SDMS Document
V_ 112252
SEl Contract; Noo 68-W-98-210
RACII r'
Remedial Response^ Enforcement. Oversight and Non-time. Critical Removal•'Activities a t Sites of Release or Threatened Release of Haza rdous Substances in EPA Region II
Federal Programs Gorporation A Subsidiary of Camp Dresser.& McKee Inc: • . • • ' • ' .
in association with TAMS-
300477
I h
REVISED HEALTH AND SAFETY PLAN HITEMAN LEATHER SITE
REMEDIAL INVESTIGATION/FEASABILITY STUDY WEST WINFIELD, NEW YORK
Work Assignment No.: 032-RICO-02CG
f Prepared for:
U.S. Environmental Protection Agency 290 Broadway
New York, New York 10007-1866
Prepared by: CDM Federal Programs Corporation
125 Maiden Lane - 5* Floor - New York, New York 10038
b
EPA Work Assignment No. EPA Region Contract No. CDM Federal Programs Corporation Document No. Prepared by
Site Manager Telephone Number EPA Remedial Project Manager Telephone Number ' Date Prepared
032-RICO-02CG n 68-W-98-2I0.
3220-032-PP-HASP-01766 CDM FEDER.^L PROGRAMS CORPORATION Pamela Philip (212)785-9123 Jack O'Dell (212) 637-4256 .
January 23, 2001
300478
CDM Federal Programs Corporation A subsidiary of Camp Oresser & McKae Inc.
consulting
engineering
cansinjcrian
operations
125 Maiden Lane 5th Floor NewYork, Mew York 10038 Tel: 212 785-9123 Fax:212 785-6114
January 23, 2001
p
w
Mr. Joel Singerman, Chief Central New York Remediation Section Remedial Project Manager
' U.S. Environmental Protection Agency 290 Broadway New York, NY 10007-1866
Mr. Jack O'Dell Remedial Project Manager U.S. Environmental Protection Agency 290 Broadway New York, NY 10007-1866 '
PROJECT;
DOC CONTROL NO.:
SUBJECT:
RAC n Contract No.: 68-W-98-210 Work Assignment No.: 032-RICO-02CG
3220-032-PP-HASP-01766
Revised Health and Safety Plan , Hiteman Leather Site Remedial Investigation/Feasability Study WestWinfield, New York '
Dear Mr. Singerman and Mr. O'Dell " , '
CDM. Federal Programs Corporation (CDM Federal), on behalf of our entire RA.C U Team, is pleased to submit this Revised Health.and Safety Plan for the Hiteman Leather Site at West Winfield, New York as partial fulfillment of Subtask No. 1.8 ofthe Statement of Work., Please note that the Health and Safety Plan has been revised to address EPA's comments (dated December 29, 2000) on the original plan. - .
If you have any questions regarding this submittal, please contact Pamela Philip at (212) 785-9123 ormyself at (908) 757-9500. . ' - ' ,
Very truly yours, • • ' ' ' CDM FEDER.AL PROGR^^MS CORPOR.ATION'
J^nne Litwin, REM . •_, . „ RAC II Technical Operations Manager _ . , , '
cc: F, Rosado, EPA-Region n f:P,Philip, CDM Federal, - • D, Butier, EPA Region n (Letter Only)"RAC H-Document Control R. Goltz/PSO File, CDM Federal
3 0 0 4 7 9
C;\Philip\PHlLlP\FiLES\lQtus\Orfic2l032\adrnnlTechnic3l Deliverable Ltr,',»od
A)
O
O o I I
300480
I
f
i
TABLE OF CONTENTS
PAGE
HEALTH AND SAFETY PLAN ^ , . . . , . . . 1
ACTIVITY HAZARD ANALYSIS . . . . . ; : 14
APPENDICES
APPENDIXA; COLD STRESS
APPENDIX B: HEAT STRESS
APPENDIX C: INCIDENT REPORT
APPENDIXD: OSHAPOSTER
APPENDIX E: EMPLOYEE MEETING RECORD
APPENDIX F: MATERIAL SAFETY DATA SHEETS
300481
tIEALTJl ANl) SAFETY PLAN TOKM
CDM Federal Uealtli and Safety Program
CDM FEDERAL PROGRAMS CORPORATION
PROJfECT DOCUMENT NO.: 3220-n.u-FP-HAS|-'-0|7(S6
MlOJECr NAMli 1-lilenwn Leullier RI/F,S WORK ASSIGNMEN T NO 032-WCO-02CG lUiGlON II
JOBSITE ADDRESS South Street CLIENT: EPA
West Winfield; NY. PROJECT NO. 3220-032
SITE CONTACT John Grabs, P,G. CLIENT CONTACT: Jack O'Dell
PHONE NO, To be installed on-site. PHONE NO, (212) 637-4256
( ) AMENDMENT NO, TO EXISTING APPROVED HSP - DATE EXISTING APPROVED HSP
OBJECTPVES OF FIELD WORK:
Tlie objectives of this project include drilling and installation of monitoring wells.as well as to sample surface water, groundwater, sediment, and surface soil. Other activities will include soil borings, test pits, and aquifer testing, Tliese activities are part of a remedial investigalion. and are to support a site decision document.
CDM FEDERAL HEALTH AND SAFETY PROGRAM MANUAL
The CDM Federal Health and Safety Program Manual includes a full description of required training in Section 4, site communications in Section 5, and HAZCOM in Sections 4 and 11. A copy of the CDM Federal Health and Safety Program Manual will be maintained on site at all times. The CDM Federal Health and Safety Program Manual is readily available in both hard copy and electronic versions off the CDM Federal Health and Safety website at: http://fednet/H&S/H&s.htm ;
TYPE: Check as many as applicable
( ) Active ( ) Landfill
(, X ) Inactive ( ) Uncontrolled
,( ) Secure ( X ) hidustrial
( ) Unknown
( ) Military
( X ) Other: Lagoons
( X ) Unsecure
( ) Enclosed space
( ) Recovery
( ) Well Field
DESCRIPTION AND FEATURES: Summarize below. Include principal operations and unusual features (containers, buildings, dykes, power lines, hills, slopes, river)
The site is a former taimery and leather manufacturing facility located on the banks ofthe Unadilla River in West Winfield, Herkimer County, NewYork, approximately 100 miles west of Albany, The site is approximately 14 acres in size. The current features of the site include the remaining foundations/concrete pads ofthe fonner factory buildings, a macadam parking lot, two small buildings (a garage and shed), three backfilled wastewater lagoons (raiiging from 30-50 feet wide by 150-340 feet long), a 2 acre wetland, an open field area, a back-filled area, and-600-700 feet ofthe Unadilla River, •
A site visit was conducted on March 2, 2000. Debris from building demolition is on the site. Two buildings still exist, including a storage garage that is maintained and operated by tiie West Winfield Department of Public Works, The portion of the site fence that runs along the Unadilla River was noted to be damaged in several places, which could allow access to the site property, • '
SURROUNDING POPULATION: ( X ) Residential ( ) Industrial ( X ) Rural ( ) Urban ( ) OTHER: Page 1 of 1
zs^ooe
t^loles; ,
hifonuRlion slio\vii nn this figue Is exlracled from the rcporl'cnlUled, "Final llozaril
Ranking System Eviilualionrl lileman Leather Company, West Winfield, Herkimer
Coiiiily. NY (Voliiiiie 2 of 6)", diiled August IB, 1998, This rig\itc was prepared by ihe
LIS Itespoiise I cam Center for Ihe USEPA.
HITEMAN LEATHER COMPANY VILLAGE OF WEST WINFIELD
HERKIMER COUNTY, NEW Y O R K
ruEfAREDfOR US Envirniiincntiil I'l olectioii Agency Coiilriicl No. 68-\V-98-2in Asslgiiiiient No. O J l - I U C O - d l C C
CDM Feileial/TAMS CnnsiiKmils, Inc. ILVC II Tenm
Figure No. 1-2
£8^ooe
HEALTH AND SAFETY PLAN FORM CDM FEDERAL PROGRAMS CORPORATION
CDM pKlernl Health and Sttfety Program
HISTORY: Summarize below, hi addition to history, include complaints from public, previous agency actions, known exposures or injuries, etc, •
Tlie Hiteman Leather Company operated from 1820 until the plant closed in 1968, The process changed from vegetable-based tanning (eg,, tree bark) to cliromium salts and acid solutions. Prior to 1959, wastewater was routed to onsite lagoons. In 1959, a fislikill was noted in the Unadilla River, which led to the lagoons being dredged and a third lagoon being added. Estimated maximum discharge was 180,000 GPD, the total quantity of discharged wastewater is unknown. The facility was shut down in 1968 due to inability to upgrade the water treatment process. The lagoons were backfilled, and no fiirther site activities (save for use of two onsite buildings by the local DPW) occurred.
An RI/FS was conducted from 1988 to 1992 by SAIC Engineering hic, prepared for the NYSDEC. The RI/FS included tl\e installation and sampling of 24 monitoring wells, 10 piezometers, and 13 soil borings, and the collection of four surface water, 20 surface soil, eight wetland sediment, and 12 river sediment samples (NYSDEC. 1992), Study results documented the presence of high levels of chromiuin in the lagoon area soils and ii\dicated contamination tliroughout the site. Other heavy metals, pesticides, polychorinated biphenyls (PCBs), volatile organic compounds (VOCs) and semivolatile organic compounds (SVOC) were also detected, at lower concentrations, throughout the site in various environmental media. Based on the results ofthe W/FS, NYSDEC subsequently referred the site to EPA. During the subsequent Site hivestigation (SI), soil samples were collected from 50 on-site locations and tlu-ee off-site locations (EPA, 1998), It concluded that the main taimery building and stack were structurally unsound. •
An HRS evaluation was conducted for the site in August 1998, Based on the 1996 SI, the site was assigned an HRS score of 50. The Hiteman Leather Site was proposed for the National Priorities List (NPL) in September, 1998 and was subsequently listed on the NPL on January 19, 1999. '
WASTE TYPES: ( X ) Liquid ( X ) Solid () Sludge ( ) Gas (. ) Unknown ( ) Other -.
WASTE CIL'^RACTERISTICS: Check as many as applicable.
( X ) Corrosive ( X ) Flammable ( ) Radioactive
( X ) Toxic ( ) Volafile ( ) Reactive
( ) h\ert Gas ( ) Ui\known ( ) Otlier specify:
WORK ZONES: Tl\e exclusion zone (EZ) includes all active areas in which contaminants may affect persormel through exposure routes, and/or in which heavy equipment and other hazardous materials may be used. The EZ will be marked off with stakes and tape. At a minirrium, an area within 50 feet of drilling operations will be considered an exclusion zone. The contamination reduction/ decontamination zone (CRZ) is the transition area between the EZ and the support zone (SZ). These zones will be established such that the wind direction is from Uie SZ to the EZ. Extra care will be required for work conducted in residential properties. Exclusion, Contaminants Reduction, and Support Zones will be detemiined by the site health & safety officer during mobilization. Other parts ofthe site will be defined on an as-needed basis, CDM Federal will use the buddy system at all times. No persomiel will be alone on site during intnisive activities, -
IL^ARDS OF CONCERN:
( X ) Heat Stress attach guidelines ( ) Noise
( X ) Cold Stress attach guidelines ( X ) Inorganic Chemicals
PRINCIPAL DISPOSAL METHODS ANi:) PRACTICES: Summarize below:
Plant wastewater was pumped into onsite settling lagoons, with effluent flowing into the Unadilla River or the adjacent wetlands. Settled solids were periodically excavated and deposited as bank material surrounding the lagoons.
( X ) Explosive/Flanunable
( ) Oxygen Deficient
( ) Radiological
( ) Biological
( ) Other specify:
( X ) Organic Chemicals
( ) Motorized Traffic
( X ) Heavy Machinery
( X ) Slips.Trips&Falls
P a g e 3 o n 3
1'8^'Ooe
HEALTH AND SAFETY PLAN FORM
CDM r'tjdcrai Health anil Sttfetv Pix>grutn
CDM FEDERAL PROGRAMS CORrORAllON
1 lAZARDOl IS MATERIAI SUMMARY Ciicle waste type and estimate amounts by cateuory |
CITEMICALS Amounts/Units: ,
/Acids
Pickling Liquors
/Caustics
Pesticides
Dyes/hiks
Cyanides
Phenols
Halogens
Dioxins ,
Other
/ Speclly: Taimery wastes (hexavalent chromiuin)
•
SOLIDS -> Amounts/Units:
Flyash
Asbestos
Milling/Mine Tailings
Feaous Smelter
Non-ferrous Smelter
Metals
Other
Specify:
SLUDGES , ' Amounts/Units:
Paint
Pigments
Metal Sludges
POTW Sludge
Aluminum
Distillation Bottoms
Other
Specify: '
SOLVENTS Amounts/Units:
/ Halogenated (chloro, bromo) Solvents
/ Hydrocarbons
Alcohols
Ketones •
Esters
Ethers
Other
Specify:
'
OILS ' Amounts/Units:
Oily Wastes
•
Gasoline
Diesel Oil
Lubricants
PCBs
Polynuclear Aromatics
Otlier
Specify;
OTHER AmountsAJnits:
Laboratory
Pharmaceutical
Hospital
Radiological
Municipal
Construction "
Munitions
Other
Specify:
OVERALL FIAZARD EVALUATION: ( ) High ( ) Medium { X ) Low ( ) Unknown (Where tasks have different hazards, evaluate each. Attach addifional sheets if necessary) See attached Activity Hazard Analysis.
JUSTIFICATION: Record search ;: ' ' • '
FIRE/EXPLOSION POTENTIAL: ( ) High ( ) Medium ( X ) Low ( ) Unkno\vn •
BACKOROONDREVrEW: ( X ) COMPLEIE ( ) INCOMPLETE Page 4 of 13
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HEALTH AND SAFETY PLAN FORM CDM FEDERAL PROGRAMS CORPORATION
CDM Federal Iliialih and Safety Program
KNOWN CONTAMINANTS
Arsenic
Barium
Chromium
Calcium
Lead
Manganese
Mercurj'
Vanadium
m & p-Xylene
HIGHEST OBSERVED CONCENTRATION
(specify units and media)
52 ing/kg-SD 4,2 mg/kg-GW
130 mgAcg-SD •
71,000 mg/kg-SD 75,000 mgAcg-S 5,7 mg/kg-SW
270,000 mg/kg-SD
280 mg/kg-SD
760 mg/kg-SD
0.14 mg/kg-SD
30mg/kg-SD'
lOOug/1-GW^
PEL/n,V ppm or mg/m'
(specify)
0.010 mg/m'
0 5 mg/m'
0,5 mg/m'
10 mg/m'
0,050 mg/m'
I mg/m'
0.05 mg/m'
0.05 mg/m'
100 ppm
IDLH ppm or mg/m' • (specify)
5 mg/in'
50 mg/m'
25 mg/m'
ND
100 mg/m'
500 mg/m'
10 mg/m'
35 mg/m'
900ppm
SYMPTOMS/EFFECTS OF ACU IE EXPOSURE
Routes: Inhalation, skin absorjition. skin and/or eye contact, ingestion Symptoms: Nasal ulcers, fever, bronchitis, melanosis, peripheral neuropatliy Chronic Effect; Carcinogen
Routes: Inhalation, ingestion, skin and/or eye contact Symptoms; Muscle spasms, slow pulse, bronchial irritation, eye and skin irritation
Routes; Inhalation, ingestion, skin and/or eye contact Symptoms: Lung damage, skin sensitization, eye irritation
Routes: Inhalation, ingestion, skin and/or eye contact Symptoms: Irritates eyes, skin, respiratory system
Routes: lidialation, ingestion, skin and/or eye contact Symptoms; Fatigue, pallor, colic, insomnia
Routes; Inhalation, mgestion Symptoms: "Dead face", dry throat, cough, metal fiime fever, insonmia, mental conftision •
Routes: hihalation. skin absorption, ingestion, skin and/or eye contact Symptoms: Severe abdominal pain, tremors, weataiess, GI irritation, fatigue, cough
Routes: hihalation. ingestion, skin and/or eye contact liritation of eyes and tliroat. green tongue, metallic taste, cough, eczema
Routes; hilialation, skin absorption, ingestion, skin and/or eye'contact Symptoms; Irritation of eyes, skin, nose and throat, dizziitess, nausea
PHOTOIONIZATION POTEN'ITAL '
NA
NA
NA
NA
NA
NA
NE
NA . \ ,
8,56
Material Safety Data Sheets (MSDSs) for all known contaminants are attached and will be kept with the on-site HASP. CDM Federal staffwill be made aware of the on-site locafion of the MSDSs.
Paee5 of 13
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HEALTH AND SAFETY PLAN FORM CDM PEDRRAL PROGRAMS CORPORATION
CDM Federal Health and Safety Program
KNOWN CONTAMINANTS
Trimethylbenzene
Endrin
Chlordane
Aldrin
*
HIGHEST OBSERVED CONGENTRATION
(specify units and media)
l30ug/l-GW
2,0 mg/kg-SD
31 mg/kg-SD
9,1 mg/kg-SD
PEL/TLV ppm or mg/m'
(specify)
25 ppm
0,1 mg/m'
0,5 mg/m'
•
0,25 mg/m'
IDLH ppm or mg/m'
(specify)
ND
2,0 mg/m'
100 mg/m'
25 mg/m'
SYMPTOMS/EFFECTS OF ACUTE EXPOSURE
Routes: Inhalation, ingestion, skin and/or eye contact Symptoms; Irritation of eye. nose & throat, pneumonia, fatigue, dizziness
Routes: Inhalation, skin absorption, ingesrion, skin and/or eye contact Symptoms: Convulsions, stupor, dizziness, ' , headache, nausea
Routes; Inlialation. skin absorption, ingestioti. skin and/or eye contact Symptoms: Confusion, blurred vision, nausea. ataxia, delirium, tremors Clu-onic Effect: Carcinogen
Routes: Inhalation, skin absorption, ingestion, skin and/or eye contact Symptoms: Headache, dizzy, nausea, limb jerks Chronic Effect: Carcinogen
PHOTOIONIZATION POTENTIAL
8,27
NE
NE ~ •
NE
NA=Not Available NE = None Estabhshed ND=None SL=Sludge U=Unknown SD=Sediment S=Soil SW=Surface Water Determined W=Waste OFF=Offsite. A = Air GW=Groundwater T=Tailings
Material Safety Data Sheets (MSDSs) for all known contaminants are attached and wiU be kept with the on-site HASP. CDM Federal staffwill be made aware ofthe on-site location ofthe MSDSs. . •
Page 6 of 13
Ui o o »( 00
IfEALTH AND SAFETY PLAN FORM
CDM Federal Health and Safely Program
;||||||||i|i|||ii|||i^^^^^^^ CDM FEDERAL PROGRAMS CORPORATION
FIELD ACTlVfTIES COVERED UNDER TIES PLAN ,
TASK DESCRlPTION/SPECffIC TECHNIQUE-STANDARD OPERATING PROCEDURES/SriE LOCATION(Attach additional sheets as necessary)
I Site Visit ' , '
2 Sampling groundwater, aquifer testing
3 Sampling surface soil, sediment, surface water, biota . .
4 Drilling borings. Installing monitoring wells
5 Test pits . ' '
6 - •
T\iie
hitrusive
Non-intrusive
Intrusive
Non-intrusive
hitrusive
Non-intrusive
Intrusive
Non-intnisive
. Intrusive
Non-intrusive
hitnisive
Non-intnisive,
Primary
A B C J )
Modified
A B C D
Modified
A B C JD
Modified
A B C D
Modified
A B C D
Modined
A B C D
Modified
Contingency
A B C D
_ • Exit Area
A B C D
Exit Area
A B C D
Exit Area
A B C D
Exit Area
A B C D
Exit Area
• A B C D
Exit Area
HAZARD
SCHEDULE
Hi Med Low
Hi 1 Med Low
Hi Med Low -. s'
Hi Med Low
Hi Med Low
Hi' Med Low
PERSONNEL* AND RESPONSIBrLiriES (Include subcontractors)
NAME ' , • ' ' ' .
Pamela J. Philip
Andrea Soo '
Lisa Campbell
John Grabs. P,G,
Sharon Budney
Olher field personnel including CDM subcontractors (drillers)
FIRMTIEGION
CDM Fed/ n
CDM Fed/ ff
CDM Fed/n
CDM Fed/n
CDM Fed/ n
CDM Fed/ n
CDM Federal HEALTH CLEARANCE
Yes
Yes
Yes
Yes-CPR/FirstAid
Yes
Yes
• RESPONSlBELfriES
WORK ASSIGNMENT MGR
SHE HEALTIT& SAFETY COORDINATOR
ALTERNATE SHE H&S COORDINATOR
FIELD TEAM LEADER
SAMPLING/ FIELD OPERATIONS
SAMPLING/FIELD OPERATIONS ,
ONSffE?
1
1 - 2 - 3 - 4 - 5
1 - 2 - 3 - 4 - 5
1 - 2 - 3 - 4 -:5
1 - 2 - 3 - 4 - 5
1 - 2 - 3 - 4 - 5
Page 7 of 13
8 8 f 0 0 £
HEALTH AND SAFETY PLAN FORM
CDM Federal Health and Safety Program
PROTECTIVE EQUIPMENT: Specify by task.
BLOCK A TASKS; 1 LEVEL; D - Modified
Respiratoi-y: (X) Not Needed ( ) SCBA Airline: ( )APR: ( ) Cailridge: ( ) Escape Mask: ( ) Other;
Head and Eye: ( ) Not Needed (x) Safety Glasses: ( ) Face Shield; (x) Goggles: (x) Hard Hat: ( ) Olher:
Boots: ( ) Not Needed (x) Boots: Leather steel-toed work boots ( ) Overboots: ( ) Rubber:
BLOCK C TASKS: 2 - 3 LEVEL: D-Modified
Respiratory: (x) Not Needed ,( ) SCBA Airline; '' ( )Al^R ( ) Cartridge: ( ) Escape Mask: ( ) Olher;
Head and Eye: ( ) Not Needed (x) Safely Glasses: ( ) Face Shield: (x) Goggles: ( ) Hard Hat: ( ) Olher:
Boots: ( ) Not Needed (x) Boots: Leather steef toed work boots ,( ) Overboots: ( ) Rubber:
iiiiiiiiliiiiiilliiip^^^^ Indicate type and/or material as necessary. Use copies (
(X) Primary ' ( ) Contingency
Prot. Clothing: (x) Not Needed ( ) Encapsulated Suit: ( ) Splash Suit: ( ) Apron ( ) Tyvek Coverall: ( ) Saranex Coverall: ( ) Cloth Coverall: ( ) Other;
Gloves: ( ) Not Needed (x) Undergloves; Latex/Nitrile ( ) Gloves; ( ) Overgloves:
( ) Olher - specify below;
(X) Primary ( ) Contingency
Prot. Clothing: ( ) Not Needed ( ) Encapsulated Suit: ( ) Splash Suil: ( ) Apron (x) Ty\'ek Coverall: ( ) Saranex Coverall; ( ) Cloth Coverall: ( ) Other;
Gloves: ( ) Not Needed (x) Undergloves: ( ) Gloves; (X) Overgloves:
( )"Other - specify below:
iiiiiiiiiiiiiiii^^
Piiiiiliiiiiiiiiiiiiffi^^ if this sheet if needed.
BLOCK B TASKS: 1 LEVEL: C
Respiratory: ( ) Not Needed ( )SCBAAiriine: (x)APR: (x) Cartridge: GCMH or equivalent ( ) Escape Mask; ( ) Other:
Head and Eye: ( ) Not Needed (x) Safety Glasses; ( ) Face Shield: • (x) Goggles; (x) Hard Hat: ( ) Other; ,
- Boots: ( ) Not Needed (xl Boots: Leather steel-toed work boots (x) Overboots: ( ) Rubber:
BLOCK D TASKS: 2 - 3 LEVEL: C
Respiratory: ( ) Not Needed ( ) SCBA, Airline: (x) APR: (x) Cartridge: GMCH or equivalent ( ) Escape Mask:
, ( ) Other:
Head and Eye: ( ) Not Needed (x) Safety Glasses: ( ) Face Shield: (x) Goggles:
( ) Hard Hat: ( ) Other:
Boots: ( ) Not Needed ( ) Boots: Leather steel-toed work boots ( ) Overboots: ( ) Rubber:
The She Health and Safety OlTlcer in conjunction with (lie Health and Safety Manager has tlie aulliority to upgrade and d
CDM FEDERAL PROGRAMS CORPOR.VnON
• ( ) Primary (x) Contingency
Prot. Clotlung: ( )Not Needed ( ) Encapsulated Suit; ( ) Splash Suit; ( ) Apron (x) Tyvek Coverall: ( ) Saranex Coverall; ( ) Cloth Coverall: ( ) Other:
Gloves; ( ) Not Needed (x) Underglo\es; ( .) Gloves: (x) Overgloves;
( ) Other - specify below:
( ) Primary (x) Contingency
Prot. Clothing; ( ) Not Needed ( ) Encapsulated Suit: ( ) Splash Suit: ( ) Apron (x) Tyvek Coverall: ( ) Saranex Coverall: ( ) Cloth Coverall: ( ) Other:
Gloves: ( ) Not Needed (x) Undergloves:
( ) Gloves: (x) Overgloves:
( ) Other - specify below: '
iwngrade the level of PPE.
-
Page 8 of 13
est 'Ooe
HEALTH AND SAFETY PLAN FORM
CDM F<;deral Health at\d Safety Program
iiiiiiiiiiiiiiiiiiiii^ iiiiiiiiilliillilliiiiiiiiliiiiiw CDM FEDERAL PROGRAMS CORPORATION
MONITORING EQUIPMENT; Specify by task. Indicate type as necessary. Attach additional sheets as necessary.
INSTRUMENT
Combustible Gas Indicator
Radiation Survey Meter
Photoionization Detector Type OVM • ( ) l l , 7 e v
( ) 10,2 ev (X) 9.8 ev ( ) ev .
Flame Ionization Detector Type
Detector Tubes/Monitox . Type Type
Respirable Dust Monitor Type Miniram Type
Other Specify
The Site Health ai
TASK
1
1 - 2 - 3
1 - 2 - 3
ACTION GUIDELINES
0-10% LEL No explosion hazard 10-25% LEL Potential explosion hazard; notify SHSC. >25% LEL Explosion hazard; interrupt task/evacuate
21.0% 02 . Oxygen nonnal <2L0% 02 Oxygen deficient; notify SHSC <19.5% 02 Interrupt task/evacuate
3X Background Notify SHSC >2niR/hr Interrupt task/evacuate
Specify: 0 - 5 ppm; Level D • 5-25 ppm; Level C >25 ppm; Intemipt task or evacuate
Specify:
Specify:
Specify: ' 0-0.1 mg/m'; Level D 0.1 -5 mg/m'; Level C , >5 mg/m'; InteiTupt task or evacuate
Specify:
d Safety Ofticer in conjunction with tlie Health and Safety Manager lias the autliority to upgrade and d
COMMENTS (Includes schedules of use)
( ) Not Needed
Monitoring will be continuous during all intrusive site activities. The equipment will be operated and calibrated in accordance with the manufacturer's specifications.
(x) Not Needed
( ) Not Needed
Monitoring will be continuous during all intnisive site activities, Tlie equipment will be operated and calibrated in accordance with the manufacturer's specifications.
(x) Not Needed
(x) Not Needed
( ) Not Needed
Monitoring will be continuous during all intrusive site activities. The equipment will
be operated and calibrated in accordance with the manufacturer's specifications.
»wngrade tlie level of PPIL Page 9 of 13
06^00£
HEALTH AND SAFETY PLAN FORM
CDM Federal Health mul Safety Piogram
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiii
iiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiiisiiiiiiii^^^^^
CDM FEDERAL PROGRAMS CORPORATION
DECOtTfAMINATION PROCEDURES
ATTACH SITE MAP INDICATING EXCLUSION, DECONTAMINATION, AND SUPPORT ZONES AS PAGE TWO
Personalized Decontamination
Respirators will be selected, used, decontaminated, and stored in accordance witli the CDM H&S Manual, as based onOSHA29CFR1910,134,
Tlie Personal decontamination station will move from location to location based upon the work site.
Wash hands and face with soap and water upon doffing personal protection equipment, .
Wash well before hand-to-mouth contact is made. Works will remove protective equipment in this order;
-Equipment drop -Hard hat -Boot covers -Outer gloves
„ -Tyvek -Respirator -Inner gloves -Face and hand wash
•
WASH HANDS AND FACE PRIOR TO ANY INGESTION OF FOOD OR LIQUIDS
( ) Not Needed
Containinent and Disposal Method
Personal protective equipment will be double bagged and placed in a dumpster for disposal in a minimum technology Subtitle D disposal facility
Sampling Equipment Decontamination
All sampling equipment will be thorouglily decontaminated between samples with Liquinox, water, and several rinses.
Tltis equipment is decontaminated bet\veen use at each sampling location by a six-step process:
• "
1. Liquinox detergent scrub
2, Rinse witlt clean potable water
3, Rinse witlt ultra pure 10% nitric acid (when sampling for metals)
4, Rinse with ASTM Type n water.
5, Rinse with methanol
6, Rinse wiUi ASTM Type 0 water, .
7, Airdr>'
' 8. Wrap with aluminum foil, shiny side out.
( ) Not Needed
Containinent and Disposal Method
Disposal sampling equipment and sampling derived wastes will be containerized and disposed of ofi'-site in accordance
, with the n3W section of the project Work Plan
Heavy Equipment Decontamination
All downhole equipment and tool parts that contact soil are constructed of heavy gauge steel and have no natural or synthetic components that could absorb and retain soil-borne organic contaminants.
1 • , .
All downhole drilling equipment and any other large equipment in the confmement zone will be bnished off and then washed with a high pressure hot water cleaner prior to first use. between mobilization to each new borehole, and prior to leaving the site after the final borehole is drilled.
• '
1 ,
( ) Not Needed
Containment and Disposal Method
Decontamination-derived wastes will be containerized and disposed of off-site in accordance with the IDW section of the project Work Plan,
Page 10 of 13
TSf'Ooe
9 HEALTH AND SAFETY PLAN FORM
CDM I'cderal Health and Safety Proeram
EMERGENCY CONTACTS
Site Telephone
EPA Release Report No;
Water Supply
Electrical & Gas Emergency
Wastewater Treatment Plant
To be installed.
National Response Center
West Winfield Village Clerk
NY State Electric and Gas
NA
. (
1-800-424-8802
315-822-3051
1-800-572-1111
NA
At least one of the field staffwill be current with respect to CPR/ First Aid by having completed a course from the American Red Cross or equivalent.
Tlie Site Health and Safety Coordinator will conduct daily safefy meetings to discuss site emergency plans and action guidelines. The buddy system will be checked at the meeting. Additionally, drilling subcontractors will certify tlie safety of their equipment
CONTINGENCY PLANS Summarize below; /
Evacuate site if any unexpected hazardous conditions are encountered. Site staff, if evacuated, will congregate upwind of Uie site in a predesignated area (to be aimounced at the daily health and safefy briefings). If a field team observes hazards for which they have not been prepared, they will withdraw for the area and call the CDM Federal H&S manager or the local H&S coordinator for guidance. Without regard to monitoring instrument reading, CDM Federal personnel will leave the site and upgrade their level of protection if they experience nausea or dizziness. Due to the low TLVs for metals, any visible dust can be a hazard, and field team members inusi pay attention fo any conditions with visible dust. Dust treatment (i.e,, wetting dowi\ soil, etc.) should be considered during dry conditions.
For minor injuries staff should use the Winfield Medical Clinic, Major injuries require the useof the emergency room at St, Luke's Hospital, ^
HEAL'ITI AND SAFETY PLAN APPROVALS •
Prepared by R, Dean Costello/ / ] / / y ,f Revised by Deborah C, Cohen: ^ ^ ^ y ^ ^ " ^ ^ C . / ^ < - ^
SHSC Signature:
HSM Signature: y^f/ / /y, A - — ^
Date; t ^ 2 3 / o l
Date;
Date; 01/23/01
CDM FEDERAL PROGRAMS CORPORATION
EMERGENCY CONTACTS
Health and Safety Manager
Project Manager
Health & Safety Coordinator
Client Contact
State Spill Number
Fire Department
Police Department
State Police
Health Department
Occupational Physician
NAME
Chuck Myers
Pamela J. Philip
Andrea Soo
Jack O'Dell
West Winfield Fire Department'
NA - See State Police,
Troop D, Herkimer, NY
Herkimer Co, Health Dept,
Dr, Jerry Berke
PHONE
1-800-313-5593
1-212-785-9123
1-212-785-9123
1-212-637-4256
800-^157-7362
315-866-0974 v
f
NA - See State Police,
315-866-7111 or 315-337-0036
315-866-6879
1-800-350-4511
MEDICAL EMERGENCY
Hospital Name; 1, Winfield Medical Clinic . 2, St, Luke's Hospital (critical care)
Hospital Address; 544 E. Main St., West Winfield, NY 1656 Champlin Ave., New Hartford, NY
Name of 24-Hour Ambulance: Rescue Crew
Route to Hospital (Attach map with route to hospital) 1). Turn left onto Rt, 51, Make Right at US 20, Clinic is about 1
2), GowestonCR-162. Turn right onto NY-5L Turn left onto U t^FMFSFF ST pvit towarHs NEW HARTFORD Turn riohl onto f
onto FRENCH RD. Turn slight right onto CHAMPLIN AVE N, 1 RD. Hospital is across the street from Utica College,
Phone: 315-822-6348 315-798-6000
Phone; 911
5 miles on left,
3-20, TakeNY-8, Take the lENESEE ST, Turn left 'urn left onto BUURSTONE
s e ^ o o e
I h
p
544 E MAIN ST, WESTWINFIELD, NY, 13491-2912, US -C MAC Q;WE:ST'"C^ — y
^ loom "aooft
^urwA^S
.-'•^^^ W-1
01S89 Maoquestcom, Inc.; 0199Q GDT, Inc,
V
300493
I l l
f
1656 CHAMPLIN AVE, UTICA, NY, 13502-4856, US
^ '^ee-.^--[! l>-, ••i^OAVElm/r HI
~ '^ % 1 r ^00 n n d'Kol.—^S5;(<^4r''>
'•-•, A r ^
.,^S5?Ne.w London J ^ J Z ^ J 2 J ( ^ ) i rrzA / ^ ?~A «i / ,L2iJ^,?V w - ' " ^ T ^
•jScarKs Und'inq ^ ^ Ispencel^Sittlerfrenj: \ > < l ' . .4S=E£^>-^ / " ' " • - . . r - - . ,—2
. i ^ 3 | i ^ h i f e ; s l r f f r S
o New York"M~""
"pc-liniicth
| T 2 A l J i .-' T^^ • '•. ) — r r ^ l f wells Conner •,
4kin 34m i
;iuqi.
9ceddr Lake, .-'f^
r^l- f _ J ^ - . • |-V¥k.§J^t:lirield juncti|p"iif__| 1 -•' , _ i , / ' ' j ^ %
5 fT? nos
1, ^ChepacheC
i ^ ' - i i
im C. dUr"— sriagei.5?acej
--[99
..' P ^ l J ^ l M l l a g Corner^—._
J__^riglii;on!5,^^'r —'•.^--Wccffd's'cornerj "yy '^- . . .^y^20
' •''"^NorthBroiikfleid ^ \ i A \ f ^ ' S i , — I i ,..f >-^-—'—' VHuntly'Carner
Btaokfieid, idallsvllle-a:
East
^South LeBafion| / ' y j 3S ["
•' " " " ' • - . , ,j3E,ar.l«lll^--— _ l 4 l l e n e - | : - |
^;fLloydsville « -v.^ /-23y-.
teonardswlllei^s*^^''^'^^'^'"
'" ' i 20l N QV 0.''*' ' ^°' " [nf Inn Lews
^,&<ibinson corners
v^Smyrnd'^ ^ - ^ calum,bjji^^,'p5rfJouth Edni?7ton « ; — , O „ . ^ „ J
Sherburne « . ^
01999 MaDQuestcom. Inc.: 01999 Navnatbn T'schnobaies
orth e'dmeston . — - ^ ^ i \ Lenfsuille
^ . ' ' ^ ^ ' " ^ • • ' " • ^ . ^^ . . . - / ^^Cat town . / / fearr'fetit-torners
/ Hartwick -piTl._jnde.x 0£S> ipHyde P a r / ;
I 300494
HEALTH AND SAFETY PLAN FOT^M ' CDM FEDERAL PROGRAMS CX^RP'ORAHON
CDM Federal Health and Safety Proarain
The ft)llowing personnel have read and ftilly understand the contents of this Health and Safety Plan and ftirther agree to all requirements contained herein.
Name Affiliation Date Signature r ' 1 '
. • . ' ' <
^ • • . • ' , - • • • - • ' •
'
J •
' • • • ' • ' • • ' .
. - ' ' - ' . . . .
— " ' • , • • '
• • ' • • • • • , " . " - • ,
• . • • • ' . • . ' . ' • • ' • '
Page 13 of 13
96^00£
CO o o »(
Ol
ACTIVITY HAZARD ANALYSIS
This Activity Hazard Analysis includes the additional potential hazard of working at night at the Puchack Well Field Site,
in AI-IA No.: 3220-032-01
(2] Work Location: West Winfield. Herkimer County. New York [3] Task Title: (1) Sampling groundwater, aquifer testing (2) Sampling surface soil, sediment, surface water, biota (3) Drilling borings, installing monitoring wells (4) Test pits, -[41 Work Phase: Field Activity 1& 2 , A. This AHA shall be reviewed annually or as requested by the workers, supervisors, and/or safety representative B.
16] Activity Steps
(1) Sampling groundwater, aquifer testing (2) Sampling surface soil, sediment, surface water, biota (3) Drilling borings, installing monitoring wells (4) Test pits.
[7] Work Groups
r Drillers and Field Team
[5] List Work Groups Needed for Each Phase Drillers and Field Team A . - • . . •
B.
[8] Hazards
Lighting
•
Environmerital Protection
[9] Hazard Coiitrols (Engineered, Operational, Documents, PPE, Qualifications)
The minimum required illumination - See Table H-120.1 attached [per Table D-3. 29CFR 1926.56(a)] Do not overload the circuit by exceeding the outlet ampere rating
• . The outdoor lighting fixt\ire(s) will be located below all live conductors. transfoiTners. or other electric equipment unless adequate safeguards are in place
At a minimum, plastic vvill be placed over the area to be drilled. If the contaminants warrant, plastic will be placed under the rig as well as a large area surrounding the rig. :, If fiiel or oil leaks on the plastic sheeting, absorbent pads will be used.
ACTIVITY HAZARD ANALYSIS
" -
)
Housekeeping - slips/trips/falls
•
Equipment Inspection
Drill rig failure
Water tanks
Eye injury
• All sites will be kept clean and free of trash and other debris. All trash will be propei-ly containerized and removed or staged daily. If mud pans are used, the pan will be cleaned out as often as possible to avoid slippery conditions.
Prior to use all drill rigs and related equipment will be inspected by health and safety and the site geologist or designate. All rigs and related equipment will be scaimed in by the geologist or field operator prior to use. Documentation from health physics will be required prior to rnobilization to the decontamination area. Drill rigs and support equipment will be inspected daily and documented by the equipment operator. The mast and cables must be able to support all , equipment and drill rods. Wire cables must be maintained in good condition, free from kinks or broken strands. All rotating shafts, pulleys or chains must be covered with protective guards. All drill rigs must be equipped witli an emergency kill switch, which is readily accessible to personnel at tlie rear of the rig. All personnel on the site will know the location of the kill switch and how to use it. All water tanks must be securely fastened to Ihe tnick frame. Water tanks should be constnicted of materials with adequate side strength, baffled to prevent the sloshing of water side to side, and must have lids with gaskets to prevent water loss. Safety glasses will be required during drilling operations
z.6^ooe
ACTIVITY HAZARD ANALYSIS
U) o o
00
' , . . •
Drillers aiid Field Team
Foot injury
Hearing loss , ~
Hand injury
Head injury
. - •
Unauthorized operation
Slips/trips
•
Crushing injuries
Rig/equipment damage
Ffre prevention
Leather steel-toes boots will be required.
Hearing protection will be required during hammering operations, Sound level readings will be taken during the initial startup ofthe operation to determine the hearing protection buffer zone, if a zone is necessary. Gloves vvill be worn during routine drilling activities. Keep hands away froin rotating augers, the hammer, and all other moving parts. Hard hats will be required during drilling operations. Hard hats will not be required during sile set up. but will be required once the mast has been raised.
Only trained and authorized personnel will operate , and/or assist in drilling operations.
Operators must comply will all applicable state certifications. If mud pans are used, the pan vvill be cleaned out as often as possible to avoid slippery conditions.
Drill rigs and drill bh stabilizer will be properly transported by either a rack, the rig. or utility trailer, tf transported on a trailer, the rods or stabilizers will be held securely in place. If feasible, all veliicles and wheeled equipment vvill have chocks placed under the wheels to prevent rolling. Wiie cables will be inspected daily. Cables with broken sfrands. weak spots, kinking, or mashed areiis will be replaced piior to use, ^
Drill rigs will contain at least on ABC type fire extinguisher. Fire extinguishers will be frilly charged and inspected weekly. Fuels will be stored in appropriate containers.
ACTIVITY HAZARD ANALYSIS
,
Decontamination . Using a steam cleaner
Drillers and Field Team
Drillers and Field Team
Drillers and Field Team
Field Team
Severe weather
Cathead hazards
Power lines/underground utilities
Hand injury
Hearing loss
Fire
Electrical
Drilling will stop when rain interferes with the safety of the operators. Drilling activities will stop during lightning. Operators, crew, and other support persomiel will move -out ofthe exclusion zone and take shelter in other vehicles. ' The operator must be trained and experienced in the useof a cathead. The rope must be in good condition. The operator shall not wear loose clotlung. Ensure that there are not any power lines or underground utilities prior to drilling activities. If work is near an overhead line, care vvill be taken to ensure there is clearance with raising the mast,
• While working near power lines, drill rods will not be leaned against the mast. If the drill bit encounters anything hard, drilling will stop and the geologist will be notified. Skid mounted steam cleairers will have protective guarding on all rotating shafts, belts, and pulleys. Nitrile gloves vvill beWorn while operating the steam cleaner. Keep hands clear of the water spray. Hearing protection will be worn during steam cleaning operation.
Turn off the steam cleaner and allow it to cool before reftieling. Generators vvill be Uinved otTwhile being refrieled. Smoking is prohibited during refueling operation. If steam cleaners are being powered by a generator, a GroundpFault Circuit InteiTupter (GFCI) will be required.
O O
VO
ACTIVITY HAZARD ANALYSIS
10] Attachments:
Document Type
Comments:
fll] References;
Docmnent Type
CDMFederaFs Health and Safety Program Manual Hiteman's Health and Safely Plan
•
Document Number
Document Number
NA (dated August 2000)
3220-032-PP-HASP-01766
Applies to Work Group
Applies to Work Group
All
All .
•
For Work Step(s)/Phase(s)
For Work Step(s)/Phase(s)
All
All
CO
o o (Jl o o
ACTIVITY HAZARD ANALYSIS
fl2
1
2
Subcontractor Approvals
Environmental. Safety, and Health
Site Sunei-visor
a. Print Name b. Signature
•
c. Date
-
.
fl3] Change Summary
[6] Activity Steps
1 -
\U
1
2
[7] WorkGroups [81 Hazards
Subcontractor Approvals
Environmental. Safety, and Health
Site Supervisor
a. Print Name
[9] Hazard Controls (Engineered, Operational, Documents, PPE, Qualifications)
•
b. Signature c. Date ^
' • ; • - .
o o (Jl o
I b ACTIVITY HAZARD ANALYSIS
PRE-JOB BRIEFING ATTENDANCE
f
AHA No: 3220-032-Oi
Service Supervisor
Job Title: AHA for Drilling Safety
Performer Organization:
Date:
Time:
I agree to work witliin the scope of work and follow the work confrois described in the briefing.
Signature
r '
Badge No. or SSN Organization
V
•
fc 300502
> •o (D 3 a
300503
I ft
f
i
APPEM)G:A
COLD STRESS
300504
I b raese Thrsshold Limit Values (TLVs) arn intended to protect waricers fram
the severest effects of cold stress (hypothernia) and coidsinjury and to describe expoiurea to cold woricing conditions under wbich ic is believed that nearly all variters can be repeatedly exposed wichaut adverse health effects. The TLV objective is to prevent the deep body core tenperaturs from falling b«low 36'C and to prevent cold injury to body extremities; • Deep body tearp«rature is the core ternperature of the body as determined by rectal temperature measorements. For a single, occasional exposure to a cold environment a drop in core temperature to no iowr than 35*C should be permitted. In addition to provisions'for total body protection, the XLV abjec'ive is to protect all parts of the body with eapha*ii on hands, feet and head from cold injury. The single mosc. important aspect of life-threatening hypothermia is the fall in the deep care temperature ofthe body.
Syscsmic hypothermia is 'caused by exposure to freezingor rapidly dropping temperature,. Its symptoms are .'usually exhibited in five stages:. ,(1) shivering, (Z) apathy, listlessness, alcepineaa, and rapid 'cooling of the. body vto less than 95*?, (3) unconsciousness, glassy stare, slow pulse, and slow respiratory rate, (i*) freezing of the extremities, and, finally, (5) death.
Woricnan should be protected from exposure to cold so that the deep core • temperature does not fall below 35*C (96.8'F); lower body temperatures will vary like result in reduced mental alertness,, reduction in rational decision making, or loss of consciousness with the'threat of fatal consequences .
Pain in the extremities maybe' the first early warning of danger to cold stress. During exposure to cold, maximum severe shivering develops when the body temperature has fallen to 35*C (95*F). This must be taken as a sign' of danger to the workers and exposure to cold.should be immediately terinated for any workers when severe shiveiing becomei evident. Useful physical or mental work is limited when severe shivering occurs.
Since prolonged exposure to^cold- air, or to immersion in cold water, at temperatures well above freezing can lead to dangerovu hypothermia, whole body protection must be provided.
I. Adequate iniulating clothi.ng to maintain- core temperatures abov-36*C muat be provided to workers if work is p«rfarmed in air temperiture belov U'C ( ^Q 'T) . . Wind chill factor or .the cooling-pov«r of the air"is" a critical factor. The higher the wind speed and the lower the temperature in the work area,, the -greater .the inaulation value of the protective clothing .required. An equivalent chill temperature chart relating the actual dry bulb air temperature and the wind velocity is presented in Wind Chill Chart. The equivalent ciil temperature should be ujed when estimating the combined cooling effect of wind and low air temperatures on exposed akin or'when determining clothing insulation requirements to maintain the deep body core temperature.
300505 35I3K
I b
f
I I I
Unless there are unusual or extenuating circumstances cold injury to other than hands, feet, and head is not likely to occur without the developmenc of the initial -signs of hypothermia. Older workers or workers 'wich circulatory prable.iis require special precautionary protection agains cold injury. The uae-of extra insulating clothing and/or a reduction in, the duration of the exposure period are among the special precautions which should be considered. The precautionary actions to be taken will depend upon the physical condition of' the worker and should be determined with the advice of a physician with knowledge of the cold stress factors and the medical condition of the worker.
-Employees shall be excluded from work' in cold at -1*C (30*?) cr below if they are suffering f ram' disease.s or taking medicatior.-which interferes with normal body temperature regulation ar reduces tolerance" to work in cold environments. - Workers who are routinely -exposed to temperatures below -2^*C' (-10*F) with wind• speeds less than five miles per hour, or air temperatures below -IS'C (0*F) with wind speeds above.five miles per hour should be medically certified as suitable for such exposures.
Trauma sustained in freezing or subzero conditions -requires special attention because an injured worker is predisposed to secondary cold injury. Special provisions must be made to prevent hypothermia and secondary freezing of damaged tissues in addition to providing for first aid treatment.
In cold environments, wind-chill temperature ii a better description of thermal conditions than the ambient temperature alone. The wind- adds to 'the rate of -cooling and it is the combination of wind speed and air temperature that is most important. In the wind-chill char,, arbitrary risks of frost bite are given.for short exposure periods. For example, at a wind-chill temperature of -25 (from a 5 F temperature and 15 MPH wind) exposed flesh may freeze within one minute. However, fingers, toes, nose -tips, ears or cheeks- may become frost bitten at ambient temperatures as high aa 328 .F with high winds. This is ' approximately the freezing point of akin in the absence of aubcooling. • • ' _
Hypothermia (general lowering of body temperature)' can occur frc« exposure to-conditions well above freezing. The lethal deep body temperature is placed at about 78 F. This condition can occur where a worker is imnersed in cold water *divers), is expoied to cool, high winds, is in -a state.of physical exhaustion, or,has insufficient food. Alcohol should not be consumed in cold enviramnents because the resultant, dilation of -blood vessels can permit a rapid Loss of body heat increasing the risk of hypothermia. for warming purposes, liquid intake should be ht, non-alcoholic beverages or soup.
3 5 1 3 K -300506
I b I I I I t I I f
Frost Bite "' •
1. Frost nip or incipient frostbite." The condition is characterized by sudden blanching or whitening of skin.
2. Superficial frostbite. Skin has a waxy or white appearanca and is firm to the touch, but tissue beneath is resilient.
3. Deep frostbite. Tissues are cold, pale, and solid; extremely-serious injury.
Frost bite may be 'either superficial involving only the-skin or deep,, extendi.ng below the skin. Frost bite may be considered to be superficial if exposure time was short. Otherwise assume the injury to be deep and, therefore, serious, in which case it should be treated, at a hospital rather.than in the field. Superficial frost bite can.be treated by
1. covering the cheeks with warm hands until pain returns,
2. placing uncovered' frost bitten fingers under the opposing armpit next- to the skin,
3. placing bare frost bitten feed under the clothing against the skin of a companion
i*. never rewarm a frost bitten part by massage, exposure to open fire, cold water soaks or rxibbing with snow. Gradual rewarming against the skin is always preferred. It is important to know that pain will occur when thawing has occurred.
5. ' where deep frost bite exists, it is essential to get the patient • to the hospital as quickly as poss''.ble. Frozen parts should be
protected from additional cold inj.iry but no attempts should he made to.thaw them in the field. Tlie patient should also be kept" warm.
For work practices at or belQw'-12*C (lO'F) £CT the following shall apply:
1. The worker shall be under constant protective observation (buddy system or supervision).
2. The work rate should not be so high aa to cause heavy sweating that will result in wet clothing; if heavy work must be done, rest periods amst be taken in heated - she!ters and opportunity for -changing into dryciothing shall be provided.
3. New employees shall not'be required'to work full-time in cold in the first days until they became accustomed to the working •conditions and required protective clothing.
'*. The weight and. bulkineaa of clothing shall be included in estimating the required work performance and weight to he lif-tad by the worker.
.3513K
300507
I b I I I I i I I f I I I I I I i I I
5. The work ahall he arranged in such a way that sitting still cr itanding itiil far long periods is - minimized. Unpra tecte"d metal chair seats ahall not he <j^sd. The worker should be protected frc» drafts to the gre_tes extent possible.
6. The workers ahall be instructed in safety and health procedures. The training program shall include as a minimum instruction in: • -
a. Proper, rewarming procedures'and appropriate first aid treatment.
b. Proper clothing practices.
c. Proper , eating and drinking- habits.
d. Recognition of impending frostbite.
e. Recagnitian signs and symptoms of impending hypothermia or excessive cooling of the body even when shivering does not occur. - . . ^
f. Safe work practices.
Special caution shall be exercised when working with toxic substances and when workers are exposed to vibration. Cold exposure may require reduced exposure.limits.-
Eye protection for workers employed ' aut-of—doors' in a snow and/or' ice-covered -terrain shall be supplied. Special safety goggles to protect against-ultraviolet' light and glare (which can produce temporary conjuncti'rLtis and/or temporary loss of vision) and bloving ice crystals ae required when there is an expanse of ano-w coverags causing a potential eye exposure hazard.
Workplace mchitoring- ia required as follows:
Suitable -thermometry should be arranged at any workplace where the environmental temperaturt is belo^ 16*C (60*F) to enable' overall compliance with the requirements of-the TLV to be maintained.
In outdoor situations, the windspeed ahould be meas-ured and recorded at least evary k h a n r t , together with the air' temperature whenever the air temperature is below -1*C (3Q'F).
For exposed skin, continuous exposure should not be permitted when the air speed results in.an equivalent chill temperature of -32*C (-25'F). Superficial or deep.local tis-aue freezing will, occur at temperatures below -I'C regardless of wind speed.
300508
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f
M.'^ir'r.-^.ira.iui. Regiiara
If work ia performed continuously in the cald at ,an- equivalent chill temperaturt (ZCT) or below '-7*C (20*F) heated warming shelters (tents, cabins, rest rocoia, etc.) shall be made available nearby and the workers should be encoxiraged to-use these shelters at regular intei-vala, fhe frequency depending on the severity of the environmental exposure. The onset of heavy shivering, frostnip, the feeling.of excessive fatigue, drowsiness, irritability, or euphoria, are indications for inmediate return to the shelter. When entering the heated shelter the outerlayer -of clothing shall be removed and the remainder of the clothing loosened to permit sweat .evaporation or a- change of dry work clothing provided. A change of dry work clothing shall be provided as necessary to prevent workers from returning to their work with wet clothing. Dehydration, or the loss of body fluids, occurs insidiously in - the cold environment and may increase the susceptibility of the worker to cold injury due to a significant change in blood flow to the extremities. Warm sweet drinks and soups should be provided at the work site to provide caloric intake and fluid volume. The intake of coffee should be limited because of a diuretic and circulatory effect.
Protective'Clothing
1. Clothing for both cold-wet (moderately cold weather ahove lUF) and cold-dry (temperatures below lUT) should be available.
2. Clothing worn loosely and in.layers provides maximum protection because the trapped layers of warm air are more effective insulators than the cloth itself.
_ • 3. Clothing must be kept dry. If not, the exposure to cold must be altered with periods of rewarming .>tnd drying of clothes.
^. Moisture should be kept off clothes by brushing'" or shaking snow from it prior to entering heated shelters-.
5 .' Means of evaporating perspiration should be encouraged by opening the neck, waist, arm aleeves and ankle fasteners as needed..to'provide periodic fresh air circulation.
6. During severe wind-chill conditions, a cold weather mask or wool scarf ahould also be worn.
7. When wearing face, protectors that they be removed periodically to check for frost bite.
a. S'kin cn the hands can freeze easily, therefore, cold metal should never be touched with'bare hands. Special protection of the hands is required to maintain manual dexterity far the prevention accidents. If the air.temperature is -17.5'C (0*F), the hands should be- protected by mittens..
3513K 3 0 0 5 0 9
I b I I I t I I I f I I I I I I
I I
9. Pants ahould be tucked in and lapped over boot tops to prevent the entry of snow and cold water into the boat.
10. The.,ioot wear for outdoor work in wet snow ahould be water proof and reach well up on the' leg. The soles and upper part of the-boot should provide good insulation as well". A combination of working boots and rubber overboots provides this insulation.
11. Socks should, be fairly heavy and reach well up on the leg to encourage wicking and evaporation of sweat.
Other Precautions
Balanced meals and adequate liquid intake are essential to body heat production and the prevention of dehydration. Dehydration is as prevalent in cold regions as it is in hot, dry areas. Warm liquids (hot soup or tea) are obviously preferable since they do not have to be warmed by the body after consumption. Cold foods and drinks should only be eaten as a matter' of necessity. Hair should be cut t d beards shaved or clipped closely. .Long hair or a. beard add very little in insulation value and natural hair oils soil the clothing. In the open, a beard ser'/es as a base for ice build-up and will mask the appearance of frost bite. Electric razors are preferable aince they do not remove protective oils from the face.
300510
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G
1
- I G
-3G
- 3 3
- 3 7
- 1 1
-A2
~A'.\
-At-,
- 4 7
-A
- 0
- 3 f i
- 3 7
-AA
-GO
-G-l
-G7
-r.u
- G I
-G2
- i ; i
- in
- 3 7
-AW
-G7
-C4
-GO
-7 1
-7-1
-7G
-7(1
l l ieJ L l l i l c Cunilil<»i»lilii OaiKjcr DBIIIJC-/
DANGcn pnoM pnccziNG o r nxp
l u m ; - • JY
-3Q
--in
- I I I
- 7 0
- 7 7
- 0 2
-JIG
-U7
-no
- 9 1
DSI;D
1 ' I - : i i
- 37
-GO
-7 3
-(13
- 0 0
- 9 7
- 9 9
- 1 0 3
-10<1
- l O G
- I O
- 17
- 7 0
-IIG
-on
- 1 0 4
- 1 0 9
-1 13
- 1 1 l i
-1 U l
- 1 3 0
- i T T
-GG
-0 1
- 9 7
-1 ny
-1 17
- 1 3 3
- 1 3 7
-131
- 1 3 3
- 1 3 4
V« rv G ie i i l DiiM()cf
PL I i .S I I
-Gil
-GG
- 9 3
- 1 0 9
-13 1
- 1 3 0
-137
- 1 4 3
- 1 4 0
-147
- 1 4 0
T1«: f , . l l . .w ln ( I . . u p f c O o l . . . t.»^ic l .u r t l l . . u . i . . r o i ' - l v d . K i i y i l « r . . , . l c in/..,..,:x.i.... i« » ' * . ' ^ . i l . l . i c :
i n.H.: nr.U (l-K » : lU n>,J.: l irU " T . Mly c.u..l..l-. IA ...H': " ' * '« - - , , , . . , . , ,l..cr. Id .-MJ.: ••••'-""f. ' "J
i i i i n i i > i t i M i w .
300511
> XI
n a X
m
300512
I
APPENDIX B
.HEAT STEESS
f
I 300513
r
i I I
.ADOPTED THRESHOLD LIMIT VALoES
Warlc - Rest Reaime u-—«.
These Threstiold Limi" Values (TLVs)' refer zo hea.t sccess -randit ions " under which 'it is believed that nearly ail ' or ,icer s . ,Tiay,,be repeatedly expd'sed wi-thouc advrse healrh' effects. 7:.0 TLVs shown in Ta'ole 1 are aasad an the assumption that nearly all ace 1 i.Tia 11 zed , fully clothed workers with adequate .wa-er and salt intake should be able' to funccion effectively under the given working conditions without , exce'eding a deeo bocv temperature of Sa^C. ' '
I. "••ork load Categories
'Heat produced -by the body and the environmental ' heat together determine the total -heat load. Therefore, if -work is ,to be performed under' hot 'en,v ironmental conditions, the workload category -of.each job shall be established and the heat exposure limit pertinent to the workload evaluated against the applicable standard .'i-n order to protect the worker exposure beyond the pe.rraissible limit.
The 'work load category- may be established by ranking each job into light, medium, and heavy ' categories onthe basis of. type of operation. Where the work load is ranked into one' of said three categories, i.e.,
(.1) light work (up to 200 kcal/hr or 800 3tu/hr): e.g., sitting or standing to control machines, performing light hand' or arm work,
(2) moderate work (20-0-350 kcal/hr or 800-1400, 3tu/hr,): e.g., walking about with moderate lifting' and pushing, or ' '
(3) heavy work (350-500 kcal/hr , or 1400-2000 3tu/h:): e.g., pick and. shovel wor)c,
The permiss-ible heat exposure limit' for that workload shall be detennined from Table 1. '
2. Work-Rest Regimen
The permissible exposure limits specified in. Table 1 and Figure 1 are based on he assumption - that the W3GT' value of the- resting place is the same .or very close to that of the wQTkolace.- .
300514
I
t
4
The permissible exposure limits for continuous WQ-:>. ^.^ applicaole where -there, is a work-rest regimen of a' -- -IG work week and. an 8-nour work day with a short .Tiorn'-- =-^ afternoon break (approximately 15 minutes) and a Icnc^-iunch break (approximately 30 mi.nutes). Higher exoasu^^ limits a're permitted if additional', resting tin'e is allowed. " .Ml breaks, including unscheduled pauses and administr"ative or operational waiting periods curing <JO:'<~ may be counted as' rest time when additional -rest allowance must be given because of high environmental temperatures.
3 . -nothing: . . . - . ^
The -permissiole heat- e'xposure TLVs are valid for lirnt summer clothing as' customarily worn by workers when war:<ing under hoc environmental- conditins. If special clothing 'is required for performing a particular job and this clothing. IS heavier or it impedes sweat evaporation or has' hiahe: insulation value, the' wo'rker's heat tolerance .iS' reduced, and the permissi-ble heat exposur e • 1 imits • indicated in'Table 1 and Figure 1 are not applicable. For each ' job category
-' where special clothing is. required, the permissible hat exposure limit'shall be established by- an expert.
4. \cclimatiration and Fitness:
Acclimatization to heat 'involves a series of physiological and psychological adjustments that occur in an individual during this first week of exposure to hot environmental-conditions. The recommended heat.stress TLVs are .valid for acclimated workers who are physicall fit. Fxtra caution must, be employed when unacclimated or physically unfit workers must be exposed to heat stress conditions.
300515
I b TABLE 1
J^cnnissiblc Mcnl. Exposure Threshold Limit Values (Values arc given in °C WBGT)
*
Work —Rest Regimen
Continuous work
75% Work 25% Rci'l, each hour
50% Work 50% Rest, each hour
25% WorV 75% Rest, each, hour
Light
. 30.0
30.6
31.4
32.2
"Work Load
Moderate
26.7
28.0
. 29.4
• 31.1
Heavy
' .25 .0 ' '
25.9
.27.9
30.0
3 5 < ^
30
• U
03
?5
20
6 LECHO COXTmuOUt
r sT . warn* - n x "CJT c*C>» 50'X •0<»« • »•>. t - i i f C n
l(X
<00
200
aoo
300 kcal/hr l?00
4IX
1600
500
20C0
- ^ 9 5
690
6i5
^80 ^
5
W5
9 70
300516
sT STRESS P r e v e n t i v e Manaaemsnt
.adverse wea the r c o n c i t i o n s ar planning and conducting site can caus.e g^ysical discomfort
important- considerations cold
:: 1 operations
__ loss of , emciency, and perso.na in]ur-y. Of particular importance ' is . neat -stress resulting when protective clothing decreases natural .body ventilation.
Hot or ficiency,
Provide ' plenty of liquids. To replace body fluids- (water and electrolytes) lost because of sweating, use a Q.l cercent saltwater solution, more heavily salted foods,
The commercial mixes mixes . em.cloyees oh a low-sodium.
may be or
preferable CG~,mer rial tor se
Body' water loss (3WL) due . to sweating should' be measured cv weighing "the worker "in -the morning an.d in the evening. Tne clothing 'worn should be similar, at both weighings; preferaoly Che worker should be nude. The scale should be accurate to plus or minus 1/4 lb. -aWL .should not exceed 1.5 percent of .the total body weight. If it does, . the worker should be instructed to
intake of fluids by the ' w~eight lost", should be maintained at a constant level' This requires replacement of salt lost in
increase his daily Ideally, body fluids during the work day. sweat as well.
Have workers drink 16 ounces of water before beginning work, or • after lunch. Provide .disposable
Monitoring of personnel wearing impervious clothing should commence when the ambient . temperature is 1Q°? or, above. Frequency of monitoring should increase as ' the ambient temperature increases or as slow recovery rates are indicated. When temperatures .exceed 80°F, workers should be monitored for heat stress after every work period. .-The following are important considerations:
I
Heart rate' (HR) should be measured by the radial pulse for 30. sec.-as early as passible in the resting period. The HR at the beginning of the rest period should not exceed 110 beats/min. If the HR' is higher,., the next work, period-" should be shortened b"y 10 min'. (or 33 percent), while the length of the rest period stays tne same. If the pulse rate' is 100 beats/min. at the beginning of the next rest period, the following work cycle should be shortened by 33 percent.
300517
I b a t - ' - -
- '-1 c
Body temperature should be measured orallv clinical thermometer as early as possible in ene •period. Cral temperature (OT) at the b e g m n m c o-rest period should not exceed 99°F. If it does," ne*t work period should be shortened by 10 'mm. (o: 23 peccent), while the length of the rest period stays tne sanie. However, if the QT exceeds 99.7"? at tne ^ beginning of the next period, the following work cycle should be further shortened by 33 "percent.' CT snould be measured again at the end of the .rest period ro 'make sure that it has dropped below 99°F. • • •
Acclimate' workers to site work conditions by slowly increasing workloads/, i.e.", do. not begin, site 'wcr!< activities with extremely demanding activitle's.
Provide cooling devices to aid natural body ventilation. These devices, however, add weight, and' their use should be balanced against worker efficiency. Long cotton underwear acts' as a wick to help absorb' moisture-and protect the skin from direct contact with heat-absorbing, protecti ve clothing. It should be the minimum under-garment worn.
Install mobile . showers" and/or hose-down" facilities to reduce body temperature and .cool protective clothing.
In extremely hot weather, conduct nonemergency response opera.tions in.the 'early morning or evening.
.Ensure that adequate - shelter is availab'le to protect' personnel against heat, cold, rain, snow, etc., which can decrease physical efficiency and .' increase the probability of accidents. "" .
In -hot weather, ' rotate shifts of workers' wearing "impervious clothing.
Good hygienic standards must be maintained by frequent change of clothing and daily showering. Clothing should be permitted to dry during rest periods.' Persons' who notice sicin problems should immediately consult medical
. personnel.
HSA-T STRESS CONDITIONS
1 . -• Heat Cramcs
h Heat cramps are caused by- perspiration that is not balanced-by adequate fluid intake. Heat cr'amps ' are often the first sign of a condition that can .lead to heat stroke.
300518
I b
I
a Symptoms -- Acute painful spasms .of volunta-v r:\us-' -s e.g.,abdomenandextremities.
° Tceatment — Remove victim to a cool area and loose.-., closing. Have patient drink. 1 to 2 cups, water immediately, and every , 20 minutes thereafter until sym-ctoms subside. Total water consumption should ' oe 1 to.2 gallons per day. Consult with physician.
Heat Rash
.Heac rash is caused by continuous exposure to heat and'humid air . and aggravated by chafing clothes. ' The condition decreasesabilitytotolerate heat.
o Sympcoms -- Mild red rash, especially in areas of -.'-•= Dody in contact with protective gear.-
o Treatment — Decrease amount of time in protective gear and provide powder to help absorb moisture and decrease
' chafing.
Heat Stroke
Heat stroke is an acute and dangerous reaction to heat stress caused by a failure of heat regulating mechanisms of the body -- the individual's temperature control system that causes sweating "stops working correctly. Body temperature rises so hig'h that brain damage and death, will result if the person is not cooled quickly.' ' '-- '
o Symptoms — P.ed ,• hot, dry skin, al though per son may have been' sweating' earlier; nausea; dizziness; . confusion; extremely high body -temperature; rapid respiratory and. pulse fate; unconsciousness or coma.
0 Treatment — Cool the victim quickly. If the body temperature . is not brought -down fast, permanent brain damage or death, will result. Soalc the victim in cool, but not cold, water; sponge the body .with cool water or pour water on the body to reduce the temperature to a safe level (102°?). Observe the. victim and obtain medical help., Do not give coffee, tea, or alcoholic beverages.
Heat Exhaustion
Hea.t exhaustion is a state of very definite weakness or exhaustion caused by the loss of fluids from the body. The condition is much less dangerous than heat stoke, but it nonetheless must be treated.
300519
I b Symptoms — P a l e , c l a m m y , m o i s t skin; profuse rg
sp i r a t i o n and extreme w e a k n e s s . Body tem.perature n o r m a l , p u l s e is weak and r a p i d , breathing The- p e r s o n may have """a h e a d a c h e , may v o m i t , dizvy .
IS shallow and may o'
Treatment — Remove the'• pe'rson to a cool, loosen clothing, place in a
rest. Consult ph ditioned place, position and .provide bed espec-ially in severe cas'es . is not sensitive enough replacement. Have patient im.mediately, and every 20 symptoms subside. Total about 1 to 2 gallons per day
air he
_ ' _ s 1 c 1 a T h e normal thirst mec'nani
to ensure body flu drink I t o 2 c u p s - w a -m i n u t e s thereaft
water, c o n s u m p t i o n
! _ 1 n -ow
n , sm • i d
s n o u l d t i l
f
I 300520
>
T5 (D 3
a X O
300521
I b
APPENDIX C
INCIDENT REPORT
f
300522
I b
CDM Federal Injury/Illness Report
Informatloa aibonflnftired^W^ oflnyalvedlEmpIoyee
f
First Name: Middle Initisil
Last Name:
SSN:
Employee Number:
Employee Status; • • CDM Federal
Sex: Age:
• Subcontractor
Name of Subcontractor Firm:
Address and Phone No.;
Employment Category:
• Regular Full time
Q Regular Part time
Q Temporary
• Non-employee
Length of Employment
Q In training • 3-5 years
• <6 months D 5-10 years
• 6 mos-1 yr a 10-20 years
n 1-3 years D 20+ years
l i m e in Occupation:
D In training • 3-5 years
• <6 months O 5-10 years
D 6 mo-1 yr • 10-20 years
Q 1-3 years D 20+ years
4
Infonnation aboitt Acciden^^ | tuy/I I taea«
Date of Accident:
Specific Location of Accident;
Witness(es) to the Accident/Injury:
Employee's Usual Occupation:
Occupation at Time of Accident;
Supervisor:
Time:
Injury or Illness?
Property Damage?
Vehicle Involved?
• Injury
D Yes
D Yes
a Illness
D N O
a No u> o o Ul to w
^ U M Federal Prujirams Corpoaicion Form A
I b
Injury/Hlness Severity:
a First Aid Only
• Medical Treatment
D Lost Workdays - Restncted Activity
O Lost Workdays- Away from Work
Q Fatality Date:
• Toted Number of Lost Days:
Injury/Illness Report Page 2
OSHA Illness C o d e
D Occupational Skin Diseases or Disorders
• Dust Diseases of the Lungs
• Respiratory Conditions Due to Toxic Agents
D Poisoning '
• Disorders Due to Physical Agents
D Disorders Associated with Repeated Trauma
D All other Occupational Illnesses
Phase of Employee's Workday at Time of Injury:
D Performing Work Duties D During Meals
D Entering or Leaving Workplace D Other
D During Rest Period
General Type of Task Being Performed at Time of Injury/Il iness:
f Specific Activity Being Performed at Time of Injury/Illness:
Employee Was Working:
• Alone O With a Crew or Fellow Worker D Other Crew size:
Supervision at Time of Accident:
• Directly Supervised Q Indirectly Supervised D Not Supervised • Supervision Not Feasible
Name, Address, and Phone Number of Attending Physician:
k
Name and Address of Hospital:
w U I V I Foieral ProKr.ims Corpor.u Form A
300524
I b Injury/Illness Report
Page 3
Body Part Affected (circle all that are applicable):
r
Abdomen
Ankle
Arm
Back
Brain
Chest
Digestive
Ear
Elbow
Eye
Face
Finger
Foot
Hand
Head
Heart
Hips
Kidneys, Intest.
Knee
Leg
Lungs
Multiple
Muse. Skel.
Neck
Nervous Sys.
Scalp
Shoulder
Skull
Thigh
Toe
Wrist
Other
Unknown
Injury Type (circle all that are applicable):
Amputation Contusion Elec. Shock
Asphyxia Crush/Bruise Fracture
Burn/Chemical Cut/Puncture Freezing
Burn/Heat Dermatitis Hearing Loss
Concussion Dislocation Hernia
Injury Source (circle all that are applicable):
Heat Stroke
Infect. Disease
Inflammation
Multiple-
Occ. Disease
Poisoning
Radiation
Scratch
Sprain/Strain
Other
Unknown
Air Pressure
Animals
Animal Product
Body Motion
Boilers
Boxes/
Containers
Buildings/
Structures
Ceramics
Chemicals
Clothing
Coal/Petroleum
Cold
Drugs &
Medicines
Electricity
Fire/Smoke
Food Products
Furniture
Glass
Hand Tool
Heat
Hoists
Infectious
Agents
Ladders
Liquids
Machines
Molten Metal
Miner/Metallic
Minerals/
Nonmetallic
Noise
Paper
Particles
Plants
Plastics
Power Tools
Power Trans.
Apparatus
Pumps
Radiating
Substances
Soaps
Silica
Scrap/Debris
Steam
Textiles
Vehicles/
Forklifts
Wood
Working Surfaces
Other
Unknown
Accident Type Code (circle all that are applicable):
Struck Against Fall on Same Rub/Abrasion
Struck By Level Bodily Reaction
Fall From Caught In/ Overexertion
Elevation Between Electrocution
Temp, Extremes Motor 'Vehicle
Radiations/ Other
Caustics Unknown
Public Transport
U ) O o cn to cn
O U M PetieruL Protiranis (Corporation Form A
I b
f
k
Injury!Illness Report Page 4
Hazardous Conditians (circle aU that are applicable):
Defects in Dress/ Apparel Inadequately Placement Hazards Other
Environmental Hazards Guarded Work Public Hazards Unknown
Hazardous Procedures Environment None
Accident Part Code (circle aU that are applicable):
Parts of Boilers Parts of Conveyors Hand Tools Parts of Vehicles None
Parts of Buildings Parts of Hoists Power Tools Machines
Other
Description of Accident
"^^SMlStM^M^MBi^^E^^^x^vx^/BhxBe:^ Place a check in the box of each factor that applies to this inc ident
EQUIPMENT - Was a Hazardous Condition a Contributing Factor?
a Defect in Equipment/Tools D Hazardous Condition Not Recognized a Hazardous Condition Not Reported • Employee Not Informed/Job Procedure Not Specified • No Equipment Inspection Procedure • Inspection Procedure Failed to Detect Hazard • Correct Equipment/Tools Not Used D Correct Equipment Not Available • Employee Not Informed of Correct Equipment O Substitute Equipment • Equipment Design Contributed to Operator Stress/Error • Design/Quality of Tool Contributed to Hazardous Condition a Other/Unknown ^ _ _ _ W
O o
ENVIRONtvIENT - Was the Location/Position.of Equipment, Materials, or Employee a Contributing Factor? tjl to
\ ^ \ j n i Federal Pn-iyrnnu 0,>rpi.ir.irion F o r m A
I b
t
i
Injury/Illness Report Page 5
D Location/Position Contributed to a Hazardous Condition • Hazardous Condition Not Recognized D Hazardous Condition Npt Reported a Employee Not Informed of Correct Job Procedure for Hazard .D Employee Did Not Belong in the Area O. Hazardous Condition Not Visible to Employee a Insufficient Workspace Q Poor Environmental Control D Uncontrolled Release of Hazardous Material ^ O Other/Unknown
PEOPLE - Was the Job Procedure(s) a Contributing Factor?
• Aggravation of a Pre-existing Condition 0 No Written/Known Procedure O Job Procedure Inadequate ' O Employee Not Trained on Proper Job Procedure D Employee Deviated from Proper Job Procedure Q Employee Not Physically/Mentally Capable of Performing Job n Job Procedure Too Difficult O Job Procedure Encourages Deviation D Other/Unknown
PERSONAL PROTECTIVE EQUIPMENT
n Employee not using PPE O PPE Not Specified for Task O PPE Unavailable
• a Employee Not Advised of PPE O Employee Not Properly Trained in PPE • PPE Used Incorrectly a PPE Inadequate D Emergency Equipment Not Specified (Shower, Eyewash, Etc) D Emergency Equipment Not Available ^ O Emergency Equipment Not Used D Emergency Equipment Malfunctioned D Other/Unknown
MANAGEMENT - Was a Management Defect a Contributing Factor?
Q Supervisor Failed to Detect/Anticipate/Report Hazardous Condition a Supervisor Failed to Detect/Correct Deviations from Job Procedure Q No Supervisor Review of Hazards and Job Procedures D Supervisor Responsibility Not Defiried/Understood a Supervisor Not Trained in Accident Prevention • Failure to Initiate Corrective Action for Known Hazard •' ' • Other/Unknown
CO OCCUPATIONAL HEALTH- Was a Chemical or Physical Agent a Contributing Factor? , o
O cn to -J
w O i V l Federal PaiHrnms Corponirion ' F o r m A
I b Injury/Illness Report
Page 5
Physical Agent:
a Noise, Vibration
• Temperature Extremes • '
• Ionizing Radiation- X, Gamma, Beta, or Alpha Radiati^
a Non-ionizing Radiation - Microwave, Laser, Ultraviolet, or Radio Frequency
a Ergonorruc - Repetitive Motion.Trauma, Inappropriate Lighting, Glare l l S r e c t or Insufficient Tooling, Benches, Seating ^ e , incorrect
tion
Chemica] Agent: .
• Solvents a Acid, Bases • Particulates
• Other Toxic Chemicals
Biological Agent:
• Microorganism •JInsect
O Animal Animal Species O Allergens .
CORRECTIVE ACTION REQUIRED:
iSmsmmm^mmmmmmmmmmmmm
Immediate Supervisor
H&S Coordinator
Performance Center Mgr.
Corp. H&S Director '
[ Fof Offfce Usa Onty;
Case No.'s of Others Injured, 111, or Involved
Sol Ac Par Che
Mic Inse
Alle
vent Name
d or Base Name
ticulate Name smical Name
roorganism
ct's Name
rgen Name
~ _
iiiiiiiiiiiiPiiiiiiiiii in the Same Accident:
Case No.:
Region:
Project No.:
OSHA Recordable?
Date
Date
Date
Date
iiP;Si#|li*i;JiiP?
• Yes a
.
mmmmtmmmmmii
No
Address:
Accident or Diag.nosis Date':
. 1
^^^
.
— *
CO o o cn to 00
CDM Federal Pcusrams Corponit
Form A
I b
Photos Relating to Acddenyinjary .(Make copies of this page as necessary.)
Insert photos here.
f
I
Injury/I l lness Repor t Page 7
CO o o cn to
OLIIVI Federal ProKHims Corporacian F o r m A
I b InjurylIllness Report
Page 8
t
Witness Statement (Make copies of this page as necessary.)
Name:
Address:
This statement is in reference to:
Site of accident (job name, location):
Date of accident '
Employer:
Position/Craft
Phone:
Describe what you know about the accident, what you saw or heard, what you were doing before the accident, what you did after the accident (Use additional pages as necessary)
i This statement is true to the best of my knowledge and memory.
Signature _ Date
V'UfVI Federal Proyranui Corporati
00 o o cn 00
o
Form A
>
3 Q.
300531
I h I I I I I I I P I I I I I I
I I
APPENDIX D
OSHA POSTER
300532
I b
p
The Occupational Safety and Health Act of 1970 provides job safety and health protection for workers by promoting safe and healthful working conditions ^ -throughout the Nation. Provisions of the Act inclucle the following: ' ]
^^.
Employers All employers must furnish to employees employment and a place of
employment free from recognized hazards that are causing or are likely to cause death or senous harm to employees Employers must comply with occupational safety and health standards issued under the Act ^ ' i.i''
Emptoyees Employees must comply with all occupational safety and health
standards rules regulations and orders issued under the Act that apply to their own actions and conduct on the job <• ' ^ ^ C. "'
The Occupational Safety and Health Administration (OSHA) of the U S Department of Labor has the pnmary responsibility for administenng the Act OSHA issues occupational safety and health standards and its Compliance Safety and Health Officers conduct lobsite inspections to help ensure compliance with the Act
Inspection -_ '- The Act requires that a representative of the employer and a representative authonzed by the employees^be given an opportunity to accompany the OSHA inspector for the purpose of aiding the inspection ^-^ 1
Where there is no authonzed employee representative the OSHA Compliance Officer must consult with a reasonable number of emptoyees concerning safety and health conditions in the workplace ^ -" -.
Complaint Employees or thetr representatives have the nght lo file a complaint
with the nearest OSHA office requesting an inspectlon<if they believe * ^ unsafe or unhealthtui conditions exist in their workplace OSHA will '''! „
r withhold on request names of employees complaining ^ :a •" ^ J^XJ-^ " The Act provides that employees may not be discharged or discnmi-..
nated against m any way for filing safety and health complaints or for otherwise exercising their nghts under the Act
^ Employees who believe they have been discnminated against may,file "- a complaint with their nearest OSHA office within 30 days of the alleged'
K~ discnminatory action - ^ <. * . _ ' ,^ j -^
Citation J- -It upon inspeclran OSHA believes an employer has violated the Act a' •
atation alleging such violations will be issued to the employer Each citation will specify a time penod within which Ihe alleged violation must be cor^ reeled
The OSHA oitation must be prominently displayed at or near the place of alleged violation for three days or until it is corrected whicheveris later to warn employees of dangers that may exist there
Proposed Penalty
The Act provides for mandatory civil'penalties against employers of up v to S7 000 for each senous violation and for optional penalties of up to ^ ^ ~^ I S7 000 for each nonsenous violation Penalties of up to S7 000 per day " j <* f ~ may be proposed for failure to correct violations within ttie prdpos"ed time ^^" ' ^ penod and for each day the violation continues beyond the prescnbed f,^>T^3;' abatement date Also any employerwhowillfullyorrepeatedly vioiates'the ^ ^ Act may be assessed penalties of up to S70 000 for each such violation A ^^ minimum penalty of S5 000 may be imposed for each willful violation A , \ violation of posting requirements can bnng a penalty of up to $7 000 •^^^' '~Ss • There are also provisions for cnminal penalties Any willful violation"'"^- ^
^resulting in the death of any employee upon conviction is punishable by at""" fine of up to $250 000 {or S500 000 if the employer ts a corporation) or by ' \ -impnsonment for up to SIX months or both A second conviction of an employer doubles the possible ternrof impnsonment Falsifying reconds ' ' ^ V -reports or applications is punishable by a fine of S 10 000 or up to six ^ ^ ,..•. -•months in Jail or^both > ' > ^-j-_^^>% "^J-^ \ ^ ^ i ^ ^ - ^ ^ " ^ ^ ^ -
Voluntary Activity
--"t ^ •^ While providing penalties for violations ^the Act also encourages ^ ^ ^ s ^ c ^ i ^ ^ ^•'"'^efforts by labor and management befor^arToSHA mspection-to reduce^-s.tls^'T
" ^ ^ workplace hazards voluntarily and to develop and improve safet/and ^ ^A "^l health programs in all workplaces and industnes OSHAs Voluntary
' ' Protection Programs recognize outstanding efforts of this nature - ;y- ' OSKA has published Safety and Health Program Management^;; ^t ^ i ^ -?- <
\ " "^ Guidelines to assist employers in establishing or perfecting"programs to j^s^^ PU=^^ • ^ - -" prevent or control employee exp lo re to workplace hazards'^There'are ^ ^ ^ j r
many public and private organizations that can provide information and ^^^ ~ """ -assistance in this effort if requested Also your local OSHA office can
^ 1 * provide considerable help and advice on solving safety and health prob- ^^^
_s'ytr4 lems or i^n refer you lo other sources for help such as t ra in ing-4s- ' "C^^^- . " ^ -
Consultation x \ ... Free assistance in identifying and-correcting hazards andiin improving .,," f ^
'_. safety andhealth management IS available to^employe?s without*crtation ..M ^% ^ -or penalty through OSHA-supportedprograrris in each State iTtiese t , ^ - - j £ f < _ -
' programs are usually administered by the State Labor or Health depart-" ' "S* ••^'•mentora State university r ' ^ , . 1 ' ' f ' J . ' ^ • ' ' t f J - " r . ' t j j f >5i^i
^.*' ' - ._-' -^yy'j- _ t'^-t,%'s '.-.«£'''i'ift -•fet -'
^.-^^ Employers in States operating OSHA approved Slate Plans should " l
obtain and post the State s equivalent poster - • ^ . "IA ~ ~
Posting Instructions
Under provisions of Title 29 Cade'at Federal Regulations Part 1903 2(a)(1) employers must post this notice , . (or facsimile) in a conspicuous place where notices to employees are customaniy posted
i More Information
Additional information and copies of 'he Act OSHA safety and health standards and other applicable regulations may be obtained from your employer or from the nearest OSHA Regional Office in the following locations
Atlanta GA Boston fylA Chicago IL Dallas TX Denver CO Kansas City MO New York NY Philadelphia PA San Francisco CA Seattle WA
(404) 562 2300 (817) 565-9860 (312) 353 2220 (214) 757 4731 (303) 844-1600 (816)425-5861 (212) 337-2378 (215) 598-1201 (415) 975 4310 (206) 553-5930
( ^ Y ^ ^ - ^ ^ j q ^
, Washington DC 1997 (Rep nnted) OSHA 2203
Alexis fvf Herman Secretary of Labor _
U.S. Department of Labor Occupational Safety and Health Administration
U> O o cn to Ui
T?iis information will be made available ta sensory impaired individuals UDon requesL , Voice pfione. (202) 219-8615. TOO message leierral qtiana. 1,300-326-2577
> "O
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APPENDIX E
EMPLOYEE MEETING RECORD
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I 300535
I CDM FEDERAL PROGRAMS CORPORATION
EMPLOYEE MEETING RECORD
Date: . Time:
Duration of training:
Topics discussed:
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Projea # or office locatiGn: Instructor:
Attendance Print Name Signature
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,
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HIGH-PimiTY STANDARDS - ARSENIC Page 1 of 5
HIGH-PURITY STANDARDS -- ARSENIC MATERIAL SAFETY DATA SHEET NSN: 681000N065017 Manufacturer's CAGE: 0YZE5 Part No. Indicator: A •_ , Part Number/Trade Name: ARSENIC
General Information
Company's Name: HIGH-PURITY.STANDARDS Company's P. 0. Box: 30188 Company's City: CHARLESTON Company's State: SC Company's Country: US Company's Zip Code: 29417 Company's Emerg Ph #: 803-556-3411 Company's'Info Ph #: 803-556-3411 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 •Status : SMJ Date MSDS Prepared: 01MAR95 Safety Data Review Date: 160CT95 MSDS Serial Number: BZRFZ -
Ingredients/Identity Information
Proprietary: NO Ingredient: ARSENIC; (AS) (SARA 313) (CERCLA) Ingredient Sequence Number: 01' Percent: 0.1 • NIOSH (RTECS) Number: CG0525000 ' '• -CAS Number: 7440-38-2 OSHAPEL: SEE 1910.1018 -, , ' ACGIH TLV: 0.01 MG/M3, Al ' • .
Proprietary: NO Ingredient: NITRIC ACID;(HN0*3) (SARA 302/313)' (CERCLA) Ingredient Sequence Number: 02• ' ' Percent: 2 . ' • \ NIOSH (RTECS) Number:' QU5775000 CAS Number:"- 7697-37-2 OSHA PEL: 2' PPM •'. . ACGIH TLV: 2 PPM/4 STEL
Proprietary:•NO Ingredient: SUP DAT: SUFFICIENT CONC CAUSES CYANOSIS." ONSET OF THIS CNDTN MAY BE.DELAYED 2-4 HRS/EVEN LONGER. ARSENIC & ITS(ING 4) Ingredient Sequence Number: 03 • NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ' , ' ' ' ACGIH TLV: NOT APPLICABLE , ' • • ,
Proprietary: NO ' • • Ingredient: ING 3: CMPDS CAUSE SYMPCHARACT BY, CONSTRICTION OF THROAT FOLLOWED -BY DYSPHAGIA, EPIGASTRIC PAIN, VOMIT & WATERY (ING 5) Ingredient Sequence Number: 04 NIOSH (RTECS) Number: 9999999ZZ . ' ' •• OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT , APPLICABLE ' - ' .
Proprie.tary: NO . Ingredient: ING 4: DIARR. BLOOD MAY APPEAR IN VOMITUS & STOOL. IF AMT
3 0 0 5 3 7
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ACTIVITY HAZARD ANALYSIS
fl2
1 ,
2
Subcontractor Ajyirovals
Environmental, Safety, and Health
Site Svipervisov
ft. Flint Name b. Signature • c. Date
•
|13] Change Summarv
f61 Activity Steps
. .
\U
1
2
[71 Work Groups
•
f8] Hazards
Sulicoiitractor Approvals
Environmental, Safety, and Health
Site SiipeiAfisor
a, Flint NaiTie
• • . •
[9] Hazard Controls (Engineered, Operational, Documents, PPE, Qualifications)
'
b. Signature c. Date
I b ACTIVITY HAZARD ANALYSIS
PRE-JOB BRIEFING ATTENDANCE
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AHA No: 3220-032-01
Service Supervisor
Job Title: AHA for Drilling Safety
Performer Organization:
Date: ,
Time:
I aere'e to work within the scope of work and follow the work controls descnbed in the bnefina.
Signature
,
Badge No. or SSN
•
Organization
•
i 300539
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300540
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p APPENDIX F
MATERIAL SAFETY DATA SHEETS
V 300541
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HIGH-PURITY STANDARDS - ARSENIC
HIGH-PURITY STaiMD J?.DS -- J JlSENIC MATERIAL SAFETY DATA SHEET NSN: 68L000N065017 Manufacturer's CAGE: 0YZE5 Part No. Indicator:' A. Part Number/Trade Name: ARSENIC
Page 1 of 5
General Information
P
Company's Name: HIGH-PURITY STANDARDS Company's P. 0. Box: 3 0133 • • Company's .City: CHARLESTON Company's State: SC Company's Country: US Company's Zip Code: 29417 Company's Emerg Ph #: 303-556-3411 Company's Info Ph #: 803-556-3411 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001, Status: SMJ Date MSDS Prepared:, 01MAR95 Safety Data. Review Date: 160CT95 MSDS Serial Number: BZRFZ
Ingredients/Identity Information
Proprietary: NO Ingredient: ARSENIC; (AS) (SABA Ingredient Sequence Number: 01 Percent: 0.1 NIOSH (RTECS) Number: CG0525000 CAS Number: 7440-38-2 OSHA PEL: SEE 1910.10,18 ACGIH TLV: 0.01 MG/M3, Al
Proprietary: NO Ingredient: NITRIC ACID;(HN0*3) Ingredient Sequence Number: 02 • Percent: 2 NIOSH (RTECS) Number: QU5775000 CAS Number: 7597-37-2 OSHA PEL: 2 PPM ACGIH TLV: 2 PPM/4 STEL
!13) (CERCLA)
(SAJIA 302/313) (CERCLA)
Proprietary: NO Ingredient: SUP DAT: SUFFICIENT CONC CAUSES CYANOSIS. MAY BE DELAYED 2-4 HRS/EVEN LONGER.' ARSENIC & ITS(ING Ingredient Sequence Number: 03 NIOSH (RTECS) 'Number:' 9999999ZZ OSHJV PEL: NOT APPLICABLE ACGIH TLV: NOT .APPLICABLE ' '
ONSET OF THIS CNDTN 4)
I Proprietary: NO Ingredient: ING 3: CMPDS CAUSE S'mP CHARACT BY CONSTRICTION FOLLOWED BY DYSPHAGIA, ' EPIGASTRIC'PAIN, VOMIT & WATERY (ING Ingredient Sequence Number: 04 NIOSH (RTECS) 'Number: 99999992Z OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
OF 5)
THROAT
Proprietary: NO Ingredient: ING
O o Ul
to
DIARR. BLOOD MAY APPEAR IN VOMITUS & STOOL.- IF AMT
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HIGH-PURITY STANDARDS--ARSENIC Page 2 of 5
INGESTED IS SUFFICIENTLY HIGH, SHOCK MAY DEVELOP DUE (ING 6) Ingredient Sequence Number: 05 NIOSH (.RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 5: TO SEV FLUID LOSS. CONTINUED POIS BY INGEST CAN CAUSE WT LOSS, NAUS, DIARR ALTERNATING W/CONSTIPATION, (ING 7) Ingredient Sequence Number: 06 NIOSH (RTECS) Number:"'9999999ZZ ' ^ • ' OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 5: PIGMENTATION & ERUPTION OF SKIN,. LOSS OF HAIR, & PERIPHERAL NEURITIS. POLYNEURITIS MAY ALSO. RESULT. (ING 8) Ingredient Sequence Number: 07 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary:- NO Ingredient: ING 7: HORIZONTAL WHITE LINES (STRIATIONS) ON FINGERNAILS S TOENAILS ARE COMMONLY SEEN W/CHRONIC EXPOS & ARE. (ING 9) Ingredient Sequence Number: 08 NIOSH (RTECS)' Number: 9-999999ZZ-OSHA PEL: NOT APPLICABLE -ACGIH TLV: NOT APPLICABLE
•Proprietary: NO - ' _ " • Ingredient: ING 8: CONSIDERED TO BE DIAGNOSTIC ACCOMPANIMENT - OF ARSENICAL POLYNEURITIS. -IF ARSENIC POIS OCCURS DUE TO (ING 10) Ingredient Sequence Number: 09 . ' -NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ' ' •
.Proprietary: NO , . Ingredient: ING 9: INHAL, COUGH, CHEST PAIN, DYSPNEA, HDCH & EXTREME GEN WEAK PRECEDE GI SYMP. ACUTE POIS DUE TO INHAL IS. (ING 11) Ingredient Sequence Number: 10 [ NIOSH . (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 10: RARE IN" INDUS, BUT CHRONIC BRTHG OF INORG.ARSENIC CMPDS' IS THE MOST COMMON CAUSE OF HAZ IN WORK.' PLACE. (ING 12) Ingredient Sequence Number: 11 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE- ' ACGIH TLV: NOT APPLICABLE -
Proprietary: NO , ' ' ' Ingredient: ING 11: THIS CNDTN IS DIVIDED INTO 3 PHASES BASED ON DISTRESS SIGNS & SYMP: PHASE I: VICTIM DEVELOPS WEAK, LOSS (ING 13) • Ingredient Sequence Number: 12 'NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO
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HIGH-PURITY STANDARDS - ARSEMC Pase 3 of 5
Ingredient: ING 12: OF APPETITE, NAUS, OCCAS VOMIT, STOM DISCOMFORT & SOME DIARR. PHASE II: CONJUNC & CATARRHAL STATE OF (ING 14) Ingredient Sequence Number: 13 NIOSH '(RTECS) Number: 9999999ZZ OSHA. PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 13: MUC MEMB OF NOSE, LARYNX '& RESP PASSAGES DEVELOPS. CORYZA, HOARSENESS, & MILD TRACHEOBRONCHITIS MAY (ING 15) Ingredient' Sequence Number:. 14 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT'APPLICABLE
Proprietary: NO • Ingredient: ING 14: OCCUR. PERFORATION OF .NASAL SEPTUM IS COMMON, S PROBABLY THE MOST TYPICAL LESION OF UPPER RESP TRACT IN (ING 16) Ingredient Sequence Number: 15 NIOSH (RTECS) Number: 9999999ZZ . - OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 15: OCCUR EXPOS TO ARSENIC DUST. SKIN LESIONS, ECZEMATOID-& ALLERGIC IN TYPE, ARE COMMON. PHASE III: SYMPS (ING 17) Ingredient Sequence Number: 16 NIOSH (RTECS) Number: 9999999Z2 OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 16: OF PERIPHERAL NEURITIS, INITIALLY IN HANDS & FEET, WHICH IS ESSENTIALLY SENSORY, WILL DEVELOP. IN MORE (ING 18) Ingredient Sequence Number: 17 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE "ACGIH TLV: NOT APPLICABLE
Proprietary: NO . Ingredient: ING 17: SEV CASES, MOTOR PARAi WILL-OCCUR. FIRST MUSCLES AFFECTED BY THIS ARE USUALLY TOE EXTENSORS & PERONEI. (ING 19) Ingredient Sequence Number: 18 NIOSH (RTECS) Number: 9999999ZZ OSHAPEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO " Ingredient:' ING 18: IN ONLY MOST SEV CASES WILL PARAL OF FLEXOR MUSCLES OF FEET/OF EXTENSOR MUSCLES OF HANDS OCCUR. (ING 20) Ingredient Sequence Number: 19 NIOSH (RTECS) Number: 9999999ZZ OSH^. PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE ' • •
Proprietary: NO Ingredient: ING 19: ARSENIC IS ALSO CONSIDERED TO' BE A MUTAGEN. Ingredient Sequence Number: 20 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Physical/chemical'Characteristics
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HIGH-PURITY STANDARDS - ARSENIC Page 4 of 5
Appearance And Odor: CLEAR, COLORLESS ODORLESS SOLUTION Boiling Point: 212F,lOOC 'Vapor Pressure (MM Hg/70 F): N/A Vapor Density (Ad.r=l) : N/A Specific Gravity: 1 (H*20=l) • " Solubility In Water: COMPLETE - ,
Fire and Explosion Hazard Data
Flash Point: N/A - ' ' Lower Explosive Limit: N/A - -Upper Explosive Limit: N/A - , Extinguishing Media: USE MEDIA SUITABLE FOR SURROUNDING FIRE (FP N). Special Fire Fighting Proc:'WEAR NIOSH/MSHA APPROVED SCBA -S FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Exp1 Hazrds: TOXIC GASES PRODUCED: NO, N0*2 .
Reactivity Data
Stability: YES Cond To Avoid (Stability):' METALS, HYDROXIDES, CARBONATES, CYANIDES. Materials To Avoid:. STRONG REDUCING AGENTS. Hazardous Decomp Products: NO, N0*2. Hazardous Poly Occur: NO - -Conditions To Avoid (Poly): NOT RELEVANT.
Health Hazard Data
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of.Entry - Ingestion: NO ' . Health Haz Acute And Chronic: ACUTE: ARSENIC & ITS CMPDS CAN BE FATAL IF INHALED, SWALLOWED/ABSORBED THRU SKIN. PRLNG CONT RSLTS IN LOC HYPEREMIA & LATER VESICULAR/PUSTULAR ERUPTION. MOIST MUC MEMB ARE MOST SENSITIVE TO IRRITANT ACTION. CONJUNCTIVA, MOIST & MACERATED'AREAS OF SKIN, EYELIDS, ANGLES OF EARS, NOSE, MOUTH & RESP (EFTS OF OVEREXP) Carcinogenicity - NTP: YES . ' Carcinogenicity -' lARC: YES • Carcinogenicity - OSHA: YES _ • Explanation Carcinogenicity:- ARSENIC: lARC MONO, SUPP, VOL 7, PG 100, 1987: GROUP 1. NTP'7TH'ANNUAL REPORT ON CARCINS, 1994: KNOWN TO BE (SUP. DAT) Signs/Symptoms Of Overexp: HLTH HAZ: MUCOSA ARE ALSO VULNERABLE TO IRRITANT EFTS. WRISTS ARE COMMON SITE OF DERM. ARSENIC IS ALSO CAPABLE OF PRODUCING KERATOSES, ESPECIALLY TO PALMS <5 -SOLES. THERE IS • SUFFICIENT EVIDENCE THAT SUPPORTS FACT THAT SKIN CANCER IN HUMANS IS ASSOC W/EXPOS TO INORG ARSENIC CMPDS IN DRUGS, DRINKING WATER & IN (SUP DAT) Med Cond Aggravated By Exp: BURNS, DERMATITIS, LARYNGEAL SPASM, PULMONARY . EDEMA CAN BE AGGRAVATED BY HN0*3. Emergency/First Aid Proc: CALL MD. INGESTION: DO NOT INDUCE VOMITING. IF CONSCIOUS, GIVE WATER, MILK. EYES/SKIN: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. INHALATION: REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE OXYGEN OR ARTIFICIAL RESPIRATION) (FP N) . ' •" - ' '~~'
Precautions for Safe Handling and Use 00
- == o S t e p s I f M a t l R e l e a s e d / S p i l l : REMOVE SOURCE OF IGNITION I F HYDROGEN I S A O HAZARD. PROVIDE OPTIMUM VENTILATION.'FLUSH TO HOLDING AREA FOR -p NEUTRALIZATION. N e u t r a l i z i n g A g e n t : NONE SPECIFIED BY MANUFACTURER. W a s t e D i s p o s a l M e t h o d : -FOLLOW FEDERAL, STATE, AND LOCAL REGULA.TIONS FOR
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ACID WASTE. EPA HAZARDOUS WASTE #: POIO. Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED. Other Precautions: NONE SPECIFIED BY MANUFACTURER.
Control Measures,
Respiratory Protection: USE NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: LOCAL EXHAUST. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPRVD CHEM WORKERS GOGGS .(FP N) . Other Protective Equipment: LAB COAT/APRON: VENT HOOD. EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA (FP N). Work. Hygienic Practices: NONE SPECIFIED BY'MANUFACTURER. Suppl. Safety & Health Data: CARCIN EXPLAN: CARCIN. OSHA REGULATED:- CFR 29 1910.1018. EFTS OF OVEREXP: OCCUR ENVIRON. THERE ARE ALSO CASE REPORTS THAT SUGGEST THAT THERE IS AN' ASSOC BETWEEN EXPOS TO ARSENIC CMPDS'i BLOOD ' ' .DYSCRASIAS & LIVER TUMORS. IT MAY CAUSE IRRIT .5 -ABSORPTION INTO BODY WHICH LEADS TO FORMATION OF METHEMOGLOBIN WHICH IN (ING 3) - '
Transportation Data
Disposal Data
Label Data
Label Required: YES • Technical Review Date: 160CT95 , ' Label .Date: 160CT95 Label Status: G ' Common.Name: ARSENIC Chronic Hazard: YES - ' Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Severe: X ' Fire Hazard-None: X - ^ . Reactivity Hazard-None: X Special Hazard Precautions: POISON. ACUTE: ARSENIC & ITS COMPOUNDS ZM>\ BE' FATAL IF INHALED, SWALLOWED OR ABSORBED THROUGH SKIN. PROLONGED CONTACT RESULTS- IN LOC HYPEREMIA AND LATER VESICULAR OR PUSTULAR ERUPTION. MOIST MUCOUS MEMBRANES ARE MOST SENSITIVE TO IRRITANT ACTION. CONJUNCTIVA, MOIST AND -MACERATED AREAS OF SKIN, EYELIDS, ANGLES OF EARS, NOSE, MOUTH 4 RESP MUCOSA ARE ALSO VULNERABLE TO THE IRRITANT EFFECTS. DERMATITIS MAY OCCUR ON WRISTS. CHRONIC: CANCER HAZARD. ARSENIC IS LISTED AS A HUMAN SKIN AND LIVER CARCINGEN(FP N). Protect Eye: Y Protect Skin: Y , Protect Respiratory: Y Label Name: HIGH-PURITY STANDARDS Label P.O. Box: 30188 Label City: CHARLESTON Label State: SC Label Zip Code: 29417 Label Country: US ' ' • . - • Label Emergency Number: 803-556-3411
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ENVmON^lENTAL RESOURCE ASSOCIATES - 1000 PPM BARTU 'l - LABORATO,, Page 1 of;
ENVIRONMENTAL RESOURCE ASSOCIATES — 1000 PPM BARIUM - LABORATORY STAi>;DARD MATERIAL SAFETY DATA SHEET NSN; 655000F037416 Manufacturer's CAGE: 1R664-Part No. Indicator: A • Part Number/Trade Name: 1000 PPM BARIUM
General Information
Item -Name: LABORATORY STANDARD Company's.Name: ENVIRONMENTAL RESOURCE ASSOCIATES Company's Street: 5540 MARSHALL ST Company's City: ARVADA' Company's State: CO ' - '• ~ . Company's Country: US Company's Zip Code: 80002-3108 Company's Emerg Ph S.: 303-431-8454 Company's Info Ph #: 303-431-8454 -Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SE - . -Date MSDS Prepared: 05MAR92 Safety Data Review Date: 22NOV94 MSDS Preparer's Name: DANIEL A GOLDSTEIN Preparer's Company: ENVIRONMENTAL RESOURCE ASSOCIATES Preparer's St Or P. 0.. Box: 5540 MARSHALL ST Preparer's City: ARVADA - , Preparer's State: CO Preparer's Zip Code: 80002-3108 MSDS Serial-Number: BWHZQ
Ingredients/Identity Information
Proprietary: NO -Ingredient: NITRIC ACID, HYDROGEN NITRATE Ingredient Sequence Number: 01 Percent: <5 NIOSH (RTECS) Number': QU5775000 - -• ' CAS Number: 7597-37-2 'OSHA PEL:;--2 PPM ACGIH TLV: 5.2 MG/CUM
Proprietary: NO Ingredient: BARIUM NITRATE Ingredient Sequence Number: 02 -Percent: .<1 NIOSH (RTECS) Number: CQ9625000 CAS Number: 10022-31-8 OSHA PEL: 0.5 MG/CUM ACGIH TLV: 0.5 MG/CUM
Physical/Chemical Characteristics
Appearance And Odor: CLEAR LIQUID W/NO ODOR Boiling Point: (SEE SUPP) ' - ' ' Vapor Pressure (MM Hg/70 F): 28 , ^ Vapor Density (Ai-r=l) : >1 - Q Specific Gravity: 1 Ol
Lity In Water: COMPLETE pH: <1 - .
Evaporation Rate And Ref: (WATER =1): 1 Solubility In Water: COMPLETE ^
'Ui-*,n,. l l r ^ c A c r^r i^ nt^T-naW a r l i i / m c / H o / o i t - i / m c r l c / V i / n ? 1 fi/n? 1 fi h t m l 1 / 7 / 2 0 0 1
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HIGH-PURITY STANDARDS - CHROMTUJ I Page 1 of 3
HIGH-PURITY ST.AJvIDARDS — CHROMIUM MATERIAL SAFETY DATA SHEET NSN: 681000N066370 Manufacturer's CAGE: 0Y2ES Part No. Indicator: A Part Number/Trade Name: CHROMIUM
General Information
Company's Name: HIGH-PURITY STANDARDS Company's P. 0. Box: 3018 8 Company''s City: CHARLESTON Company's State: SC Company's Country: US Company's Zip Code: 29417 Company's Emerg Ph #: 803-556-3411 Company's Info.Ph #: 803-556-3411 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 .Status : SMJ Date MSE S Prepared: 01NOV93 Safety. Data Review Date: 10NOV95 MSDS Serial Number: CBDNR . '
Ingredients/Identity. Information
Proprietary: NO Ingredient: CHROMIUM (III) CHLORIDE (1:3); (CHROMIUM) (SARA 302/313) (IN 10% INGREDIENT-2) Ingredient Sequence Number: 01 Percent: 1 NIOSH (RTECS) Numb'er: GB5425000' CAS Number: 10025-73-7 OSHA PEL: 0.1 MG (CR03)/M3 ACGIH TLV: 0.05 MG(CR)/M3
Proprietary: NO Ingredient: NITRIC ACID; (HN0*3). (SARA 302/313) (CERCLA) Ingredient Sequence .Number; 02 Percent: 10 ' . - , NIOSH (RTECS) Number: QU5775000 CAS Number: 7697-37-2 OSHA PEL: 2 PPM ACGIH TLV: 2 PPM/4 STEL
Physical/Chemical Characteristics
Appearance And Odor: DARK .BLUE, ODORLESS SOLUTION. - Boiling Point:, 212F, lOOC Melting Point :' N/A - ' Vapor Pressure (MM Hg/70 F) ,: N/A Vapor Density (Aa.r=l)~: N/A Specific Gravity: 1 (H*20=l) Solubility In Water: COMPLETE
Fire and Explosion Hazard Data
Flash Point: NOT APPLICA.BLE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media:. MEDIA SUITABLE FOR SURROUNDING FIRE (FP N) . Special Fire Fighting. Proc: WEAR NIOSH/MSHA APPROVED SCBA i FULL .' 3 0 0 5 4 8
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PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: NOT APPLICABLE. TOXIC GASES PRODUCED:NO, NO*2 GAS.
Reactivity Data
Stability: YES' -Cond To Avoid (Stability): METALS, HYDROXIDES, CARBONATES, CYANIDES. Materials To Avoid: STRONG REDUCING AGENTS. Hazardous Decomp Products: NO, N0*2. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT
Health.Hazard Data
LD50-LC50 Mixture: NONE SPECIFIED BY - MANUFACTURER. Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: LIQUID MAY-CAUSE BURNS TO SKIN AND EYES. Carcinogenicity - NTP: NO Carcinogenicity - lARC: NO Carcinogenicity - OSHA: NO -Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS. Med Cond Aggravated By Exp: NONE IDENTIFIED.-Emergency/First Aid Proc: INHAL:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE 0*2/ARTF RESP) (FP N). CALL A PHYSICIAN. INGESTION:DO NOT INDUCE VOMITING, IF CONSCIOUS GIVE-WATER, MILK. EYES:FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. SKIN:FLUSH WITH PLENTY OF WATER.
Precautions for Safe Handling and Use,
Steps If Matl Released/Spill': REMOVE -SOURCE OF IGNITION IF HYDROGEN IS A HAZARD. PROVIDE OPTIMUM VENTILATION. .'FLUSH TO HOLDING AREA FOR NEUTRALIZATION. , ' - - . Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method:. FOLLOW FEDERAL, STATE AND LOCAL REGULATIONS FOR ACID WASTE. •Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED. Other Precautions: NONE SPECIFIED BY MANUFACTURER.
Control Measures
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: LOCAL EXHAUST. VENT HOOD. Protective Gloves: IMPERVIOUS GLOVES (FP N). PROPER GLOVES. Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT) Other Protective Equipment: ANSI APPROVED EMERGENCY EYE WASH AND DELUGE SHOWER (FP N). LAB COAT/APRON; VENT HOOD.- ' Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: EYE PROT:AND FULL LENGTH.FACE SHIELD (FP N).
. Transportation Data
Dis-posal Data
Label Data
Label Required: YES Technical Review Date: 10NOV95
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HIGH-PURITY STANDARDS - CHROMIU^I Page 3 of 3
Label Status: G " Common Name: CHROMIUM Chronic Hazard: NO -Signal Word: CAUTION! Acute Health Hazard-Slight: X . ' Contact Hazard-Slight: X ' . " ' Fire Hazard-None: X Reactivity Hazard-None: X • Special Hazard Precautions:-ACUTE:LIQUID MAY CAUSE BURNS TO SKIN AND EYES. CHRONIC:NONE SPECIFIED BY MANUFACTURER. Protect Eye: Y , , ' Protect Skin: Y Protect Respiratory: Y , . Label Name: HIGH-PURITY STANDARDS Label P.O. Box: 3018 8 Label City: CHARLESTON ' ^ . Label State: SC Label Zip Code: 29417 Label Country: US ' ' Label Emergency Number: 803-556-3411
300550
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INORGANIC VENTUmES - CALCIUM 10000 UG-ML (1% W-V) - LABORATORY S.. Page 1 of 3
INORGAIIIC VENTURES — CALCIUM 10000 UG-ML (1% W-V) - LABORATORY STANDARD MATERIAL SAFETY DATA SHEET -NSN: 681000F025232 Manufacturer's CAGE: 0EK28 Part No. Indicator: B ' . Part Number/Trade Name: CALCIUM 10000' UG/ML (1% W/V)
General Information
Item Name: LABORATORY STANDARD Company's. Name: INORGANIC VENTURES INCORPORATED Company's Street: 195 LEHIGH AVENUE SUITE 4 Company's City: LAKEWOOD Company's State: NJ . . Company's Country: US Company's Zip Code: 08701-5000 - .. • Company's' Emerg Ph #': -800-669-6799 Company's Info Ph #: 800-569-6799 Record-No. For Safety Entry: 002 Tot Safety Entries This Stk#: 00-2 Status :• FE ' Date MSDS Prepared: 01JAN91 ' • -Safety Data Review Date: 16NOV94 Preparer's Company: INORGANIC VENTURES INCORPORATED Preparer's St Or P. 0. Box: 195 LEHIGH AVENUE SUITE 4 Preparer's City: LAKEWOOD -Preparer's State: NJ Preparer's Zip Code: 08701-5000 MSDS Serial Number: BWHPW
- Ingredients/Identity Information
Proprietary: NO -Ingredient: CALCIUM NITRATE • ' . Ingredient Sequence Number: 01 NIOSH (RTECS) Number: EW2985000 CAS Number: '10124-37-5 .
Proprietary: NO -Ingredient: NITRIC ACID, HYDROGEN NITRATE Ingredient Sequence Number: 02' NIOSH (RTECS) Number: QU5775000 CAS Number: 7697-37-2 OSHA PEL: 5 MG/CUM, 'ACGIH TLV: 5 MG/CUM
Proprietary: NO Ingredient': WATER Ingredient Sequence Number: 03 NIOSH (RTECS) Number: ZCOllOOOO CAS Number: 7732-18-5
Physical/Chemical Characteristics
Appearance And Odor: CLEAR COLORLESS SOLUTION W/SLIGHT ODOR. - Boiling Point: 212F . Specific Gravity: '1 . - ' • '-Solubility In Water: COMPLETE '
Fire and Explosion Hazard Data
Extinguishing Media: USE APPROPRIATE MEDIA FOR SURROUNDING FIRE.
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INORGANIC VENTURES - CALCIU^I 10000 UG-ML (1% W-V) - LABORxATORY S.. Page 2 of 3
Special Fire Fighting Proc: WEAR PROPER PROTECTIVE EQUIPMENT & SELF CONTAINED BREATHING 'APPARATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE. • . . - •
Reactivity Data
Stability: YES ' ~ -Materials To Avoid: ORGANIC MATERIALS, STRONG REDUCING AGENTS. Hazardous Decomp Products: OXIDES OF NITROGEN. Hazardous Poly Occur: NO ,
Health Hazard Data
Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route.Of Entry- - Ingestion: NO Health Haz Acute And Chronic: INHALATION: SEVERE IRRITATION/BURNS OF ,, RESPIRATORY SYSTEM,- PULMONARY EDEMA, LUNG INFLAMMATION, MAY BE F.ATAL. SKIN/ EYES: SEVERE IRRITATION/BURNS. INGESTION: SEVERE BURNS/ULCERATION OF MOUTH, THROAT & -STOMACH. Carcinogenicity - NTP: NO Carcinogenicity - lARC: NO ' ' . Carcinogenicity - OSHA: NO ' , Explanation Carcinogenicity: NONE- j Signs/Symptoms Of Overexp: IRRITATION, BURNS, COUGHING, DIFFICULT' BREATHING, CHEST PAINS, UNCONSCIOUSNESS. Emergency/First Aid Proc: INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS GIVE WATER, MILK/MILK OF MAGNESIA. SKIN/EYES: FLUSH W/PLENTY OF WATER FOR 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Precautions for Safe Handling and Use
Steps If Matl Released/Spill: WEAR SCBA & FULL PROTECTIVE CLOTHING. STOP LEAK IF POSSIBLE W/OUT RISK. USE .WATER SPRAY TO REDUCE VAPORS. TAKE-UP W/ SAND/OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA W/WATER. .Waste Disposal Method: DISPOSE OF lAW/FEDERAL, STATE & LOCAL REGUIATIONS. CORROSIVE. WASTE D002. Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED. STORE IN CORROSION-PROOF AREA.
Control Measures
Respiratory Protection: NONE REQUIRED. Ventilation: LOCAL EXHAUST/VENT HOOD. ' -Protective Gloves: REQUIRED Eye Protection: SAFETY GLASSES Other Protective Equipment: LAB COAT Work Hygienic Practices : REMOVE/LAUNDER CONTAMINATED CLOTHING '& SHOES BEFORE REUSE.
Transportation Data
Disposal Data
Label Data
Label Required: YES Label Status: G . Common Name: CALCIUM lOOOO UG/ML (1% W/V) Special Hazard Precautions: INHALATION: SEVERE IRRITATION/BURNS OF
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I INORGANIC VENTURES - CALCrU^I 10000 UG-ML (1% W-V) - LABORATORY S.. Page 3 of 3
RESPIRATORY SYSTEM, PULMONARY EDEMA, LUNG INFLAMMATION, MAY BE F-ATA.L. SKIN/ EYES: SEVERE IRRITATION/BURNS. INGESTION: SEVERE BURI^JS/ULCERATION OF MOUTH, THROAT & STOMACH. IRRITATION, BURNS, COUGHING, DIFFICULT BREATHING, CHEST PAINS, UNCONSCIOUSNESS. Label Name: INORGANIC VENTURES - INCORPORATED Label Street: 195 LEHIGH AVENUE SUITE 4 . Label City: LAKEWOOD Label State: NJ Label Zip Code: 08701-5000 Label Country: US Lab.el Emergency Number: 800-669-6799
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TR METALS -LEAD ' Paae.l of 4
TR METALS -- LEAD MATERIAi SAFETY'DATA SHEET NSN: 681000N084293 Manufacturer's CAGE: 04MC9 Part No. Indicator: A . Part Number/Trade-Name: LEAD
General Information'
Company's Name: TR METALS Company's Street: 1 PAVILION AVE Company's City: RIVERSIDE Company's State: NJ ^ Company's Country: US Company's Zip Code: 08075 Company's Emerg Ph #: 800-424-9300(CHEMTREC) Company's Info Ph #: 609-461-9000 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Statu's : SMJ Date MSDS Prepared: 01JAN93 Safety Data Review Date:' 25MAR98 MSDS Serial Number: CGSQQ
Ingredients/Identity Information
Proprietary: NO Ingredient: LEAD (SARA 313) .(CERCLA) Ingredient Sequence Number: 01 Percent: 99.99 NIOSH-(RTECS) Number:. OF7525000 , ' ' CAS Number: 7439-92-1. OSHA PEL: N/K (FP N) ' ' .• .ACGIH TLV: ,0.15 MG/M3 DUST
Proprietary: NO Ingredient: SUPDAT: NERVOUS SYS DAMAGE RESULTING IN SEVERE HDCHS, CONVULSIONS, COMA, DELIRIUM & DEATH. ALCOHOL & PHYSICAL'(ING 3) Ingredient Sequence Number: 02 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 2: EXERTION CAN BRING ON'SYMPTOMS. OTHER EFFECTS OF LONG TERM EXPOSURE CAN RESULT IN DECREASED FERTILITY, (ING 4) Ingredient Sequence Number: 03 . NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO Ingredient: ING 3: MISCARRIAGE S BIRTH DEFECTS. Ingredient Sequence Number: 04. • NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO . Ingredient: HYGIENE PRACTS: HYGIENE IE, WASH HANDS & FACE BEFORE EATING, DRINKING, PUTTING ON MAKE-UP OR SMOKING. SHOWERING (ING 6) Ingredient Sequence Numb'er: 05
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TR METALS - LEAD Page 2 of 4
NIOSH (RTECS) Number: 9999999ZZ ,OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE-
Proprietary: NO Ingredient:' ING 5: IS REQUIRED BEFORE PUTTING ON STREET CLOTHES. Ingredient 'Sequence Number: 06 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
•Physical/Chemical Characteristics
Appearance And Odor: HEAVY, DUCTILE, SOFT, BLUISH-GRAY METAL. Boiling Point:'3164F,1740C Melting Point: 621F,327C Vapor Pressure (MM H-g/70 F) : 1 @ 973C Vapor Density (Air=l): N/A Specific Gravity: 11,34 (H*20=l) • Evaporation Rate And Ref: N/A Solubility In Water: INSOLUBLE Percent Volatiles By Volume: N/A
Fire and Explosion Hazard Data
Flash Point:' N/A Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: CLASS D EXTINGUISHERS: DRY POWDER TYPE. -Special Fire Fighting Proc: USE NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). •Unusual Fire And Expl Hazrds: NONCOMBUSTIBLE IN SOLID METAL FORM'. FLAMMABLE IN THE FORM OF DUST WHEN EXPOSED,TO HEAT'OR 'FLAME.
Reactivity Data
'Stability: YES . , , ' " Cond To Avoid (Stability): EXCESSIVE HEAT (IE,. ABOVE MELTING POINT). SEE MATERIALS TO-AVOID. Materials To Avoid: REACTS VIOLENTLY W/HYDROGEN PEROXIDE, CHLORINE TRIFLUORIDE, AMMONIUM NITRATE, POTASSIUM. INCOMPAT WITH NAN*3, (SUPDAT) Hazardous Decomp Products: WHEN HEATED -TO ABOVE MELTING POINT (IE, DECOMPOSITION) EMITS HIGHLY TOXIC FUMES OF LEAD. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT
Health Hazard Data
LD50-LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. . Route Of Entry - Inhalation: YES .- ' "" Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES - -Health Haz Acute And Chronic: LEAD APPEARS ON THE NAVY LIST OF OCCUR CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HEALTH PROFESSIONALS CONCERNING LATEST HAZ LIST INFO & SAFE HANDLING & EXPOSURE INFO (FP N). SKIN: MAY CAUSE IRRIT. EYES: MAY CAUSE IRRIT. NORMAL HANDLING OR PROCESSING OF'LEAD MAY RESULT IN GENERATION OF LEAD DUST (EFTS OF OVEREXP) Carcinogenicity - NTP: NO , . . Carcinogenicity - lARC: NO , ' ' , Carcinogenicity - OSHA: NO -Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: HLTH HAZ: &/0R FUME. LEAD IS CUMULATIVE TOXIN, .
^ EFTS OF PB EXPOS MAY NOT DEVELOP QUICKLY. SYMPS INCL DECREASED-PHYSICAL
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TR METALS - LEAD : ,. Page 3 of 4
FITNESS, LOSS OF APPETITE, ABDOMINAL PAINS, CONSTIPATION, FATIGUE, SLEEP DISTURBS-, HEA.DACHE, ANEMIA, IRRITABILITY, TREMORS, HALLUCINATIONS' & DISTORTED PERCEPTION, MUSCLE S JOINT P.AIN, MUSCLE (SUPDAT) Med Cond Aggravated By Exp: DISEASES OF THE BLOOD AND BLOOD FORMING ORGANS, KIDNEYS,- .NERVOUS SYSTEM AIID REPRODUCTIVE SYSTEM. Emergency/First Aid Proc: INHALATION: REMOVE TO FRESH AIR. GET IMMEDIATE MEDICAL ATTENTION. EYES: FLUSH WELL WITH WATER FOR AT LEAST 15 MINUTES. IF IRRITATION PERSISTS SEEK MEDICAL ATTENTION. SKIN: WASH AREA THOROUGHLY WITH SOAP AND W'ATER. INGESTION: GIVE WATER. SEEK IMMEDIATE MEDICAL ATTENTION.
Precautions for Safe Handling and Use
Steps If Matl Released/Spill: LEAD IN DUST FORM; MINIMIZE EXPOSURE. WEAR FULL PROTECTIVE CLOTHING INCLUDING NIOSH APPROVED RESPIRATORS. CLEAN UP USING DUSTLESS METHODS (IE, VACUUM, DO NOT USE COMPRESSED AIR) .. PLACE IN CLOSED LABELED CONTAINERS FOR RECYCLING OR PROPER DISPOSAL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND, LOCAL REGULATIONS'. MAY HAVE VALUE ON A RECYCLED . BASIS . Precautions-Handling/Storing: STRICT CONTROL OF ATMOSPHERIC CONCENTRATION IN PROCESSING AND WORK AREAS. KEEP MATERIAL DRY. AVOID STORAGE NEAR INCOMPATIBLE MATERIALS. Other Precautions: NOT APPLICABLE. '
Control Measures
Respiratory Protection: NIOSH APPROVED HIGH EFFICIENCY•RESPIRATOR FOR DUST AND LEAD FUME. USE A2>;D PROCESS IN A. WELL "VENTILATED AREA. 'Ventilation: LOCAL EXHAUST: AS REQUIRED FOR LEAD DUST S FUME. MECHANICAL (GEN): AS REQUIRED TO MAINTAIN APPROP OSHA PEL/TLV LEVELS. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: ANSI APPRVD CHEM WORKERS' GOGGLES (FP N) . Other Protective Equipment: ANSI APPRVD EYE WASH & DELUGE SHOWER (FP N). FULL PROT CLTHG & SHOES, INCLUDING .HARD HATS, REQD- FOR WORK W/MOLTEN METAL. Work Hygienic Practices: NO EATING, DRINKING OR SMOKING WHILE PROCESSING OR HANDLING LEAD OR IN LEAD AREAS. PRACTICE GOOD PERSONAL (ING 5) Suppl. Safety & Health Data: MATL TO AVOID: ZR, DISODIUM ACETYLIDE & OXIDANTS. CAN REACT STRONGLY W/OXIDIZING MATLS. EFTS OF OVEREXP: WEAK. INHAL OF LARGE AMTS OF LEAD MAY LEAD'TO SEIZURES, COMA & PALE SKIN, BLUE LINE AT GUM MARGIN, DECREASED HAND-GRIP & PARALYSIS OF WRIST JOINTS. PRLNGD VERY HIGH EXPOS CAN ALSO RSLT IN KIDNEY DMG S (ING'2)
Transportation Data
Disposal Data
Label Data
Label Required: YES . - ' Technical Review Date: 25MAR98 ' Label Date: 23MAR9 8 Label Sta.tus : G Common Name: LEAD Chronic Hazard: YES Signal Word: WARNING! •' -Acute Health Hazard-Moderate: X Contact Hazard-Slight; X , Fire Hazard-None-: X . - . Reactivity Hazard-None: X Special Hazard Precautions: ACUTE: EYES/SKIN: IRRITATION.. CHRONIC: LEAD APPEARS ON THE NAA/Y OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS.LIST (FP N).
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TR METALS - LEAD Page 4 of 4
SYMPTOMS OF LEAD OVEREXPOSURE INCLUDE DECREASED PHYSICAL FITNESS, LOSS OF APPETITE, ABDOMINAL P.AINS, CONSTIPATION, FATIGUE, SLEEP DLSTURBAl-JCES, HEADACHE, ANEMIA, IRRITABILITY, TREMORS, HALLUCINATIONS AND DISTORTED PERCEPTION, MUSCLE AND JOINT PAIN, MUSCLE WEAKNESS, SEIZURES, COMA & DEATH. .WEMIA, PALE SKIN, BLUE LINE AT -GUM MARGIN, DECREASED HAND-GRIP STRENGTH, ABDOMINAL PAIN, NAUSEA, VOMITING, AND PARALYSIS OF WRIST JOINTS. KIDNEY AND NERVOUS SYSTEM DAMAGE. Protect Eye: Y ' Protect Skin: Y ', . Protect Respiratory: Y Label Name: TR MET.ALS Label Street: 1 PAVILION AVE Label City: RIVERSIDE Label State: NJ Label Zip Code: 08075 Label Country: US . Label Emergency Number: 800-424-9300(CHEMTREC)
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INORGANIC VENTURES - MANGANESE 1000 UG-ML (0.1% W-V) - LABORATO.. Page 1 of 3
INORGANIC VENTURES — MANGANESE 1000 UG-ML (0.1% W-V) - LABORATORY STANDARD MATERIAL SAFETY DATA SHEET NSN: 681000F025261 Manufacturer's CAGE: 0EK28 - ^ Part No. Indicator: B Part Number/Trade Name: MANGANESE 1000 UG/ML (0.1% W/V)
General Information
Item Name: LABORA.TORY STANDARD Coinpany'.s Name: INORGANIC VENTURES INCORPORATED Company's Street: 195 LEHIGH AVENUE SUITE 4 Company's City: LAKEWOOD . ^ ' Company's State: NJ -Company',s Country: US Company's Zip Code: 08701-5000 •Company's Emerg Ph #: 800-669-6799 Company's Info Ph #: 800-669-6799 Record No. For Safety Entry: 002 Tot Safety Entries This Stk#: -002 "Status: FE - - -Date MSDS Prepared:'01JAN91 Safety Data Review Date: 21NOV94 Preparer's Company: INORGANIC VENTURES INCORPORATED Preparer's St Or P. 0. Box: 195 LEHIGH AVENUE SUITE 4 -Preparer's City: LAKEWOOD Preparer's State: NJ Preparer's Zip Code: 08701-5000 MSDS Serial Number: BWHQN -
Ingredients/Identity Information
Proprietary: NO ' _ • Ingredient: MANGANESE NITRATE Ingredient Sequence Number: 01 ' NIOSH (RTECS) Number: QU9780000 CAS Number: 10377-66-9 OSHA PEL: 5MG/CUM (MN) -ACGIH TLV: 5MG/CUM (MN)
Proprietary: NO Ingredient: NITRIC ACID, HYDROGEN NITRATE Ingredient Sequence Number: 02 . NIOSH (RTECS) Number: QU5775000 CAS Number: 7697-37-2 • , OSHA PEL:- 5 ,MG/CUM ' ACGIH TLV: 5 MG/CUM ,
Proprietary: NO ' -- ' Ingredient: WATER Ingredient Sequence Number: 03 . NIOSH (RTECS) Number:-ZCOllOOOO CAS Number: 7732-18-5
Physical/Chemical Characteristics
Appearance Ajid Odor: CLEAR COLORLESS SOLUTION W/NO ODOR. Boiling Point: 212F Specific Gravity:- 1 - . ' . Solubility In Water: COMPLETE
Fire and Explosion Hazard Data
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INORGANIC VENTURES - MANGANESE 1000 UG-ML (0.1% W-V) - LABORATO.. Page 2 of 3
Extinguishing Media: USE APPROPRIATE MEDIA FOR SURROUNDING FIRE. Special Fire Fighting Proc: WEAR, PROPER PROTECTIVE EQUIPMENT & SELF CONTAINED BREATHING APPAJATUS W/FULL FACEPIECE OPERATED IN POSITIVE PRESSURE MODE.
Reactivity Data
Stability: YES Materials To Avoid: ORGANIC MATERI.ALS, STRONG REDUCING AGENTS. Hazardous Decomp Products: OXIDES OF NITROGEN. Hazardous Poly Occur: NO ,
Health Hazard Data
Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO . Route Of Entry - Ingestion: NO -Health Haz Acute And Chronic: SKIN/EYES: LIQUID MAY CAUSE BURNS. Carcinogenicity - NTP: NO Carcinogenicity - lARC: NO Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE Signs/Symptoms Of Overexp: BURNS,'COUGHING, DIFFICULTY BREATHING, NAUSEA, VOMITING, ,LOSS OF CONSCIOUSNESS. Emergency/First Aid Proc: INGESTION: DON'T INDUCE VOMITING. IF CONSCIOUS GIVE WATER, MILK/MILK OF MAGNESIA. SKIN/EYES: FLUSH W/PLENTY' OF WATER FOR• 15 MINS. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Precautions for Safe Handling and Use
Steps If Matl Released/Spill: WEAR SCBA & FULL PROTECTIVE CLOTHING. STOP LEAK IF POSSIBLE W/OUT RISK. USE WATER SPRAY TO REDUCE VAPORS. TAKE UP W/ SAND/OTHER NON-COMBUSTIBLE ABSORBENT MATERIAL & PLACE INTO CONTAINER FOR LATER DISPOSAL. FLUSH AREA W/WATER. Waste Disposal Method: DISPOSE OF lAW/FEDERAL, STATE & LOCAL ENVIRONMENTAL REGULATIONS. CORROSIVE WASTE D002. Precautions-Handling/Storing: KEEP CONTAINER TIGHTLY CLOSED.. STORE IN CORROSION-PROOF AREA.
Control Measures.
Respiratory Protection: NONE REQUIRED. J Ventilation: LOCAL EXHAUST/VENT HOOD. Protective Gloves: REQUIRED ' ' -Eye Protection: SAFETY GLASSES Other Protective Equipment: LAB COAT Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE.
Transportation Data
Disposal Data
Label Data
, L a b e l R e q u i r e d : ' YES L a b e l S t a t u s : G • Common Name: MANGANESE 1000 UG/ML ( 0 . 1 % W/V) S p e c i a l H a z a r d P r e c a u t i o n s : SKIN/EYES: LIQUID MAY CAUSE BURNS. BURNS," COUGHING, DIFFICULTY BREATHING, NAUSEA, VOMITING, LOSS OF CONSCIOUSNESS.
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INORGANIC VENTURES - MANGANESE 1000 UG-ML (0.1% W-V) - LABOR.ATO.. Page 3 of 3
Label Name: INORGANIC VENTURES INCORPORATED Label Street: 195 LEHIGH .A /ENUE SUITE 4 Label City: LAKEWOOD Label -State: NJ Label Zip Code: 08701-5000 Label Country: US Label Emergency Number: 800-669-6799
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CANNON INSTRUMENT - MERCURY Paae 1 of 3
C J INON INSTRUMENT — MERCURY MATERIAL SAFETY DATA SHEET NSN: 681000N072047 Manufacturer's CAGE: 94481 Part No. Indicator: A Part Number/Trade Name: MERCURY
General Information
Company's Name: CANNON INSTRUMENT CO Company's P.' 0. Box: 16
. Company's City: STATE COLLEGE Company's State: PA Company'.s Country: US . Company's Zip Code: 16804-0016 Company's Emerg Ph #: 8 00-424-9300 (.CHEMTREC) Company's Info Ph #: 814-353-8000 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 'status: SMJ Date MSDS Prepared: 01MAR94 Safety Data' Review Date: 13AUG96 MSDS Serial Number: CBXNP - , .
Ingredients/Identity Information
Proprietary: NO -Ingredient: MERCURY; (OR QUICKSILVER) (SARA 313) (CERCLA) Ingredient Sequence Number: 01 . Percent:. 100 NIOSH (RTECS) Number: OV4550000 CAS Number: 7439-97-6 OSHA PEL: 0.1 MG/M3, C ACGIH TLV: 0.02 5 MG/M3, S
Physical/Chemical Characteristics
Appearance And Odor: SILVER METALLIC LIQUID;' NO ODOR. Boiling Point: 674F,357C Vapor Pressure (MM H'g/70' F) : 0.0019- -Vapor Density (Air=l): 1.015 -Specific Gravity: 13.59 (H*20=l) Evaporation Rate And Ref: <1 Solubility In.Water: 0 ' Percent Volatiles By Volume: 100
Fire and Explosion Hazard Data
Flash Point: NOT APPLICABLE Lower Explosive Limit: N/A Upper Explosive Limit: N/A Extinguishing Media: MEDIA SUITABLE FOR SURROUNDING FIRE (FP N) . ., : . Special Fire Fighting Proc: USE NIOSH APPROVED SCBA & FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: NOT APPLICABLE
Reactivity' Data
Stability: YES Cond To Avoid (Stability): AVOID LONG EXPOSURE TO AIR, HEAT, NON- FERROUS METALS. Materials To Avoid: NON-FERROUS.METALS. '
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Hazardous Decomp Products: NOT APPLICABLE Hazardous Poly Occur: NO Conditions To Avoid (Poly) : NOT RELEVAI fT
Health Hazard Data
LD50-LC50 Mixture:' NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation: YES Route Of' Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: ACUTE/CHRONIC:NERVOUS IRRIT.ABILITY, MERCURY APPEARS.ON THE NAVY LISTING OF OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFO & SAFE HANDLING & .(EFTS OF' OVEREXP) Carcinogenicity - NTP: NO Carcinogenicity - lARC: NO , Carcinogenicity - OSHA: NO ' Explanation Carcinogenicity:. NOT RELEVANT Signs/Symptoms Of Overexp: HLTH HAZ:EXPOSURE INFORMATION (FP N). Med Cond Aggravated By Exp: KNOWN ALLERGY TO MERCURY.
, Emergency/First Aid-Proc: INHALATION:REMOVE TO FRESH AIR. SUPPORT BREATHING (GIVE 0*2/ARTF RESP)" (FP'N). EYES:WASH WITH WATER FOR AT LEAST 15 MINUTES. SKIN:WASH WITH STANDARD SOAP S WATER. INGESTION:CONTACT QUALIFIED MD - DO NOT INDUCE VOMITING.
Precautions for Safe- Handling and Use
Steps If Matl Released/Spill: CLEAN UP SPILLS IMMEDIATELY. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL MUST BE I/A/W FEDERAL, STATE S LOCAL REGULATIONS (FP N). DO NOT INCINERATE. RETURN TO RECLAMATION CENTER. Precautions-Handling/Storing: -ALWAYS KEEP' MERCURY STORED IN A SEALED CONTAINER AWAY FROM HEAT. Other Precautions: STORE IN .SEALED CONTAINERS.^
Control" Measures
Respiratory Protection:. SHOULD BE NIOSH APPROVED. -YES. Protective- Gloves: IMPERVIOUS GLOVES' (FP N). -Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (FP N) . Other Protective Equipment: EYE .WASH FOUNTAIN & DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N).'WEAR PROTECTIVE CLOTHING - AVOID CONTACT. Work Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety & Health Data: NONE SPECIFIED BY MANUFACTURER.
- Transportation Data
Disposal Data
Label Data
Label Required: YES Technical Review Date: 13AUG96 Label Date: 07AUG96 Label Status: G ' -Common Name: MERCURY Chronic Hazard: -YES Signal Word: WARNING! Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X
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GANNON INSTRUMENT - MERCURY Page 3 of 3
Fire Hazard-None: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE/CHRONIC:MERCURY APPEARS ON THE NA A" OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS LIST (FP N). NERVOUS. IRRIT.ABILITY,, WEAKNESS, TREMORS, GINGIVITIS, ERETHISM, GREYING OF LENS' OF EYE. Protect Eye: Y . -, Protect Skin: Y ' Protect Respiratory: Y ' , Label -Name:' CANNON INSTRUMENT CO Label P.O. Box: lb" Label City: STATE COLLEGE Label-State: PA Label Zip Code: 16804-0015 Label Country: US Label Emergency Number: 800-424-9300 (CHEMTREC)
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ENVIRONJ^IENTAL RESOURCE ASSOCIATES - 1000 PPM VANADIUM - LABOR.. Paae 1 of 3
ENVIRONMENTAL RESOURCE ASSOCIATES -- 1000 PPM VANADIUM - LABORA.TORY STANDARD . MATERI.AL SAFETY DATA SHEET NSN: 655000F037435 Manufacturer's CAGE: '1R664 Part' No. Indicator: A ~ ~ - , Part Number/Trade Name: 1000 PPM VANADIUM
General Information
Item Name: LABORATORY STANDARD Company's Name: ENVIRONMENTAL RESOURCE ASSOCIATES Company'.s Street: 5540 MARSHALL ST' -Company's City: ARVADA Company's State: CO Company's Country: US Company's Zip Code: 80002-3108 Company's Emerg Ph #: 303-431-8454 Company's Info Ph #: 303-431-8454 Record No. For Safety Entry: 001 - ' . -Tot Safety Entries This Stk#: 001 Status: SE Date MSDS Prepared:_05MAR92 Safety Data Review Date: 29NOV94 MSDS Preparer's Name: DANIEL A GOLDSTEIN Preparer's Company: ENVIRONMENTAL RESOURCE ASSOCIATES Preparer's St Or P. 0. Box: 5540 MARSHALL ST Preparer's City: ARVADA Preparer's State: CO Preparer's Zip Code: 80002-3108 MSDS Serial Number: BWJBN • • ' - -
'Ingredients/Identity Information
Proprietary:, NO -Ingredient: NITRIC ACiD, HYDROGEN NITRATE Ingredient Sequence Number: 01 Percent: <5 NIOSH (RTECS) Number: QU5775000 CAS Number: 7697-37-2 . OSHA PEL: 2 PPM ACGIH TLV: 5.2 MG/CUM
Proprietary: NO Ingredient: VANADIUM OXIDE, VANADIUM TRIOXIDE Ingredient Sequence Number: 02 Percent: <1 NIOSH (RTECS) Number: YW30500.00 CAS Niimber: 1314-34-7 OSHA PEL: 0.05 MG/CUM ACGIH TLV: 0.05 MG/CUM Other Recommended Limit: 0.05 MG/CUM NIOSH
Physical/Chemical Characteristics
Appearance And Odor: CLEAJ LIQUID W/NO ODOR Boiling Point: (SEE SUPP) . Vapor Pressure (MM Hg/70 F) : 28 Vapor Density (Air=l): >1 Specific Gravity: 1' Evaporation Rate And Ref: •(WA'TER =1) : 1 • ' Solubility In Water: COMPLETE' p H : < 1 • -
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ENVIRONMENTAL RESOURCE ASSOCIATES - 1000 PPM VANADIUVI - LABOR.. Page 2 of 3
Fire and Explosion Hazard Data
Extinguishing Media: NONE Special Fire Fighting Proc: NONE Unusual. Fire And Expl Hazrds: NONE
Reactivity Data
Stability: YES. Cond To Avoid (Stability):•FREEZING Materials To Avoid: METALS Hazardous Decomp Products: HYDROGEN Hazardous Poly Occur: NO Conditions To Avoid (Poly): NONE
Health Hazard Data
Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: POISON & CORROSIVE TO SKIN, EYES,' MUCOUS MEMBRANES/LUNGS. MAY BURN ANY TISSUE & CAUSE BLINDNESS. MAY CAUSE GI TRACT PERFORATION, PULMONARY EDEMA. -VANADIUM: SYSTEMIC INTOXICATION IS UNLIKELY. Carcinogenicity -NTP: NO Carcinogenicity - lARC: NO' ' - . " ' Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NONE Signs/Symptoms Of Overexp: IRRITATION, BURNING, COUGH, METHEMOGLOBINEMIA, VOMITING. & DIARRHEA. Med Cond Aggravated By Exp: ASTHMA.. ' Emergency/First Aid Proc: EYES/SKIN: FLUSH W/COPIOUS AMOUNTS OF WATER. INHALATION: GIVE MOIST OXYGEN. INGESTION: GIVE WATER/MILK. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Precautions for Safe Handling and Use
-Steps If Matl Released/Spill: NEUTRALIZE & FLUSH W/WATER/NEUTRALIZE & ABSORB: VENTILATE 'AREA. Neutralizing Agent: BAKING.SODA. Waste Disposal Method: DISPOSE OF'.AS NON-HAZARDOUS WASTE lAW/FEDERAL, STATE & LOCAL REGULATIONS.' Precautions-Handling/Storing: AVOID FREEZING/ROUGH HANDLING/BREAKAGE. -Other' Precautions: AVOID INHALATION/DIRECT CONTACT W/DRIED RESIDUE. AVOID MIST/AEROSOL FORMATION. AVOID SKIN CONTACT DUE TO POSSIBLE SENSITIZING.
Control Measures
Respiratory Protection: WEAR ACID GAS TYPE- DUST/MIST RESPIRATOR IF MIST PRODUCTION OCCURS. Ventilation: MECHANICAL/LOCAL EXHAUST: USE TN HOOD. -Protective Gloves: ACID PROOF Eye Protection: .SPLASH GOGGLES-Other Protective Equipment: ACID PROOF APRON W/SLEEVES, LAB COAT, CLOSED SHOES-, SAFEETY SHOWER, EYE WASH. Suppl. Safety'&• Health Data: BOILING POINT (0-5% ACID): 212-212.72F.
Transportation Data
Disposal Data
300565 >i+tn//mQHQ nHr r n r n p j l prlii/mQHi;/«:iri/ms;ri.s/h/n21 6 / n 2 3 3 h t m l 1 /7 /2001
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ENVmON^IENTAL RESOURCE ASSOCIATES - 1000 PPiM VANADIU^I - LABOR., Page 3 of 3
Label Data
Label Required: YES Label Status: G Common Name: 1000 PPM VANADIUM Special Hazard Precautions: POISON & CORROSIVE TO SKIN, EYES, MUCOUS MEMBRANES/LUNGS. MAY BURN ANY TISSUE'S CAUSE BLINDNESS.--MAY CAUSE GI TRACT PERFORATION, PULMONARY EDEMA. VANADIUM: SYSTEMIC INTOXICATION IS UNLIKELY. IRRITATION, BURNING, COUGH, METHEMOGLOBINEMIA, REDNESS, SHORT' BREATH, P.AIN, VOMITING, DIARRHEA, CYANOSIS. VANADIUM SALTS: VOMITING S DIARRHEA. Label Name: ENVIRONMENTAL RESOURCE ASSOCIATES Label Street:' 5540 MARSHALL ST - -Label City:^ ARVADA Label State: CO . ' ' Label Zip Code: 80002-3108 Label Country: US , . . Label Emergency Number: 303-431-8454
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I T BAKER - M-XYLENE, X523 . Page 1 of 2
J T BAKER -- M-XYLENE, X52 3 • MATERIAL SAFETY DATA SHEET NSN: 681000N061477 Manufacturer's CAGE: 70829 Part No. Indicator: A Part Number/Trade Name: M-XYLENE, X523
General Information
Company's'Name: J, T BAKER INC Company's Street.: 222 RED SCHOOL LANE Company's City: PHILLIPSBURG Company's State: NJ Company's Country: US Company's Zip Code: 08865 Company's Emerg Ph #: 908-859-2151;800-424-9300(CHEMTREC) Company''s Info Ph #: 800-582-2537 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 09MAR92 Safety Data Review Date: 12JUL95 MSDS Serial Number: BXYPV
Ingredients/Identity Information
Proprietary: NO Ingredient: M-XYLENE; (M-DIMETHYLBENZENE) (SARA 313) (CERCLA) Ingredient Sequence Number:" 01 - • Percent: 90-100 NIOSH (RTECS) Number: ZE2275000 CAS Number:- 108-38-3 OSHA PEL: 100 PPM ACGIH TLV: 100 PPM/150STEL
Physical/Chemical Characteristics
Appearance And Odor: CLEAR, COLORLESS LIQUID. .AROMATIC ODOR. Boiling Point: 282F,139C Melting Point: -54F,-48C Vapor Pressure (MM Hg/70 F): 8.3 .@ 120C Vapor Density (Air=l): 3.66 Specific Gravity: 0.87 {H*20=l) Evaporation Rate And Ref: 0.51 (BUTYL ACETATE=1) Solubility In Water: NEGLIGIBLE (<0.1%) Percent Volatiles By Volume: 100
Fire and Explosion Hazard Data
Flash Point: 81.OF,27.20 Flash Point Method: CC - - ' -Lower Explosive Limit: 1.1% Upper Explosive Limit: 7.0% - -Extinguishing Media: USE ALCOHOL FOAM, DRY CHEMICAL OR CARBON. DIOXIDE. (WATER MAY BE INEFFECTIVE). ' . -Special Fire Fighting Proc: WEAR'NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP (FP N)• MOVECNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK. USE WATER TO KEEP FIRE-EXPOSED CNTNRS COOL. Unusual Fire And- Expl Hazrds: VAPS MAY FLOW ALONG SURFS TO DIST IGNIT SOURCES & FLASH BACK. CLSD CNTNRS EXPOSED, TO HEAT MAY EXPLODE. CONT W/ STRONG OXIDIZERS MAY CAUSE FIRE. TOX GASES(SUPDAT)- . - -
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J T BAKER - M-XYLENE, X523 Page 2 of 2
Reactivity Data
Stability: YES -Cond To Avoid (Stability): HEAT, FLAME, OTHER SOURCES OF IGNITION. Materials To Avoid: STRONG OXIDIZING AGENTS.
Health Hazard Data
Precautions for Safe Handling 'and Use
Control Measures
Transportation Data
Disposal Data-
Label- Data
Label Required:. YES Technical Review Date: 12JUL95 Label Status: G • • -, . Common Name: M-XYLENE, X52-3 Chronic Hazard:. YES • -Signal Word: DANGER!. Acute Health Hazard-Moderate: X Contact Hazard-Moderate: X " ' Fire Hazard-Severe: X Reactivity Hazard-None: X - . -Special Hazard Precautions: FLAMMABLE. ACUTE:INHALATION:HEADACHE, -NAUSEA, VOMITING, DIZZINESS, DROWSINESS, IRRITATION OF UPPER RESPIRATORY TRACT, NARCOSIS, UNCONSCIOUSNESS, AND MAY BE FATAL. SKIN/EYE:IRRITATION. INGESTION:HEADACHE, NAUSEA, VOMITING, DIZZINESS, GASTROINTESTINAL KIDNEY DAMAGE, LOW BLOOD•PRESSURE. Protect Eye: Y ' -Protect Skin: Y Protect Respiratory: Y Label Name: J T BAKER INC Label Street: 222 RED SCHOOL LANE • ' Label City: PHILLIPSBURG Label State: NJ ' ' ' Label Zip Code: 08865 Label Country: US - .: Label Emergency Number: 908-859-2151;800-424-9300(CHEMTREC)
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SPECTRUTvI CHEVnCAL MFG - P-XYLENE Page 1 of 2
SPECTRUM CHEMICAL MFG -- P-XYLENE , M;i.TERIAL SAFETY DATA SHEET
NSN: 685000F053489 Manufacturer's CAGE: 63415 Part No. Indicator: A " , -Part Number/Trade Name: P-XYLENE
General Information
Company's Name: SPECTRUM CHEMICAL MFG CORP - _ .. -Company's Street:- 14422 S SAN PEDRO STREET Company's City: GARDENA . Company's State: CA - - - •
. Company's Country: US ' Company's Zip Code: 90248-9985 Company's-Emerg Ph #: 310-516-8000 ' - . . . -
- Company's Info .Ph #': 310-516-8000-.Record No. For Safety Entry: 001 Tot Sa-fety Entries This Stk#: ,001
- Status: SE , Date MSDS Prepared.: 17DEC96 Safety Data Review Date: 18APR97
• Preparer's Company:' SPECTRUM CHEMICAL MFG CORP Preparer's St Or P. 0. Box: 14422 S SAN PEDRO STREET Preparer's City: GARDENA'_ Preparer's State: CA , -Preparer's Zip Code: 90248-9985 MSDS Serial Number: CDRNQ ' ' .' '
Ingredients/Identity Information
Proprieta-ry:. NO Ingredient: P-XYLENE Ingredient,Sequence Number: 01 -Percent: 100 ' . NIOSH (RTECS) Number: ZE2625000 ' . CAS Number: 106-42-3 - -ACGIH TLV: 100 PPM ^ - -
Physical/Chemical Characteristics r , .
Appearance And Odor: COLORLESS - Boiling Point: 280.4F Melting Point: 53.6F Vapor Pres^sure (MM Hg/70 F) : 9 Vapor Density (Air=l): 2.7 Specific Gravity:- 0.86 Solubility In Water: INSOLUBLE
Fire and Explosion Hazard Data
Flash Point: 77F - - ' . : Flash Point Method: CC .' " , Lower Explosi've Limit: 1.1 Upper Explosive Limit: '7 - -Extinguishing Media: SMALL: DRY CHEMICALS, 002, ALCOHOL FOAM/WATER SPRAY. LARGE: USE^WATER SPRAY/FOG. Special Fire Fighting Proc: USE. WATER SPRAY/FOG. COOL CONTAINING VESSELS W/WATER JET TO PREVENT PRESSURE BUILD-UP, AUTOIGNITION/EXPLOSION.
Reactivity Data -- - - -
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s t a b i l i t y : YES. Cond To Avoid (Stability): OPEN FLAMES, SPARKS, HEAT Materials- To Avoid: OXIDIZING AGENTS Hazardous Poly Occur: NO
Health Hazard Data ^
Route Of Entry - Inhalation: YES Route Of Entry - Skin: NO Route Of Entry - Ingestion: YES IRRITAN'T. INGESTION/INH/iJATION: SLIGHTLY DAJ>IGEROUS, CAN RESULT,IN DEATH. TOXIC TO BLOOD, KIDNEYS, THE NERVOUS SYSTEM, LIVER. Carcinogenicity'- NTP: NO Carcinogenicity - lARC: NO Carcinogenicity - OSHA: NO - ' - ' Explanation Carcinogenicity: NONE , ' ) . Signs/Symptoms Of .Overexp: IRRITATION, REDNESS, ITCHING, WATERING, INFLAMMATION, BLISTERING. Emergency/First Aid Proc: EYES: DON'T USE OINTMENT. SKIN: GENTLY S THOROUGHLY WASH W/RUNNING WATER & NON-ABRASIVE SOAP. COVER W/EMOLLIENT. WASH W/DISINFECTANT & COVER W/ANTI-BACTERIAL CREAM. INHALATION: REST IN A VENTIALTED'AREA. INGESTION: DON'T INDUCE- VOMITING. OBTAIN MEDICAL ATTENTION IN ALL CASES.
Precautions for Safe Handling and Use
Steps If Matl Released/Spill: SMALL: ABSORB W/AN INERT MATERIAL DISPOSE OF' APPROPRIATELY. LARGE: POISONOUS FLAMMABLE LIQUID. KEEP AWAY FROM HEAT & OTHER SOURCES OF IGNITION. STOP LEAK- W/O RISK. ABSORB W/DRY EARTH, SAND/ OTHER NON-COMBUSTIBLE MATERIAL. ' ' . " Waste Disposal Method: DISPOSE OF lAW/FEDERAL, STATE" S LOCAL REGULATIONS.
Control Measures
Respiratory Protection: APPROPRIATE IF VENTILATION IS INADEQUATE. Ventilation: EXHAUST VENTILATION/OTHER ENGINEERING CONTROLS TO KEEP AIRBORNE CONCENTRATIONS OF VAPOjlS BELOW "TLV. Protective Gloves: IMPERVIOUS . ' - •' Eye Protection: SPLASH GOGGLES .Other Protective Equipment: FULL .SUIT, B.OOTS & GLOVES. Work' Hygienic Practices: REMOVE/LAUNDER CONTAMIANTED CLOTHING BEFORE REUSE. '
Transportation Data
Disposal Data
Labe l Data
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POLYSCIENCE-r^IESITYLENE, 251C-8 Page 1 of 3
POLYSCIENCE — MESITYLENE, 251C-8 MATERIAL SAFETY DATA SHEET NSN: 681000N047372 Manufacturer's CAGE: 58378 - ' ' Part No. Indicator: A ''-'•' •Part Number/Trade Name: MESITYLENE, 251C-8
General Information
Company's Name: POLYSCIENCE Company's Street: 7800 MERRIMAC AVE , , . ' Company's City:.NILES Company's' State: IL Company's Country: US . . . ' , • Company's Zip Code: 60648 Company's Emerg Ph #: 312-965-0611 Company's Info Ph #: 312-956-0611 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ ' ' ' -Date MSDS . Prepared: '0'1AUG92 Safety Data Review Date: 13NOV95 MSDS Serial Number: -BTQWY Hazard Characteristic Code: F4 ~ .
Ingredients/Identity Information -. - -
. Proprietary: NO Ingredient: MESITYLENE - - ' Ingredient Sequence Number: 01 , -NIOSH (RTECS) Number: OX6825000 , CAS Number: 108-67-8 OSHA PEL: N/K ' (FP N) - ' - ' ' '
. ACGIH TLV: N/K (FP N)
: Physical/Chemical Characteristics
Appearance And Odor:'COLORLESS LIQUID. Boiling Point: 325F,163C Melting Point-: -49F,-45C ', Vapor Pressure (MM Hg/70 F): SUPDAT Vapor Density (Air=l): 4.1 Specific Gravity: 0.864
Fire and Explosion Hazard Data
Flash Point: 112F,44C Lower Explosive Limit: 0.8 8% Extinguishing Media: WATER SPRAY. CARBON DIOXIDE, DRY"CHEMICAL POWDER OR APPROPRIATE FOAM. Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). COMBUSTIBLE.
- Unusual Fire And Expl Hazrds: VAPOR MAY TRAVEL CONSIDERABLE DISTANCE TO SOURCE- OF IGNITION & FLASH BACK.'
Reactivity Data
Stability: YES Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER. -Materials To Avoid: STRONG OXIDIZING .AGENTS. - , Hazardous Decomp Products: TOXIC FUMES OF: CARBON MONOXIDE, CARBON ' ' " ' ' ' DIOXIDE.
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POLYSCIENCE - MESITYLENE, 25 lC-8 Page 2 of 3
Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVMIT
Health Haz-ard Data
LD50-LC50--Mixture: 'NONE SPECIFIED BY MANUFACTURER. Route Of Entry - Inhalation:' YES Route Of Entry - Skin: YES Route Of Entry - Ingestion: YES Health Haz. Acute And Chronic: ACUTE: MAY BE HARMFUL BY INHALATION, "INGESTION OR SKIN ABSORPTION. VAPOR OR MIST IS IRRITATING TO THE EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. TO THE BEST OF MANUFACTURER'S KNOWLEDGE,"THE CHEMICAL, PHYSICAL & TOXICOLOGICAL PROPERTIES HAVE NOT .BEEN'THOROUGHLY IN^VESTIGATED. Carcinogenicity - NTP: NO Carcinogenicity - lARC; NO ' . Carcinogenicity - OSHA: NO , • Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms Of Overexp: SEE HEAL.TH'HAZARDS . Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYES: IMMEDIATELY FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: IMMEDIATELY FLUSH WITH SOAP & COPIOUS AMOUNTS OF WATER/ INHAL: REMOVE TO FRESH .AIR.-IF NOT BREATHING GIVE WASH OUT MOUTH WITH WATER PROVIDED PERSON IS CONSCIOUS. CALL MD. WASH CONTAMINATED CLOTHING BEFORE REUSE.
Precautions for Safe Handling and' Use
Steps If Matl Released/Spill: EVACUATE AREA. WEAR NIOSH/MSHA APPROVED SCBA, RUBBER BOOTS S HEAVY RUBBER GLOVES. ABSORB-ON SAND OR VERMICULITE & PLACE IN CLOSED CONTAINERS FOR DISPOSAL. VENTILATE AREA & WASH SPILL SITE , AFTER MATERIAL PICKUP IS COMPLETE. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: THIS COMBUSTIBLE MATERIAL MAY BE'BURNED IN A CHEMICAL INCINERATOR EQUIPPED WITH AN AFTERBURNER & SCRUBBER. OBSERVE ALL •FEDERAL, STATE & LOCAL LAWS. Precautions-Handling/Storing: KEEP TIGHTLY CLOSED. KEEP"AWAY FROM HEAT & . OPEN FLAME. STORE IN COOL, DRY PLACE. KEEP AWAY FROM SOURCES OF IGNITION. NO SMOKING. Other Precautions:" HARMFUL LIQUID & FUMES. IRRITANT. HARMFUL BY INHALATION, IN CONTACT WITH SKIN S IF SWALLOWED. IRRITATING TO EYES, RESPIRATORY SYSTEM & SKIN. TAKE OFF IMMEDIATELY ALL CONTAMINATED CLOTHING.
Control Measures
Respiratory Protection': NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: MECHANICAL EXHAUST REQUIRED. Protective Gloves: RUBBER GLOVES. • -Eye Protection: ANSI APPRVD CHEM WORKER GOGGLES (FP N). Other Protective Equipment: WEAR SUITABLE PROTECTI'VE CLOTHING. ANSI APPRVD SAFETY SHOWER S EYE BATH. Work Hygienxc Practices: AVOID INHALATION. DO NOT GET IN EYES, ON SKIN, ON CLOTHING. WASH THOROUGHLY AFTER HANDLING. Suppl. Safety & Health Data: VP:2,.49 @ 250, 14 @ 550.'
Transportation Data
Disposal Data
Label Data
3 00572
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POLYSCIENCE-MESIT^XENE, 251C-8 Paae 3 of 3
Label Required: YES Technical Review Date: ll'JAN94 Label Date: 11JAN94 Label Status: G - ,, , -Common Name: MESITYLENE, 251C-8 , Chronic Hazard: NO Signal Word: WARNING! Acute Health Hazard-Slight: X Contact Hazard-Slight:' X'' Fire Hazard-Moderate: X • Reactivity Hazard-None: X 'Special Hazard Precautions: COMBUSTIBLE! KEEP AWAY FROM HEAT & OPEN FLAME. ACUTE: VAPOR OR-MIST IS IRRITATING TO THE, EYES, MUCOUS MEMBRANES & UPPER RESPIRATORY TRACT. CAUSES SKIN IRRITATION. CHRONIC: NONE LISTED BY" MANUFACTURER. Protect Eye: Y Protect Skin: Y Protect Respiratory: Y. Label Name: .POLYSCIENCE Label- Street: 7800 MERRIMAC AVE '- ' Label City: NILES , , , Label State: IL . . . Label Zip Code:'60648 Label Country: US Label Emergency Number: 312-965-0611
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POLYSCIENCE -ENDRIN, 510C-4 ' Page 1 of 3
POLYSCIENCE — ENDRIN, 510C-4 MATERIAL SAFETY DATA SHEET NSN: 681000N047396 Manufacturer's CAGE: 58378 Part No-. Indicator: A Part Number/Trade Name: ENDRIN, 510C-4 . . -1,
General Information
Company's Name: POLYSCIENCE Company's Street: 7800 MERRIMAC AVE Company's City: NILES Company's State: IL ' ' Company's Country: US' Company's Zip Code: 50648 Company's^Emerg Ph.#: 321-965-0611 Company's Info Ph -#: 321-965-0611 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ Date MSDS Prepared: 01MAR9'2 Safety Data Review Date: 14NOV95 MSDS Serial Number: BSTJG Hazard Characteristic Code: T2
Ingredients/Identity Information
Proprietary: NO Ingredient: 1,4:5,8-DIMETHANONAPHTHALENE, 1, 2 , 3, 4 , 10 , lO-HEXACHLORO-6, 7-EPOXY-1, 4,4A, 5,6,7,8,8A- OCTAHYDRO-, ENDO, ENDO-; (ING 2) ' • ' Ingredient Sequence Number: 01 NIOSH .(RTECS) Number: IO1575000 CAS Number: 72-20-8 OSHA PEL: N/K (FP N) ACGIH TLV: N/K (FP N)
Proprietary: NO ' Ingredient: ING 1: (ENDRIN) (MFR CAS # 105208-85-3) Ingredient .Se'quence Number: 02 NIOSH (RTECS) Number:" 9999999ZZ • OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Physical/Chemical Characteristics
Appearance And Odor: NONE SPECIFIED BY MANUFACTURER.
Fire and Explosion Hazard Data
Extinguishing Media: USE EXTINGUISHING MEDIA APPROPRIATE TO SURROUNDING
FIRE CONDITIONS. Special Fire Fighting Proc: WEAR NIOSH/MSHA APPROVED SCBA AND.FULL PROTECTIVE EQUIPMENT (FP N)'. . Unusual Fire And Expl Hazrds: EMITS TOXIC FUMES UNDER FIRE CONDITIONS.
Reactivity Data
Stability: YES " ' Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER. Materials To Avoid: STRONG OXIDIZING-AGENTS, ACIDS. Hazardous Decomp Products: TOXIC FUME OF: CARBON MONOXIDE, CARBON DIOXIDE. ----- - — • HYDROGEN CHLORIDE GAS.
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POLYSCIENCE - ENDRIN, 510C-4 Page 2 of 3
Hazardous Poly Occur: NO
Conditions To Avoid (Poly): NOT RELEVANT
Health Hazard Data -
LD50-LC50 Mixture: LD50:(ORAL,RAT)3 MG/KG ' ' Route Of Entry - Inhalation: YES , ' " . Route Of Entry - Skin: YES Route Of Entry - Ingestion: NO ' Health Haz Acute And Chronic: ACUTE:' MAY BE F.ATAL' IF INHALED, SWALLOWED/ WEAKNESS, NAUSEA, TWITCHING AND TINGLING OF LIMBS, DEAFNESS AND METAL , CONFUSION, CONVULSIONS, SOMETIMES ACCOMPA^IIED BY VIOLENT MUSCULAR CONTRACTIONS AND PERIODS OF UNCON MAY ALSO OCCUR.- (EFTS OF OVEREXP) Carcinogenicity - NTP: NO, • Carcinogenicity - lARC: NO , Carcinogenicity - OSHA: NO Explanation Carcinogenicity: NOT RELEVANT Signs/Symptoms • Of Overexp: HLTH HAZ: CHRONIC: CONTAINS A RADIOACTIVE NERVES, LIVER. ' " Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: SKI f: OBTAIN MED ATTN IMMED. INGEST: WASH OUT FLUSH WITH COPIOUS AMOUNTS OF WATER "FOR AT LEAST 15 MINUTES. ASSURE ADEQUATE FLUSHING BY SEPARATING EYELIDS W/FINGERS. CALL A- PHYSICIAN.
Precautions for Safe Handling and Use • •
Steps If Matl Released/Spill: EVAC AREA. WEAR NIOSH/MSHA APPRVD SCBA, RUBB BOOTS S HEAV/ RUBB GLOVES. COVER W/AN ACTIVATED CARBON ABSORB, TAKE UP & PLACE IN CLSD CONTRS. TRANSPORT OUTDOORS. VENT AREA S WASH SPILL SITE AFTER •MATL PICKUP IS COMPLETE. HNDLE AS A RADIOACTIVE SPILL. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSE OF SPILLED MATERIAL AS RADIOACTIVE WASTE. CONSULT LOCAL, STATE AND FEDERAL REGULATIONS ON DISPOSAL OF RADIOACTIVE WASTE. OBSERVE ALL FEDERAL, STATE, AND LOCAL LAWS. P-recautions-Handling/Storing: DO NOT BREATHE VAPOR. - RADOIACTIVE MATERIAL. CAN CAUSE DEPRESSION. _ ' ,' • Other Precautions:.'VERY TOXIC BY INHALATION, IN CONTACT" W/SKIN.AND IF SWALLOWED. IRRITATING TO EYES, RESP SYS AND SKIN. KEEP, AWAY FROM SOURCES OF IGNITION. NO SMOKING. " '
•' Control Measures
Respiratory Protection: NIOSH/MSHA APPROVED SCBA SHOULD BE WORN. Ventilation: USE ONLY IN A CHEMICAL FUME HOOD. Protective Gloves: HEAVY RUBBER,GLOVES. Eye Protection: ANSI APPRVD CHEM WORK .GOGGLES (SUPP) ' • Other Protective Equipment: NONE SPECIFIED BY MANUFACTURER. Work.Hygienic Practices: NONE SPECIFIED BY MANUFACTURER. Suppl. Safety S Health Data: EYE PROT: WITH FULL LENGTH FACESHIELD (FP N) .
Transportation Data '
Disposal Data
Label Data'
Label Required: YES Technical Review Date: 19JAN94 ' '- ' Label Date: 19JAN94 -Label Status: G-Common Name: ENDRIN, 510C-4 3 0 0 5 7 5
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POLYSCIENCE - ENDRIN, 510C-4 Page 3 of
Chronic Hazard: YES Signal Word: DANGER! Acute Health Hazard-Severe: X Contact Hazard-Severe: X - ' Fire Hazard-None: X Reactivity Hazard-None: X ' ' Special Hazard Precautions: RADIOACTIVE MATERIAL. KEEP FROM IGNITION SOURCES. ACUTE: MAY BE FATAL IF INHALED, -SWALLOWED OR ABSORBED THRU SKIN. EXPOSURE CAN CAUSE: WEAKNESS, NAUSE;^., TWITCHING AND TINGLING OF LIMBS, DEAFNESS AND MENTAL CONFUSION, CONVULSIONS, SOMETIMES ACCOMPANIED BY VIOLENT MUSCULAR CONTRACTIONS AND PERIODS "OF UNCONSCIOUSNESS MAY ALSO OCCUR. CHRONIC: CONTAINS A RADIOACTIVE ISOTOPE WHICH MAY PRODUCE CANCER AND GENETIC MUTATION. TARGET ORGANS: "NERVES,"LIVER. Protect Eye: Y • ~ Protect Skin:" Y Protect Respiratory: Y Label Name: POLYSCIENCE . Label Street: 7800 MERRIMAC AVE Label City: NILES Label State: IL • Label Zip Code: 60643 Label Country: US Label Emergency Number: 321-965-0611
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CHEM SERVICE - CHLORDANE, F91 Page 1 of 4
CHEM SERVICE -- CHLORDANE, F91 MATERIAL SAFETY DATA SHEET NSN: 581000N069932 Manufacturer's CAGE: 8Y898 Part No. Indicator: A Part Number/Trade Name: CHLORDANE, F91
' - - General Information
Company's Name: CHEM SERVICE Company's P. 0. Box: 3108 Company's City: WEST CHESTER Company's State: PA' Company's Country: US •Company's Zip Code: 19381 . ' Company's Emerg Ph #: 610-692-3026 Company's Info Ph #: 610-692-3026 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status:.SMJ
Date"MSDS Prepared: 07DEC92 Safety Data Review Date: 22APR96 MSDS Serial Number:'BZStG<'
: Ingredients/Identity Information
Proprietary: NO Ingredient: 4 , 7-METHAN0INDA>t, 1, 2 , 4, 5, 6, 7, 8 , 8-OCTACHLORO-3A, 4 , 7 , 7A-TETRAHYDRO-; (CHLORDANE) (SARA 302/313) (CERCLA) "Ingredient Sequence Number: 01 Percent:- 100 NIOSH (RTECS) Number: PB9800000 CAS Number: 57-74-9. OSHA PEL: 0.5 MG/M3, S . ACGIH TLV: 0.5 MG/M3, S
Proprietary: NO Ingredient: SUPDAT:EXHIBITING SIGNS OF SHOCK-KEEP WARM & QUIET. CONT POIS CTL CTR IMMED IF NEC. DO NOT ADMIN LIQS/INDUCE (ING 3) Ingredient Sequence- Number: 02 - -NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE -
Proprietary: NO Ingredient: ING 2:VOMIT TO UNCON/CONVULSING PERS. IF PATIENT IS VOMIT-WATCH CLOSELY TO MAKE SURE AIRWAY DOES NOT BECOME (ING 4) Ingredient Sequence Number: 03 NIOSH (RTECS) Number: 9999999ZZ OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
Proprietary: NO - ,, GASTRIC LAVAGE (E.G. 2-5% SODIUM BICARBONATE). NOTE:AN (ING 5) Ingredient Sequence Number: 04 -NIOSH (RTECS)" Number: 9999999ZZ' OSHA PEL: NOT APPLICABLE ACGIH TLV: NOT APPLICABLE
- Proprietary: NO Ingredient: ING- 4:ANTIDOTE IS A SUBSTANCE-INTENDED TO COUNTERACT EFT OF A ' " "' -POIS. IT SHOULD BE ADMINISTERED ONLY BY MD/TRAINED (ING 6)
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CHEM SERVICE-CHLORDANE, F91 Page 2 of 4
Ingredient Sequence Number: 05 NIOSH '(RTECS) Number: 9999999ZZ OSHA. PEL: NOT APPLICABLE ACGIH TLV: _ NOT APPLICABLE
Proprietary": NO , Ingredient: ING 5:EMERGENCY PERSONNEL. MEDICAL ADVICE CAN BE OBTAINED FROM A POISON .CONTROL CENTER." Ingredient Sequence Number: 06 -NIOSH (RTECS) Number: 9999999ZZ" OSHA PEL: NOT APPLICABLE „ -ACGIH TLV: NOT APPLICABLE
,Physical/Chemical Characteristics
Appearance And Odor: AMBER LIQUID; PUNGENT, ACRID ODOR-. ^ - " - -. Vapor Pressure (MM Hg/70 F): 1-5 @ 20 ' Vapor Density (Air=l): 7.63 Specific Gravity: 1:59-1, Solubility In Water: INSOL (IMMISCIBLE)
Fire and Explosion Hazard Data -
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL ROWDER OR SPRAY. Special Fire Fighting Proc: USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE EQUIPMENT ,(FP N) . • Unusual Fire And Expl Hazrds:. NO EXPLOSION LIMITS ARE AVAILABLE FOR THIS
• COMPOUND..
Reactivity -Data
Stability: YES-Cond To Avoid (Stability): COMBUSTIBLE. DECOMPOSES UNDER ALKALINE CONDITIONS. - " ^ - " Materials To Avoid: INCOMPATIBLE W/STRONG BASES, STRONG OXIDIZING AGENTS. Hazardous Decomp Products: EMITS TOXIC FUMES UNDER 'FIRE CONDITIONS. ^ . Hazardous Poly Occur: NO . Conditions To Avoid (Poly): NOT RELEVANT
Health Hazard Data.
LD50-LC50 Mixture: LD50:(ORAL,RAT) 367 MG/KG. Route Of Entry -. Inhalation: YES Route Of Entry - Skin: YES Route Of Entry"- Ingestion: YES
. Health Haz Acute .And Chronic: THIS CMPD IS CONSIDERED TO BE TOX. ALL CHEMS SHOULD BE CONSIDERED HAZ - AVOID DIRECT PHYSICAL CONT! SUSPECTED CARCIN-MAY PRDCE ,CANCER. CAN CAUSE DELAYED-LUNG INJURY, NERV- SYS INJURY. VAPS &/0R DIRECT EYE CONT CAN CAUSE SEV EYE BURNS- CAN CAUSE 'EYE IRRIT. INGEST -.MAY CAUSE DIARR. PRLNG EXPOS MAY CAUSE (EFTS OF OVEREXP) Carcinogenicity - NTP: NO , - " . . . - • " Carcinogenicity - lARC: YES Carcinogenicity - OSHA: NO , Explanation Carcinogenicity: CHLORDANE:lARC MONOGRAPHS ON EVAL OF CARCIN RISK OF CHEMS-TO MAN-, .VOL 53, PG 115, 1991: GROUP 2B. ANIMAL: LIVER. Signs/Symptoms Of Overexp: HLTH "HAZ:NAUS, HDCH, DIZZ -&/0R EYE DMG. MAY BE FATAL IF ABSORBED THRU SKIN, INHALED/SWALLOWED! EXPOS CAN CAUSE LIVER/ KIDNEY DMG. RPTD EXPOS TO VAPS &/0R DUST CAN CAUSE EYE INJURY. MAY BE RAPIDLY ABSORBED THRU SKIN W/POTNTL ADVERSE HLTH EFTS. CAN CAUSE GI" -DISTURBS, BLADDER INJURY, SKIN IRRIT. BASED ON TOX OF (SUPP DATA) Med Cond Aggravated By Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: EYES:FLUSH CONTINUOUSLY W/WATER FOR AT LST 15-20 - - -MINS. SKIN:FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAVE OCCURRED- USE
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CHEM SERVICE - CHLORDANE, F91 Page 3 of 4
SOAP-& WATER TO CLEANSE. REMOVE S WASH CONTAM CLTHG. INHAL:REMOVE PATIENT TO FRESH AIR. ADMIN-OXYG IF PATIENT IS H.AVING DFCLTY BRTHG. IF P.ATIENT H.AS, STOPPED BRTHG ADMIN ARTE RESP. IF PATIENT IS IN CARDIAC ARREST ADMIN CPR. CONTINUE LIFE SUPPORTING MEASURES UNTIL MED (SUPDAT)-
• Precautions for Safe Handling and Use
Steps If Matl Released/Spill: EVACUATE AREA. WEAR APPROPRIATE OSHA REGULATED EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE OR SIMILAR ' MATERI,AL. SWEEP UP & PLACE IN-APPROPRIATE CONTAINER. HOLD FOR DISPOSAL. WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Method: DISPOSAL MUST BE I/A/W FEDERAL, STATE'& LOCAL . • REGULATIONS (FP N). BURN IN A CHEMICALS INCINERATOR EQUIPPED W/AFTERBURNER S SCRUBBER. Precautions-Handling/Storing: AVOID CONT W/SKIN, EYES & CLTHG. DO NOT
• BREATHE VAPS. KEEP TIGHTLY CLSD. STORE IN COOL, DRY PLACE. STORE ONLY W/ COMPAT CHEMS. Other Precautions: PERSONS NOT SPECIFICALLY & PROPERLY TRAINED SHOULD NOT HANDLE THIS CHEM/ITS CNTNR. THIS PROD IS FURNISHED FOR LAB USE ONLY! PRODS
- MAY NOT BE USED AS DRUGS, COSMETICS, AGRICULTURAL/PESTICIDAL PRODS, FOOD ADDITIVES/AS HOUSEHOLD CHEMS.
K ^ Control Measures
Respiratory Protection: NIOSH/MSHA APPROVED RESPIRATOR. Ventilation: THIS CHEMICAL SHOULD BE HANDLED ONLY IN A HOOD. Protective Gloves :, IMPERVIOUS GLOVES (FP N), . Eye Protection: ANSI APPROVED CHEM WORKERS GOGGS (SUPDAT).. Other Protective Equipment: EYE WASH FOUNTAIN &. DELUGE SHOWER WHICH MEET ANSI DESIGN CRITERIA (FP N). USE APPROP NIOSH/MSHA APPRVD- SAFETY EQUIP. -Work Hygienic Practices: CONTACT LENSES SHOULD NOT BE WORN IN LABORATORY. Suppl. -Safety i Health Data: EFTS OF OVEREXP:CMPDS OF SIMILAR STRUCTURE THIS MATL IS PROBABLY HIGHLY HAZ. CAN CAUSE GEN FEELING OF DISORIENTATION & CONVLS. THIS CHEM IS CONSIDERED TO BE CARCIN- BY STATE OF CALIFORNIA. EYE
" PROT:& FULL LGTH FCSHLD (FP N). FIRST. AID PROC:ASSISTANCE HAS ARRIVED. '- -INGEST:DO NOT INDUCE VOMIT. IF PATIENT IS (ING 2)
Transportation Data
Disposal Data
Label Data
Label Required: YES " ,. Technical Review Date: 22APR96 Label Date: 14MAR96 Label Status: G . . ' • Common-Name: CHLORDANE, F91 Chronic Hazard: YES - , , Signal Word: DANGER! -Acute Health Hazard-Moderate: X . . Contact Hazard-Severe: X Fire Hazard-None: X -Reactivity Hazard-None: X -"" Special Hazard Precautions: THIS COMPOUND IS CONSIDERED TO BE TOXIC. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS - AVOID DIRECT PHYSICAL CONTACT! ACUTE:CAN CAUSE DELAYED LUNG INJURY, NERVOUS SYSTEM, INJURY. VAPORS AND/OR DIRECT EYE CONTACT CAN CAUSE SEVERE EYE BURNS. CAN CAUSE EYE IRRITATION. INGESTION MAY CAUSE DIARRHEA.. PROLONGED EXPOSURE MAY CAUSE NAUSEA, .'" ' HEADACHE, DIZZINESS AND/OR EYE DAMAGE. MAY BE FATAL IF ABSORBED THROUGH
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I CHEM SERVICE-CHLORDANE, F91 Page 4 of 4 o^
CANCER HA.ZARD. CHLORDANE IS LISTED AS AN ANIMAL LIVER CARCINOGEN (FP N) Protect Eye: Y " Protect Skin; Y Protect Respiratory: Y Label Name:, CHEM SERVICE Label P.O. Box: 3103 Label City: WEST CHESTER Label State: PA Label Zip Code: 19381, Label Country: US Label Emergency Number: 610-692-3026
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ULTRA SCIENTIFIC - CHLORDANE SOLUTION @ 100 UG-ML IN HEXANE, 94148 Page 1 of 3
ULTRA. SCIENTIFIC — CHLORDANE SOLUTION @ 100 UG-ML IN HEXANE, 94143' MATERIAJL SAFETY DATA SHEET NSN: 681000N050431 Manufacturer's CAGE: 0MU35 Part No. Indicator: A
Part Number/Trade Name: CHLO,RDANE "SOLUTION- (5 100 UG/ML IN HEXANE, , 94143
General Information
Company's Name: ULTRA SCIENTIFIC Company's Street: 250 SMITH STREET Company's City: NORTH KINGSTOWN Company's State: RI Company's Country: US -Company's Zip Code: 02852 Company's Emerg Ph #,: 4,01-294-9400 Company's Info Ph #: 401-294-9400 Record No. For Safety Entry: 001 Tot Safety Entries This Stk#: 001 Status: SMJ , " . Date MSDS Prepared: 06OCT93 " Safety Data Review Date: 13JUL94 MSDS Serial Number: BVDTC Hazard Characteristic Code: NK
Ingredients/Identity Information
Proprietary-: NO , .Ingredient: HEXANE; (N-HEXANE) Ingredient Sequence Number: 01 Percent: 99.98 NIOSH (RTECS) Number: MN9275000 CAS Number: 110-54-3 " . OSHA PEL : 500 .PPM ACGIH TLV: "50 PPM . •
Proprietary: NO , Ingredient: 4, 7-METHAI^roiNDAN, 1, 2', 4, 5, 6, 7, 8 , 8-OCTACHLORO- 3A,4,7,7A-TETRAHYDRO-; (CHLORDANE) (SARA III) LD50:(ORAL, RAT) 547 MG/KG Ingredient Sequence .Number: 02 Percent: 0.013 • - " ' NIOSH (RTECS) Number: PB9800000 CAS Number: 57-74-9 OSHA PEL: 0.5 MG/M3, S - , " . ACGIH TLV: 0.5 MG/M3, S '
Physical/Chemical Characteristics
Appearance And Odor': COLORLESS LIQUID. • . -
Fire and Explosion Hazard Data
Flash Point: N/A . ' ' •
Extinguishing Media: CARBON DIOXIDE, DRY CHEMICAL POWDER, OR WATER SPRAY. Special Fire Fighting Proc: USE NIOSH/MS'HA APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT (FP N). Unusual Fire And Expl Hazrds: NONE SPECIFIED BY MANUFACTURER.
Reactivity Data
Stability: YES Cond To Avoid (Stability): NONE SPECIFIED BY MANUFACTURER. '
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ULTRA SCIENTIFIC - CHLORDANE SOLUTION @ 100 UG-ML IN HEX.ANE, 94148 Page 2 of:
Materials To Avoid: NONE SPECIFIED BY MANUFACTURER. 'Hazardous Decomp Products: NONE SPECIFIED BY MANUFACTURER. Hazardous Poly Occur: NO Conditions To Avoid (Poly): NOT RELEVANT
Health Hazard Data
LD50-LC50 Mixture: SEE INGREDIENT 2 Route Of Entry - Inhalation: YES ' Route Of Entry - Skin: YES Route.Of Entry - Ingestion: YES Health Haz Acute And Chronic: TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE CONSIDERED HAZARDOUS. DIRECT PHYSICAL CONTACT SHOULD BE AVOIDED. Carcinogenicity -.NTP:- NO - ' Carcinogenicity - lARC: NO Carcinogenicity - OSHA: NO . . ' Explanation Carcinogenicity: NOT RELEVANT• Signs/Symptoms Of Overexp: SEE HEALTH HAZARDS. Med Cond Aggravated By' Exp: NONE SPECIFIED BY MANUFACTURER. Emergency/First Aid Proc: INGEST: CALL MD IMMEDIATELY (FP N) .. EYES: FLUSH WITH COPIOUS AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. SKIN: FLUSH WITH COPIOUS AMOUNTS OF WATER.-INHAL: REMOVE TO FRESH AIR. GIVE OXYGEN IF NECESSARY. CONTACT MD.
Precautions for Safe Handling and Use
Steps If Matl Released/Spill: DUE TO THE SMALL QUANTITY INVOLVED, SPILLS OR LEAKS SHOULD NOT POSE A SIGNIFICANT PROBLEM. A LEAKING BOTTLE MAY BE PLACED IN A PLASTIC- BAG & NORMAL DISPOSAL PROCEDURES FOLLOWED. LIQUID SAMPLES MAY BE ABSORBED ON VERMICULITE OR SAND. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal'Method: BURN IN A CHEMCIAL INCINERATOR EQUIPPED WITH AN AFTERBURNER AND SCRUBBER. OBSERVE ALL FEDERAL, STATE AND LOCAL LAWS CONCERNING DISPOSAL. " ' " PrecautionSTjHandling/Storing: KEEP TIGHTLY CLOSED AND STORE IN A COOL, DRY PLACE. Other Precautions: THIS MATERIAL SHOULD ONLY BE USED BY THOSE PERSONS TRAINED IN THE SAFE HANDLING OF HAZARDOUS CHEMICALS.
Control Measures
Respirato'ry Protection: USE NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR EXPOSURE OF CONCERN (FP N). • -Ventilation: NONE SPECIFIED BY MANUFACTURER. Protective Gloves: IMPERVIOUS. GLOVES (FP N)'. . Eye Protection: ANSI APPROVD CHEM WORKER GOGGLES (FP N) . Other Protective Equipment: USE APPROP NIOSH/MSHA APPRVD,SFTY EQUIP. WEAR CHEMICAL RESISTANT CLTHG SUCH AS LAB COAT &/0R RUBBER APRON TO (SUPDAT) Work Hy.gienic Practices:- NONE SPECIFIED BY MANUF.ACTURER. Suppl. Safety & Health Data: OTHER PROT EQUIP: PREVENT CONTACT" WITH EYES, SKIN S CLOTHING.
Transportation Data
Disposal Data
Label Data
Label Required: YES ,. , -- Technical-Review Date: 13JUL94 • Label Data: 19APR94
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ULTRA SCIENTIFIC - CHLORDANE SOLUTION (a), 100 UG-ML IN HEXANE, 94148
Label Status: G Common Name: CHLORDANE SOLUTION (§ 100 UG/ML IN HEXANE, 94143 Chronic Hazard: NO Signal Word: WARNING! Acute Health Hazard-Moderate: X , - . Contact Hazard-Slight: X Fire Hazard-None: X Reactivity Hazard-None: X Special Hazard Precautions: ACUTE: TOXIC; IRRITANT. ALL CHEMICALS SHOULD BE C0NSI"DERED HAZARDOUS. CHRONIC: NONE LISTED BY MANUFACTURER. Protect Eye:-. Y Protect Skin: Y -Protect Respiratory: Y -Label Name: ULTRA SCIENTIFIC Label" Street: 250 SMITH STREET Label City: NORTH KINGSTOWN Label State: RI - - " . . Label Zip Code: 02852 Label .Country: US Label Emergency Number: 401-294-9400
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CHEM SERVICE - F895 ALDRIN lOOUG-ML IN METHANOL Page 1 of 3
CHEM SERVICE -- F895 ALDRIN lOOUG-ML IN METHANOL MATERIAL SAFETY DATA SHEET NSN: 555000F038137 Manufacturer's CAGE: 8Y893 Part No. Indicator: A Part Number/Trade Name: F395 ALDRIN lOOUG/ML IN METHANOL
General Information
Company's Name: CHEM SERVICE INC Company's Street: 660 TOWER LN Company's P. O. Box: 3108 Company's City: WEST CHESTER Company's State: PA Company's Country:. US -Company's Zip Code:' 19381-3108 Company's Emerg Ph #: 215-38 6-2100/800-452-9994 Company's Info Ph #: 215-692-3026/800-452-9994 Record No..For Safety Entry: 001 Tot Safety Entries This Stk,#:' 001 .Status: SE Date MSDS Prepared: 07DEC92 Safety Data Review Date: 24JAN95 Preparer's Company:, ,CHEM SERVICE INC. Preparer's St Or P. 0'. Box: 660 TOWER LN Preparer's City: WEST CHESTER Preparer's State: PA Preparer's Zip Code: 19381-3108 MSDS- Serial Number: BWKRP '__'•-
Ingredients/Identity Information
Proprietary: NO Ingredient: ALDRIN Ingredient Sequence Number: 01'. NIOSH (RTECS) Number: IO2100000 CAS Number: 309-00-2 ' , OSHA PEL: 0.25 MG/CUM • , ACGIH TLV: 0.25 MG/CUM (SKIN)
Proprietary: NO ' -Ingredient: METHANOL (METHYL ALCOHOL), COLUMBIAN - SPIRITS *94-4* Ingredient Sequence Number: 02 , - < - - , NIOSH (RTECS) Number: PC1400000 CAS Number: 67-56-1 OSHA PEL: 260 MG/CUM ACGIH TLV: 262 MG/CUM (SKIN) Other Recommended Limit: 200 PPM"
Physical/Chemical Characteristics
Appearance And Odor:" COLORLESS LIQUID Boiling Point: 148.3F Melting Point,: -144. 4F Vapor Pressure (MM Hg/70 F): 97 Vapor Density (Air=l).: 1.11 . " - • Solubility In Water: MISCIBLE
Fire and Explosion Hazard Data
Flash Point: 51.8F Lower Explosive Limit: 6.7
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Upper Explosive Limit: 36 -Extinguishing Media: C02/DRY CHEMICAL POWDER. DON'T USE WATER. Unusual Fire And Expl Hazrds: FLAMMABLE CHEMICAL
Reactivity Data
Stability: YES CondTo Avoid (Stability): MOISTURE. Materials To Avoid: STRONG ACIDS,- ACID.HALIDES & ANHYDRIDES, STRONG . OXIDIZING AGENTS, STRONG REDUCING AGENTS, ACTIVE METALS Hazardous Decomp Products: TOXIC FUMES. Hazardous Poly Occur: NO - ."
Health Hazard Data
LD50-LC50 Mixture: ORAL LD50(.RAT): 5628 MG/KG Route Of Entry - Inhalation: YES Route Of Entry - Skin: YES - - -Route Of Entry - Ingestion: YES Health Haz Acute And Chronic: MAY BE FATAL IF ABSORBED THROUGH THE SKIN/ INHALED/SWALLOWED. MAY CAUSE BLINDNESS IF SWALLOWED/-EYE INJURY. EXPOSURE CAN CAUSE LIVER/KIDNEY DAMAGE & CARDIOVASCULAR SYSTEM INJURY. Carcinogenicity - NTP: NO, Carcinogenicity - lARC: NO ' ' ' Carcinogenicity - OSHA: NO•. ' -Explanation Carcinogenicity: NONE Signs/Symptoms Of Overexp: GASTROINTESTINAL DISTURBANCES, CONVULSIONS.' Emergency/First Aid Proc: EYES: FLUSH W/WATER FOR 15-20 MINS. SKIN: FLUSH W/WATER FOR 15-20 MINS. IF NO BURNS HAV.E OCCURED, USE w/sOAP & WATER. INHALATION: REMOVE TO FRESH AIR. GIVE OXYGEN/CPR IF NECESSARY. OBTAIN MEDICAL ATTENTION IN ALL CASES. .
Precautions for Safe Handling and Use
Steps If -Matl Released/Spill: EVACUATE AREA. WEAR APPROPRIATE OSHA REGULATED EQUIPMENT. VENTILATE AREA. ABSORB ON VERMICULITE/SIMILAR MATERIAL. SWEEP UP S PLACE IN AN APPROPRIATE CONTAINER. HOLD FOR DISPOSAL.'
' .WASH CONTAMINATED SURFACES TO REMOVE ANY RESIDUES. ' - . Waste Disposal Method: BURN IN A CHEMICALS.INCINERATOR EQUIPPED W/AN AFTERBURNER & SCRUBBER IN ACCORDANCE W/LOCAL, STATE -& FEDERAL REGULATIONS. Precautions-Handling/Storing:' KEEP TIGHTLY CLOSED. STORE IN A COOL, DRY PLACE. STORE ONLY W/COMPATIBLE MATERIALS! Other Precautions: AVOID CONTACT W/SKIN/EYES/CLOTHING. DON'T BREATHE
. VAPORS. PRODUCT IS FOR LABORATORY USE ONLY.. MAY NOT BE USED AS DRUGS/ COSMETICS/AGRICULTURAL/PESTICIDAL PRODUCTS/HOUSEHOLD. DON'T W EAR CONTACT LENSES IN THE LAB. PRODUCT-FLAMMABLE/HYGROSCOPIC '
Control Measures
Respiratory Protection: USE APPROPRIATE OSHA/MSHA APPROVED SAFETY EQUIPMENT. Ventilation: HANDLE ONLY IN A HOOD. Protective Gloves: REQUIRED. Eye'Protection: EYE SHIELDS. Work Hygienic Practices: REMOVE/LAUNDER CONTAMINATED CLOTHING & SHOES BEFORE REUSE. - ' Suppl. Safety & Health Data: THE DATA FOR THIS MSDS IS FOR METHYL ALCOHOL.
Transportation Data
Disposal Data ' ' " '
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I CHEM SERVICE - F895 ALDRIN 1OOUG-ML IN METHANOL Page 3 of 3
Label Data
Label Required: YES Label' Status :- G Common Name: F895 ALDRIN lOOUG/ML .IN .METHANOL Special Hazard Precautions: MAY BE-FATAL 'iF ABSORBED THROUGH THE SKIN/ INHALED/SWALLOWED. MAY CAUSE BLINDNESS IF SWALLOWED/EYE INJURY. EXPOS.URE CAN CAUSE LIVER/KIDNEY DAMAGE & CARDIOVASCULAR SYSTEM INJURY. -GASTROINTESTINAL DISTURBANCES, CONVULSIONS. Label Name: CHEM SERVICE INC Label Street: 660 TOWER LN -Label P.O.. Box: 3108 Label City: WEST CHESTER Label State: PA •Label Zip Code: 19381-3108 . . . Label Country: US . ' . - . . -Label Emergency Number: 215-336-2100/800-452-9994
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C D M Federal Programs Gorporatipri ".- ; •• */4 Subsidiary of Carrip Dresser &.McKee Inc., -,, '" .
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