1
TEGO® Antifoam products
for the Production of
SBR-Latex & SBR-Rubber
BL Interface & Performance
2
Two Types of Styrene Butadiene Rubber (SBR)
Defoamer for the Production of SBR-Latex and SBR-Rubber
2. SBR-Rubber
▪ Synonyms: SBR, SBR-Elastomer, SB-Elastomer, SB-Rubber
▪ Solid material, properties similar to natural rubber, cross-linkable
▪ Main applications: tires, tubes, mechanical rubber goods, shoe sole
▪ 60% of globally produced SBR
1. SBR-Latex
▪ Synonyms: SB-Latex, SBR liquid
▪ Liquid material
▪ Main applications: paper coating, carpet backside, foams, asphalt
▪ 40% of globally produced SBR
3
1. SBR-Latex and its Main Applications
Defoamer for the Production of SBR-Latex and SBR-Rubber
Paper coatings Carpet backings
65%
15%
8%
2%
9%*
Total market: 3,2 Mio t
Asphalt modificationFoams & adhesives
4
TEGO® Antifoam in the Production of SBR-Latex
Defoamer for the Production of SBR-Latex and SBR-Rubber
Water
Monomer
Additives
Emulsifier:
Sulfonate
Sulfate
Ethersulfate
SBR-Latex
TEGO® Antifoam 2291
Monomer removal
(Styrene)
Reactor Stripper
5
Test Method – Sintered Glass Test
Defoamer for the Production of SBR-Latex and SBR-Rubber
Preparation
One liter surfactant solution is poured into a 2-litre graduated cylinder.
Defined amount of prediluted antifoam is added.
Test
Six liters of air per minute are bubbled through the sintered glass into the solution
whereby foam is formed.
When the foam reaches the 2 liter mark antifoam is added again and the time is noted.
This is done for 30 minutes.
Analysis
The total number of dosages is used as measurement for the antifoam’s efficiency.
In case the antifoam efficiency is checked in emulsifiers or dispersants for the
production of polymer dispersions this test is run at 60 °C.
6
Test Method – What the Sintered Glass Test looks like
Defoamer for the Production of SBR-Latex and SBR-Rubber
The cylinder has to be filled
with 1000 mL of surfactant
solution
When the foam reaches
2000 mL another amount of
antifoam is added
7
TEGO® Antifoam 2291 is 2 to 3 Times More Efficient
Defoamer for the Production of SBR-Latex and SBR-Rubber
Less dosages (=shorter bar) means higher efficiency of the antifoam
0
2
4
6
8
10
12
14
do
sa
ge
s
Competitor 1
(Si-containing)
Competitor 2
(Si-free)
TEGO® Antifoam
2291
Sulfonate
Ethersulfate
8
TEGO® Antifoam 2291 – Product Information
Defoamer for the Production of SBR-Latex and SBR-Rubber
100% active material, silicone free, dosage level: 0,01 - 0,1%
Can be used as delivered or from a predilution in water.
Compliant with Regulation (EU) 10/2011, BfR XIV, FDA 176.210,
FDA 175.105, FDA 175.300, FDA 176.170, FDA 176.180 and 177.2600
Is listed in the following chemical inventories:
EINECS, TSCA, ENCS, AICS, PICCS, CHINA, DSL, ECL, NZIOC
TEGO® Antifoam 2291 is a defoamer based on paraffinic oil
9
2. SBR-Rubber and its Main Applications
Defoamer for the Production of SBR-Latex and SBR-Rubber
Mechanical goods
Non-tire automotive
Tires
75%
15%
6%
4%
Miscellaneous
Total market: 4,5 Mio t
10
TEGO® Antifoam – Excellent Defoaming & no Fouling
Defoamer for the Production of SBR-Latex and SBR-Rubber
Water
Monomer
Additives
Latex
Coagulation
Rubber
Emulsifier:
Soap
TEGO® Antifoam
2450 / 2460 Acid
Reactor Stripper
Monomer removal
(Styrene)
11
TEGO® Antifoam products are 1,5 to 6 Times More Efficient
Defoamer for the Production of SBR-Latex and SBR-Rubber
Less dosages (=shorter bar) means higher efficiency of the antifoam
0
2
4
6
8
10
12
14
16
18
do
sa
ge
s
Competitor 3 Competitor 4 TEGO®
Antifoam 2450
TEGO®
Antifoam 2460
Soap 1 (Italian Producer)
Soap 2 (German Producer)
12
Conventional Antifoams can Create Undesired Fouling
Defoamer for the Production of SBR-Latex and SBR-Rubber
Reactor Stripper Coagulation
Rubber
Fouling = partial coagulation
Water
Monomer
Additives
Emulsifier:
Soap
AcidConventional Antifoams
13
Test Method for Fouling Caused by Defoamer
Fouling/Coagulation test
▪ 100 g of the test dispersion including 0,1% defoamer as
delivered is poured into a beaker and stirred for 30 minutes
at 60°C.
▪ The dispersion is filtrated and the filter (with coagulate) is
dried in an oven.
▪ After that the amount of the dry coagulate is weighted.
Defoamer for the Production of SBR-Latex and SBR-Rubber
14
No Coagulation Observed with TEGO® Antifoam 2450/2460
Dispersion 1 Dispersion 2
Controle 0,00g 0,02g
Competitor 3 0,02g 0,00g
Competitor 4 0,07g 0,05g
TEGO® Antifoam 2450 0,00g 0,00g
TEGO® Antifoam 2460 0,02g 0,00g
Defoamer for SBR-Latex 0,22g 0,31g
Standard Defoamer 0,24g 0,27g
Defoamer for the Production of SBR-Latex and SBR-Rubber
15
TEGO® Antifoam 2450 & 2460 - Product Information
Defoamer for the Production of SBR-Latex and SBR-Rubber
We recommend to test both products in a specific formulation to identify the most suitable defoamer.
Dosage level: 0,02 – 0,2%
Can be used as delivered or from a predilution in water.
It is preferred to use the antifoam undiluted
Both compliant with FDA 176.210 and FDA 175.105, in addition 2450 compliant to Regulation (EU)
10/2011, BfR XIV
Listed in the following chemical inventories:
EINECS, TSCA, ENCS, AICS, PICCS, CHINA, DSL, ECL
TEGO® Antifoam 2450 is a defoamer based on vegetable oil, TEGO® Antifoam 2460 is a defoamer
based on mineral oil (2460), 100% active material, both contain no silicone oil
16
TEGO® Antifoam and Emulsifiers for SBR-Latex & SBR-Rubber
Defoamer for the Production of SBR-Latex and SBR-Rubber
TEGO® Antifoam 2291 X X X X
TEGO® Antifoam 2450 X X
TEGO® Antifoam 2460 X X
Emulsifiers for E-SBR Production
Alk
yl
Eth
er
Su
lfa
te
So
diu
m S
alt
s
Alk
yl
Su
lfa
tes
So
diu
m
Sa
lts
Alk
ylb
en
ze
ne
Su
lfo
nic
Ac
ids
So
diu
m S
alt
s
Dia
lky
l
Su
lfo
su
cc
inic
Ac
ids
So
diu
m S
alt
s
Dis
pro
po
rtio
na
ted
Re
sin
Ac
id S
oa
ps
Fa
tty
Ac
idS
oa
ps
17
Overview Food Contact Status and National Registrations
Defoamer for the Production of SBR-Latex and SBR-Rubber
R
eg
. 1
0/2
01
1
F
DA
17
6.2
10
F
DA
17
5.1
05
F
DA
17
6.1
70
F
DA
17
6.1
80
F
DA
17
5.3
00
F
DA
17
7.2
60
0
B
FR
XIV
R
eg
istr
ation
s
TEGO® Antifoam
2291X X X X X X X X
EINECS, TSCA, DSL,
ENCS, AICS, ECL,
PICCS, CHINA,
NZIOC
TEGO® Antifoam
2450X X X X
EINECS, TSCA, DSL,
ENCS, AICS, ECL,
PICCS, CHINA
TEGO® Antifoam
2460X X
EINECS, TSCA, DSL,
ENCS, AICS, ECL,
PICCS, CHINA
18
TEGO® Antifoam for SBR – Your benefits & What You Can Expect
Defoamer for the Production of SBR-Latex and SBR-Rubber
TEGO® Antifoam 2291 for SBR-Latex
▪ Substantial cost savings due to 2 to 3 times higher efficiency
▪ Broad food contact status gives freedom for final applications, e.g. coated paperboard for food packaging
TEGO® Antifoam 2450 & 2460 for SBR-Rubber
▪ Substantial cost savings due to 1.5 to 6 times higher efficiency
▪ Products do not cause fouling/precipitation in stripper
Support by our technical team in testing and identifying the optimal defoamer for your specific
application!
19