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ThyssenKrupp Uhde‘s commercially provenPRENFLO® and HTWTM Gasification TechnologiesHalle (Saale), June 13, 2013
Claudio Marsico – Director Sales – Gas Technologies Division
2. ibi Fachsymposium
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 2Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 3Copyright TK Uhde 2012
ThyssenKrupp Group
ThyssenKrupp AG
Steel Europe
Elevator Technology
Industrial Solutions
Components Technology
Workforce: ~150,000
Material Services
TK Fördertechnik
Marine Systems
TK Polysius
TK Uhde
vereinfacht, vorläufig
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 4Copyright TK Uhde 2012
From the idea to operation of a chemical plant
Operation and service phase
Project implementation phase
Training of operating personnelPlant maintenance and operation
Materials management and spare partsPlant optimisation and upgrading
Licence award or procurementBasic / detail engineering
Procurement / inspection / shippingProject execution
ConstructionCommissioning
Project development / market studyFeasibility study
Project financing
Concept development and assessmentExecution of R&D projects
Acquisition of technologies / companies
Research phase
Bid phase
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 5Copyright TK Uhde 2012
Site-SeeingMore than 2.000 plants built by Uhde on all continents
130 plants
115 plants375 plants120 plants
105 plants500 plants150 plants
Fertilisers RefineriesNitric acid Aromatics185 plants 380 plants 75 plants
Org. Chemicals/petrochemicalsHydrogen, ammonia, methanol Plastics, synthetic fibres Polyester / polyamides400 plants
Electrolysis Coke Plant Technologies Tank storage facilities Industrial plants150 plants
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 6Copyright TK Uhde 2012
Overview of our Product divisions
ElectrolysisAmmonia &Urea
Hydrogen &Nitrates
RefiningTechnologies
Org. Chemicals/PolymersGas Technologies Polyester Coke Plant
Technologies
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 7Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 8Copyright TK Uhde 2012
fossil fuel prices
fossil fuel availability
proven technology
clean technology
polygeneration
CCS
sellable by-productsfossil fuel flexibility ideal for low rank fuel
Feedstock Technology Product
Market drivers for gasification of solids
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 9Copyright TK Uhde 2012
Energy reserves (Giga tons, oil equivalent)
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 10Copyright TK Uhde 2012
Synthesis Gas as a Central Part of Uhde‘s Process ChainGasification: Feedstock - Process - Product
Gas, Naphtha
Oil/Residues
SteamReformer/ ATR
SteamReformer/ ATR
HTWGasificationHTWGasification
Synthesis Gas
CO +H2
Synthesis Gas
CO +H2
Methanol
Ammonia
Power Plant(IGCC)
FischerTropschSynthesis
CO-Conversion
Methanation
DieselDiesel
Petrol + LPGPetrol + LPG
Urea
Diesel, NaphthaDiesel, Naphtha
PetroleumCoke
Hard Coal
Biomass
PRENFLOGasificationPRENFLOGasification
Biomass
Brown Coal
Waste
LubricantsLubricants
MTO
MTG
Feedstock Gasification Syngas ProductFurther processing
HydrogenHydrogen
SyntheticNaturalGasSyntheticNaturalGas
ElectricityElectricity
FertilizerFertilizer
Oil GasificationOil Gasification
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 11Copyright TK Uhde 2012
PRENFLOPSG, PDQ
entrained-flow gasification
HTW (High Temperature Winkler)fluidized-bed gasification
Various Materials require various Gasification Technologies Uhde‘s Gasification Portfolio
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 12Copyright TK Uhde 2012
Gasification Technologies
550 °C 1350 – 1600 °C800 – 1100 °C
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 13Copyright TK Uhde 2012
Uhde‘s Gasifiers
PSG PDQ HTWEntrained-flow gasification Fluidized bed gasification
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 14Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 15Copyright TK Uhde 2012
PRENFLO burner test rig6 t/d (450 m³n/h syngas)
PRENFLO Fürstenhausen48 t/d (3,500 m³n/h syngas)
PRENFLO Puertollano 2,400 t/d (180,000 m³n/h syngas)
Start Up: 1984
Start Up: 1985
Start Up: 1998
Scale Up Factor:8
Scale Up Factor:50
Koppers-TotzekStart of development 1941
57 yearsShell-Koppers pilot plant Hamburg150 t/d coal
Start Up: 1978
DevelopmentsFrom Koppers-Totzek to PRENFLO
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 16Copyright TK Uhde 2012
Koppers-Totzek gasification plant in Modderfontein, S. Africa(Design capacity: 1,000 t/d of ammonia)
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 17Copyright TK Uhde 2012
Koppers-Totzek gasification plant in India(Capacity: 900 t/d of ammonia)
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 18Copyright TK Uhde 2012
Features• dry coal/petcoke powder
feed• 4 horizontal co-annular
burners• membrane wall• waste heat boiler (PSG)
PRENFLO with Steam Generation (PSG)1000 MWth, 40 bar
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 19Copyright TK Uhde 2012
PRENFLO Plant in Fürstenhausen, Germany
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 20Copyright TK Uhde 2012
ELCOGAS IGCC plant: Gasification Island, Spain
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 21Copyright TK Uhde 2012
Dry-fed, single train IGCC with CCS Pilot Plant at Elcogas, Spain300 MW net based on petcoke / coal feedstock
PRENFLO Gasification
Gas Treatment
Coal PreparationASU
CombinedCycle
New CO2 capturePilot Plant
implemented
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 22Copyright TK Uhde 2012
Features• dry coal/petcoke powder
feed• 4 horizontal co-annular
burners• membrane wall• direct water quench
PRENFLO with Direct Quench (PDQ)1000 MWth, 40 bar
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 23Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 24Copyright TK Uhde 2012
Start Up: 1988
HTW-Peat Gasification, Kemira
HTW- Pilot PlantRheinbraun Wachtberg40 t/d Lignite, 10 bar
HTW- Demonstration PlantRheinbraun Berrenrath720 t/d Lignite, 10 bar
KoBra IGCC RWE, Hürth3700 t/d Lignite 27 bar
Start Up: 1978
Start Up: 1986
Engineering: 1994
Scale Up Factor:18
Scale Up Factor:5
Atmospheric Winkler generators1956 – 1964 260 t/d Lignite
>20 Years
HTW Laboratory PlantRWTH-Aachen12 t/d Coal, Atm.
Start Up: 1974
HTW-Pilot Plant (WVW)Rheinbraun Wesseling185 t/d Lignite, 25 bar
Start Up: 1989
DevelopmentsThe HTW Process
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 25Copyright TK Uhde 2012
HTW High Temperature Winkler - Gasifier
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 26Copyright TK Uhde 2012
HTW- Laboratory Plant (PDU)RWTH Aachenapprox. 50 kg/h1974
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 27Copyright TK Uhde 2012
HTW Pilot PlantRWE-Plant-WachtbergFrechen / Germany1,6 t/h1978 - 1985
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 28Copyright TK Uhde 2012
HTW PlantWVW- UK-WesselingWesseling / Germany7,7 t/h Lignite10 – 25 bar1988 - 1990
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 29Copyright TK Uhde 2012
HTW Syngas PlantKemira OyOulu / Finnland30 t/h Peat≈ 300 t/d NH3
1988 - 1991
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 30Copyright TK Uhde 2012
25 t/h dried lignite – 140 MWth34,000 m³/h of syngas≈ 300 t/d Methanol67,000 total operating hours84 % availability (last 10 years) 1986 - 1997
HTW Commercial Scale Demo PlantBerrenrath/Germany
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 31Copyright TK Uhde 2012
KoBra - Engineering 1993 - 1994
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 32Copyright TK Uhde 2012
HTW-Precon-GasificationNiihama / Japan48 t/d Municipal Waste1999 - 2002
Sumitomo Heavy Industries Ltd.
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 33Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 34Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaCoal-to-Gasoline (CTG) plant *
*) Photo Courtesy TransgasDevelopment
#1 coal preparation
#2 coal gasification
#3 CO-shift reactor
#4 acid gas removal
#5 methanol synthesis #6 methanol-to-gasoline #7 gasoline storage
PRENFLO PDQ gasifiers
ApplyingTK Uhde‘s PRENFLOGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 35Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaPresentation of Feasibility Study
Ulaanbaatar, Mongolia, June, 2008
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 36Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaMongolia and Germany sign co-operation agreement
CTL project is of strategic importance
Ulaanbaatar, Mongolia, October, 2011
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 37Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaSigning of agreement between Gov’t of Mongolia andTK Uhde in presence of Mongolian President Elbegdorj
ThyssenKrupp Schloss Landsberg, Essen, Germany, March 31, 2012
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 38Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaSigning of PRENFLO licence agreement between ICM andTK Uhde in presence of Mongolian President Elbegdorj
ThyssenKrupp Schloss Landsberg, Essen, Germany, March 31, 2012
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 39Copyright TK Uhde 2012
ICM‘s 18,000 bbl/d CTL Plant in MongoliaMinister Battulga at ThyssenKrupp’s Reference Plant
Elcogas, Puertollano, Spain, April 08, 2013
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 40Copyright TK Uhde 2012
JAM Project in China – Commissioning in 2009Converting Coal into Gasoline
Pilot Plant100,000 tpa of gasoline
Commercial Plant1,000,000 tpa of gasoline
Basic Engg. for MTG concluded
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 41Copyright TK Uhde 2012
TransGas Coal-to-Liquids complex (18,000 bbl/d)PRENFLO with MTG based on coal
Mingo County, West Virginia
ApplyingTK Uhde‘s PRENFLOGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 42Copyright TK Uhde 2012
TransGas Coal-to-Liquids complex (18,000 bbl/d) Ground Breaking Ceremony, 09 May 2011, West VirginiaPlant Site
U.S. Senator Joe Manchin III. and WV Governor Earl Ray Tomblin
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 43Copyright TK Uhde 2012
TargetDevelopment and commercialisation of integrated process chain for production of 2nd generation biofuels
UhdeTotal
CEAIFP
Sofi-proteol
Axens
BioTfueL – integrated process chainPRENFLO with FT based on solid and liquid feedstock
ApplyingTK Uhde‘s PRENFLOGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 44Copyright TK Uhde 2012
Life-cycle analysis for optimum equilibrium between technical-economicalperformance and environmental demands
Coal
Petcoke
Wood
Straw etc.
Feedstock Pretreatment Gasification Gas Treatment
Milling
Torrefaction CO-Shift
Synthesis
GaselTM
Fischer-Tropsch
Synthesis and Product
Upgrading
Biodiesel; BiokeroseneAGR
Liquid Residues
BioTfueL – integrated process chainPRENFLO with FT based on solid and liquid feedstock
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 45Copyright TK Uhde 2012
SGCE – 9,500 bpd CTL, MozambiquePRENFLO PDQ for high-ash coal
ApplyingTK Uhde‘s PRENFLOGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 46Copyright TK Uhde 2012
Biomass-to-Methanol Plant, Hagfors / Värmland / SwedenArtist View
Photo courtesy VärmlandsMetanol AB
ApplyingTK Uhde‘s HTWGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 47Copyright TK Uhde 2012
C.GEN – 450 MWe IGCC with CCS, Killingholme, UKPRENFLO PDQ selected
Optional hydrogen production
Carbon capture & storage
Synergies due tomaximum integrationinto existingindustrial network
High level ofstandardization –beneficial for futureplants
Feedstock: hard coal,petcoke and biomass
ApplyingTK Uhde‘s PRENFLOGasification Technology
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 48Copyright TK Uhde 2012
Alliancesand to co-operate in the field of coal gasification
JV KEPCO-Uhde Inc. founded in July 2011 in Seoul, South Korea
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 49Copyright TK Uhde 2012
Alliancesin the field of Coal-to-Liquids
A) Coal-to-GASOLINE via Methanol (MTG)
B) Coal-to-DIESEL via Fischer-Tropsch
+
+
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 50Copyright TK Uhde 2012
Co-operationsLessons learnt from operators
A) PRENFLO entrained-flow Gasification Technology
B) HTW fluidised-bed Gasification Technology
+
+
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 51Copyright TK Uhde 2012
ThyssenKrupp and Uhde
Uhde‘s experience and expertise in gasification
PRENFLO (PSG / PDQ)
High Temperature Winkler (HTW)
Updates on Projects and Alliances
Presentation Outline
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 52Copyright TK Uhde 2012
Gasification is a proven technology, a vast number of gasifiers are operating since decades successfully on commercial basisGasification allows flexibility in feedstock and polygenerationof productsGasification is environmental friendly
Uhde has more than 70 years of experience in gasification based on 8 different gasification technologies… received more than 100 contract awards for gasifiers
… has proven single sourcing capability
… has built the world‘s largest solid fuel based, single train IGCC
… is a process oriented EPC contractor and not only licensor
… has built more than 2,000 plants worldwide
Summary
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 53Copyright TK Uhde 2012
Gasification Uhde „Site“-SeeingKoppers-Totzek gasificationModderfontein, South Africacoal-to-ammonia/fertilisers
GE (Texaco) coal gasificationOberhausen, Germanycoal-to-hydrogen & oxochemicals
HTW coal gasificationBerrenrath, Germanycoal-to-methanol
PRENFLO coal gasificationFürtenhausen, Germanycoal-to-methanol
PRENFLO IGCCPuertollano, Spainpetcoke/coal-to-power
HTW MSW gasificationNiihama, Japanwaste-to-energy
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 54Copyright TK Uhde 2012
SummaryUhde is Technology Provider and EPC Contractor
2. ibi FachsymposiumJune 13, 2013 – Halle (Saale) – Page 55Copyright TK Uhde 2012
PRENFLO IGCC, Puertollano, SpainSummer 2013
Thank you for your attentionThank you for your attention