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Turbidity vs TSS

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Why is Quantifying Suspend Solids Important? The concentration of total suspended solids (TSS) is important to both river and lake ecosystems for ecolog and water quality reasons. Inorganic suspended solids attenuate light, primarily through the proces scattering. High concentrations of suspended solids degrade optical water quality by reducing water clarity decreasing light available to support photosynthesis. Suspended solids have been shown to alter pred prey relationships (for example turbid water might make it difficult for fish to see their prey (e.g., insec Suspended solids also influence metabolic activity and provide surface area for the sorption and transport o array of constituents. Deposited solids alter streambed properties and aquatic h abitat for fish, macrophy and benthic organisms. Deposited sediment may be available for resuspension and subsequent trans during periods of increased stream discharge Suspended solids in most freshwater systems originate f watershed sources, pollutant point sources, and sediment resuspension. More rarely other sources, suc hydrogeologic structures can be important. High stream total suspended solids can impact water quality deposition in downstream lakes and reservoirs. How Can Suspended Solids Be Measured Remotely? Suspended solids concentrations are highly variable in most streams. Characterization and quantification of variability is critical to accurately assess TSS impacts on aquatic systems, including the development of m loading estimates. Large increases in TSS and TSS loading (TSS L ) are widely observed in streams du runoff events. This often results in a large portion of the total TSS L being delivered during relatively interval s of high flow. Frequent measurements of flo w are widely availab le from USGS (United St Department of the Interior U.S. Geological Survey) gauging stations, but practical limitations in sampling h generally limited the frequency of TSS data. System-specific empirical relationships between TSS and flow have been widely developed and utilize estimate TSS L as a function of flow. However, a number of authors have discussed the accuracy limitations of TSS-flow relationships in predicting TSS L . The success of T SS-flow relationshi ps in predic TSS L depends strongly on the scatter around the best-fit regression line. Increased frequency of sampling, with an emphasis on coverage of runoff events, has been shown to result in stronger SS- relationship s and thereby increase the precision of TSSL estimates. However, manual event based samp and the associated laboratory analyses are tedious and costly. Even with the aid of automated samp equipment, laboratory demands continue to limit such a monitoring program.  An alternative approach to estimate stream TSS L is based on frequent monitoring of turbidity that is hi correlated to TSS. This may have distinct advantages if the associated temporal coverage benefits ( deployed instrumentation for in situ measurements) more than compensate for the uncertainty in relationship between TSS and turbidity (Tn). Relationships between TSS and Tn are expected to be impe and system-specific because of variations in composition and particle size distributions that influence m concentration and light scattering differ ently. Yet the TSS-Tn relationship is stronger than the TSS- relationship in most cases. The approach of turbidity measurements as a surrogate of T SS has at least advantages:
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Why is Quantifying Suspend Solids Important?

The concentration of total suspended solids (TSS) is important to both river and lake ecosystems foand water quality reasons. Inorganic suspended solids attenuate light, primarily through the scattering. High concentrations of suspended solids degrade optical water quality by reducing watedecreasing light available to support photosynthesis. Suspended solids have been shown to alt

prey relationships (for example turbid water might make it difficult for fish to see their prey (e.gSuspended solids also influence metabolic activity and provide surface area for the sorption and tranarray of constituents. Deposited solids alter streambed properties and aquatic habitat for fish, mand benthic organisms. Deposited sediment may be available for resuspension and subsequeduring periods of increased stream discharge Suspended solids in most freshwater systems orwatershed sources, pollutant point sources, and sediment resuspension. More rarely other sourcehydrogeologic structures can be important. High stream total suspended solids can impact waterdeposition in downstream lakes and reservoirs.

How Can Suspended Solids Be Measured Remotely?

Suspended solids concentrations are highly variable in most streams. Characterization and quantific

variability is critical to accurately assess TSS impacts on aquatic systems, including the developmeloading estimates. Large increases in TSS and TSS loading (TSSL) are widely observed in strerunoff events. This often results in a large portion of the total TSSL being delivered during relintervals of high flow. Frequent measurements of flow are widely available from USGS (UnDepartment of the Interior U.S. Geological Survey) gauging stations, but practical limitations in samgenerally limited the frequency of TSS data.System-specific empirical relationships between TSS and flow have been widely developed andestimate TSSL as a function of flow. However, a number of authors have discussed the aclimitations of TSS-flow relationships in predicting TSSL. The success of TSS-flow relationships iTSSL depends strongly on the scatter around the best-fit regression line. Increased frequensampling, with an emphasis on coverage of runoff events, has been shown to result in strongrelationships and thereby increase the precision of TSSL estimates. However, manual event baseand the associated laboratory analyses are tedious and costly. Even with the aid of automate

equipment, laboratory demands continue to limit such a monitoring program.  An alternative approach to estimate stream TSSL is based on frequent monitoring of turbidity thcorrelated to TSS. This may have distinct advantages if the associated temporal coverage bedeployed instrumentation for in situ measurements) more than compensate for the uncertarelationship between TSS and turbidity (Tn). Relationships between TSS and Tn are expected to band system-specific because of variations in composition and particle size distributions that influconcentration and light scattering differently. Yet the TSS-Tn relationship is stronger than threlationship in most cases. The approach of turbidity measurements as a surrogate of TSS has advantages:

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1. increased in situ measurement capabilities of deployable instrumentation can support rpatterns over short time scales that cannot reasonably be addressed by manual TSS-based p

2. an important feature of the optical impact of TSS (i.e., light attenuation), and often a primary concern, is measured.

Sampling Approach and Data Analysis

TSS-flow and TSS-Tn relationships were developed for the robotic monitoring platform (described heDorwin Avenue (see map) utilizing USGS flow measurements made concurrent with the robotic statiTSS measurements over the October 2003 through September 2004 period (USGS water year 2004Water samples were collected by an automated refrigerated sampler (ISCO® 6712). Samples weredaily during baseline conditions. The sampling frequency increased substantially for nine runoff eveto once every two hours. Adjustments in sampling frequency were made occasionally during storms remote commands. These samples were analyzed in the laboratory for Tn and TSS, and fixed (nosuspended solids (FSS). I n situ measurements of Tn and temperature (T) were made with the probedescribed here. Probe measurements were made every 15 minutes. A total of 23,905 Tn measuremmade by the robotic platform for the study period. Using data collected at the robotic platform, relatio

between TSS (units of mg/L), flow (Q) and turbidity (Tn) were developed in the form:TSS = A·Q

and 

TSS = C·Tnd The coefficients were determined using least-square regression over paired measurements. The coeare:

 A = 10.07, b = 1.12, C = 2.38, and d = 0.81.TSSL (units of metric tons (1000 kg) per hour) is calculated from the product of flow and calculated T

Results

Data collected at the robotic platform (including USGS flow data) are used to generate time-series p

and TSSL. Additionally, cumulative loading (summation of TSSL over time) is presented. Lastly, twopresented to illustrate in (perhaps) meaningful units the amount of TSS passing through the Onondasystem. The first plot approximates the number of dump trucks (12 cubic yard) required to carry theThe second approximates the depth the sediment would measure if spread around the playing area football field. In these two analyses, the volume of the TSS is approximated by assuming density ofsuspended solids were 2 g/cm3.

Most recent loading estimates 

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Questions or Suggestions: [email protected] 

Last Modified: Tuesday, September 15, 2009

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