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3V Product Specification - The Chemistry · PDF fileeno "..:> ~ 'l:;8.' 1000

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Edition 1/1 PNC 400 Thickening agent Chemical and physical characteristics (*) Viscosity (mPa's) of water dispersions (Brookfield RV, 20 rpm, 25°C) Appearance Bulk density pH (0.5% water dispersion) Chemical Name INCI NAME Carboxyvinyl polymer sodium salt Sodium Carbomer Hygroscopic white powder 0.3-0.45 g/cm 3 6.0-7.5 The shape of the agitator and the agitation speed are different from those used to disperse the acid polymer. The best way to operate is to use the equipment normally employed during the neutralizing phase of carbomer (anchor type). Slow addition of the powder avoids the formation of lumps and guarantees a quick thickening. During the preparation of emulsions, PNC 400 can be dispersed in the oil or in the water phase before the emulsification step or sprinkled directly into the emulsion, stirring until an homogeneous system is obtained. Figure 2 - Viscosity vs pH of polymer dispersion Figure 1 - Viscosity vs polymer concentration % of polymer 1000 0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 10000 100000 en o " .. :> 'l:; 8 1000 .' <:" .. - liS 10000 f 100000 100 2 3 4 5 6 7 8 9 10 11 12 13 14 pH 0.2% water dispersion 0.5% water dispersion Contrary to traditional carbomers, PNC 400 does not require any pre-dispersion and thickens as soon as sprinkled into water or water/alcohol blend (up to 70:30) giving a clear viscous gel. Use ("J Typical values not qualified for quality control purpose Applications PNC 400 is a pre-neutralized synthetic polymer that can be used as thickener, suspending agent and stabilizer in most cosmetic products. The use of pre-neutralized Carbomers provides several advantages: superior handling (low dusting powder) quick dispersion simplification of production process (elimination of neutralizing phase) constant pH during all the production process possibility to modify the viscosity of finished products PNC 400 dispersions are characterized by high viscosity and clarity (see Fig. 1 and 2). % Dispersion Viscosity Spindle Min. Max 0.2 13,000 25,000 6 0.5 35,000 55,000 7 The information contained in this data sheet is based on our present and best knowledge. However we make no warranty, whether expressed or implied. including warranties of merchantability or of fitness for a particular use or purpose. Consequently the product must be tested by the user according to his needs and his production and application conditions and purposes. Neither do we assume any responsibility for infringement of third parties patent rights which may arise from the use of the product. For industrial use only. '7Cosmetic Division 11 V llli '"," S.PA P.o. Box 219 Via Torquato Tasso, 58 24100 Bergamo (Italy) Tel.: +39 (35)4165111 Fax: +39 (35) 239569 Tlx.: 300108 3V and logotype are registered tr.Idemarks of 3V Partltcipazioni Industriali S.p.A. Milano· Italy
Transcript

Edition 1/1

PNC 400Thickening agent

Chemical and physical characteristics (*)

Viscosity (mPa's) of water dispersions(Brookfield RV, 20 rpm, 25°C)

Appearance

Bulk density

pH (0.5% water dispersion)

Chemical Name

INCI NAME

Carboxyvinyl polymer sodium salt

Sodium Carbomer

Hygroscopic white powder

0.3-0.45 g/cm3

6.0-7.5

The shape of the agitator and the agitation speed aredifferent from those used to disperse the acid polymer. Thebest way to operate is to use the equipment normallyemployed during the neutralizing phase of carbomer (anchortype). Slow addition of the powder avoids the formation oflumps and guarantees a quick thickening.During the preparation of emulsions, PNC 400 can bedispersed in the oil or in the water phase before theemulsification step or sprinkled directly into the emulsion,stirring until an homogeneous system is obtained.

Figure 2 - Viscosity vs pH of polymer dispersion

Figure 1 - Viscosity vs polymer concentration

% of polymer

1000

0.0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6

10000

100000

.~eno"..:>

~'l:;

8 1000

.'<:"..-

liS~ 10000

f

100000

100

2 3 4 5 6 7 8 9 10 11 12 13 14

pH

0.2% water dispersion 0.5% water dispersion

Contrary to traditional carbomers, PNC 400 does not requireany pre-dispersion and thickens as soon as sprinkled intowater or water/alcohol blend (up to 70:30) giving a clearviscous gel.

Use

("J Typical values not qualified for quality control purpose

Applications

PNC 400 is a pre-neutralized synthetic polymer that can beused as thickener, suspending agent and stabilizer in mostcosmetic products.The use of pre-neutralized Carbomers provides severaladvantages:

superior handling (low dusting powder)quick dispersionsimplification of production process (elimination ofneutralizing phase)constant pH during all the production processpossibility to modify the viscosity of finished products

PNC 400 dispersions are characterized by high viscosityand clarity (see Fig. 1 and 2).

% Dispersion Viscosity Spindle

Min. Max

0.2 13,000 25,000 6

0.5 35,000 55,000 7

The information contained in this data sheet is based on our present and best knowledge. However we make no warranty, whether expressed or implied.including warranties of merchantability or of fitness for a particular use or purpose. Consequently the product must be tested by the user according to hisneeds and his production and application conditions and purposes. Neither do we assume any responsibility for infringement of third parties patent rightswhich may arise from the use of the product. For industrial use only.

'7Cosmetic Division

~'-" J'~ 11 V llli '"," S.PA

P.o. Box 219 Via Torquato Tasso, 58 24100 Bergamo (Italy)Tel.: +39 (35)4165111 Fax: +39 (35) 239569 Tlx.: 3001083V and logotype are registered tr.Idemarks of 3V Partltcipazioni Industriali S.p.A. Milano· Italy

The pH achieved at 0.5% in water is around 7. If a lower pHis required, little adjustments are possible by addition ofacids (e.g. HCI, H3P04, citric and lactic acid). High amountsof acid should be avoided because of the formation of saltthat affects the viscosity widely.If a strong reduction of pH is needed, the use of blend ofPNC 400 and the corresponding acid polymer (Le.Synthalen K) provides good viscosity in a broad range of pHwithout using any neutralizing agent.In normal conditions, gels prepared with PNC 400 neitherprevent nor promote the growth of micro-organisms;therefore the addition of a suitable preservative system isadvisable.UV rays can cause loss of viscosity in PNC 400 gels. Theaddition of water-soluble UV-absorbers, such as UVASORBS5 (Benzophenone-4), can help for preventing polymerdegradation.

Toxicological Information

LOso (oral) > 2000 mg/kg

Acute skin irritation non irritant

Acute eye irritation non irritant

Skin sensitization (max. test) non-sensitizing

(TOXicological tests performed on the acid form)

Transport, storage and handling

Labelling: product not classified as hazardous according tointernational transport regulations.Store in the original closed containers in a dry cool place.Protect from moisture. Do not breathe dust and avoidcontact with skin, eyes and mucous membranes. In case ofcontact, wash immediately with plenty of water.

For further information please refer to safety data sheet.

7 c~~:etic DivisionP.O. Box 219 Via Torquato Tasso, 58 24100 Bergamo (ltalYITel.: +39 (35) 4165111 Fax: +39 (35) 239569 Tlx.: 3001083V and logotype are registered lnldemarks of 3V Partecipazioni Industrial! S.p.A. Milano - Italy


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