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NBS TECHNICAL NOTE 270-7
REFERENCE
Selected Values of
Chemical Thermodynamic
Properties
U.S.
DEPARTMENTOF
COMMERCENational
|— QC— of
100 is
ho.Z70-7
Tables for the Lanthanide
(Rare Earth) Elements
(Elements 62 through 76 in the
Standard Order of Arrangement)
NATIONAL BUREAU OF STANDARDS
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iATIOHAL B'JF.E?.0 CF STU^IBAHIIS
^'^^ Selected Values of Chemical Thermodynamic
p7JoProperties
Q^ , Tables for the Lanthanide (Rare Earth) Elements
(Elements 62 through 76 in the Standard Order
of Arrangement)
R. H. Schumm, D. D. Wagman, S. Bailey,
W. H. Evans, and V. B. Parker
Physical Chemistry Division
Institute for Materials Research
•^^. National Bureau of Standards"" Washington, D.C. 20234
NBS Technical Notes are designed to supplement the
Bureau's regular publications program. They provide a
means for making available scientific data that are of
transient or limited interest. Technical Notes may be
listed or referred to in the open literature.
\ /
U.S. DEPARTMENT OF COMMERCE, Frederick B. Dent, SecreioTy
NATIONAL BUREAU OF STANDARDS, Richard W. Roberts, D/recfor
Issued April 1973
National Bureau of Standards Technical Note 270-7
Nat. Bur. Stand. (U.S.), Tech. Note 270-7, 93 pages (April 1973)
CODEN: NBTNAE
For sale by the Superintendent of Documents, U.S. Government Printing Oflfice, Washington, D.C. 20402
(Order by SD Catalog No. C13.46:270-7).
Price $1.25 domestic postpaid or $1.00 G.P.O. Bookstore
Abstract
Contains tables of values for the standard heats and Gibbs (free)
energies of formation, entropies and enthalpies at 298.15 K and
heats of formation at K for compounds of the rare- earth elements
(the lanthanides; lutetium through lanthanum; elements 62 through
76 in the Standard Order of Arrangement). These tables are a
continuation of the comprehensive revision of NBS Circular 5 00.
Key words: Cerium compounds; dysprosium compounds; enthalpy;
entropy; erbium compounds; europium compounds; gadolinium
compounds ; Gibbs energy of formation; holium compounds; lanthanides;
lanthanum compounds; lutetium compounds; neodymium compounds;
praseodymium compounds; promethium; rare- earth elememts;
samarium compounds; terbium coinpounds; thulium compounds;
ytterbium compounds.
Ill
PREFACE
Technical Note ZlO-7 is the seventh part of a series of Notes
containing the tables of numerical material prepared as a revision of
Series I of National Bureau of Standards Circular 500, Selected
Values of Chemical Thermodynamic Properties, by F. D. Rossini,
D. D. Wagman, W. H. Evans, S. Levine, and I. Jaffe. This Note
contains data for the compounds of 15 elements, numbered 62 through
76 in the Standard Order of Arrangement. In addition there is an
Appendix which contains a list of all the corrections and misprints
which have been detected in the previous Notes of this Series.
The continued encouragement and support of the Office of
Standard Reference Data of the National Bureau of Standards is
gratefully acknowledged.
IV
Contents
Preface iv
Introduction vii
Standard Order of Arrangements of the Elements^ Figure 1 . . xi
Table A. Conversion Factors for Units of Molecular Energy . xii
Table 62 Lutetium 1
Table 63 Ytterbium 4
Table 64 Thulium 9
Table 65 Erbium 13
Table 66 Holmium 16
Table 67 Dysprosium 21
Table 68 Terbium 25
Table 69 Gadolinium 29
Table 70 Europium ...» 33
Table 71 Samarium 37
Table 72 Promethium 42
Table 73 Neodymium 43
Table 74 Praseodymium 48
Table 75 Cerium 53
Table 76 Lanthanum 60
Appendix 69
Index of Contents c 73
SELECTED VALUES OF CHEMICAL THERMODYNAMIC PROPERTIES
INTRODUCTION
Substances and Properties Included in the Tables
The tables contain values where known of the enthalpy and Gibbs
energy of formation, enthalpy, entropy and heat capacity at 298.15 K(ZS^C), and the enthalpy of formation at K, for all inorganic substances
and organic molecules containing not more than two carbon atoms. In
some instances such as metal-organic compounds, data are given for
substances in which each organic radical contains one or two carbon
atoms
.
No values are given in these tables for metal alloys or other
solid solutions, fused salts, or for substances of undefined chemical
composition.
Physical States
The physical state of each substance is indicated in the column
headed "State" as crystalline solid (c), liquid (liq), glassy or amorphous
(amorp), or gaseous (g). Solutions in water are listed as aqueous (aq).
For non-aqueous systems the physical state is that normal for the
indicated solvent at 298.15 K.
Definition of Symbols
The symbols used in these tables are defined as follows: P =
pressure; V = volumie; T = absolute temperature; E = intrinsic or
internal energy; S = entropy; H = E + PV = enthalpy (heat content);
G = H - TS = Gibbs energy (formierly the ^ree energy); C = (dH/dT)-., =
heat capacity at constant pressure.
VI
Conventions Regarding Pure Substances
The values of the thermodynamic properties of the pure substances
given in these tables are for the substances in their standard states
(indicated by the superscript " on the thermodynamic symbol). Thesestandard states are defined as follows:
For a pure solid or liquid, the standard state is the substance
in the condensed phase under a pressure of one atmosphere.For a gas the standard state is the hypothetical ideal gas at unit
fugacity, in which state the enthalpy is that of the real gas at the sametemperature and at zero pressure.
The values of A Hf " and AGf" given in the tables represent the changein the appropriate thermodynamic quantity when one gram -formulaweight of the substance in its standard state is formed, isothermally at
the indicated temperature, from the elements, each in its appropriatestandard reference state. The standard reference state at 25 "C for
each element except' phosphorus has been chosen to be the standardstate that is thermodynamically stable at 25 "C and at one atmospherepressure. For phosphorus the standard reference state is the crystalline
white form; the more stable forms have not been well characterizedthermochemically. The same reference states have been maintained for
the elements at K except for the liqmd elements bromine and mercury,for which the reference states have been chosen as the stable crystalline
forms. The standard reference states are indicated in the tables by the
fact that the values of A Hi" and A Gf ° are exactly zero.
The values of H^q^ -Hq represent the enthalpy difference for the
given substance between 298.15 K and K. If the indicated standardstate at 25 °C is the gas, the corresponding state at K is the hypo-thetical ideal gas; if the state at 25 "C is solid or liqiiid, the corres-ponding state at K is the thermodynamically 'stable crystalline
solid, \anless otherwise specifically indicated.
The values of S° represent the virtual or "thermal" entropy of the
substance in the standard state at 298.15 K, omitting contributions fromnuclear spins. Isotope mixing effects, etc. , are also excluded exceptin the case of the hydrogen-deuterium ( H- H) system. Where data havebeen available only for a particular isotope, they have been correctedwhen possible to the normal isotopic composition.
The values of the enthalpies of formation of gaseous ionic speciesare computed on the convention that the value of AHf ° for the electronis zero. Conversions between and 298.15 K are calculated usingthe value of H2Q8-Hq = 1. 481 kcal per mole of electrons, and assumingthat the values of H2Q0-H0 for the ionized and vui-ionized molecules are
the same.
VII
Conventions Regarding Solutions
Solutions in water are designated as aqueous (aq); other solventsare designated by name or chemical formula. The concentration of the
solution is expressed in terms of the number of moles of solvent asso-ciated with one mole of the solute. If no concentration is indicated, the
solution is assumed to be "dilute".
The standard state for a non-dissociated solute in aqueous solution
is taken as the hypothetical ideal solution of unit molality, which has beendesignated as "std. state, m = 1". For strong electrolytes in aqueoussolution the conventional standard state is the ideal solution of unit
activity (unit mean molality). For nonaqueous solutions the standardstate of the solute is the hypothetical ideal solution of unit molefraction of solute (std. state, X2 = 1).
The value of IHl" given the tables for a solute in its standardstate is the apparent molal enthalpy of formation of the substance in
the infinitely dilute real solution. At this dilution the partial molalenthalpy is equal to the apparent molal quantity. At concentrations
other than the standard state, the value of A Hf° represents the apparententhalpy of the reaction of formation of the solution from the elennents
comprising the solute, each in its standard reference state, and the
appropriate total number of moles of solvent. In this representation
the value of AHf° for the solvent is not required. The experimental value
for a heat of dilution is obtained directly as the difference between the
two values of A Hf° at the corresponding concentrations.
The values of the thermodynainic properties tabulated for the
individual ions in aqueous solution are based on the usual conventionthat the values of AHf°, AGf°, S° and Cp° for H+ (aq, std. state, m = 1)
are zero. The properties of a neutral electrolyte in aqueous solution
in the standard state are equal to the algebraic sum of these values for
the appropriate kinds and number of individual ions assumed to constitute
the molecule of the given electrolyte. When the undissociated species,
rather than the s\im of the ions, is meant, the notation "undissociated"
or "\in-ionized" is used. For an ionic species the properties tabulated
refer to that undissociated ion. By adopting the above convention with
respect to aqueous H , it follows that the thermodynamic relation A Gf°
= A Hf° - T ASf° will not hold for an individual ionic species. Howeverno problem arises when neutral chemical systems are considered.
Vlll
Unit of Energy and Fundamental Constants
All of the energy values given in these tables are expressed in termsof the thermochemical calorie. This unit, defined as equal to 4.1840
joules, is generally accepted for the presentation of chemical thermo-dynamic data. Values reported in other units have been converted to
calories by means of the conversion factors for molecular energy given
in Table A.The following values of the fundamental physical constants have
been used in these calculations:
R = gas constant = 8. 3143 + 0. 0012 J/deg mol = 1.98717 + 0. 00029
cal/deg molF = Faraday constant = 96487. + 1. 6 coulombs /mol
= 23060,9 ±0.4 cal/volt equivalent
Z = Nhc = 11.96258 + 0.00107 J/cm"^ mol = 2.85912 -k 0.00026 cal/cm"^ molC2 = second radiation constant = hc/k = 1.43879 ± 0.00015 cm degO'C = 273.15 K
These constants are consistent with those given in the Table of GeneralPhysical Constants, recommended by the National Academy of Sciences -
National Research Council . The formula weights in the tables havebeen calculated for the molecular formula given in the Formula andDescription column using the 1961 Table of Relative Atomic Weights basedon the atomic mass of ^ C = 12 exactly .
Internal Consistency of the Tables
All of the values given in these tables have been calculated fromthe original articles, using consistent values for all subsidiary anda\ixiliary quantities. The original data were corrected where possible
for differences in energy units, molecular weights, temperature scales,
etc. Thus we have sought to maintain a vmiform scale of energies for
all the substances in the tables. In addition the tabulated values of the
properties of a substance satisfy all the known physical and thermodynamicrelationships among these properties. The quantities A Hf ", A Gf °, andS" at 298.15 K satisfy the relation:
A Gf = A Hf° - T ASf".
NBS Technical News Bulletin, October 1963.
2A. E. Cameron and E. Wichers, J. Am. Chem, Soc. 84, 4192 (1962).
IX
Furthermore the calculated value of any thermodynamic quantity for a
reaction is independent of the path chosen for the evaluation.
In Sonne cases new^er data may have become available on certain
substances after the values were selected for these tables. Becauseof the need to maintain the internal consistency of the tables, it is not
always possible to incorporate these newer data into the tables without
a detailed analysis of the effect of such a change. Unless great care is
used, relatively significant errors in calculated values of A H° or A G"for specific reactions may result from the introduction of such data.
Uncertainties
The uncertainty in any value in the tables depends on the uncertain-
ties of all the determinations in the total chain of reactions used to
establish the value.
A discussion of the uncertainties will be included in the final
publication of these tables in the National Standard Reference DataSystem. However we have followed certain rules with respect to
significant figures to indicate these ixncertainties. Values are tabulated
in general such that the overall uncertainty lies between 2 and 20 units
of the last figure. On the other hand, values are given so that the
experimental data from which they are derived may be recovered with
an accuracy equal to that of the original quantities. Thus the numberof significant figures for any one value in the tables need not representthe absolute accuracy of that value. For solutions of varying connposition
values are frequently tabulated to more figures to make possible the
recovery of enthalpies of solution and dilution. Similarly values of
A Hfrt and AHflqo ic may be given to different numbers of significant
figures. In this instance the quantity with the lesser number of figures
is used to represent the uncertainty estimate. The larger number of
figures is used for the other quantity to retain the significance of the
temperature correction term.
Arrangement of the Tables
The compounds in the tables are entered according to the StandardOrder of Arrangement, (see Figure 1), by the principle of latest position.
In this scheme, a compound is listed \ander the element occurring latest
in the list; water of hydration is neglected. Within a given element-table will be found all of the compoonds of that element with elementsoccurring earlier in the order; the arrangement within a table follows
the same ordering. An exception occurs in the carbon tables (Table 23),
which is divided into subgroups consisting of all compounds with onecarbon atom, then all with two carbon atoms, etc.
X
STANDARD ORDER OF ARRANGEMENT
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TABLES OF SELECTED VALUES OF PROPERTIES
SERIES I
Enthalpy of Formation at K
Enthalpy of Formation at 298. 15 K
Gibbs Energy of Formation at 298. 15 K
Enthalpy at 298. 15 K
Entropy at 298. 15 K
Heat Capacity at 298. 15 K
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CO•H«
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fl) 2 .3 5^ ^ .3 5 ^ ^ 3 2
66
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ti ^ CO <J- m ^D r^ 1-1 1 t-t t-l .-1
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67
APPENDIX
Errata for Technical Notes 270-3, llQ-k, 270-5, and 270-6
TN Page
3 22 HFCliq) ^Hf°gg = -71.65 kcal/mol
X denotes undetermined residualentropy
3 26 HCl in 150H2O(aq) ^298 = -39.710 kcal/mol
3 32 HBr(g) AHfJ = -6.826 kcal/mol
3 41 I Cl', std. state. ^298 = -32.9 kcal/mol
m=l(aq) Z^f = -27.8 kcal/mol
S" = 52.9 cal/deg mol
3 43 S(g) mf° = 56.951 kcal/mol
s" = 40.084 cal/deg mol
3 48 H2S"^(g) ^5 = 237.0 kcal/mol
H2S2(liq) ^298 = -4.33 kcal/mol
H2S2(g) = 3.71 kcal/mol
H^S^Cliq) = -3.57 kcal/mol
H2-S3(g) = 7.29 kcal/mol
H2S^(liq) = -2.99 kcal/mol
^284(8) = 10.57 kcal/mol
H2S3(liq) = -2.49 kcal/mol
H2S3(g) = 13.84 kcal/mol
H2Sg(liq) = -1.99 kcal/mol
3 56 Se(g) H°-H° = 1.4815 kcal/mol
S** = 42.21 cal/deg mol
Cp^ - 4.978 cal/deg mol
3 61 N(g) Z^Gf° = 108.886 kcal/mol
S« = 36.613 cal/deg mol
3 85 PH„, std. state. ^298 = -2.27 kcal/mol
in=l(aq) ^f° = 6.05 kcal/mol
S" = 28.7 cal/deg mol
69
TN
3
Page
85
86
87
89
91
97
132
196
208
231
APPENDIX
Errata (Cont.)
+PH. , std. state,
in=l(aq)
H PO "_, std. state,
in=l(aq)
H PO in 0.75H2O(aq)
PH. OH, std state,
in=l(aq)
t£.V
tGV
.AHf298
22.0 kcal/mol
-270.17 kcal/mol
-304.35 kcal/mol
AHf° = -70.59 kcal/mol
ZCf° = -50.64 kcal/mol
S° = 45.4 cal/deg mol
H.P^O^ in 500H-0 should be in 150H^O4 2 7 2 2
PN(g) AHfQ
AsCl^Cliq)
AsCl^Cg)
ZNGf
298
298
^5AHf
298
298
= 8. kcal/mol
7.76 kcal/mol
2.47 kcal/mol
= -62.0 kcal/mol
= 51.7 c:>l/deg mol
= -62.12 kcal/mol
= -62.5 kcal/mol
= -59.5 kcal/mol
C2H glycollate ion ^^^298 " "155.9 kcal/mol
std. state, m=l(aq)
B (amorp) X denotes undetermined residualentropy
Al (c) ; the third, fourth and fifth lines should read;
P
k
298
TeCSeO^)^ should be TY^iSQ.0^
^
AHf^gg = -391. kcal/mol
= -397. kcal/mol
(Delete value for ^^\^^Mf°^o = -395. kcal/mol
Tl2Se(c)
TlOCH^Cc)
formula weight = 487.70
AHf° - = -39.7 kcal/molzyb
70
4
4
4
4
4
4
APPENDIX
Errata (Cont.)
TN Page
3 233 ZnO«2ZnO •2H2 0(c) ^298 = -368.6 kcal/mol
ZnO'2ZnO • 3H2 0(c) ^298 = -438.6 kcal/mol
3 234 ZnF^Cc) ASf -170.5 kcal/mol
3 244 ZnAs2(c)
Zn^As^ (c)
^298 =
^l98=
-10.0 kcal/mol
-7.7 kcal/mol
3 248 CdF , std. state. ^298 = -177.14 kcal/mol
in=l(aq)
4 3 Hgl(g) ^0 =
^298 =
^^298 =
32.9 kcal/mol
31.64 kcal/mol
21.14 kcal/mol
14
16
57
59
60
62
CuC 12(c) Cp< 17.18 cal/deg mol
Cu„(OH) CI should be CuCl •3Cu(0H)<,, formula weight 427.110
CoBr in 1000H20(aq) AEIf° g = -71.6 kcal/mol
[Co(NH3)g]3+
std.
state, m=l(aq)
[Co(NH2)g]N^^"^, std.
state, m=l(aq)
,3+.
ASf°
AGf°
= -37.6 kcal/mol
= 35. eu cal/deg mol
42.9 kcal/mol
60. cal/deg mol
[Co(NH3)^(H20)2]""(aq) AHf°gg = -244.2 kcal/mol
= -125.5 kcal/mol
S° =107 cal/deg mol
Z^f° = -117.4 kcal/mol
S* = 140. cal/deg mol
[Co(NH3)g](N03)3, (c) ^f<
std. state^ m=l(aq)
63 [Co(NH3)^Cl2] cis(aq) ^^293 = -160.5 kcal/mol
trans (aq) ^298^ -162.3 kcal/mol
[Co(NH^),Cl^]Cl cis(c) AHf° _ = -209.1 kcal/mol
trans (c) AEIf° _= -209.7 kcal/molZyo
cis(aq) ^^f^Qo = -200.5 kcal/mol
trans(aq) AHf° _=-202.3 kcal/molZyo
71
APPENDIX
Errata (Cont.)
TN Page
4 63 [Co(NR^) ]C1^ std. Z^Gf° = -131.7 kcal/mol
state, tn=l(aq) S° = 75. cal/deg mol
4 63 [CoCNH^) (H20)2]Cl2(c) ^^298 " "366^9 kcal/mol
in lO^OOOF^O (aq) AHf°gg = -364.1 kcal/mol
4 64 [Co(NH„),](C10, )^(c) AGf° = -53.0 kcal/mol
S° = 147. cal/deg mol
std. state, m=I(aq) Z^f° = -43.8 kcal/mol
S" = 166. cal/deg mol
4 65 [Co(NH„)^]Br„ (aq) Z£f° = -112.2 kcal/molJ D J
Std. state, m=l S° = 94. cal/deg mol
4 66 [Co(NH2)g]l3 (aq) Z^° = -74.6 kcal/mol
std. state, m=l S° = 113. cal/deg mol
4 67 [Co(NH„),]SO,'^ ASf° = -220.2 kcal/molJO HStd. state, m=l(aq) S° = 57. cal/deg mol
4 68 Co(HCO ) should be Co(HCO )
4 70 [Co(NH3) C^O ]"''(aq) -^£298 " "298.0 kcal/mol
4 98 PtS(c) ^298"^0 " ^'^^^ kcal/mol
m£^ = -19.020 kcal/mol
4 99 PtTe2(c)^298""o
" ^'^^^ kcal/mol
S* = 28.92 cal/deg mol
Cp" = 18.03
4 108 Mnl2-4H20(c) ^^298 " '^^^'^ kcal/mol
4 113 MnC20^(c) ^^^298 " "2^5.9 kcal/mol
MnC20 .2H20(c) ^^298 " "389.2 kcal/mol
S° = 48. cal/deg mol
MnC20 •3H20(c) ^^^298 " "'^59.1 kcal/mol
5 2 ^10^8^" ^^^' ^^^^®^ "^^298 ="^^^^' kcal/mol
in=l(aq) S" = 53. cal/deg mol
H V^^O^g"^" std. state, ^£398 =-1846. kcal/mol
m=l(aq)
72
INDEX OF CONTENTS
ChemicalSynabol
Ag
Al
Ar
As
At
Au
B
Ba
Be
Bi
Br
C
Ca
Cd
Ce
CI
Co
Cr
Cu
Dy
Er
Eu
F
Fe
Ga
Gd
Ge
H
Element Table Volvime -
Number Page Number
Silver 37 4- 29
Alumimam 29 3-207
Argon 5 3- 17
Arsenic 20 3- 95
Astatine 13 3- 42
Gold 38 4- 39
Boron 28 3-196
Barium 96 6- 78
Beryllium 92 6- 1
Bismuth 22 3-103
Bromine 11 3- 31
Carbon 23 3-106
Calciiom 94 6- 30
Cadmivim 34 3-248
Cerium 75 7- 53
Chlorine 10 3- 24
Cobalt 40 4- 54
Chromium 51 4-120
Copper 36 4- 13
Dysprosium 67 7- 21
Erbium 6,5 7- 13
Europivim 70 7- 33
Fluorine 9 3- 21
Iron 41 4- 74
Gallium 30 3-218
Gadolinium 69 7- 29
Germanium 25 3-177
Hydr ogen 2 3- 12
73
ChemicalSymbol
He
Hf
Hg
Ho
I
In
Ir
Kr
La
Lu
Mg
Mn
Mo
N
Nb
Nd
Ne
Ni
O
Os
P
Pb
Pd
PmPo
Pr
Pt
Ra
Element Table Volume -
Number Page Number
Helium 3 3- 15
Hafnium 59 5- 22
Mercury 35 4- 1
Holmium 66 7- 16
Iodine 12 3- 36
Indium 31 3-223
Iridium 46 4-103
Krypton 6 3- 18
Lanthanum 76 7- 60
Lutetium 62 7- 1
Magnesium 93 6- 9
Manganese 48 4-106
Molybden\im 52 4-129
Nitrogen 18 3- 61
Niobium 55 5- 6
Neodymium 73 7- 43
Neon 4 3- 16
Nickel 39 4- 43
Oxygen 1 3- 11
Osmixom 47 4-104
Phosphorus 19 3- 84
Lead 27 3-187
Palladium 42 4- 90
Promethium 72 7- 42
Polonium 17 3- 60
Praseodymium 74 7- 48
Platinum 45 4- 96
Radium 97 6-103
74
ChemicalSymbol
Re
Rh
Rn
Ru
S
Sb
Sc
Se
Si
Sm
Sn
Sr
Ta
Tb
Tc
Te
Ti
Tl
Tm
V
WXe
Y
Yb
Zn
Zr
Element Table Volume -
Number Page Number
Rhenium 50 4-117
Rhodium 43 4- 93
Radon 8 3- 20
Ruthenium 44 4- 94
Sulfur 14 3- 43
Antimony- 21 3- 99
Scandium 60 5- 24
Selenium 15 3- 56
Silicon 24 3-171
Samarium 71 7- 37
Tin 26 3-181
Strontium 95 6- 57
Tantalum 56 5- 10
Terbi\im 68 7- 25
Technetixom 49 4-116
Telluriiim 16 3- 58
Titanium 57 5- 12
Thallivim 32 3-227
Thulium 64 7- 9
Vanadiiom 54 5- 1
Tungsten 53 4-134
Xenon 7 3- 19
Yttrium 61 5- 28
Ytterbium 63 7- 4
Zinc 33 3-233
Zirconium 58 5- 18
* U. S. GOVERNMENT PRINXrNG OFFICE : 1 973—51 1 .325/241
75
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U.S. DEPT. OF COMM.BIBLIOGRAPHIC DATA
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PUBLICATION OR REPORT NO.
NBS-TN-270-73. Recipient's Accession No.
4. TITLE AND SUBTITLESelected Values of Chemical Thermodynamic PropertiesTables for the Lanthanide (Rare Earth) Elements(Elements 6Z through 76 in the Standard Order of Arrangement)
5. Publication Date
April 1973
6. Performing Organization Code
7. AUTHOR(S) R. H. Schumm, D. D. Wagman, S. Bailey,W. H. Evans, and V. B. Parker
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Contains tables of values for the standard heats and Gibbs (free)
energies of formation, entropies and enthalpies at 298.15 K and heatsof formation at K for compounds of the rare-earth elements ( thelanthanides ; lutetium through lanthanum; elements 62 through 76 in theStandard Order of Arrangement). These tables are a continuation of
the comprehensive revision of NBS Circular 500.
Keywords: Cerium compounds; dysprosium compounds; enthalpy;entropy; erbium compounds; europium compounds; gadolinium compounds;Gibbs energy of formation; holium compounds; lanthanides; lanthanumcompounds; lutetium compounds; neodymium compounds; praseodymiumcompounds; promethium compounds; rare-earth elements; samariumcompounds; terbium compounds; thulium compounds; ytterbium compounds,
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