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Appendix A: Constants, Units,and Conversion Factors
See Tables A.1, A.2 and A.3
Table A.1 Physical constants
Universal gas constant Ru ¼ 8314:34 J/(kmol K)
Boltzmann constant kb ¼ 1:38054� 10�23 J/K
Stefan–Boltzmann constant rSB ¼ 5:67� 10�8 W/(m2 K4ÞAtmospheric pressure patm ¼ 1:013� 105 Pa
Gravitational acceleration g ¼ 9:807 m/s2
Table A.2 Prefixes
Factor Prefix Symbol Factor Prefix Symbol
1018 Exa E 10−1 Deci d
1015 Peta P 10−2 Centi c
1012 Tera T 10−3 Milli m
109 Giga G 10−6 Micro l
106 Mega M 10−9 Nano n
103 Kilo k 10−12 Pico p
102 Hecto h 10−15 Femto f
10 Deka da 10−18 Atto a
© Springer Nature Switzerland AG 2020A. Faghri and Y. Zhang, Fundamentals of MultiphaseHeat Transfer and Flow, https://doi.org/10.1007/978-3-030-22137-9
747
Table A.3 Conversion factors
Physical quantity Conversion factor
Acceleration ft/s2 0.30480 m/s2
m/s2 3.2808 ft/s2
Area ft2 0.092903 m2
cm2 0.15500 in2
m2 10.764 ft2
Density lbm/in3 1728.0 lbm/ft3
lbm/ft3 16.018 kg/m3
kg/m3 0.062428 lbm/ft3
g/m3 62.428 lbm/ft3
Energy Btu 1.0551 kJ
Btu 0.0002930 kW h
Btu 0.25200 kcal
ft lbf 0.0012851 Btu
kW h 3412.8 Btu
kcal 3.9683 Btu
kJ 0.94782 Btu
HP h 2544.4 Btu
Energy flux Btu/h ft2 3.1546 W/m2
kcal/h m2 0.36867 Btu/h ft2
cal/s cm2 13272.0 Btu/h ft2
W/cm2 3170.0 Btu/h ft2
W/m2 0.8598 kcal/h m2
W/m2 0.31700 Btu/h ft2
Enthalpy Btu/lbm 2324.4 J/kg
J/kg 0.00043021 Btu/lbm
Force lbf 32.1740 lbm ft/s2
lbf 4.448 N
kgf 2.2046 lbf
kgf 9.80665 N
N 0.22481 lbf
Heat transfercoefficient
Btu/h ft2 °F 5.6782 W/m2 K
kcal/h m2 °C 0.20482 Btu/h-ft2 °F
W/m2 K 0.17611 Btu/h-ft2 °F
W/m2 K 0.8598 kcal/h m2 °C
Kinematic viscosity (m)Thermal diffusivity (a)Mass diffusivity (D)
ft2/h 2.5807�10−5 m2/s
ft2/s 0.092905 m2/s
m2/s 10000 cm2/s (stokes)
m2/s 38750 ft2/h
m2/s 10.764 ft2/s
Length in 25.4 mm
ft 0.3048 m
in 0.08333 ft
mm 0.039370 in
m 3.2808 ft(continued)
748 Appendix A: Constants, Units, and Conversion Factors
Table A.3 (continued)
Physical quantity Conversion factor
Mass lbm 0.45359 kg
kg 2.2046 lbm
Mass flow rate lbm/h 0.45359 kg/h
lbm/s 3600 lbm/h
kg/s 7936.6 lbm/h
kg/h 2.2046 lbm/h
Power Btu/s 1.055 kW
Btu/h 0.293 W
W 3.412 Btu/h
W 9.48�10−4 Btu/s
HP 0.746 kW
HP 0.707 Btu/s
Pressure psi 6895 Pa
atm 1.013�105 Pa
atm 14.696 psi
bar 105 Pa
torr 1.000 mmHg
torr 133.32 Pa
psi 27.68 in H2O
ft-H2O 0.4335 psi
Specific heat, specific entropy Btu/lbm °F 4.1868 kJ/kg K
kcal/kg °C 1.000 Btu/lbm °F
kJ/kg K 0.23885 Btu/lbm °F
Temperature °F T(°C) = 5/9[T(°F) − 32] °C
°C T(°F) = 9/5 T(°C) + 32 °F
°C T(K) = T(°C) + 273.15 K
°F T(°R) = T(°F) + 459.67 °R
Thermal conductivity Btu/h ft °F 1.7307 W/m K
cal/cm s °C 418.68 W/m K
W/m K 0.5778 Btu/h ft °F
Velocity ft/s 0.30480 m/s
km/h 0.27778 m/s
mile/h 1.609 km/h
Viscosity kg/s m 1 N s/m2
posi 0.1 N s/m2
lbm/s ft 1.4882 N s/m2
lbm/h ft 4.1338�10−4 N s/m2
N s/m2 0.67195 lbm/s ft
N s/m2 2419.08 lbm/h ft
Volume L 1 dm3
L 0.001 m3
ft3 0.02832 m3
in3 16.39 cm3
yd3 0.7646 m3
m3 35.313 ft3
(continued)
Appendix A: Constants, Units, and Conversion Factors 749
Table A.3 (continued)
Physical quantity Conversion factor
Volume Gal (U.S.) 3.785 L
Gal (IMP) 4.546 L
Pint (U.S.) 0.4732 L
Pint (IMP) 0.5683 L
Volume flow rate ft3/min 4.7196�10−4 m3/s
ft3/s 0.0028318 m3/s
m3/s 2118.8 ft3/min
Volumetric heat generation rate Btu/h ft3 10.35 W/m3
W/m3 0.0966 Btu/h ft3
750 Appendix A: Constants, Units, and Conversion Factors
Appendix B: Transport Properties
List of Properties Tables
Table B.1 Air at 1 atm (Bergman and Lavine 2017)Table B.2 Carbon dioxide (CO2) at 1 atm (Bergman and Lavine 2017)Table B.3 Helium (He) at 1 atm (Bejan 2013)Table B.4 Hydrogen (H2) at 1 atm (Bergman and Lavine 2017)Table B.5 Nitrogen (N2) at 1 atm (Bergman and Lavine 2017)Table B.6 Oxygen (O2) at 1 atm (Bergman and Lavine 2017)Table B.7 Water (H2O) vapor at 1 atm (Bergman and Lavine 2017)Table B.8 Volume expansion coefficients for liquids (Mills and Coimbra 2015)Table B.9 Density and volume expansion coefficients of water (Mills and Coimbra 2015)Table B.10 AluminumTable B.11 Aluminum alloy, 2024-T6Table B.12 Cartridge brassTable B.13 CopperTable B.14 Fused silicaTable B.15 Inconel® X-750Table B.16 IronTable B.17 MolybdenumTable B.18 NickelTable B.19 NiobiumTable B.20 Plain carbon steelTable B.21 Stainless steel 304Table B.22 TantalumTable B.23 TitaniumTable B.24 TungstenTable B.25 Phase Change Materials (PCMs)Table B.26 Thermophysical properties at saturation for acetoneTable B.27 Thermophysical properties at saturation for ammoniaTable B.28 Thermophysical properties at saturation for cesiumTable B.29 Thermophysical properties at saturation for Dowtherm®
Table B.30 Thermophysical properties at saturation for ethaneTable B.31 Thermophysical properties at saturation for ethanolTable B.32 Thermophysical properties at saturation for Freon®-113Table B.33 Thermophysical properties at saturation for Freon®-123Table B.34 Thermophysical properties at saturation for Freon®-134a
© Springer Nature Switzerland AG 2020A. Faghri and Y. Zhang, Fundamentals of MultiphaseHeat Transfer and Flow, https://doi.org/10.1007/978-3-030-22137-9
751
Table B.35 Thermophysical properties at saturation for Freon®-21Table B.36 Thermophysical properties at saturation for Freon®-22Table B.37 Thermophysical properties at saturation for heliumTable B.38 Thermophysical properties at saturation for heptaneTable B.39 Thermophysical properties at saturation for leadTable B.40 Thermophysical properties at saturation for lithiumTable B.41 Thermophysical properties at saturation for mercuryTable B.42 Thermophysical properties at saturation for methanolTable B.43 Thermophysical properties at saturation for nitrogenTable B.44 Thermophysical properties at saturation for potassiumTable B.45 Thermophysical properties at saturation for rubidiumTable B.46 Thermophysical properties at saturation for silverTable B.47 Thermophysical properties at saturation for sodiumTable B.48 Thermophysical properties at saturation for waterTable B.49 Binary diffusion coefficients at 1 atma (Bergman and Lavine 2017)Table B.50 Diffusion coefficients in air at 1 atm (1.013 � 105 Pa)a (Mills and Coimbra 2015)Table B.51 Diffusion coefficients in solids, D ¼ D0 exp �Ea=RuTð ÞTable B.52 Schmidt number for vapors in dilute mixture in air at normal temperature, enthalpy of
vaporization and boiling point at 1 atma (Mills and Coimbra 2015)Table B.53 Schmidt numbers for dilute solution in water at 300 Ka (Mills and Coimbra 2015)Table B.54 Solubility and permeability of gases in solids (Mills and Coimbra 2015)Table B.55 Henry’s constant for selected gases in water at moderate pressurea
Table B.56 Solubility of selected gases and solids (Bergman and Lavine 2017)Table B.57 Solubility of inorganic compounds in watera (Mills and Coimbra 2015)Table B.58 Equilibrium compositions for the NH3-water system (Mills and Coimbra 2015)Table B.59 Equilibrium compositions for the SO2-water system
a (Mills and Coimbra 2015)Table B.60 Thermodynamic properties of water vapor-air mixtures at 1 atm (Mills and Coimbra 2015)
752 Appendix B: Transport Properties
Table B.1 Air at 1 atm (Bergman and Lavine 2017)
T Temp.(K)
qDensity(kg/m3)
cpSpecificheat(kJ/Kg-K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
100 3.5562 1.032 71.1 2.00 9.34 2.54 0.786
150 2.3364 1.012 103.4 4.426 13.8 5.84 0.758
200 1.7458 1.007 132.5 7.59 18.1 10.3 0.737
250 1.3947 1.006 159.6 11.44 22.3 15.9 0.72
300 1.1614 1.007 184.6 15.89 26.3 22.5 0.707
350 0.995 1.009 208.2 20.92 30.0 29.9 0.700
400 0.8711 1.014 230.1 26.41 33.8 38.3 0.690
450 0.7740 1.021 250.7 32.39 37.3 47.2 0.686
500 0.6964 1.030 270.1 38.79 40.7 56.7 0.684
550 0.6329 1.040 288.4 45.57 43.9 66.7 0.683
600 0.5804 1.051 305.8 52.69 46.9 76.9 0.685
650 0.5356 1.063 322.5 60.21 49.7 87.3 0.690
700 0.4975 1.075 338.8 68.10 52.4 98 0.695
750 0.4643 1.087 354.6 76.37 54.9 109 0.702
800 0.4354 1.099 369.8 84.93 57.3 120 0.709
850 0.4097 1.110 384.3 93.80 59.6 131 0.716
900 0.3868 1.121 398.1 102.9 62.0 143 0.720
950 0.3666 1.131 411.3 112.2 64.3 155 0.723
1000 0.3482 1.141 424.4 121.9 66.7 168 0.726
1100 0.3166 1.159 449 141.8 71.5 195 0.728
1200 0.2902 1.175 473 162.9 76.3 224 0.728
1300 0.2679 1.189 496 185.1 82 238 0.719
1400 0.2488 1.207 530 213 91 303 0.703
1500 0.2322 1.23 557 240 100 350 0.685
1600 0.2177 1.248 584 268 106 390 0.688
1700 0.2049 1.267 611 298 113 435 0.685
1800 0.1935 1.286 637 329 120 482 0.683
1900 0.1833 1.307 663 362 128 534 0.677
2000 0.1741 1.337 689 396 137 589 0.672
2100 0.1658 1.372 715 431 147 646 0.667
2200 0.1582 1.417 740 468 160 714 0.655
2300 0.1513 1.478 766 506 175 783 0.647
2400 0.1448 1.558 792 547 196 869 0.63
2500 0.1389 1.665 818 589 222 960 0.613
3000 0.1135 2.726 955 841 486 1570 0.536
Appendix B: Transport Properties 753
Table B.2 Carbon dioxide (CO2) at 1 atm (Bergman and Lavine 2017)
T Temp.(K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
280 1.9022 0.830 140 7.36 15.20 9.63 0.765
300 1.7730 0.851 149 8.40 16.55 11.00 0.766
320 1.6609 0.872 156 9.39 18.05 12.50 0.754
340 1.5618 0.891 165 10.60 19.70 14.20 0.746
360 1.4743 0.908 173 11.70 21.20 15.80 0.741
380 1.3961 0.926 181 13.00 22.75 17.60 0.737
400 1.3257 0.942 190 14.30 24.30 19.50 0.737
450 1.1782 0.981 210 17.80 28.30 24.50 0.728
500 1.0594 1.020 231 21.80 32.50 30.10 0.725
550 0.9625 1.050 251 26.10 36.60 36.20 0.721
600 0.8826 1.080 270 30.60 40.70 42.70 0.717
650 0.8143 1.100 288 35.40 44.50 49.70 0.712
700 0.7564 1.130 305 40.30 48.10 56.30 0.717
750 0.7057 1.150 321 45.50 51.70 63.70 0.714
800 0.6614 1.170 337 51.00 55.10 71.20 0.716
Table B.3 Helium (He) at 1 atm (Bejan 2013)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−6 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
4.22 16.900 9.78 1.25 0.0739 0.011 0.00064 1.15
7 7.530 5.71 1.76 0.234 0.014 0.00321 0.73
10 5.020 5.41 2.26 0.449 0.018 0.00642 0.70
20 2.440 5.25 3.58 1.470 0.027 0.0209 0.70
30 1.620 5.22 4.63 2.860 0.034 0.0403 0.71
60 0.811 5.20 7.12 8.800 0.053 0.125 0.70
100 0.487 5.20 9.78 20.10 0.074 0.291 0.69
200 0.244 5.19 15.1 62.20 0.118 0.932 0.67
300 0.162 5.19 19.9 122.0 0.155 1.830 0.67
600 0.0818 5.19 32.2 396.0 0.251 5.940 0.67
1000 0.0487 5.19 46.3 946.0 0.360 14.20 0.67
754 Appendix B: Transport Properties
Table B.4 Hydrogen (H2) at 1 atm (Bergman and Lavine 2017)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
100 0.24255 11.230 42.1 17.4 67 24.6 0.707
150 0.16156 12.600 56.0 34.7 101 49.6 0.699
200 0.12115 13.540 68.1 56.2 131 79.9 0.704
250 0.09693 14.060 78.9 81.4 157 115 0.707
300 0.08078 14.310 89.6 111 183 158 0.701
350 0.06924 14.430 98.8 143 204 204 0.700
400 0.06059 14.480 108.2 179 226 258 0.695
450 0.05386 14.500 117.2 218 247 316 0.689
500 0.04848 14.520 126.4 261 266 378 0.691
550 0.04407 14.530 134.3 305 285 445 0.685
600 0.04040 14.550 142.4 352 305 519 0.678
700 0.03463 14.610 157.8 456 342 676 0.675
800 0.03030 14.700 172.4 569 378 849 0.670
900 0.02694 14.830 186.5 692 412 1030 0.671
1000 0.02424 14.990 201.3 830 448 1230 0.673
1100 0.02204 15.170 213.0 966 488 1460 0.662
1200 0.02020 15.370 226.2 1120 528 1700 0.659
1300 0.01865 15.590 238.5 1279 568 1955 0.655
1400 0.01732 15.810 250.7 1447 610 2230 0.650
1500 0.01616 16.020 262.7 1626 655 2530 0.643
1600 0.01520 16.280 273.7 1801 697 2815 0.639
1700 0.01430 16.580 284.9 1992 742 3130 0.637
1800 0.01350 16.960 296.1 2193 786 3435 0.639
1900 0.01280 17.490 307.2 2400 835 3730 0.643
2000 0.01210 18.250 318.2 2630 878 3975 0.661
Table B.5 Nitrogen (N2) at 1 atm (Bergman and Lavine 2017)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
100 3.4388 1.070 68.8 2.00 9.58 2.6 0.768
150 2.2594 1.050 100.6 4.45 13.9 5.86 0.759
200 1.6883 1.043 129.2 7.65 18.3 10.4 0.736
250 1.3488 1.042 154.9 11.48 22.2 15.8 0.727
300 1.1233 1.041 178.2 15.86 25.9 22.1 0.716
350 0.9625 1.042 200.0 20.78 29.3 29.2 0.711
400 0.8425 1.045 220.4 26.16 32.7 37.1 0.704
450 0.7485 1.050 239.6 32.01 35.8 45.6 0.703
500 0.6739 1.056 257.7 38.24 38.9 54.7 0.700
550 0.6124 1.065 274.7 44.86 41.7 63.9 0.702(continued)
Appendix B: Transport Properties 755
Table B.6 Oxygen (O2) at 1 atm (Bergman and Lavine 2017)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
100 3.9450 0.9620 76.4 1.94 9.25 2.44 0.796
150 2.5850 0.9210 114.8 4.44 13.8 5.80 0.766
200 1.9300 0.9150 147.5 7.64 18.3 10.4 0.737
250 1.5420 0.9150 178.6 11.58 22.6 16.0 0.723
300 1.2840 0.9200 207.2 16.14 26.8 22.7 0.711
350 1.1000 0.9290 233.5 21.23 29.6 29.0 0.733
400 0.9620 0.9420 258.2 26.84 33.0 36.4 0.737
450 0.8554 0.9560 281.4 32.90 36.3 44.4 0.741
500 0.7698 0.9720 303.3 39.40 41.2 55.1 0.716
550 0.6998 0.9880 324.0 46.30 44.1 63.8 0.726
600 0.6414 1.0030 343.7 53.59 47.3 73.5 0.729
700 0.5498 1.0310 380.8 69.26 52.8 93.1 0.744
800 0.4810 1.0540 415.2 86.32 58.9 116 0.743
900 0.4275 1.0740 447.2 104.6 64.9 141 0.740
1000 0.3848 1.0900 477.0 124.0 71.0 169 0.733
1100 0.3498 1.1030 505.5 144.5 75.8 196 0.736
1200 0.3206 1.1150 532.5 166.1 81.9 229 0.725
1300 0.2960 1.1250 588.4 188.6 87.1 262 0.721
Table B.5 (continued)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
600 0.5615 1.075 290.8 51.79 44.6 73.9 0.701
700 0.4812 1.098 321.0 66.71 49.9 94.4 0.706
800 0.4211 1.220 349.1 82.9 54.8 116 0.715
900 0.3743 1.146 375.3 100.3 59.7 139 0.721
1000 0.3368 1.167 399.9 118.7 64.7 165 0.721
1100 0.3062 1.187 423.2 138.2 70.0 193 0.718
1200 0.2807 1.204 445.3 158.6 75.8 224 0.707
1300 0.2591 1.219 466.2 179.9 81.0 256 0.701
756 Appendix B: Transport Properties
Table B.7 Water (H2O) vapor at 1 atm (Bergman and Lavine 2017)
TTemp. (K)
qDensity(kg/m3)
cpSpecificheat(kJ/kg K)
lViscosity(10−7 N s/m2)
mKinematicviscosity(10−6 m2/s)
kThermalconductivity(10−3 W/m K)
aThermaldiffusivity(10−6 m2/s)
PrPrandtlnumber
380 0.5863 2.060 127.1 21.68 24.6 20.4 1.060
400 0.5542 2.014 134.4 24.25 26.1 23.4 1.040
450 0.4902 1.980 152.5 31.11 29.9 30.8 1.010
500 0.4405 1.985 170.4 38.68 33.9 38.8 0.998
550 0.4005 1.997 188.4 47.04 37.9 47.4 0.993
600 0.3652 2.026 206.7 56.60 42.2 57.0 0.993
650 0.3380 2.056 224.7 66.48 46.4 66.8 0.996
700 0.3140 2.085 242.6 77.26 50.5 77.1 1.000
750 0.2931 2.119 260.4 88.84 54.9 88.4 1.000
800 0.2739 2.152 278.6 101.7 59.2 100.0 1.010
850 0.2579 2.186 296.9 115.1 63.7 113.0 1.020
Table B.8 Volume expansion coefficients for liquids (Mills and Coimbra 2015)
Liquid T (K) b � 103 (1/K) Liquid T (K) b � 103 (1/K)
Ammonia 293 2.45 Hydrogen 20.3 15.1
Engine oil (SAE 50) 273 0.70 Mercury 273 0.18
430 0.70 550 0.18
Ethylene glycol C2H4(OH)2 273 0.65 Nitrogen 70 4.9
373 0.65 77.4 5.7
Refrigerant-22 250 2.27 80 5.9
260 2.41 90 7.2
270 2.58 100 9.0
280 2.78 110 12
290 3.03 120 24
300 3.35 Oxygen 89 2.0
310 3.75 Sodium 366 0.27
320 4.30 Therminol® 60 230 0.79
330 5.09 250 0.75
340 6.34 300 0.70
350 8.64 350 0.70
Refrigerant-134a 230 2.00 400 0.76
240 2.09 450 0.84
250 2.20 500 0.96
260 2.32 550 1.1
270 2.47
280 2.65
290 2.86
300 3.13
310 3.48
320 3.95
330 4.61
340 5.60
350 7.32
Glycerin C3H5(OH)3 280 0.47
300 0.48
320 0.50
Appendix B: Transport Properties 757
Table B.9 Density and volume expansion coefficients of water (Mills and Coimbra 2015)
T (K) q (kg/m3) b � 106 (1/K) T (K) q (kg/m3) b � 106 (1/K)
273.15 999.8679 −68.05 320.00 989.12 436.7
274.00 999.9190 −51.30 330.00 984.25 504.0
275.00 999.9628 −32.74 340.00 979.43 566.0
276.00 999.9896 −15.30 350.00 973.71 624.4
277.00 999.9999 1.16 360.00 967.12 697.9
278.00 999.9941 16.78 370.00 960.61 728.7
279.00 999.9727 31.69 373.15 957.85 750.1
280.00 999.9362 46.04 380.00 953.29 788
285.00 999.5417 114.1 390.00 945.17 841
290.00 998.8281 174.0 400.00 937.21 896
295.00 997.8332 227.5 450.00 890.47 1129
300.00 996.5833 276.1 500.00 831.26 1432
310.00 993.4103 361.9
Table B.10 Aluminum
Aluminum, Al, Tm = 933 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 2732 0.481 300
150 2726 0.683 250
200 2719 0.797 237
250 2710 0.859 235
300 2701 0.902 237
400 2681 0.949 240
600 2639 1.042 231
800 2591 1.134 218
Table B.11 Aluminum alloy, 2024-T6
Aluminum Alloy, 2024-T6, Tm = 775 K (Bergman and Lavine 2017) (4.5% Cu, 1.5% Mg, 0.6% Mn)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 0.473 65
200 0.787 163
300 2770 0.875 177
400 0.925 186
600 1.042 186
758 Appendix B: Transport Properties
Table B.12 Cartridge brass
Cartridge brass, Tm = 1188 K (Bergman and Lavine 2017)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 75
200 0.360 95
300 8530 0.380 110
400 0.395 137
600 0.425 149
Table B.13 Copper
Copper, Cu, Tm = 1358 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 9009 0.254 480
150 8992 0.323 429
200 8973 0.357 413
250 8951 0.377 406
300 8930 0.386 401
400 8884 0.396 393
600 8787 0.431 379
800 8642 0.448 366
1000 8568 0.446 352
1200 8458 0.480 339
Table B.14 Fused silica
Silicon dioxide, SiO, Tm = 1883 K (Bergman and Lavine 2017)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 0.69
200 1.14
300 2220 0.745 1.38
400 0.905 1.51
600 1.040 1.75
800 1.105 2.17
1000 1.155 2.87
1200 1.195 4.00
Appendix B: Transport Properties 759
Table B.15 Inconel® X-750
Inconel X-750, Tm = 1665 K (Bergman and Lavine 2017)(73% Ni, 15% Cr, 6.7% Fe)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 8.7
200 0.372 10.3
300 8510 0.439 11.7
400 0.473 13.5
600 0.510 17.0
800 0.546 20.5
1000 0.626 24.0
1200 27.6
1500 33.0
Table B.16 Iron
Iron, Fe, Tm = 1810 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 7900 0.216 134
150 7890 0.324 104
200 7880 0.384 94
250 7870 0.422 87
300 7860 0.450 80
400 7830 0.491 70
600 7760 0.555 55
800 7690 0.692 43
1000 7650 1.034 32
1200 7620 28
1400 7520 31
1600 7420
1800 7420
Table B.17 Molybdenum
Molybdenum, Mo, Tm = 2892 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 10,260 0.140 180
150 10,250 0.196 149
200 10,250 0.223 143
250 10,250 0.241 140
300 10,240 0.248 138
400 10,220 0.261 134
500 10,210 0.268 130
600 10,190 0.274 126
800 10,160 0.280 118
1000 10,120 0.292 112
1200 10,080 105
1400 10,040 100
760 Appendix B: Transport Properties
Table B.18 Nickel
Nickel, Ni, Tm = 1728 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 8960 0.323 165
150 8940 0.329 120
200 8930 0.383 105
250 8910 0.416 98
300 8900 0.444 91
400 8860 0.490 80
600 8780 0.590 66
800 8690 0.530 68
1000 8610 0.556 72
1200 8510 0.582 76
1400 8410 80
1600 8320
Table B.19 Niobium
Niobium, Nb, Tm = 2740 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 8600 0.202 55
150 8590 0.238 53
200 8580 0.254 53
250 8570 0.263 53
300 8570 0.268 54
400 8550 0.272 55
500 8530 0.277 57
600 8510 0.281 58
800 8470 0.290 61
1000 8430 0.298 64
1200 8380 0.307 68
1400 8340 71
Table B.20 Plain carbon steel
Plain Carbon Steel, Tm = 1480 °C (Bergman and Lavine 2017)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
300 7854 0.434 60.5
400 0.487 56.7
600 0.559 48.0
800 0.685 39.2
1000 1.169 30.0
Appendix B: Transport Properties 761
Table B.21 Stainless steel 304
Stainless Steel 304, Tm = 1670 K (Bergman and Lavine 2017)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 0.272 9.2
200 0.402 12.6
300 7900 0.477 14.9
400 0.515 16.6
600 0.557 19.8
800 0.582 22.6
1000 0.611 25.4
1200 0.640 28.0
1500 0.682 31.7
Table B.22 Tantalum
Tantalum, Ta, Tm = 3252 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 16,490 0.108 59
150 16,480 0.125 58
200 16,460 0.132 58
250 16,450 0.137 57
300 16,440 0.141 58
400 16,410 0.145 58
500 16,370 0.148 59
600 16,340 0.149 59
800 16,270 0.152 59
1000 16,200 0.160 60
1200 16,130 61
1400 16,060 62
762 Appendix B: Transport Properties
Table B.23 Titanium
Titanium, Ti, Tm = 1953 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 4510 0.295 31
150 4515 0.406 27
200 4520 0.464 25
250 4515 0.501 23
300 4510 0.525 21
400 4490 0.555 20
600 4470 0.597 19
800 4440 0.627 19
1000 4410 0.652 21
1200 4380 22
1400 4350 24
1600 4320
Table B.24 Tungsten
Tungsten, W, Tm = 3660 K (Rohsenow et al. 1998)
TTemp. (K)
qDensity (kg/m3)
cSpecific heat (kJ/kg K)
kThermal conductivity (W/m K)
100 19,310 0.089 208
150 19,300 0.113 192
200 19,290 0.125 185
250 19,280 0.131 180
300 19,270 0.135 174
400 19,240 0.137 159
500 19,220 0.139 146
600 19,190 0.140 137
800 19,130 0.144 125
1000 19,080 0.148 118
1200 19,020 112
1400 18,950 108
Appendix B: Transport Properties 763
Table
B.25
Phasechange
materials(PCMs)
PCMs
Chemical
form
ula
T m meltin
gpo
int
(°C)
h s‘
latent
heat
(kJ/kg
)
qs Solid
density
(kg/m
3 )
q ‘ Liquid
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
3N
s/m
2 )
k s Solid
thermal
cond
uctiv
ity(W
/mK)
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
c p,s
Solid
specific
heat
(kJ/kg
K)
c p,‘
Liquid
specific
heat
(kJ/kg
-K)
b Liquidthermal
expansion
coefficient
(10−
4 1/K)
n-Tetradecane
aC14H30
5.5
226
825
771
0.15
n-Hexadecaneb
C16H34
18.2
228.9
833
774
0.15
051.80
2.31
n-Octadecanec
C18H38
27.5
244
814a
774a
3.9
0.35
80.15
22.15
2.18
8.5
n-Eicosaneb
C20H42
36.40
247.3
815
780
0.15
01.92
2.46
8.5
Galliu
md
Ga
29.78
80.16
6095
6093
1.81
33.5
32.0
0.34
0c0.38
151.2
Aluminum
cAl
660.4
395
2702
2380
e1.3
238
94.03
1.07
61.08
1.2
Water
fH2O
033
3.7g
920
1000
1.75
1.88
0.56
92.04
4.23
−0.68
05
Acetic
acid
aCH3C
OOH
16.7
187
1214
1050
1.31
0.18
2040
1960
Sodium
hydrog
enph
osph
ate
dodecahy
dratea
Na 2HPO
4�12
H2O
3628
015
2014
460.51
40.47
616
9019
404.35
a Haleet
al.(19
71),
b Hum
phries
andGrigg
s(197
7),cBenno
nandIncrop
era(198
8);dBrent
etal.(19
88),
e IidaandGuthrie
(198
8),fBergm
anandLavine(201
7),gCengele
tal.
(201
9)
764 Appendix B: Transport Properties
Table
B.26
Therm
ophy
sicalprop
ertiesat
saturatio
nforaceton
e
Acetone,(CH3)2C
O,Molecular
mass:58
.1,(T
sat=56
.25°C
;T m
=−93
.15°C
;Reayet
al.20
14;Fagh
ri20
16)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(kg/m
3 )
q v Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
-K)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heatb
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
−40
0.01
660.0
860.0
0.03
0.80
068
.00.20
031
.02.04
1.10
9
−20
0.03
615.6
845.0
0.10
0.50
073
.00.18
90.00
8227
.62.07
1.16
0
00.10
564.0
812.0
0.26
0.39
578
.00.18
30.00
9626
.22.11
1.21
5
200.27
552.0
790.0
0.64
0.32
382
.00.18
10.01
1023
.72.16
1.27
1
400.60
536.0
768.0
1.05
0.26
986
.00.17
50.01
2621
.22.22
1.32
8
601.15
517.0
744.0
2.37
0.22
690
.00.16
80.01
4318
.62.29
1.38
6
802.15
495.0
719.0
4.30
0.19
295
.00.16
00.01
6116
.22.39
1.44
4
100
4.43
472.0
689.6
6.94
0.17
098
.00.14
80.01
7813
.42.49
1.50
2
120
6.70
426.1
660.3
11.02
0.14
899
.00.13
50.01
9510
.72.61
1.56
0
140
10.49
394.4
631.8
18.61
0.13
210
3.0
0.12
60.02
158.1
2.77
1.61
6a Interpo
latio
nfrom
Roh
seno
wet
al.(199
8),b Interpo
latio
nfrom
Vargaftik
(197
5)
Appendix B: Transport Properties 765
Table
B.27
Therm
ophy
sicalprop
ertiesat
saturatio
nforam
mon
ia
Ammon
ia,NH3,Molecular
mass:17
.0,(T
sat=23
9.9K;T m
=19
5.5K;ASH
RAE,20
09;Lem
mon
etal.20
16)
T Tem
p.(°C)
p v Saturatio
npressure
(106
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(kg/m
3 )
q v Vapor
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
5N
s/m
2 )
lv Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tensiona
(N/m
)
c p,‘
Liquid
specificheat
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
200
0.00
8646
1477
728.9
0.08
899
50.728
69.5
0.80
30.01
970.06
044.22
72.07
6
210
0.01
7746
1451
717.5
0.17
4641
.498
72.1
0.76
80.01
990.05
634.28
52.11
2
220
0.03
3811
1425
705.8
0.31
9034
.668
74.8
0.73
30.02
010.05
234.34
22.16
0
230
0.06
0439
1398
693.7
0.54
8929
.494
77.7
0.69
90.02
050.04
854.39
72.22
2
240
0.10
226
1369
681.4
0.89
7225
.485
80.6
0.66
50.02
100.04
474.44
92.29
8
250
0.16
496
1339
668.9
1.40
422
.308
83.6
0.63
20.02
160.04
104.49
82.39
2
260
0.25
529
1307
656.1
2.11
519
.734
86.6
0.60
00.02
230.03
744.54
82.50
3
270
0.38
100
1273
642.9
3.08
617
.606
89.6
0.56
90.02
310.03
404.59
92.63
4
280
0.55
077
1237
629.2
4.38
015
.812
92.7
0.53
90.02
400.03
064.65
62.78
8
290
0.77
413
1198
615.0
6.07
114
.274
95.8
0.50
90.02
510.02
744.72
22.96
7
300
1.06
1411
5960
0.2
8.24
712
.933
98.9
0.48
00.02
640.02
424.80
03.17
7
310
1.42
3511
1358
4.6
11.01
11.749
102
0.45
20.02
790.02
124.89
73.42
3
320
1.87
2110
6656
8.2
14.51
10.691
106
0.42
50.02
960.01
835.01
83.71
8
330
2.41
9610
1455
0.9
18.89
9.73
109
0.39
80.03
160.01
555.17
64.07
8
340
3.07
8995
853
2.4
24.40
8.86
113
0.37
20.03
390.01
295.38
54.53
0
350
3.86
4189
551
2.3
31.34
8.04
118
0.34
50.03
690.01
045.67
15.12
5
360
4.79
0282
549
0.3
40.18
7.28
123
0.31
90.04
080.00
806.08
25.95
5
370
5.87
4074
546
5.5
51.65
6.55
131
0.29
30.04
610.00
586.71
57.21
4
380
7.13
5264
943
6.5
67.16
5.83
140
0.26
70.05
460.00
387.81
89.39
5
390
8.59
7752
940
0.2
89.85
5.09
155
0.24
00.07
010.00
2010
.31
14.19
766 Appendix B: Transport Properties
Table
B.28
Therm
ophy
sicalprop
ertiesat
saturatio
nforcesium
Cesium,Cs,Molecular
mass:13
2.9,
(Tsat=94
3K;T m
=20
1.6K;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(10−
3kg
/m3 )
l ‘ Liquid
viscosity
(10−
4N
s/m
2 )
l v Vapor
viscosity
(10−
5N
s/m
2 )
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
500
0.00
0354
4.30
1.72
39.91
3.18
11.46
018
.79
61.9
0.23
20.19
82
600
0.00
5653
4.20
1.66
615
.50
2.55
81.66
819
.02
0.00
530
57.1
0.22
40.23
44
700
0.04
3752
3.30
1.60
910
5.20
2.16
31.89
318
.79
0.00
631
52.3
0.21
90.26
45
800
0.20
2651
1.60
1.55
243
3.60
1.89
02.12
418
.33
0.00
724
47.5
0.21
70.28
21
900
0.65
8049
9.50
1.49
512
75.90
1.69
02.33
617
.51
0.00
807
42.7
0.22
20.28
78
1000
1.68
0048
6.50
1.43
829
90.40
1.53
62.56
716
.47
0.00
878
37.9
0.23
10.28
50
1100
3.60
0047
2.60
1.37
759
24.10
1.41
52.78
215
.49
0.00
942
33.1
0.23
90.27
76
1200
6.77
0045
8.80
1.31
110
,364
.80
1.31
62.99
513
.57
0.01
000
28.3
0.24
80.26
81
1300
11.510
044
4.60
1.24
316
,520
.70
1.23
43.19
811
.60
0.01
060
23.5
0.25
60.25
82
1400
18.020
042
9.98
1.17
424
,307
.20
1.16
43.39
89.39
0.01
110
18.0
1500
26.720
041
5.40
1.10
234
,048
.30
1.10
43.58
97.50
0.01
150
14.0
a Vargaftik
(197
5)
Appendix B: Transport Properties 767
Table
B.29
Therm
ophy
sicalprop
ertiesat
saturatio
nforDow
therm
®
Dipheny
lmixture
(Dow
therm
a ),Molecular
mass:16
6.0,
(Tsat=25
8°C
;T m
=12
°C;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
5N
s/m
2 )
lv Vapor
viscosity
(10−
5N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specificheat
(kJ/kg
K)
c p,v
Vapor
specificheat
(kJ/kg
K)
100
0.00
634
599
50.03
510
1.0
0.68
0.12
631
.61.88
150
0.05
132
995
30.24
60.3
0.77
0.11
926
.52.14
200
0.24
531
491
20.99
40.7
0.87
0.11
021
.82.34
250
0.84
329
187
13.20
29.7
0.97
0.10
417
.32.60
300
2.33
026
482
58.70
22.7
1.07
0.09
612
.92.76
350
5.20
023
577
220
.018
.21.17
0.09
08.9
2.89
400
10.43
207
709
42.0
14.9
1.26
0.08
35.0
3.01
a Dow
therm
isan
eutectic
mixture
of73
.5%
phenuletherand26
.5%
diph
enyl
768 Appendix B: Transport Properties
Table
B.30
Therm
ophy
sicalprop
ertiesat
saturatio
nforethane
Ethane,
C2H
6,Molecular
mass:30
.1,(T
sat=−88
.6°C
;T m
=−18
3.3°C
;Ivanov
skiiet
al.,19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
q v Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
7N
s/m
2 )
lv Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specificheat
(kJ/kg
K)
c p,v
Vapor
specificheat
(kJ/kg
K)
−12
00.09
653
058
20.23
025
8049
.00.14
921
.23
2.82
1.29
7
−10
00.60
050
656
20.92
118
0055
.00.13
717
.93
2.94
1.34
9
−80
1.70
048
054
02.60
013
6061
.00.12
514
.60
3.05
1.40
1
−60
3.70
045
051
66.20
011
0067
.00.11
30.01
1611
.30
3.16
1.45
9
−40
7.20
041
448
812
.700
900
73.0
0.10
00.01
388.00
3.26
1.52
1
−20
14.000
368
454
25.500
760
79.0
0.08
80.01
604.60
3.38
1.58
5
025
.000
304
414
46.000
660
85.5
0.07
70.01
851.20
3.48
1.66
0
2038
.000
200
360
85.000
600
91.0
0.06
60.02
090.08
1.73
6a Interpo
latio
n(Roh
seno
wet
al.19
98)
Appendix B: Transport Properties 769
Table
B.31
Therm
ophy
sicalprop
ertiesat
saturatio
nforethano
l
Ethanol,C2H
5OH,Molecular
mass:46
.0,(T
sat=78
.3°C
;T m
=−11
4.5°C
;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
lv Vapor
viscosity
(10−
5N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heatb
(kJ/kg
K)
c p,v
Vapor
specific
heatc
(kJ/kg
K)
00.01
210
48.4
0.90
10.03
61.79
900.77
40.18
30.01
1724
.42.27
1.34
200.05
810
30.0
0.80
00.08
51.19
800.83
50.17
90.01
3922
.82.40
1.40
400.18
010
11.9
0.78
90.31
60.81
900.90
00.17
50.01
6021
.02.57
1.48
600.47
298
8.9
0.77
00.74
80.58
800.95
90.17
10.01
7919
.22.78
1.54
801.08
696
0.0
0.75
71.43
00.43
201.03
00.16
90.01
9917
.33.03
1.61
100
2.26
092
7.0
0.73
03.41
00.31
801.09
20.16
70.02
1915
.53.30
1.68
120
4.29
088
5.5
0.71
06.01
00.24
301.15
70.16
50.02
3813
.43.61
1.75
140
7.53
083
4.0
0.68
010
.670
0.19
001.21
90.16
30.02
5611
.23.96
160
12.756
772.9
0.65
017
.450
0.15
001.29
30.16
10.02
729.0
180
19.600
698.8
0.61
027
.650
0.12
001.36
90.15
90.02
886.7
200
29.400
598.3
0.56
444
.480
0.09
501.46
40.15
70.03
954.3
220
42.800
468.5
0.51
074
.350
0.07
251.61
80.15
50.03
212.2
240
60.200
280.5
0.41
513
5.50
00.04
881.94
80.15
30.1
a Interpo
latio
nfrom
Roh
seno
wet
al.(199
8),b Interpo
latio
nfrom
Vargaftik
(197
5),c Reayet
al.(201
4)
770 Appendix B: Transport Properties
Table
B.32
Therm
ophy
sicalprop
ertiesat
saturatio
nforFreon®
-113
Freon-11
3,C2F
3Cl 3,Molecular
mass:18
7.4,
(Tsat=47
.68°C
;T m
=−36
.6°C
;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
itya
(W/m
K)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
−30
0.02
8316
6.88
1.68
70.26
391.67
089
.40.08
8925
.30.85
50.58
7
−20
0.09
0516
1.48
1.64
30.78
001.13
094
.20.08
6722
.80.88
20.59
7
00.15
0015
8.68
1.62
11.25
100.94
896
.70.08
2221
.50.92
10.62
1
100.23
8715
5.83
1.59
81.93
000.78
099
.00.07
9920
.60.93
70.62
7
300.54
2014
9.93
1.55
44.15
000.59
010
4.0
0.07
5418
.10.96
20.64
7
501.09
4314
3.82
1.50
88.00
000.47
510
8.5
0.07
090.00
866
16.0
0.98
60.66
7
702.01
2013
7.46
1.45
514
.300
00.40
111
3.0
0.06
6413
.91.00
40.68
9a A
SHRAE(200
1)
Appendix B: Transport Properties 771
Table
B.33
Therm
ophy
sicalprop
ertiesat
saturatio
nforFreon®
-123
Freon-12
3,CHCl 2CF 3,Molecular
mass:15
2.9,
(Tsat=27
.8°C
;T m
=−10
7°C
;ASH
RAE20
01)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
−60
0.00
8120
4.20
1.66
50.07
01.38
375
.00.10
200.00
435
25.78
0.93
20.55
3
−40
0.03
5819
6.63
1.62
00.28
30.98
683
.10.09
610.00
549
23.19
0.94
80.58
5
−20
0.12
0018
9.11
1.57
40.88
00.73
590
.90.08
980.00
661
20.66
0.96
80.61
7
00.32
6518
1.44
1.52
62.24
20.56
598
.40.08
370.00
774
18.18
0.99
00.65
1
200.75
6117
3.44
1.47
74.90
50.44
310
5.6
0.07
780.00
889
15.77
1.01
40.68
6
401.54
4716
4.95
1.42
59.62
90.35
211
2.6
0.07
240.01
008
13.43
1.03
80.72
4
602.85
8915
5.73
1.37
017
.331
0.28
411
9.4
0.06
730.01
134
11.16
1.06
60.76
7
804.89
0914
5.54
1.31
129
.189
0.23
112
6.3
0.06
260.01
273
8.97
1.10
00.81
6
772 Appendix B: Transport Properties
Table
B.34
Therm
ophy
sicalprop
ertiesat
saturatio
nforFreon®
-134
a
Freon-13
4a,CF 3CH2F,Molecular
mass:10
2.0,
(Tsat=−26
.4°C
;T m
=−10
1°C
;ASH
RAE20
09)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
−60
0.15
9123
7.95
1.47
40.92
680.66
383
.00.12
10.00
656
20.80
1.22
30.69
2
−40
0.51
2122
5.86
1.41
82.76
90.47
291
.20.11
10.00
817
17.60
1.25
50.74
9
−20
1.32
7321
2.91
1.35
86.78
50.35
399
.20.10
10.00
982
14.51
1.29
30.81
6
02.92
8019
8.60
1.29
514
.428
0.27
110
7.3
0.09
200.01
151
11.56
1.34
10.89
7
205.71
7118
2.28
1.22
527
.778
0.21
111
5.81
0.08
330.01
333
8.76
1.40
51.00
1
4010
.166
163.02
1.14
750
.075
0.16
312
5.5
0.07
470.01
544
6.13
1.49
81.14
5
6016
.818
139.13
1.05
381
.413
0.12
413
7.9
0.06
610.01
831
3.72
1.66
01.38
7
Appendix B: Transport Properties 773
Table
B.35
Therm
ophy
sicalprop
ertiesat
saturatio
nforFreon®
-21
Freon-21
,CHFC
l 2,Molecular
mass:10
2.9,
(Tsat=8.90
°C;T m
=−13
5°C
)(V
argaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(103
kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
−60
0.02
5326
91.55
40.14
70.84
989
0.13
229
.81
0.50
1
−40
0.09
5426
21.51
00.51
00.59
795
0.12
326
.99
0.52
3
−20
0.28
4725
31.47
01.41
00.44
410
00.11
624
.17
0.99
40.54
5
00.70
8524
31.42
03.31
00.34
510
60.10
921
.35
1.01
50.56
6
201.53
0023
21.38
06.81
00.27
211
20.10
218
.35
1.04
80.58
8
402.95
522
01.33
012
.690
0.22
911
80.09
50.00
9415
.71
1.09
30.60
6
605.21
620
61.28
021
.930
0.20
012
40.08
70.01
0412
.89
1.14
90.62
3
808.56
719
11.22
035
.710
0.19
513
00.08
00.01
1310
.07
0.64
1
100
13.283
174
1.16
055
.860
0.18
013
60.07
20.01
227.25
0.65
9
120
19.666
155
1.08
085
.470
0.17
014
20.06
00.01
324.43
0.67
7a Interpo
latio
nfrom
Roh
seno
wet
al.(199
8)
774 Appendix B: Transport Properties
Table
B.36
Therm
ophy
sicalprop
ertiesat
saturatio
nforFreon®
-22
Freon-22
,CHF 2Cl,Molecular
mass:86
.5,(T
sat=−40
.8°C
;T m
=−16
0°C
;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
4N
s/m
2 )
lv Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tensiona
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
−10
00.01
9926
9.29
1.55
70.11
966.00
80.0
0.14
870.00
446
28.1
1.07
50.49
7
−80
0.10
3425
7.43
1.51
40.56
15.00
87.5
0.13
850.00
525
24.8
1.08
30.52
8
−60
0.37
5224
5.42
1.46
51.86
54.14
95.0
0.12
830.00
612
21.5
1.09
10.56
4
−40
1.05
4023
2.92
1.41
24.88
53.49
101.7
0.11
810.00
831
18.5
1.10
50.61
1
−20
2.45
6021
9.40
1.35
110
.821
3.02
110.4
0.10
790.00
929
15.0
1.13
00.65
4
04.98
3020
4.28
1.28
521
.285
2.67
118.7
0.09
770.01
026
11.7
1.17
10.74
1
209.09
7018
6.89
1.21
438
.550
2.40
126.8
0.08
750.01
123
8.7
1.23
20.85
4
4015
.315
016
6.22
1.13
266
.225
2.19
134.5
0.07
720.01
221
5.8
1.31
90.99
4
6024
.236
013
9.94
1.03
011
1.65
2.00
142.1
0.06
460.01
318
3.3
1.52
61.24
3a Ivano
vskiiet
al.(198
2)
Appendix B: Transport Properties 775
Table
B.37
Therm
ophy
sicalprop
ertiesat
saturatio
nforheliu
m
Helium,He,
Molecular
mass:4.0,
(Tsat=−26
8°C
;T m
=−27
1°C
;Reayet
al.20
14;Fagh
ri20
16)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
7N
s/m
2 )
l v Vapor
viscosity
(10−
8N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heatb
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
−27
10.06
22.8
148.3
26.0
390
200.01
810.00
393
0.26
5.18
2.04
5
−27
00.32
23.6
140.7
17.0
370
300.02
240.00
607
0.19
2.49
2.69
9
−26
91.00
20.9
128.0
10.0
290
600.02
770.00
803
0.09
3.99
4.61
9
−26
82.29
4.0
113.8
8.5
134
900.03
500.00
962
0.01
11.5
6.64
2a Tou
louk
ianet
al.(197
0),b V
argaftik
(197
5)
776 Appendix B: Transport Properties
Table
B.38
Therm
ophy
sicalprop
ertiesat
saturatio
nforheptane
Heptane,C7H
16,Molecular
mass:10
0.2,
(Tsat=98
.43°C
;T m
=−90
.59°C
;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(103
kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tensiona
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heatb
(kJ/kg
K)
−20
0.00
3866
383.1
0.71
720.68
900.14
00.00
842.10
0.83
00.01
5237
5.6
0.70
050.00
0070
0.52
600.13
40.00
992.16
0.87
200.04
7236
6.0
0.68
360.00
0200
0.41
400.12
90.01
1520
.86
2.23
0.92
400.12
3035
4.7
0.66
650.00
0500
0.33
800.12
30.01
3218
.47
2.30
0.97
600.28
0034
2.6
0.64
910.00
1100
0.28
100.11
80.01
5116
.39
2.39
1.02
800.57
0033
0.1
0.63
110.00
2000
0.23
900.11
30.01
7014
.35
2.47
1.05
100
1.06
0631
6.7
0.61
240.00
3597
0.19
8073
.60.01
8912
.47
2.57
1.09
120
1.83
3030
2.9
0.59
260.00
6075
0.16
7278
.20.02
0710
.63
2.67
1.16
140
2.97
9028
7.4
0.57
110.00
9785
0.14
2783
.40.02
288.87
2.78
160
4.59
9026
9.5
0.54
810.01
5110
0.12
1789
.70.02
517.19
2.89
a Interpo
latio
nfrom
Roh
seno
wet
al.(199
8),b R
eayet
al.(201
4)
Appendix B: Transport Properties 777
Table
B.39
Therm
ophy
sicalprop
ertiesat
saturatio
nforlead
Lead,
Pb,Molecular
mass:20
7.2,
(Tsat=17
40°C
;T m
=32
7.5°C
;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(102
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(103
kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
1400
0.09
8692
09.27
0.14
70.91
227.46
347.28
1500
0.21
0892
09.14
0.29
60.88
477.90
335.88
1600
0.42
0092
09.01
0.55
90.85
868.34
324.48
1700
0.80
1092
08.89
1.01
10.83
528.78
313.08
1800
1.36
2092
08.76
1.63
50.81
439.21
301.68
1900
2.31
0092
08.63
2.64
80.79
589.66
290.28
2000
3.74
1092
08.51
4.10
60.77
9410
.10
278.88
2100
5.55
0092
08.37
5.81
70.75
9010
.54
260.00
2200
8.20
0092
08.25
8.25
60.74
1010
.98
248.00
2300
11.850
092
08.12
11.480
0.72
3011
.42
237.00
2400
16.750
092
07.99
15.600
0.70
5011
.86
225.00
2500
22.600
092
07.86
20.280
0.68
7012
.30
214.00
a Reayet
al.(201
4)
778 Appendix B: Transport Properties
Table
B.40
Therm
ophy
sicalprop
ertiesat
saturatio
nforlithium
Lith
ium,Li,Molecular
mass:6.9,
(Tsat=16
15K;T m
=45
3.7K;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(102
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
q v Vapor
density
(103
kg/m
3 )
l‘ Liquid
viscosity
(10−
4N
s/m
2 )
l v Vapor
viscosity
(10−
8N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
900
0.12
5621
712
472.8
0.01
22.78
489
0.1
52.75
335.8
4.16
6.95
6
1000
0.96
8021
400
462.6
0.08
52.47
297
5.2
55.10
321.8
4.16
8.17
1
1100
5.12
0021
000
452.4
0.41
52.25
210
55.0
57.42
0.12
030
7.8
4.15
9.11
4
1200
20.500
020
740
442.2
1.54
02.07
211
28.0
59.62
0.13
829
3.8
4.14
9.72
3
1300
65.860
020
380
432.0
4.65
01.92
212
13.0
61.94
0.15
627
9.8
4.16
10.019
1400
179.40
0020
020
421.7
11.960
1.79
512
89.0
64.00
0.17
226
6.0
4.19
10.049
1500
426.50
0019
670
411.5
26.900
1.68
513
68.0
66.50
0.18
325
2.0
4.20
9.89
1
1600
908.40
0019
330
401.3
54.610
1.59
014
42.0
68.50
0.19
223
8.0
4.23
9.61
1
1700
1769
.300
018
990
391.1
101.50
01.50
615
18.0
71.00
0.19
822
6.0
4.25
9.25
9
1800
3190
.000
018
670
380.9
175.10
01.43
215
87.0
73.00
0.20
221
2.0
4.27
8.87
1
1900
5397
.000
018
370
370.0
283.90
01.38
016
66.0
75.50
0.20
719
8.0
4.30
8.48
1
2000
8640
.400
018
080
360.0
436.30
01.30
017
46.0
77.00
0.20
918
2.0
4.32
8.09
8a V
argaftik
(197
5)
Appendix B: Transport Properties 779
Table
B.41
Therm
ophy
sicalprop
ertiesat
saturatio
nformercury
Mercury,Hg,
Molecular
mass:20
0.6,
(Tsat=63
0.1K;T m
=23
4.3K;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
lv Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
100
0.00
0374
530
3.31
713
351.42
0.00
242
1.24
136
09.47
50.46
000.13
711.04
200
0.02
315
300.05
613
111.97
0.11
800
1.03
946
410
.64
0.43
600.13
551.04
300
0.33
015
296.82
412
873.50
1.39
100
0.92
656
211
.69
0.00
430.40
500.13
531.04
400
2.10
240
293.31
412
632.60
7.57
200
0.85
366
212
.60
0.00
580.37
700.13
641.04
500
8.22
2028
9.11
612
386.00
26.000
000.80
476
213
.39
0.00
730.32
900.13
891.04
600
23.460
0028
3.76
912
130.00
66.660
000.76
786
214
.04
0.00
900.29
890.14
271.04
700
54.030
0027
6.84
511
863.00
140.75
000
0.73
996
114
.58
0.01
070.26
870.14
781.04
a Kakac
etal.(198
7)
780 Appendix B: Transport Properties
Table
B.42
Therm
ophy
sicalprop
ertiesat
saturatio
nformethano
l
Methano
l,CH4O
,Molecular
mass:32
.0,(T
sat=64
.7°C
;T m
=−98
°C;Lem
mon
etal.20
16;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(103
kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
00.04
1112
10.0
0.80
970.00
0058
00.81
7088
0.20
524
.52.40
2.99
200.10
311
91.1
0.79
090.00
0175
10.57
8095
0.20
422
.62.50
3.50
400.35
811
63.9
0.77
210.00
0452
10.44
6010
10.20
30.00
157
20.9
2.63
3.96
600.86
111
30.4
0.75
280.00
1029
90.34
7010
80.20
20.00
178
19.3
2.79
4.35
801.81
910
84.4
0.73
260.00
2122
90.27
1011
50.20
00.00
199
17.5
2.97
4.72
100
3.73
110
30.0
0.71
100.00
4042
10.21
4012
30.19
80.00
220
15.7
3.17
5.14
120
6.55
197
1.3
0.68
730.00
7235
90.17
0013
00.19
60.00
241
13.6
3.40
5.69
140
10.810
904.3
0.66
080.01
2378
00.13
6013
60.19
40.00
262
11.5
3.68
6.51
160
17.609
828.0
0.63
040.02
0529
00.10
9014
30.00
283
9.3
4.02
7.61
180
16.869
741.1
0.59
430.03
3184
00.08
8315
00.00
303
6.9
4.49
8.29
200
38.434
636.4
0.54
920.05
2124
00.07
1615
70.00
324
4.5
5.27
8.06
220
56.728
473.1
0.48
490.08
8140
00.05
8316
60.00
344
2.1
7.54
Appendix B: Transport Properties 781
Table
B.43
Therm
ophy
sicalprop
ertiesat
saturatio
nfornitrog
en
Nitrog
en,N2,Molecular
mass:28
.0,(T
sat=−19
5.65
°C;T m
=20
9.85
°C;Vargaftik,19
75)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(103
kg/m
3 )
q v Vapor
density
(103
kg/m
3 )
l‘ Liquid
viscosity
(10−
5N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heata
(kJ/kg
K)
700.38
5920
5.7
0.83
80.00
1920
1048
.00
0.14
200.00
6610
.53
1.93
51.08
801.36
9019
4.5
0.79
00.00
6013
9055
.20
0.12
800.00
778.27
1.96
41.14
903.60
0018
0.5
0.74
60.01
5011
6062
.00
0.11
200.00
916.16
2.02
81.26
100
7.77
5016
2.2
0.69
10.03
2081
068
.80
0.09
550.01
114.00
2.17
61.47
110
14.670
013
7.0
0.62
60.06
2074
075
.60
0.08
020.01
382.00
2.56
61.97
120
25.150
095
.70.52
80.12
4564
082
.10
0.06
280.01
950.20
4.14
a ASH
RAE(200
1)
782 Appendix B: Transport Properties
Table
B.44
Therm
ophy
sicalprop
ertiesat
saturatio
nforpo
tassium
Potassium,K,Molecular
mass:39
.1,(T
sat=10
32.2
K;T m
=33
6.4K;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(10−
3kg
/m3 )
l ‘ Liquid
viscosity
(10−
4N
s/m
2 )
lv Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(10−
1kJ/kgK)
600
0.00
0925
821
4376
6.9
0.69
2.38
043
.85
98.2
0.77
10.81
94
700
0.01
022
2108
743.3
6.68
1.98
140
.72
0.01
4292
.20.76
20.96
46
800
0.06
116
2068
719.6
36.44
1.70
713
437
.58
0.01
7586
.20.76
11.06
6
900
0.24
4120
2369
5.7
134.80
1.50
714
834
.45
0.02
0580
.20.76
91.11
6
1000
0.73
2219
7067
1.6
380.20
1.35
416
331
.32
0.02
2874
.20.79
21.12
1
1100
1.86
419
2464
7.3
871.90
1.23
317
828
.19
0.02
4868
.20.81
91.10
0
1200
3.91
318
7262
2.9
1703
.00
1.13
519
625
.05
0.02
6662
.20.84
61.06
4
1300
7.30
418
2059
8.4
2969
.10
1.05
321
222
.00
0.02
8056
.20.87
31.02
2
1400
12.44
1765
573.6
4768
.70
0.98
422
819
.00
0.02
9353
.00.89
90.97
96
1500
20.0
1711
548.8
7062
.10
0.92
524
216
.00
0.03
0347
.00.92
4
Appendix B: Transport Properties 783
Table
B.45
Therm
ophy
sicalprop
ertiesat
saturatio
nforrubidium
Rub
idium,Rb,
Molecular
mass:85
.5,(T
sat=95
9.2K;T m
=31
2.7K;Vargaftik
1975
)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
q v Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
4N
s/m
2 )
l v Vapor
viscosity
(10−
4N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heat
(kJ/kg
K)
c p,v
Vapor
specific
heat
(kJ/kg
K)
500
0.00
0173
388
9.6
1386
0.00
0358
53.23
29.8
81.6
0.36
90.33
53
600
0.00
3664
870.9
1340
0.00
6386
2.58
0.11
227
.80.00
7375
.70.36
20.41
00
700
0.03
174
849.7
1294
0.04
819
2.18
0.13
525
.90.00
8969
.80.35
70.46
79
800
0.15
8482
7.3
1248
0.21
451.89
0.15
824
.10.01
0363
.90.35
30.49
79
900
0.54
7680
4.6
1202
0.67
261.69
0.18
322
.20.01
1558
.00.35
30.50
35
1000
1.46
778
2.2
1156
1.65
81.53
0.20
820
.30.01
2551
.30.36
00.49
37
1100
3.29
575
9.6
1110
3.43
71.40
0.24
418
.50.01
3344
.50.37
30.47
62
1200
6.46
673
7.0
1064
6.27
41.30
0.26
816
.70.01
4137
.70.38
50.45
58
1300
11.43
714.5
1018
10.36
1.21
0.28
915
.00.01
4930
.90.39
90.43
54
1400
18.6
694.0
972
12.35
1.14
0.31
413
.60.01
5626
.00.40
80.41
30
1500
28.5
674.0
926
22.22
1.08
0.33
612
.00.01
6019
.00.41
80.39
00
784 Appendix B: Transport Properties
Table
B.46
Therm
ophy
sicalprop
ertiesat
saturatio
nforsilver
Silver,Ag,
Molecular
mass:10
7.9,
(Tsat=22
12°C
;T m
=96
0.5°C
;Ivanov
skiiet
al.19
82)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(kg/m
3 )
l‘ Liquid
viscosity
(10−
3N
s/m
2 )
lv Vapor
viscosity
(10−
6N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
itya
(W/m
K)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specificheat
(kJ/kg
K)
c p,v
Vapor
specificheat
(kJ/kg
K)
1500
0.01
008
298
8782
0.00
762.88
61.69
191.3
827.5
1600
0.02
420
298
8683
0.01
698
2.47
64.69
192.7
810.1
1700
0.05
300
298
8585
0.03
548
2.08
67.69
194.1
792.1
1800
0.10
800
298
8485
0.06
823
1.75
70.69
195.5
775.3
1900
0.20
600
298
8385
0.12
300
1.44
73.69
196.9
757.9
2000
0.38
300
298
8289
0.21
880
1.17
76.69
198.3
740.5
2100
0.63
500
298
8190
0.35
480
0.90
79.69
199.7
723.1
2200
0.86
000
298
8092
0.57
540
0.67
82.69
705.7
2300
1.36
000
298
8000
0.87
100
0.44
85.69
638.0
2400
2.53
000
298
7894
1.23
000
0.24
88.69
680.0
2500
3.84
000
298
7796
1.82
000
0.05
91.69
665.0
a Brenn
anandKroliczek(197
9)
Appendix B: Transport Properties 785
Table
B.47
Therm
ophy
sicalprop
ertiesat
saturatio
nforsodium
Sodium
,Na,
Molecular
mass:23
.0,(T
sat=11
51.2
K;T m
=37
1.0K;Ivanov
skiiet
al.19
82;ANL19
95)
T Tem
p.(°C)
p v Saturatio
npressure
(102
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q ‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(10−
3kg
/m3 )
l‘ Liquid
viscosity
(10−
4N
s/m
2 )
lv Vapor
viscosity
(10−
8N
s/m
2 )
k ‘ Liquid
thermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
itya
(W/m
K)
r Liquid
surface
tension
(10−
3N/m
)
c p,‘
Liquid
specific
heata
(kJ/kg
K)
c p,v
Vapor
specific
heat
(10−
1kJ/kgK)
600
0.04
744
2987
3.2
0.02
23.27
614
8075
.17
172.1
1.30
11.80
700
0.95
143
4184
9.4
0.39
62.69
016
6070
.53
0.02
7716
2.1
1.27
72.28
800
8.76
042
3782
5.6
3.27
02.29
818
2765
.88
0.03
4315
2.1
1.26
02.59
900
48.760
4131
801.8
16.500
2.01
820
1061
.25
0.04
0614
2.1
1.25
22.72
1000
192.20
040
2677
8.0
59.980
1.80
922
1156
.60
0.04
5513
2.1
1.25
22.70
1100
584.28
039
2575
4.2
168.10
01.64
523
9851
.96
0.04
9212
2.1
1.26
12.62
1200
1465
.400
3829
730.4
396.60
01.51
425
7747
.00
0.05
2211
2.1
1.27
92.51
1300
3165
.000
3742
706.6
804.50
01.40
727
6342
.50
0.05
4710
2.1
1.30
52.43
1400
6097
.400
3656
682.8
1459
.200
1.31
729
3837
.50
0.05
7092
.11.34
02.39
1500
1071
6.60
035
7765
8.0
2424
.800
1.24
031
1733
.00
0.05
9282
.01.38
42.36
1600
1749
5.90
035
0063
5.2
3750
.900
1.17
632
8128
.50
72.0
1.43
72.34
1700
2691
9.90
034
2561
1.4
5482
.400
1.11
734
4924
.00
62.0
1.50
02.41
1800
3935
0.00
033
5358
7.6
7627
.700
1.06
736
2019
.00
52.0
1.57
42.46
a Vargaftik
(197
5)
786 Appendix B: Transport Properties
Table
B.48
Therm
ophy
sicalprop
ertiesat
saturatio
nforwater
Water,H2O
,Molecular
mass:18
.0,(T
sat=10
0°C
;T m
=0.0°C
;Lem
mon
etal.20
16)
T Tem
p.(°C)
p v Saturatio
npressure
(105
Pa)
h ‘v
Latent
heat
(kJ/kg
)
q‘ Liquid
density
(kg/m
3 )
qv Vapor
density
(kg/m
3 )
l ‘ Liquid
viscosity
(10−
7N
s/m
2 )
l v Vapor
viscosity
(10−
7N
s/m
2 )
k ‘ Liquidthermal
cond
uctiv
ity(W
/mK)
k v Vapor
thermal
cond
uctiv
ity(W
/mK)
r Liquidsurface
tension
(10−
3N/m
)
c p,‘
Liquid
specificheat
(kJ/kg
K)
c p,v
Vapor
specificheat
(kJ/kg
K)
200.02
3368
2453
.899
9.0
0.01
729
1001
697
.30.59
80.01
8272
.88
4.18
41.90
6
400.07
3749
2406
.599
3.05
0.05
110
6530
103.1
0.63
10.01
9669
.48
4.18
01.93
1
600.19
9190
2358
.498
3.28
0.13
020
4664
109.4
0.65
40.02
1266
.07
4.18
51.96
5
800.47
3590
2308
.997
1.82
0.29
320
3543
115.9
0.67
00.02
3062
.69
4.19
72.01
2
100
1.01
3250
2251
.295
8.77
0.59
740
2817
122.7
0.67
90.02
5158
.91
4.21
62.08
0
120
1.98
5400
2202
.994
3.39
1.12
100
2321
129.6
0.68
30.02
7554
.96
4.24
42.17
7
140
3.61
3600
2144
.992
5.93
1.96
560
1965
136.5
0.68
30.03
0150
.79
4.28
32.31
1
160
6.18
0400
2082
.290
7.44
3.25
890
1702
143.4
0.68
00.03
3146
.51
4.33
52.48
8
180
10.027
0020
14.0
887.31
5.15
970
1501
150.3
0.67
30.03
6442
.19
4.40
52.71
3
200
15.551
0019
39.0
865.05
7.86
530
1343
157.2
0.66
30.04
0137
.77
4.49
62.99
0
Appendix B: Transport Properties 787
Table B.49 Binary diffusion coefficients at 1 atma (Bergman and Lavine 2017)
Substance A Substance B T (K) DAB (m2/s)
Gases NH3 Air 298 0.28 � 10−4
H2O Air 298 0.26 � 10−4
CO2 Air 298 0.16 � 10−4
H2 Air 298 0.41 � 10−4
O2 Air 298 0.21 � 10−4
Acetone Air 273 0.11 � 10−4
Benzene Air 298 0.88 � 10−5
Naphthalene Air 300 0.62 � 10−5
Ar N2 293 0.19 � 10−4
H2 O2 273 0.70 � 10−4
H2 N2 273 0.68 � 10−4
H2 CO2 273 0.55 � 10−4
CO2 N2 293 0.16 � 10−4
CO2 O2 273 0.14 � 10−4
O2 N2 273 0.18 � 10−4
Dilute solutions Caffeine H2O 298 0.63 � 10−9
Ethanol H2O 298 0.12 � 10−8
Glucose H2O 298 0.69 � 10−9
Glycerol H2O 298 0.94 � 10−9
Acetone H2O 298 0.13 � 10−8
CO2 H2O 298 0.20 � 10−8
O2 H2O 298 0.24 � 10−8
H2 H2O 298 0.63 � 10−8
N2 H2O 298 0.26 � 10−8
Solids O2 Rubber 298 0.21 � 10−9
N2 Rubber 298 0.15 � 10−9
CO2 Rubber 298 0.11 � 10−9
He SiO2 293 0.4 � 10−13
H2 Fe 293 0.26 � 10−12
Cd Cu 293 0.27 � 10−18
Al Cu 293 0.13 � 10−33
aAssuming ideal gas behavior, the pressure and temperature dependence of the diffusion coefficient for a binary mixtureof gases may be estimated form the relation DAB / p−1 T 3/2
788 Appendix B: Transport Properties
Table B.50 Diffusion coefficients in air at 1 atm (1.013 � 105 Pa)a (Mills and Coimbra 2015)
T [K] Binary diffusion coefficient (m2/s � 104)
O2 CO2 CO C7H16 H2 NO SO2 He
200 0.095 0.074 0.098 0.036 0.375 0.088 0.058 0.363
300 0.188 0.157 0.202 0.075 0.777 0.180 0.126 0.713
400 0.325 0.263 0.332 0.128 1.25 0.303 0.214 1.14
500 0.475 0.385 0.485 0.194 1.71 0.443 0.326 1.66
600 0.646 0.537 0.659 0.270 2.44 0.603 0.440 2.26
700 0.838 0.684 0.854 0.354 3.17 0.782 0.576 2.91
800 1.05 0.857 1.06 0.442 3.93 0.978 0.724 3.64
900 1.26 1.05 1.28 0.538 4.77 1.18 0.887 4.42
1000 1.52 1.24 1.54 0.641 5.69 1.41 1.06 5.26
1200 2.06 1.69 2.09 0.881 7.77 1.92 1.44 7.12
1400 2.66 2.17 2.70 1.13 9.90 2.45 1.87 9.20
1600 3.32 2.75 3.37 1.41 12.5 3.04 2.34 11.5
1800 4.03 3.28 4.10 1.72 15.2 3.70 2.85 13.9
2000 4.80 3.94 4.87 2.06 18.0 4.48 3.36 16.6aOwing to the practical importance of water vapor-air mixtures, engineers have used convenient empirical formulas forDH2Oair. A formula that has been widely used is
DH2O;air ¼ 1:97� 10�5 p0p
� �TT0
� �1:685m2=s; 273 K\T\373 K
where p0 ¼ 1 atm; T0 ¼ 256 K. The following formula has also found increasing use (Marrero and Mason 1972)
DH2Oair ¼ 1:87� 10�10 T2:072
p; 280 K\T\450 K
¼ 2:75� 10�9 T1:632
p; 450 K\T\1070 K
for p in atmospheres and T in Kelvins. Over the temperature range 290–330 K, the discrepancy between the twoformulas is less than 2.5%. For small concentrations of water vapor in air, the older formula gives a constant value ofScH2Oair = 0.61 over the temperature range 273–373 K. On the other hand, the Marrero and Mason (1972) formula givevalues of ScH2Oair that vary from 0.63 at 280 K to 0.57 at 373 K
Table B.51 Diffusion coefficients in solids, D ¼ D0 exp �Ea=RuTð Þ (Mills and Coimbra 2015)
System D0 m2/s Ea
a (kJ/kmol)
Oxygen-Pyrex glass 6:19� 10�8 4:69� 104
Oxygen-fused silica glass 2:61� 10�9 3:77� 104
Oxygen-titanium 5:0� 10�3 2:13� 105
Oxygen-titanium alloy (Ti-6Al-4 V) 5:82� 10�2 2:59� 105
Oxygen-zirconium 4:68� 10�5 7:06� 105
Hydrogen-iron 7:60� 10�8 5:60� 103
Hydrogen-a-titanium 1:80� 10�6 5:18� 104
Hydrogen-b-titanium 1:95� 10�7 2:78� 104
Hydrogen-zirconium 1:09� 10�7 4:81� 104
Hydrogen-Zircaloy-4 1:27� 10�5 6:05� 105
Deuterium-Pyrex glass 6:19� 10�8 4:69� 104
Deuterium-fused silica glass 2:61� 10�9 3:77� 104
(continued)
Appendix B: Transport Properties 789
Table B.52 Schmidt number for vapors in dilute mixture in air at normal temperature, enthalpy of vaporization andboiling point at 1 atma (Mills and Coimbra 2015)
Vapor Chemical formula Scb h‘v J/kg � 10−6 Boiling point temperature K
Acetone CH3COCH3 1.42 0.527 329
Ammonia NH3 0.61 1.370 240
Benzene C6H6 1.79 0.395 354
Carbon dioxide CO2 1.00 0.398 194
Carbon monoxide CO 0.77 0.217 81
Chlorine Cl2 1.42 0.288 238
Ethanol CH3CH2OH 1.32 0.854 352
Helium He 0.22 4.3
Heptane C7H16 2.0 0.340 372
Hydrogen H2 0.20 0.454 20.3
Hydrogen sulfide H2S 0.94 0.548 213
Methanol CH3OH 0.98 1.100 338
Napthalenec C10H8 2.35 0.567 491
Nitric oxide NO 0.87 0.465 121
Octane C8H18 2.66 0.303 399
Oxygen O2 0.83 0.214 90.6
Pentane C5H12 1.49 0.357 309
Sulfur dioxide SO2 1.24 0.398 263
Water vapor H2O 0.61 2.257 373aWith the Clausius–Clapeyron relation, one may estimate vapor pressure as
psat ’ exp �Mh‘vRu
1T � 1
TBP
� �n oatm; for T � TBP
bThe Schmidt number is defined as Sc ¼ l=qD ¼ v=D. Since the vapors are in small concentrations, values for l, q andv can be taken as pure air valuescCho et al. (1992); h‘v ¼ 0:567� 106 J/K is at 300 K
Table B.51 (continued)
System D0 m2/s Ea
a (kJ/kmol)
Helium-Pyrex glass 4:76� 10�8 2:72� 104
Helium-fused silica glass 5:29� 10�8 2:55� 104
Helium-borosilicate 1:94� 10�8 2:34� 104
Neon-borosilicate 1:02� 10�10 3:77� 104
Carbon-FCC iron 2:3� 10�5 1:378� 105
Carbon-BCC iron 1:1� 10�6 8:75� 104
aActivation energy
790 Appendix B: Transport Properties
Table B.53 Schmidt numbers for dilute solution in water at 300 Ka (Mills and Coimbra 2015)
Solute Schmidt number, Sc Molecular mass, M (kg/kmol)
Helium 120 4.003
Hydrogen 190 2.016
Nitrogen 280 28.02
Water 340 18.016
Nitric Oxide 350 30.01
Carbon monoxide 360 28.01
Oxygen 400 32.00
Ammonia 410 17.03
Carbon dioxide 420 44.01
Hydrogen sulfide 430 34.08
Ethylene 450 28.05
Methane 490 16.04
Nitrous oxide 490 44.02
Sulfur dioxide 520 64.06
Sodium chloride 540 58.45
Sodium hydroxide 490 40.00
Acetic acid 620 60.05
Acetone 630 58.08
Methanol 640 32.04
Ethanol 640 46.07
Chlorine 670 70.90
Benzene 720 78.11
Ethylene glycol 720 62.07
n-Propanol 730 60.09
i-Propanol 730 60.09
Propane 750 44.09
Aniline 800 93.13
Benzoic acid 830 122.12
Glycerol 1040 92.09
Sucrose 1670 342.3aFor other temperatures use Sc=Sc300 K ’ ðl2=qTÞ=ðl2=qTÞ300 K, where l and q are for water, and T isabsolute temperature. For chemically similar solutes of different molecular weights useSc2=Sc1 ’ ðM2=M1Þ0:4. A table of ðl2=qTÞ=ðl2=qTÞ300 K for water follows
T [K] ðl2=qTÞ=ðl2=qTÞ300 K T [K] ðl2=qTÞ=ðl2=qTÞ300 K
290 1.66 340 0.221
300 1.00 350 0.167
310 0.623 360 0.123
320 0.429 370 0.097
330 0.296
Spalding (1963)
Appendix B: Transport Properties 791
Table B.54 Solubility and permeability of gases in solids (Mills and Coimbra 2015)
Gas Solid T (K) S0 [m3 (STP)/m3 atm]or S′a
Permeabilityb m3(STP)/m2s(atm/m)
H2 Vulcanized rubber 300 S0 ¼ 0:040 0.34 � 10−10
Vulcanized neoprene 290 S0 ¼ 0:051 0.053 � 10−10
Silicone rubber 300 4.2 � 10−10
Natural rubber 300 0.37 � 10−10
Polyethylene 300 0.065 � 10−10
Polycarbonate 300 0.091 � 10−10
Fused silica 400 S00 ffi 0:035
Nickel 800 S00 ffi 0:030
360 S00 ffi 0:202
440 S00 ffi 0:192
He Silicone rubber 300 2.3 � 10−10
Natural rubber 300 0.24 � 10−10
Polycarbonate 300 0.11 � 10−10
Nylon 66 300 0.0076 � 10−10
Teflon 300 0.047 � 10−10
Fused silica 300 S00 ffi 0:018
800 S00 ffi 0:026
Pyrex glass 300 S00 ffi 0:006
800 S00 ffi 0:024
7740 glass(94% SiO2 + B2O3 + P2O5
5% Na2O + Li2 + K2O1% other oxides)
470 S0 ¼ 0:0084 4.6 � 10−13
580 S0 ¼ 0:0038 1.6 � 10−12
720 S0 ¼ 0:0046 6.4 � 10−12
7056 glass(90% SiO2 + B2O3 + P2O5
8% Na2O + Li2 + K2O1% PbO, 0.5% other oxides)
390 S0 ¼ 0:0039 1.2 � 10−14
680 S0 ¼ 0:0059 1.0 � 10−12
O2 Vulcanized rubber 300 S0 ¼ 0:070 0.15 � 10−10
Silicone rubber 300 3.8 � 10−10
Natural rubber 300 0.18 � 10−10
Polyethylene 300 4.2 � 10−12
Polycarbonate 300 0.011 � 10−10
Silicone-polycarbonate copolymer(57% silicone)
300 1.2 � 10−10
Ethyl cellulose 300 0.09 � 10−10
N2 Vulcanized rubber 300 S0 ¼ 0:035 0.054 � 10−10
Silicone rubber 300 1.9 � 10−10
Natural rubber 300 0.062 � 10−10
Silicone-polycarbonate copolymer(57% silicone)
300 0.53 � 10−10
Teflon® 300 0.019 � 10−10
(continued)
792 Appendix B: Transport Properties
Table B.54 (continued)
Gas Solid T (K) S0 [m3 (STP)/m3 atm]or S′a
Permeabilityb m3(STP)/m2s(atm/m)
CO2 Vulcanized rubber 300 S0 ¼ 0:90 1.0 � 10−10
Silicone rubber 300 21 � 10−10
Natural rubber 300 1.0 � 10−10
Silicone-polycarbonate copolymer(57% silicone)
300 7.4 � 10−10
Nylon 66 300 0.0013 � 10−10
H2O Cellophane 310 0.91–1.8 � 10−10
Ne Fused silica 300–1200
S00 ffi 0:002
Ar Fused silica 900–1200
S00 ffi 0:01
aSolubility S0 = Volume of solute gas (0 °C, 1 atm) dissolved in unit volume of solid when the gas is at 1 atm partialpressure. Solubility coefficient S00 ¼ c1;g=c2bPermeability K ¼ DABS0
From various sources, including Geankoplis (1993), Doremus (1973) and Altemose (1961)
Table B.55 Henry’s constant for selected gases in water at moderate pressurea
H ¼ pA;i=xA;i (bars)
T (K) NH3 Cl2 H2S SO2 CO2 CH4 O2 H2
273 21 265 260 165 710 22,880 25,500 58,000
280 23 365 335 210 960 27,800 30,500 61,500
290 26 480 450 315 1300 35,200 37,600 66,500
300 30 615 570 440 1730 42,800 45,700 71,600
310 – 755 700 600 2175 50,000 52,500 76,000
320 – 860 835 800 2650 56,300 56,800 78,600
323 – 890 870 850 2870 58,000 58,000 79,000aBergman and Lavine (2017) and Spalding (1963)
Table B.56 Solubility of selected gases and solids (Bergman and Lavine 2017)
Gas Solid T (K) S ¼ cA;s=pA;g (k mol/m3 bar)
O2 Rubber 298 3.12 � 10−3
N2 Rubber 298 1.56 � 10−3
CO2 Rubber 298 40.15 � 10−3
He SiO2 293 0.45 � 10−3
H2 Ni 358 9.01 � 10−3
Appendix B: Transport Properties 793
Table
B.57
Solubilityof
inorganiccompo
unds
inwater
a(M
illsandCoimbra20
15)
Solute
Form
ula
Solid
Phase
T(K
)
273.15
280
290
300
310
320
330
340
350
360
370
373.15
Aluminum
sulfate
Al 2(SO4)3
18H2O
31.2
32.8
35.5
39.1
44.3
50.3
57.0
63.9
70.8
78.3
84.6
89.0
Calcium
bicarbon
ate
Ca(HCO3)2
–16
.15
16.30
16.53
16.75
16.98
17.20
17.43
17.65
17.88
18.10
18.33
18.40
Calcium
chloride
CaC
l 26H
2O59
.563
.371
.593
.313
7.2
––
––
––
–
CaC
l 22H
2O–
––
––
–13
4.6
140.2
145.3
150.9
157.0
159.0
Calcium
hydrox
ide
Ca(OH) 2
–0.18
50.17
90.16
80.15
70.14
50.13
20.12
00.10
90.09
80.08
80.08
00.07
7
Potassium
chloride
KCl
–27
.629
.933
.136
.139
.141
.844
.647
.450
.253
.155
.856
.7
Potassium
nitrate
KNO3
–13
.318
.528
.241
.358
.278
.710
2.3
129.2
159.2
191.6
232.1
246.0
Potassium
sulfate
K2SO4
–7.35
8.63
10.51
12.38
14.20
15.95
17.64
19.25
20.88
22.36
23.69
24.1
Sodium
bicarbon
ate
NaH
CO3
–6.9
7.76
9.14
10.63
12.20
13.90
15.79
––
––
–
Sodium
carbon
ate
Na 2O3
10H2O
710
.818
.733
.4–
––
––
––
–
Na 2CO3
1H2O
––
––
49.1
47.8
46.7
46.2
45.9
45.7
45.55
45.5
Sodium
chloride
NaC
l–
35.7
35.8
35.9
36.2
36.5
36.9
37.2
37.6
38.2
38.8
39.5
39.8
Sodium
nitrate
NaN
O2
–73
7885
9310
111
112
113
214
415
917
518
0
Sodium
sulfate
Na 2SO
410
H2O
5.0
7.7
16.1
34.1
––
––
––
––
Na 2SO
47H
2O19
.526
.739
.6–
––
––
––
––
Na 2SO
4–
––
––
49.6
47.4
45.7
43.7
44.0
43.3
42.7
42.5
a Solub
ility
expressedin
kilogram
sof
anhy
drou
ssubstancethat
issolublein
100kg
water
794 Appendix B: Transport Properties
Table B.58 Equilibrium compositions for the NH3-water system (Mills and Coimbra 2015)
pA;g (atm) xA;‘290 K 300 K 310 K 320 K 330 K
0.02 0.030 0.019 0.012 0.008 0.006
0.04 0.056 0.036 0.024 0.016 0.012
0.06 0.078 0.052 0.035 0.024 0.017
0.08 0.096 0.064 0.046 0.032 0.023
0.1 0.11 0.079 0.056 0.040 0.029
0.2 0.18 0.14 0.099 0.057 0.052
0.4 0.26 0.21 0.16 0.12 0.092
0.6 0.31 0.26 0.20 0.16 0.13
0.8 0.35 0.29 0.23 0.19 0.15
1.0 – 0.32 0.27 0.22 0.17
Table B.59 Equilibrium compositions for the SO2-water systema (Mills and Coimbra 2015)
pA;g (atm) xA;‘ � 103
290 K 300 K 310 K 320 K
0.001 0.12 0.084 0.059 0.042
0.003 0.25 0.18 0.13 0.093
0.01 0.62 0.42 0.31 0.22
0.03 1.4 1.1 0.73 0.51
0.1 4.1 2.9 2.0 1.4
0.3 11.0 7.9 5.6 3.9
1.0 33.0 24.0 18.0 12.0aNotice that Henry’s law is invalid for the SO2-water system, even at very dilute concentrations
Table B.60 Thermodynamic properties of water vapor-air mixtures at 1 atm (Mills and Coimbra 2015)
Temp.(°C)
Saturation mass fraction Specific volume (m3/kg) Enthalpya, b (KJ/kg)
Dry air Saturated air Liquid water Dry air Saturated air
10 0.007608 0.8018 0.8054 42.13 10.059 29.145
11 0.008136 0.8046 0.8086 46.32 11.065 31.481
12 0.008696 0.8075 0.8117 50.52 12.071 33.898
13 0.009289 0.8103 0.8148 54.71 13.077 36.401
14 0.009918 0.8131 0.8180 58.90 14.083 38.995
15 0.01058 0.8160 0.8212 63.08 15.089 41.684
16 0.01129 0.8188 0.8244 67.27 16.095 44.473
17 0.01204 0.8217 0.8276 71.45 17.101 47.367
18 0.01283 0.8245 0.8309 75.64 18.107 50.372
19 0.01366 0.8273 0.8341 79.82 19.113 53.493
20 0.01455 0.8302 0.8374 83.99 20.120 56.736
21 0.01548 0.8330 0.8408 88.17 21.128 60.107
22 0.01647 0.8359 0.8441 92.35 22.134 63.612
23 0.01751 0.8387 0.8475 96.53 23.140 67.259(continued)
Appendix B: Transport Properties 795
References
Altemose, V. O. (1961). Helium diffusion through glass. Journal of Applied Physics, 32, 1309–1316.American Society of Heating, Refrigerating and Air Conditioning Engineers (ASHRAE). (2009). ASHRAE handbook of
fundamentals. New York, NY: ASHRAE.Argonne National Laboratory (ANL). (1995). Thermodynamic and transport properties of the sodium liquid and vapor.
ANL/RE-95/2, https://www.ne.anl.gov/eda/ANL-RE-95-2.pdf. Accessed on September 17, 2018.Bejan, A. (2013). Convection heat transfer (4th ed.). New York, NY: Wiley.Bennon, W. D., & Incropera, F. P. (1988). Developing laminar mixed convection with solidification in a vertical
channel. Journal of Heat Transfer, 110, 410–415.Bergman, T. L., & Lavine, A. S. (2017). Fundamentals of heat and mass transfer (8th ed.). Hoboken, NJ: Wiley.Brennan, P. J., & Kroliczek, E. J. (1979). Heat pipe design handbook (Vol. 2). Towson, MD: NASA Goddard by B&K
Engineering, Inc., Suite 825, One Investment Place.Cengel, Y. A., Boles, M. A., & Kanoglu, M. (2019). Thermodynamics—An engineering approach (9th ed.). New York,
NY: McGraw-Hill.Cho, C., Irvine, T. F., Jr., & Karni, J. (1992). Measurement of the diffusion coefficient of naphthalene into air.
International Journal of Heat and Mass Transfer, 35, 957–966.
Table B.60 (continued)
Temp.(°C)
Saturation mass fraction Specific volume (m3/kg) Enthalpya, b (KJ/kg)
Dry air Saturated air Liquid water Dry air Saturated air
24 0.01861 0.8415 0.8510 100.71 24.147 71.054
25 0.01978 0.8444 0.8544 104.89 25.153 75.004
26 0.02100 0.8472 0.8579 109.07 26.159 79.116
27 0.02229 0.8500 0.8615 113.25 27.166 83.400
28 0.02366 0.8529 0.8650 117.43 28.172 87.862
29 0.02509 0.8557 0.8686 121.61 29.178 92.511
30 0.02660 0.8586 0.8723 125.79 30.185 97.357
31 0.02820 0.8614 0.8760 129.97 31.191 102.408
32 0.02987 0.8642 0.8798 134.15 32.198 107.674
33 0.03164 0.8671 0.8836 138.32 33.204 113.166
34 0.03350 0.8699 0.8874 142.50 34.211 118.893
35 0.03545 0.8728 0.8914 146.68 35.218 124.868
36 0.03751 0.8756 0.8953 150.86 36.224 131.100
37 0.03967 0.8784 0.8994 155.04 37.231 137.604
38 0.04194 0.8813 0.9035 159.22 38.238 144.389
39 0.04432 0.8841 0.9077 163.40 39.245 151.471
40 0.04683 0.8870 0.9119 167.58 40.252 158.862
41 0.04946 0.8898 0.9162 171.76 41.259 166.577
42 0.05222 0.8926 0.9206 175.94 42.266 174.630
43 0.05512 0.8955 0.9251 180.12 43.273 183.037
44 0.05817 0.8983 0.9297 184.29 44.280 191.815
45 0.06137 0.9012 0.9343 188.47 45.287 200.980
46 0.06472 0.9040 0.9391 192.65 46.294 210.550
47 0.06842 0.9068 0.9439 196.83 47.301 220.543
48 0.07193 0.9097 0.9489 201.01 48.308 230.980
49 0.07580 0.9125 0.9539 205.19 49.316 241.881aThe enthalpies of dry air and liquid water are set equal to zero at a datum temperature of 0 °CbThe enthalpy of an unsaturated water vapor-air mixture can be calculated as h ¼ hdryair þðm1=m1;satÞðhsat � hdryairÞ
796 Appendix B: Transport Properties
Doremus, R. H. (1973). Glass science. New York: Wiley.Faghri, A. (2016). Heat pipe science and technology (2nd ed.). Columbia, MO: Global Digital Press.Geankoplis, C. J. (1993). Transport processes and unit operations (3rd ed.). Englewood Cliffs, NJ: Prentice-Hall.Hale, D. V., Hoovers, M. J., & O’Nell, M. J. (1971). Phase change materials handbook. NASA-CR-61363.Humphries, W. R., & Griggs, E. I. (1977). A design handbook for phase change thermal control and energy storage
devices. NASA-TP-1074.Iida, T., & Guthrie, R. I. L. (1988). The physical properties of liquid metals. Oxford, UK: Oxford University Press.Ivanovskii, M.N., Sorokin, V.P., and Yagodkin, I.V., 1982, The Physical Principles of Heat Pipes, Clarendon Press,
Oxford, UK.Kakac, S., Shah, R. K., & Aung, W. (Eds.). (1987). Handbook of single-phase convective heat transfer. New York, NY:
Wiley.Lemmon, E. W., McLinden, M. O., & Friend, D. G. (2016). Thermophysical properties offluid systems. In P. I. Linstrom
& W. G. Mallard (Eds.), NIST chemistry WebBook, NIST Standard Reference Database Number 69. Gaithersburg,MD: National Institute of Standards and Technology, 20899. http://webbook.nist.gov.
Marrero, T. R., & Mason, E. A. (1972). Gaseous diffusion coefficients. Journal of Physical and Chemical ReferenceData, 1, 3–118.
Mills, A. F., & Coimbra, C. F. M. (2015). Basic heat and mass transfer (3rd ed.). San Diego, CA: Temporal Publishing,LLC.
Reay, D. A., Kew, P. A., & McGlen, R. J. (2014). Heat pipes—Theory, design, and applications (6th ed.). New York:Elsevier.
Rohsenow, W. N., Hartnett, J. P., & Ganic, E. N. (Eds.). (1998). Handbook of heat transfer fundamentals (3rd ed.).New York, NY: McGraw-Hill.
Spalding, D. B. (1963). Convective mass transfer. New York, NY: McGraw-Hill.Touloukian, Y. S., Liley, P. E., & Saxena, S. C., (Eds.). (1970). Thermophysical properties of matter (Vol. 3). New
York, NY: Plenum.Vargaftik, N. B. (1975). Handbook of physical properties of liquids and gases. New York, NY: Hemisphere.
Appendix B: Transport Properties 797
Appendix C: Vectors and Tensors
C.1 Vectors
The term scalar refers to a single real number used to describe the magnitude of a quantity. Pressure,temperature, and internal energy are all scalar. A vector is defined as an entity that possesses bothmagnitude and direction or as a directed line segment subject to the parallelogram law of addition. Inthree-dimensional space, a vector may be specified by three vector components. A unit vector is avector whose magnitude is unity. A vector in a three-dimensional Cartesian coordinate system can beexpressed as
A ¼ iAx þ jAy þ kAz ðC:1Þ
where i, j, and k are unit vectors in the x-, y-, and z-directions. The vector components in the x-, y-,and z-directions are Ax, Ay, and Az, respectively. A vector in a Cartesian coordinate system is shown inFig. C.1. It can be seen that the magnitude of the vector is
Aj j ¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiA2x þA2
y þA2z
qðC:2Þ
and that its three components are the projections of the vector on the x, y, and z-axes.A vector can also be represented in matrix form:
A ¼Ax
Ay
Az
24
35 ðC:3Þ
The dot product (also referred to as the scalar or inner product) of two vectors A and B is a scalar;it is obtained by summation of the product of each of their corresponding components, i.e.,
A � B ¼ AxBx þAyBy þAzBz ðC:4Þ
The cross product (or vector product) of two vectors A and B is a vector, i.e.,
A� B ¼i j k
Ax Ay Az
Bx By Bz
��������������
¼ i AyBz � AzBy
� �þ j AzBx � AxBzð Þþ k AxBy � AyBx
� � ðC:5Þ
© Springer Nature Switzerland AG 2020A. Faghri and Y. Zhang, Fundamentals of MultiphaseHeat Transfer and Flow, https://doi.org/10.1007/978-3-030-22137-9
799
C.2 Operations with the $ Operator
C.2.1 Cartesian Coordinate System
An important vector for fluid mechanics and heat transfer is the r operator (pronounced Del ornabla), which is defined as
r ¼ i@
@xþ j
@
@yþ k
@
@zðC:6Þ
in a three-dimensional Cartesian coordinate system. It can be applied to a scalar function, /, to obtainits gradient,
grad/ ¼ r/ ¼ i@/@x
þ j@/@y
þ k@/@z
ðC:7Þ
which is a vector.The r operator can also be applied to a vector function such as velocity,
V ¼ iuþ jvþ kw ðC:8Þ
to get its divergence:
divV ¼ r � V ¼ @u
@xþ @v
@yþ @w
@zðC:9Þ
or its curl:
curlV ¼ r� V ¼ i@w
@y� @v
@z
� þ j
@u
@z� @w
@x
� þ k
@v
@x� @u
@y
� ðC:10Þ
Another related operator that is very useful in fluid mechanics and heat transfer is Laplacianoperator, defined as
Figure C.1 Vector and its components
800 Appendix C: Vectors and Tensors
r2 ¼ r � r ¼ @2
@x2þ @2
@y2þ @2
@z2ðC:11Þ
Application of the Laplace operator to a scalar function / results in
r2/ ¼ @2/@x2
þ @2/@y2
þ @2/@z2
ðC:12Þ
Forming the dot product of the velocity and the gradient of a scalar / results in a scalar:
V � r/ ¼ u@/@x
þ v@/@y
þw@/@z
ðC:13Þ
which is used to describe the advection of the property /.The operation
r � ðar/Þ ¼ @
@xa@/@x
� þ @
@ya@/@y
� þ @
@za@/@z
� ðC:14Þ
results in a scalar that describe the diffusion of the property /.Application of the Laplace operator to a velocity vector, V, results in a vector:
r2V ¼ ir2uþ jr2vþ kr2w ðC:15Þ
C.2.2 Cylindrical Coordinate System
The cylindrical coordinate system (r, u, z) shown in Fig. C.2 is related to Cartesian coordinates (x, y, z)by
x ¼ r cosu y ¼ r sinu z ¼ z ðC:16Þ
The velocity vector, V, in a cylindrical coordinate system has three components, i.e.,
V ¼ krVr þ kuVu þ kzVz ðC:17Þ
where kr; ku and kz are the unit vectors in r-, u-, and z-directions, respectively.The operations involving the r operator and either the general scalar function / or the vector V in
a cylindrical coordinate system is summarized below:
grad/ ¼ r/ ¼ kr@/@r
þ ku1r
@/@u
þ kz@/@z
ðC:18Þ
divV ¼ r � V ¼ 1r
@ðrVrÞ@r
þ 1r
@Vu
@uþ @Vz
@zðC:19Þ
Appendix C: Vectors and Tensors 801
r2/ ¼ 1r
@
@rr@/@r
� þ 1
r2@2/@u2
þ @2/@z2
ðC:20Þ
V � r/ ¼ Vr@/@r
þ Vu
r
@/@u
þVz@/@z
ðC:21Þ
r � ar/ ¼ 1r
@
@rra
@/@r
� þ 1
r
@
@uar
@/@u
� þ @
@za@/@z
� ðC:22Þ
r2V ¼ kr@
@r
1r
@
@rrVrð Þ
�þ 1
r2@2Vr
@u2� 2r2@Vu
@uþ @2Vr
@z2
�
þ ku@
@r
1r
@
@rrVu� � �
þ 1r2@2Vu
@u2þ 2
r2@Vr
@uþ @2Vu
@z2
�
þ kz1r
@
@rr@Vz
@r
� þ 1
r2@2Vz
@u2þ @2Vz
@z2
� ðC:23Þ
C.2.3 Spherical Coordinate System
The spherical coordinate system (r, h, u) shown in Fig. C.3 is related to the Cartesian coordinatesystem by
x ¼ r sin h cosu y ¼ r sin h sinu z ¼ r cos h ðC:24Þ
A velocity vector, V, has three components, i.e.,
V ¼ krVr þ khVh þ kuVu ðC:25Þ
where kr; kh; and ku are the unit vectors in r, h, and u directions, respectively.The operations involving the r operator and either the general scalar function / or the vector V in
a spherical coordinate system are summarized below:
Figure C.2 Relationship between cylindrical and Cartesian coordinates
802 Appendix C: Vectors and Tensors
grad/ ¼ r/ ¼ kr@/@r
þ kh1r
@/@h
þ ku1
r sin h@/@u
ðC:26Þ
divV ¼ r � V ¼ 1r2@ðr2VrÞ
@rþ 1
r sin h@ðVh sin hÞ
@hþ 1
r sin h@Vu
@uðC:27Þ
r2/ ¼ 1r2
@
@rr2@/@r
� þ 1
r2 sin h@
@hsin h
@/@h
� þ 1
r2 sin2 h
@2/@u2
ðC:28Þ
V � r/ ¼ Vr@/@r
þ Vh
r
@/@h
þ Vu
r sin h@/@u
ðC:29Þ
r � ðar/Þ ¼ 1r2
@
@rr2a
@/@r
� þ 1
r2 sin h@
@hsin hð Þa @/
@h
�
þ 1
r2 sin2 h
@
@ua@/@u
� ðC:30Þ
r2V ¼ kr r2Vr � 2Vr
r2� 2r2@Vh
@h� 2Vh cot h
r2� 2r2 sin h
@Vu
@u
�
þ kh r2Vh þ 2r2@Vr
@h� Vh
r2 sin h� 2 cos h
r2 sin2 h
@Vu
@u
�
þ kz r2V/ � Vu
r2 sin2 hþ 2
r2 sin h@Vr
@uþ 2 cos h
r2 sin2 h
@Vh
@u
� ðC:31Þ
C.3 Tensors
A tensor of rank n in the Cartesian coordinate system has 3n components. A scalar can be consideredas a tensor of rank 0 because it has only one component. A vector is a tensor of rank 1 since it hasthree components. As was demonstrated in Sect. 1.3.2, the normal and shear stresses in a fluid can be
Figure C.3 Relationship between spherical and Cartesian coordinates
Appendix C: Vectors and Tensors 803
described by a tensor of rank 2. The defining characteristics of a tensor are the manner in which itscomponents transform under a rotation of the coordinate system where the components are defined.The transformation law for the components of tensor of a rank two is given as
s0ij ¼ aikajlskl ðC:32Þ
where the prime denotes the tensor components in the rotated coordinate, and aik and ajl represent,respectively, the cosines of the angles between the ith rotated axis and the kth original axis, andbetween the jth rotated axis and the lth original axis. It should be noted that it is not the tensor itselfthat transforms under this change in the reference coordinate system but, rather, the coordinates thatdescribe the tensor.
Application of the r operator to each component of the velocity vector V ¼ iuþ jvþ kw alsoyields a tensor of rank two:
rV ¼
@u
@x
@u
@y
@u
@z@v
@x
@v
@y
@v
@z@w
@x
@w
@y
@w
@z
26666664
37777775
ðC:33Þ
which is a dyadic product of two vectors r and V, and it can be used to determine the strain ratetensor.
The dot product of a vector and a tensor of rank 2 is a vector. For example, the dot product of ther operator and a stress tensor is
r � s ¼ s � r ¼
@
@x@
@y@
@z
2666664
3777775
sxx sxy sxzsyx syy syzszx szy szz
24
35 ¼
@sxx@x
þ @sxy@y
þ @sxz@z
@syx@x
þ @syy@y
þ @syz@z
@szx@x
þ @szy@y
þ @szz@z
26666664
37777775
ðC:34Þ
where r � s ¼ s � r is valid because the stress tensor is a symmetric tensor. For the case that thetensor is not symmetric, the order of vector and tensor cannot be switched in their dot product.
The contraction of two tensors of rank two a and b is obtained by summing the products of thecorresponding components from both tensors:
a:b ¼ axxbxx þ axybxy þ axzbxz þ ayxbyx þ ayybyy þ ayzbyzþ azxbzx þ azybzy þ azzbzz
ðC:35Þ
which can also be written as
a:b ¼ aijbij ðC:36Þ
using the summation convention of tensors. According to the summation convention, the repetition ofan index in a term denotes a summation with respect to that index over its range (i, j = x, y, z). The
804 Appendix C: Vectors and Tensors
definitions and operations of the vectors and tensors reviewed here provide foundations for thegoverning equations for multiphase systems. Additional information about tensors and their associ-ated operations can be found in a continuum mechanics textbook, such as Fung (1994).
Reference
Fung, Y. C. (1994). First course in continuum mechanics (3rd ed.). New York: Prentice Hall.
Appendix C: Vectors and Tensors 805
Appendix D: Convective Heat TransferCorrelations
See Table D.1.
Table D.1 Convective heat transfer correlations for various heat and mass transfer modes and geometries
Heattransfermode
Geometry Nusselt number Comments andrestrictions
Dimensionlessnumbers
Forcedconvection
Flow parallel to aflat plate
Nux ¼ 0:332Re1=2x Pr1=3
ðPr[ 0:6ÞNux ¼ 0:565Re1=2x Pr1=2
ðPr� 0:05Þ
Isothermal surface
Rex\5� 105
(laminar)
Nux ¼ hx
k
Rex ¼ u1x
m
Nu ¼0:037ðRe0:8L � 871ÞPr0:33ð0:6�Pr� 60Þ
5� 105\ReL\108
(turbulent)Nu ¼
�hL
k
ReL ¼ u1L
m
Flow in a pipe(conventional size)
Nu ¼ 3:66
þ 0:0668ðD=LÞRePr1þ 0:04½ðD=LÞRePr�2=3
Isothermal surfaceRe� 2300
Thermal entry region
Nu ¼�hD
k
Re ¼ �uD
m�u is mean velocityNu ¼ 0:027Re0:8
� Pr0:33 l=lwð Þ0:14ð0:7�Pr� 16;700Þ
L=D 10
Re[ 10; 000
(Fully developedturbulent)lw is viscosityevaluated at Tw
Flow in a pipe(miniature)
Nu ¼ ð1þFÞ
� ðf =8ÞðRe� 1000ÞPr1þ 12:7ðf =8Þ0:5ðPr2=3 � 1Þ
f ¼ ½1:82 logReÞ � 1:64��2
F ¼ 7:6� 10�5Re
� ½1� ðD=D0Þ2�
D0 = 1.164 mm isreferencediameterCorrelation wasobtained for waterat D = 0.102, 0.76and 1.09 mm
Nu ¼�hD
k
Re ¼ �uD
m
Flow between parallelplates
Nu ¼ 7:54
þ 0:03ðDh=LÞRePr1þ 0:016½ðDh=LÞRePr�2=3
Isothermal surfaceRe� 2800
(laminar)
Nu ¼�hDh
k
Re ¼ �uDh
mNu ¼ 0:023Re0:8Pr0:33
ðPr[ 0:5ÞRe[ 10;000
(Turbulent)
(continued)
© Springer Nature Switzerland AG 2020A. Faghri and Y. Zhang, Fundamentals of MultiphaseHeat Transfer and Flow, https://doi.org/10.1007/978-3-030-22137-9
807
Table D.1 (continued)
Heattransfermode
Geometry Nusselt number Comments andrestrictions
Dimensionlessnumbers
Flow across a circularcylinder
Nu ¼ 0:3
þ 0:62Re1=2Pr1=3
½1þð0:4=Pr=Þ2=3�1=4
� 1þ Re
282000
� 5=8" #4=5
RePr[ 0:2
(both laminar andturbulent)
Nu ¼�hD
k
Re ¼ u1D
m
Flow across a sphere Nu ¼ 2þð0:4Re0:5
þ 0:06Re2=3ÞPr0:4ðl=lwÞ14
3:5\Re
\76;000
0:71�Pr� 380
lw is viscosityevaluated at Tw
Flow through a packedbed of spheres
Nu ¼ 1:625Re1=2Pr1=3 15�Re� 120
D—diameter ofsphereA—bed cross-sectional area
Nu ¼�hD
k
Re ¼ _mD
Al
Freeconvection
On a vertical surface Nu1=2 ¼ 0:825
þ 0:387Ra1=6
½1þð0:492=PrÞ9=16�8=27
DT ¼ Tw � T1j jApplicable to bothlaminar andturbulent
Nu ¼�hL
k
Ra ¼ gbDTL3
ma
On a horizontal heatedsquare facing up
Nu ¼ 0:54ðGr PrÞ1=4 Isothermal surface
105 �Gr� 7� 107
For rectangle, useshorter side of L
Nu ¼�hL
k
Gr ¼ gbDTL3
m2
(continued)
808 Appendix D: Convective Heat Transfer Correlations
Table D.1 (continued)
Heattransfermode
Geometry Nusselt number Comments andrestrictions
Dimensionlessnumbers
On a horizontal heatedsquare facing down
Nu ¼ 0:27ðGr PrÞ1=4Isothermal surface3� 105 �Gr
� 3� 1010
For rectangle, useshorter side of L
Nu ¼�hL
k
Gr ¼ gbDTL3
m2
On a horizontal cylinder Nu1=2 ¼ 0:60þ
0:387Ra1=6
½1þð0:559=PrÞ9=16�8=27
Ra\1012Nu ¼
�hD
k
Ra ¼ gbDTD3
ma
On a sphere Nu ¼ 2
þ 0:589Ra1=4
½1þð0:469=PrÞ9=16�4=9
DT ¼ Tw � T1Ra\1011
Pr 0:7
Nu ¼�hD
k
Ra ¼ gbDTD3
ma
Evaporation Falling filmevaporation
Laminar
Nu ¼ 1:10Re�1=3d
ðRed � 30Þ
Nu—local NusseltnumberC—mass flow rateper unit width ofthe vertical surface
Nu ¼ hðm2‘ =gÞ13
k
Red ¼ 4Cl
Wavy laminar
Nu ¼ 0:828Re�0:22d
ð30�Red � 1800ÞTurbulent
Nu ¼ 0:0038Re0:4d Pr0:65
ðRed [ 1800Þ
Condensation On a vertical surface Laminar (Nusselt)
Nu ¼ 1:10Re�1=3d
ðRed � 30Þ
Nu—local NusseltnumberC—mass flowrate per unit widthof the verticalsurface
Nu ¼ hðm2‘ =gÞ13
k
Red ¼ 4Cl
Wavy laminar
Nu ¼ RedRe1:22d � 5:22
ð30�Red � 1800ÞTurbulent
Nu ¼ 0:023Re0:25d Pr�0:5
(continued)
Appendix D: Convective Heat Transfer Correlations 809
Table D.1 (continued)
Heattransfermode
Geometry Nusselt number Comments andrestrictions
Dimensionlessnumbers
On tubes Nu ¼ 0:729
� D3h‘vg q‘ � qvð Þnk‘m‘DT
�14
DT ¼ Tsat � Twn—number oftubes
Nu ¼ �hDk‘
In microscale channel(Dh\1:5 mm)
Nu ¼ We�JaRe PrY Y ¼ 1:3
for Re� 65
Y ¼ ð0:5Dh � 1Þ=ð2DhÞ
for Re[ 65
We ¼ q‘V2L
r
Ja ¼ cp‘ðTsat�TwÞhlv
Re ¼ GDhl‘
G—mass flux (kg/s m2)
Boiling Nucleate, saturated poolboiling
Nu ¼ Ja2‘
C3Prm‘
m = 2 for waterm = 4.1 for otherfluidsC = 0.013 water-copper or stainlesssteelC = 0.006 for water-nickel or brass
Nu ¼�hLck‘
Lc ¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
r‘gðq‘ � qvÞ
r
Ja‘ ¼ cp;‘DTh‘v
DT ¼ Tw � Tsat
Film boiling on ahorizontal plate
Nu ¼ 0:425
� GrPrv1þ 0:4 Jav
Jav
� �14
Term in parenthesesaccounts forsensible heatingeffect in vapor film
Nu ¼�hLckv
Lc ¼ffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffiffi
r‘gðq‘ � qvÞ
r
Gr ¼ g½ðq‘ � qvÞ=qv�L3cm2v
Jav ¼ cp;vDTh‘v
Film boiling on ahorizontal cylinder
Nu ¼ 0:62
� Gr Prv1þ 0:4 Jav
Jav
� �14
D film thicknessNu ¼
�hD
kv
Gr ¼ g½ðq‘ � qvÞ=qv�D3
m2v
Jav ¼ cp;vDTh‘v
Film boiling on a sphere Nu ¼ 0:4
� GrPrv1þ 0:4 Jav
Jav
� �13
D filmthickness
(continued)
810 Appendix D: Convective Heat Transfer Correlations
Table D.1 (continued)
Heattransfermode
Geometry Nusselt number Comments andrestrictions
Dimensionlessnumbers
Boiling in microchannel(D = 1.39–1.69 mm)
Nu ¼ 30Re0:857
� Bo0:714ð1� xÞ�0:143
Correlationobtained by usingFreon® 141x is quality
Nu ¼ �hDk‘
Bo ¼ q00h‘vG
G—mass flux (kg/s m2)
Melting Melting in a rectangularcavity
Nu ¼ ð2sÞ�1=2
þ ½c1Ra1=4 � ð2sÞ�1=2�� ½1þðc2Ra3=4s3=2Þn�1=n
c1 ¼ 0:35; c2 ¼ 0:175
Nusselt number isfunction of time
Nu ¼�hH
k
Ra ¼ gbDTH3
mas ¼ SteFo
Fo ¼ a‘ tH2
Solidification Solidification around ahorizontal tube
Nu ¼ 0:52Ra1=4 D is transientequivalent outerdiameter of the
solid Ra� 109
Nu ¼�hD
k
Ra ¼ gbDTD3
ma
Sublimation Nux ¼ 0:458Re1=2x Pr1=3
Shx ¼ 0:459Re1=2x Sc1=3
Uniform heat fluxsurface
Rex\5� 105
Nux ¼ hx
k
Shx ¼ hmx
D
Appendix D: Convective Heat Transfer Correlations 811
Index
AAblation, 283–286, 315, 316, 660Accumulative distribution, 626, 627, 681Activation energy, 325, 338, 661, 790Adhesion, 284, 405Adiabatic tube, sublimation, 329, 333Adiabatic wall evaporation, 154Adsorption, 203, 204, 207Anisotropic materials, 17, 25Annular condensation heat transfer, 411Annular-dispersed flow, 543, 564Annular flow, 3–7, 185, 388, 409, 540, 541, 562–567,
584, 589, 601, 610, 611Archimedes number, 303, 381, 382, 645, 646Area-averaged homogeneous model, 169, 170, 173Area-averaged models, 168Arrhenius equation, 661Atmospheric reduced pressure (APCVD), 338Average kinetic energy, 145Avogadro’s number, 79, 82, 145Axisymmetric film condensation, 597
BBarrel reactors, 338Bernard cellular flow, 197, 198Binary diffusion coefficients, 788, 789Binary solidification, 292Binary vapor mixtures, 326, 356, 357, 372, 374Bingham plastic fluids, 668Biot number, 199, 200, 270, 289, 349Boilers, 569Boiling, 4, 6, 11, 18, 26, 62, 67, 68, 87, 91, 199, 344, 357,
373, 415, 469–473, 487–489, 492, 493, 499–501,506–511, 515, 519, 521, 529–531, 535, 569 –573,578–581, 583, 600, 603, 608–613, 689, 714–716,718–720, 807
Boiling point line, 357Boltzmann constant, 133, 670, 747Boltzmann equation, 12, 145Boltzmann statistical averaging, xiiiBounds on two-phase flow, 554Boussinesq assumption, 112Brinkman’s equation, 691, 695–697Bubble detachment, 472
Bubble dynamics, 469, 497Bubble-free bed expansion, 648Bubble growth, 1, 87, 469, 475, 478, 480–489, 491, 493,
497, 500, 528, 573, 576, 584Bubble lift-off, 573, 575, 577, 578Bubble point line, 357Bubbling fluidization, 648, 682Bubbly flow, 4, 6, 7, 539, 563, 564, 569, 584, 585, 610Buckingham’s theorem, 233, 319, 530, 668Burnout point, 472
CCaloric, 8Capillary action, 617, 703Capillary depression, 205, 366, 367, 369Capillary phenomenon, 205, 589Capillary pressure, 84, 190, 192, 193, 204, 206, 207, 209,
210, 226, 246, 491, 603, 608, 609, 701, 702, 709,712, 714, 728
Carbon dioxide, 9, 52, 59, 135, 502, 791Centrifugal field via rotating disk, 413CFD, 680CFD-DEM, 680Chemical equilibrium, 39, 45, 53–56Chemical reactions, 52, 53, 106, 119, 186, 325, 337, 338,
341, 415, 649, 706, 712Chemical reaction sublimation, 325, 333, 334Chemical stability, 50, 51Chemical Vapor Deposition (CVD), 120, 324, 325, 337–
344Chimney effect, 427, 432Churn flow, 539–542Clapeyron equation, 39, 60, 62, 63, 91, 366, 474, 495Clausius-Clapeyron equation, 12, 63, 91, 480, 594, 717Cohesion, 147Cohesive force, 639–641Collisions, 11, 33, 144, 145, 623, 630, 633, 638, 644, 680Combustion, 3, 7, 8, 52, 53, 56, 96, 133–138, 140, 184,
189, 333, 334, 336, 417, 660Combustors, 7Completely wetting, 203Condensation, 4, 7, 11, 18, 26, 66–68, 76, 79, 83, 85, 88,
92, 129–131, 210, 212, 214, 224, 225, 231, 236,248–250, 323, 355–360, 366, 368, 369, 371–373,
© Springer Nature Switzerland AG 2020A. Faghri and Y. Zhang, Fundamentals of MultiphaseHeat Transfer and Flow, https://doi.org/10.1007/978-3-030-22137-9
813
814 Index
376, 378, 379, 381, 383–385, 387, 388, 391, 392,396–398, 403, 405, 407–411, 440, 459, 469, 483,514, 530, 535, 541, 544, 547, 550, 562–566, 573,583–590, 592, 595–597, 617, 623, 689, 701, 704,708, 724, 727, 730, 743, 807
Condensers, 231, 372, 562Conduction-controlled melting, 309Contact angles, 190, 202–204, 207, 223, 246, 405, 475,
488, 507, 575Contact melting, 27–30, 259, 298–300, 303Continuous size distributions, 627Continuum flow, 30Continuum regime, 12, 13Continuum surface force (CSF) model, 240, 241Convection-controlled melting, 319, 732Convective cooling, 289, 405, 408, 590Convective heat transfer coefficient, 17, 24, 27, 35, 36,
151, 199, 245, 261, 268, 290, 315, 323, 395, 406,463, 465, 516, 595, 599, 643, 651, 652
Convective heat transfer correlation, 184, 471, 500, 501Convective mass transfer, 20, 24, 26, 27Conversion factors, 748Cool evaporation, 421Coordination number, 631–633, 636, 637, 681Couette flow, 13, 120, 181Counter-current condensation, 248Coupling factor, 643, 671–673Creep flow, 111Crispation number, 199, 201Critical droplet radius, 361Critical Heat Flux (CHF), 503, 504, 506, 509, 581, 582,
603, 612, 613Critical Helmholtz velocity, 504, 505Critical velocity for turbulent fluidization, 650Cryopreservation, 732Cumulative distribution function, 629Cyclic dryout, 610Cylindrical coordinate systems, 286
DDamping coefficient, 633–636Damping functions, 430Darcian velocity, 728Darcy’s law, 689–691, 695–697, 704, 721, 722, 725, 728,
732, 733, 735, 740, 741Deformation tensor, 211Dense phase conveying system, 654, 660, 683Dense Suspension Up-flow (DSU), 650Deposition, 4, 5, 11, 323, 324, 337, 338, 340, 346, 347,
349, 350, 506, 639Dew point, 37, 133, 136, 356–358, 371Dew point line, 357Diffusion coefficients, 220Diffusive mass fluxes, 24Dilute phase conveying system, 654Dilute Pneumatic Conveying (DPC), 650Dimensional analysis, 26, 28, 36, 233, 319, 504, 526,
527, 530, 572, 589
Dimensionless numbers, 26, 199, 387, 388, 807Direct contact condensation, 323Direct contact evaporation, 418–421, 456Direct Methanol Fuel Cells (DMFCs), 205Direct numerical simulation, 519Discrete Element Method (DEM), 630, 633, 635, 636,
680Discrete number frequency, 625, 626, 628, 681Discrete particles, 4, 176, 623Discrete size distributions, 624Disjoining pressure, 40, 80, 81, 83, 84, 127, 190,
206–210, 213, 219, 226, 227, 234, 249, 251, 495,590, 593
Dispersed bubble flow, 543Dispersed flow, 33, 623, 624, 638Dispersed phases, 4, 7, 30, 164, 177Dispersion forces, 74Distribution functions, 145, 273, 274, 287, 315, 370, 405,
628, 629, 637, 638, 681Disturbance amplification, 236Disturbance wavelength, 230Dittus-Boelter/McAdams equation, 565, 579Drag coefficient, 148, 149, 184, 490, 639, 640, 642, 682Drag force, 161, 165, 489, 490, 512, 574–577, 624, 639,
641, 642, 661, 662, 677Drift velocity, 164, 165Dropwise condensation, 355, 359, 360, 366–368, 370,
371, 405Dune flow, 653Dynamic behaviors of interface, 227, 661Dynamic viscosity, 14, 376, 676, 689, 691, 703
EEffective thermal conductivity, 140, 671, 674, 676, 677,
699, 707, 712, 737EHD-induced flow, 573EHD number, 572Electro-Discharge Machining (EDM), 603, 608Electronics cooling, 1, 585Electrophoretic force, 572Elongated bubbles, 610Embryo droplets, 88, 363Emissive power, 18, 19Energy flux, conversion factor, 159, 335, 440, 748Enthalpy Method, 259, 304, 308, 319Equations of state, 67, 91Equilibrium, 34, 39–43, 46, 49–51, 53–57, 60, 62–70,
74–80, 84–86, 89–91, 161, 164, 165, 169, 189,190, 193, 195, 196, 201–204, 206–208, 216, 224,253, 293, 355, 357, 358, 360, 362–367, 369, 374,405, 420, 421, 435, 473–475, 484, 598, 672, 682,688, 698, 699, 701, 703, 707, 716, 732, 736
Equilibrium bubble radius, 77Equilibrium criteria, 39, 40, 42, 46, 65Equilibrium radius, 359, 361, 363–366Equivalent diameter, 624, 682Equivalent heat capacity method, 259, 304, 309Ergun equation, 645
Eulerian approach, 95, 96, 176, 238Eulerian averaging, 140, 141, 144Evaporating film, 226, 445Evaporation, 4, 5, 10, 11, 18, 34, 35, 76, 79, 140, 153,
161, 182, 184, 185, 199, 207, 212, 214–216, 219,221, 223–225, 231, 236, 247–249, 251, 325, 383,409, 415–421, 425–428, 430, 431, 433, 434,436–438, 440, 442, 445, 448–450, 452–454,456–463, 465, 466, 469, 473, 476, 477, 483, 489,494, 498–500, 503, 511, 521, 524–528, 535, 544,547, 550, 603, 608–610, 614, 617, 623, 680, 701,703, 704, 714, 718, 739, 807
Extrinsic average velocity, 688, 694Extrinsic phase average, 142
FFalling film evaporation, 438, 441, 442, 452, 465, 807Fick’s law, 22–25, 35, 118, 215Fictitious density, 385Film boiling, 5, 186, 469, 470, 472, 484, 503, 507–512,
514–520, 529, 530, 603, 689, 715, 719–722, 807Film condensation, 4, 5, 26, 95, 360, 377, 382–384,
388–390, 397, 402, 404, 406, 407, 409, 566, 567,589, 590, 597, 723, 724
Film evaporation, 4, 6, 7, 83, 95, 210, 417, 421, 431,463–465
Film evaporators, 415, 427, 438Film thickness, 132, 182, 186, 206–208, 226, 227, 233,
234, 236, 248, 249, 251, 303, 325, 352, 367, 372,378, 379, 386–388, 391, 392, 407–411, 439,443–445, 449, 477, 495, 517, 524, 525, 529, 530,590, 591, 595–597, 610, 723, 726, 727, 807
Filmwise condensation, 355, 359, 360, 366, 367, 370,371, 592
Fixed melting, 298, 299Flat miniature evaporator, 601Flow boiling, 569, 573, 579, 601, 608, 610, 611, 613, 615Flow condensation, 372, 564, 565, 588Flow evaporation, 325, 521, 601Flow maps, 540, 541, 543, 544, 665Flow pattern regime map for slurry flow, 665Flow patterns, 470, 535, 536, 539, 542, 544, 554, 559,
562, 563, 569, 584, 589, 610, 648, 653, 663, 676Flow regimes, 2, 3, 12, 177, 234, 390, 535, 536, 539–541,
543, 544, 562–564, 566, 569, 571, 573, 578, 584,586, 587, 611, 649, 667
Fluidization, 3, 645, 648–651, 683, 743Fluidized bed, 7, 623, 624, 644–652, 682, 683, 743Fluid-particle flow, 638Fluid-particle interactions, 624Fluxes, 21–25, 35, 128, 133, 189, 213, 214, 224, 260,
341, 376, 402, 404, 506, 541, 601, 603, 606, 609,676, 728
Forced convection, 18, 26, 27, 36, 368, 402, 423, 460,469, 470, 473, 500, 515, 565, 569, 573, 606, 807
Forced convective boiling, 4, 469, 544, 569, 571, 573,582
Forced convective condensation, 403, 535
Forchheimer inertia coefficient, 737Fourier’s law, 1, 16, 25, 130, 180, 213, 260, 366, 370,
379, 386, 690, 699, 712Free convection, 18, 219, 469, 470, 498, 515, 807Free energy approach, 49, 51Free liquid surface curvature, 193Free molecular flow regime, 12Free surfaces, numerical simulation, 127Freezing, 5, 6, 268, 269, 291, 292, 297, 316, 318, 323,
732Frequency function, 625–627, 681Frictional, 179, 181, 550–553, 559, 590, 592, 603, 617,
633, 634, 657, 660, 667, 693–695Frictional coefficient, 37, 181Frictional factor, 552, 659, 660Frictional pressure drop, 550, 558, 658Frictional pressure gradients, 551, 556, 557Front tracking methods, 519Froude number, 26, 36, 581, 587, 654, 656, 660Fuel burning rate, 138, 139Fuel cell, 187, 205, 706, 742
GGas Diffusion Layers (GDLs), 706–708, 742Gas dynamic model, 352, 633Gas-particle systems, 624, 644Gaussian error function, 224Generalized Fick equation, 24Generalized Maxwell-Stefan Equations, 25, 35Gibbs-Duhem equation, 83, 208Gibbs free energy, 42, 44, 45, 50, 51, 54, 55, 61, 62, 64,
73, 76, 78, 91, 92, 361, 362, 364, 365Gibbs phase rule, 65Gran-Hertz-History, 640Granular flow, 3, 177, 623Grashof numbers, 26, 36, 319, 521, 530, 573, 720Gravity-dominated condensation, 724, 727Griffith’s correlation, 371
HHamaker constant, 82, 635, 636, 682Heat pipes, 1, 11, 12, 37, 80, 83, 198, 207, 388, 472, 530,
583, 603, 606, 687, 692, 714, 715, 741, 744Heat sinks, 606, 676Heaviside function, 243, 520Hedstrom number, 669Helium properties, 754, 776, 790Helmholtz free energy, 41, 42, 44, 45, 49, 54, 71, 75, 92,
477Helmholtz instability, 504Henry’s constant, 217Heterogeneous bubble growth, 483Heterogeneous condensation, 355, 356Heterogeneous evaporation, 418, 420, 438Heterogeneous flow, 664, 665Heterogeneous nucleation, 68, 355, 473Heterogeneous reaction, 120
Index 815
Holdup void fraction, 169, 536Homogeneous bubble growth, 87, 478Homogeneous condensation, 356Homogeneous flow, 177, 538, 545, 551, 610, 653, 664Homogeneous flow model, 545, 616Homogeneous fluidization, 648Homogeneous model, 143, 144, 158, 160, 164, 165, 167,
173, 184, 185, 544–547, 550, 551, 559, 561, 614,664
Homogeneous nucleation, 68, 88, 89, 355, 473, 479, 484,486, 487
Homogeneous reacting systems, 119Horizontal film evaporation, 421Horizontal reactors, 338Horizontal two-phase flow, 230, 542–544Hot evaporation, 420, 421Hot gas evaporation, 417–419, 456, 459, 460, 466Hot wall tubular LPCVD reactors, 338Hydrophobic materials, 205Hydrostatic pressure gradient, 385Hydrotransport, 177, 663Hyperbolic function, 127
IImmiscible fluids, 166Inclined microchannel evaporation, 3, 259Indirect contact condensation, 603Injection velocity, 327Inorganic compounds, solubility, 794Integral formulation, 99, 127Integral solution, 259, 271, 273–277, 281, 286, 294, 297,
298, 315, 316, 318, 352Interactive force, 147–149, 184, 187Interfaces, 1, 2, 4, 7, 80, 95, 96, 98–100, 107, 148, 151,
153, 159, 168, 189, 190, 193, 201, 203, 209, 228,242, 243, 258, 312, 351, 355, 357, 358, 360, 362,366–370, 373, 376, 380, 386, 394–396, 399, 404,407, 408, 471, 514, 535, 536, 564, 737
Interface shapes at equilibrium, 193Interface tracking, 7, 95, 223Interface velocity, 244, 263Interfacial phenomena, 189, 190, 236, 700, 702Interfacial resistance, 224, 226, 249, 357, 367, 590, 594,
684Interfacial temperature, 207, 210, 216, 226, 293, 323,
349, 404, 420, 421, 430, 592, 595Interfacial tension gradients, 190, 196, 203, 204, 487Interfacial velocity, 130, 143, 213, 242, 244, 264, 323,
478, 519Intermolecular forces, 70, 191, 203, 206Internal energy, 41, 44–48, 51, 52, 54, 56, 57, 69, 71, 72,
91, 92, 102, 104, 114, 131, 170, 179, 361, 743,799
Interphase forces, 159Interphase phase-change energy, 159Intrinsic phase average, 142, 154, 691, 705Isothermal compatibility, 184
Isotropic materials, 17, 25
JJakob number, 26, 398, 424, 425, 458, 461, 481, 482,
488, 530, 576, 578, 726, 727Joule, heat concept, 8, 9Jump conditions, 1, 2, 7, 95, 96, 107, 127, 168, 209, 247,
248, 519
KKapitza number, 26, 232, 448, 449Kapitza resistance, 674Kattan-Thome-Favrat flow pattern, 571Kelvin equation, 209, 226, 249Kelvin-Helmholtz instability, 228, 230Kinetic energy, 26, 130, 145, 170, 213, 672Kinetic theory, 12, 20, 23, 88, 133, 224Kucherov-Rikenglaz equation, 225Kutateladze correlation, 406
LLagrangian approach, 95, 96, 237, 238, 241, 242, 680Lagrangian averaging, 140, 144Lagrangian interface tracking technique, 236Laminar condensate flow, 15, 385, 440, 494, 512Laminar falling film, 448Laminar film condensation, 359, 372–374, 377, 379, 380,
384, 385, 396, 398, 407, 408, 411, 448Laplace operator, 165, 801Laplace-Young equation, 75–78, 473, 478, 590, 604, 608Laser Chemical Vapor Deposition (LCVD), 325, 338,
346– 348, 351Laser drilling, 257Latent heat, 1, 2, 8, 10, 11, 13, 26, 27, 35, 62, 91, 130,
140, 184, 213, 225, 240, 244, 257, 259, 260, 264,269, 277, 295, 303, 305, 309, 312, 315, 317, 319,323–325, 329, 330, 334–336, 351, 366, 371, 376,379, 381, 383, 384, 387, 397, 408, 418–421, 425,427, 430, 434, 445, 454, 456, 457, 460, 471, 478,510, 518, 530, 676, 678, 679, 703, 704, 712, 732,738
Lattice Boltzmann Equation (LBE), 12Lattice Boltzmann method (LBM), 12Leibniz’s rule, 108Leidenfrost drops, 523, 528Leidenfrost effect, 521Leidenfrost phenomena, 470Lennard-Jones potential, 133Leverett function, 709, 712Lewis number, 137, 333–335Limiting viscosity, 668, 683, 684Liquid droplets, 3, 6, 7, 40, 136, 148, 149, 161, 184, 245,
356, 360, 367, 369, 370, 405, 417, 484, 540, 603Liquid fuel droplets, 136–140, 184, 466Liquid jet, 4, 5, 418, 460, 461, 465
816 Index
Index 817
Liquid microlayer, 206Liquid-particle systems, 3, 663Liquid slugs, 610, 617Liquid-solid particle flow, 623Liquid-solid transport in ducts, 624Liquid-vapor flow patterns, 196, 470, 535, 536, 543, 559,
569, 617Liquid-vapor interface, 74, 83, 91, 133, 134, 137, 138,
183, 190, 191, 196, 197, 201, 204, 206, 208–210,212, 226, 227, 245–248, 255, 355, 357, 360, 368,369, 371, 374–376, 378, 379, 381, 385, 386, 391,395, 398–404, 407, 408, 411, 415, 417, 430, 438,439, 443, 472, 475, 477–480, 495, 496, 503, 504,510–513, 518–520, 530, 559, 563, 571, 590–595,597, 605, 617, 714, 715, 721, 722
Liquid-vapor meniscus, 246, 249, 603, 717Lockhart-Martinelli correlations, 553Lower bound, 554, 561Low pressure chemical vapor deposition (LPCVD), 338Lumped capacitance model, 643
MMacroscopic (integral) formulation, 96, 98Marangoni effect, 196–199, 210, 592Marangoni number, 199, 201, 245Mass-averaged velocity, 21, 22, 106, 123, 124, 158, 160,
165Mass species equation, 16, 215, 247Mass transfer, 1, 2, 4, 8, 13, 20, 24, 25, 27, 96, 105, 118,
123, 134, 144, 146, 153, 166, 189, 199, 208,214–218, 223, 228, 232, 236, 252, 324, 325,328–330, 333, 346, 347, 352, 366, 368, 398–400,404, 419, 423, 424, 426, 434, 438, 457, 459, 463,466, 486, 535, 536, 624, 639, 660, 669, 676, 689,698, 700, 701, 714, 718, 807
Maxwell equations, 347Maxwell relations, 44Maxwell-Stefan diffusivity, 347Mean-field potential energy, 81Mean film thickness, 232, 233, 381Mean free time, 638Mean number diameter, 628Mechanical energy balance equation, 113Mechanical stability, 48, 50, 67, 85, 86Melting, 4–7, 10, 11, 18, 27, 28, 37, 91, 95, 183, 218,
246, 257 –262, 264–266, 268, 270, 271, 274, 275,277–281, 284, 286–288, 298–300, 303–306, 309,312–319, 323, 472, 639, 661, 676, 677, 689,732–738, 764, 807
Meniscus, 204, 207, 219, 223, 246, 249, 251, 253, 596,603, 605, 716, 717
Metastable equilibrium, 66, 67, 77, 484Microchannel, 11, 12, 187, 251, 597–599, 610, 669, 673,
674, 743, 807Microchannel heat exchangers, 672, 743Micro-Electro-Mechanical Systems (MEMS), 11, 187,
585
Microfilm region, 207Micrometer-scale particle packing, 633Microscopic (differential) formulation, 96Miniature heat sinks, 601, 606Miniature/micro channels, 12, 205, 207, 249, 250, 252,
535, 565, 583–585, 587–590, 601, 606, 608, 609,614, 617, 807
Minimum bubbling velocity, 649Minimum contact angle, 476Minimum equilibrium size, 366Minimum fluidization velocity, 645–649, 651, 682Minimum slugging velocity, 649Mixture model, 144, 164–168, 176, 177, 186Molar-averaged velocity, 21, 118Molar fluxes, 376Molar fraction, 15, 20, 21, 23, 63, 64, 118, 197, 376, 708Molecular Dynamic Simulation (MDS), 145Molecular statistical averaging, 140, 144Momentum production rate, 159Momentum response time, 32, 33, 165, 638Morton number, 233Moving boundary problem, 258Multicomponent PCM, 258, 312Multi-fluid models, 145, 158, 545, 638, 639Multiphase flows, 2, 7, 164, 177Multiphase Mixture Model (MMM), 689, 701, 709–713Multiphase mixtures, 31, 32, 158, 159, 169, 689, 701Multiphase systems, 1, 2, 4, 5, 7, 13, 26, 56, 95, 96, 143,
805Mush zone, 257, 258, 293–289, 309, 310, 318
NNanoencapsulated Phase Change Material (NEPCM),
675–680Nanoscale, 127Naphthalene sublimation, 324Natural convection, 18, 26, 36, 112, 223, 258, 261, 262,
266, 277, 290–292, 295, 299, 304, 313–315, 340,346, 348, 352, 427, 469, 471, 499, 714, 732, 734,737–739
Navier-Stokes equation, 11, 12, 572Net surface reaction rate, 341Neumann problem, 270Neumann stability criterion, 308Newton-Raphson/secant method, 13Newton’s law of viscosity, 14, 25, 111, 667Noncondensable gas, 368, 377, 398–404, 411, 420, 473,
475Nonequilibrium Molecular Dynamics (NEMD), 672Nonspherical particle, 624, 681Nonwetting, 203, 355, 356, 506, 523Normal contact force, 634, 635, 640Nucleate boiling, 77, 415, 469–473, 475, 484, 489, 493,
497–501, 503, 504, 506–510, 529, 569, 578–581,597, 600, 603, 611, 612, 714, 715, 718
Nucleate site density, 492
818 Index
Nucleation, 6, 66, 68, 85, 87–89, 355, 360, 361, 367, 469,471, 473, 475–477, 483, 484, 486, 489, 492, 493,497, 500, 508, 521, 526, 573, 600, 611, 715, 716
Number-averaged particle diameter, 626, 681Number density, 81, 82, 88, 370, 492, 493, 499, 661Numerical simulation, 190, 214, 259, 319, 334, 347, 427,
469, 493, 630, 660Numerical solution, 214, 262, 289, 308, 312, 314, 319,
347, 485, 520, 526, 595, 597, 729Nusselt evaporation, 418Nusselt number, 17, 26, 27, 151, 181, 182, 318, 328, 332,
333, 350, 351, 377, 379, 380, 382, 388, 394, 396,423, 446–448, 459, 500, 515, 516, 518, 567, 568,588, 599, 672, 727, 730, 734, 807
OOhm’s law, 572One-region problem, 257, 265, 274, 275, 315OpenFOAM, 662Oscillating Heat Pipes (OHP), 671
PPacked bed, 297, 653, 664, 719, 720, 740, 807Packing density, 630–633, 681Partial Differential Equations (PDEs), 96, 127Partially wetting, 203Particle number density, 144, 637Particulate fluidization, 7Partition coefficient, 219Peclet number, 26, 30, 349, 488, 677Permeability, 688–690, 692, 693, 695, 703, 708, 719,
724, 728, 730, 737, 740, 741, 792Phase Change Materials (PCMs), 284, 293, 295, 319, 732,
764Phase diagrams, 218, 219, 292, 358Phase interface fitted grid, 237, 241Phases, 1–5, 7, 9, 31, 39, 56–58, 60–62, 65, 68, 70,
74–76, 78, 83, 91, 95, 96, 98–101, 103, 107,127–129, 141, 142, 144–155, 158–160, 164–169,173, 176, 177, 183–185, 189, 193, 194, 197, 201,203, 208, 212–215, 218, 228, 230, 236–243, 257,259–262, 266, 270, 271, 277, 280, 295, 304, 305,311, 314, 315, 317, 319, 324, 357, 358, 420, 431,474, 478, 495, 513, 529, 535–538, 541, 542, 544,545, 547–549, 551, 556–559, 566, 568, 580, 593,601, 623, 639, 699–703, 705–707, 709, 711–713,721, 725, 728, 735, 736
Physical constants, 747Physical Vapor Deposition (PVD), 324Pigment, 660, 661Planck’s constant, 18Plug flow, 5, 539, 543, 563Pneumatic conveying system, 649, 653, 654Pneumatic transport, 3, 177, 623, 624, 653, 654Poisson’s ratio, 634–636
Polyatomic gas, 344Pool boiling, 4, 230, 469, 470, 472, 473, 477, 483, 493,
498, 504, 506–511, 528, 529, 573, 579, 597, 598,715, 719, 807
Porosity, 636, 637, 681, 682, 687, 689–693, 695, 699,703, 705, 712, 719, 724, 727, 731
Porous media, 204, 259, 312, 359, 406, 470, 653, 671,687, 689–693, 695, 698–701, 703, 709, 712, 714,718–721, 723, 727, 728, 732, 735, 736, 740, 743
Porous media boiling, 470, 714, 718, 721Power, 1, 3, 289, 348, 349, 351, 498, 528, 530, 550, 668,
674, 675, 684, 748Power law equation, 498Prandtl number, 26, 152, 290, 291, 393, 395, 412, 424,
430, 446, 448, 451, 565, 576, 581, 753–757Precursors, 325, 337–340, 343, 351Preheating duration, 279Pressure drop, 1, 179, 411, 412, 415, 524, 535, 540,
544–546, 550, 552–556, 558, 570, 573, 587, 589,597, 601, 606, 614, 616, 644, 653, 657–659, 667,668, 675, 703–705
Pressure gradients, 24, 25, 161, 422, 544, 554, 604, 609,689
Proton Exchange Membrane Fuel Cell (PEMFC), 706Puddle thickness, 523, 524Pulsating Heat Pipes (PHP), 5, 251, 617Pulverized coal, 623, 624, 642, 646, 660, 682, 683Pure substance, 4, 56, 58, 60, 66, 86, 115, 180, 197
QQuality, 32, 148, 184, 187, 243, 356, 538, 540, 541, 543,
545, 547, 556, 562, 563, 568, 579, 588, 609, 611,612, 614–616, 807
RRadiation, 16, 18, 19, 102, 315, 352, 456, 472, 514, 516,
518, 529, 530, 643, 644, 706Raindrop algorithm, 623, 630Random packing, 629, 630, 682Rarefied vapor self-diffusion model, 96Rayleigh number, 26, 292, 572, 730, 734, 739Rayleigh-Taylor instability, 228, 523, 718Reference frame velocity, 340Reference velocity, 116Relative (slip) velocity, 164Response times, 32Rizk’s correlation, 654, 655, 657Rohsenow’s correlation, 488, 500, 501Rolling friction coefficient, 635, 636, 641Rotational energy, 18Runge-Kutta method, 253, 331, 729
SSaltation flow, 664
Index 819
Saltation velocity, 653–657, 683Saturated boiling, 469, 470, 506, 576Saturation pressure, 13, 63, 76–78, 84, 91, 92, 187, 216,
226, 357, 371, 420, 425, 434, 474, 580, 594, 595,609, 702, 708, 717
Saturation temperature, 63, 66–68, 85, 91, 130, 136, 137,140, 207, 249, 250, 355–357, 366, 367, 369, 371,378, 379, 383, 386, 397, 399, 404, 407, 408, 411,415, 418, 420–422, 425, 426, 438, 449, 455–457,460, 465, 469, 474–476, 482, 498, 507, 513, 521,562, 569, 572, 579, 598, 615, 702, 703, 718,721–725, 743
Scale analysis, 2, 26–28, 30, 36, 37, 263, 274, 302, 453,455, 530
Scaling, 2, 27, 30, 524, 690Scanning velocity, 348, 349Schmidt number, 26, 403, 424, 425, 430, 463, 791Sedimentation, 3, 166, 177, 623Selective Area Laser Deposition (SALD), 339, 346, 351Selective Laser Sintering (SLS), 630, 633, 682Self-assembly, 624, 680, 681Self-diffusion coefficient, 133Self-diffusion equation, 133Sensible heat, 9, 10, 26, 27, 35, 263, 264, 301, 309, 314,
315, 335, 336, 351, 427Separated flow model, 166–168, 173, 174, 177, 545, 547,
549, 550, 559Settling velocity, 641, 664–666, 683Sherwood number, 24, 27, 328, 332, 333, 350, 351, 424Size distribution of particles, 623, 624, 681Sliding friction coefficient, 634, 636Slip flow regime, 12Slip ratio, 2, 537, 538, 550, 558–560, 567, 614Sludge layer, 3, 623Slug flow, 3, 460, 540, 543, 564, 584, 648, 649, 653, 654,
660Slurry flow, 3, 7, 623, 663–666, 677Smooth-surface model, 418, 715Solidification, 4–7, 10, 11, 18, 27, 95, 183, 218, 257–
259, 261, 262, 264, 265, 268, 270, 271, 274, 286,288–298, 304, 309, 312–314, 318, 319, 639, 689,732, 735, 737, 807
Solid-liquid interface, 29, 183, 201, 203, 257–264, 266,268, 271, 275–277, 280–284, 288–293, 304, 305,307, 310, 311, 313–315, 362, 591, 595, 733, 738,739
Solid-liquid phase change, 4, 257–260, 262, 263, 286,292, 293, 295, 304, 310, 312, 735, 737
Solid loading, 3, 654, 659Solid-vapor phase change, 4Species equation, 118, 124, 153, 156, 162, 215, 220, 331,
700, 706, 710, 711, 713Specific heats, 9, 219, 310, 374, 422, 432Spherical coordinate system, 466, 478, 802Sphericity, 642, 645, 646, 682Stability, 1, 39, 40, 46, 55, 56, 86, 87, 198, 199, 227, 235,
308, 510, 606, 630Stable equilibrium, 46, 66, 86, 362
Stagnant vapor reservoir, 372, 382Standard deviation, 626, 628, 629, 633, 650, 681Standard reference state, 135Stationary grid approach, 237Stefan-Boltzmann constant, 19, 516, 747Stefan-Maxwell equation, 347Stefan number, 27, 263, 264, 266, 270, 276, 277, 301Sticking coefficient, 341, 347, 348Stokes drag force, 690Stokes flow, 682, 690Stokes number, 3, 27, 33, 176, 177Stratified flow, 168, 543, 563–565, 567, 584, 610, 614Stratified wavy flow, 543, 567Stream functions, 327, 423, 529, 725, 733Stress-strain rate relationships, 15Stress tensors, 14, 101, 110, 111, 116, 159, 210, 213, 340,
691Strong numerical solution, 304Subcooled boiling, 469, 470, 516, 530, 569, 573, 578,
597Subcooling, 280, 283, 285, 286, 378–381, 386, 387, 407,
408, 410, 503, 506, 515, 590, 591, 609, 723, 726,729
Subeutectic concentration, 293Sublimation, 4, 5, 11, 215, 216, 323–327, 329, 333–336,
349–351, 639, 807Supereutectic concentration, 293Superficial velocity, 31, 500, 537, 538, 587, 614, 645,
648, 649, 654, 683Superheat, 40, 66, 68, 85–89, 292, 297, 323, 381, 415,
421, 453, 461, 473, 475–478, 484–486, 488, 492,597, 598, 600, 603, 611, 715, 716, 718, 723
Superheated liquids, 85, 87Supersaturation, 79, 80, 92, 421Surface excess, 70Surface pressure, 203Surface roughness, 208, 501, 503, 506, 551, 667Surface tension, 26, 27, 40, 70–74, 77, 92, 102, 127, 168,
183, 185, 189, 190, 193, 196–198, 201–205, 207,209, 210, 213, 219, 221, 229, 234, 240–242, 244,245, 249, 250, 254, 358, 360–362, 366, 430, 448,478, 480, 483, 488–490, 495, 523, 530, 557, 574,575, 577, 584, 587, 590, 592, 595, 601, 603, 608,617, 703, 724, 727, 731, 732
Surface waves, 240, 427, 429
TTaitel-Dukler flow map, 556, 569Tangential contact force, 634, 635Taylor series, 47, 364Temperature-transforming model, 259, 304, 310–312Tensors, 114, 116, 804, 805Terminal velocity, 641–643, 646, 647, 650, 651,
655–657, 665, 666, 682Thermal energy, 8, 9, 16, 52, 72, 114, 150, 259, 264, 277,
286, 289, 303, 312, 313, 317, 351, 409, 472, 546,651, 732
820 Index
Thermal expansion coefficient, 36Thermal penetration depth, 27, 28, 272–275, 279,
281–283, 315Thermal radiation, 18Thermal resistances, 366, 367, 405, 456Thermal stability, 47–50Thermodynamic equilibrium, 1, 39, 40, 56, 65, 83, 85,
119, 293, 429, 711, 712Thermodynamic laws, 1, 40, 41, 52, 73Thermodynamic limit of superheat, 68, 86, 87Thermodynamic pressure, 14Thermodynamic relations, 115Thermodynamic surfaces, xiiiThermophysical properties, 1, 120, 300, 343, 417, 456,
460, 515, 556, 651, 669, 676Thermosyphon, 396, 410, 416, 464, 587Thin liquid films, 80, 381, 421, 443Todes’ correlation, 652Transfer driving force, 335, 336Transitional velocities, 666Transition boiling, 469, 470, 472, 507–511, 529, 720Transition regime, 12, 472, 508Transport velocity for fast fluidization, 650Tube, external heating, sublimation, 325, 329, 332, 333,
350, 470, 501, 514, 528Turbulence modeling, 127Turbulent condensate flow, 390Turbulent falling film, 452Turbulent film condensation, 359, 383, 390, 391, 406Turbulent film regime, 382Turbulent fluidization, 648, 649Two-component flows, 4Two-fluid model, 144, 173, 547Two-phase flow, 26, 37, 174, 250, 255, 470, 535–548,
550–553, 556–558, 560, 561, 563, 565, 569 –573,583, 584, 586, 587, 589, 597, 601, 608, 610, 613,614, 623, 624, 703, 743
Two-phase flow patterns, 584Two-phase single-component systems, 56Two-region problem, 257, 270, 278, 294, 735
UUltra-thin liquid films, 80, 190, 206Unstable equilibrium, 66, 87, 365, 366Upper bound, 555, 561Urethane-based paint, 660
VVan der Waals equation, 58–60, 67, 68, 86, 87, 90–92Van der Waals limit, 87Vapor bubbles, 4–6, 75, 77, 148, 199, 356, 415, 421, 469,
471, 473, 484, 493, 504, 510, 528, 539, 569, 578,587, 603, 613, 623, 648, 714, 718
Vapor deposition, 324, 325, 337, 346Vaporization, 11, 13, 35, 62, 66, 85, 88, 91, 213, 236,
283, 366, 371, 376, 383, 384, 397, 418, 421, 422,427, 430, 445, 460, 465, 478, 521, 530, 569, 573,703, 714, 718
Vapor pressure, 76, 78, 79, 81, 83, 84, 86, 89, 92, 132,156, 190, 204, 206–208, 216, 217, 223, 226, 253,420, 460, 464, 474, 475, 491, 594, 595, 597, 603,608, 716, 717
Vectors, 17, 109, 128, 446, 634, 799, 801, 802, 804, 805Verlet method, 635Vertical falling film evaporation, 418, 427Vertical reactors, 338Vibrational energy, 18Viscous dissipation, 26, 114, 116–118, 120, 123, 130,
134, 170, 180, 181, 185, 186, 240, 244, 340, 422,432, 698
Voidage, 645, 646, 649, 650, 652, 657, 682, 683Void fraction, 2, 31, 535–538, 545, 547, 550, 558–563,
566, 567, 569, 614–617, 687, 743Volume average, 142, 143, 145, 691, 695, 696, 723, 724Volume-averaged multifluid models, 145Volume-averaged velocity, 688, 693, 703, 704Volume-average pressure, 691Volume-averaging model, 185Volume flow rate, 614, 748Volume fractions, 30, 31, 166, 167, 177, 238, 675, 678,
679, 702Volume of Fluid (VOF) method , 168, 238, 239, 241, 242,
519Volumetric averaging, 141Volumetric condensation rate, 707, 708Volumetric heat generation rate, 706
WWall superheat, 464, 473, 475, 492, 600, 715Water droplets, 153, 160, 465, 521, 525Wave equation, 127Wave velocity, 233, 235Wavy condensate regime, 381Wavy film analysis, 446Wavy flows, 381, 443Weber number, 27, 430, 560, 601, 608, 609, 611, 613Wetting, 190, 193, 202–204, 207, 208, 355, 356, 503,
504, 508, 709Wicked surfaces, 715, 718Wicks, 687, 692, 714Wispy annular flow, 540
YYield stress, 668, 683, 684Young-Laplace equation, 193, 194, 208, 229, 234Young’s modulus, 634–636