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Water Desalination Lecture 6 - NEW

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  • 1

  • Abbreviations

    1- TTDh Heater Terminal Temperature Difference. 2- TTDc = Condenser Terminal Temperature Difference.3- Tloss = temperature difference between brine and condensing vapor temperature.

  • To Simplify the Single Stage Flash in Mathematical Analysis, the following assumption must be considered :

    1-Specific heat at constant pressure(Cp) = 4.18 kJ/kg C.

    2- The overall heat transfer coefficient Uh = Uc = 2 KW/m2 c

    3- Neglect the Steam Sub-cooling and super heating

    4-Neglect all heat losses

    5- Xp zero ( Salt Free)

  • 1- Mf = Mb + Md

    2- Xf Mf = Xb Mb

  • 3,4) Ms s = Mf cp (To T1 ) = Uh Ah (LMTD)h

    Where :

    s : latent heat of steam

    Uh: heater overall heat transfer coefficient (KW/m2 C)

    Ah : Area of heater (m2)

    (LMTD)h : Logarithmic Mean Temperature Difference of heater

  • 5,6) Md v = (Mcw + Mf ) cp ( T1 Tcw )= Mf cp ( To Tb) = Uc Ac (LMTD)c

    Where :

    v : latent heat of Vapor

    Uc: overall heat transfer coefficient (KW/m2 c)

    Ac : Area of condenser (m2)

    (LMTD)c : Logarithmic Mean Temperature Difference of condenser

  • Where :

    (LMTD)h : Logarithmic Mean Temperature Difference of heater

    To: Top brine temperature

    Ts: Steam temperature

    (To T1)7) (LMTD)h =

    ln (Ts T1 )(Ts To )

  • Where :

    (LMTD)c : Logarithmic Mean Temperature Difference of condenser

    Tcw: cold water temperature

    Tv: vapor temperature

    (T1 Tcw)8) (LMTD)c =

    ln (Tv Tcw)(Tv T1 )

  • Where :

    PR : Performance Ratio

    s : steam latent heat

    v : vapor latent heat

    Md s Mf cp (To Tb ) s (To Tb ) 9) PR = = =

    Ms v Mf cp (To T1 ) v (To T1 )

  • 10) Tst = To - Tb

    11) To T1 = Tst + T loss+ TTDcWhere :

    TTDc : Condenser Terminal Temperature Difference

    Tloss : Thermodynamic losses

    Tst : stage temperature drop

  • C

  • Given

    To : Top brine temperature = 90c Tb: Temperature of reject brine= 40 C

    Tcw : cold water temperature = 30cTs : Steam temperature = 100c

    s : steam latent heat = 2256 kJ/kg (at 100 C)

    v : vapor latent heat = 2412.5 kJ/kg (at 38 C)

    Xf : The salinity of intake seawater = 42,000 ppm

    TTDc : The condenser terminal temperature difference = 3c

    T loss : Thermodynamic loss = 2c

  • Required

    Performance Ratio

    Salinity of brine

    Area of heater (m2)

    Area of condenser (m2)

    PR

    Mf/ Md

    Mcw / Md

    Xb

    Ah

    Qin / Md

    Ac

    specific flow rate of the cooling water

    specific flow rates of feed seawater

  • Solution

    Tst = To - Tb = 90 - 40 = 50CTTDh = Ts To= 100 - 90 = 10CTv = Tb - Tloss = 40 - 2 = 38Cv = 2412.5 kJ/kg (at 38

    oC)s = 2256 kJ/kg (at 100

    oC)

    (s)(Tst )

    PR =

    (Tst + Tloss +TTDc) (v)

    = ((2256) (50)) /((50+2+3)(2412.5))= 0.85 kg distillate/kg steam

  • Solution

    Md v = Mf Cp TstMf/Md = v /(Cp (Tst ))

    = 2412.5/((4.18)(50)) = 11.54 kg feed seawater/kg distillate

    Md v = (Mf+Mcw) Cp (To- Tst - Tloss-TTDc-Tcw)Mcw/Md = v(Cp (To- Tst -Tloss-TTDc-Tcw)) - (Mf/Md)

    = (2412.5)/((4.18)(90-50-2-3-30)) - 11.54 = 103.9 kg cooling seawater/kg distillate

    Mb = 11.54 - 1 = 10.54 kg brine/kg distillateXb = Xf Mf/Mb = (42000) (11.54)/(10.54) = 45984.8 ppm

  • Solution

    ((Ms) s))

    Ah/Md =

    ((Md)(Uh)(LMTD)h)

    = 2256/((0.85)(2)(29.4))

    = 45.1 m2/(kg/s)

    (LMTD)h = Tst + Tloss + TTDc

    ln (( TTDh + Tst + Tloss + TTDc) / TTDh )

    = (50+2+3) / ln((10+50+3+2)/(10))

    = 29.4 oC

  • Solution

    Ac/Md = v /((Uc)(LMTD)c)

    = 2412.5/((2)(17.4))= 69.3 m2/(kg/s)

    Qin /Md = Ms .s/Md

    = 50/ln((50+3)/3)= 17.4 C

    Tstln((Tst +TTDc)/(TTDc))

    = 2256/.85 = 2654.11 kJ/ kg distilled water

    (LMTD)c =

  • This method is a great improvement in the single stage flush

    The same process as single stage flush. The process is repeated several time and It recommend with the

    same temperature difference

    The target is to decrease the amount of energy stored in the steam so the process dont need to be cooled.

    So the maximum efficiency increased.

  • 1) Md v = Mf cp (To Tn )= Mf cp n. Tst

    Where :v: latent heat of vapor @ ( T = (To + Tb )/2 )Md : MdiTo Tb : n Tst

    As :n :is the number of stagesTst :is the average temperature difference of stage (recommended to be the same difference).

  • Required

    Performance Ratio

    Salinity of brine

    Area of heater (m2)

    Area of condenser (m2)

    PR

    Mp / Md

    Xb

    Ah / Md

    Ac / Md

    specific flow rates of feed seawater

  • Tst = (To Tn ) / 23 = (90-40)/23 = 2.174 C

    Taverage = (To + Tn ) / 2 = (90+40)/2 = 65C

    v = 2346 kJ/kg

    (n Tst )sPR =

    (Tst + Tloss + TTDc ) v= (23)(2.174)(2256)/((2.174+2+3)(2346.5))

    = 6.7 kg distillate water/kg steam

    Solution

  • Solution

  • Solution

    Xb = Mf .Xf /Mb = (42000) (11.22)/(10.22) = 46,126 ppm

    Mf/Md = v/(Cp(To - Tb))

    = 2346.5/((4.18)(90-40))= 11.22 kg intake seawater/kg distillate

    Mb/Md = 11.22 - 1 = 10.22 kg/kg distillate

    The specific feed flow rate is

  • Solution

    = (2.174+2+3)/ln((10+2.174+2+3)/(10))

    = 13.27 C

    Ah / Md = Ms s / (Md Uh (LMTD)h

    = 2256/((6.7)(2)(13.27))

    = 12.7 m2/(kg/s)

    (LMTD)h = Tst + Tloss + TTDc

    ln (( TTDh + Tst + Tloss + TTDc) / TTDh )

  • Solution

    (LMTD)c = (T st ) / ln (T st + TTDc )/(TTDc))

    = 2.174/ln((2.174+3)/3) = 3.98 C

    Ac / Md = Mf Cp Tst / (Uc (LMTD)c )=(11.22)(4.18)(2.174)/((2)(3.98))

    = 12.8 m2/(kg/s distilled water)

    Total area = Ah + n Ac = 307.1 m2

  • Conclusion:. Single stage once through type is more efficient and more

    economical in energy consumption.. Single stage once through type is more suitable for

    environment.. Single stage once through type need more area to be

    executed.

  • Until now we have discussed two different types of waterdistillation (the single stage flash, and the single through multistage flashing) accompanied with a proper Thermodynamicsanalysis of the systems.

    In this section we will discuss a third type of multi stageflashing which is MSF with brine mixing, and by the end ofreading this lecture you should:

    1. Know the theory of operation of this type2. Spot the advantages and disadvantages of this type.3. Understand the thermodynamics analysis of this type.4. Compare between the three types with respect to (PR)

    and total Area.

  • productSteam in

    Steam Out(Condensate)

    Reject

    Feed water

    Bri

    ne

    to

    be

    m

    ixe

    d

    (schematic diagram of MSF with brine mixing)

  • According to previous figure:

    It is a basic MSF except that a portion of a mass of a value equalto (Mr Mf) was taken from the exiting brine with temperature of(Tb) to be mixed with the entering feed water having the mass(Mf) & temperature (Tcw) raising its temperature to (Tr) butincreasing its salinity as well.

    After the mixing process, the steps are the same as any MSFdistillation process.

  • What is its idea?It is simply based on the idea of making a use of the brine

    outcome by recirculating a portion of it in the MSF cycle , thusmaking use of its thermal energy instead of throwing it away.

    Why do we insert a saline solution back into the system ?In this type of desalination it is acceptable to do so -as long as

    we are operating within the predetermined limitations (salinity up to70,000 ppm)- because we are using thermal energy to extract freshwater by means of evaporation and condensation.

  • What happens if we exceeded the 70,000 ppm limit?This will cause the following problems in the cycle:

    1. Will cause excessive fouling and scaling throughout the system.2. Decreases the overall efficiency.3. The resulting reject could have huge impacts on the environment, which

    would require more handling.

    What is the purpose of using brine recirculation (Adv.)?1. Decreasing the feed water flow rate which decreases the amount of the pre-

    treatment required for the feed water.2. Improving the thermal efficiency of the cycle by recirculating the brine which

    has higher thermal energy than feed water, instead of throwing it away.3. Decreasing the amount of brine water exiting the system.

  • What are the main disadvantages of using brine recirculation?1. Due to excessive salinity the system requires frequent cleaning and maintenance in order to prevent scaling.2. Requires larger area.

  • 1. By applying mass balance to the whole system we get,

    M = Mb + Md .. . Equation ( 1 )

    2. By applying salinity balance on the whole system we get,

    M . X = Mb . Xb + Md . Xd

    ( Xd ) assumed to be zero, due to its very small value Therefore,

    M . X = Mb . Xb .. . Equation ( 2 )

  • From ( 1 ) and (2 ):

    X (Mb + Md ) = Mb . XbMd . X = Mb ( Xb - X )

    XMb = . Md .. . Equation (3 )

    Xb - X Where,

    Mb is the mass flow rate of brine.Md is the mass flow of distilled water.X , Xb are the salinity of both feed and distilled water respectively.

  • (Figure 2)

    4,5. By applying energy balance on the heater ( figure 2 )we get,

    Ms . s = Mr . Cp . (To - T1 )

    Md . v = Mr . Cp . (To - Tb)

    . Equation ( 4 )

    . Equation ( 5 )

  • 6. And from previous lecture we could deduce that,

    Md (To - Tb ) . sPR = = .. . Equation ( 6 )

    Ms (To - T1 ) . v

    Note: the performance ratio may be considered as a measure of efficiency.

    . Equation (7)

  • Figure(8.4)

  • Step 1: Analyzing the given information and requirements

    Given:

  • Required to find:

  • . From equation ( 8.3 ), get the mass of exiting brine :

    ( X ) * ( Md )Mb=

    ( Xb Xf )( 42000 ) * ( 1 )

    Mb= ( 70000 42000 )

    Mb = 1.5 Kg/S

    . And From equation ( 8.1 ), We could get the mass of entering water:Mf = Mb + Md

    Mf = 1+ 1.5 = 2.5 Kg/S

  • . Knowing the value of PR ( from equation 8.4 ), get the values ofMs & T1 , or do energy balance for the heater to get T1:

    Md 1PR = 8 =

    Ms Ms

    Therefore, Ms = 0.125 Kg/S

  • PR=Md/Ms=8, and Md=1 kg/s then Ms=0.125 kg/s

    For the heater we have ,

    ( Ms ) * ( s ) = ( Mr ) * ( Cp ) * ( To T1 )

    ( 0.125 ) * ( 2200 ) = ( 17.942 ) * ( 4.18 ) * ( 90 T1 )

    Which gives out that T1 = 86.66 cwe had deduced that,

    Md (To - Tb ) . sPR = = =8 .. . Equation ( 6 )

    Ms (To - T1 ) . v

    Then Tb = 60.8 deg C

    Also, To-N.Tst=Tb

    Then Tb = 90 23 * Tst then Tst =1.3 deg C

  • . And we know that,( Md ) * ( v )

    Mr * cp =(To - Tb )

    . Then,( 1 ) * ( 2400 )

    Mr * 4.18 =( 90 60.8 )

    Therefore, Mr = 17.942 Kg/S

    ( Md ) * ( Xf ) + ( Mr Mf ) * Xb = ( Mr )* ( Xr )

    Therefore, Xr = 66098 PPM

  • .

    . LMTDh =

    . LMTDh = =12.93C

    . LMTDc = =

    then, LMTDc= 3.65C

  • last step area calculationAcondenser*Uc*LMTDC=Mr*CP*TstageAcondenser*2*3.65=17.942*4.18*1.3then

    Acondencer= 14 m2

    Aheater*Uh*LMTDh=Ms*sAheater*2*12.93=0.125*2200then

    Aheater=10.634 m2

  • Type SSFMSF once through

    MSF with brine

    mixing

    PR 0.67 6.7 8

    Total Area (m^2)

    105 302 332

    This table has a great significance, since it means that we have improved the PR but it with accompanied by size issues (increased size ).

  • In this type we utilized the useful thermal energy going out with the reject, thus maximizing the PR values, and increasing the recovered water amount.

    The increase in the PR values is accompanied with an increase in total area.

    Frequent maintenance and cleaning is a must with this type of distillation to prevent fouling or scaling that may occur due to the high percentage of salinity.

    The maximum allowable amount of salinity to be recirculated is about 70,000 ppm.

    If the maximum value was exceeded, scaling and fouling will take place in the system, as well as an increase in the environmental impact of the reject.

  • 5858

    Item Details

    No. of Students per topic Three Students maximum

    Output Format Power Point + videos

    Equations editing To be written on equation editor; not photo

    Dead line 2nd & 9th of May, 2014

    Presentation 15-20 minutes maximum

    Deliverable form CD including the presentation

    Topic 1 Using CFD in Desalination

    1. Finite difference and finite element

    2. Main Boiling Equations and solution assumptions

    3. Main Flush Equations and solution assumptions

    4. Main Flush Equations and solution assumptions

    5. Main salt separation Equations and solution assumptions

  • 5959

    Item Details

    Topic 2 Methods of Humidification and Dehumidification Desalination

    1. Open Air Open Water Systems

    2. Open Air Closed Water Systems

    3. Closed Air Open Water Systems

    Topic 3 Hybrid Solar Energy and Desalination

    1. Available Arrangements

    2. Relevant calculations

    3. Case Studies with its calculations (minimum two cases)

    Topic 4 Hybrid Wind Energy and Desalination

    1. Available Arrangements

    2. Relevant calculations

    3. Case Studies with its calculations (minimum two cases)

  • 6060

    Item Details

    Topic 5 Hybrid Geothermal Energy and Desalination

    1. Available Arrangements

    2. Relevant calculations

    3. Case Studies with its calculations (minimum two cases)

    Topic 6 Arrangements of RO Membrane

    1. Available practical membranes specification with catalog cuts

    2. Arrangements of membranes (Series and Parallel)

    3. Case Studies with its calculations (minimum two cases)

    Topic 7 Full Design of MSF Plant

    1. Practical Arrangements (not schematic)

    2. Relevant calculations (Heat exchanger Fuel Steam -)

    3. Case Studies with its calculations (minimum two cases)

  • 6161

    Topic 1 Asmaa Ramadan El Sayed

    Ibrahim Gad El Haq

    Topic 2 Ahmed Mahmed Osman

    Wael Wadee

    Mohamed Fouad

    Topic 3 Ahmed Tarif

    Mohamed Bashir

    Waleed Mohamed

    Topic 4 ---------------------

    Topic 5 ---------------------

    Topic 6 Ashraf Hussein

    Mohamed Tarek

    Mohamed Hussein

    Topic 7 Mohamed Essam

    Mohamed Hamdy

    Aya Ahmed

  • 62

    62

  • 63


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