PROGRAM OUTCOMES AND PROGRAM SPECIFIC OUTCOMES · Understand theoretical concepts of instruments...

PROGRAM OUTCOMES

[PO.1]. Critical Thinking: Take informed actions after identifying the assumptions that frame our thinking and actions,

checking out the degree to which these assumptions are accurate and valid, and looking at our ideas and decisions

(intellectual, organizational, and personal) from different perspectives.

[PO.2]. Effective Communication: Speak, read, write and listen clearly in person and through electronic media in English

and in one Indian language, and make meaning of the world by connecting people, ideas, books, media and

technology.

[PO.3]. Social Interaction: Elicit views of others, mediate disagreements and help reach conclusions in group settings.

[PO.4]. Effective Citizenship: Demonstrate empathetic social concern and equity centred national development, and the

ability to act with an informed awareness of issues and participate in civic life through volunteering.

[PO.5]. Ethics: Recognize different value systems including your own, understand the moral dimensions of your decisions,

and accept responsibility for them.

[PO.6]. Environment and Sustainability: Understand the issues of environmental contexts and sustainable

development.

[PO.7]. Self-directed and Life-long Learning: Acquire the ability to engage in independent and life-long learning in the

broadest context socio-technological changes

PROGRAM SPECIFIC OUTCOMES

[PSO.1]. Develop knowledge, understanding and expertise in their chosen field of chemical science.

[PSO.2]. Develop an understanding of eco-friendly chemical processes and impact of chemistry on health and

environment.

[PSO.3]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields as well as

interpret and use data generated in instrumental chemical analyses.

[PSO.4]. Provide opportunities to excel in academics, research or Industry

MANIPAL UNIVERSITY JAIPUR School of Basic Sciences

DEPARTMENT OF CHEMISTRY

PROGRAM OUTCOMES AND PROGRAM SPECIFIC OUTCOMES

M.Sc. –Chemistry | Academic Year: 2017-18

PROGRAM ARTICULATION MATRIX

SEMESTER COURSE

CODE

PO 1 PO 2 PO 3 PO 4 PO 5 PO 6 PO 7 PSO 1 PSO 2 PSO 3 PSO 4

I

CY2111 3 2 2 2 3 2 2 2 2 3 3

CY2112 2 1 2 2 1 2

CY2113 2 1 2 2 1 2

CY2114 3 2 2 2 3 3 3 2 2 3

CY2115 3 2 3 3 3 3 3 3 3 3 3

BS2103 2 1 2 2 1 1 2 2 2 1 1

MA2120 2 2 2 1 2 2 3 2 2 2 2

EN2111 2 2 3 2 2 2

II

CY2211 3 2 2 2 3 3 3 2 2 3

CY2212 3 1 1 2 2 3 1 2 2

CY2213 2 1 2 2 1 2

CY2214 3 2 2 3 3 2 3 3

CY2215 2 3 2 3 3

EN2295 3 1 2 2

CV2291 3 3 3 2 2 3 2 2 2 2 2

III

CY2311 3 2 2 3 3 2 2 3

CY2312 3 2 3 3 3 3 3

CY2313 3 1 1 2 3 3 3 3 3

CY2314 3 2 2 2 2 2 3 2 2 3

CY2315 3 2 3 3 3 2 3

CY2351 3 3 1 3 3 2 2 3

IV

AVERAGE 2.52 1.19 1.62 1.05 0.81 1.71 2.29 2.24 1.67 1.53 2.38

A. Introduction: This course is offered by Dept. of Chemistry as a core course, targeting students who wish to

pursue research& development in industries or higher studies in the field of Inorganic Chemistry. It offers in depth

knowledge about stereochemistry and bonding in the main group compounds. It also provides knowledge about

synthesis and properties of various important main group compounds and makes a student familiar with their

applications in various fields. It gives a profound knowledge on non-aqueous solvents also. Students are expected

to have background knowledge on main group elements and their basic properties for a better learning.

B. Course Outcomes: At the end of the course, students will be able to

[1492.1]. Describe the stereochemistry and bonding in the main group compounds

[1492.2]. Recall basic properties of main group elements and understand various synthetic methods of

important main group compounds

[1492.3]. Recognize important applications of main group elements

[1492.4]. Predict the geometries of various main group compounds based on VSEPR theory, valence bond

theory and molecular orbital theory

[1492.5]. Understand various aspects of the reactivity of non-aqueous solvents

C. PROGRAM OUTCOMES AND PROGRAM SPECIFIC OUTCOMES

[PO.1]. Critical Thinking: Take informed actions after identifying the assumptions that frame our thinking and

actions, checking out the degree to which these assumptions are accurate and valid, and looking at our

ideas and decisions (intellectual, organizational, and personal) from different perspectives.

[PO.2]. Effective Communication: Speak, read, write and listen clearly in person and through electronic media

in English and in one Indian language, and make meaning of the world by connecting people, ideas, books,

media and technology.

[PO.3]. Social Interaction: Elicit views of others, mediate disagreements and help reach conclusions in group

settings.

[PO.4]. Effective Citizenship: Demonstrate empathetic social concern and equity centred national

development, and the ability to act with an informed awareness of issues and participate in civic life

through volunteering.

[PO.5]. Ethics: Recognize different value systems including your own, understand the moral dimensions of

your decisions, and accept responsibility for them.


development.

[PO.7]. Self-directed and Life-long Learning: Acquire the ability to engage in independent and life-long learning

in the broadest context socio-technological changes

[PSO1]. Develop knowledge, understanding and expertise in their chosen field of chemical science

[PSO2]. Develop an understanding of eco-friendly chemical processes and impact of chemistry on health and

environment.

[PSO3]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields as

well as interpret and use data generated in instrumental chemical analyses.

[PSO4]. Provide opportunities to excel in academics, research or Industry.


Department of Chemistry

Course Hand-out

CHEMISTRY OF MAIN GROUP ELEMENTS | CY2111 | 3 Credits | 2103

Session: Aug. 16 – Dec 16 | Faculty: Dr. Veena Dhayal | Class: M.Sc. I Semester

D. Assessment Plan:

Criteria Description Maximum Marks

Internal Assessment

(Summative)

Sessional Exam I 20

Sessional Exam II 20

In class Quizzes and Assignments ,

Activity feedbacks (Accumulated and

Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)

A minimum of 75% Attendance is required to be maintained by a student to be

qualified for taking up the End Semester examination. The allowance of 25%

includes all types of leaves including medical leaves.

Homework/ Home Assignment/

Activity Assignment

(Formative)

There are situations where a student may have to work in home, especially

before a flipped classroom. Although these works are not graded with marks.

However, a student is expected to participate and perform these assignments

with full zeal since the activity/ flipped classroom participation by a student will be

assessed and marks will be awarded.

E. SYLLABUS

Stereochemistry and Bonding in main group compounds: VSEPRT, hybridization, covalently bonded

molecules; Hydrogen, alkali and alkaline earth metals: hydrides, application of crown ethers; Noble gases:

Isolation and properties, preparation and structure of noble gas compounds; Boron compounds: Boranes,

carboranes, metalloboranes, metallocarboranes, borazines; Compounds of carbon and silicon: Fullerenes,

carbon nano-tubes, carbides, fluorocarbons, silanes, silicates, zeolites and silicones; Compounds of oxygen

group elements: Metal selenides and tellurides, oxyacids and oxoanions of S & N; Compounds of nitrogen

group elements: BN, PN and SN compounds - preparation, structure and bonding; Compounds of halogen

group elements: Interhalogens, oxyacids and oxoanions of halogens; Reaction in non-aqueous solvents:

Reaction in liquid ammonia, liquid sulphur dioxide, DMF, DMSO.

F. TEXT BOOKS

1. F.A. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, John Wiley.

2. J. E. Huhey, Inorganic chemistry: principles of structure and reactivity. Harper and Row, 2010.

1. J. D .Lee, Concise Inorganic Chemistry. ELBS Publication, 2010.

G. REFERENCE BOOKS

1. Shriver, D.F., Atkins, P.W., Langford, C.H., Inorganic Chemistry, Oxford University Press, 2010.

2. Miessler, G.L., Tarr, D.A., Inorganic Chemistry, Pearson Publications, 2011.

3. Wulfsberg, G., Inorganic Chemistry, University Science Books, Viva Books Pvt. Ltd, 2013.

H. Lecture Plan:

LEC NO TOPICS

1. Stereochemistry and Bonding in main group compounds

2. VSEPR Theory

3. hybridizaion

4. covalently bonded molecules

5. Hydrogen, alkali and alkaline earth metals

6. Synthesis, properties and applications of hydrides

7. Synthesis, properties and applications of crown ethers

8. Noble gases: Isolation

9. Properties of noble gases

10 preparation and properties of noble gas compounds

11 structure of noble gas compounds

12 Revision

13. Boron compounds: Synthesis, properties, applications and structure of Boranes

14. Synthesis, properties, applications and structure of carboranes,

15. Synthesis, properties, applications and structure of metalloboranes,

16. Synthesis, properties, applications and structure of metallocarboranes

17. Synthesis, properties, applications and structure of borazines

18. Compounds of carbon and silicon:

19. Synthesis, properties, applications and structure of Fullerenes

20. Synthesis, properties, applications and structure of carbon nano-tubes,

21. Synthesis, properties, applications and structure of carbides

22. Synthesis, properties, applications and structure of fluorocarbons

23. Synthesis, properties, applications and structure silanes

24. Properties, applications and structure of silicates

25. Properties, applications and structure zeolites

26. Synthesis, properties, applications and structure silicones

27. Revision

28. Compounds of oxygen group elements: Metal selenides

29. Metal tellurides,

30. Synthesis, properties, applications and structure of oxyacids and oxoanions of S

31. Synthesis, properties, applications and structure of oxyacids and oxoanions of N

32. Compounds of nitrogen group elements: BN

33. PN compounds - preparation, structure and bonding

34. SN compounds - preparation, structure and bonding

35. Compounds of halogen group elements: Interhalogens

36. oxyacids and oxoanions of halogens

37. Reaction in non-aqueous solvents:

38. Reaction in liquid ammonia

39. Reactions in liquid sulphur dioxide

40. Reactions in DMF

41. Reactions in DMSO

42. Revision

I. Course Articulation Matrix: (Mapping of COs with POs)

CO

STATEMENT

CORRELATION WITH PROGRAM OUTCOMES CORRELATION WITH PROGRAM

SPECIFIC OUTCOMES

PO 1 PO 2 PO 3 PO 4 PO 5 PO 6 PO 7 PSO 1 PSO 2 PSO3 PSO 4

AU 1492.1 Describe the stereochemistry and bonding in the main group

compounds

3 2 2 2 2

AU 1492.2 Recall basic properties of main group elements and

understand various synthetic methods of important main

group compounds

2 2 2 2 1 1

AU 1492.3 Recognize important applications of main group elements

1 2 2 3 2

AU 1492.4 Predict the geometries of various main group compounds

based on VSEPR theory, valence bond theory and molecular

orbital theory

2 1 2 2 2 2

AU 1492.5 Understand various aspects of the reactivity of non-aqueous

solvents

2 1 3 2 2 3

1- Low Correlation; 2- Moderate Correlation; 3- Substantial Correlation

A. Introduction: This course is offered by Dept. of Chemistry as a core subject for the M.Sc. programme, with an

emphasis on fundamental understanding of stereochemistry, stereoselectivity and stereospecificity. The course

explains detail about reaction mechanism of organic reaction and aromaticity. Students are expected to have

background knowledge in organic chemistry up to the undergraduate level for this course.


[2112.1]. Understand the stereochemistry, stereoselectivity and stereospecificity.

[2112.2]. Learn about chirality, resolution of racemates Conformational analysis.

[2112.3]. Discuss the nucleophilic substitution reactions.

[2112.4]. Learn about Elimination reactions.

[2112.5]. Addition to carbon–carbon multiple bonds.

[2112.6]. Discuss the aromaticity.


[PO.1]. Critical Thinking: Take informed actions after identifying the assumptions that frame our thinking

and actions, checking out the degree to which these assumptions are accurate and valid, and looking at our


[PO.2]. Effective Communication: Speak, read, write and listen clearly in person and through electronic

media in English and in one Indian language, and make meaning of the world by connecting people, ideas,

books, media and technology.


settings.


development, and the ability to act with an informed awareness of issues and participate in civic life through

volunteering.




development.

[PO.7]. Self-directed and Life-long Learning: Acquire the ability to engage in independent and life-long

learning in the broadest context socio-technological changes


[PSO.2]. Develop an understanding of eco-friendly chemical processes and impact of chemistry on health

and environment.

[PSO.3]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields

as well as interpret and use data generated in instrumental chemical analyses.




Course Hand-out

Stereochemistry, Reaction Mechanism And Aromaticity | CY2112 | 3 Credits | 2 1 0 3

Session: Jul 16 – Dec 16 | Faculty: Dr. Rahul Shrivastava | Class: Core Subject; MSc

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)

There are situations where a student may have to work in home, especially before

a flipped classroom. Although these works are not graded with marks. However, a

student is expected to participate and perform these assignments with full zeal since

the activity/ flipped classroom participation by a student will be assessed and marks

will be awarded.

E. SYLLABUS

Stereochemistry: Chirality, Stereochemistry of different compounds, Resolution of racemates, Stereoselectivity and

Stereospecificity, Conformational analysis of ethane and cycloalkanes; Reaction Mechanism: Methods of determining

reaction mechanism, Nucleophilic substitution reactions Factors affecting reactivity, Elimination reactions, Addition

to carbon–carbon multiple bonds, Radicals in organic synthesis; y: Huckle's rule, Aromatic electrohilic substitution,

Nucleophilic aromatic substitution, various types

F. TEXT BOOKS

Robinson M.J. T., Organic stereochemistry, Oxford University Press, 2005.

Eliel E. L., Wilen S. H., Manden L. N., Stereochemistry of Carbon compounds, Wiley, 2005.

G. REFERENCE BOOKS

Bruckener, R., Advanced organic chemistry: Reaction mechanism, Elsevier, 2009.

Singh, M.S., Advanced organic chemistry: Reactions and mechanism, Pearson Education, 2014.1. Atkins P.W., Paula,

J. De, Physical Chemistry, W.H. Freeman, 2012

H. Lecture Plan

Lecture

number

Topics

1 Concept of isomerism, types of isomerism, optical isomerism.

2 Elements of symmetry

3 Molecular chirality, enantiomers, disteroisomer, stereo genic centers, optical activity,

properties of enantiomers and disteroisomer

4 Chiral and achiral molecules with two stereo genic centers, stereoisomers,

mesocompounds,

5 Resolution of enantiomers, inversion, retention and racemization.

6 Relative and absolute configurations, sequence rules,

7 D & L systems of nomenclature.

8 R & S systems of nomenclature

9 E and Z system, geometrical isomerism in alicyclic compounds

10 Conformation, conformational analysis of ethane, n-butane and cyclohexane’s, axial and

equatorial bonds

11 Newman projection and Saw horse formulae

12 Fischer and Flying wedge formulae.

13 Stereoselectivity

14 Stereospecificity

13 Hemolytic and heterolysis bond breaking, Types of Reagents: Electrophiles and

nucleophiles, free radical

14 Types of organic reactions, Energy consideration, reactive intermediates- carbocation,

carbanion.

15 Free radicals and carbines

16 Methods of determination of reaction mechanism (Product analysis, intermediates,

17 Isotope effect, Kinetics and Stereo chemical studies

18 Methods of determining reaction mechanism

19 Nucleophilic substitution reactions

20 Factors affecting reactivity of nucleophilic substitution reactions,

21 Examples of nucleophilic substitution reactions

22 Elimination reactions

23 Examples of elimination reactions

24 Addition to carbon–carbon multiple bonds

25 Addition to carbon–carbon multiple bonds

26 Examples of addition to carbon–carbon multiple bonds

27 Synthetic use of addition of carbon–carbon multiple bonds

28 Radicals in organic synthesis

29 Examples of radicals in organic synthesis

30 Use of radicals in organic synthesis

31 Aromaticity and anti-aromicity

32 Huckle's rule

33 Aromatic electrohilic substitution,

34 Examples of aromatic electrohilic substitution,

36 Nucleophilic aromatic substitution

37 Examples of nucleophilic aromatic substitution

1. Course Articulation Matrix: (Mapping of COs with POs)

CO

STATEMENT

CORRELATION WITH PROGRAM

OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO 7 PSO 1 PSO 2 PSO 3 PSO 4

CY

2112.1

Understand the stereochemistry, stereoselectivity

and stereospecificity.

1 1 2 2 1 2

CY

2112.2

Learn about chirality, resolution of racemates

Conformational analysis.

1 1 2 2 1 2

CY

2112.3

Discuss the nucleophilic substitution reactions. 2 1 2 1

CY

2112.4

Learn about Elimination reactions. 2 1 2 1

CY

2112.5

Addition to carbon–carbon multiple bonds. 1 1 1 1

CY

2112.6

Discuss the aromaticity 1 1 1 1



emphasis on fundamental understanding of Surface chemistry and thermodynamics. The course explains Schrödinger

equation, electrical double layer and advanced chemical kinetics topics. Students are expected to have background

knowledge in physical chemistry up to the undergraduate level for this course.


[2113.1]. Understand the surfaces and interfaces.

[2113.2]. Learn about Dispersed systems, Surfactants, CMC, Emulsions

[2113.3]. Discuss the laws of thermodynamics.

[2113.4]. Learn about binary solutions and partial molar properties.

[2113.5]. Gibbs energies of pure phases and allotropes.

[2113.6]. Discuss the statistical thermodynamics.









settings.



volunteering.




development.





and environment.






Course Hand-out

Surface Chemistry and Thermodynamics | CY2113 | 3 Credits | 2 1 0 3

Session: Jul 17 – Dec 17 | Faculty: Dr. Praveen Kumar Surolia | Class: Core Subject; MSc

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Surface chemistry: Surfaces and interfaces, Dispersed systems, Surfactants, CMC, Emulsions, Colloids, vesicles,

foams and aerosols; Thermodynamics: Laws of thermodynamics, Reaction equilibrium, Gibbs energies of pure

phases and allotropes, Binary solutions, Partial molar properties & their significance, Statistical thermodynamics,

Maxwell-Boltzmann, Bose-Einstein and Fermi-Dirac statistics, Derivation of distribution laws (most probable

distribution) for the three types of statistics, Evaluation of translational, rotational and vibrational partition functions

for monatomic, diatomic and polyatomic gases.

F. TEXT BOOKS

1. Atkins P.W., Paula, J. De, Physical Chemistry, W.H. Freeman, 2012

G. REFERENCE BOOKS

1. McQuarrie, D. A., Statistical Mechanics, Viva Books Pvt. Ltd.: New Delhi, 2013.

H. Lecture Plan:

Lecture

No.

Topics

1 Introduction: Surfaces and interfaces

2 Surface Chemistry: Curved surfaces, capillary action

3 Surface Chemistry: Vapour pressure of droplets-Kelvin equation

4 Surface Chemistry: Adsorption of gases on solids, adsorption curves

5 Surface Chemistry: Freundlich adsorption isotherm

6 Surface Chemistry: Langmuir adsorption isotherm

7 Surface Chemistry: multimolecular theory-BET adsorption isotherm

8 Revision

9 Colloidal state and micelles, Surfactants

10 Brownian movement, Coagulation, sol-gel, stability of sols, sol-gel transformation

11 Electrical double layer, determination of charge on colloidal particles

12 Vesicles, foams and aerosols

13 Revision

14 Thermodynamics: Energy, work, heat content, zeroth law of thermodynamics

15 First law of thermodynamics, application, maximum work

16 Second law of thermodynamics, entropy, spontaneous and non-spontaneous processes

17 Revision

18 Cyclic process, Carnot cycle

19 Entropy- variation with temperature, volume and pressure

20 Free energy and work function

21 Revision

22 Maxwell’s equations and applications

23 Gibbs-Helmholtz equation

24 Clapeyron equation, Clausius-Clapeyron equation

25 Revision

26 Third law of thermodynamics, Nernst’s heat theorem

27 Binary solutions, partial molar properties, chemical potential

28 Gibbs-Duhem equation, determination of partial molar properties

29 Variation of chemical potential with temperature and pressure

30 Revision

31 Statistical thermodynamics: Probability, fundamentals of statistical methods

32 Most probable distribution and Maxwell-Boltzmann distribution law

33 Partition function, entropy and probability

34 Revision

35 Partition function of molecules with different types of energy

36 Evaluation of partition function for monoatomic gases

37 Evaluation of partition function for diatomic gases

38 Evaluation of partition function for polyatomic gases

39 Revision

40 The Bose-Einstein statistics

41 The Fermi-Dirac statistics

42 Result for three types of statistics

43 Revision


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7

PSO 1 PSO 2 PSO 3 PSO 4

CY

2113.1

Understand the surfaces and interfaces 1 1 2 2 1 2

CY

2113.2

Learn about Dispersed systems, Surfactants, CMC,

Emulsions

1 1 2 2 1 2

CY

2113.3

Discuss the laws of thermodynamics 2 1 2 1

CY

2113.4

Learn about binary solutions and partial molar

properties

2 1 2 1

CY

2113.5

Gibbs energies of pure phases and allotropes 1 1 1 1

CY

2113.6

Discuss the statistical thermodynamics 1 1 1 1


A. Introduction: This course is offered by Dept. of Chemistry for 1nd Semester M. Sc. students. The objective of the

course is to acquaint the students with various modern instrumental methods of analysis which covers

electrochemical method of potentiometric and voltametric analyses, spectrophotometric methods such as atomic

absorption, fluorescence, UV-Vis, and chromatographic methods such as paper chromatography, HPLC, GC. The

student with the knowledge of the advanced knowledge will be able to explain scientifically various analytical

chemistry related problems, which in turn help in life-long self learning.


[CY2114.1]. Explain the theoretical principles and important applications of modern analytical methods.

[CY2114.2]. Apply statistical inference in the form of Accuracy, Precision, Error

[CY2114.3]. Explain the theoretical principles of various separation techniques in chromatography, and

typical

applications of chromatographic techniques.

[CY2114.4]. Use analytical methods based on, electro-analytical technique, thermo gravimetry and atomic

and

molecular spectrometry and be familiar with appropriate use for these method.

[CY2114.5]. Assess and suggest a suitable analytical method for a specific purpose, and also suggest

alternative

analytical methods.

[CY2114.6]. Apply the above within drugs and the manufacturing industry



checking out the degree to which these assumptions are accurate and valid, and looking at our ideas and

decisions (intellectual, organizational, and personal) from different perspectives.

[PO.2]. Effective Communication: Speak, read, write and listen clearly in person and through electronic media in

English and in one Indian language, and make meaning of the world by connecting people, ideas, books, media and

technology.


[PO.4]. Effective Citizenship: Demonstrate empathetic social concern and equity centred national development, and

the ability to act with an informed awareness of issues and participate in civic life through volunteering.

[PO.5]. Ethics: Recognize different value systems including your own, understand the moral dimensions of your

decisions, and accept responsibility for them.


development.

[PO.7]. Self-directed and Life-long Learning: Acquire the ability to engage in independent and life-long learning in

the broadest context socio-technological changes




Course Hand-out

Analytical Chemistry | CY2114| 3 Credits | 2 1 0 3

Session: Aug 16 – Dec 16 | Faculty: Arunava Agarwala | Class: 1nd Semester M. Sc. (Chemistry)



environment.




D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I (Closed Book) 20

Sessional Exam II (Closed Book) 20

Assignments and Class tests

(Accumulated and Averaged)

10

End Term Exam

(Summative)

End Term Exam (Closed Book) 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)

There are situations where a student may have to work in home. Although these

works are not graded with marks. However, a student is expected to participate

and perform these assignments with full zeal since the activity will help the

students in developing better understanding.

E. SYLLABUS

Measurement and data analysis: Accuracy, precision, Significant figures, Gaussian distribution of data, standard

deviation, regression analysis, least squares method, correlation coefficient; Solvent extraction: Extraction equilibria and

extraction systems - Chelation, solvation and ion-pair formation; Chromatography: Ion exchange chromatography,

planar chromatography - paper and TLC, HPLC; Spectral methods: Bear-Lambert Law, UV-Visible spectrophotometry

Instrumentation and application, AES, Flame photometry, Fluorescence spectrophotometry; Radioanalytical methods:

Radioactivity as analytical tool. Neutron activation analysis; Thermal methods: TGA, DTA, DSC – Basics,

instrumentation and applications; Electroanalytical techniques: Polarography, conductometry, potentiometry, and

coulometry, anodic stripping, Electrophoresis and its applications.

.

F. TEXT BOOKS

A book or a set of books which covers 60% or more of the syllabus can be written under this category. (Not more than 3)

T1. Christian, G. D., Analytical Chemistry, 5th Edition, John Wiley &Sons, Inc, New York, 2004.

T2. Skoog, D. A., West, D. M., Principles of Instrumental Analysis, Holt Rinahart Winston, New York, 2006.

G. REFERENCE BOOKS

R1. Robinsons, K. A., Chemical Analysis, Harper Collins Publishers, New York, 2010.

R2. Wiliard, H. A., Merrit, L. L., Dean, J. A., Instrumental methods of Analysis, van Nostrand, New York, 2013.

H. Lecture Plan:

Lecture

number

Topics

1 Introduction to analytical chemistry: Difference between qualitative and quantitative

analysis.

2 Language of Analytical Chemistry: Accuracy, Precision, Error

3 Language of Analytical Chemistry (contd.): Sensitivity and Selectivity

4 Numerical problems: : Accuracy, Precision, Error

5 Discussion about Gaussian distribution of data, standard deviation.

6 Regression analysis, least squares method, correlation coefficient.

7 Solvent extraction: Introduction and Importance

8 Distribution coefficient; Distribution ratio; Percent extracted; Multiple extraction

9 Extraction involving additional equilibrium: Weak acids and weak bases.

10 Extraction of metal as a chelate compound

11 Extraction of metal as a chelate compound (contd.): Role of pH of the madium

12 Chromatographic technique: General introduction, definition and classification.

13 Gas chromatography (GC): General instrumentation; Performing GC separation; GC

column; GC detectors.

14 Gas chromatography (contd.): Temperature selection; quantitative measurements;

15 Resolution of analyte; Separation factors; Carrier gas

16 Application of gas chromatographic technique: Identification and quantification of

compound

17 Liquid chromatography: General introduction

18 Column chromatography: Technique, column material, role of solvent polarity.

19 Paper chromatography, thin layer chromatography: Principle and application

20 High performance liquid chromatography (HPLC): General instrumentation.

21 Column material: Reverse phase and normal phase; Mobile phase; Detector.

22 Ion exchange chromatography: Technique (column material) and application.

23 Spectroscopic method of chemical analysis: General discussion about various

spectroscopic techniques.

24 Bear-Lambert Law: Relation between absorbance (A) and transmittance (T), numerical

problems related to Bear-Lambert Law.

25 UV-Visible spectrophotometry instrumentation: Source, monochromator, detector.

26 Analysis of sample using UV-Visible spectrophotometer

27 Application of UV-Visible spectrophotometry: Identification of chemical substance,

multicomonent analysis, photometric titration.

28 Atomic Absorption spectroscopy: Principle, instrumentation and application.

29 Atomic emission spectroscopy: Principle, instrumentation and application.

30 Fluorescence spectroscopy: Principle, instrumentation and application.

31 Flame photometry: Instrumentation and use of flame photometry

32 Radio-analytical methods: Introduction about radioactivity, decay constant.

33 Radioactivity as analytical tool (radio-carbon dating), neutron activation analysis

34 Thermal methods of analysis: Introduction

35 TGA: Instrumentation and application

36 DTA, DSC : Basics, instrumentation and applications

37 Electrochemistry: General discussion

38 Electro-analytical techniques: Introduction

39 Polarography: Importance of polarography as analytical tool

40 conductometry, potentiometry: Instrumentation and application

41 Coulometry, anodic stripping, Electrophoresis and its applications

42 Revision


CO

STATEMENT

CORRELATION WITH PROGRAM OUTCOMES CORRELATION WITH


PO 1 PO 2 PO 3 PO 4 PO 5 PO 6 PO 7 PSO 1 PSO 2 PSO 3 PSO4

CY 2114.1 Explain the theoretical principles and

important applications of modern

analytical methods

3 2 1 1 2 3 3 2 1 2

CY 2114.2 Apply statistical inference in the form of

Accuracy, Precision, Error

2 1 2 1 3 2 3 2 2 3

CY 2114.3 Explain the theoretical principles of

various separation techniques in

chromatography, and typical applications

of chromatographic techniques

3 2 1 2 2 3 3 1 1 3

CY 2114.4 Use analytical methods based on,

electro-analytical technique, thermo

gravimetry and atomic and molecular

spectrometry and be familiar with

appropriate use for these method

3 2 1 1 3 3 3 1 1 2

CY 2114.5 Assess and suggest a suitable analytical

method for a specific purpose, and also

suggest alternative analytical methods

3 2 1 1 2 2 3 2 2 2

CY 2114.6 Apply the above within drugs and the

manufacturing industry

2 1 1 2 3 3 3 1 1 3


A. Introduction: This course is offered by Dept. of Chemistry to postgraduate students for M.Sc. programme, targeting

students who wish to pursue masters or higher studies & research in the field of physical chemistry and analytical

chemistry with specific focus on the interdisciplinary nature. The course offers in depth knowledge of Groups,

Symmetry elements, Elements of group theory, point groups, Spectroscopy, Selection rules Fluorescence &

Phosphorescence, Symmetry aspects of molecular orbital theory with examples, Hybrid orbitals & molecular orbitals.

Students are expected to have background knowledge in mathematics & physical chemistry up to the undergraduate

level for this course.


[1611.1]. Understand introduce the concepts and importance of symmetry and group theory in solving chemical

problems.

[1611.2]. Apply concepts of symmetry and group theory in solving chemical structural problems.

[1611.3]. Use of character tables and projection operator techniques.

[1611.4]. Apply of symmetry and group theory in spectroscopy.

[1611.5]. Understand Microwave, Infrared-Vibration-rotation Raman and infra-red Spectroscopy and their

applications for chemical analysis.

[1611.6]. Apply the concept of Electronic spectroscopy of different elements and simple molecules and Nuclear

Magnetic and Electron Spin Resonance Spectroscopy for organic compounds analysis, medical diagnostics.








[PO.3]. Social Interaction: Elicit views of others, mediate disagreements and help reach conclusions in

group settings.



volunteering.



[PO.6]. Environment and Sustainability: Understand the issues of environmental contexts and

sustainable development.


learning in the broadest context socio-technological changes.



Course Hand-out

Group Theory and Spectroscopy | CY 2115 | 3 Credits | 2 1 0 3

Session: July 16 – Dec 16 | Faculty: Dr. Debasis Behera | Class: M.Sc. , I semester



environment.




D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Group theory: Groups, Symmetry elements, Elements of group theory, Symmetry point groups, Representation of point

groups, reducible & irreducible representations; Spectroscopy: Rotational & vibrational spectroscopy: Intensity & width of a

spectral line, Electromagnetic spectrum, Rotational Raman spectra, Selection rules for vibrational spectrum, anharmonicity,

vibration-rotation spectra & spectral branches, Electronic spectroscopy: Nature of transition, Franck-Condon factor, Quantum

yield and radiative processes, Fluorescence & Phosphorescence, Elementary ideas of laser and laser action, Symmetry aspects of

molecular orbital theory with examples, Hybrid orbitals & molecular orbitals.

F. TEXT BOOKS

1. Cotton, F.A., Chemical Applications of Group Theory, John Wiley (1990) 3rd ed.

2. Rakshit, S.C., Molecular Symmetry Groups and Chemistry, The New Book Stall (1988).

3. Dass, N.N., Symmetry and Group Theory for Chemists, Asian Books Pvt. Ltd (2004).

4. Gopinathan, M.S., and Ramakrishnan, V., Group Theory in Chemistry, Vishal Publishers (2006)

G. REFERENCE BOOKS

1. Jaffe, H.H., Orchin, M., Symmetry in chemistry, Dover Publications, 2008

H. Lecture Plan:

Lecture

No.

Topics

1 Symmetry elements and operation: Symmetry elements and symmetry operation

2 Definitions of group, Subgroup, examples

3 Relation between orders of a finite group and its subgroup.

4 Conjugacy relation and classes.

5 Point symmetry group and its matrix representations.

6 Matrix multiplication of point groups.

7 Schonflies symbols, Representations of groups by matrices (representation for the Cn, Cnv,

Cnh, Dnh).

8 Character of a representation.

9 Numerical problems and revision.

10 Character Table and their Uses: The great orthogonality theorem and its importance.

11 Construction of character tables

12 Reducible and irreducible representations. Examples

13 Group theory and quantum mechanics, Projection operator

14 Using projection operator to construct symmetry adopted linear combinations (SALCs).

15 Chemical Applications: Molecular orbital theory chemistry,

16 Chemical Applications: Molecular orbital theory and its application in organic and inorganic

chemistry,

17 Molecular vibrations

18 Normal coordinates,

19 Selection rules- Infra Red and Raman spectra.

20 Numerical problems and revision

21 Spectroscopy: Rotational & vibrational spectroscopy: introduction

22 Spectroscopy: Rotational & vibrational spectroscopy: Intensity & width of a spectral line,

23 Electromagnetic spectrum, Rotational Raman spectra,

24 Mutual exclusion principle, Resonance Raman spectroscopy

25 Coherent anti Stokes Raman spectroscopy (CARS). Selection rules for vibrational spectrum,

anharmonicity,

26 vibration-rotation spectra & spectral branches,

27 Electronic spectroscopy: Nature of transition

28 Franck-Condon factor, Quantum yield and radiative processes,

29 Fluorescence & Phosphorescence,

30 Elementary ideas of laser and laser action

31 Symmetry aspects of molecular orbital theory with examples,

32 Hybrid orbitals & molecular orbitals.

33 Revision of Symmetry elements and operation

34 Revision of Character Table and their Uses

35 Revision of Rotational & vibrational spectroscopy

36 Revision Electronic spectroscopy


CO

STATEMENT


SPECIFIC OUTCOMES


CY

1611.1

Understand introduce the concepts and importance of symmetry

and group theory in solving chemical problems.

3 2 2 3 2 3

CY

1611.2

Apply concepts of symmetry and group theory in solving

chemical structural problems.

2 3 3 2 3

CY

1611.3

Use of character tables and projection operator techniques. 3 3 2 2

CY

1611.4

Understand Microwave, Infrared-Vibration-rotation Raman and

infra-red Spectroscopy and their applications for chemical

analysis.

3 3 3 3 2

CY

1611.5

Understand of basic concept of phase equilibrium of one

component system and two component systems.

2 3 3

CY

1611.6

Apply the concept of Electronic spectroscopy of different

elements and simple molecules and Nuclear Magnetic and

Electron Spin Resonance Spectroscopy for organic compounds

analysis, medical diagnostics.

2 3 2 3 3 2


A. Introduction: This course is offered by Dept. of Biosciences as a core course in M.Sc. (Hons.) Chemistry

Programme targeting students who wish to pursue their career in interdisciplinary fields such biochemistry,

biomolecules structure and functions, etc. This course is designed with an objective to motivate and ignite the young

minds towards pursuing interdisciplinary curriculums with respect to biological and chemical sciences. The course

imparts a thorough knowledge of the basic concepts of the biological sciences such as structure, function and types

of biomolecules present in a cell. This learning can be further utilised in combination with chemistry to attain various

outcome based learning objectives such as studying the activity of various compounds, studying the structure and

dynamics of various biomolecules, etc.

B. Course Outcomes: At the end of the course, students will be able to understand the:

[BS 2103.1]. Biomolecules: types, structure, functions in cellular life and importance in context with day to day

life.

[BS 2103.2]. Cell: types, structure and functions of different cell organelles. Comparative microscopic study of

different types of cells.

[BS 2103.3]. Bioenergetics: laws of thermodynamics w.r.t. the living system and their importance

[BS 2103.4]. Enzymes: concept of coenzymes & cofactors, kinetics, mode of action, classification and role in

different biological processes

[BS 2103.5]. Metabolites: primary and secondary, economically important metabolites and their applications in

food, agriculture, medicine and industry.

[BS 2103.6]. Modern tools and techniques of biotechnology: principles, working and applications.




decisions (intellectual, organizational and personal) from different perspectives.


English and in one Indian language, and make meaning of the world by connecting people, ideas, books, media

and technology.







development.


the broadest context socio-technological changes.


Department of Biosciences

Course Hand-out

Biology for Chemists| BS 2103 | 2 Credits | 2 0 0 2

Session: Aug 16 – Nov 16 | Faculty: Dr. Singh Abhijeet | Class: Core course



environment.




D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20


In class Quizzes and Assignments and

Seminars

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Chemistry of Biological molecules: Amino acids, Proteins, Nucleic acids, Carbohydrates, Lipids,

Phospholipids, Membrane, Cells, Bioenergetics, Enzymes, Coenzymes/Cofactors, Kinetics, Role of metals,

Secondary Metabolites, Biogenesis, Applications & Relevance of Biomolecular Sciences in New

technologies

F. TEXT BOOKS

1 . Lehninger, A.L., Nelsen, D.L. Cox, M.M., Principles of biochemistry, W.H. Freeman, 2004.

2. Whitemore G., Biology for Chemists, Saujanya Publications, New Delhi, 2006.

G. REFERENCE BOOKS

1. J.M. Berg, JL Tymoczko and L Stryer. Biochemistry, W.H. Freeman Publishers, USA, 2010.

H. Lecture Plan:

LEC

NO

TOPICS

1. Cell: history, cell theory and types

2. Comparative study of structure of Prokaryotic and Eukaryotic cells

3. Cell organelles: structure and role in normal functioning of cell

4. Tutorial

5. Biomolecules: introduction and history

6. Amino acids & proteins: types, structures and functions

7. Carbohydrates: classification, structure, functions

8. Tutorial

9. Lipids: types, structure and functions

10. Nucleic acids: types, structure and functions

11. Bioenergetics: laws of thermodynamics

12. Tutorial

13. Enzyme: coenzymes, cofactors, classification

14. Enzyme kinetics: Michaelis-Menten equation

15. Examples and application of enzymes in food, agriculture, medicine industries, etc.

16. Tutorial

17. Metabolism: introduction, types and importance

18. Primary metabolites: types, synthesis and commercial importance

19. Secondary metabolites: types, synthesis and commercial importance

20. Tutorial

21. Biotechnological tools & techniques: introduction

22. Applications of biotechnological tools in food, agriculture and medicinal industries.

23. Examples of commercial products developed using biotechnological approach.

24. Tutorial


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


[BS 2103.1]. Biomolecules: types, structure, functions in cellular life and importance in

context with day to day life.

2 1 2 1 1 2

[BS 2103.2]. Cell: types, structure and functions of different cell organelles. Comparative

microscopic study of different types of cells.

1 1

[BS 2103.3]. Bioenergetics: laws of thermodynamics w.r.t. the living system and their

importance

1 1

[BS 2103.4]. Enzymes: concept of coenzymes & cofactors, kinetics, mode of action,

classification and role in different biological processes

1 2 2 2 2 2 1

[BS 2103.5]. Metabolites: primary and secondary, economically important metabolites

and their applications in food, agriculture, medicine and industry.

1 1 2 2 1 2 1 2 1

[BS 2103.6]. Modern tools and techniques of biotechnology: principles, working and

applications

1 1 1 2 1 1 1


A. Introduction: This course is offered by Dept. of Mathematics & Statistics in I Semester of M. Sc. (Chemistry) for the

students of Biology group. The objective is to develop basic computing skills and application of quantitative and statistical

operations required for biological studies and rationalization of experimental designs.


[2120.1] Acquire mathematical concepts in continuous learning and connecting ideas like numerical analysis, calculus and

coordinate geometry to other subjects.

[2120.2] Understand the basic computing skills and statistical operations.

[2120.3] Support learning through applications of mathematics.

C. Program outcomes and Program specific outcomes:

[PO.1] Critical Thinking: Take informed actions after identifying the assumptions that frame our thinking and actions,



[PO.2] Effective Communication: Speak, read, write and listen clearly in person and through electronic media in


technology.

[PO.3] Social Interaction: Elicit views of others, mediate disagreements and help reach conclusions in group settings.

[PO.4] Effective Citizenship: Demonstrate empathetic social concern and equity centred national development, and


[PO.5] Ethics: Recognize different value systems including your own, understand the moral dimensions of your


[PO.6] Environment and Sustainability: Understand the issues of environmental contexts and sustainable

development.

[PO.7] Self-directed and Life-long Learning: Acquire the ability to engage in independent and life-long learning in


[PSO.1] Develop knowledge, understanding and expertise in their chosen field of chemical science.

[PSO.2] Develop an understanding of eco-friendly chemical processes and impact of chemistry on health and

environment.

[PSO.3] Understand theoretical concepts of instruments that are commonly used in most chemistry fields as well as


[PSO.4] Provide opportunities to excel in academics, research or Industry


Department of Mathematics & Statistics

Course Hand-out

Mathematics for Chemists MA2120 | 2 Credits | 2 0 0 2

Session: Jul 16 – Nov 16 | Faculty: Dr Reema Jain

D. Assessment Plan:

E. Syllabus

Basic Trigonometry; Basic Coordinate Geometry: Cartesian and polar coordinates; Functions, limits, continuity, Differential and

Integral calculus, Differential equations; Arithmetic and Geometric progression series: Binomial theorem; Permutations and

Combinations; Probability and Statistics.

F. Text Books

1. Chandrika Prasad, Text book on Differential Calculus & elementary differential equations, Pothishala, 2006.

2. Mario F.Triola, Elementary Statistics, 9th Updated Edition, 2004.

3. Shanti Narayan, Integral Calculus , S.Chand, 2005.

G. Reference Books

1. Mortimer, R., Mathematics for Physical Chemistry, Academic Press, 2005.

2. Cockett, M., Doggett, G., Mathematics for Chemists, Vol 1, 2, Royal Society of Chemistry, UK, 2003.

3. Yates, P., Chemical calculations – Mathematics for Chemistry, Chemical Rubber Company (CRC) Press, 2007.

4. Loney, S.L., Trigonometry, Gk Publisher, 2005.

H. Lecture Plan

Lecture No. TOPICS

1 Introduction and significance of course

2-4 Basic Trigonometry

5-6 Basic Coordinate Geometry

7-9 Cartesian and polar coordinates

10-13 Functions, limits, continuity

14-16 Basic differentiation and integration

17-19 Differential equations


Internal Assessment

(Summative)





Averaged)

10

End Term Exam

(Summative)


Total 100

Attendance

(Formative)




Homework/ Home

Assignment/ Activity

Assignment

(Formative)





will be awarded.

20-21 Arithmetic and Geometric progression series

22-23 Binomial theorem

24-27 Permutations and Combinations

28-30 Probability and Statistics


CO

STATEMENT


OUTCOMES

CORRELATION WITH

PROGRAM SPECIFIC

OUTCOMES


MA2120.1 Acquire mathematical concepts in continuous

learning and connecting ideas like numerical

analysis, calculus and coordinate geometry to

other subjects.

2 3 2 2

MA2120.2 Understand the basic computing skills and

statistical operations.

2 2 2 2 2

MA2120.3 Support learning through applications of

mathematics

2 1 2 2 2


A. Introduction: This course is offered by Department of Languages to the students of MSc, in the 1 Semester. The

course is designed to help students across different disciplines, to improve their written and oral communication

skills. The focus is on honing the skills of reading, writing, listening, and speaking. By providing suitable examples,

the students will be exposed to various forms of personal and professional communication. The self-learning tasks

will facilitate to enhance effective communication skills in a modern & globalized context


[2111.1] Show a vital awareness of interpersonal communication skills and use verbal and non-verbal expression

with ease and confidence

[2111.2] Practice the unique qualities of professional rhetoric and writing style, such as sentence conciseness,

clarity, accuracy, honesty, avoiding ambiguity, using direct order organization, readability, coherence and transitional

devices.

[2111.3] Demonstrate competence in interactive speaking in both informal and simulated formal situations

[2111.4] Employ a range of communication skills and tools with sophistication and understanding to present and

engage with complex and challenging ideas

[2111.5] Compare and contrast systematic differences in syntax, semantics, and pragmatics of English language.


[PO.1]. Critical Thinking: Explore, explain and critically evaluate how literary texts and the language in which

they are written shape perceptions of students’ understanding of social realities and their own selves.

[PO.2]. Effective Communication: Articulate ideas and perspectives, by developing and enhancing the

communicative skills of listening, speaking, reading, and writing in interpersonal and interactive contexts, in print and in

electronic media, for various audiences and purposes.

[PO.3]. Social Interaction: Develop competence in understanding, appreciating, and respecting social diversity

derived from the representation of points-of-view in literary texts, thereby facilitating conflict resolution, and social

harmony.

[PO.4]. Effective Citizenship: Inculcate values of patriotism and of unity, and transfer these values to real-life

through selfless volunteering and activism, for promoting community welfare.

[PO.5]. Ethics: Recognise the diversity and complexity of ethical dilemmas in the real world, and educate oneself to

base ones actions on responsibility, and respect for human rights.

MANIPAL UNIVERSITY JAIPUR School of Humanities and Social Sciences

DEPARTMENT OF LANGUAGES

Course Hand-out

COMMUNICATIONS SKILLS & TECHNICAL PAPER WRITING| EN 2111 | 3 Credits | 3 0 0 3

Session: July 17 – Dec 17 | Faculty: Prof Richa Arora | Class: MSc I SEM

[PO.6]. Environment and Sustainability: Study and understand Nature and the environment on the basis of

important literary texts and researches, so as to initiate responsible individual and collective action, towards sustaining

our shared environment.

[PO.7]. Self-directed Life-long Learning: Taking initiatives and challenges to choose learning opportunities and

programmes, implementing learning goals, and sustaining intellectual growth and excellence in a constantly changing

global scenario.




environment.




D. Assessment Plan:


Internal Assessment

(Summative)





Averaged)

10

End Term Exam

(Summative)


Total 100

Attendance

(Formative)




Make up Assignments

(Formative)

Students who misses a class will have to report to the teacher about the absence.

A makeup assignment on the topic taught on the day of absence will be given which

has to be submitted within a week from the date of absence. No extensions will be

given on this. The attendance for that particular day of absence will be marked

blank, so that the student is not accounted for absence. These assignments are

limited to a maximum of 5 throughout the entire semester.


Activity Assignment

(Formative)

There are situations where a student may have to work at home, especially before




will be awarded.

E. SYLLABUS

Grammar: Conditionals/Tenses, relative clauses, subject–verb agreement, passive voice; Written communication: Discuss

a topic of general interest, but related to science in about 300 words. (Analyze, comment, argue, reflect, persuade, etc; Oral

Communication: (i) Consulting a dictionary for correct pronunciation (familiarity with phonetics symbols and stress-marks

only) (ii) Dialogue; Scientific writing: Writing a Scientific Report on a project undertaken or an experiment conducted (theory

+ practice); Soft Skills: Gestures/ postures – Body language, gesture, posture; Presentation skills: (i) How to make power

point presentation (ii) Body language during presentation (iii) Resume writing (tailor made); Mock Interview: Each student to

face an interview and to demonstrate the above taught skills.

F. /G. TEXT BOOKS/ Reference Books

1. Quirk, R, Greenbaum, S., Advanced English Usage, Pearson Education 2005.

2. Banerjee, M., Mohan, K., Developing Communication Skills, Macmillan Publications, 2010.

3. Chaturvedi, P.D., Business Communication, Pearson Publications, 2011.

4. Mathew, M.J., Business Communication; RBSA Publications, 2011.

5. John Seely, The Oxford Guide to Writing and Speaking, New Delhi: Oxford UP, 2004.

6. T Balasubramaniam, A Textbook of English Phonetics for Indian Students, New Delhi: Macmillan, 2010.

H. Lecture Plan:

LEC NO TOPICS

1 Introduction and Course Hand-out briefing

2 & 3 Communication- Types & Barriers

4-6 Communication Cycle, Formal & Informal Communication

7 & 8 Oral Communication

9 & 10 Classroom activity

11 & 12 What is Grammar? Linguistics versus traditional Grammar

13-17 Symbols for the sounds of English and phonemic transcription

17-21 Description of vowels and consonants of English language

22 Introduction to Technical Writing

23 Report Writing –Introduction

24 Report Writing –Types

25-27 Resume Writing, Difference between Resume, CV & Bio-Data

28-29 Soft Skills- Introduction, Body language, gesture, posture

30 GD

31-36 Presentation Skills, Mock Interview, GDs

37-41 REVISION

I. Course Articulation Matrix: (Mapping of COs with POs & PSOs)

1-Low Correlation; 2- Moderate Correlation; 3- Substantial Correlation

CO STATEMENT Correlation with Program Outcomes (POs) Correlation with Program Specific

Outcomes (PSOs)

PO1 PO2 PO3 PO4 PO5 PO6 PO7 PSO 1 PSO2 PSO3 PSO4

EN 2111.1

To show a vital awareness of interpersonal

communication skills and use verbal and non-verbal

expression with ease and confidence

2 2 3 2 2 2

EN 2111.2

Practice the unique qualities of professional rhetoric

and writing style, such as sentence conciseness,

clarity, accuracy, honesty, avoiding ambiguity, using

direct order organization, readability, coherence and

transitional devices

2 2 3 2 1 2

EN 2111.3

Demonstrate competence in interactive speaking in

both informal and simulated formal situations

2 2 2 2 1

EN 2111.4

Employ a range of communication skills and tools

with sophistication and understanding to present and

engage with complex and challenging ideas

2 2 2 1 1

EN 2111.5

Compare and contrast systematic differences in

syntax, semantics, and pragmatics of English language.

1 2 2 1 1

A. Introduction: This course is offered by Dept. of Chemistry for 2nd Semester M. Sc. students. The objective of the

course is to acquaint the students with the advanced concepts of chemistry related to Transition metals. The

student with the knowledge of the advanced knowledge will be able to explain scientifically various transition

metal chemistry related problems, which in turn help in life-long self learning.


[CY2211.1]. Define various aspects, like Nomenclature and stereochemistry of transition metal complexes.

[CY2211.2]. Explain the different theories of bonding involving metal complexes.

[CY2211.3]. Apply knowledge of metal-ligand bond interaction in explaining reactions of metal complexes.

[CY2211.4]. Explain magnetic properties of transition metal complexes.

[CY2211.5]. Analyze modes of bonding in metal-metal multiple bonds and poly-ions.

[CY2211.6]. Design and use new metal complex in environment friendly method.







technology.







development.






environment.






Course Hand-out

Chemistry of Transition Metal | CY2211| 3 Credits | 2 1 0 3

Session: Jan 17 – May 17 | Faculty: Arunava Agarwala | Class: 2nd Semester M. Sc. (Chemistry)

D. Assessment Plan:


Internal Assessment

(Summative)



Assignments and Class tests


10

End Term Exam

(Summative)


Total 100

Attendance

(Formative)





Activity Assignment

(Formative)

There are situations where a student may have to work in home. Although these

works are not graded with marks. However, a student is expected to participate

and perform these assignments with full zeal since the activity will help the

students in developing better understanding.

E. SYLLABUS

Metal-Ligand bonding: Nomenclature and stereochemistry of compounds, Valence Bond Theory (VBT), Crystal field theory

(CFT), Crystal field stabilization energy (CFSE), Molecular orbital theory of octahedral, tetrahedral and square planar

complexes; Metal ligand equilibrium in solution: Factors affecting stability of metal complexes with reference to the

nature of metal ion and ligand chelate effect and its thermodynamic origin; Electronic spectra of transition metal

complexes: Types of electronic transition, selection rules for d-d transitions; Magnetic properties of transition metals:

Origin of magnetic moment, spin contribution, spin only formulas, orbital contribution, spin-spin coupling; Reaction

mechanism of transition metal complexes: Energy profile of a reaction, reactivity of metal complex, inert and labile

complexes; Compounds with metal-metal multiple bonds and Poly-ions: Metal carboxylate and halide compounds

with metal –metal multiple bonds.

.

F. TEXT BOOKS

A book or a set of books which covers 60% or more of the syllabus can be written under this category. (Not more than 3)

T1. Lee, J. D., Concise Inorganic Chemistry. ELBS Publication, 2010.

T2. Sarkar, R . General and Inorganic Chemistry, New Central Book Agency (P) Ltd. 2014.

T3. Shriver & Atkins’ Inorganic Chemistry, Oxford University Press

G. REFERENCE BOOKS

R1. Cotton F. A. and Wilkinson, G. Advanced Inorganic Chemistry, John Wiley, 2011.

R2. Huhey, J. E., Inorganic chemistry: principles of structure and reactivity. Harper and Row, 2010

H. Lecture Plan:

Lecture

number

Topics

1 Warner’s theory related to Coordination compounds

2 Deferent methods of detection of metal complexes.

3 Valence Bond Theory (VBT) for Metal complexes

4 Crystal Field Theory (CFT): introduction

5 Splitting in Octahedral field

6 Splitting in Square planar field

7 Splitting in Tetrahedral field

8 Comparison of splitting of d orbital degeneracy in different fields

9 Factors effecting d-orbital (Strong field ligand and weak field ligand)

10 Evaluation of Δo value through spectroscopy.

11 Calculation of magnetic moment for different complexes

12 Concepts of different types of ligands

13 Isomerism in metal complexes.

14 Revision

15 Kinetics of formation of metal complex

16 Thermodynamics of formation of metal complex

17 Factors affecting stability of metal complexes: General

18 Factors affecting stability of metal complexes: With respect to metal ion

19 Factors affecting stability of metal complexes: With respect nature of ligands.

20 Discussion of chelate effect.

21 Electronic spectra of transition metal complexes: Introduction

22 Types of electronic transition

23 Contd. Types of electronic transition

24 Selection rule in electronic transition

25 Contd. Selection rule in electronic transition

26 selection rules for d-d transitions

27 Methods of detection of spectroscopic transition

28 Tanabe -Sugano Diagram

29 Contd. Tanabe -Sugano Diagram

30 Revision

31 Magnetic properties of transition metals: Introduction

32 Origin of magnetic moment, Experimental determination of magnetic moment.

33 Spin contribution, orbital contribution

34 Reaction mechanism of transition metal complexes

35 Reactivity of metal complexes

36 Contd. Reactivity of metal complexes

37 Labile metal complexes

38 Inert metal complexes

39 Trans effect

40 Metal carboxylate Metal-Metal multiple bond.

41 Metal Halide Metal-Metal multiple bond.

42 Revision


CO

STATEMENT




CY 2211.1 Define various aspects, like Nomenclature and

stereochemistry of transition metal complexes

3 2 1 1 2 3 3 2 1 2

CY 2211.2 Explain the different theories of bonding involving

metal complexes

2 1 2 1 3 2 3 2 2 3

CY 2211.3 Apply knowledge of metal-ligand bond interaction

in explaining reactions of metal complexes

3 2 1 2 2 3 3 1 1 3

CY 2211.4 Explain magnetic properties of transition metal

complexes

3 2 1 1 3 3 3 1 1 2

CY 2211.5 Analyse modes of bonding in metal-metal multiple

bonds and poly-ions

3 2 1 1 2 2 3 2 2 2

CY 2211.6 Design and use new metal complex in

environment friendly method

2 1 1 2 3 3 3 1 1 3



emphasis on fundamental understanding of Quantum chemistry, electrochemistry and chemical kinetics. The course

explains Schrödinger equation, electrical double layer and advanced chemical kinetics topics. Students are expected

to have background knowledge in physical chemistry up to the undergraduate level for this course.


[2212.1]. Understand the differential equation and Schrödinger equation.

[2212.2]. Discuss the electrical double layer and metal/electrolyte interface.

[2212.3]. Learn about kinetic equivalence terms and theories of reaction rates.

[2212.4]. Discuss the Elementary gas phase reactions and Fast reaction kinetics.

[2212.5]. Understand the Chain reactions, Acid Base Catalysis

[2212.6]. Discuss Physical and Chemical adsorption and adsorption isotherms









settings.



volunteering.




development.





and environment.






Course Hand-out

Quantum chemistry, electrochemistry and chemical kinetics | CY2212 | 3 Credits | 2 1 0 3


D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Quantum Chemistry: Solution of differential equations by power series method, Solution of the Schroedinger

equation for the hydrogen atom; Electrochemistry: Metal/Electrolyte interface, Structure of the double layer,

Fundamental of electrolytic corrosion, Chemical Kinetics: order or reaction, kinetic equivalence terms, Theory of

reaction rates, Elementary gas phase reactions, Fast reaction kinetics, Chain reactions, Acid Base Catalysis, Kinetics

in the excited electronic states, Physical and Chemical adsorption, adsorption isotherms, Langmuir Hinshelwood and

Eley Rideal mechanisms, Heat of adsorption Kinetics of solid state reactions.

F. TEXT BOOKS

1. Laidler, K.J., Chemical Kinetics, Harper and Row, New York, 3rd Edition, 2007.

2. Pilling, M.J., Seakins, P.W., Reaction Kinetics, Oxford Univ. Press, 2nd Edition, 2009.

G. REFERENCE BOOKS

1. Rajaram, J., Kuriacose, J.C., Kinetics and Mechanism of Chemical Transformations, Macmillan India, 2012.

2. Billing, G.D., Mikkelsen, K.V., Introduction to Molecular Dynamics and Chemical Kinetics, John Wiley, 2012.

H. Lecture Plan:

Lecture

No.

Topics

1 Introduction: Quantum chemistry, differential equation

2 Solution of differential equation by power series method

3 Wave theory of matter, Heisenberg’s uncertainty principle

4 Schrödinger equation

5 Eigen values and eigenfunctions

6 Revision

7 Postulates of quantum mechanics

8 Solution of the Schrödinger equation for the hydrogen atom

9 Electrochemistry of solutions

10 Metal/electrolyte interface

11 Electrical double layer: structure of double layer

12 Revision

13 Helmholtz-Perrin theory

14 Gouy-Chapman theory

15 Stern theory

16 Overpotential, overvoltage

17 Revision

18 Corrosion, introduction and types

19 Electrolytic corrosion, fundamentals and principles

20 Factors affecting and control

21 Galvanization

22 Revision

23 Chemical Kinetics: Introduction, reaction rates

24 Order and molecularity of reaction, difference, pseudo-molecular reaction

25 Methods of determining rate laws

26 Determination of order of a reaction

27 Rate law: Zero order and first order reaction

28 Rate law: second order and nth order reaction

29 Revision

30 Theories of reaction rates: Collision theory

31 Collision theory of unimolecular reactions, Lindmann’s theory, Steric factor

32 Theory of absolute reaction rates, activated complex theory

33 Arrhenius equation, activation energy and chemical reactions

34 Revision

35 Fast reactions: Kinetics of fast reactions, chemical relaxation method, relaxation time

36 Flash photolysis method, Flow method, Nuclear magnetic resonance method

37 Chain reactions: kinetics of thermal hydrogen-bromine reaction and photochemical hydrogen-

bromine reaction

38 kinetics of decomposition of ethane

39 Kinetics of homogeneous catalysis-acid base catalysis

40 Kinetics of heterogeneous catalysis

41 Physical and chemical adsorption: Langmuir Hinshelwood and Eley Rideal mechanisms

42 Heat of adsorption kinetics of solid state reactions

43 Revision


CO

STATEMENT




CY 2212.1 Understand the differential equation and

Schrödinger equation.

3 1 2 2 1

CY 2212.2 Discuss the electrical double layer and

metal/electrolyte interface

2 3 1

CY 2212.3 Learn about kinetic equivalence terms and

theories of reaction rates

2 1 2 3 1

CY 2212.4 Discuss the Elementary gas phase reactions and

Fast reaction kinetics

2 2 2 1

CY 2212.5 Understand the Chain reactions, Acid Base

Catalysis

1 1 1

CY 2212.6 Discuss Physical and Chemical adsorption and

adsorption isotherms

2 2 2 2 1 2 2



emphasis on fundamental understanding of synthesis and reactivity of alkene and alkyne. The course explains detail

about reactivity of carbonyl compound and their synthetic utility.

Alkenes and alkynes: Synthesis of alkenes and alkynes, Reactions of alkenes and alkynes;

Carbonyl compounds: Modern methods of synthesis from alcohols, Reactions of carbonyl compounds, addition of

N, O, and S nucleophiles, emphasis on synthetic utility of these reactions, rearrangement reactions involving electron

deficient carbon, nitrogen, oxygen centers, the synthetic utility of these rearrangements.


[2213.1]. Understand the reactivity of alkenes

[2213.2]. Learn about synthesis and chemical properties of alkyne.

[2213.3]. Discuss the carbonyl compounds and their derivatives.

[2213.4]. Learn about the addition of N, O, and S nucleophiles to carbonyl compounds.

[2213.5]. Learn about the rearrangement reactions.

[2213.6]. Synthetic utility of these rearrangements.









settings.



volunteering.




development.





and environment.






Course Hand-out

ADVANCED ORGANIC CHEMISTRY OF MULTIPLE BONDS | CY 2213 | 3 Credits | 2 1 0 3

Session: Jan 16 – July 16 | Faculty: Dr. Rahul Shrivastava | Class: Core Subject; MSc

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Alkenes and alkynes: Synthesis of alkenes and alkynes, Reactions of alkenes and alkynes;

Carbonyl compounds: Modern methods of synthesis from alcohols, Reactions of carbonyl compounds, addition of

N, O, and S nucleophiles, emphasis on synthetic utility of these reactions, rearrangement reactions involving electron

deficient carbon, nitrogen, oxygen centers, the synthetic utility of these rearrangements.

F. TEXT BOOKS

Carey, F. A., Sundberg, R. I. , Advanced Organic Chemistry, Part A and B, 3rd edition, Plenum Press, New York,

2010.

March, J., Advanced Organic Chemistry, 4th edition, Wiley Interscience, 2011

G. REFERENCE BOOKS

Bruckener, R., Advanced organic chemistry: Reaction mechanism, Elsevier, 2009.

Singh, M.S., Advanced organic chemistry: Reactions and mechanism, Pearson Education, 2014.1. Atkins P.W., Paula,

J. De, Physical Chemistry, W.H. Freeman, 2012

H. Lecture Plan

Lecture

number

Topics

1 - 7 Synthesis, physical and chemical properties of alkenes and their derivative

8 - 15 Synthesis, physical and chemical properties alkynes and their derivatives

16-22 Synthesis, physical properties and chemical reactions aldehydes and

ketones and their derivatives.

23-28 Synthesis, physical properties and chemical reactions of unsaturated

aldehydes and ketones and their derivatives.

29-34 Synthesis, physical properties and chemical reaction of carboxylic

acids and their derivatives.


CO

STATEMENT


SPECIFIC OUTCOMES


CY 2213.1 Understand the reactivity of alkenes

1 1 2 1 2

CY 2213.2 Learn about synthesis and chemical properties

of alkyne.

1 1 2 2 1 2

CY 2213.3 Discuss the carbonyl compounds and their

derivatives.

2 1 2 1

CY 2213.4 Learn about the addition of N, O, and S

nucleophiles to carbonyl compounds.

2 1 2 1

CY 2213.5 Learn about the rearrangement reactions. 1 1 1 1

CY 2213.6 Synthetic utility of these rearrangements.. 1 1 1 1


A. Introduction: This course is offered by Dept. of Chemistry as a post-graduate course. Spectroscopy is the study of

the interaction between matter and electromagnetic radiation. The structures in chemistry are symbols representing

real existence of the compounds that form the substance of study in organic chemistry. The student had in the course

of the study of organic chemistry written many structures without asking how the structures had come to be. This

course offers the student the opportunity to learn and appraise the use of spectroscopic instruments in the

determination of the structures of organic compounds. The instruments include: UV, IR, NMR, and MS. The student

shall learn the theory of the various instruments and the interpretation of spectra.


[2214.1] Understand the basic concept of different Spectroscopic techniques

[2214.2] Know the application of spectroscopic techniques

[2214.3] Understand the usage of different spectroscopic techniques to determine the molecular structure and

constant

[2214.4] Demonstrate a working knowledge of mass spectroscopy (MS), ultraviolet-visible (UV-Vis) spectroscopy,

infrared (IR) spectroscopy, and nuclear magnetic resonance (NMR) spectroscopy

[2214.5] Elucidate the structures of organic molecules from spectral data



actions, checking out the degree to which these assumptions are accurate and valid, and looking at our ideas

and decisions (intellectual, organizational, and personal) from different perspectives.





settings.







development.



Course Hand-out

Spectroscopy-Application in Organic and Inorganic Chemistry | CY 2214 | 3 Credits | 2 1 0 3

Session: Jan 17 – May 17 | Faculty: Dr Rama Kanwar | Class: M.Sc. (II Sem.)

Session: Jan 17 – May 17 | Faculty: Vinoth R | Class: Open Elective





environment.

[PSO.3]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields as


[PSO.4]. Provide opportunities to excel in academics, research or Industry.

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I (Close Book) 20

Sessional Exam II (Close Book) 20



Averaged)

10

End Term Exam

(Summative)

End Term Exam (Close Book) 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

UV-VIS spectroscopy: Electronic levels and types of electronic transitions in organic, inorganic and

organometallic systems, UV spectra of aromatic and heterocyclic compounds; IR and Raman spectroscopy: FT

technique, group frequencies, vibrational coupling, Raman spectroscopy; Mass spectrometry: Ion production: EI, CI,

FD, FAB, Ion analysis techniques; Nuclear Magnetic Resonance Spectroscopy: NMR phenomenon, spin ½ nuclei,

1H, 13C, 19F and 31P, Zeeman splitting; ESR spectroscopy: ESR phenomenon, introduction to the ESR spectra of

organic free radicals and ion radicals, transition metal complexes, application of spin traps.

F. TEXT BOOKS

1. Fundamentals of molecular spectroscopy by Colin N. Banwell, Elaine M. McCash. McGraw Hill Education

2. Elementary Organic Spectroscopy by Y R Sharma, S. Chand Publishing.

3. Introduction to Spectroscopy Author(s): Donald L. Pavia, Gary M. Lampman, George S. Kriz, Cengage Learning

publisher

G. REFERENCE BOOKS

1. Silverstein, R. M., Bassler, G. C., Morril, T.C., Spectrometric Identification of Organic Compounds, John Wiley,

New York, 1991.

2. Kemp, W., Organic Spectroscopy, 2nd edition, ELBS Macmillan, Hongkong, 1987.

3. Ebsworth, E. A. V., Rankin, D. W. H., Cradock, S., Structural Methods in Inorganic Chemistry, Blackwell

Publications, ELBS, London, 1988.

https://www.goodreads.com/author/show/1000133.Colin_N_Banwell

https://www.goodreads.com/author/show/1000132.Elaine_M_McCash

H. Lecture Plan:

LEC

NO

TOPICS

1 UV-VIS spectroscopy: Introduction

2-4 types of electronic transitions in organic compounds

5,6 types of electronic transitions in inorganic compounds

7 types of electronic transitions in organometallic compounds

8 Woodward’s rule: Butadiene Systems

9 Woodward’s rule: α, β-unsaturated carbonyl Systems

10,11 UV spectra of aromatic compounds

12 UV spectra of heterocyclic compounds

13 IR spectroscopy: Introduction

14 FT technique

15 group frequencies

16, 17 vibrational coupling

18, 19 IR Spectra of organic compounds

20, 21 IR Spectra of inorganic compounds

22, 23 Raman spectroscopy: Introduction

24 Examples

25 Mass spectrometry: Ion production

26 EI (Electronic Ionization)

27 CI (Chemical ionization )

28 FD (Field desorption)

29 FAB (Fast atom bombardment)

30 Ion analysis techniques

31 Nuclear Magnetic Resonance Spectroscopy: NMR phenomenon

32 spin ½ nuclei

33 Coupling and coupling constant

34 1H NMR

35 13C NMR

36 19F NMR

37 31P NMR

38 Zeeman splitting

39 ESR spectroscopy: ESR phenomenon

40 introduction to the ESR spectra of organic free radicals

https://en.wikipedia.org/wiki/Field_desorption

https://en.wikipedia.org/wiki/Fast_atom_bombardment

41 ESR spectra of organic ion radicals

42 ESR spectra of transition metal complexes and application of spin traps


CO

STATEMENT


OUTCOMES

CORRELATION WITH PROGRAM SPECIFIC

OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


CY 2214.1 Understand the basic concept of

different Spectroscopic techniques

2 3 3 2

CY 2214.2 Know the application of spectroscopic

techniques

3 2 3

CY 2214.3 Understand the usage of different

spectroscopic techniques to determine

the molecular structure and constant

2 2 2 2

CY 2214.4 Demonstrate a working knowledge of

mass spectroscopy (MS), ultraviolet-

visible (UV-Vis) spectroscopy, infrared

(IR) spectroscopy, and nuclear magnetic

resonance (NMR) spectroscopy

2 2 2

CY 2214.5 Elucidate the structures of organic

molecules from spectral data

2 2 3 3


A. Introduction: This course is offered by Dept. of Chemistry. CY 2215 discusses the environment with a chemistry

perspective. It helps in developing an understanding of the chemical basis of environmental science.


[2215.1]. Demonstrate understanding of the general aspects of nature.

[2215.2]. Describe causes and effects of major environmental issues like climate change and measures adopted for

the mitigation of these issues.

[2215.3]. Recognize different types of toxicity in the environment and their control.

[2215.4]. Understand the importance of alternative clean fuels



actions, checking out the degree to which these assumptions are accurate and valid, and looking at our






settings.







development.



Program Specific Outcomes for M.Sc Chemistry Program

[PO.8]. PSO1. Develop knowledge, understanding and expertise in their chosen field of chemical science

[PO.9]. PSO2. Develop an understanding of eco-friendly chemical processes and impact of chemistry on health

and environment.

[PO.10]. PSO3. Understand theoretical concepts of instruments that are commonly used in most chemistry

fields as well as interpret and use data generated in instrumental chemical analyses.

[PO.11]. PSO4. Provide opportunities to excel in academics, research or Industry



Course Hand-out

Environmental Chemistry| CY 2215 | 3 Credits | 2 1 0 3

Session: Jan 17 – May 17 | Faculty: Dr. Nitu Bhatnagar | Class: M.Sc

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I (Open Book) 20

Sessional Exam II (Open Book) 20



Averaged)

10

End Term Exam

(Summative)

End Term Exam (Open Book) 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)

There are situations where a student may have to work in home, especially





E. SYLLABUS

General aspects of environment: Environmental components (atmosphere, hydrosphere, lithosphere and biosphere);

Environmental pollution: Types & classification of pollutants, Effects and control of air pollutants-Gaseous, particulates;

Greenhouse effect: Greenhouse gases - Major sources and effect, effect on global warming and agriculture; Ozone

depletion: Formation, reactions, role, and processes of ozone depletion, Consequences of ozone

depletion; Environmental toxicology: Introduction; threshold limiting value (TLV); Toxicity and control of

toxicants; Renewable energy: Alternative clean fuels- Solar, biomass energy, hydrogen, hydrothermal, geothermal, wind,

etc.; Climate change in future: Predictions, consequences. Mitigation and adaptation to climate change. Montreal

protocol 1987, Rio de Janeiro summit 92 Kyoto protocol 97, Johannesburg 2002, Copenhagen summit

2009.

F. TEXT BOOKS

1. Bharucha, E., Textbook of Environmental Studies for Undergraduate Courses, New Delhi and Bharati Vidyapeeth Institute of

Environmental Education and Research, Pune.

G. REFERENCE BOOKS

1. Manahan S. E., Environmental Chemistry, CRC Press, 2010

2. Baird, C., Cann, M., Environmental Chemistry, Fourth Edition;W.H. Freeman and Company, New York, 2008.

3. De, A.K., Environmental Chemistry, Fourth Edition; New Age International Pvt. Ltd., New Delhi, 2003.

H. Lecture Plan:

LEC NO TOPICS


2 Scope and importance of environmental chemistry

3,4 Environmental components: atmosphere, lithosphere, hydrosphere, biosphere

5,6 Types & classification of pollutants

7,8 Effects and control of air pollutants-Gaseous, particulates

9 Effects and control of water pollutants

10 Revision

11 Greenhouse gases - Major sources

12 Greenhouse gases: Effects

13 Effect on global warming and agriculture

14, 15 Ozone depletion: Formation, reactions

16,17 Role and processes of ozone depletion

18, 19 Consequences of ozone depletion

20 Environmental toxicology: Introduction

20 threshold limiting value (TLV)

21 Toxicity and control of toxicants

22 Revision

23 Renewable energy: Alternative clean fuels- Solar

24 biomass energy, hydrogen

25 hydrothermal, geothermal

26 wind

27 Climate change in future: Predictions, consequences

28,29 Mitigation and adaptation to climate change

30,31 Montreal protocol 1987

32,33 Rio de Janeiro summit 92

34,35 Kyoto protocol 97

36, 37 Johannesburg 2002

38, 39 Copenhagen summit 2009

40 Revision

41 Conclusion and Course Summarization


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


[2215.1]. Demonstrate understanding of the general

aspects of nature.

2 3 2 3

[2215.2]. Describe causes and effects of major

environmental issues like climate change and

measures adopted for the mitigation of these

issues.

2 3

[2215.3]. Recognize different types of toxicity in the

environment and their control.

3 2

[2215.4]. Understand the importance of alternative clean

fuels

3 2 3 2


A. Introduction: This course is offered by Department of Languages as an open elective to Post Graduate (PG)

students across all streams in Manipal University Jaipur, during even semester. The course offers an advanced and

in depth knowledge of English language skills as required in the professional world. It covers concepts across

various language skills like Listening, Speaking, Reading and Writing, apart from focus on correct usage and

vocabulary building. There is no specific prerequisite on the part of students for the course.


[2295.1] Develop an understanding of the mechanisms and processes involved in speaking and writing in a second

or foreign language i.e. English, that will help them later on in their professional careers.

[2295.2] Enhance their written and spoken English language skills for professional needs.

[2295.3] Demonstrate their understanding of grammar and presentation skills for effective communication.

[2295.4] Write well organized Self Introductions, CVs, Resume, and Preliminaries to Interviews.

[2295.5] Use enhanced reading abilities to increase vocabulary and gain deeper understanding by using context

clues.







technology.







development.



MANIPAL UNIVERSITY JAIPUR School of Humanities and Social Sciences

DEPARTMENT OF LANGUAGES

Course Hand-out

Professional Language Skills and Grammar Competence | EN 2295 | 3 Credits | 3 0 0 3

Session: Jan 2017 – May 2017 | Faculty: Dr Arun Kumar Poonia | Class: PG OPEN ELECTIVE: EVEN SEMESTER



environment.




D. Assessment Plan:


Internal Assessment

(Summative)





Averaged)

20

End Term Exam

(Summative)


Total 100

Attendance

(Formative)




Make up Assignments

(Formative)

Students who misses a class will have to report to the teacher about the absence.

A makeup assignment on the topic taught on the day of absence will be given

which has to be submitted within a week from the date of absence. No

extensions will be given on this. The attendance for that particular day of absence

will be marked blank, so that the student is not accounted for absence. These

assignments are limited to a maximum of 5 throughout the entire semester.


Activity Assignment

(Formative)

There are situations where a student may have to work at home, especially





E. SYLLABUS

Writing Skills: Principles of Written Communication, Techniques of Paragraph Writing, Structure and Format of

Letter Writing, Writing CV or Resume, Writing preliminaries for an Interview; Usage of Grammar: Basic &

Advanced Grammar, Functional Grammar, Kinds of Grammar, Syntax and Synthesis, Fluency vs Accuracy,

Vocabulary tests: synonyms, antonyms, idioms/phrases, words often confused and misused, Error detection and

word usages, Sentence Patterns, Question Tags, Spellings and word meanings, Comprehension Test ability;

Language Competence: Extempore Sessions, Effective Self Introduction, Mock Sessions, Presentations.

F. /G. TEXT BOOKS/ Reference Books

1. Bovee, Courtland, L., John V. Thill and Barbara E. Schatzman. Business Communication Today. Seventh Edition. New

Delhi: Pearson Education, 2004.

2. Ehrlich, Eugene. English Grammar. New Delhi: McGraw Hill, 2005.

3. Halliday, M.A.K. Introduction to Functional Grammar. London: Arnold, 2013.

4. Koneru, Aruna. Professional Communication. New Delhi: Tata McGraw Hill, 1998.

5. Krishnaswamy, N. Modern English: A Book of Grammar Usage and Composition. New Delhi: Macmillan India, 2000.

6. Lesikar, Raymond V. and Marie E. Flatley. Basic Business Communication: Skills for Empowering the Internet Generation.

New Delhi: Tata McGraw-Hill, 2002.

7. Pease, Allan and Barbara Pease. The Definitive Book of Body Language. New Delhi: Manjul Publishing House, 2005.

8. Raman, Meenakshi and Sangeeta Sharma. Technical Communication: Principles and Practice 2/e. New Delhi: Oxford

University Press, 2013.

9. Sethi, A. Handbook of Standard English and Indian Usage. New Delhi: Prentice Hall, 2007.

H. Lecture Plan:

LEC NO TOPICS


2 Writing Skills: Principles of Written Communication

3-4 Techniques of Paragraph Writing

5 Structure and Format of Letter Writing

6-10 Writing CV or Resume

11-12 Writing preliminaries for an Interview

13 Usage of Grammar: Basic & Advanced Grammar

14 Functional Grammar, Kinds of Grammar

15 Syntax and Synthesis

16 Fluency vs Accuracy

17-20 Vocabulary tests: Spellings and word meanings, synonyms, antonyms, idioms/phrases,

words often confused and misused

21-22 Error detection and word usages

23-25 Sentence Patterns, Question Tags

26-30 Comprehension Test ability

31 Language Competence: Effective Self Introduction

32-34 Extempore Sessions , Mock Sessions

35-42 Presentations


1-Low Correlation; 2- Moderate Correlation; 3- Substantial Correlation

CO STATEMENT Correlation with Program Outcomes (POs) Correlation with Program Specific

Outcomes (PSOs)

PO1 PO2 PO3 PO4 PO5 PO6 PO7 PSO1 PSO 2 PSO 3 PSO 4

EN 2295.1

Develop an understanding of the mechanisms and processes

involved in speaking and writing in a second or foreign

language i.e. English, that will help them later on in their

professional careers.

1 1 2

EN 2295.2

Enhance their written and spoken English language skills for

professional needs.

1 1 1

EN 2295.3

Demonstrate their understanding of grammar and

presentation skills for effective communication.

3

EN 2295.4

Write well organized Self Introductions, CVs, Resume, and

Preliminaries to Interviews.

1 2 1

EN 2295.5

Use enhanced reading abilities to increase vocabulary and

gain deeper understanding by using context clues.

1

A. Introduction: This course is offered by Dept. of Civil Engineering as an open elective course, targeting M.Tech and

M.Sc. students who want to pursue higher studies in the field of environmental engineering, including environment

economics and environment management system. Offers in depth knowledge of management of natural resources

and conservation of biodiversity by covering various acts to protect the environment. Students are expected to have

background knowledge of basics science for a better learning.

B. Course Outcomes: At the end of the course, students will be able to:

[1691.1]. Apply the knowledge about the basic fundamentals of science, ecology and ecosystem to protect the

environment to promote sustainable development

[1691.2]. Understand the basic concept of ecosystem and identify the problems mainly responsible for

environmental degradation.

[1691.3]. Development of solution to protect the biodiversity by using different techniques.

[1691.4]. Economic analysis of the natural environment by using model with proper understanding the limitations

of the analytical tool.

[1691.5]. Investigate the impact of various anthropogenic activity in societal and environmental context. Students

can demonstrate the knowledge in terms of design reports and give presentations on various topics of environmental

concern with effective communication.







technology.






[PO.6]. Environment and Sustainability: Understand the issues of environmental contexts and sustainable development.



[PO.8]. Develop knowledge, understanding and expertise in their chosen field of chemical science.

[PO.9]. Develop an understanding of eco-friendly chemical processes and impact of chemistry on health and

environment.

[PO.10]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields as well as


[PO.11]. Provide opportunities to excel in academics, research or Industry

MANIPAL UNIVERSITY JAIPUR School of Civil and Chemical Engineering

Department of Civil Engineering

Course Hand-out

Environmental Engineering | CV 2291| 3 Credits | 3 0 0 3

Session: January 17 – July 17 | Faculty: Mr. Anil Dutt Vyas | Class: Open Elective

D. Assessment Plan:


Internal Assessment

(Summative)



In class Quizzes and Assignments , Activity

feedbacks (Accumulated and Averaged)

10

End Term Exam

(Summative)


Total 100

Attendance

(Formative)




Homework/ Home


Assignment

(Formative)





will be awarded.

E. SYLLABUS

Environmental Economics:

Introduction, Economic Tools for Evaluation, Cleaner Development Mechanisms (CDM) and their Applications;

Environmental Laws and Policies:

Water Act, Air Act, Environment Protection Acts, Solid Waste Management Rules, Hazardous and Biomedical Waste Rules;

Environmental Audit:

Methods, Procedure, Reporting and Case Studies;

Environmental Management System and Techniques:

Environmental Safety and ISO 14000 Standards, ISO 14001 Standards, Environmental Management Systems, (EMS) Total

Quality Management (TQM) and Total Safety Management (TSM), ISO 9000 and ISO 18000 Standards.

F. TEXT BOOKS

1. B.N. Lohani, “Environmental Quality Management”, South Asian Publishers, New Delhi, 1984.

2. Chanlett, “Environmental Protection”, McGraw Hill Publication, Newyork, 1973.

3. G.E. Danoy and R.F. Warner, “Planning and Design of Engineering Systems”, Unwin Hyman Publications, 1969.

G. REFERENCE BOOKS

1. MOEF, Government of India, “Carrying Capacity Based Developmental Planning Studies for the National Capital

Region”, 1995-96.

2. NEERI, Nagpur, Annual Reports, 1995 & 1996.

3. UNEP / UNDP – Environmental Sustainable Development.

4. T.V. Ramachandra & Kulakarni, “Environmental Laws – MOEF”, Government of India.

H. Lecture Plan:

Lesson

Plan

Topics

L1 Environmental Economics: Introduction,

L2 Economic Tools for Evaluation,

L3 Cleaner Development Mechanisms (CDM)

L4 CMD Applications;

L5 Environmental Laws and Policies: Water Act,

L6 Air Act,

L7 Environment Protection Acts,

L8 Environment Protection Acts,

L9 Solid Waste Management Rules,

L10 Solid Waste Management Rules

L11 Hazardous and Biomedical Waste Rules;

L12 Hazardous and Biomedical Waste Rules;

L13 Environmental Audit: Methods,

L14 Environmental Audit: Methods

L15 Procedure,

L16 Reporting

L17 Case Studies;

L18 Environmental Management System and Techniques:



L21 Environmental Safety and ISO 14000 Standards,

L22 Environmental Safety and ISO 14000 Standards

L23 ISO 14001 Standards,

L24 ISO 14001 Standards,

L25 Environmental Management Systems, (EMS)

L26 Environmental Management Systems, (EMS)

L27 Total Quality Management (TQM)

L28 Total Quality Management (TQM)

L29 Total Safety Management (TSM),

L30 Total Safety Management (TSM),

L31 ISO 9000 and ISO 18000 Standards.




L35 Revision-1

L36 Revision-2


CO

STATEMENT




CV

1691.1

Apply the knowledge about the basic fundamentals of

science, ecology and ecosystem to protect the

environment to promote sustainable development

3 1 1 2 2

CV

1691.2

Understand the basic concept of ecosystem and

identify the problems mainly responsible for

environmental degradation.

3 2 1 2 2

CV

1691.3

Development of solution to protect the biodiversity

by using different techniques.

1 3 1 2 1

CV

1691.4

Economic analysis of the natural environment by using

model with proper understanding the limitations of

the analytical tool.

3 1 2 1

CV

1691.5

Investigate the impact of various anthropogenic

activity in societal and environmental context.

Students can demonstrate the knowledge in terms of

design reports and give presentations on various

topics of environmental concern with effective

communication

2 2 3 1 2 2


A. Introduction: This course is offered by Dept. of Chemistry as a post-graduate course. The aim of the course is to

make students familiar with the concepts and applications in two important topics in advanced organic chemistry,

namely concerted organic reactions and organic photochemistry. This course will also uncover all the major topics

in heterocyclic chemistry. In addition to lectures there will be tutorial sessions and assignments in this course.


[2311.1] Understand the wide range of diversity in Organic Chemistry with the help of knowledge of

photochemistry.

[2311.2] Explain various reactions involved in understanding the mechanism of pericyclic reactions.

[2311.3] Identify the problems and applications of photochemistry and pericyclic reactions.

[2311.4] Understand organic photochemical reactions, their mechanisms and applications in organic synthesis.

[2311.5] Impart the knowledge of Heterocyclic compounds.



actions, checking out the degree to which these assumptions are accurate and valid, and looking at our ideas

and decisions (intellectual, organizational, and personal) from different perspectives.





settings.







development.






Course Hand-out

Photochemistry, Pericyclic Reactions and Heterocyclic | CY 2311 | 3 Credits | 2 1 0 3

Session: July 17 – Nov 17 | Faculty: Dr Rama Kanwar | Class: M.Sc. (III Sem.)


environment.

[PSO.3]. Understand theoretical concepts of instruments that are commonly used in most chemistry fields as



D. Assessment Plan:


Internal Assessment

(Summative)





Averaged)

10

End Term Exam

(Summative)


Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Photochemistry: Photochemical reactions, quantum yield, transfer of excitation energy, actinometry;

Determination of reaction mechanism: Determination of rate constants of reactions; Photochemistry of

alkenes: Rearrangement of 1,4- and 1,5-dienes; Photochemistry of carbonyl compounds: Intramolecular

reactions of carbonyl compounds-saturated, Intermolecular cyloaddition reactions-dimerisations and oxetane

formation; Photochemistry of aromatic compounds: Isomerisations, additions and substitutions; Miscellaneous

photochemical reactions: Photo-Fries reaction of anilides, Photo-Fries rearrangement; Pericyclic reactions:

Classification of pericyclic reactions; Electrocyclic reactions: Conrotatory and disrotatory motions, Sigmatropic

rearrangements: H-shifts and alkyl-shifts, supra and antarafacial migrations; Heterocyclic: Carbocyclic ring systems.

F. TEXT BOOKS

1. Photochemistry and Pericyclic Reactions by Jagdamba Singh, New Age International Publication 2012.

2. Heterocyclic Chemistry by R. K. Bansal

3. Pericyclic Reactions: A Mechanistic and Problem-Solving Approach by S. P. Singh and Sunil Kumar

G. REFERENCE BOOKS

1. Gilbert, A., Baggot, J., Essentials of Molecular Photochemistry, Blackwell Scientific Publication, 1991.

2. Turro N.J., Molecular Photochemistry, W.A.Benjamin Inc., New York, 1967.

3. Cox, A., Kemp, T.J., Introductory Photochemistry, McGraw Hill, 1971.

4. Reaction Mechanism in Organic Chemistry, S M Mukherji, S P Singh, Macmillan Publishers India Limited, 1984.

H. Lecture Plan:

LEC NO TOPICS

1. Photochemistry: Photochemical reactions

2. Photochemical reactions

3. Photochemical reactions

4. quantum yield

5. transfer of excitation energy

6. actinometry

7. Determination of reaction mechanism: Determination of rate constants

of reactions

8. Determination of rate constants of reactions

9. Photochemistry of alkenes: Rearrangement of 1,4- and 1,5-dienes

10. Rearrangement of 1,4- and 1,5-dienes

11. Photochemistry of carbonyl compounds: Intramolecular reactions of

carbonyl compounds

12. Intramolecular reactions of carbonyl compounds

13. Intermolecular cyloaddition reactions-dimerisations and oxetane

formation

14. Intermolecular cyloaddition reactions-dimerisations and oxetane

formation

15. Photochemistry of aromatic compounds: Isomerisations, additions and

substitutions

16. Isomerisations, additions and substitutions

17. Miscellaneous photochemical reactions: Photo-Fries reaction of anilides

18. Photo-Fries rearrangement

19. Pericyclic reactions: Classification of pericyclic reactions

20. Classification of pericyclic reactions

21. Electrocyclic reactions: Molecular orbitals

22 Electrocyclic reactions: Conrotatory motions

23 Electrocyclic reactions: disrotatory motions

24. Electrocyclic reactions: Examples

25. Electrocyclic reactions: Examples

26. Sigmatropic rearrangements: H-shifts

27. Sigmatropic rearrangements: Examples

28. Sigmatropic rearrangements: alkyl-shifts,

29. Sigmatropic rearrangements: Examples

30. supra and antarafacial migrations

31. Heterocyclic: Introduction: Molecular orbital picture and aromatic

characteristics of pyrrole, furan,

32. Heterocyclic: Carbocyclic ring systems Introduction: Molecular orbital

picture and aromatic characteristics of thiophene and pyridine

33. Heterocyclic: Preparation and reactions of Indole.

34. Heterocyclic: Preparation and reactions of quinolone and isoquinoline

35. Heterocyclic: Fischer iodole synthesis

36. Heterocyclic: Skraup synthesis

37 Heterocyclic: Bischler-Napieralski synthesis

38. Heterocyclic: electrophilic substitution reactions of indole, Quinolone and

isoquinoline

39. Heterocyclic: electrophilic substitution mechanism of nucleophile

substitution reactions in pyridine derivatives

40. Heterocyclic: Comparison of basicity of pyridine, piperdine and pyrrole


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


CY 2311.1 Understand the wide range of diversity in

Organic Chemistry with the help of

knowledge of photochemistry

3 2 3 2

CY 2311.2 Explain various reactions involved in

understanding the mechanism of pericyclic

reactions

2 2 2 2

CY 2311.3 Identify the problems and applications of

photochemistry and pericyclic reactions

2 3 2

CY 2311.4 Understand organic photochemical reactions,

their mechanisms and applications in organic

synthesis

2 3 2

CY 2311.5 Impart the knowledge of Heterocyclic

compounds

3 2 2 2 3


A. Introduction: This course is offered by Dept. of Chemistry as a Core Course, targeting students

who wish to pursue research & development in industries or higher studies in field of Organometallic

Chemistry, including Homogeneous catalysis, Heterogeneous catalysis and Bioorganometallic Chemistry.

It offers in depth knowledge of the field of organometallic chemistry covering the development of this

subject, state-of-art reactions involved in this subject, and gives an insightful discourse on the industrial

importance of various organometallic compounds. Students are expected to have background knowledge

on organic and inorganic chemistry for a better learning.


[CY2312.1] Understand the fundamental and basic aspects of organometallic chemistry.

[CY2312.2] Learn about the interdisciplinary character of organometallic chemistry among the

conventional branches of chemistry as well as the industrial aspects of organometallic chemistry

[CY2312.3] Understand the chemical processes involved in the various renowned industrial conversions

(e.g Olefin polymerization, Hydrogenation, etc.) carried out in presence of organometallic complexes.

[CY2312.4] Understand the merging of two disciplines – organometallic chemistry and biology and learn

about the emerging well-recognized sub-discipline, i.e., bioorganometallic chemistry.

[CY2312.5] Gain the knowledge of various organometallic reactions and would be incited with the ideas

to carry out hands-on research in the field of Organometallic Chemistry









settings.



volunteering.




development.


learning in the broadest context socio-technological changes.

[PSO.1] Develop knowledge, understanding and expertise in their chosen field of chemical science



Course Hand-out : Programme name: M. Sc. Chemistry

Organometallic Chemistry| CY 2312| 3 Credits | 2 1 0 3

Session: Jul 17 – Dec 17 | Faculty: Dr. Sriparna Ray | Class: Core Course (M.Sc. Chemistry)

[PSO.2] Develop an understanding of eco-friendly chemical processes and impact of chemistry on health

and environment.

[PSO.3] Understand theoretical concepts of instruments that are commonly used in most chemistry fields


[PSO.4] Provide opportunities to excel in academics, research or Industry.

D. Assessment Plan:

Criteria Description Maximum

Marks

Internal Assessment

(Summative)



In class Assignments , Activity feedbacks


10

End Term Exam

(Summative)


Total 100

Attendance (Formative) A minimum of 75% Attendance is required to be maintained by a student

to be qualified for taking up the End Semester examination. The allowance

of 25% includes all types of leaves including medical leaves.

Homework/ Home


Assignment (Formative)

There are situations where a student may have to work in home,

especially before a flipped classroom. Although these works are not

graded with marks. However, a student is expected to participate and

perform these assignments with full zeal since the activity/ flipped

classroom participation by a student will be assessed and marks will be

awarded.

E. SYLLABUS

Introduction: Classification of organometallic compounds based on hapticity and polarity of M-C

bond; Alkyl and aryl complexes of transition metals: Synthesis, stability and decomposition

pathways; Compounds with Metal-carbon multiple bonds: Alkylidenes, alkylidynes, nucleophilic

and electrophilic reactions on the ligands; Transition metal π-complexes: Transition metal π-

complexes with unsaturated organic molecules, CO, alkenes, alkynes, allyl, diene, Important reactions

relating to nucleophilic and electrophilic attack on ligands and to organic synthesis; Bimetallic and

cluster complexes: Structure and applications in catalysis; Fluxional organometallic

compounds: Fluxionality and dynamic equilibria in organometallic compounds; Basic

organometallic reactions: Ligand substitution, oxidative reactions, Importance of organometallic

compounds in biological systems.

F. TEXT BOOKS

1. R. C. Mehrotra and A. Singh, Organometallic Chemistry, A Unified Approach, New Age

International, 2015.

2. Gupta, B. D. and Elias, A. J., Basic Organometallic Chemistry, Universities Press.

G. REFERENCE BOOKS

1. D. F. Shriver, P. W. Atkins and C. H. Langford, Inorganic Chemistry, Oxford Univ. Press, 2010.

2. J. E. Huheey, E. A. Keiter and R.L. Keiter, Inorganic Chemistry, Principles of Structure and Reactivity, Pearson

Education, 2014.

3. F. A. Carey G. Wilkinson, C. A. Murillo and M. Bochmann, Advanced Inorganic Chemistry, Wiley

Interscience, 2014.

4. C. E. Housecroft and A. G. Sharpe, Inorganic Chemistry, Prentice Hall, 2015.

H. Lecture Plan:

Lecture Topics

1 Introduction: Classification of organometallic compounds based on hapticity

2 Classification of organometallic compounds based on polarity of M-C bond

3-4 Alkyl and aryl complexes of transition metals: Synthesis

5-6 Alkyl and aryl complexes of transition metals: Stability and decomposition pathways

7-8 Compounds with Metal-carbon multiple bonds: Alkylidenes

9-10 Alkylidynes

11-13 Compounds with Metal-carbon multiple bonds: nucleophilic reactions on the

ligands

14-16 Compounds with Metal-carbon multiple bonds: electrophilic reactions on the

ligands

17-20 Transition metal π-complexes: with CO

21-23 Transition metal π-complexes: with unsaturated organic molecules, alkenes, alkynes

24-26 Transition metal π-complexes: with allyl, dienes

27-28 Important reactions relating to nucleophilic attack on ligands and to organic synthesis

29-31 Important reactions relating to electrophilic attack on ligands and to organic synthesis

32-35 Bimetallic complexes: Structure and applications in catalysis

36-38 Cluster complexes: Structure and applications in catalysis

39 Fluxional organometallic compounds: Fluxionality and dynamic equilibria in

organometallic compounds

40 Basic organometallic reactions: Ligand substitution reactions

41 Basic organometallic reactions: oxidative reactions

42 Importance of organometallic compounds in biological systems


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7

PSO 1 PSO 2 PSO3 PSO4

CY 2312.1 Understand the fundamental and basic aspects

of organometallic chemistry.

3 3

CY 2312.2 Learn about the interdisciplinary character of

organometallic chemistry among the

conventional branches of chemistry as well as

the industrial aspects of organometallic

chemistry.

2 2

CY 2312.3 Understand the chemical processes involved in

the various renowned industrial conversions (e.g

Olefin polymerization, Hydrogenation, etc.)

carried out in presence of organometallic

complexes.

2 2

CY 2312.4 Understand the merging of two disciplines –

organometallic chemistry and biology and learn

about the emerging well-recognized sub-

discipline, i.e., bioorganometallic chemistry.

3 3

CY 2312.5 Gain the knowledge of various organometallic

reactions and would be incited with the ideas to

carry out hands-on research in the field of

Organometallic Chemistry.

3 3



emphasis on solid-state materials and their understanding. The course explore the preparative methods and

characterization of solid materials, then study of electrical, magnetic, optical properties and superconductivity of

solids. Students are expected to have background knowledge in physical and inorganic chemistry up to the

undergraduate level for this course.


[2313.1]. Learn the preparative methods of solids and single crystal growth.

[2313.2]. Understand the characterization methods of solids.

[2313.3]. Understand of crystalline and amorphous solids.

[2313.4]. Discuss superconductivity, zeolites, fullerenes and nanocrystalline solids.

[2313.5]. Discuss band theory of solids.

[2313.6]. Learn about the magnetic types, soft and hard magnetic materials.









settings.



volunteering.




development.





and environment.






Course Hand-out

Solid State Chemistry | CY2313 | 3 Credits | 2 1 0 3


D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Crystal Structure: Crystalline and amorphous solids, methods of characterizing crystal structure - Powder x-ray diffraction,

electron and neutron diffraction; Preparative methods: Solid state reaction, chemical precursor method, co-Precipitation,

sol-gel, metathesis; Methods of Single Crystal Growth: Solution growth, Melt Growth-Bridgeman, Czochralski, Kyropoulus,

Verneuil; Chemical Vapour Transport; Characterization: Thermal analysis: TGA, DTA, DSC; Electrical properties: Band

theory of solids -metals and their properties; Magnetic properties: Dia, para, ferro, ferri, and antiferro magnetic types; soft

and hard magnetic materials; Optical properties: Luminescence of d- and f- block ions; structural probes; up and down

conversion materials; Superconductivity: Basics, discovery and high Tc materials; Additional Topics: Amorphous materials,

zeolites, fullerenes and nanocrystalline solids.

F. TEXT BOOKS

1. West, A. R., Solid State Chemistry and its Applications, John Wiley & Sons, 2007.

2. Smart, L., Moore, E., Solid State Chemistry - An Introduction, Chapman & Hall, 2012.

G. REFERENCE BOOKS

1. Keer, H. V., Principles of the Solid State, Wiley Eastern Limited, 2013.

2. Chakrabarty, D. K., Solid State Chemistry, New Age Publishers, 2013.

H. Lecture Plan:

Lecture

No.

Topics

1 Introduction: Crystalline and amorphous solids

2 Crystal symmetry, centre of symmetry, plane of symmetry, axes of symmetry

3 Symmetrical elements of cube

4 Point groups and space groups

5 Unit cell, space lattice, types of crystal systems

6 Revision

7 Metallic crystal structures: Primitive, FCC, BCC, HCP

8 Metallic crystal structures: Density calculations and numerical

9 Characterization of crystal structures: X-ray diffraction technique, generation and diffraction

10 Characterization of crystal structures: X-ray diffraction technique, Powder diffraction patterns,

uses of powder diffraction

11 Characterization of crystal structures: Electron diffraction technique, advantages and

disadvantages

12 Characterization of crystal structures: Neutron diffraction technique

13 Revision

14 Preparative methods: Solid state reaction

15 Preparative methods: Chemical precursor method, co-Precipitation

16 Preparative methods: Sol-gel, metathesis

17 Revision

18 Methods of Single Crystal Growth: Solution growth, Melt Growth-Bridgeman

19 Methods of Single Crystal Growth: Czochralski, Kyropoulus

20 Methods of Single Crystal Growth: Verneuil; Chemical Vapour Transport

21 Revision

22 Characterization: Thermal analysis: TGA

23 Characterization: Thermal analysis: DTA

24 Characterization: Thermal analysis: DSC

25 Revision

26 Electrical properties: Band theory of solids

27 Electrical properties: Metals and their properties

28 Magnetic properties: Dia, para, ferro, ferri, and antiferro magnetic types

29 Magnetic properties: Soft and hard magnetic materials

30 Optical properties: Luminescence of d- and f- block ions

31 Optical properties: Structural probes; up and down conversion materials

32 Revision

33 Superconductivity: Basics, discovery

34 Superconductivity: High Tc materials

35 Amorphous materials

36 Zeolites

37 Zeolites

38 Zeolites

39 Revision

40 Fullerenes

41 Fullerenes

42 Nanocrystalline solids

43 Revision


CO

STATEMENT


OUTCOMES


SPECIFIC OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


CY 2313.1 Learn the preparative methods of solids and single

crystal growth

3 1 2 3 1 2 2

CY 2313.2 Understand the characterization methods of solids 3 1 2 3 3 3 3

CY 2313.3 Understand of crystalline and amorphous solids 1 1 2 1 2 2

CY 2313.4 Discuss superconductivity, zeolites, fullerenes and

nanocrystalline solids

2 1 2 3 2 2 2 2

CY 2313.5 Discuss band theory of solids 1 2 1

CY 2313.6 Learn about the magnetic types, soft and hard

magnetic materials

1 1 1 1


A. Introduction: This course is offered by Dept. of Chemistry for M.Sc chemistry students. Green chemistry is an

opportunity for introducing innovative solutions to chemical problems and applying sustainability towards molecular

design. Chemists have the ability to design products and processes that have reduced impacts on humans and the

environment and therefore creating sustainable chemical building blocks for materials and products in our society.

B. Course Outcomes: At the end of the course, students will be able to:

[2314.1]. Conceptualize the sustainability

[2314.2]. Understand how to apply this concept in our research fields of interest aiming to safe our plant

[2314.3]. Think prospectively about how to change our education subjects to be sustainable learning tools by

Investigating examples of green chemistry applications relevant to students

[2314.4]. Understand the important role of the green chemistry and how to deal with it in our practical life

C. PROGRAM OUTCOMES AND PROGRAM SPECIFIC OUTCOMES:







[PO.3]. Social Interaction: Elicit views of others, mediate disagreements and help reach conclusions in

group settings.



volunteering.




development.



[PSO.1].Develop knowledge, understanding and expertise in their chosen field of chemical science

[PSO.2].Develop an understanding of eco-friendly chemical processes and impact of chemistry on health and environment.

[PSO.3].Understand theoretical concepts of instruments that are commonly used in most chemistry fields as well as interpret

and use data generated in instrumental chemical analyses.

[PSO.4].Provide opportunities to excel in academics, research or Industry



Course Hand-out

Green Chemistry CY 2314 Credits | 2103]

Session: July 17 – Dec 17 | Faculty: Dr Babia Malik | Programme: M.Sc.

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Green chemistry: Green chemistry and Sustainability, Dimensions of sustainability, Limitations/Obstacles in pursuit of the

goals of Green Chemistry, Opportunities for the next generation of materials designers to create a safer future; Basic

principles of Green Chemistry and their illustrations with examples; Examples of green synthesis/reaction: Green

starting materials, Green reagents, Green solvents and reaction conditions, Synthesis of Ibuprofen, Adipic acid etc., Hazard

assessment and mitigation in chemical industry; Future trends in Green Chemistry: Oxidation-reduction reagents and

catalysts, Biomimetic, multifunctional reagents, Combinatorial green chemistry, Proliferation of solvent less reactions,

Noncovalent derivatization, Biomass conversion, emission control, Biocatalysis.

F. TEXT BOOKS

1. Ahluwalia V.K. Green Chemistry ,NarosaPublishingHouse,2013

2. M. Kolb Vera Green Organic Chemistry and Its Interdisciplinary Applications CRC Press, 2016

3. Ahluwalia V. K. and Kidwai .M. New Trends in Green Chemistry, Springer, 2004

4. Wei Zhang, Berkeley Cue Green Techniques for Organic Synthesis and Medicinal Chemistry Wiley, 2012

G. References:

1. Anastas, P.T., Warner, J.C., Green Chemistry: Theory and Practice, Oxford University Press, 2008.

2. Lancaster, M., Green Chemistry: Introductory Text, Royal Society of Chemistry, London, 2010.

3. Ryan, M.A., Tinnesand, M., Introduction to Green Chemistry, American Chemical Society, Washington, 2012.

4. Cann, M.C., Connelly, M.E., Real world cases in Green Chemistry, American Chemical Society, Washington, 2013.

H. Lecture Plan:

Lecture

Number

Topics

1. Introduction of Green Chemistry and Sustainability

2. Requirement of Green Chemistry

3. Limitations/Obstacles in pursuit of the goals of Green Chemistry

4. Basic principles of Green Chemistry

5. Prevention of waste/byproducts

6. Maximum Incorporation of the materials used in the process into the

final product (Atom Economy): Green metrics

7. Prevention/Minimization of hazardous/toxic products

8. Designing safer chemicals - different basic approaches

9. Selection of appropriate auxiliary substances (solvents, separation

agents etc.)

10. Energy requirements for reactions—use of microwave, ultrasonic

energy.

11. Selection of starting materials—use of renewable starting materials

12. Revision

13. Avoidance of unnecessary derivatization—careful use of

blocking/protection groups

14. Use of catalytic reagents (wherever possible) in preference to

stoichiometric reagents

15. Designing biodegradable products (xi) Prevention of chemical accidents.

16. Strengthening/development of analytical techniques to prevent and

minimize the generation of hazardous substances in chemical processes.

17. Development of accurate and reliable sensors and monitors for real

time in process monitoring.

18. Development of accurate and reliable sensors and monitors for real

time in process monitoring.

19. Green starting materials

20. Revision

21. Green starting materials

22. Green reagents

23. Green reagents

24. Green reagents

25. Green solvents and reaction conditions




29. Revision

30. Green catalysis

31. Green catalysis

32. Oxidation reagents and catalysts

33. Reducing reagents and catalysts

34. Biomimetic reagents

35. Biomimetic reagents

36. Multifunctional reagents

37. Multifunctional reagents

38. Combinatorial green chemistry

39. Proliferation of solvent less reactions

40. Non covalent derivatization

41. Biomass conversion, emission control, Biocatalysis

42. Revision


CO

STATEMENT


OUTCOMES

CORRELATION WITH


PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7

PSO

1

PSO 2 PSO 3 PSO 4

CY 2314.1 Conceptualize the sustainability 3 3 1 2 3

CY 2314.2 Understand how to apply this concept in our

research fields of interest aiming to safe our

plant

2 2 2 1

CY 2314.3 Think prospectively about how to change our

education subjects to be sustainable learning

tools by

Investigating examples of green chemistry

applications relevant to students

2 2 1 2 1 1

CY 2314.4 Understand the important role of the green

chemistry and how to deal with it in our

practical life

2 3 2 1


A.

Introduction: This course is offered by Dept. of Chemistry for M.Sc chemistry students. Industrial chemistry course

covers general introduction of industrial processing principles as applicable to chemical and allied industries along with

understanding of areas where a skill needed for efficient utilization of resources in chemical industries. Students will be able

to understand detail of source of raw materials used in the chemical and allied industries, description about processing of

chemical raw materials into finished products.

B. Course Outcomes:

CY2315.1 Learn basic concepts of industrial processing

CY2315.2 Understand proceedings of various chemical industries

CY2315.3 Learn about actual operations in chemical industries

CY2315.4 Understand detail of raw materials used sourcing and processing, conversion of chemical materials to final

products

CY2315.5 Understand the role of chemist in various industries

C. PROGRAM OUTCOMES






technology.




[PO.5]. Ethics: Recognize different value systems including your own, understand the moral dimensions of your decisions,

and accept responsibility for them.


development.



PROGRAM SPECIFIC OUTCOME

[PSO.1]. Develop knowledge, understanding and expertise in their chosen field of chemical science


environment.



Course Hand-out

Industrial Chemistry | CY 2315 | 3 Credits | 2 1 0 3

Session: Jul 17 – Dec 17 | Faculty: Dr. Lalita Ledwani | Programme: M.Sc.




D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20



Activity feedbacks (Accumulated

and Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)

A minimum of 75% Attendance is required to be maintained by a student

to be qualified for taking up the End Semester examination. The

allowance of 25% includes all types of leaves including medical leaves.

Homework/ Home


Assignment

(Formative)

There are situations where a student may have to work in home,

especially before a flipped classroom. Although these works are not

graded with marks. However, a student is expected to participate and

perform these assignments with full zeal since the activity/ flipped

classroom participation by a student will be assessed and marks will be

awarded.

E. Course Contents:

Course Contents: Petroleum and Petrochemical Industry: Composition of crude petroleum, Refining Processes:

distillation, thermal and catalytic methods Lubricants: Classification of lubricants, lubricating oils, Silicate Industries: a)

Glass: b) Ceramics (c) Cements Fertilizers: Different types of fertilizers. Surface Coatings: Classification of surface

coatings. Paints and pigments Dyes: General introduction and classification with special reference to textile and edible dyes

and fabric brighteners. Industrial preparation and uses of malachite green, indigo and bismark brown. Cosmetics and

Perfumes: A general study including preparation and uses of the following: Hair dye, hair spray, Shampoo, Sun-tan lotions,

face powder, lipsticks, talcum powder, nail enamel, creams, antiperspirants and artificial flavours. Essential oils Oils and Fats:

Classification of oils, Soap and detergent.

F./G.

H. Lecture Plan:

Lecture

Number

Topics

1. Introduction and Classification of Crude Oil

2. Outline of various Petroleum Industries, Types of Refinery Industries

3. Refining Processes: Atmospheric Distillation and Vacuum Distillation

4. Thermal Cracking, Vis-breaking and Coking

5. Fluid Catalytic Cracking, Reforming

6. Hydrprocess, Hydrocraking and Hydrotreating

7. Crude oil Assay, Properties of Crude Oil

8. Petrochemical Industries: General Introduction

9. Petrochemicals from Saturated Hydrocarbons

10. Petrochemicals from Unsaturated Hydrocarbons

11. Petrochemicals from BTX

12. Macromolecules

13. Polymerization Reactions

14. Lubricants, Mechanism of Lubrications

15. Classification of Lubricants

16. Properties of Lubricating Oil

17. Silicate Industries, Glass

18. Ceramics

19. Cement

20. Fertilizers: Different Types of Fertilizers

21. Surface Coatings, Corrosion and its Control

22. Classification of Surface Coatings

23. Classification of Surface Coatings

24. Paints and Pigments

25. Dyes: General Introduction Industrial Preparation

26. Classification of Dyes with special reference to Textile

27. Classification of Dyes with special reference to Edible dyes

28. Classification of Dyes with special reference to Fabric brighteners

29. Uses of Malachite Green, Indigo and Bismark brown

30. Cosmetics and Perfumes: A general study including preparation

31. Hair dye, Hair spray, Shampoo

32. Sun-tan lotions, face powder, lipsticks, talcum powder, nail enamel, creams,

antiperspirants and artificial flavours.

33. Essential Oils

34. Adhesives

35. Adhesives Action

36. Physical Factors Influencing Adhesive Action

37. Factors Affecting Adhesives

38. Oils and Fats, Classification of Oils

39. Soap and Detergent

40. Revision

41. Revision

42. Revision


CO

STATEMENT


OUTCOMES

CORRELATION WITH

PROGRAM SPECIFIC

OUTCOMES

PO

1

PO

2

PO

3

PO

4

PO

5

PO

6

PO

7


CY 2315.1 Learn basic concepts of industrial processing 3 3 2 3 2

CY 2315.2 Understand proceedings of various chemical

industries

2 2 3 3 2

CY 2315.3 Learn about actual operations in chemical

industries

2 3 3 2

CY 2315.4 Understand detail of raw materials used sourcing

and processing, conversion of chemical materials

to final products

1 2 3 3 1 2

CY 2315.5 Understand the role of chemist in various

industries

2 2 2 3 1 2 3


A. Introduction: This course is offered by Dept. of Chemistry as an elective course for the M.Sc. programme, targeting

students who wish to pursue higher studies & research in the field of synthetic organic or inorganic chemistry with

specific focus on the interdisciplinary nature. The course offers in depth knowledge of the basics of transition metal

chemistry, the theories of bonding, spectra, magnetic properties and gives detailed knowledge on reaction mechanism

and organometallic reactions involving transition metals. Students are expected to have background knowledge in

inorganic and organic chemistry up to the undergraduate level for this course.


[2351.1]. Learn the properties of highly important transition metals in great details.

[2351.2]. Understand the theory of bonding.

[2351.3]. Learn the coordination chemistry in detail.

[2351.4]. Learn and apply the spectroscopic properties and techniques especially for transition

metal compounds.

[2351.5]. Understand the reaction mechanisms of transition metal compounds.

[2351.6]. Create the link between organic and inorganic chemistry.









settings.







development.




[PSO.2]. Develop an understanding of eco-friendly chemical processes and impact of chemistry on

health and environment.

[PSO.3]. Understand theoretical concepts of instruments that are commonly used in most chemistry

fields as well as interpret and use data generated in instrumental chemical analyses.




Course Hand-out

Organo-Transition Metal Chemistry | CY 2315 | 3 Credits | 2 1 0 3

Session: Jul 17 – Dec 17 | Faculty: Dr. Susruta Samanta | Class: M.Sc. (III Semester)

D. Assessment Plan:


Internal Assessment

(Summative)

Sessional Exam I 20




Averaged)

10

End Term Exam

(Summative)

End Term Exam 50

Total 100

Attendance

(Formative)





Activity Assignment

(Formative)





will be awarded.

E. SYLLABUS

Transition metal chemistry: Structure, bonding, and properties of transition metal ligand complexes; HSAB concept;

Thermodynamic stability; Successive and overall stability constants Irving-William series; Chelate and macrocyclic effect.

Theories of bonding: VBT, CFT and their limitations; D-orbital splitting in octahedral, JT distorted octahedral, square planner,

square pyramidal, trigonal bipyramidal, tetrahedral complexes; CFSE for d1 to d10 complexes. Electronic spectra: UV-Vis,

charge transfer, colours, intensities, and origin of spectra; Interpretation, term symbols, and splitting of terms in free atoms,

selection rules for electronic transitions. Reaction mechanisms: Substitution reaction in octahedral and square planner

complexes; Trans effect and its influence, anation and base hydrolysis, stereochemistry, inner and outer sphere electron transfer

mechanism. Lanthanides and Actinides: Contraction, coordination, optical spectra, and magnetic properties.

Organometallic Chemistry: Valance electron count (16/18 rule); Structure and bonding in mono and poly-nuclear metal

carbonyls; Substituted metal carbonyls and related compounds; Synthesis and reactivity of metal carbonyls. Types of M-C

bonds: Synthesis and reactivity of metal alkyls, carbenes, alkenes, alkynes, and arene complexes; Metalocenes and bet

metalocenes, isolobal analogy. Reactions of organometallic complexes: Substitution, oxidative addition, reductive

elimination, insertion and deinsertion; Catalysis – hydrogenation, hydroformylation, Monsanto process, Wacker process, alkene

polymerization.

F. TEXT BOOKS

1. D. F. Shriver, P. W. Atkins and C. H. Langford, Inorganic Chemistry, Oxford Univ. Press, 2010.

2. J. E. Huheey, E. A. Keiter and R.L. Keiter Inorganic Chemistry, Principles of Structure and Reactivity, Pearson

Education, 2014.

3. G. F. Miessler and D. A. Tarr Inorganic Chemistry, Pearson Education, 2004.

G. REFERENCE BOOKS

1. R. Sarkar, General and Inorganic Chemistry Part II, New Central Book Agency, 2015.

2. R. C. Mehrotra and A. Singh, Organometallic Chemistry, A Unified Approach, New Age International, 2015.

H. Lecture Plan:

Lecture

No.

Topics

1 Introduction: d-block elements and transition metals

2 Properties of transition metals: HSAB principle, Irving-William series

3 Isomerism in transition metal complexes: Types of isomers, optical properties

4 Thermodynamics of transition metal complexes: Formation constant, stepwise and

overall formation constants

5 Thermodynamics of transition metal complexes: chelate effect, macrocyclic effect;

Revision of the unit

6 Theories of bonding: VBT, CFT, LFT, their limitations

7 Theories of bonding: d-orbital splitting and CFSE

8 Theories of bonding: JT distortion

9 Theories of bonding: CFSE for d1 – d10 complexes; Revision of the unit

10 Electronic spectra: UV-Visible spectra, colours, origin of colours, intensities

11 Electronic spectra: Term symbols, free atom splitting, selection rules for electronic transition

12 Electronic spectra: Charge transfer spectra; Revision of the unit

13 Reaction mechanisms: Substitution reaction in octahedral complexes

14 Reaction mechanisms: Substitution reaction in square planner complexes

15 Reaction mechanisms: Trans effect and its influence

16 Reaction mechanisms: Anation and base hydrolysis

17 Reaction mechanisms: Stereochemistry

18 Reaction mechanisms: Inner and outer sphere electron transfer mechanism; Revision of the

unit

19 Lanthanides and Actinides: Introduction, contraction

20 Lanthanides and Actinides: Coordination

21 Lanthanides and Actinides: Optical spectra

22 Lanthanides and Actinides: Magnetic properties; Revision of the unit

23 Organometallic Chemistry: Valance electron count (16/18 rule)

24 Organometallic Chemistry: Structure and bonding in mono and poly-nuclear metal

carbonyls

25 Organometallic Chemistry: Substituted metal carbonyls and related compounds

26 Organometallic Chemistry: Synthesis and reactivity of metal carbonyls

27 Organometallic Chemistry: Synthesis and reactivity of metal carbonyls; Revision of the unit

28 Types of M-C bonds: Synthesis and reactivity of metal alkyls

29 Types of M-C bonds: Synthesis and reactivity of metal carbenes

30 Types of M-C bonds: Synthesis and reactivity of metal alkenes, alkynes, arenes

31 Types of M-C bonds: Metalocenes and bet metalocenes

32 Types of M-C bonds: Isolobal analogy; Revision of the unit

33 Reactions of organometallic complexes: Substitution

34 Reactions of organometallic complexes: oxidative addition

35 Reactions of organometallic complexes: reductive elimination

36 Reactions of organometallic complexes: insertion and deinsertion

37 Reactions of organometallic complexes: Catalysis – hydrogenation, hydroformylation

38 Reactions of organometallic complexes: Monsanto process, Wacker process

39 Reactions of organometallic complexes: alkene

Polymerization; Revision of the unit

40 Recap: Theories of bonding, electronic spectra

41 Recap: Organometallic chemistry

42 Recap: Types of M-C bonds

43 Recap: Reactions of organometallic complexes


CO

STATEMENT


SPECIFIC OUTCOMES


CY 2351.1 Learn the properties of highly important

transition metals in great details.

3 2 3 1 1

CY 2351.2 Understand the theory of bonding. 2 1 3

CY 2351.3 Learn the coordination chemistry in detail. 2 3 2 2

CY 2351.4 Learn and apply the spectroscopic properties and

techniques especially for transition metal

compounds.

3 3 1 1 3

CY 2351.5 Understand the reaction mechanisms of

transition metal compounds.

3 1 2 1

CY 2351.6 Create the link between organic and inorganic

chemistry.

2 1 3 1 3


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