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Tunnel Effect &AFM-STM

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    What is Quantum Tunneling?

    At the quantum level, matter has

    corpuscular and wave-like properties

    Tunneling can only be explained by the

    wave nature of matter as described byquantum mechanics

    Classically, when a particle is incident

    on a barrier of greater energy than the

    particle, reflection occurs

    When described as a wave, the

    particle has a probability of existing

    within the barrier region, and even on

    the other side of it

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    2

    Tunnel effect

    .

    The above equation shows that T can be

    nonzero i.e, there is a finite probability of finding

    particle in region III.

    )(2where

    EUmC

    CLeT 2_

    An approximate expression for the transmission

    coefficient, when T

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    3

    Quantum tunnelling was first used to explain

    alpha decay. Alpha particles coming out of thenucleus have energy of 4-5 MeV, still they cantunnel out from the nucleus with bindingenergy of the order 25 MeV.

    However the probability of emission of analpha particle is 1 in 1038events. In a tunnel

    diode, the charge carriers tunnel through thepotential barrier (depletion layer). Quantumtunnelling has found many applications invarious fields.

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    Quantum tunnelling (Tunnel effect)

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    STM

    The Scanning Tunneling Microscope was invented in 1981 byGerd Binnig and Heinrich Rohrer

    When a metal tip, usually made of tungsten or platinum-

    iridium, is brought within .4-.7nm of the sample, electrons

    tunnel across the gap and create a current in the tip

    This current is then fed to a computer and used to generate an

    image of the atomic surface of the sample

    At this distance the coulomb force between the tip and an

    atom of the sample is actually enough to move the atom

    This has allowed physicists to create images and structures on

    the atomic level

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    STM : Scanning tunnelling Microscope

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    STM

    1

    Scanning tunnelling microscope: A scanningtunnelling microscope (STM) is an instrument for

    imaging surfaces at the atomic level.

    It was developed in 1981 by Gerd-Binnig andHeinrich-Rohrer (at IBM Zrich), and for their

    invention they got the Nobel Prize in Physics in

    1986.

    The basic principle behind an STM is quantum

    tunnelling.

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    2 When a conducting tip is brought near to the

    sample surface, a bias voltage applied betweenthe two can allow electrons to tunnel through

    the vacuum between them.

    The resulting tunnelling current is a function oftip position, applied voltage, and electronic

    nature of the sample.

    Information is acquired by monitoring the

    current as the tip's position scans across the

    surface, and is usually displayed in image form.

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    3

    STM requires extremely clean and stable

    surfaces, sharp tips, excellent vibration control,and sophisticated electronics.

    The tip is scanned over the surface using apiezoelectric probe. Using STM individual atoms

    can be imaged and manipulated.

    For a current to flow the substrate beingscanned must be conductive. Insulators cannot

    be scanned through the STM. STM has become a very important tool in

    research and technology development at thenano-scale.

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    Scanning Tunnelling Microscope

    Tungsten STM tip(photo taken with an SEM)

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    STM Images

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    AFM

    1

    Atomic force microscope (AFM):The atomicforce microscope (AFM) is a very powerful

    microscope invented by Binnig, Quate and

    Gerber in 1986.

    Besides imaging at the atomic level it is also

    one of the foremost tools for the manipulation

    of matter at the nanoscale.

    The AFM consists of a cantilever with a sharp

    tip (probe) at its end that is used to scan the

    specimen surface.

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    2

    AFM:The cantilever is typically silicon or silicon nitride

    with a tip radius of curvature on the order of

    nanometers.

    When the tip is brought near the sample surface,

    forces between the tip and the sample lead to a

    deflection of the cantilever according to Hooke'slaw.

    The deflection is measured using a laser spot

    reflected from the top surface of the cantilever into

    an array of photodiodes.

    Currently AFM is the most common form of

    scanning probe microscopy

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    AFM

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    AFM- Working Principle

    The AFM brings a probe inclose proximity to thesurface

    The force is detected by the

    deflection of a spring,usually a cantilever (divingboard)

    Forces between the probe

    tip and the sample aresensed to control thedistance between the thetip and the sample.

    van der Waals force curve

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    Two Modes

    Repulsive (contact)

    At short probe-sample distances,

    the forces are repulsive

    Attractive Force (non-contact)

    At large probe-sample distances,the forces are attractive

    The AFM cantelever can be used to

    measure both attractive force

    mode and repulsive forces.

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    AFM Examples

    View of Silicon Surface Reconstruction

    Carbon Nanotube Used as a Conducting

    AFM Tip for Local Oxidation of Si.


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