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Secondary Treatment (Biological)

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    Seminar on Activated Sludge Pro

    Submitted to:

    Dr. V.K.Rattan

    Dr. SSB UICET Panjab University

    Submitted by:

    Girish Gupta

    ME Chemical 2ndyear

    Roll No. 1202

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    Index

    Introduction

    Types of biological treatment plant

    Activated Sludge Process

    Principle of activated sludge process

    Activated sludge Process Design equation

    Reference

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    Secondary Treatment (Biologica

    Removal of remaining dissolved or colloidal organic matter

    Biodegradation of pollutants is allowed to take place in loca

    To promote formation of less offensive oxidized product

    What engineers do in water treatment plants?

    Ans.

    To design capacity of treatment units

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    Types of Biological Treatments P

    1. Attached Growth Process

    2. Suspend Growth Process

    1. Attached growth process : microorganisms grow on the surfarock or plastics

    Example : Open Trickling Filters

    Where water is distributed over rocks and trickles down to drain wthrough vent pipes enclosed bio towers which similar but shapedmedia instead of rocks called R.B.C

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    R.B.C

    R.B.C. is Rotating Biological Contactors

    Consists of Large Submerged Disc

    Rotate continuously to provide microorganisms grows on the

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    Suspended Growth Process

    Biological Treatment Process based on the growth and retensuspension of microorganisms

    These microorganisms convert biodegradable, organic wasteconstituents and certain inorganic fractions into new cell mabyproducts, both of which then can be removed by settling, stripping, and other physical means.

    Example Activated Sludge Process

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    Activated Sludge Process

    Activated sludge is a process for treating sewage and industrialwastewaters using air and a biological floc composed of bacterprotozoa

    Purposes

    1. oxidizing carbonaceous biological matter.

    2. oxidizing nitrogeneous matter: mainly ammonium and nitrogenmatter.

    3. removing phosphates.

    4. driving off entrained gases such as carbon dioxide, ammonia,

    5. generating a biological floc that is easy to settle.

    6. generating a liquor that is low in dissolved or suspended mater

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    Activated sludge process

    Activated sludge process is consists of

    1. Aeration Tank

    2. Settling Tank or Clarifiers

    Aeration tank contain sludge which can be described as microcontain

    Mostly bacteria , Protozoa , Fungi, Algae etc.

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    Oxygen Supply

    Diffused compressed air

    Mechanical surface aeration

    Pure oxygen

    Purpose of aeration

    1. Provides oxygen required for aerobic bio-oxidation

    2. Provides sufficient mixing for adequate contact between actand organic substances

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    Submersible Aerator/Mixer

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    Sludge is continuously mixed and aerated by

    1. Compressed Air Bubblers along bottom

    2. Mechanical Aerators on surface

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    Process

    1. Waste water to be treated enters tanks and mixed with cultorganic compound for growth producing over microorganirespirators which mostly in formation of CO2 and water

    2. To provide biological removal of nutrients like nitrogen and

    3. After sufficient aeration time to reach the required level of tsludge is carried by the flow into the settling tank, or clarifie

    often of the circular design.

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    Note:

    1. the success of this process is the formation of a type of culturflocculate naturally, producing a settling sludge and a reasoupper, or supernatant layer.

    2. If the sludge does not behave this way, a lot of solids will be water leaving the clarifier, and the quality of the effluent waspoor.

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    The type of activated sludge system that has just been descrcontinuous flow process.

    There is a variation in which the entire activated sludge procein a single tank, but at different times.

    Steps include filling, aerating, settling, drawing off supernatan

    A system like this, called a sequencing batch reactor, can provi

    flexibility and control over the treatment, including nutrient remoamenable to computer control.)

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    To design of AS, the following must bdetermined:

    Volume of reactor1. Number of basins

    2. Dimensions of each basin

    Volume of reactor is determined from:

    1. Kinetic relationships

    2. Space loading relationships

    3. Empirical relationships Sludge production per day (Xw), kg/day

    Oxygen required per day (Or), kg/day

    Final clarifier

    o Number of basins

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    Schematic of activated sludge

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    Calculate (R / Q) Ratio

    In order to maintain the desired MLSS(Mixed liquid solids) in the aeration tank, R/Q ratio must be calcula

    Calculate the Sludge Density Index (SDI)1. Sample MLSS from downstream of aeration tank

    2. Determine SS in MLSS

    3. Place 1 liter of the MLSS in 1-liter graduate cylinder

    4. Settle the sludge for 30 minutes

    5. Measure volume occupied by settled sludge

    6. Compute SS in settled sludge in mg/l

    7. SS represents SDI

    8. The test approximates the settling that occurs in final clarifier

    If SDI = 10,000 mg/l and MLSS must be 2,500 mg/l

    Then, Q(0) + R(10,000) = (Q+R)(2500)

    R/Q = (2500)/(7500) = (1/3) = 33.3 %

    So, R is 33.3% of feed wastewater (Q)

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    Sludge Volume Index (SVI) = 1/ SDI

    Is the volume in ml occupied by 1 gram of settled activated sludg

    It is a measure of settling characteristics of sludge

    Is between 50 and 150 ml/gm, if process is operated properly

    Why Qw?Microbes utilize organic substances for respiration and synthesis

    The net cell production (Qw) must be removed from the system t

    constant MLSS

    Qw is usually 1 to 6 % of feed wastewater flowrate (Q)

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    Kinetics of Microbial Growth

    Biochemical reaction

    Biomass concentration.

    The concentration of biomass, X (mg/L),increases as a function of time due toconversion of food to biomass:

    Where m is the specific growth rate constant

    (d-1). This represents the mass of cellsproduced/mass of cells per unit of time.

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    Monod Kinetics

    oGrowth rate

    Growth rate constant, , is a function of the substrate concentr

    o Two constants are used to describe the growth rate

    m(mg/L) is the maximum growth rate constant (the which the susbtrate concentration is not limiting)

    Ksis the half-saturation constant (mg/L) (i.e., concent

    S when = m/2

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    Substrate utilization

    Where Y is the yield factor (mg of biomass produced/mg of foodconsumed)

    Y range:

    Aerobic: 0.4 - 0.8 mg/mg

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    Since the hydraulic retention time, q= V/Qo, then

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    Typical range of F/M ratio in activated sludge units

    Treatment Proc ess F/MKg BOD

    5/Kg MLSS/day

    Extended aerat ion 0.03 - 0.8

    Convent ional 0.8 - 2.0

    High rate > 2.0

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    Mean Cell Residence Time (qc)

    It is defined as:

    X = active biological solids in the reactor

    X = active biological solids in the waste activated sludge flow

    Units of qcis daysMean cell residence time is sometimes referred to as slu

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    F/M Ratio and qc

    Both parameters are used characterize the performance of the activprocess

    A high F/M ratio and a low qcproduce filamentous growth that have poocharacteristics

    A low F/M ratio and a high qccan cause the biological solids to undergoendogenous degradation and cell dispersion

    For municipal wastewater

    qcshould be at least 3 to 4 days

    If nitrification is required, qcshould be at least 10 days

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    Divide by X

    qc is the average time a cell remains in the system, thus

    ekX

    tSY

    X

    tX

    //

    tX

    Xc

    /q

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    The F/M ratio is the rate of substrate removal per unit weight of the cells,

    Thus

    X

    tS

    M

    F

    /

    e

    c

    kM

    FY

    q

    1

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    Since F/M was also expressed as:

    Then,

    tX

    S

    M

    F

    e

    c

    ktX

    SY

    q

    1

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    Types of Reactors

    Plug-flow reactors

    Dispersed plug-flow reactors

    Completely-mixed reactors

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    Plug-flow and Dispersed-flow Reactor

    In plug-flow reactors, there is negligible diffusion apath through the reactor

    In dispersed-flow reactors, there is significant diffus

    flow path through the reactor

    Both types of reactors are used in conventional and tap

    activated sludge

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    Conventional Activated Sludge

    Rectangular aeration tank

    F/M = 0.2 to 0.4 (kg BOD5/kg MLSS-day)

    Space loading = 0.3 to 0.6 (kg BOD5/day-m3)

    qc= 5 to 15 (days)

    Retention time (aeration tank) = 4 to 8 (hours)

    MLSS = 1500 to 3000 (mg/l)

    Recycle ratio (R/Q) = 0.25 to 1.0

    Plug-flow and Dispersed-flow

    BOD removal = 85 to 95 (%)

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    Tapered Aeration

    It is a modification of the conventional process

    F/M = 0.2 to 0.4 (kg BOD5/kg MLSS-day)

    Space loading = 0.3 to 0.6 (kg BOD5/day-m3)

    qc= 5 to 15 (days)

    Retention time (aeration tank) = 4 to 8 (hours)

    MLSS = 1500 to 3000 (mg/l)

    Recycle ratio (R/Q) = 0.25 to 1.0

    Plug-flow and Dispersed-flow

    BOD removal = 85 to 95 (%)

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    Performance

    qis the detention time for the plug-flow reactor

    The volume of the plug-flow or dispersed-flow

    given by:

    qXKt

    eS

    S

    0

    q )( RQV

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    Design parameters for activated sludge proces

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    Process q c d) q h) F/M Qr/Q X (mConventional 5-15 4-8 0.2-0.4 0.25-5 1,500-

    Complete-mix 5-15 3-5 0.2-0.6 0.25-1 3,000-

    Step-aeration 5-15 3-5 0.2-0.4 0.25-0.75 2,000-

    Modif ied-

    aeration

    0.2-0.5 1.5-3 1.5-5.0 0.05-0.15 200

    Contact-

    stabi l ization

    5-15 0.5-1

    3-6

    0.2-0.6 0.25-1 1,000-

    4,00

    10,0Extended-

    aeration

    20-30 18-36 0.05-0.15 0.75-1.5 3,000-

    High-rate

    aeration

    5-10 0.5-2 0.4-1.5 1-5 4,00

    10,0

    Pure-oxygen 8-20 1-3 0.25-1.0 0.25-0.5 6,000-

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    Design Parameters

    The retention time and reactor volume for completely mreactors can be determined by:

    q

    q

    QV

    SXK

    SS

    t

    ti

    Activated Sludge Design Equat

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    Activated Sludge Design Equat

    Influent biomass + biomass production = effluent

    biomass + sludge wasted

    Substitute biomass production equation

    Assume that influent and effluent biomassconcentrations are negligible and solve

    Mass balance of biomass production

    Mass balance of food substrate

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    Influent substrate + substrate consumed = effluentsusbtrate + sludge wasted substrate

    Substitute substrate removal equation

    Assume that no biochemical action takes place in

    clarifier. Therefore the substrate concentration in thaeration basin is equal to the substrateconcentrations in the effluent and the wasteactivated sludge. Solve:

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    Thank Yo


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