Fatty Alcohol Ethoxylates SURFONIC® L24, TDA series surfactants, TERIC® 12A / 13A / 17A series surfactants
Fatty Alcohol Alkoxylates HYDRAPOL™ RP series surfactants, SURFONIC® LF series surfactants, TERIC® BL series surfactants
Fatty Amine Ethoxylates SURFONIC® T series surfactants, TERIC® 16M / 18M series surfactants
Alkylphenol Ethoxylates SURFONIC® NP / OP series surfactants, TERIC® N / X, series surfactants
Fatty Acid Ethoxylates SURFONIC® E-400 series surfactants, TERIC® SF / OF series surfactants
Castor Oil Ethoxylates SURFONIC® CO series surfactants, TERIC® 380 surfactant
EO : PO Block Copolymers SURFONIC® POA-L series surfactants, TERIC® PE series surfactants
Reverse EO : PO Block Copolymers SURFONIC® POA-17R2, POA-17R4, and POA-25R2 surfactants
Phosphate Esters SURFONIC® PE series surfactants
Functional Fluids JEFFOX™ series fluids
Glycols MEG, DEG, TEG
Polyethylene Glycols PEG and POGOL® series glycols
Polypropylene Glycols PPG
Glycol Ether Solvents GLYSOLV™ series solvents
Synthetic Sodium Sulphonates SURFONIC® SM series surfactants
About HuntsmanHuntsman Corporation is a publicly traded global manufacturer and marketer of differentiated and specialty chemicals with 2017 revenues of approximately $8 billion. Our chemical products number in the thou-sands and are sold worldwide to manufacturers serving a broad and diverse range of consumer and industrial end markets. We operate more than 75 manufacturing, R&D and operations facilities in approxi-mately 30 countries and employ approximately 10,000 associates within our four distinct business divisions. For more information about Huntsman, please visit the company’s website at ww.huntsman.com.
Huntsman Performance Products Performance Products brings together innovation and world-leading process technologies to produce more than 2,000 components used to formulate products that enhance people’s lives:
• Amines: Largest global producer of specialty amines used in composites, coatings, fuel and lube additives, and gas treating
• Maleic Anhydride: The leading global producer and supplier into areas such as unsaturated polyester resins, food, oil additives and coatings
• Surfactants: Integrated producer of a wide range of products for home and personal care, oilfield, agriculture, and process industries
• Ethylene and Derivatives: Highly integrated manufacturer of ethylene, ethylene oxide, ethylene glycol and other derivatives
The division has 14 manufacturing plants and had 2017 revenues of USD 2.1 billion.
DisclaimerHuntsman Corporation warrants only that its products meet the specifications stated in the sales contract. Typical properties, where stated, are to be considered as representative of current production and should not be treated as specifications. While all the information presented in this document is believed to be reli-able and to represent the best available data on these products, HUNTSMAN MAKES NO WARRANTY OR GUARANTEE OF ANY KIND, EXPRESS OR IMPLIED, INCLUDING BUT NOT LIM-ITED TO ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, NON-INFRINGEMENT OF ANY INTELLECTUAL PROPERTY RIGHT OF ANY THIRD PARTY, OR WARRANTIES AS TO QUALITY OR CORRESPONDENCE WITH PRIOR DESCRIPTION OR SAMPLE, AND ANY USER OF PRODUCTS DESCRIBED HEREIN SHOULD CONDUCT A SUF-FICIENT INVESTIGATION TO ESTABLISH THE SUITABILITY OF ANY PRODUCT FOR ITS INTENDED USE AND ASSUMES ALL RISK AND LIABILITY WHATSOEVER RESULTING FROM THE USE OF SUCH PRODUCT, WHETHER USED SINGLY OR IN COMBINATION WITH OTHER SUBSTANCES. Products may be toxic and require special precautions in handling. For all products described herein, the user should obtain detailed information on toxicity, together with proper shipping, handling, and storage procedures, and should comply with all applicable safety and environmental standards. The behavior, hazards and/or toxicity of the products referred to in this publication in manufacturing processes and their suitability in any given end-use environment are dependent upon various conditions such as chemical compat-ibility, temperature, and other variables, which may not be known to Huntsman. It is the sole responsibility of the user of such prod-ucts to evaluate the manufacturing circumstances and the final products under actual end-use requirements and to adequately advise and warn future purchasers and users thereof.
JEFFADD® , JEFFAMINE®, POGOL®, SURFONIC® and TERIC®
are registered trademarks of Huntsman Corporation or an affili-ate thereof in one or more, but not all, countries.
DGA™, GLYSOLV™, HYDRAPOL™ and JEFFOX™ are a trademark of Huntsman Corporation or an affiliate thereof.
SURFONIC® POA block copolymers are very useful in a variety of metalworking operations. These products are made by the sequential addition of ethylene oxide and propylene oxide. The functional attributes of these products - defoaming, wetting, lubricity, solubilization, emulsification, thickening and dispersion - all depend on the ratio of ethylene oxide to propylene oxide, the molecular weight and blocking pattern of the molecule.
SURFONIC® POA-L101 surfactant
EO/PO block copolymers
Clear to hazy liquid, substantially free of foreign matter
1 150 5.5-7.5 5% in 10:6
IPA:H2O
800 13-17 3-10% • Emulsifier and dispersant • Solubilizer for semi-synthetics and synthetic fluids
SURFONIC® POA-17R2 surfactant
Reverse EO/PO block copolymers
Colorless to light yellow liquid
8 100 6.0-7.5 205 (38°C)
35 3-10% • Prime surfactant in cleaners and wetting agent • Lubricant in synthetic fluids
SURFONIC® POA-17R4 surfactant
Reverse EO/PO block copolymers
Colorless to light yellow liquid
7-12 80 5.5-7.0 254 (38°C)
44-48 3-10% • Reduces misting • Lubricant in synthetic fluids
SURFONIC® POA-25R2 surfactant
Reverse EO/PO block copolymers
Colorless to light yellow liquid
6.3 100 6.0-7.5 570 30 3-10% • Lubricant in synthetic fluids • Solubilizer in semi-synthetic fluids
JEFFOX™ functional fluids are alkoxylates of mono-, di- or tri-functional starting materials. These versatile fluids have varying degrees of solubility in water and oil. The fluids possess many desirable properties of natural lubricants and have distinctive properties of their own. They are recommended for use in difficult applications such as drilling, quenching and as a gear oil component.
JEFFOX™ WL-660 fluid
EO/PO block copolymers
Clear liquid - - 7.7 158 (38°C)
66 5-15% • Exceptional lubrication, excellent finishes and longer tool life • High viscosity index used at a wide range temperatures
JEFFOX™
WL-5000 fluidEO/PO block copolymers
Clear amber liquid
- 200 - 1080 (38°C)
53 5-15%
LOW FOAM SURFACTANT
Alcohol alkoxylates are ideally suited for metalworking operations. They tend to have low foam and excellent wetting characteristics. Some products can work as defoamers in water-based systems.
TERIC® 168 surfactant
Alcohol alkoxylate Clear to hazy liquid
11.1 250 6.0-8.0 1% aq.
70 (20°C)
28-37 2-15% • A low foaming surfactant with excellent wetting properties. It may be used in low foam metal cleaning formulations
SURFONIC® JL-80X surfactant
Alcohol alkoxylate Clear liquid 13.1 100 7.0 51 59 2-15% • Used in metal cleaning operations • Special structure eliminates gel phase common to alcohol ethoxylates in aqueous solutions
SURFONIC® LF-17 surfactant
Alcohol alkoxylate Not more than a trace of turbidity
- 100 5.0-7.51% aq.
96 32-36 5-20% • Used in low foam semi-synthetic cutting fluids• Used in low foam, highly effective microemulsion or solution cleaners • Wetting agent in acid cleaner formulations • LF-17/LF-18 may be used as an efficient low foam emulsifier in metalworking fluids• LF-37 has excellent wetting performance and a very low foaming tendency• Emulsifier and rinse aid for metal cleaning• Solubilizer / emulsifier for semi-synthetic formulations • Co-emulsifier for semi-synthetics • Rinse aid for cleaners • Emulsifier for semisynthetics
Huntsman Performance Products is a major integrated supplier of amines, emulsifiers and surfactants, offering a wide range of products to the Metalworking industry. More than being merely a supplier, Huntsman offers direct benefits through synthesis-based and application research, attention to manufacturing efficiencies, and personalized technical support.
Product Description
Properties1
Function
CharacteristicEq
uiva
lent
W
eigh
t
Appe
aran
ce
at 2
5ºC
Max
. Col
or,
Pt-C
o
pH, 5
%
Aque
ous
Solu
tion
Visc
osity
,Cs
t, 25
°C
Flas
h po
int,
PMCC
, ºC
Sugg
este
d Do
sage
AMINES
Amines are an important component in both metalworking fluids and metal cleaning applications where they act as a corrosion inhibitor and a source of reserve alkalinity. Amine selection is based on metals encountered, misting concern, toxicity, alkalinity requirements and stability.
124 1-10% • Enhances pH stability as a pH buffer • Low tendency to leach cobalt/copper from tooling• Less staining of some Al alloys compared to other amines• Common intermediate for amides• Low acute toxicity and low nitrosamine potential
126 1-10% • Replacement for TEA and minimizes corrosion on aluminum• Reserve alkalinity source
POLYETHERAMINES
JEFFAMINE® polyetheramines contain primary amino groups attached to the end of a polyether backbone. The polyether backbone is normally based on either propylene oxide (PO), ethylene oxide (EO), or copolymer (PO/EO).
JEFFAMINE® D-2000 polyetheramine
Diamine of polypropylene glycol (PPG)
2000 Colorless to light yellow liquid
25 10.5 248 185 0.1-0.5% • Can be used as a defoamer • Low foaming tendency
JEFFAMINE® D-400 polyetheramine
Diamine of polypropylene glycol (PPG)
430 Colorless to pale yellow liquid
30 11.6 22 163 - • Increased lubricity performance for amide • Low tendency to leach cobalt/copper from tooling
JEFFADD® MW-703 polyetheramine
Triamine of a triol reacted with propylene oxide (PO)
440 Colorless to pale yellow liquid
50 11.6 72 196 0.5-5% • Increased lubricity• Low tendency to leach cobalt/copper from tooling • Enhances pH stability
AMINE ETHOXYLATES
SURFONIC® T series surfactants can be used in different types of metalworking operations. These products can be applied to both soluble oil and semi-synthetic formulations and act as co-emulsifiers to help solubilize additives.
SURFONIC® T-5 surfactant
Tallow amine ethoxylate - Amber liquid 9 (HLB)
9.0-10.5 71 (40°C)
374 5-10% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
SURFONIC® T-10 surfactant
Tallow amine ethoxylate - Clear to turbid amber liquid
12.4 (HLB)
9.4 (1%)
69 (40°C)
350 5-10% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
1 Properties are for reference only. Please approach Huntsman for actual specificationsOnly selected products have been showcased in this brochure. Please approach Huntsman for a full range of surfactant products.
SURFACTANTS
Linear alcohol ethoxylates are widely used as emulsifiers, cleaners, penetrants and wetting agents. Appropriate selection of the alcohol chain length and degree of ethoxylation can provide the surfactant properties for a particular application. Primarily emulsifiers are most appropriate to the formulation of vegetable oils, glycerides, higher viscosity paraffinic oils, cycle oils and waxes. Castor oil ethoxylates are used as emulsifiers and dispersing agents for water-miscible formulations. Huntsman offers a variety of castor oil ethoxylates with varying degrees of ethoxylation to suit customer needs.
Product Description Function
TERIC® 17AN surfactant (N stands for 2 EO to 25 EO) C16 - C18 (Cetyl - Oleyl) alcohol ethoxylates • Extensively used as emulsifiers, cleaners, penetrants and wetting agents in metalworking formulations
• Appearance (25°C) varies from clear liquids to white waxy solids, depending on the alcohol used and degree of ethoxylation
SURFONIC® TDA series surfactants Iso-C13 (iso-Tridecanol) ethoxylates
SURFONIC® L-24 series (2 EO to 22 EO) C12 - C16 alcohol ethoxylates
SURFONIC® CO series surfactants Castor oil ethoxylates• Emulsifiers and dispersing agents that can impart some lubricity in formulations
Product Description
Properties1
Function
Characteristic
Appe
aran
ce
at 2
5ºC
HLB
Pour
poi
nt
ºC
Dens
ity,
25ºC
, g/m
L
Visc
osity
,Cs
t, 25
°C
Clou
d po
int
ºC (1
%
aque
ous)
Sugg
este
d Do
sage
NPE REPLACEMENTS
Alkyl poly(alkylene oxide) derivatives based on a synthetic linear primary alcohol. Due to their low viscosities, the surfactants are easily handled.
HYDRAPOL™ RP40 surfactant
Alkyl poly (alkylene oxide) derivative based on a synthetic linear primary alcohol
Clear to slightly turbid liquid
7.8 -10 0.949 28.5 (20°C)
45 0.5-6% • Soft gel structures lead to easy dispersal and dissolution
HYDRAPOL™ RP50 surfactant
Alkyl poly (alkylene oxide) derivative based on a synthetic linear primary alcohol
- 5-20% • Inherently low foaming• Solvent free product• Clean labeling and no VOC• Stable emulsions after shearing
SYNTHETIC SODIUM SULPHONATE
Huntsman is a major manufacturer of alkyl benzenes with an existing and developing range of higher molecular weight materials. Our SURFONIC® SM products are synthetic sodium sulphonates that offer excellent emulsification and corrosion inhibition. These products are used as primary emulsifiers in soluble oil and semi-synthetic fluids. These products can be used to replace natural sodium sulfonates in metalworking fluids.
SURFONIC® SM-60 HBH surfactant
Synthetic sodium sulphonate Clear, brown liquid - 510 average
MW
60% active
content
1500 - 5-15% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
SURFONIC® SM-100 HBH surfactant
Synthetic sodium sulphonate Clear, brown liquid - 510average
MW
78% active
content
1700 (50°C)
- 5-15% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
SURFONIC® SM-50 HBA surfactant
Synthetic sodium sulphonate Clear, brown liquid - 497average
MW
50% active
content
3500 (50°C)
- 5-15% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
SURFONIC® SM-60 MXA surfactant
Synthetic sodium sulphonate Clear, brown liquid - 425average
MW
60% active
content
3000 - 5-15% • Wetting agent • Emulsifier in soluble oil and semi-synthetic fluids
EXTREME PRESSURE ADDITIVES - PHOSPHATE ESTERS
Phosphate esters provide extreme pressure (EP) properties to water-based and synthetic formulations. Additionally, they provide lubricity and emulsification actives and may provide excellent corrosion resistance in different kinds of metalworking formulations.
SURFONIC® PE-1198LA surfactant
Alkylaryl ethoxylate complex phosphate in free acid form
Viscous yellow liquid
Acid Value: 95-110
mgKOH/g, pH 2#
-9.4 1.12 1510 (40°C)
2.5 (5% pH)
0.5-3% • Excellent aluminum protection• Good EP performance• Hard water tolerance
SURFONIC® PE-2852 surfactant
Aliphatic phosphate in free acid form
Clear liquid Acid Value: 125-160 mgKOH/g,
pH 2#
-32 1.05 116 (40°C)
- 0.5-3% • Good corrosion inhibition • Good EP performance
