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Red Wine Maceration

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    Red WinemakingFermentation Temperature

    Skin and seed contact time

    Extraction Techniques

    Cold Soak

    Thermovinification

    Extended Maceration

    Pre-fermentation J uice Runoff

    Enzyme Additions

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    Red winemaking

    Mixing Techniques

    Pressing

    Some Experimental Results

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    Reds Ferment Warm

    Most reds ferment at warm temperatures (70-90F)

    Oxidation is generally not an issue because surface

    layer of CO2

    Skins and seeds are less dense than fermentingliquid forming a cap (about 1/3 volume)

    Cap requires mixing to prevent drying

    Mixing techniques vary and influence the color andastringency of the wine

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    Seed And skin Contact

    Duration of contact time is controlling factor forextraction of color and tannin extraction.

    Tannins impart astringent character to wine and act asa color stabilizer

    Alcohol also helps to extract color and tannin

    Higher tannin is desirable in wines that are meant to beaged (unpleasantly too tannic young)

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    Red FermentorAnatomy of a red fermentation

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    Pigment Extraction

    Anthocyanins are the watersoluble pigments that areextracted from the skins of thegrapes.

    Copigmentation:Anthocyaninsinteract with themselves andother colorless cofactors toprovide color beyond what

    would be expected fromthemselves.

    Anthocyanins are susceptible

    to bleaching by sulfur dioxide.Smalllosses due to this areacceptable during winemaking.

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    Tannin Extraction

    Tannins are water solublecompounds that impartastringent character.

    Tannins and othercompounds can combinewith anthocyanins to

    stabilize color known aspolymeric pigments.

    Polymeric pigments are

    more stable to sulfurdioxide bleaching.

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    Rates of Extraction

    AnthocyaninsExtracted after two to three days

    Decline after maximum reached

    Tannins

    Extracted slowly and increase with contact time

    Polymeric Pigments

    Formed during winemaking and aging

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    Extraction Profiletannin and anthocyanins

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    Polymeric pigmentFormation

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    Mixing TechniquesPunch-Down

    Device used to break up cap and submerge it into fermentingliquid

    Pump-Over

    Volume of liquid is taken from racking valve and pumped backonto cap to wet it.

    Rack and Return

    Entire volume of liquid is racked off and then poured back ontocap to fully submerse it.

    Often seeds are removed from bottom of tank during thisprocess to avoid extraction of bitter compounds.

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    Punch-down

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    Punch-downExample

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    Punch-DownMechanical device

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    Pump-over

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    Pump-overFixed irrigator

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    Punch-down

    vs. Pump-overWhich method is more effective?It depends on the cultivar.

    Also depends on whether mechanism is mechanical or manuallybased.

    Pump over has been found to be extractive technique in manycases.

    Pump over variables

    Duration of pump over

    Cap temperature during pump over

    Skin content of liquid

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    Special Apparatus:Rotary Fermentors and Pulsed Air

    Rotary Fermentors

    Horizontal Fermentor

    Mechanically rotates

    Mixes during rotation

    Pulsed Air

    Compressed gas at bottom of tank

    Inert gas

    Forced through cap

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    Pulsed Air to Mix Cap

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    Rotary fermentor

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    Cold Soak

    Must is held at low temperature prior tofermentation (10 to 15C)

    Winemakers claim it improves color

    Done with varieties that are low in anthocyanins

    such as Pinot noir.

    Prominent technique for Oregon Pinot noirproduction

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    Cold soak continuedAqueous extraction supposedly improves wine color

    Anthocyanins are extracted early in fermentation while tannins arelater.

    Heat and alcohol are prominent extraction elements

    Anthocyanins are unstable and highly reactive and can degrade orbe stabilized by other compounds

    Stable color = Polymeric pigments formed through reactions withtannins and anthocyanins

    No good evidence it enhances stable color formation.

    Likely cold soak combined with other extraction methods may beable to help improve wine color but not on its own.

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    Thermovinification

    Procedure:

    Pre-fermentation heating of skin/seeds

    (140 to 160F) for a short timeExtract with juice

    Press

    Cool

    Start Fermentation

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    ThermovinificationResults:

    Damages skin cells (hypodermal cells)

    Denatures oxidative enzymes

    Release of anthocyanins

    No tannin enhancement

    Good for color improvement

    Suggested for varietals that have low color

    Research demonstrated effective with Pinot noir

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    Extended MacerationProlonged skin/seed contact after primary fermentation is

    complete

    Cultivar not a factor

    Tannins and anthocyanins

    Time period variable

    7, 13, 21 and 44 days have reported in literature

    Tank space can be become an issue

    Winemakers discuss this method as a means of buildingbody for the wine not just astringency

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    Pre-fermentation RunoffSaigne: Bleed off

    Removal of free run juice before fermentation

    Increase of skin/seed to juice ratio

    Used to simulate variation in berry size w/out change in berrycomposition.

    Phenolic Enhancement

    Color, tannin, polymeric pigment, total phenolics

    Varietal Differences

    Enhancement lost in some cases over time

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    Enzyme AdditionsPectolytic enzymes

    Enzyme = protein that is able to accelerate reaction withoutbeing used as substrate

    Lysis=breakdown

    Pectins are water soluble polysaccarides that are found inthe cell walls of plants

    Most enzyme preparations are impure

    Can contain enzymatic activities that will destabilizeanthocyanins

    beta-glycosidases destabilize anthocyanins

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    Enzyme additionsEnzyme mixture cocktail

    Difficult to know what enzyme activity you have in cocktail

    Research findings:

    Anthocyanin extraction not enhanced

    Tannins and other phenolics are enhanced

    Polymeric pigments

    Enzymes are affected by pH, EtOH, Temperature

    Some empirical investigation required

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    Role of Pressing in Red

    WinemakingThe end of extraction of skin/seed components

    Determining when to press depends on wine type

    Different types of presses are used to achieve differentoutcomes

    Bladder presses are the most commonly used

    Screw and basket presses are old effective means

    Continuous presses are more rare

    Both screw and continuous presses are avoided becausethey often damage seeds and skins and extract unwantedcomponents

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    ExperimentMerlot (Columbia Basin 5 ton/acre)

    10 ton fermentor (2 reps)

    Treatment

    Saigne

    %Water

    Addition

    Volume

    Change

    Brix

    Target

    Contact

    Time

    Control 0% 17.50% +17.5%23.8Brix

    7 days

    High Alcohol 0% 5% +5.0%26.8

    Brix7 days

    Low Saigne 18% 14.50% -3.50%23.8Brix

    7 days

    High Saigne 22% 11% -11% 23.8Brix

    7 days

    ExtendedMaceration

    14.60% 10.60% -4%23.8Brix

    20 days

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    Anthocyanins7 days not 3 days

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    Tannin Extraction

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    Extraction Proportions

    Control

    High

    Alcohol

    Low

    Saigne

    High

    Saigne

    Extended

    MacerationSkin

    Tannin42% 26% 40% 27% 22%

    SeedTannin 58% 74% 60% 73% 78%

    WineTannin

    (Calc)

    622 mg/L 976 mg/L 803 mg/L 977 mg/L 1704 mg/L

    WineTannin

    (Act.)552 mg/L 665 mg/L 547 mg/L 811 mg/L 1080 mg/L

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    ConclusionMany mixingtechniques

    Many macerationtechniques

    Experiment to find theones that fit your style

    Acknowledgements:

    WAC

    Chateau Ste.Mi h ll


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