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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 1 Introduction to Soil Engineering D. A. Cameron 2007
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Page 1: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 1

Introduction to Soil Engineering

D. A. Cameron

2007

Page 2: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 2

StaffCIVIL ENGINEERING

Dr. Don Cameron

[email protected]

P2-35

ph 8302 3128

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 3

Reference

Barnes, G E

“Soil Mechanics, Principles and Practice,” MacMillan Press

Civil Engineering students will need

this text in 3rd year

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 4

The engineering behaviour of soil

1. How soils are formed 2. The basic units which form soil material 3. Engineering concepts of sand, silt and clay 4. The Unified Soil Classification System 5. Stress in soil, total and effective 6. Water flow in saturated soils 7. Erosion, scour or piping 8. Physical improvement of soil (“compaction”)9. Terminology

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 5

Origins of Soils

• Residual

• Alluvial

• Aeolian = wind blown

• Glacial

• Marine

• Lacustrine

• Organic

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 6

Mountains

Lakes, estuaries, deltas OceanOcean

River valleys

Coastline

G

B, ‘C’G

S

C, O (organic)

M = silts

Water Transport and Soil DevelopmentWater Transport and Soil Development

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 7

Soil from Rocks = Residual

SAND - quartz, silica

SILT - finer quartz & silica (8:4:2)

CLAY - clay minerals

(from weathered feldspar & mica )− very fine “clay” particles

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 8

Particle Interactions

Coarse soils v. Fine soils

[sand and gravel] v. [silt and clay]

STRENGTH DERIVED FROM

Friction, interlock v.

physico-chemical interaction

Page 9: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 9

Clean Sand - under the microscope

1 mm = 1000m

angular particles from quarry

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 10

Fine - Grained Soils

Cohesion

“Apparent” cohesion

“apparent” tensile strength,

arising from

electrostatic forceselectrostatic forces

(are stronger, the finer the particle)

Page 11: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 11

Molecular Structure of the Clay Minerals

Lecture 1

Civil Engineering Practice

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 12

http://pubpages.unh.edu/~harter/crystal.htm#

Phyllosilicates

are the clay “building blocks”

Tetrahedrons & Octahedrons

• Clays form from weathering and secondary sedimentary processes

• Clays are usually mixed − other clays

− microscopic crystals of carbonates, feldspars, micas and quartz

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 13

1. The Tetrahedron Unit

Silica, Si4+

forms a tetrahedron

with 4 x O2-

Has a nett -ve charge of 4-

Page 14: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 14

1. Silica Tetrahedron Unit

8-, 4+

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 15

Tetrahedral sheets

• Formed by sharing of O2- between

units

• Corner O2- shared, creating the

sheet

• Nett –ve charge at top of

tetrahedral sheets!

Page 16: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 16

Sharing

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 17

2. The Aluminium Octahedral Unit

Al3+ with six O2-

Each oxygen ion is left

with 1.5 –ve charge

Page 18: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 18

Aluminium Octahedra

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 19

Octahedral sheets

• Octahedral sheets formed by each

oxygen being bonded to two Al ions

• Each O ion left with one –ve charge

• IF charge satisfied by hydrogen ions,

the Gibbsite mineral is formed

Page 20: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 20

Sharing

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 21

The Kaolinite CLAY Mineral

• Top oxygen ions in Silica sheet

bonded to Aluminium sheet

– “1:1 clay mineral”

• Each top oxygen ion shared by 2 Al

and 1 O ion

• This unit = “a clay micelle”

(approx. 0.7 nm thick and 10 x10 nm)

Page 22: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 22

Kaolinite micelle

Gibbsite layer

Silicate layer

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 23

Kaolinite clay mineral

…consists of stacks of micelles

Usually hydrogen bonds

micelles together:

a strong bond

stable clay mineral

Page 24: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 24

Kaolinite

Hydrogen bonding

Micelle

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 25

Kaolinite

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 26

2:1 Clay Minerals “The Mica Group”

3 sheets, 2 silica tetrahedra,

1 aluminium octahedron = a micelle

Many different clay minerals occur

with this basic unit

e.g. “Illite” (Adelaide clays) and

“Montmorillonite” (basaltic clays)

Page 27: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 27

Smectite (includes montmorillonite)

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DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 28

2. Clay mineral stack

0.1x10-6 m

1. Clay mineral 1x10-

7 m

3. Aggregate

1 to 4x10-5 m

4. Clod

0.1 mm = 1x10-4 m?

Page 29: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 29

Properties of the clay minerals

When mixed with a little water,

clays become “plastic”

i.e. are able to be moulded

SO, moisture affects clay soil

engineering properties

Page 30: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 30

Properties of the clay minerals

• Can absorb or lose water between the

silicate sheets

− negative charge attracts H2O

• When water is absorbed, clays may

ExpandExpand !!

− water in spaces between stacked layers

− Montmorillonite most expandable

− Kaolinite the least

Page 31: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 31

Illite v Montmorillonite Different forms of bonding between these minerals

Illite - main component of shales and other argillaceous rocks

- stacks keyed together by K+

- nett negative charge

Montmorillonite

- stacks keyed together by Na++ or Ca++

and H2O

- greater nett negative charge

Page 32: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 32

Clay Minerals – capacity for water

i) Kaolinite (China clay) Water absorption, approximately 90%

ii) Montmorillonite (Bentonite, Smectite)

Water absorption, approximately 300 -

700%

iii) Illite Intermediate water absorption

Page 33: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 33

“Specific surface” = grain area/grain mass

TYPE OF

SOIL

SPECIFIC SURFACE

(m2/g)

Kaolin 80

Glauconite 400

Black earth 440 - 990

Bentonite 1300 - 1390

Page 34: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 34

The influence of charges

“The greater the surface area, the

greater the charge”

− the greater the affinity for water

− some water strongly adsorbed in a very

thin layer

− other water “free” in the soil “pores”

Electrostatic forces give rise to

COHESION in soils with clay minerals

Page 35: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 35

Uses of Kaolinite

Ceramics (China clay)

Filler for paint, rubber & plastics

Glossy paper production

Page 36: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 36

Uses of Montmorillonite The “Smectite” group

facial powder (talc)

filler for paints & rubbers

an electrical, heat & acid resistant porcelain

plasticizer in moulding sands

drilling muds

repairing leaking farm dams

Page 37: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 37

In Summary

1. The basic building blocks of clays are small

2. Si, O, H and Al are the chief ingredients

3. Tetrahedral & octahedral sheets possible

4. Different combinations of sheets form the basic

micelles of clay minerals

5. Clay mineral properties vary due to the nature of

bonding of the sheets between micelles

Page 38: The+clay+minerals+2007

DIVISION OF INFORMATION TECHNOLOGY, ENGINEERING AND THE ENVIRONMENT 38

Revision

• What is a clay micelle?

• Describe how a 1:1 clay mineral is formed

• How does the Mica group of clay minerals differ from the 1:1 clay minerals?


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