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RobertLongoFebruary17,2016TheActivitySeries–PenniesandNailsPurpose:Thepurposeofthisexperimentistotestwhetherornotareactionwilltakeplacebetweenthecopperacetateinthevinegarsolutionfromthepenniesandtheironnail,whiledeepeningunderstandingoftheactivityseriesandhowitcanbeusedtopredictareaction.Results:AfterIallowedthepenniestositinthevinegarandsaltsolutionforsometimeinordertodissolvethecopperoxideoffthesurface,Iaddedthenailintothebowlandallowedittositforsometime.Idefinitelynoticedthatareactiontookplace,asthecopperthatwasinthevinegarseemstoaccumulateonthesurfaceofthenail,turningitadeeporange-redcolor.ItseemsIwasnotabletoscrapeoffallofthegalvanizationfromthesurfaceofthenail,asthereactionoccurredverystrongonsomepartsofthenail’ssurface,andnotatallonothers.ThereactionthatseemedtooccurwasFe+Cu(CH3COO)2-àFe(C2H3O2)2+Cu.Thisconfirmedthatironismorereactivethancopper,asitwasabletodisplacethecopperinthecopperacetatefoundinthevinegar.
WhatILearned:Thisexperimentwasreallyabletogivemeamuchstrongerunderstandingoftheactivityseriesanditsroleinpredictingwhetherornotareactionwouldoccur.Iftheexperimentwasreversedbydissolvingironoxideinvinegarandsalttoformironacetateandplacingcopperinthesolution,areactionwouldnotoccurbecausecopperislessreactivethanironandwouldnotbeabletoseparatetheironfromtheacidicaciditformedacompoundwith.Thisexperimentalsoallowedtoadeeperunderstandingofoxidationandreactionwitheachmetalsreacting,withtheaceticacidsolution.Thecopperwentthroughareductionwhenitgainedelectronsbyjoiningtothesurfaceofthenailandtheoppositehappenedwiththeiron,asitwasoxidizedwhenitjoinedwiththeaceticacidmoleculeinthesolution.
Whythiswasagoodexperiment;Whilereadingaboutthechemistrythatoccurssurroundingtheactivityseriesanditsvalueinpredictingwhetherareactionwilltakeplaceandaboutoxidationandreduction,itismuchmoreusefultoseeitinaction.Thisexperimentisveryusefulinprovidingasmall-scaleexampleofareactionthattakesplaceinlargescalestocreatepuremetals.