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SALINITY & AGGRESSIVITY ASSESSMENT 291 Flushcombe Road Blacktown NSW 2148 October 2020 rawearthenvironmental.com.au
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Page 1: SALINITY & AGGRESSIVITY ASSESSMENT

SALINITY & AGGRESSIVITY ASSESSMENT

291 Flushcombe Road

Blacktown

NSW 2148

October 2020

rawearthenvironmental.com.au

Page 2: SALINITY & AGGRESSIVITY ASSESSMENT

Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 1

REPORT DISTRIBUTION

Report Title Salinity & Aggressivity Assessment

Site Address 291 Flushcombe Road, Blacktown NSW 2148

Project Number SAL- Blacktown

Prepared For Grace Village ELC

Document Number 1

Author Daniel Taylor

Environmental Scientist

B.Sc. (Geology)

Licensed Asbestos Assessor

(Registration Identification LAA 001282)

Date 21st October 2020

Raw Earth Environmental

Pty Ltd

Enquiries:

[email protected]

www.rawearthenvironmental.com.au

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 2

TABLE OF CONTENTS

1. INTRODUCTION ..................................................................................................................... 3

1.1 BACKGROUND .................................................................................................................... 3

1.2 PROPOSED DEVELOPMENT ................................................................................................. 3

1.3 REGULATORY FRAMEWORK ................................................................................................ 4

1.4 FIEDWORK & LABORATORY ANALYSIS ................................................................................. 5

2. SITE INFORMATION ............................................................................................................... 6

2.1 SITE IDENTIFICATION .......................................................................................................... 6

2.2 SITE DESCRIPTION ............................................................................................................... 7

3. FIELDWORK & LABORATORY ANALYSIS .................................................................................. 8

4. SUBSURFACE CONDITIONS .................................................................................................... 9

5. INVESTIGATION CRITERIA .................................................................................................... 10

6. SALINITY & AGGRESSIVITY RESULTS ..................................................................................... 12

7. CONCLUSIONS ..................................................................................................................... 13

8. LIMITATIONS ....................................................................................................................... 15

9. REFERENCES ........................................................................................................................ 17

FIGURES

Figure 1 - Site Locality Plan

Figure 2 - Site Plan

APPENDICES

Appendix A – Laboratory Analytical Results

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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1. INTRODUCTION

1.1 BACKGROUND

Raw Earth Environmental Pty Ltd (Raw Earth) were engaged to conduct a Salinity & Aggressivity

Assessment (SAA) for the property located at 291 Flushcombe Road, Blacktown NSW 2148 (the site).

As shown in Figure 1, the site is located approximately 29.5km west of the Sydney Central Business

District, within the Local Government Area of Blacktown City Council.

The site covers an approximate area of 1,800m2 (as shown in Figure 2) and is identified as Lot 1 DP

871994. The site is currently occupied by one residential single-storey dwelling with a detached

garage and an associated driveway, one small storage shed, one large storage shed, one underground

septic tank and one telecommunications services pit located in the north-western portion of the site.

On-site vegetation showed no signs of decay and/or stress.

1.2 PROPOSED DEVELOPMENT

Raw Earth understand that site is proposed to be redeveloped to allow for the development of a

childcare center which may involve the following works:

● Tree removal and demolition of existing structures; and

● Civil works including construction of new structures and playgrounds.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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Site photographs are included in the Photographic Log in Appendix A.

1.3 REGULATORY FRAMEWORK

The following regulatory framework and guidelines were considered during the preparation of this

report:

● Department of Urban Affairs and Planning, NSW Environmental Protection Authority,

Managing Land Contamination – Planning Guidelines – SEPP 55 – Remediation of Land, 1998;

● National Environment Protection Measures (2013), Schedule B1 – Guideline on Investigation

Levels for Soil and Groundwater;

● National Environment Protection Measures, Schedule B2 – Guideline on Site

Characterisation, 2013;

● NSW Environmental Protection Authority, Waste Classification Guidelines Part 1: Classifying

Waste, 2014;

● NSW Environmental Protection Authority, Sampling Design Guidelines, 1995;

● NSW Environmental Protection Authority, Guidelines on the Duty to Report Contamination

under Contaminated Land Management Act, 1997;

● NSW Department of Environment and Conservation, Guidelines for the Assessment and

Management of Groundwater Contamination, 2007;

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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● NSW Office of Environment & Heritage, Guidelines for Consultants Reporting on

Contaminated Sites, 2011; and

● State Environment Protection Policy 55 (SEPP 55). Remediation of Land Under the

Environmental Planning and Assessment Act.

1.4 FIEDWORK & LABORATORY ANALYSIS

● Site inspections and soil investigation programs were undertaken on 13th October 2020;

● Hand auger excavation of 6 boreholes spread across accessible areas of the site to collect an

even distribution of samples representative of site conditions; and

● Laboratory analysis of samples collected from the site by a National Association of Testing

Authorities (NATA) accredited laboratory.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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2. SITE INFORMATION

2.1 SITE IDENTIFICATION

The location of the site is shown in Figure 1 with a detailed site plan shown in Figure 2.

Table 1: Site Details

Address 291 Flushcombe Road, Blacktown NSW 2148

Deposited plan Lot 1 DP 871994

Locality map Figure 1

Site plan Figure 2

Site photographs Appendix A

Area 1,800m2

Local Government Area Blacktown City Council

Current Land Use R2 low density residential

Surrounding Land Use Residential

Previous Land Use Residential

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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2.2 SITE DESCRIPTION

A qualified Environmental Scientist inspected the site on 13th October 2020. Observations noted

during the inspection are summarised below.

At the time of the site inspection, the site contained the following structures and features:

• The site consisted of a single-storey residential dwelling with one small, and one large shed,

and one chicken shed along the western boundary portion of the site;

• An underground septic tank was also found attached to the residential dwelling, off the

western portion of the main dwelling;

• Potential Asbestos Containing Material (ACM) was suspected being present within the fabric

of on-site structures, including the main dwelling and backyard sheds;

• Flaking paint was identified on external wall surfaces of on-site structures and could contain

lead due to the age of the structures;

• Grass and vegetation which displayed no sign of stress covered most external ground

surfaces with exceptions of the footprints of on-site structures and the concrete driveway in

the south- eastern corner of the site;

• One telecommunications services pit was found located in the front yard (eastern portion);

and

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 8

• There was no evidence of other underground storage tanks, and/or chemical/ fuel storage on

site.

3. FIELDWORK & LABORATORY ANALYSIS

A site inspection and soil sampling program was undertaken on 13th October 2020. Hand auger

excavation of 6 boreholes spread across accessible areas of the site to collect an even distribution of

samples representative of site conditions. Samples were collected from a maximum depth of 0.4m

below ground surface (mbgl) or prior refusal.

Laboratory analysis of samples collected from the site by a National Association of Testing Authorities

(NATA) accredited laboratory.

Soil samples were collected directly from the auger, placed in laboratory prepared 250mL soil jars,

labelled, and placed on ice in an esky for transport under chain of custody (COC) to a NATA accredited

laboratory for the analysis of the COPC. The hand auger was decontaminated between each borehole

excavation with Decon90.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 9

4. SUBSURFACE CONDITIONS

Subsurface conditions across the site as observed during borehole excavations were generally silty

topsoil underlain by a silty clay, brown with pale brown/ orange mottle, humid to moist, medium to

low plasticity. Borehole locations are referenced in Figure 2.

No groundwater was encountered during the investigation. This is due to the shallow excavation of

boreholes. Groundwater may present at the site at an increased depth.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 10

5. INVESTIGATION CRITERIA

Table 2: Salinity & Aggressivity Criteria

Reference Element

Type

High Perm.

Soils

Low Perm.

Soils

pH Chloride

(mg/kg)

Sulfate SO4

(mg/kg)

AS 2159-2009 Concrete

Elements

Mild Non >5.5 N/A <5,000

Moderately Mild 4.5-5.5 5,000-10,000

Severely Moderately 4.0-4.5 10,000-20,000

Very

Severely

Severely <4.0 >20,000

Steel

Elements

Non Non >5.0 <5,000 N/A

Mild Non 4.0-5.0 5,000-20,000

Moderately Mild 3.0-4.0 20,000-50,000

Severely Moderately <3.0 >50,000

Dryland

Salinity 1993

Electrical Conductivity Saturation Extract ECe (dS/m)

value range, based on an introduction of a

multiplication factor from Calculating electrical

conductivity and Salinity (NSW Catchment

Management Authority)

Non-Saline <2

Slightly Saline 2-4

Moderately

Saline

4-8

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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Very Saline 8-16

Highly Saline >16

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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6. SALINITY & AGGRESSIVITY RESULTS

Table 3: Salinity and Aggressivity Results

Sample Reference

Analyte Units SA1 SA2 SA3 SA4

pH 1:5 pH Units 5.9 5.4 5.8 5.6

Chloride mg/kg 7.2 4.3 1.5 92

Sulfate mg/kg 21 16 30 74

Electrical

Conductivity

uS/cm 65 41 47 160

dS/m 0.065 0.041 0.047 0.16

Multiplication

factor (35-40%

clay content)

8.6 8.6 8.6 8.6

ECe (dS/m) 0.559 0.353 0.404 1.376

Aggressivity Steel in low and

high permeability

soils

Non Non Non Non

Page 14: SALINITY & AGGRESSIVITY ASSESSMENT

Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 13

Concrete in low

permeability soils

Non Mild Non Non

Concrete in high

permeability soils

Mild Moderate Mild Mild

Salinity Non-Saline Non-Saline Non-Saline Non-Saline

7. CONCLUSIONS

The property located at 291 Flushcombe Road, Blacktown NSW 2148 (‘the site’) was the subject of a

Salinity & Aggressivity Assessment.

The salinity assessment found site conditions to be Non-saline.

The aggressivity assessment indicates the following:

- Steel in low and high permeability soils were found to be Non-aggressive;

- Concrete in low permeability soils were found to be non-aggressive to mild; and

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 14

- Concrete in high permeability soils were found to be mild to moderate.

It is recommended appropriate foundation design and construction should be further investigated by

a Geotechnical Engineer and/or Structural Engineer prior to the design and construction stage of any

new proposed development to identify and confirm a suitable foundation system.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

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8. LIMITATIONS

Raw Earth Environmental Pty Ltd (Raw Earth) understands to the best of our knowledge, the

information within this report is accurate at the date of issue. However, due to the irregularity and

dynamic nature of subsurface conditions, soil and groundwater characteristics are capable of change

over a short period of time. No warranties, expressed or implied, are made. The contents of this report

must be read in full.

Subsurface conditions across a site cannot be fully defined by an investigation. Soil and/or

groundwater samples were analysed for common contaminants and/or indicators of contamination

only. Sample analytical results obtained during the investigation may not be representative of the

extremes of contamination which could be present at the site. Therefore, there is not guarantee that

other toxic compounds and/or hazardous materials do not exist within the site.

If the unexpected finds of materials suspected to be hazardous or toxic occur, all site works must

cease, and Raw Earth must be immediately contacted for further instruction.

Raw Earth performed the services in a manner consistent with the normal level of care and expertise

exercised by members of the environmental consulting profession. There is no investigation thorough

enough to dismiss a particular material, which presently or in the future is considered hazardous at

the site. Regulatory criteria are subject to change, where concentrations of a particular contaminant

currently considered low, could be subject to review and fall under different regulatory standards and

criteria and may require remediation in the future.

The results of this assessment are based on the site conditions and regulatory criteria identified at the

time of the site inspection. Raw Earth will not be liable to revise the report to account for any changes

in site characteristics, regulatory requirements, assessment criteria or the availability of additional

information, subsequent to the issue date of this report. The scope and period of Raw Earths’ services

are subject to restrictions and limitations. Raw Earth did not perform a complete assessment of all

possible conditions that may exist at the site.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 16

Raw Earth takes no responsibility or liability for errors in any data obtained from scientific laboratories,

regulatory agencies, statements from sources outside of Raw Earth, or developments resulting from

situations outside the scope of this project.

All conclusions and recommendations regarding the site are the opinion of Raw Earth. Opinions are

judgements, which are based on our understanding and interpretation of current regulatory standards

and should not be construed as legal opinions.

We trust the information contained within this document meets your requirements. Should you have

any queries, please do not hesitate to contact the Raw Earth.

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Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 17

9. REFERENCES

● Australian Standard 2159-2009: Piling – Design and Installation.

● Department of Urban Affairs and Planning, NSW Environmental Protection Authority,

Managing Land Contamination – Planning Guidelines – SEPP 55 – Remediation of Land, 1998.

● Department of Mineral Resources, The Geological Map of Penrith, Geological Series Sheet

9030, Scale 1:100,000, Edition 1, 1991.

● Google Earth, https://www.google.com/earth.

● NSW Catchment Management Authority, Calculating Electrical Conductivity and Salinity.

● NSW Department of Natural Resource, Site Investigations for Urban Salinity, dated 2002.

● National Environment Protection Measures, Schedule B1 – Guideline on Investigation Levels

for Soil and Groundwater, 2013.

● National Environment Protection Measures, Schedule B2 – Guideline on Site

Characterisation, 2013.

● NSW Environmental Protection Authority, Waste Classification Guidelines Part 1: Classifying

Waste, 2014.

● NSW Environmental Protection Authority, Sampling Design Guidelines, 1995.

● NSW Environmental Protection Authority, Guidelines on the Duty to Report Contamination

under Contaminated Land Management Act, 1997.

● NSW Department of Environment and Conservation, Guidelines for the Assessment and

Management of Groundwater Contamination, 2007.

● NSW Office of Environment & Heritage, Guidelines for Consultants Reporting on

Contaminated Sites, 2011.

Page 19: SALINITY & AGGRESSIVITY ASSESSMENT

Salinity & Aggressivity Report 291 Flushcombe Road, Blacktown NSW 2148

rawearthenvironmental.com.au 18

● Six Maps, https://www.maps.six.nsw.gov.au.

● State Environment Protection Policy 55 (SEPP 55). Remediation of Land Under the

Environmental Planning and Assessment Act.

● WaterNSW, waternsw.com.au.

Page 20: SALINITY & AGGRESSIVITY ASSESSMENT

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FIGURES

Page 21: SALINITY & AGGRESSIVITY ASSESSMENT

Figure 1 Locality Map

Project 291 Flushcombe Road, Blacktown NSW

Site location

Page 22: SALINITY & AGGRESSIVITY ASSESSMENT

Figure 2 Site Plan

Project 291 Flushcombe Road, Blacktown NSW

Site boundary

Soil Sampling Locations

SA3

SA2

SA1

SA4

Large Shed

Garage

Main Dwelling

Small Shed

Page 23: SALINITY & AGGRESSIVITY ASSESSMENT

rawearthenvironmental.com.au

APPENDIX A

Laboratory Analytical Results

Page 24: SALINITY & AGGRESSIVITY ASSESSMENT

Accreditation No. 2562

Date Reported

Contact

SGS Alexandria Environmental

Unit 16, 33 Maddox St

Alexandria NSW 2015

Huong Crawford

+61 2 8594 0400

+61 2 8594 0499

[email protected]

4

SGS Reference

Email

Facsimile

Telephone

Address

Manager

Laboratory

(Not specified)

SAL - Blacktown

[email protected]

(Not specified)

0409 492 988

3/134 HASTINGS PARADE

NORTH BONDI NSW 2026

RAW EARTH ENVIRONMENTAL

DANIEL TAYLOR

Samples

Order Number

Project

Email

Facsimile

Telephone

Address

Client

CLIENT DETAILS LABORATORY DETAILS

20 Oct 2020

ANALYTICAL REPORT

SE212211 R0

12 Oct 2020Date Received

Accredited for compliance with ISO/IEC 17025 - Testing. NATA accredited laboratory 2562(4354).

COMMENTS

Dong LIANG

Metals/Inorganics Team Leader

Shane MCDERMOTT

Inorganic/Metals Chemist

SIGNATORIES

Member of the SGS Group

www.sgs.com.aut +61 2 8594 0400

f +61 2 8594 0499

Australia

Australia

Alexandria NSW 2015

Alexandria NSW 2015

Unit 16 33 Maddox St

PO Box 6432 Bourke Rd BC

Environment, Health and SafetySGS Australia Pty Ltd

ABN 44 000 964 278

Page 1 of 520-October-2020

Page 25: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0ANALYTICAL REPORT

SE212211.001

Soil

12 Oct 2020

SA1

SE212211.002

Soil

12 Oct 2020

SA2

SE212211.003

Soil

12 Oct 2020

SA3

SE212211.004

Soil

12 Oct 2020

SA4

Parameter LORUnits

Sample Number

Sample Matrix

Sample Date

Sample Name

Soluble Anions (1:5) in Soil by Ion Chromatography Method: AN245 Tested: 13/10/2020

Chloride mg/kg 0.25 7.2 4.3 1.5 92

Sulfate mg/kg 5 21 16 30 74

pH in soil (1:5) Method: AN101 Tested: 13/10/2020

pH pH Units 0.1 5.9 5.4 5.8 5.6

Conductivity and TDS by Calculation - Soil Method: AN106 Tested: 13/10/2020

Conductivity of Extract (1:5 dry sample basis) µS/cm 1 65 41 47 160

Moisture Content Method: AN002 Tested: 16/10/2020

% Moisture %w/w 1 9.4 9.4 8.9 11.5

Page 2 of 520-October-2020

Page 26: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0QC SUMMARY

MB blank results are compared to the Limit of Reporting

LCS and MS spike recoveries are measured as the percentage of analyte recovered from the sample compared the the amount of analyte spiked into the sample.

DUP and MSD relative percent differences are measured against their original counterpart samples according to the formula : the absolute difference of the two results divided

by the average of the two results as a percentage. Where the DUP RPD is 'NA' , the results are less than the LOR and thus the RPD is not applicable.

Conductivity and TDS by Calculation - Soil Method: ME-(AU)-[ENV]AN106

DUP %RPD LCS

%Recovery

Conductivity of Extract (1:5 dry sample basis) LB211103 µS/cm 1 4 - 38% 98%

LORUnits Parameter QC

Reference

Moisture Content Method: ME-(AU)-[ENV]AN002

DUP %RPD

% Moisture LB211399 %w/w 1 1%

LORUnits Parameter QC

Reference

pH in soil (1:5) Method: ME-(AU)-[ENV]AN101

DUP %RPD LCS

%Recovery

pH LB211103 pH Units 0.1 1 - 6% 99%

LORUnits Parameter QC

Reference

Soluble Anions (1:5) in Soil by Ion Chromatography Method: ME-(AU)-[ENV]AN245

MB DUP %RPD LCS

%Recovery

Chloride LB211102 mg/kg 0.25 <0.25 22 - 86% 96%

Sulfate LB211102 mg/kg 5 <5.0 13 - 40% 97%

LORUnits Parameter QC

Reference

Page 3 of 520-October-2020

Page 27: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

METHOD METHODOLOGY SUMMARY

METHOD SUMMARY

The test is carried out by drying (at either 40°C or 105°C) a known mass of sample in a weighed evaporating basin.

After fully dry the sample is re-weighed. Samples such as sludge and sediment having high percentages of

moisture will take some time in a drying oven for complete removal of water.

AN002

pH in Soil Sludge Sediment and Water: pH is measured electrometrically using a combination electrode and is

calibrated against 3 buffers purchased commercially. For soils, sediments and sludges, an extract with water (or

0.01M CaCl2) is made at a ratio of 1:5 and the pH determined and reported on the extract. Reference APHA

4500-H+.

AN101

Conductivity and TDS by Calculation: Conductivity is measured by meter with temperature compensation and is

calibrated against a standard solution of potassium chloride. Conductivity is generally reported as µmhos/cm or

µS/cm @ 25°C. For soils, an extract of as received sample with water is made at a ratio of 1:5 and the EC

determined and reported on the extract, or calculated back to the as-received sample. Salinity can be estimated

from conductivity using a conversion factor, which for natural waters, is in the range 0.55 to 0.75. Reference APHA

2510 B.

AN106

Anions by Ion Chromatography: A water sample is injected into an eluent stream that passes through the ion

chromatographic system where the anions of interest ie Br, Cl, NO2, NO3 and SO4 are separated on their relative

affinities for the active sites on the column packing material . Changes to the conductivity and the UV-visible

absorbance of the eluent enable identification and quantitation of the anions based on their retention time and

peak height or area. APHA 4110 B

AN245

Page 4 of 520-October-2020

Page 28: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Unless it is reported that sampling has been performed by SGS, the samples have been analysed as received.

Solid samples expressed on a dry weight basis.

Where "Total" analyte groups are reported (for example, Total PAHs, Total OC Pesticides) the total will be calculated as the sum of the individual

analytes, with those analytes that are reported as <LOR being assumed to be zero. The summed (Total) limit of reporting is calcuated by summing

the individual analyte LORs and dividing by two. For example, where 16 individual analytes are being summed and each has an LOR of 0.1 mg/kg,

the "Totals" LOR will be 1.6 / 2 (0.8 mg/kg). Where only 2 analytes are being summed, the " Total" LOR will be the sum of those two LORs.

Some totals may not appear to add up because the total is rounded after adding up the raw values.

If reported, measurement uncertainty follow the ± sign after the analytical result and is expressed as the expanded uncertainty calculated using a

coverage factor of 2, providing a level of confidence of approximately 95%, unless stated otherwise in the comments section of this report.

Results reported for samples tested under test methods with codes starting with ARS -SOP, radionuclide or gross radioactivity concentrations are

expressed in becquerel (Bq) per unit of mass or volume or per wipe as stated on the report. Becquerel is the SI unit for activity and equals one

nuclear transformation per second.

Note that in terms of units of radioactivity:

a. 1 Bq is equivalent to 27 pCi

b. 37 MBq is equivalent to 1 mCi

For results reported for samples tested under test methods with codes starting with ARS -SOP, less than (<) values indicate the detection limit for

each radionuclide or parameter for the measurement system used. The respective detection limits have been calculated in accordance with ISO

11929.

The QC and MU criteria are subject to internal review according to the SGS QAQC plan and may be provided on request or alternatively can be

found here: www.sgs.com.au/en-gb/environment-health-and-safety .

This document is issued by the Company under its General Conditions of Service accessible at www.sgs.com/en/Terms-and-Conditions.aspx.

Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein.

Any holder of this document is advised that information contained hereon reflects the Company 's findings at the time of its intervention only and

within the limits of Client's instructions, if any. The Company's sole responsibility is to its Client only. Any unauthorized alteration, forgery or

falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law .

This report must not be reproduced, except in full.

IS

LNR

*

**

***

Insufficient sample for analysis.

Sample listed, but not received.

NATA accreditation does not cover the

performance of this service.

Indicative data, theoretical holding time exceeded.

Indicates that both * and ** apply.

FOOTNOTES

LOR

↑↓

QFH

QFL

-

NVL

Limit of Reporting

Raised or Lowered Limit of Reporting

QC result is above the upper tolerance

QC result is below the lower tolerance

The sample was not analysed for this analyte

Not Validated

Page 5 of 520-October-2020

Page 29: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Date Reported

Contact

SGS Alexandria Environmental

Unit 16, 33 Maddox St

Alexandria NSW 2015

Huong Crawford

+61 2 8594 0400

+61 2 8594 0499

[email protected]

4

SGS Reference

Email

Facsimile

Telephone

Address

Manager

Laboratory

(Not specified)

SAL - Blacktown

[email protected]

(Not specified)

0409 492 988

3/134 HASTINGS PARADE

NORTH BONDI NSW 2026

RAW EARTH ENVIRONMENTAL

DANIEL TAYLOR

Samples

Order Number

Project

Email

Facsimile

Telephone

Address

Client

CLIENT DETAILS LABORATORY DETAILS

20 Oct 2020

STATEMENT OF QA/QC

PERFORMANCE

SE212211 R0

COMMENTS

12 Oct 2020Date Received

All the laboratory data for each environmental matrix was compared to SGS' stated Data Quality Objectives (DQO). Comments

arising from the comparison were made and are reported below.

The data relating to sampling was taken from the Chain of Custody document.

This QA/QC Statement must be read in conjunction with the referenced Analytical Report.

The Statement and the Analytical Report must not be reproduced except in full.

All Data Quality Objectives were met with the exception of the following:

Duplicate Conductivity and TDS by Calculation - Soil 1 item

Soluble Anions (1:5) in Soil by Ion Chromatography 2 items

Samples clearly labelled Yes Complete documentation received YesSample container provider SGS Sample cooling method IceSamples received in correct containers Yes Sample counts by matrix 4 SoilDate documentation received 12/10/2020 Type of documentation received COCSamples received in good order Yes Samples received without headspace YesSample temperature upon receipt 6°C Sufficient sample for analysis YesTurnaround time requested Standard

SAMPLE SUMMARY

Member of the SGS Group

www.sgs.com.aut +61 2 8594 0400

f +61 2 8594 0499

Australia

Australia

Alexandria NSW 2015

Alexandria NSW 2015

Unit 16 33 Maddox St

PO Box 6432 Bourke Rd BC

Environment, Health and SafetySGS Australia Pty Ltd

ABN 44 000 964 278

Page 1 of 920/10/2020

Page 30: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

SGS holding time criteria are drawn from current regulations and are highly dependent on sample container preservation as specified in the SGS “Field Sampling Guide for

Containers and Holding Time” (ref: GU-(AU)-ENV.001). Soil samples guidelines are derived from NEPM "Schedule B(3) Guideline on Laboratory Analysis of Potentially

Contaminated Soils". Water sample guidelines are derived from "AS/NZS 5667.1 : 1998 Water Quality - sampling part 1" and APHA "Standard Methods for the Examination

of Water and Wastewater" 21st edition 2005.

Extraction and analysis holding time due dates listed are calculated from the date sampled, although holding times may be extended after laboratory extraction for some

analytes. The due dates are the suggested dates that samples may be held before extraction or analysis and still be considered valid.

Extraction and analysis dates are shown in Green when within suggested criteria or Red with an appended dagger symbol (†) when outside suggested criteria. If the sampled

date is not supplied then compliance with criteria cannot be determined. If the received date is after one or both due dates then holding time will fail by default.

HOLDING TIME SUMMARY

Method: ME-(AU)-[ENV]AN106Conductivity and TDS by Calculation - Soil

Sample No.Sample Name QC Ref Sampled Received Extraction Due Extracted Analysis Due Analysed

SA1 SE212211.001 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 19 Oct 2020 19 Oct 2020

SA2 SE212211.002 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 19 Oct 2020 19 Oct 2020

SA3 SE212211.003 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 19 Oct 2020 19 Oct 2020

SA4 SE212211.004 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 19 Oct 2020 19 Oct 2020

Method: ME-(AU)-[ENV]AN002Moisture Content

Sample No.Sample Name QC Ref Sampled Received Extraction Due Extracted Analysis Due Analysed

SA1 SE212211.001 LB211399 12 Oct 2020 12 Oct 2020 26 Oct 2020 16 Oct 2020 21 Oct 2020 19 Oct 2020

SA2 SE212211.002 LB211399 12 Oct 2020 12 Oct 2020 26 Oct 2020 16 Oct 2020 21 Oct 2020 19 Oct 2020

SA3 SE212211.003 LB211399 12 Oct 2020 12 Oct 2020 26 Oct 2020 16 Oct 2020 21 Oct 2020 19 Oct 2020

SA4 SE212211.004 LB211399 12 Oct 2020 12 Oct 2020 26 Oct 2020 16 Oct 2020 21 Oct 2020 19 Oct 2020

Method: ME-(AU)-[ENV]AN101pH in soil (1:5)

Sample No.Sample Name QC Ref Sampled Received Extraction Due Extracted Analysis Due Analysed

SA1 SE212211.001 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 14 Oct 2020 13 Oct 2020

SA2 SE212211.002 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 14 Oct 2020 13 Oct 2020

SA3 SE212211.003 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 14 Oct 2020 13 Oct 2020

SA4 SE212211.004 LB211103 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 14 Oct 2020 13 Oct 2020

Method: ME-(AU)-[ENV]AN245Soluble Anions (1:5) in Soil by Ion Chromatography

Sample No.Sample Name QC Ref Sampled Received Extraction Due Extracted Analysis Due Analysed

SA1 SE212211.001 LB211102 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 10 Nov 2020 20 Oct 2020

SA2 SE212211.002 LB211102 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 10 Nov 2020 20 Oct 2020

SA3 SE212211.003 LB211102 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 10 Nov 2020 20 Oct 2020

SA4 SE212211.004 LB211102 12 Oct 2020 12 Oct 2020 19 Oct 2020 13 Oct 2020 10 Nov 2020 20 Oct 2020

20/10/2020 Page 2 of 9

Page 31: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Surrogate results are evaluated against upper and lower limit criteria established in the SGS QA /QC plan (Ref: MP-(AU)-[ENV]QU-022). At least two of three routine level soil

sample surrogate spike recoveries for BTEX/VOC are to be within 70-130% where control charts have not been developed and within the established control limits for charted

surrogates. Matrix effects may void this as an acceptance criterion. Water sample surrogate spike recoveries are to be within 40-130%. The presence of emulsions,

surfactants and particulates may void this as an acceptance criterion.

Result is shown in Green when within suggested criteria or Red with an appended reason identifer when outside suggested criteria. Refer to the footnotes section at the end

of this report for failure reasons.

SURROGATES

No surrogates were required for this job.

20/10/2020 Page 3 of 9

Page 32: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Blank results are evaluated against the limit of reporting (LOR), for the chosen method and its associated instrumentation, typically 2.5 times the statistically determined

method detection limit (MDL).

Result is shown in Green when within suggested criteria or Red with an appended dagger symbol (†) when outside suggested criteria.

METHOD BLANKS

Conductivity and TDS by Calculation - Soil Method: ME-(AU)-[ENV]AN106

Sample Number Parameter Units LOR Result

LB211103.001 Conductivity of Extract (1:5 dry sample basis) µS/cm 1 0.71

Soluble Anions (1:5) in Soil by Ion Chromatography Method: ME-(AU)-[ENV]AN245

Sample Number Parameter Units LOR Result

LB211102.001 Chloride mg/kg 0.25 <0.25

Sulfate mg/kg 5 <5.0

20/10/2020 Page 4 of 9

Page 33: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Duplicates are calculated as Relative Percentage Difference (RPD) using the formula: RPD = | OriginalResult - ReplicateResult | x 100 / Mean

The RPD is evaluated against the Maximum Allowable Difference (MAD) criteria and can be graphically represented by a curve calculated from the Statistical Detection Limit

(SDL) and Limiting Repeatability (LR) using the formula: MAD = 100 x SDL / Mean + LR

Where the Maximum Allowable Difference evaluates to a number larger than 200 it is displayed as 200.

RPD is shown in Green when within suggested criteria or Red with an appended reason identifer when outside suggested criteria. Refer to the footnotes section at the end of

this report for failure reasons.

DUPLICATES

Conductivity and TDS by Calculation - Soil Method: ME-(AU)-[ENV]AN106

UnitsParameterOriginal LORDuplicate Original Duplicate Criteria % RPD %

SE212211.001 LB211103.014 Conductivity of Extract (1:5 dry sample basis) µS/cm 1 65 68.1990996060 33 4

SE212211.004 LB211103.018 Conductivity of Extract (1:5 dry sample basis) µS/cm 1 160 108.3473462953 31 38 ②

Moisture Content Method: ME-(AU)-[ENV]AN002

UnitsParameterOriginal LORDuplicate Original Duplicate Criteria % RPD %

SE212211.004 LB211399.016 % Moisture %w/w 1 11.5 11.4 39 1

pH in soil (1:5) Method: ME-(AU)-[ENV]AN101

UnitsParameterOriginal LORDuplicate Original Duplicate Criteria % RPD %

SE212211.001 LB211103.014 pH pH Units 0.1 5.9 6.0 32 1

SE212211.004 LB211103.018 pH pH Units 0.1 5.6 6.0 32 6

Soluble Anions (1:5) in Soil by Ion Chromatography Method: ME-(AU)-[ENV]AN245

UnitsParameterOriginal LORDuplicate Original Duplicate Criteria % RPD %

SE212211.001 LB211102.014 Chloride mg/kg 0.25 7.2 5.8 34 22

Sulfate mg/kg 5 21 18 56 13

SE212211.004 LB211102.018 Chloride mg/kg 0.25 92 37 30 86 ②

Sulfate mg/kg 5 74 49 38 40 ②

20/10/2020 Page 5 of 9

Page 34: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Laboratory Control Standard (LCS) results are evaluated against an expected result, typically the concentration of analyte spiked into the control during the sample

preparation stage, producing a percentage recovery. The criteria applied to the percentage recovery is established in the SGS QA /QC plan (Ref: MP-(AU)-[ENV]QU-022). For

more information refer to the footnotes in the concluding page of this report.

Recovery is shown in Green when within suggested criteria or Red with an appended dagger symbol (†) when outside suggested criteria.

LABORATORY CONTROL SAMPLES

Conductivity and TDS by Calculation - Soil Method: ME-(AU)-[ENV]AN106

LORUnitsParameterSample Number Result Expected Criteria % Recovery %

LB211103.002 Conductivity of Extract (1:5 dry sample basis) µS/cm 1 NA 303 85 - 115 98

pH in soil (1:5) Method: ME-(AU)-[ENV]AN101

LORUnitsParameterSample Number Result Expected Criteria % Recovery %

LB211103.003 pH pH Units 0.1 7.4 7.415 98 - 102 99

Soluble Anions (1:5) in Soil by Ion Chromatography Method: ME-(AU)-[ENV]AN245

LORUnitsParameterSample Number Result Expected Criteria % Recovery %

LB211102.002 Chloride mg/kg 0.25 96 100 70 - 130 96

Sulfate mg/kg 5 97 100 70 - 130 97

20/10/2020 Page 6 of 9

Page 35: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Matrix Spike (MS) results are evaluated as the percentage recovery of an expected result, typically the concentration of analyte spiked into a field sub -sample during the

sample preparation stage. The original sample 's result is subtracted from the sub-sample result before determining the percentage recovery. The criteria applied to the

percentage recovery is established in the SGS QA/QC plan (ref: MP-(AU)-[ENV]QU-022). For more information refer to the footnotes in the concluding page of this report.

Recovery is shown in Green when within suggested criteria or Red with an appended reason identifer when outside suggested criteria. Refer to the footnotes section at the

end of this report for failure reasons.

MATRIX SPIKES

No matrix spikes were required for this job.

20/10/2020 Page 7 of 9

Page 36: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0

Matrix spike duplicates are calculated as Relative Percent Difference (RPD) using the formula: RPD = | OriginalResult - ReplicateResult | x 100 / Mean

The original result is the analyte concentration of the matrix spike. The Duplicate result is the analyte concentration of the matrix spike duplicate.

The RPD is evaluated against the Maximum Allowable Difference (MAD) criteria and can be graphically represented by a curve calculated from the Statistical Detection Limit (SDL) and Limiting Repeatability (LR) using the formula: MAD = 100 x SDL / Mean + LR

Where the Maximum Allowable Difference evaluates to a number larger than 200 it is displayed as 200.

RPD is shown in Green when within suggested criteria or Red with an appended reason identifer when outside suggested criteria. Refer to the footnotes section at the end of this report for failure reasons.

MATRIX SPIKE DUPLICATES

No matrix spike duplicates were required for this job.

20/10/2020 Page 8 of 9

Page 37: SALINITY & AGGRESSIVITY ASSESSMENT

SE212211 R0FOOTNOTES

Samples analysed as received.

Solid samples expressed on a dry weight basis.

QC criteria are subject to internal review according to the SGS QA/QC plan and may be provided on request or alternatively can be found here :

https://www.sgs.com.au/~/media/Local/Australia/Documents/Technical Documents/MP-AU-ENV-QU-022 QA QC Plan.pdf

① At least 2 of 3 surrogates are within acceptance criteria.

② RPD failed acceptance criteria due to sample heterogeneity.

③ Results less than 5 times LOR preclude acceptance criteria for RPD.

④ Recovery failed acceptance criteria due to matrix interference.

⑤ Recovery failed acceptance criteria due to the presence of significant concentration of analyte (i.e. the

concentration of analyte exceeds the spike level).

⑥ LOR was raised due to sample matrix interference.

⑦ LOR was raised due to dilution of significantly high concentration of analyte in sample.

⑧ Reanalysis of sample in duplicate confirmed sample heterogeneity and inconsistency of results.

⑨ Recovery failed acceptance criteria due to sample heterogeneity.

⑩ LOR was raised due to high conductivity of the sample (required dilution).

† Refer to relevant report comments for further information.

*

**

***

-

IS

LNR

LOR

QFH

QFL

NATA accreditation does not cover the performance of this service .

Indicative data, theoretical holding time exceeded.

Indicates that both * and ** apply.

Sample not analysed for this analyte.

Insufficient sample for analysis.

Sample listed, but not received.

Limit of reporting.

QC result is above the upper tolerance.

QC result is below the lower tolerance.

This document is issued by the Company under its General Conditions of Service accessible at www.sgs.com/en/Terms-and-Conditions.aspx.

Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein.

Any holder of this document is advised that information contained hereon reflects the Company 's findings at the time of its intervention only and

within the limits of Client's instructions, if any. The Company's sole responsibility is to its Client only. Any unauthorized alteration, forgery or

falsification of the content or appearance of this document is unlawful and offenders may be prosecuted to the fullest extent of the law .

This test report shall not be reproduced, except in full.

20/10/2020 Page 9 of 9

Page 38: SALINITY & AGGRESSIVITY ASSESSMENT

M

_ )SGS CHAIN OF CUSTODY & ANALYSIS REQUEST Page_1_of _1_

SGS Environmental Services Company Name: Raw Earth Environmental project Name/No: gfL " e\acUie'gj^ .Unit 16, 33 Maddox Street Address: Hastings Pde, Bondi NSW Purchase Order No:Alexandria NSW 2015 Results Required By: StandardTelephone No: (02) 85940400 Telephone: 0409492988Facsimile No: (02) 85940499 Contact Name: Daniel Taylor Facsimile:Email: au.samplereceij.t.sy [email protected] Email Results: [email protected]

U)CLljj

LLJ Z

"""" '"""" '" Sa":::ed '"'j:'" ! i S 1, i

§ d § 2 d dSAt )Z/'o I 7" _ __ ,JCJ " K K

9tk- ' _ 2 __ x' _ __ > " " fUf8 3 "'C" p )0 pGrIM )

)

-X- ---- - _ - Y " Ytl'folD

tMC- ) --- ---' - -- -- --—----- Hr"Ljj

t- - SGS EHS Sydney COC

-SE212211"""" l'|||MmmNii|ln|||ll|i|ll||lilll||i

/

- 1 ' ' ' t---R.,,n,u,.,., By' F) "i 7 1t~- """ Da'e/Time: Received By' GemCye- 'ZKt ' Da'e"'m" ( z/'tQ / 20 (9 51" ""nRelinquished By: Date/Time: ' Received By: Date/Time

Samples Intact' / No " " """ "" " Temperature: Ambient / ille ' Sample Cooler Sealed: Yesl No " Laboratory Quotation No:/1 Comments:

Page 39: SALINITY & AGGRESSIVITY ASSESSMENT

SAMPLE RECEIPT ADVICE SE212211

CLIENT DETAILS

(Not specified)

Email Email

Address

Project

Order Number

SGS Reference

(Not specified)

SAL - Blacktown

Client

Contact

RAW EARTH ENVIRONMENTAL

DANIEL TAYLOR

Address 3/134 HASTINGS PARADE

NORTH BONDI NSW 2026

LABORATORY DETAILS

Laboratory

Manager

Telephone

Facsimile

Report Due

Facsimile

Telephone

Samples 4

0409 492 988

[email protected]

Samples Received

SGS Alexandria Environmental

Huong Crawford

+61 2 8594 0400

+61 2 8594 0499

[email protected]

Unit 16, 33 Maddox St

Alexandria NSW 2015

SUBMISSION DETAILS

This is to confirm that 4 samples were received on Monday 12/10/2020. Results are expected to be ready by COB Tuesday 20/10/2020. Please

quote SGS reference SE212211 when making enquiries. Refer below for details relating to sample integrity upon receipt.

Mon 12/10/2020

Tue 20/10/2020

SE212211

Samples clearly labelled Yes Complete documentation received YesSample container provider SGS Sample cooling method IceSamples received in correct containers Yes Sample counts by matrix 4 SoilDate documentation received 12/10/2020 Type of documentation received COCSamples received in good order Yes Samples received without headspace YesSample temperature upon receipt 6°C Sufficient sample for analysis YesTurnaround time requested Standard

2 soil samples have been placed on hold as no tests have been assigned for them by the client. These samples will not be processed.

Unless otherwise instructed, water and bulk samples will be held for one month from date of report, and soil samples will be held for two months.

COMMENTS

This document is issued by the Company under its General Conditions of Service accessible at www.sgs.com/en/Terms-and-Conditions.aspx.

Attention is drawn to the limitation of liability, indemnification and jurisdiction issues defined therein.

Member of the SGS Group

www.sgs.com.aut +61 2 8594 0400

f +61 2 8594 0499

Australia

Australia

Alexandria NSW 2015

Alexandria NSW 2015

Unit 16 33 Maddox St

PO Box 6432 Bourke Rd BC

Environment, Health and SafetySGS Australia Pty Ltd

ABN 44 000 964 278

Page 40: SALINITY & AGGRESSIVITY ASSESSMENT

SAMPLE RECEIPT ADVICE SE212211

CLIENT DETAILS

SAL - BlacktownRAW EARTH ENVIRONMENTAL ProjectClient

SUMMARY OF ANALYSIS

No. Sample ID Co

nd

uct

ivity a

nd

TD

S b

y

Ca

lcu

latio

n -

So

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Mo

istu

re C

on

ten

t

pH

in s

oil

(1:5

)

So

lub

le A

nio

ns (

1:5

) in

So

il

by

Ion

Ch

rom

ato

gra

ph

y

001 SA1 1 1 1 2

002 SA2 1 1 1 2

003 SA3 1 1 1 2

004 SA4 1 1 1 2

The above table represents SGS' interpretation of the client-supplied Chain Of Custody document.

The numbers shown in the table indicate the number of results requested in each package.

Please indicate as soon as possible should your request differ from these details .

Testing as per this table shall commence immediately unless the client intervenes with a correction .

Page 2 of 213/10/2020


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