loroa thaneIDibromochlorome thane11,1 ,2-Tr ich loroethane1 Banzftn*

*1*1111**

_'*1111t1*

_l1111

11

312131

11 t ran«,-l,3-Dichloropropene _ 11 Brano* arm *!4-Nl̂ hyl-2-Pen tanone1 2 -Htajnnonai _. _,.,„„ITeVraehlaroaithene ,„„.,._

111

1 1 ,l,Z,2-Tet rach loroa thane _ *1 Toluene »ICh lorohanzanalEthylbenzene ..,.IStyranaIXulane (total)

IToluene-dSIBromnf luorahanzane _mt _1 1 ,2-Dich Ioroethana-d41

**11

1111

1

1

1

1

.1851

.3091

.3611

.8191

.9341

.6971

.6761

.0671'.7511.3051.0311.7971.0361.9491.8751.5041.6591.3741.4001.4721.4131.2241.2991.2951.2531.5191.2851.5251.5641.9061.1481.5581.1121.7791

.7371

.7581

.83511

1i.t

1

412131

11

1

1

1

1

1

.5861

./SI'•rWH.

.9311

.3911

.8211

.1521

.2761

.9031

.4531

.2391

.6551

.0311

.1801

.0581

.5071

.686 1

.3981

.4091

.5121

.4141

.2311

.4741

.2981

.2511

.5671

.3351

.5651

.5871

.9701

.1971

.6171

.2391

.8841

.7441

.8171

.57611

33.57.

13.48.17.12.19.5.11.6.7.14.24.20.

4.6.2.a.3.13.1.1.9.17.7.4.7.4.10.11.13.

7.14.

815•9-*79896«5149«9639515*1532520*186U0«314*55

491

(gp*

272

FORM (JI I YOA 1/87 Rev.

TOTAL IONFlTi >D7933 39.0-560.0 UU. IFB'VOH

TIC

70000-

60000-

90000-

40000-

30000-

80000-

10000-

600

D QC79069VS,QV70069,S

000 1000

Quant Output Fila: AD7535::U3Data Fila: >D7535Nama: IFB/UOA 9x26x89 DMimci QC70069«JS,QU70069,S:M4,5,, 5UL CAL I*II*XUOA

Id File: ID1046::USTit la: IFB, PPxyQA, XUOA13Last Calibration: 890926 15:32

Operator ID: GH6356Quant Time: 890926 17:08Injected at: 890926 16:23

273

QUANT REPORT

Operator IDOutput FileData File:

GM6356*D7535>D7535::UO

Quant Rev: 7

Name: IFB/UOA 9/26x89 DMisc: QC70069US,QU70069,S:M4,5,, 5UL CAL I+II+XVOA

Quant TimeInjected at

Di lut ion Factor

Page 1

890926 17:09890926 16:23

1.00000

ID File: ID1046::USTitle: IFB, PP/UQA, XUOA13Last Calibration: 890926 I1


1)2)3)4)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)41)42)

•Bromoch lorome thaneMethyl chlorideMethyl bromideDich lorodifluorome thaneVinyl chlorideChloroetheneMe thy lene ch lor ideAero lainAcetoneAery loni t r i leCarbon diaulfideTr ich lorof luorome thane1 , 1-D ich loroe thy lane1, 1-0 ich loroe thaneTet rahydrofuran1 ,2-Trans-d ich loroe thy leneCh loroforml,2-Dichloroethane-D4 C5URR)1 ,2-D ich loroe thane

*1 ,4-Di f luorobanzeneMethyl ethyl ketone1 ,1 ,1-Tr ich loroe thaneCarbon tet rachlor ideCarbon tet rachlor idaUinyl acetateDich lo rob romoma thane1 ,2-Oichloropropanec i3-l , 3-D ichloropropy leneTr ich loroe tbylaneCh 1 o rod i broeneie t thanebis (Ch lorovwJUtdC) etherBenzene •̂ JsK*?.":..'-1 , 1 ,2-Tr ich Ibroe thanet r ana- 1, 3-D ieh lorop ropy lane2-Ch loroe thy 1 vinyl etherBromof orm*Chlorobenzene-d5Methyl- iso-butyl ketone2-Hexenone1,1,2 ,2-Tetrach loroe thaneTet rech loroe thy leneToluene-08 (SURR)To luene

12.762.954.315.325.406.919.3910.2410.3210.9811.1011.6812.4213.7713.8514.5115.0115.7515.8323.3915.8717.2217.2617.6517.8118.0819.5519.7820.3320.8720.9120.9121.0221.0220.9523.5128.4024,0925.6025.7625,8727,0427.24

26128636991130194216218235238253'272307309326339358360555361396397407411418456462476490491491494494492558684573612616619649654

4065464460197946518277917378595654394173333732743616877712064251870118023837959087131661640676729978885242593075119318347Q399915408231420322504042232653131281162791823923537103131976475208312781851332430311939626253534

250.00334.57393.78393.03352.18284.28372.184017.76294.62367.72282.37290.54298.94263.81196.26278.49267.14214.71230.25250.00213.46310.6843.22302.34251.26260.16266.25255.21271.21250.84267.85283.66258.11252.88270.88247.55250.00272 . 77294.55260.22269.12250.89267.51

NGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNGNG*"*/~l 1~l tNG274

95979998999498899493999592961009296899897889996979698999598981009686901009678999797978893

QUANT REPORT

Operator 10: GM6356Output File: "-07535::U3Data File: >D7535::UOName: IFB/VOA 9/26x99 DMiac: QC70069gS,QU70069,S:M4,5,

ID File: ID1Q46::USTitle: IFB, PP/YOA, XUQA13Last Calibration: 890926 19:32

Quant Rev: 7 Quant TimeIn jected at

Dilut ion Factor

Page 2

890926 17:09890926 16:-23

1.00000

5UL CAL I+II+XUOA


ChlorobenzeneEthylbanzenep-Bromof luorobenzene CSURR)Styrenem-Xyleneo*p-Xy lanes

29.5631.2734.9237.2537.7539.30

689759952912925965

660663403945122684134570497589

260.63 NG275.99 NG269.70 NG278.64 NG293.93 NG567.47 NG

988186959890

43)44)45)46)47)48)

• Compound is ISTD

275

7AUOLATILE CONTINUING CALIBRATION CHECK

Cont ract:

SAS No.:

Lab Name:ETC Corp. \—Laboratory

Lab Code: Case No.:

Instrument ID:GC/MS D

Lab File ID: >07549

Calibration Date: 09/27/89

Ini t Calib. Dates(s):

SDG No

Time: 10 U ?

Matrix:(soi1/water) SOIL Level:Clow/mod) LOW Column:(pack/cap) PACK

Mm RRF50 for SPCC(#) - 0.300 (0.250 for Bromoform) Max SRSD for CCC(») -

11 COMPOUND

1 Ch lorome thane1 BromomethanelUinvl Chloride1 Ch loroethane1 Me thy lane Ch lor ide1 AcetoneICarbon Disulf ida1 1 rl-Dichloroethene,1 1 t 1-Dich loroethane1 1 ,2-D ich lore thene (totalIChloroform1 1 ,2-Dich loroethane ,12-Butanone1 1 , 1 , 1-Tr ich la roe thane(Carbon Tet rach lor ideI Uiny 1 Acetate1 Bromodich lorome thane1 1 ,2-Dich loropropane1 c is-1 ,3-Dich loropropene_1 Tr ichloroetheneIDibromoch lorome thanet 1 rl ,2-Tr ich lo roe thane ,„1 Benzene

11

*1*111

_ 1**

) _ 1*I1111I*

__ 11111

___ ! 1RRF IRRF50 1

1

1

312131

11 t rans- 1,3-0 ich. loropropene __ 1I Bromoform *14-ttethy 1-2-Pentanona .,l?-Ha««nnna . _ _1 T-t-raehloraathana , BI

111

11 ,1 j?,2-T«t rach loroethane _ *1 Toluene , *iCh larohanzena MlEthy lhanzane MIStyrenaIXylena (total!

1 To luena-dfl ,IBromof luorahanzene1 l,2-Dichloroethane-d41

*

11

1111

1

1

1

1

. 1851

.3091

.3611

.8191

.9341

.6971

.6761

.0671

.7511

.3051

.0311

.7971

.0361

.9491

.8751

.5041

.6591

.3741

.4001

.4721

.4131

.2241

.2991

.2951

.2531

.5191

.2851

.5251

.5641

.9061

.1481

.5581

.1121

.7791

.7371

.7581

.83511

1/

21312131

1

1

1

1

1

1

.3991

.8681

.1181

.0681

.8591

.1101

.7711

.3331

.1301

.7781

.0431

.0801

.9921

.5841

.7141

.401 1

.4251

.5021

.4241

.2361

.3931

.3031

.2551

.6431

.3991

.5711

.6321

.9791

.2021

.5931

.2161

.8701

.7901

.8081

.67111

SO

18.

6.126.53.5.4.

2.3.1.

20.13.13.15.8.

6.6.2.5.7.2.

23!40.8.12.

4.

9.11.

3.6.9.

11

1*

017131010«7*213*110171418141

1121814121717*7131710*

7*

3171

017101

1

TOTAL ION CHROnflTOSRflnFil« >D7549 39.6-266.0 wu. IFB'VQfl 9/V7/99 D QC79eS9VS ,QV70069 ,S i

800

70000-

60000-

400 600

4 8 12 16 20 84 88 32 36 40

Data File: >D7549::UOName: IFB/UOA 9/27/89 DMisc: QC70069"JS,0^70069,S:M4,5,, 5UL CAL

Id File: 101046::USTitle: IFB, PP/UOA, XUOA13Last Calibration: 890926 18:02

Operator 10: GI16356Quant Time: 890927 10:51Injected at: 890927 10:07

Quant Output File: ^07549::AQ

II+XUOA

277

QUANT REPORT Page

Quant Rev: 7Operator ID: GM6356Output File: 0̂7549::AQData File: >D7549::UOName: IFB/UOA 9/27/89 DMisc: QC70069US,QU70069,S:M4,5,, 5UL CAL

ID File: ID1046::USTitle: IFB, PP/UOA, XUQA13Last Calibration: 890926 18:02

Quant TimeIn ject ad at

Di lution Factor

890927 10:51890927 10:07

1.00000


1)2)3)4)4)5)5)6)7)8)9)10)11)12)13)14)15)16)17)18)19)20)21)22)23)23)24)25)26)27)28)29)30)31)32)33)34)35)36)37)38)39)40)

"Bromochlorome thaneMethyl chlor ideMethyl bromideOich lor odifluoro me thaneDich lorod i fluorome thaneUinyl chlorideUinyl chlorideCh loroethaneMe thy lene ch lor ideAero le inAcetoneAery Ion i t r i leCarbon disulfideTrichlorofluoromethane1,1-Dichloroethylene1,1-Dich loroethaneTetrahydrofuran1,2-Trans-dich loroe thy leneCh lorof orml,2-Dichloroeth.ane-04 (SURR)1 ,2-Dich loroethane

•1 ,4-0 if luorobenzeneMethyl ethyl ketone1 , 1,1-Tr ich loroe thaneCarbon t a t raerh lor ideCarbon tet raehlor ideUinyl acetal* ...Dich lorobrofliome thane1 , 2-D ich loropropanec is-1 , 3-D ich lorop ropy leneTrichloroethyleneCh lorod ibromome thaneb iaCChloromethyl )ether .Benzene1 ,1 ,2-Tr ich loroe thanetrans-l;3-Dichloropropylene2-Ch loroe thy 1 vinyl etherBromof orm

*Chlorobenzene-d5Methyl-iso-butyl ketone2-Hexanone1,1 , 2, 2- Tetrach loroethaneTetrachloroethylene

1224555569101010101112131314141515231517171717ia

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