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RetentionQuantifying for

precursor/MRM transitions for

precursor/ Declustering CollisionCollisioncell exit

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o. es c e me, m n pro uc on pro uc on po en a , energy, po en a ,

178 Spinosad 14.14 732/142 732/142; 732/98 48 45; 96 2; 2

179 Fensulfothion 14.20 309/157 309/157; 309/173 35 33; 31 3; 2

180 Dimethametryn 14.69 256/186 256/186; 256/96 36 28; 20 2; 2

181 Propanil 15.77 218/162 218/162; 218/127 45 23; 41 2; 2

182 Triticonazole 16.10 318/70 318/70; 318/125 28 42; 50 2; 3

183 Fluridone 16.22 330/309 330/309; 330/259 54 47; 61 3; 5

184 Prochloraz 16.31 376/308 376/308; 376/266 31 17; 22 5; 4

185 Methfuroxam 16.79 230/137 230/137; 230/111 32 27; 20 3; 2

186 Benoxacor 17.35 260/149 260/149; 260/134 40 23; 41 4; 2

187 Ethoxysulfuron 17.42 399/261 399/261; 399/218 60 21; 33 3; 3

188 Epoxiconazole 14.82; 17.84 330/121 330/121; 330/141 32 32; 25 2; 2

189 Fluquinconazole 18.39 376/349 376/349; 376/307 53 26; 32 9; 4

190 Mepanipyrim 18.86 224/77 224/77; 224/106 40 55; 36 2; 2

191 Methoxyfenozide 19.31 369/149 369/149; 369/313 19 25; 10 5; 5

192 Mepronil 19.48 270/119 270/119; 270/228 28 31; 20 2; 3193 Oryzalin 19.84 347/288 347/288; 347/198 38 24; 40 2; 2

194 Fenoxycarb 20.03 302/116 302/116; 302/88 26 17; 31 2; 2

195 Thenylchlor 20.23 324/127 324/127; 324/99 30 24; 45 2; 2

196 Ditalimfos 20.34 300/148 300/148; 300/130 40 19; 42 2; 2

197 Fluorochloridone 20.52 312/292 312/292; 312/212 49 28; 43 5; 3

198 Etridiazol 21.58 247/219 247/219; 247/183 30 18; 26 3; 3

199 Butafenacil 21.65 475/331 475/331; 475/349 50 27; 14 4; 7200 Pyrimitate 21.75 306/170 306/170; 306/154 35 27; 28 3; 2

201 Bromobutide 21.83 312/194 312/194; 312/119 35 18; 26 2; 2

202 Fenoxanil 21.83; 22.05 329/302 329/302; 329/189 38 16; 35 3; 2

203 Monalide 20.15; 21.98 240/85 240/85; 240/93 39 27; 53 2; 3204 Kresoxim-methyl 22.29 314/235 314/235; 314/222 15 20; 18 3; 2

205 Quinalphos 22.37 299/163 299/163; 299/147 34 33; 31 2; 2

206 Benzoylprop-ethyl 23.71 366/105 366/105; 366/320 25 30; 13 2; 4

207 Coumaphos 24.39 363/227 363/227; 363/307 63 34; 25 4; 4

208 Phosalone 24.93 368/182 368/182; 368/111 31 23; 59 2; 2

209 Phoxim 24.95 299/97 299/97; 299/129 36 35; 18 2; 3

210 Piperophos 25.17 354/171 354/171; 354/143 26 30; 43 3; 2

211 Chlorphoxim 25.50 333/97 333/97; 333/163 22 34; 20 2; 2

212 MCPA-butoxyethyl ester 25.95 301/227 301/227; 301/155 43 8; 30 5; 2

213 Fluoroglycofen-ethyl 26.41 465/344 465/344; 465/223 47 21; 50 4; 2

214 Piperonyl butoxide 26.55 356/177 356/177; 356/119 15 19; 50 2; 2

215 Dithiopyr 26.62 402/354 402/354; 402/296 38 24; 35 5; 2

216 Flumiclorac-pentyl 27.00 441/308 441/308; 441/252 45 36; 51 3; 3

217 Oxyfluorfen 27.21 362/316 362/316; 362/237 32 18; 30 5; 2

218 Butachlor 27.25 312/238 312/238; 312/147 22 13; 46 2; 2

219 Iodofenphos 27.38 412/125 412/125; 412/287 43 30; 37 2; 10

220 Temephos 27.61 467/419 467/419; 467/341 40 27; 41 5; 4

221 Pendimethalin 27.85 282/212 282/212; 282/194 23 17; 25 2; 2

222 Fenpyroximate 28.38 422/366 422/366; 422/214 33 23; 38 6; 5

No. PesticideRetentiontime, min

Quantifying forprecursor/product ion

MRM transitions forprecursor/product ion

Declusteringpotential, V

Collisionenergy, V

Collisioncell exit

potential, V

223 Pyrethrin 28.70 329/133 329/133; 329/143 39 25; 26 2; 5

224 Fenpropathrin 29.20 350/125 350/125; 350/97 35 23; 42 2; 2

225 Pyridaben 29.62 365/147 365/147; 365/309 65 37; 19 2; 3

226 Aspon 29.74 379/115 379/115; 379/97 27 46; 82 4; 2

227 Spirodiclofen 29.89 411/71 411/71; 411/313 48 29; 17 2; 5

228 Leptophos 30.09 411/171 411/171; 411/379 51 30; 23 7; 16

229 Phenothrin 30.78; 30.98 351/183 351/183; 351/333 45 30; 14 3; 5

D group

230 Cyromazine 2.24 167/125 167/125; 167/108 46 25; 29 6; 6

231 Thiofanox sulfoxide 2.31 235/104 235/104; 235/178 16 13; 9 2; 3

232 Propamocarb 1.82; 2.33 189/102 189/102; 189/144 22 24; 17 3; 5

233 Ethirimol 2.36 210/140 210/140; 210/98 46 30; 39 2; 2

234 Dazomet 8.86 163/90 163/90; 163/120 27 12; 15 3; 3

235 Dicrotophos 9.23 238/112 238/112; 238/127 18 18; 24 2; 2

236 Metamitron 10.02 203/175 203/175; 203/104 33 22; 35 5; 3

237 Crimidine 10.04 172/136 172/136; 172/107 37 27; 30 4; 5

238 Dimethoate 10.55 230/199 230/199; 230/125 19 11; 28 3; 1.5

239 Terbumeton 10.73 226/170 226/170; 226/114 34 25; 34 3; 4

240 Desmetryn 10.79 214/172 214/172; 214/82 48 23; 45 4; 3

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.

242 Hexazinone 11.43 253/171 253/171; 253/85 32 23; 45 3; 3

243 Carbetamide 11.50 237/192 237/192; 237/118 18 11; 18 2; 4

244 Dodemorph 11.58; 11.76 282/116 282/116; 282/98 29 30; 40 2; 2

245 Triamiphos 11.90 295/135 295/135; 295/110 47 34; 55 2; 5

246 Chlorotoluron 13.30 213/72 213/72; 213/140 29 38; 33 3; 3

247 Carbaryl 13.50 202/145 202/145; 202/127 20 15; 40 2; 2

248 Fluometuron 13.51 233/72 233/72; 233/160 29 40; 39 2; 4

249 Fosthiazate 13.51 284/104 284/104; 284/228 22 34; 13 2; 3

250 4,4-Dibromobenzophenone 13.55 339/283 339/283; 339/121 63 25; 44 2; 3

251 Isoproturon 13.84 207/72 207/72; 207/165 27 35; 19 2; 2

252 Carboxin 13.90 236/143 236/143; 236/124 37 22; 31 2; 2

253 Fenfuram 14.24 202/109 202/109; 202/120 38 34; 21 2; 2

254 Norflurazon 14.39 304/284 304/284; 304/160 66 27; 41 6; 5

255 3,4,5-Trimethacarb 14.65 194/137 194/137; 194/122 18 16; 37 2; 4

256 Nuarimol 14.99 315/81 315/81; 315/252 50 47; 31 2; 3

257 Diphenamid 15.22 240/134 240/134; 240/167 35 32; 31 2; 6

258 Buturon 15.52 237/84 237/84; 237/126 39 24; 40 2; 2

259 Thionazin 15.74 249/97 249/97; 249/221 22 43; 12 3; 2260 Benodanil 15.82 324/231 324/231; 324/203 50 30; 47 6; 2

261 Cyproconazole 16.22 292/70 292/70; 292/125 38 45; 42 2; 4

262 Fenobucarb 16.34 208/95 208/95; 208/152 36 26; 12 2; 2

263 Methacrifos 16.88 241/125 241/125; 241/209 20 27; 12 2; 2

264 Simeconazole 16.96 294/70 294/70; 294/135 59 39; 30 2; 4

265 Anilazine 16.98 275/155 275/155; 275/169 33 34; 33 3; 6

266 Crufomate 17.26 292/236 292/236; 292/108 46 24; 40 4; 4

No. PesticideRetentiontime, min

Quantifying forprecursor/product ion

MRM transitions forprecursor/product ion

Declusteringpotential, V

Collisionenergy, V

Collisioncell exit

potential, V

267 Aziprotryne 17.53 226/156 226/156; 226/198 20 19; 13 3; 2

268 Azoxystrobin 17.70 404/372 404/372; 404/344 32 20; 33 6; 3

269 Triadimefon 18.00 294/197 294/197; 294/225 29 20; 17 2; 2

270 Ethoprophos 18.08 243/131 243/131; 243/97 33 27; 46 3; 3

271 Pyridaphenthion 18.32 341/189 341/189; 341/205 46 28; 26 2; 3

272 Coumatetralyl 18.63 293/175 293/175; 293/91 58 29; 56 3; 3

273 Trietazine 19.22 230/99 230/99; 230/132 40 32; 30 3; 2

274 Isoprothiolane 19.82 291/189 291/189; 291/231 13 28; 15 2; 3

275 Tebutam 19.91 234/91 234/91; 234/192 54 40; 21 1.5; 3

276 Triflumizole 20.12 346/278 346/278; 346/69 15 13; 30 5; 2

277 Flufenacet 20.53 364/194 364/194; 364/152 11 17; 27 7; 6

278 Propetamphos 20.66 282/156 282/156; 282/110 30 15; 40 2; 3

279 EPTC 21.32 190/128 190/128; 190/86 20 15; 18 3; 3

280 Tebufenozide 21.36 353/133 353/133; 353/297 46 30; 11 2; 2

281 Chlorfenvinphos 21.36 359/99 359/99; 359/155 27 45; 18 3; 2

282 Mecarbam 21.70 330/199 330/199; 330/171 19 20; 24 7; 7

283 Difenoconazole 22.50 406/251 406/251; 406/337 40 35; 23 4; 5

284 Tri-iso-butyl phosphate 22.60; 23.01 267/155 267/155; 267/211 24 12; 9 2; 2

285 Pyraclofos 22.98 361/257 361/257; 361/275 43 30; 28 5; 2286 Bensulide 23.45 398/158 398/158; 398/314 21 33; 14 2; 5

287 Sulfallate 23.55 224/88 224/88; 224/116 25 30; 17 2; 1.5

288 Thiobencarb 24.08 258/125 258/125; 258/89 31 31; 71 3; 2

289 Mefenpyr-diethyl 24.35 373/160 373/160; 373/186 25 45; 50 3; 1.5

290 Pencycuron 24.49 329/125 329/125; 329/218 35 40; 20 1.5; 3

291 Vernolate 24.51 204/128 204/128; 204/162 22 16; 20 3; 6

292 Sulfotep 24.66 323/115 323/115; 323/171 25 41; 20 2; 2293 Profenefos 25.28 373/302.9 373/302.9; 373/345 34 24; 17 3; 5

294 4,4-Dichlorobenzophenone 25.43; 26.42 251/139 251/139; 251/111 32 25; 52 2; 4

295 Isofenphos 25.69 346/121 346/121; 346/245 18 54; 18 2; 3

296 Clomeprop 25.88 324/120 324/120; 324/203 47 27; 21 4; 2

297 Kadethrin 26.93 397/171 397/171; 397/143 33 19; 35 3; 1.5

298 Sethoxydim 27.09 328/178 328/178; 328/282 40 28; 16 2; 3

299 Terbufos 27.42 289/103 289/103; 289/187 20 14; 19 4; 2300 Lactofen 27.59 462/344 462/344; 462/223 64 17; 42 14; 9

301 Tebupirimfos 27.66 319/153 319/153; 319/277 34 42; 20 1.5; 4

302 Chlorpyrifos 27.87 350/198 350/198; 350/97 31 28; 46 3; 2

303 Ethion 28.17 385/143 385/143; 385/199 19 35; 12 3; 2

304 Sulprofos 28.31 323/219 323/219; 323/155 42 24; 32 2; 1.5

305 Butralin 28.62 296/240 296/240; 296/222 20 19; 30 4; 4

306 Bromophos-ethyl 29.86 393/337 393/337; 393/162 35 25; 52 3; 2

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307 Mepiquat chloride 2.02 114/98 114/98; 114/84 38 37; 39 2; 2

308 Dimethirimol 2.37; 9.39 210/140 210/140; 210/98 42 29; 35 2; 3

309 2,6-Dichlorobenzamide 9.55 190/173 190/173; 190/145 44 31; 36 2; 6

310 Atratone 10.03 212/170 212/170; 212/100 30 28; 36 6; 2

No. PesticideRetentiontime, min

Quantifying forprecursor/product ion

MRM transitions forprecursor/product ion

Declusteringpotential, V

Collisionenergy, V

Collisioncell exit

potential, V

311 Isocarbamid 10.11 186/87 186/87; 186/130 25 25; 16 3; 2

312 Chloridazon 10.33 222/104 222/104; 222/92 43 31; 37 2; 3

313 Dioxacarb 10.54 224/123 224/123; 224/167 15 22; 11 3; 3

314 Tricyclazole 10.71 190/136 190/136; 190/163 42 38; 31 2; 2

315 Flumetsulam 10.99 326/129 326/129; 326/262 44 40; 25 2; 2

316 Triazoxide 11.54 248/150 248/150; 248/124 47 48; 45 2; 2

317 Ametryn 11.90 228/96 228/96; 228/158 35 36; 32 2; 5

318 Allidochlor 12.09 174/98 174/98; 174/106 27 14; 15 3; 2

319 Fenpropidin 11.90 274/147 274/147; 274/165 46 38; 46 5; 2

320 Azamethiphos 12.22 325/183 325/183; 325/112 26 21; 51 3; 2

321 Lenacil 12.35 235/153 235/153; 235/136 26 25; 46 2; 2

322 Cinosulfuron 12.50 414/183 414/183; 414/157 39 28; 34 2; 3

323 Metribuzin 12.56 215/187 215/187; 215/171 37 23; 27 3; 5

324 Pyrifenox 12.97 295/93 295/93; 295/263 43 42; 25 2; 2

325 Terbutryn 13.45 242/186 242/186; 242/91 35 25; 37 2; 2

326 Alanycarb 13.57 339/283 339/283; 339/175 68 21; 32 12; 2

327 Dimethylaminosu lfotolu idide (DMST) 13.61 215/106 215/106 ; 215/151 35 19; 11 3; 3

328 Azaconazole 13.72 300/159 300/159; 300/231 35 40; 23 2; 4

329 Atrazine 13.79 216/174 216/174; 216/104 33 24; 40 2; 3

330 Cyprazine 13.80 228/186 228/186; 228/108 48 24; 37 2; 3

331 Heptanophos 14.31 251/127 251/127; 251/89 30 20; 49 2; 2

332 Bensulfuron-methyl 14.84 411/149 411/149; 411/182 29 31; 30 2; 2

333 Dipropetryn 14.90 256/144 256/144; 256/172 39 37; 30 4; 2

334 Metazachlor 14.91 278/134 278/134; 278/210 15 21; 14 3; 2

335 Iodosulfuron-methyl 15.41 530/390 530/390; 530/163 34 21; 22 4; 2336 Dimethomorph 15.14; 15.56 388/301 388/301; 388/165 40 28; 45 3; 2

337 Sebutylazine 15.60 230/174 230/174; 230/104 37 25; 42 2; 2

338 Bupirimate 15.92 317/108 317/108; 317/210 37 36; 30 4; 2339 Phorate sulfone 16.13 293/143 293/143; 293/171 31 24; 14 2; 4

340 Metosulam 16.65 418/175 418/175; 418/190 62 40; 38 2; 2

341 Pyrazosulfuron-ethyl 16.83 415/182 415/182; 415/369 26 31; 17 2; 3

342 Diethofencarb 16.89 268/152 268/152; 268/180 17 29; 22 3; 3

343 Azinphos-methyl 16.90 318/132 318/132; 318/261 19 21; 10 2; 10

344 Linuron 16.92 249/160 249/160; 249/182 32 25; 21 2; 2

345 Uniconazole 17.32 292/70 292/70; 292/125 44 47; 46 2; 2346 Phosmet 17.51 318/160 318/160; 318/133 22 20; 48 5; 4

347 Mefenacet 17.85 299/120 299/120; 299/148 23 36; 23 2; 2

348 Tetraconazole 18.35 372/159 372/159; 372/150 41 44; 46 6; 4

349 Tebuconazole 18.46 308/70 308/70; 308/125 57 45; 55 2; 3

350 Propyzamide 18.50 256/190 256/190; 256/173 36 20; 32 2; 2

351 Methyl parathion 18.67 264/232 264/232; 264/250 33 20; 18 3; 5

352 Hexaconazole 19.06 314/70 314/70; 314/159 34 45; 45 3; 6

353 Metolachlor 19.93 284/252 284/252; 284/176 34 22; 36 3; 2

354 Malathion 19.93 331/127 331/127; 331/99 30 18; 35 2; 2

355 Alachlor 20.17 270/238 270/238; 270/162 29 14; 25 3; 2

No. PesticideRetentiontime, min

Quantifying forprecursor/product ion

MRM transitions forprecursor/product ion

Declusteringpotential, V

Collisionenergy, V

Collisioncell exit

potential, V

356 Diniconazole 20.31 326/70 326/70; 326/159 34 50; 45 3; 3357 Furmecyclox 20.99 252/170 252/170; 252/110 23 17; 31 3; 2

358 Isazofos 21.72 314/120 314/120; 314/162 32 40; 22 2; 2

359 Nitralin 22.39 346/304 346/304; 346/262 27 20; 25 4; 2

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