087920 AVGAS 100LL - Total ItaliaSDS # : 087920 AVGAS 100LL Revision Date: 2018-12-13 Version 1 For...

SAFETY DATA SHEETaccording to Regulation (EC) No. 1907/2006

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SDS # : 087920 AVGAS 100LL

Section 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THECOMPANY/UNDERTAKING

1.1. Product identifier

Product name AVGAS 100LLSubstance/mixture Mixture

1.2. Relevant identified uses of the substance or mixture and uses advised against

Identified uses Fuel for aircraft piston engines.

1.3. Details of the supplier of the safety data sheet

Supplier TOTAL EUROPEAN TRADINGTour Coupole2 place Jean Millier92400 COURBEVOIEFRANCETél: +33 (0)1 47 44 45 46

For further information, please contact:

Contact Point Technical/ HSEQE-mail Address [email protected]

1.4. Emergency telephone number

For English and European languages: +44 1235 239 670For Arabic: +44 1235 239 671For Asia Pacific in English, Mandarin, or local languages (Philippines, India, Sri Lanka, Malaysia, Indonesia, Thailand, Vietnam,Korea, Japan): +65 3158 1074P.R. China: +86 532 8388 9090US & Canada in English, French, Spanish : +1 215 207 0061

Section 2: HAZARDS IDENTIFICATION

2.1. Classification of the substance or mixture

REGULATION (EC) No 1272/2008For the full text of the H-Statements mentioned in this Section, see Section 2.2.

Date of the previous version: not applicable Revision Date: 2018-12-13 Version 1

Version EU

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SDS # : 087920 AVGAS 100LLRevision Date: 2018-12-13 Version 1

ClassificationFlammable liquids - Category 1 - H224Aspiration toxicity - Category 1 - H304Acute oral toxicity - Category 4 - H302Acute dermal toxicity - Category 4 - H312Acute inhalation toxicity - vapor - Category 4 - H332Skin corrosion/irritation - Category 2 - H315Reproductive toxicity - Category 2 - H361dSpecific target organ toxicity (single exposure) - Category 3 - H336Specific target organ toxicity (repeated exposure) - Category 2 - H373Chronic aquatic toxicity - Category 2 - H411

2.2. Label elements

Labelled according to REGULATION (EC) No 1272/2008

Contains Gasoline, Tetraethyllead

Signal wordDANGER

Hazard StatementsH224 - Extremely flammable liquid and vaporH332 - Harmful if inhaledH312 - Harmful in contact with skinH302 - Harmful if swallowedH336 - May cause drowsiness or dizzinessH373 - May cause damage to organs through prolonged or repeated exposureH304 - May be fatal if swallowed and enters airwaysH315 - Causes skin irritationH361d - Suspected of damaging the unborn childH411 - Toxic to aquatic life with long lasting effects

Precautionary StatementsP210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smokingP261 - Avoid breathing dust/fume/gas/mist/vapors/sprayP280 - Wear protective gloves and eye/face protectionP302 + P352 - IF ON SKIN: Wash with plenty of soap and waterP301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physicianP331 - Do NOT induce vomitingP362 - Take off contaminated clothing and wash before reuseP403 + P233 - Store in a well-ventilated place. Keep container tightly closedP243 - Take precautionary measures against static dischargeP240 - Ground/bond container and receiving equipmentP241 - Use explosion-proof electrical/ ventilating/ lighting/ equipment

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P242 - Use only non-sparking toolsP273 - Avoid release to the environmentP501 - Dispose of contents/ container to an approved waste disposal plant

2.3. Other hazards

Physical-Chemical Properties Extremely flammable. Highly volatile. The vapours are heavier than air and may carry alongthe ground giving a high risk of explosion . In case of pump , Friction generated by product discharge can create static charges ofsufficient magnitude to cause SPARKS WHICH MAY LEAD TO FIRE OR EXPLOSION.

Properties Affecting Health May cause central nervous system depression with nausea, headache, dizziness, vomiting,and incoordination.Vapors or mists are irritating for mucous membranes, notably in the eyes.If swallowed accidentally, the product may enter the lungs due to its low viscosity and leadto the rapid development of very serious pulmonary lesions (medical survey during 48hours).

Section 3: COMPOSITION/INFORMATION ON INGREDIENTS

3.2. Mixture

Chemical nature A complex and variable combination of paraffinic, cyclic and aromatic hydrocarbons havinga carbon number range predominantly of C4 to C12 and boiling in the range ofapproximately 30°C to 170°C.

Hazardous ingredientsChemical Name EC-No REACH registration

NoCAS-No Weight % Classification (Reg. 1272/2008)

Gasoline 289-220-8 01-2119471335-39 86290-81-5 >99 Flam. Liq. 1 (H224)Repr. 2 (H361d)

Asp. Tox. 1 (H304)Skin Irrit. 2 (H315)STOT SE 3 (H336)

Aquatic Chronic 2 (H411)Tetraethyllead 201-075-4 no data available 78-00-2

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For the full text of the H-Statements mentioned in this Section, see Section 16.

Section 4: FIRST AID MEASURES

4.1. Description of first-aid measures

General advice IN CASE OF SERIOUS OR PERSISTENT CONDITIONS, CALL A DOCTOR OREMERGENCY MEDICAL CARE. Before attempting to rescue casualties, isolate area from all potential sources of ignitionincluding disconnecting electrical supply. Ensure adequate ventilation and check that a safe, breathable atmosphere is present

Chemical Name EC-No CAS-No Weight % Classification (Reg.1272/2008)

2-methylbutane 201-142-8 78-78-4

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before entry into confined spaces. Drench contaminated clothing with water before removing to avoid risk of sparks from staticelectricity.

Eye contact Rinse thoroughly with plenty of water, also under the eyelids. Check for and remove any contact lenses. Rinse eyes.If eye irritation persists, consult a specialist.

Skin contact Remove contaminated clothing and shoes. Wash skin with soap and water.High pressure injection of the products under the skin may have very serious consequenceseven though no symptom or injury may be apparent.In this case, the casualty should be sent immediately to hospital.Wash off with soap and water.

Inhalation In case of exposure to intense concentrations of vapours, fumes or spray, transport theperson away from the contaminated zone, keep warm and allow to rest. Immediately begin artificial respiration if breathing has ceased. Call a physicianimmediately.

Ingestion Give nothing to drink.Do NOT induce vomiting, as there is high risk of aspiration. The fluid can enter the lungsand cause damage (chemical pneumonitis, potentially fatal).Take victim immediately to hospital.Do not wait for symptoms to develop.

Protection of First-aiders CAUTION! First aid personnel must be aware of personal risk during rescue!.Use personal protective equipment. See Section 8 for more detail.

4.2. Most important symptoms and effects, both acute and delayed

Eye contact Burning feeling and temporary redness.

Skin contact Irritating to skin.

Inhalation Inhalation of vapours may cause headache, nausea, vomiting and an altered state ofconsciousness.

Ingestion Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May causecentral nervous system depression.Harmful: If swallowed accidentally, the product may enter the lungs due to its low viscosityand lead to the rapid development of very serious inhalation pulmonary lesions (medicalsurvey during 48 hours).

4.3. Indication of any immediate medical attention and special treatment needed

Notes to physician Harmful: If swallowed accidentally, the product may enter the lungs due to its low viscosityand lead to the rapid development of very serious inhalation pulmonary lesions (medicalsurvey during 48 hours). Treat symptomatically.

Section 5: FIRE-FIGHTING MEASURES

5.1. Extinguishing media

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Suitable Extinguishing Media Extinguishing media - small fires. Carbon dioxide (CO 2). Dry powder. Sand or earth.Extinguishing media - large fires. Foam. Foams on base of general-purpose emulsifier.Water spray. Water fog (trained personnel only).

Unsuitable Extinguishing Media Do not use a solid water stream as it may scatter and spread fire.Simultaneous use of foam and water on the same surface is to be avoided as waterdestroys the foam.

5.2. Special hazards arising from the substance or mixture

Special Hazard In case of fire hazardous decomposition products may be produced such as:. Sulfur oxides.Incomplete combustion and thermolysis may produce gases of varying toxicity such ascarbon monoxide, carbon dioxide, various hydrocarbons, aldehydes and soot. These maybe highly dangerous if inhaled in confined spaces or at high concentration.Vapors may form explosive mixtures with air.

5.3. Advice for fire-fighters

Special protective equipment forfire-fighters

In case of a large fire or in confined or poorly ventilated spaces, wear full fire resistantprotective clothing and self-contained breathing apparatus (SCBA) with a full face-pieceoperated in positive pressure mode.

Other information Cool down any tanks and surfaces exposed to fire by spraying abundantly with water. Usewater to cool tanks and parts exposed to the thermal flux not caught up in the flames.Do not allow run-off from fire fighting to enter drains or water courses. Fire residues andcontaminated fire extinguishing water must be disposed of in accordance with localregulations.

Section 6: ACCIDENTAL RELEASE MEASURES

6.1. Personal precautions, protective equipment and emergency procedures

General Information Except in case of small spillages. The feasibility of any actions should always be assessedand advised, if possible, by a trained, competent person in charge of managing theemergency. If required, notify relevant authorities according to all applicable regulations.Avoid contact with skin, eyes and inhalation of vapors. Evacuate non-essential personnel.For personal protection see section 8. Stop or contain leak at the source, if safe to do so. Cut off the electric power supply if thisoperation causes no sparks in the area containing vapors from the product. Stay upwind.In case of large spillages, alert occupants in downwind areas. ELIMINATE all ignitionsources (no smoking, flares, sparks or flames in immediate area). In case of importantspillages: risk of fire or explosion . Cover discharges with foam in order to reduce the risksof ignition. Vapours are heavier than air and may spread near ground level to sources ofignition .

Advice for non-emergencypersonnel

Do not touch or walk through spilled material. For personal protection see section 8.ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area).

Advice for emergency responders Take all appropriate steps to avoid fire, explosion and inhalation hazards to the rescuersincluding the use of breathing apparatus. In case of: Small spillages: normal antistatic working clothes are usually adequate. Large spillages: full body suit of chemically resistant and antistatic material. Work gloves

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(preferably gauntlets) providing adequate chemical resistance. Remarks:. Gloves made ofPVA are not water-resistant, and are not suitable for emergency use. Work helmet.Antistatic non-skid safety shoes or boots. Goggles and/or face shield, if splashes or contactwith eyes is possible or anticipated.Respiratory protection. In the case of vapor formation use a respirator with an approvedfilter. A Self-Contained Breathing Apparatus (SCBA) can be used according to the extent ofspill and predictable amount of exposure. If the situation cannot be completely assessed,or if an oxygen deficiency is possible, only SCBA’s should be used.

6.2. Environmental precautions

General Information The product should not be allowed to enter drains, water courses or the soil. Do not allowmaterial to contaminate ground water system. In case of spill in river, suspend the use of the water downstream to the spillpoint. Ifnecessary, Consult an expert. Local authorities should be advised if significant spillagescannot be contained.

6.3. Methods and material for containment and cleaning up

Methods for containment Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth,diatomaceous earth, vermiculite) and place in container for disposal according to local /national regulations (see Section 13). Large spillages may be cautiously covered withfoam, if available, to limit fire risk. In case of spillage in the water: Let the product spreadon the surface of the water. In case of no obstacle (barrage, bank or shore). Spillages ofliquid product in the water will likely result in a quick and complete vaporization of theproduct. In case of small spillages in closed waters , when the quantities to be recoveredare small (some tens of liters), contain product with floating barriers or other equipment.

Methods for cleaning up Never use dispersing agents. Transfer recovered product and other materials to suitable tanks or containers andstore/dispose according to relevant regulations.Do not flush into surface water or sanitary sewer system. Prevent product from enteringdrains.

6.4. Reference to other sections

Personal Protective Equipment See Section 8 for more detail.

Waste treatment See section 13.

Other information Recommended measures are based on the most likely spillage scenarios for this material.However, local conditions (wind, air temperature, wave/current direction and speed) maysignificantly influence the choice of appropriate actions. For this reason, local experts should be consulted when necessary. Local regulations may also prescribe or limit actions to be taken.

Section 7: HANDLING AND STORAGE

7.1. Precautions for safe handling

Advice on safe handling Ensure that all relevant regulations regarding explosive atmospheres, handling and storagefacilities of flammable products, are followed. Take precautionary measures against staticelectricity.

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The inspection, cleaning and maintenance of storage containers require the application ofstrict procedures and must be entrusted to qualified personnel (internal or external).Ensure adequate ventilation. Vapors may form explosive mixtures with air. Do not smoke.Avoid breathing vapors or mists. Avoid contact with skin, eyes and clothing.NEVER ATTEMPT TO PRIME THE CONTAINER SIPHON BY SUCKING WITH THEMOUTH. Prevent the formation of vapors, mists and aerosols. Do not use compressed air for filling, discharging, or handling operations. Never pierce,drill, grind, cut, saw or weld any empty container.For personal protection see section 8.

Technical measures Ensure adequate ventilation.WHILE MOVING THE PRODUCT:. To avoid ignition of vapors by static electricitydischarge, all metal parts of the equipment must be grounded.Take all necessary precautions to prevent water from entering the containers, tanks,transfer lines etc...

Prevention of fire and explosion Handle away from any source of ignition (open flame and sparks) and heat (hot manifoldsor casings). Take precautionary measures against static discharges. Ground/bondcontainers, tanks and transfer/receiving equipment. Friction generated by product dischargecan create static charges of sufficient magnitude to cause SPARKS WHICH MAY LEAD TOFIRE OR EXPLOSION. Do not allow splash loading and ensure that the product is pouredslowly, particularly at the beginning of the operation.Empty containers may contain flammable or explosive vapors. Never weld any container orempty pipe that has not been degassed.OPERATE ONLY ON COLD AND DEGASSED TANKS IN VENTILATED PREMISES (TOAVOID RISK OF EXPLOSION).Design installations (machinery and equipment) to prevent burning product from spreading(tanks, retention systems, interceptors (traps) in drainage systems).

Hygiene measures When using, do not eat, drink or smoke. Avoid contact with skin, eyes and clothing. Avoidbreathing vapors, mist or gas. Wash hands before breaks and immediately after handlingthe product. IF ON SKIN: Wash skin with soap and water. Remove contaminated clothingand shoes. Gloves must be periodically inspected and changed in case of wear, perforations orcontaminations.Provide regular cleaning of equipment, work area and clothing. Keep away from food, drinkand animal feeding stuffs. Ensure the application of strict rules of hygiene by the personnelexposed to the risk of contact with the product. Use personal protective equipment asrequired.

7.2. Conditions for safe storage, including any incompatibilities

Technical measures/Storageconditions

Storage area layout, tank design, equipment and operating procedures must comply withthe relevant European, national or local legislation.. All the electric installations, including the lighting of rooms that may contain this product,must be adapted to the risk area, in compliance with the European ATEX directives. Takeprecautionary measures against static discharges.. Ensure all equipment is electrically grounded before beginning transfer operations.Storage installations should be designed with adequate bunds so as to prevent ground orwater pollution in case of leaks or spills. Do not remove the hazard labels of the containers(even if they are empty).. Store the packed products (drums, samples, cans ...) in properly ventilated rooms, awayfrom damp, heat and any potential source of ignition.. Keep preferably in the original container. Otherwise reproduce all indication of the

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regulation label on the new container. Keep containers tightly closed and properly labelled.Store separately from oxidising agents.

Materials to Avoid Dangerous reaction with oxidizing agents (chlorates, nitrates, and permanganates...).

Packaging material Use only hydrocarbon-resistant containers, seals, pipes, etc.

7.3. Specific end uses

Specific use(s) See exposure scenarios.

Section 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1. Control parameters

Exposure limits Ingredients with workplace control parameters

Other constituents required for disclosure

Chemical Name European Union2-methylbutane

78-78-4TWA 1000 ppm

TWA 3000 mg/m3

Xylene (mixed isomers o, m, p) 1330-20-7

TWA 50 ppmTWA 221 mg/m3

STEL 100 ppmSTEL 442 mg/m3

S*n-Hexane 110-54-3


1,2,4-Trimethylbenzene 95-63-6


Ethylbenzene 100-41-4



S*toluene

108-88-3TWA 50 ppm

TWA 192 mg/m3


S*Benzene 71-43-2

S*TWA 1 ppm

TWA 3.25 mg/m3

Legend See section 16

Biological standards

Other constituents required for disclosure

DNEL Worker (Industrial/Professional)Chemical Name Short term, systemic

effectsShort term, local effects Long term, systemic

effectsLong term, local effects

Gasoline 1300 mg/m3/15min 1100 mg/m3/15min 840 mg/m3/8h (inhalation)

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86290-81-5 (inhalation) (inhalation)DNEL Consumer

Chemical Name Short term, systemiceffects

Short term, local effects Long term, systemiceffects

Long term, local effects

Gasoline 86290-81-5

1200 mg/m3/15min(inhalation)

640 mg/m3/15min(inhalation)

180 mg/m3/24h(inhalation)

8.2. Exposure controls

Occupational Exposure Controls

Engineering Measures Ensure adequate ventilation. Apply technical measures to comply with the occupationalexposure limits.When working in confined spaces (tanks, containers, etc.), ensure that there is a supply ofair suitable for breathing and wear the recommended equipment. Do not enter emptystorage tanks until measurements of available oxygen have been carried out.

Personal Protective Equipment

General Information Protective engineering solutions should be implemented and in use before personalprotective equipment is considered.

Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment. To enter tankers,tanks, reservoirs where the oxygen content is too low, wear insulating respiratoryapparatus.. In an emergency or for exceptional short-lasting jobs in an atmosphere polluted by theproduct, it is necessary to wear protective respiratory equipment. When using a mask orhalf mask :. Full face piece respirator with organic vapor/acid gas cartridge or canister. TypeA. The use of breathing apparatus must comply strictly with the manufacturer's instructionsand the regulations governing their choices and uses.

Eye Protection If splashes are likely to occur, wear:. Safety glasses with side-shields. or. Face-shield.

Skin and body protection Wear suitable protective clothing. hydrocarbon-proof clothing. Protective shoes or boots.

Hand Protection Hydrocarbon-proof gloves for aromatic hydrocarbons. Please observe the instructionsregarding permeability and breakthrough time which are provided by the supplier of thegloves. Also take into consideration the specific local conditions under which the product isused, such as the danger of cuts, abrasion, and the contact time.. Note. Gloves made of PVA are not water-resistant, and are not suitable for emergencyuse.

Repeated or prolonged exposureGlove material Glove thickness Break through time Remarks

PVA (*) > 480 min EN 374 (*) any thicknessFluorinated rubber (*) > 480 min EN 374 (*) any thickness

Nitrile rubber > 0.5 mm > 480 min EN 374

In case of contact through splashing:Glove material Glove thickness Break through time RemarksNitrile rubber > 0.3 mm > 60 min EN 374

Environmental exposure controls

General Information The product should not be allowed to enter drains, water courses or the soil.

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Section 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1. Information on basic physical and chemical properties

Appearance limpidColor bluePhysical State @20°C liquidOdor CharacteristicOdor Threshold No information available

9.2. Other information

Section 10: STABILITY AND REACTIVITY

10.1. Reactivity

General Information No information available.

Property Values Remarks Method pH Not applicableMelting point/range No information available

Boiling point/boiling range 30 - 170 °C ASTM D 86 86 - 338 °F ASTM D 86

Flash point < -40 °C ASTM D 93< -40 °F ASTM D 93

Evaporation rate Not applicableFlammability Limits in Air

upper 8.7 %Lower 1.4 %

Vapor Pressure 70 kPa @ 50 °C approximately EN 13016-1Vapor density > 3Relative density No information availableDensity 700 - 740 kg/m3 @ 15 °CWater solubility 0.025 Practically insoluble To slightly

solubleSolubility in other solvents Soluble in many common

organic solventslogPow Not applicableAutoignition temperature > 300 °C ASTM E659-78

> 572 °F ASTM E659-78Decomposition temperature No information availableViscosity, kinematic < 1 mm2/s @ 20 °C ISO 3104Explosive properties Not explosiveOxidizing Properties This product is not considered oxidising based on chemical structure considerationsPossibility of hazardous reactions None under normal processing

Freezing Point No information available

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10.2. Chemical stability

Stability Stable under recommended storage conditions.

10.3. Possibility of hazardous reactions

Hazardous Reactions None under normal processing.

10.4. Conditions to avoid

Conditions to avoid Take precautionary measures against static discharges. Heat, flames and sparks.

10.5. Incompatible materials

Materials to Avoid Dangerous reaction with oxidizing agents (chlorates, nitrates, and permanganates...).

10.6. Hazardous Decomposition Products

Hazardous Decomposition Products None under normal use.

Section 11: TOXICOLOGICAL INFORMATION

11.1. Information on toxicological effects

Acute toxicity Local effects Product Information

General Information The acute toxicity has been adequately characterised in a large number of GLP-compliantguideline investigations following oral, dermal or inhalation exposure.

Skin contact . Irritating to skin.

Eye contact This product does not meet the EU criteria for classification. Burning feeling and temporary redness.

Inhalation . Inhalation of vapours may cause headache, nausea, vomiting and an altered state ofconsciousness.

Ingestion . Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. May causecentral nervous system depression.Harmful: If swallowed accidentally, the product may enter the lungs due to its low viscosityand lead to the rapid development of very serious inhalation pulmonary lesions (medicalsurvey during 48 hours).

Acute toxicity - Component Information

Chemical Name LD50 Oral LD50 Dermal LC50 InhalationGasoline LD50 > 5000 mg/kg bw (rat -

OECD TG 401)LD50 > 2000 mg/kg bw (rabbit -OECD TG 402 - under occlusive

conditions)

LC50 (4h) > 5610 mg/m3 air(vapor) (rat - OECD 403)

Tetraethyllead = 12.3 mg/kg ( Rat ) = 850 mg/m3 ( Rat ) 1 h

Sensitization

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Sensitization This product does not meet the EU criteria for classification.

Specific effects

Carcinogenicity This product does not meet the EU criteria for classification.Other constituents required for disclosure

Chemical Name European UnionBenzene 71-43-2

Carc. 1A (H350)

Mutagenicity . This product does not meet the EU criteria for classification.Other constituents required for disclosure

Chemical Name European UnionBenzene 71-43-2

Muta. 1B (H340)

Reproductive toxicity Suspected of damaging the unborn child.

Chemical Name European UnionGasoline

86290-81-5Repr. 2 (H361d)

Tetraethyllead 78-00-2

Repr. 1A (H360Df)

Other constituents required for disclosureChemical Name European Union

n-Hexane 110-54-3

Repr. 2 (H361f)

toluene 108-88-3

Repr. 2 (H361d)

Repeated dose toxicity

Target Organ Effects (STOT)

Specific target organ systemictoxicity (single exposure)

Acute exposure studies show no evidence of systemic toxicity, other than a potential tocause narcosis / CNS depression at higher exposure concentrations.

Specific target organ systemictoxicity (repeated exposure)

The repeat dose toxicity of the substance has been studied following dermal and inhalationexposure for periods between 10 days and up to 2 years. In dermal studies, no systemictoxicity has been seen. The only effect observed was moderate to severe dermal irritation.Repeated inhalation exposure causes : light hydrocarbon nephropathy.

Aspiration toxicity The fluid can enter the lungs and cause damage (chemical pneumonitis, potentially fatal).

Other information

Other information No information available.

Section 12: ECOLOGICAL INFORMATION

12.1. Toxicity

Toxic to aquatic life with long lasting effects.

Acute aquatic toxicity - Product Information

No information available.

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Acute aquatic toxicity - Component Information

Chemical Name Toxicity to algae Toxicity to daphnia andother aquatic invertebrates

Toxicity to fish Toxicity tomicroorganisms

Gasoline 86290-81-5

EL50 (72 h) > 3.1 mg/l(Selenastrum

capricornutum/Pseudokirchnerella subcapitata - OECD

201)

EL50 (48 h) > 4.5 mg/l(Daphnia magna - OECD

202)

LL50 (96 h) > 8.2 mg/l(Pimephales promelas -

OECD 203)

Tetraethyllead 78-00-2

EC50 (48h) = 0.1 mg/LDunaliella tertiolecta

EC50 (48h) = 0.085 mg/LArtemia salina

LC50 (96h) = 19.3 mg/LPimephales promelas ()LC50 (96h) = 84 mg/L

Lepomis macrochirus ()

Chronic aquatic toxicity - Product Information No information available.

Chronic aquatic toxicity - Component Information .

Chemical Name Toxicity to algae Toxicity to daphnia andother aquatic invertebrates

Toxicity to fish Toxicity tomicroorganisms

Gasoline 86290-81-5

NOEL (21d) > 2.6 mg/l(Daphnia magna - OECD

211)

NOEL (14/28d) > 2.6 mg/l(Read across from Daphnia

magna)

Effects on terrestrial organisms No information available.

12.2. Persistence and degradability

General InformationNo product level data available.

12.3. Bioaccumulative potential

Product Information No information available.

logPow Not applicableComponent Information .

Chemical Name log PowTetraethyllead - 78-00-2 4.32

12.4. Mobility in soil

Soil Given its physical and chemical characteristics, the product is generally mobile in theground. It may contaminate ground water.

Air The product evaporates in the air and dissipates more or less depending on localconditions. However, it may stagnate in pools in low-lying areas, in an undisturbed orconfined atmosphere.

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Water The product spreads on the surface of the water. May exhibit slight solubility in water.

12.5. Results of PBT and vPvB assessment

PBT and vPvB assessment This product contains no substance considered as PBT and/or vPvB according to REACHregulation annex XIII criteria.

12.6. Other adverse effects

General Information No information available.

Section 13: DISPOSAL CONSIDERATIONS

13.1. Waste treatment methods

Waste from Residues / UnusedProducts

Dispose of in accordance with the European Directives on waste and hazardous waste.

Contaminated packaging Empty containers may contain flammable or explosive vapors. Do not cut, weld, bore, burnor incinerate emptied containers, unless they have been cleaned and declared safe. Emptycontainers should be taken to an approved waste handling site for recycling or disposal.

EWC Waste Disposal No. According to the European Waste Catalogue, Waste Codes are not product specific, butapplication specific. Waste codes should be assigned by the user based on the applicationfor which the product was used.

Section 14: TRANSPORT INFORMATION

ADR/RID UN/ID No UN1203Proper shipping name GASOLINEProper shipping name GASOLINEHazard class 3Packing Group IIADR/RID-Labels 3Environmental hazard YesClassification Code F1Special Provisions 243, 534, 363Tunnel Restriction Code (D/E)ADR Hazard Id (KemmlerNumber)

33

Description UN1203, GASOLINE, 3, II, (D/E)Excepted Quantity E2Limited quantity 1 L

IMDG/IMO UN/ID No UN1203Proper shipping name GasolineHazard class 3Packing Group IIMarine pollutant Yes

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EmS No. F-E, S-EDescription UN1203, Gasoline, 3, II, (-40°C c.c.)Special Provisions 243, 363Excepted Quantity E2Limited quantity 1 L

ICAO/IATA UN/ID No UN1203Proper shipping name GasolineHazard class 3Packing Group IIERG Code 3HSpecial Provisions A100Description UN1203, Gasoline, 3, IIExcepted Quantity E2Limited quantity 1 L

ADN UN/ID No UN1203Proper shipping name GASOLINEProper shipping name GASOLINEHazard class 3Packing Group IIEnvironmental hazard YesClassification Code F1Special Provisions 243, 363, 534Description UN1203, GASOLINE, 3, IIExcepted Quantity E2Limited quantity 1 LVentilation VE01

Section 15: REGULATORY INFORMATION

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

European Union

REACHAll substances contained in this mixture have been pre-registered, registered or are exempt from registration in accordance withRegulation (CE) No. 1907/2006 (REACh)

Other regulationsDIRECTIVE 2010/75/EU on industrial emissions. Take note of Dir 94/33/EC on the protection of young people at work. Take noteof Dir 92/85/EEC on the safety and health at work of pregnant workers.

Take note of Directive 98/24/EC on the protection of the health and safety of workers from the risks related to chemical agents atwork

International Inventories All the substances contained in this product are listed or exempted from listing in the

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following inventories:Australia (AICS)Canada (DSL/NDSL)Europe (EINECS/ELINCS/NLP)Korea (KECL)New Zealand (NZIoC)Philippines (PICCS)

Further information

No information available

15.2. Chemical Safety Assessment

Chemical Safety Assessment See exposure scenarios

Section 16: OTHER INFORMATION

Full text of H-Statements referred to under sections 2 and 3H224 - Extremely flammable liquid and vaporH225 - Highly flammable liquid and vaporH226 - Flammable liquid and vaporH300 - Fatal if swallowedH301 - Toxic if swallowedH302 - Harmful if swallowedH304 - May be fatal if swallowed and enters airwaysH310 - Fatal in contact with skinH312 - Harmful in contact with skinH315 - Causes skin irritationH319 - Causes serious eye irritationH330 - Fatal if inhaledH332 - Harmful if inhaledH335 - May cause respiratory irritationH336 - May cause drowsiness or dizzinessH340 - May cause genetic defectsH350 - May cause cancerH360Df - May damage the unborn child. Suspected of damaging fertilityH361d - Suspected of damaging the unborn childH361f - Suspected of damaging fertilityH372 - Causes damage to organs through prolonged or repeated exposureH373 - May cause damage to organs through prolonged or repeated exposureH400 - Very toxic to aquatic lifeH410 - Very toxic to aquatic life with long lasting effectsH411 - Toxic to aquatic life with long lasting effectsH412 - Harmful to aquatic life with long lasting effects

Abbreviations, acronymsACGIH = American Conference of Governmental Industrial Hygienistsbw = body weightbw/day = body weight/dayEC x = Effect Concentration associated with x% responseGLP = Good Laboratory Practice

_____________________________________________________________________________________________

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Page 18 / 41


IARC = International Agency for Research of CancerLC50 = 50% Lethal concentration - Concentration of a chemical in air or a chemical in water which causes the death of 50% (onehalf) of a group of test animalsLD50 = 50% Lethal Dose - Chemical amount, given at once, which causes the death of 50% (one half) of a group of test animalsLL = Lethal LoadingNIOSH = National Institute of Occupational Safety and HealthNOAEL = No Observed Adverse Effect LevelNOEC = No Observed Effect ConcentrationNOEL = No Observed Effect LevelOECD = Organization for Economic Co-operation and DevelopmentOSHA = Occupational Safety and Health AdministrationUVCB = Substance of unknown or Variable composition, Complex reaction products or Biological materialDNEL = Derived No Effect LevelPNEC = Predicted No Effect Concentrationdw = dry weightfw = fresh watermw = marine wateror = occasional release

Legend Section 8

TWA: Time Weight AverageSTEL: Short Time Exposure LimitPEL: Permissible exposure limitREL: Recommended exposure limitTLV: Threshold Limit Values

Revision Date: 2018-12-13Revision Note (M)SDS sections updated: 11, 12, 16.

Further information Note P: The classification as a carcinogen or mutagen need not apply if it can be shownthat the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). Whenthe substance is not classified as a carcinogen at least the precautionary statements(P102-)P260-P262-P301 + P310-P331 (Table 3.1) or the S-phrases (2-)23-24-62 (Table3.2) shall apply. This note applies only to certain complex oil-derived substances in Part 3.

Other uses than these listed under section 1.2 may have been foreseen for thesubstance(s) contained in the product. Please contact us if your use is not listed undersection 1.2.

This safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006_____________________________________________________________________________________________This safety data sheet serves to complete but not to replace the technical product sheets. The information containedherein is given in good faith and is accurate to the best of knowledge at the date indicated above.It is understood by theuser that any use of the product for purposes other than those for which it was designed entails potential risk.Theinformation given herein in no way dispenses the user from knowing and applying all provisions regulating hisactivity.The user bears sole liability for the precautions required when using the product.The regulatory texts indicatedherein are intended to aid the user to fulfil his obligations. This list is not to be considered complete and exhaustive.It isthe user's responsibility to ensure that he is subject to no other obligations than those mentioned.

+ Sensitizer * Skin designation** Hazard Designation C: CarcinogenM: Mutagen R: Toxic to reproduction

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Page 19 / 41


End of the Safety Data Sheet

/ 41

ES02001Version 1.0Trade name / designation Low Boiling point Naphta

1. Exposure scenarioManufacture of substances, Industrial.

Use DescriptorSector of useSU3 - Industrial Manufacturing (all)SU8 - Manufacture of bulk, large scale chemicals (including petroleum products)SU9 - Manufacture of fine chemicals

Process categoryPROC1 - Use in closed process, no likelihood of exposurePROC2 - Use in closed, continuous process with occasional controlled exposurePROC3 - Use in closed batch process (synthesis or formulation)PROC4 - Use in batch and other process (synthesis) where opportunity for exposure arisesPROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilitiesPROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilitiesPROC15 - Use as laboratory reagent

Environmental Release CategoryERC1 - Manufacture of substancesERC4 - Industrial use of processing aids in processes and products, not becoming part of articles

Specific Environmental Release CategoryESVOC SpERC 1.1.v1.

Processes, tasks, activities coveredManufacture of the substance or use as a process chemical or extraction agent within closed or contained systems. Includesincidental exposures during recycling/ recovery, material transfers, storage, sampling, associated laboratory activities, maintenanceand loading (including marine vessel/barge, road/rail car and bulk container).

2. Operational conditions and risk management measures

2.1. Control of environmental exposure

Product characteristicsSubstance is complex UVCB. Predominantly hydrophobic.

Amounts used:

Fraction of EU tonnage used in region: 0.1Regional use tonnage (tonnes/year): 1.87E+7Fraction of Regional tonnage used locally: 0.032Annual site tonnage (tonnes/year): 6.0E+5Maximum daily site tonnage (kg/day): 2.0E+6

Frequency and duration of use Continuous releaseEmission Days (days/year): 300

Environment factors not influenced by risk management-

Local freshwater dilution factor: 10Local marine water dilution factor: 100

Other operational conditions of use affecting environmental exposure-.

Release fraction to air from process (initial release prior to RMM): 0.05

/ 41Release fraction to wastewater from process (initial release prior to RMM): 0.003Release fraction to soil from process (initial release prior to RMM): 0.0001

Technical conditions and measures at process level to prevent releaseCommon practices vary across sites thus conservative process release estimates used.

Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soilPrevent discharge of undissolved substance to or recover from onsite wastewaterRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation)Onsite wastewater treatment required

Treat air emission to provide a typical removal efficiency of (%): 99.0Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): >= 95.2If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of (%): >= 80.4

Organizational measures to prevent/limit release from the siteDo not apply industrial sludge to natural soils. Sludge should be incinerated, contained or reclaimed.

Conditions and measures related to municipal sewage treatment plant:

Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%): 99.1Maximum allowable site tonnage (MSafe) (kg/d): 2.0E+6Assumed domestic sewage treatment plant flow (m3/d): 10000Conditions and measures related to external treatment of waste for disposalDuring manufacturing no waste of the substance is generated.

Conditions and measures related to external recovery of wasteDuring manufacturing no waste of the substance is generated.

RemarksAdditional information on the basis for the allocation of the identified OCs (operating conditions) and RMMs ( Risk ManagementMeasures) is contained in Petrorisk file

2.2. Control of exposure - Workers / Consumers

Product characteristicsPhysical StateLiquid, vapor pressure > 10 kPa at STP

Concentration of substance in productCovers percentage substance in the product up to 100 % (unless stated differently).

Amounts usedAmounts used. Not applicable.Frequency and duration of useCovers daily exposures up to 8 hours (unless stated differently)

Human factors not influenced by risk managementnot applicableOther operational conditions affecting exposureOperation is carried out at elevated temperature (> 20°C above ambient temperature). Assumes a good basic standard ofoccupational hygiene is implemented.

/ 41

3. Exposure estimation and references

Information for contributing exposure scenarioThe ECETOC TRA tool has been used to estimate consumer exposures unless otherwise indicated.

Information for contributing exposure scenarioThe Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model.

4. Guidance for Downstream User to check compliance with the Exposurescenario

HealthPredicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditionsoutlined in Section 2 are implemented. Where other Risk Management Measures/Operational Conditions are adopted, then usersshould ensure that risks are managed to at least equivalent levels. Available hazard data do not enable the derivation of a DNELfor dermal irritant effects. Available hazard data do not support the need for a DNEL to be established for other health effects. RiskManagement Measures are based on qualitative risk characterization.

EnvironmentGuidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary todefine appropriate site-specific risk management measures. Required removal efficiency for wastewater can be achieved using

2.2a. Control of worker exposure

2.2b. Control of consumer exposure

Contributing Scenarios Operational conditions and risk management measuresGeneral measures (skin irritants) Avoid direct skin contact with product. Identify potential areas for indirect skin

contact. Wear gloves (tested to EN374) if hand contact with substance likely.Clean up contamination/spills as soon as they occur. Wash off any skincontamination immediately. Provide basic employee training to prevent /minimise exposures and to report any skin problems that may develop.

General exposures (closed systems) No other specific measures identified.

General exposures (closed systems) withsample collection

No other specific measures identified.

General exposures (open systems) Provide extract ventilation to points where emissions occur.

Mixing operations (closed systems) No other specific measures identified.

Process sampling No other specific measures identified.

Laboratory activities Handle in a fume cupboard or under extract ventilation.

Bulk transfers No other specific measures identified.

Drum/batch transfers No other specific measures identified.

Equipment maintenance No other specific measures identified.

Storage No other specific measures identified.

Product Category(ies) Operational conditions and risk management measuresNot applicable

/ 41onsite/offsite technologies, either alone or in combination. Required removal efficiency for air can be achieved using on-sitetechnologies, either alone or in combination. Further details on scaling and control technologies are provided in SpERC factsheet(http://cefic.org/en/reach-for-industries-libraries html). Scaled local assessments for EU refineries have been performed usingsite-specific data and are attached in PETRORISK file – “Site-Specific Production” worksheet. If scaling reveals a condition ofunsafe use (i.e., RCRs > 1), additional RMMs or a site-specific chemical safety assessment is required. Measured data have beenused to demonstrate that the PETRORISK predicteds fence-line concentrations in air are overestimated. These data support theconclusion that no refineries have RCRs>1 (Petrorisk file in IUCLID section 13- Site-specific Production & Tier II worksheets).

/ 41


1. Exposure scenarioIndustrial, Distribution of substance.

Use DescriptorSector of useSU3 - Industrial Manufacturing (all)

Process categoryPROC1 - Use in closed process, no likelihood of exposurePROC2 - Use in closed, continuous process with occasional controlled exposurePROC3 - Use in closed batch process (synthesis or formulation)PROC4 - Use in batch and other process (synthesis) where opportunity for exposure arisesPROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilitiesPROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilitiesPROC9 - Transfer of substance or preparation into small containers (dedicated filling line, including weighing)PROC15 - Use as laboratory reagent

Environmental Release CategoryERC1 - Manufacture of substancesERC2 - Formulation of preparationsERC3 - Formulation in materialsERC4 - Industrial use of processing aids in processes and products, not becoming part of articlesERC5 - Industrial use resulting in inclusion into or onto a matrixERC6a - Industrial use resulting in manufacture of another substance (use of intermediates)ERC6b - Industrial use of reactive processing aidsERC6c - Industrial use of monomers for manufacture of thermoplasticsERC6d - Industrial use of process regulators for polymerization processes in production of resins, rubbers, polymersERC7 - Industrial use of substances in closed systems

Specific Environmental Release CategoryESVOC SpERC 1.1b. v1.

Processes, tasks, activities coveredLoading (including marine vessel/barge, rail/road car and IBC loading) and repacking (including drums and small packs) ofsubstance, including its sampling, storage, unloading distribution and associated laboratory activities.




Amounts used:




Local freshwater dilution factor: 10

/ 41Local marine water dilution factor: 100

Release fraction to air from process (initial release prior to RMM): 1E-3Release fraction to wastewater from process (initial release prior to RMM): 1E-5Release fraction to soil from process (initial release prior to RMM): 1E-5


Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soilRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation)If discharging to domestic sewage treatment plant, no onsite wastewater treatment required

Treat air emission to provide a typical removal efficiency of (%): 90Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): >=12If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of (%): >=0



Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.1E+6Assumed domestic sewage treatment plant flow (m3/d): 2000Conditions and measures related to external treatment of waste for disposalExternal treatment and disposal of waste should comply with applicable local and/or national regulations.

Conditions and measures related to external recovery of wasteExternal recovery and recycling of waste should comply with applicable local and/or national regulations.





Amounts usedNot applicable.Frequency and duration of useCovers daily exposures up to 8 hours (unless stated differently)

Human factors not influenced by risk managementnot applicableOther operational conditions affecting exposureAssumes use at not more than 20°C above ambient temperature, unless stated differently. Assumes a good basic standard ofoccupational hygiene is implemented.

/ 41


HealthThe ECETOC TRA tool has been used to estimate consumer exposures unless otherwise indicated

EnvironmentThe Hydrocarbon Block Method has been used to calculate environmental exposure with the Petrorisk model.



EnvironmentGuidance is based on assumed operating conditions which may not be applicable to all sites; thus, scaling may be necessary todefine appropriate site-specific risk management measures. Required removal efficiency for wastewater can be achieved usingonsite/offsite technologies, either alone or in combination. Required removal efficiency for air can be achieved using on-sitetechnologies, either alone or in combination. Further details on scaling and control technologies are provided in SpERC factsheet(http://cefic.org/en/reach-for-industries-libraries html).








General exposures (open systems) Provide extract ventilation to material transfer points and other openings.



Bulk closed loading and unloading No other specific measures identified.

Drum and small package filling Fill containers/cans at dedicated fill points supplied with local extractventilation.

Equipment cleaning and maintenance No other specific measures identified.



/ 41


1. Exposure scenarioFormulation & (re)packing of substances and mixtures, Industrial.

Use DescriptorSector of useSU3 - Industrial Manufacturing (all)SU10 - Formulation [mixing] of preparations and/or re-packaging (excluding alloys)

Process categoryPROC1 - Use in closed process, no likelihood of exposurePROC2 - Use in closed, continuous process with occasional controlled exposurePROC3 - Use in closed batch process (synthesis or formulation)PROC4 - Use in batch and other process (synthesis) where opportunity for exposure arisesPROC5 - Mixing or blending in batch processes for formulation of preparations and articles (multistage and/or significant contact)PROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilitiesPROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilitiesPROC9 - Transfer of substance or preparation into small containers (dedicated filling line, including weighing)PROC14 - Production of preparations or articles by tabletting, compression, extrusion, pelletisationPROC15 - Use as laboratory reagent

Environmental Release CategoryERC2 - Formulation of preparations


Processes, tasks, activities coveredFormulation, packing and re-packing of the substance and its mixtures in batch or continuous operations, including storage,materials transfers, mixing, tabletting, compression, pelletisation, extrusion, large and small scale packing, sampling, maintenanceand associated laboratory activities.




Amounts used:



Environment factors not influenced by risk management


Release fraction to air from process (initial release prior to RMM): 0.025Release fraction to wastewater from process (initial release prior to RMM): 0.002Release fraction to soil from process (initial release prior to RMM): 0.0001

/ 41


Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soilPrevent discharge of undissolved substance to or recover from onsite wastewaterRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation)If discharging to domestic sewage treatment plant, no onsite wastewater treatment required

Treat air emission to provide a typical removal efficiency of (%): 56.5Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): >=94.7If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of (%): >= 0



Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.0E+5Assumed domestic sewage treatment plant flow (m3/d): 2000Conditions and measures related to external treatment of waste for disposalExternal treatment and disposal of waste should comply with applicable local and/or national regulations.

Conditions and measures related to external recovery of wasteExternal recovery and recycling of waste should comply with applicable local and/or national regulations.







/ 41





HealthPredicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditionsoutlined in Section 2 are implemented. Where other Risk Management Measures/Operational Conditions are adopted, then usersshould ensure that risks are managed to at least equivalent levels. Available hazard data do not enable the derivation of a DNELfor dermal irritant effects. Available hazard data do not support the need for a DNEL to be established for other health effects. Risk








General exposures (open systems) Provide extract ventilation to material transfer points and other openings.

Mixing operations (closed systems) Provide extract ventilation to points where emissions occur.



Bulk transfers Ensure material transfers are under containment or extract ventilation.

Drum/batch transfers Ensure material transfers are under containment or extract ventilation.

Drum and small package filling Fill containers/cans at dedicated fill points supplied with local extractventilation.

Equipment cleaning and maintenance No other specific measures identified.


Manual Transfer from/pouring from containers Ensure material transfers are under containment or extract ventilation.


/ 41Management Measures are based on qualitative risk characterization.


/ 41


1. Exposure scenarioUse as a fuel, Industrial.

Use DescriptorSector of useSU3 - Industrial Manufacturing (all)

Process categoryPROC1 - Use in closed process, no likelihood of exposurePROC2 - Use in closed, continuous process with occasional controlled exposurePROC3 - Use in closed batch process (synthesis or formulation)PROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilitiesPROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilitiesPROC16 - Using material as fuel sources, limited exposure to unburned product to be expected

Environmental Release CategoryERC7 - Industrial use of substances in closed systems

Specific Environmental Release CategoryESVOC SpERC 7.12a.v1.

Processes, tasks, activities coveredCovers the use as a fuel (or fuel additive) and includes activities associated with its transfer, use, equipment maintenance andhandling of waste.




Amounts used:

Fraction of EU tonnage used in region: 0.1Regional use tonnage (tonnes/year): 1.4E+6Fraction of Regional tonnage used locally: 1Annual site tonnage (tonnes/year): 1.4E+6Maximum daily site tonnage (kg/day): 4.6E+6




Release fraction to air from process (initial release prior to RMM): 0.0025Release fraction to wastewater from process (initial release prior to RMM): 0.00001Release fraction to soil from process (initial release prior to RMM): 0


Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soilRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation)

/ 41If discharging to domestic sewage treatment plant, no onsite wastewater treatment required

Treat air emission to provide a typical removal efficiency of (%): 99.4Treat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): >= 76.9If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of (%): >= 0



Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d): 4.6E+6Assumed domestic sewage treatment plant flow (m3/d): 2000Conditions and measures related to external treatment of waste for disposalCombustion emissions limited by required exhaust emission controls. Combustion emissions considered in regional exposureassessment.

Conditions and measures related to external recovery of wasteThis substance is consumed during use and no waste of the substance is generated.







/ 41












Bulk closed unloading No other specific measures identified.

Refueling No other specific measures identified.

Refueling aircraft Ensure material transfers are under containment or extract ventilation.

Use as a fuel (closed systems) No other specific measures identified.

Bulk transfers No other specific measures identified.


Equipment maintenance No other specific measures identified.



/ 41


1. Exposure scenarioUse as a fuel, Professional.

Use DescriptorSector of useSU22 - Professional uses: Public domain (administration, education, entertainment, services, craftsmen)

Process categoryPROC1 - Use in closed process, no likelihood of exposurePROC2 - Use in closed, continuous process with occasional controlled exposurePROC3 - Use in closed batch process (synthesis or formulation)PROC8a - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at non-dedicated facilitiesPROC8b - Transfer of substance or preparation (charging/discharging) from/to vessels/large containers at dedicated facilitiesPROC16 - Using material as fuel sources, limited exposure to unburned product to be expected

Environmental Release CategoryERC9a - Wide dispersive indoor use of substances in closed systemsERC9b - Wide dispersive outdoor use of substances in closed systems


Processes, tasks, activities coveredCovers the use as a fuel (or fuel additive) and includes activities associated with its transfer, use, equipment maintenance andhandling of waste.




Amounts used:

Fraction of EU tonnage used in region: 0.1Regional use tonnage (tonnes/year): 1.19E+6Fraction of Regional tonnage used locally: 0.0005Annual site tonnage (tonnes/year): 5.9E2Maximum daily site tonnage (kg/day): 1.6E+3




Other operational conditions of use affecting environmental exposure.


Technical conditions and measures at process level to prevent release

/ 41Common practices vary across sites thus conservative process release estimates used.

Technical onsite conditions and measures to reduce or limit discharges, air emissions and releases to soilRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation)If discharging to domestic sewage treatment plant, no onsite wastewater treatment required

Treat air emission to provide a typical removal efficiency of (%): N/ATreat onsite wastewater (prior to receiving water discharge) to provide the required removal efficiency of (%): >= 3.4If discharging to domestic sewage treatment plant, provide the required onsite wastewater removal efficiency of (%): >= 0



Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Total efficiency of removal from wastewater after onsite and offsite (domestic treatment plant) RMMs (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.5E+4Assumed domestic sewage treatment plant flow (m3/d): 2000Conditions and measures related to external treatment of waste for disposalCombustion emissions limited by required exhaust emission controls. Combustion emissions considered in regional exposureassessment.

Conditions and measures related to external recovery of wasteThis substance is consumed during use and no waste of the substance is generated.







/ 41





HealthPredicted exposures are not expected to exceed the DN(M)EL when the Risk Management Measures/Operational Conditionsoutlined in Section 2 are implemented. Where other Risk Management Measures/Operational Conditions are adopted, then usersshould ensure that risks are managed to at least equivalent levels. Available hazard data do not enable the derivation of a DNELfor carcinogenic and dermal irritant effects. Available hazard data do not support the need for a DNEL to be established for otherhealth effects. Risk Management Measures are based on qualitative risk characterization.







Bulk closed unloading No other specific measures identified.

Preparation of material for application Mixingoperations (closed systems)


Refueling No other specific measures identified.

Use as a fuel (closed systems) No other specific measures identified.


Equipment maintenance Drain down system prior to equipment break-in or maintenance. Wearchemically resistant gloves (tested to EN374) in combination with intensivemanagement supervision controls.



/ 41


1. Exposure scenarioUse as a fuel, Consumer.

Use DescriptorSector of useSU21 - Private households (= general public = consumers)

Product categoryPC13 - Fuels

Environmental Release CategoryERC9a - Wide dispersive indoor use of substances in closed systemsERC9b - Wide dispersive outdoor use of substances in closed systems

Specific Environmental Release CategoryESVOC SpERC 9.12c.v1.

Processes, tasks, activities coveredCovers consumer uses in liquid fuels.




Amounts used:






Conditions and measures related to municipal sewage treatment plantRisk from environmental exposure is driven by humans via indirect exposure (primarily inhalation) :

Estimated substance removal from wastewater via domestic sewage treatment (%): 95.5Maximum allowable site tonnage (MSafe) (kg/d): 1.8E+5Assumed domestic sewage treatment plant flow (m3/d): 2000Conditions and measures related to external treatment of waste for disposalCombustion emissions limited by required exhaust emission controls. Combustion emissions considered in regional exposureassessment.

/ 41Conditions and measures related to external recovery of wasteThis substance is consumed during use and no waste of the substance is generated.




Concentration of substance in productUnless otherwise stated. Covers concentrations up to (%):100.

Amounts usedUnless otherwise stated. Covers use amounts up to (g) : 37500g . Covers skin contact area up to (cm2): 420.Frequency and duration of useUnless otherwise statedCovers use up to (times/day of use):0.143Covers exposure up to (hours/event):2

Other operational conditions affecting exposureUnless otherwise stated. Assumes use at ambient temperature. Assumes use in a 20 m3 room. Assumes use with typicalventilation.

2.2a. Control of worker exposureContributing Scenarios Operational conditions and risk management measures

Not applicable

/ 41


HealthThe ECETOC TRA tool has been used to estimate consumer exposures, consistent with the content of ECETOC report #107 andthe Chapter R15 of the IR&CSA TGD Where exposure determinants differ to these sources, then they are indicated


4. Guidance for Downstream User to check compliance with the Exposure

2.2b. Control of consumer exposureProduct Category(ies) Operational conditions and risk management measures

PC13 - Fuels Liquid: Automotive Refuelling Unless otherwise statedCovers concentrations up to (%):100Covers use up to (days/year):52Covers use up to (times/day of use):1Covers skin contact area up to (cm2): 210.00For each use event, assumes swallowed amount of (g):37500Covers outdoor useCovers use in room size of (m3):100For each use eventCovers exposure up to (hours/event):0.05No specific risk management measure identified beyond those operationalconditions stated

PC13 - Fuels Liquid Scooter Refuelling Unless otherwise statedCovers use up to (days/year):100Covers use up to (times/day of use):52Covers skin contact area up to (cm2): 210.00For each use event, covers use amounts up to (g):3750Covers outdoor useCovers use in room size of (m3):100For each use eventCovers exposure up to (hours/event):0.03No specific risk management measure identified beyond those operationalconditions stated

PC13 - Fuels Liquid Garden Equipment - Use Unless otherwise statedCovers concentrations up to (%):100Covers use up to (days/year):26Covers use up to (times/day of use):1For each use event, covers use amounts up to (g):750Covers outdoor useCovers use in room size of (m3):100For each use eventCovers exposure up to (hours/event):2.00No specific risk management measure identified beyond those operationalconditions stated

PC13 - Fuels Liquid: Garden Equipment -Refueling

Unless otherwise statedCovers concentrations up to (%):100Covers use up to (days/year):26Covers use up to (times/day of use):1Covers skin contact area up to (cm2): 420.00For each use event, covers use amounts up to (g):750Covers use in a one car garage (34 m3) under typical ventilationCovers use in room size of (m3):34For each use eventCovers exposure up to (hours/event):0.03

No specific risk management measure identifiedbeyond those operational conditions stated

/ 41

scenario

HealthPredicted exposures are not expected to exceed the applicable consumer reference values when the operational conditions/riskmanagement measures given in section 2 are implemented. Where other Risk Management Measures/Operational Conditions areadopted, then users should ensure that

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