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Adrian Gonzalez - MTE 208 Assigment 9

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 1 Gonzalez Adrian Gonzalez MTE 208 Dr. Faltens November 29, 2010 HW9 Carrier Statistics Lab Homework 1. What is the value for each doping level that you need to use? Explain. According to Wikipedia, an intrinsic semiconductor is one that is undoped, that is, is an i-type semiconductor, and is pure with no dopant present. Hence, we have to set N A and N D equal each other in order to obtain an intrinsic semiconductor. Notice that 10/cm 3  is the smallest possible test case. 2. Click on the Temperature tab, and deselect the box that sweeps the temperature. What is the default temperature for the simulation? The default temperatures is 300K, which is around room temperature: 300K - 273.15K = 26.85 0  C
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6. From this diagram, which has a larger effective mass, electrons or holes? Explain how you

can tell.

By theory, n = p in an intrinsic semiconductor. This means that both, electrons and holes will

have the same effective mass. This is can be proved by the final log of the simulation:

7. What is the energy that has the highest density of electrons? How far above the band edge is

this energy (in eV)?

We select "Electron density with energy" in the drop down menu, this will give us a plot with a

highest peak of density, by putting the mouse over we can see that @ 1.62e+11eV/cm3 (which

is the largest density) the energy is 1.14eV. Which is around 1.14eV-1.12eV = 0.02eV above the

band edge.

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8. What is the energy that has the highest density of holes? How far below the band edge is

this energy (in eV)?

We select "Hole density with energy" in the drop down menu, this will give us a plot with a

highest peak of density, by putting the mouse over we can see that @ 1.62e+11 eV/cm3 (which

is the largest density) the energy is -0.0127eV. Which is also represents the position below the

band edge.

9. What is the approximate width of the energy range where electrons are found? What is theapproximate width of the energy range where holes are found? How do these energies

compare to Eg ? How do these energies compare to kT (the thermal energy)?

An approximation for where the electrons and holes can be found can be anything that is

located under the cure of each plot. That is, for electrons the approximate width of the energy

range where they can be found could be between 1.12eV and 1.3eV (by looking at the graph).

Similarly, an approximate width of the energy range where holes are found can be between

0.0eV and 0.2eV. These energies are symmetrical, since the simulation results are from an

intrinsic semiconductor, thus the number of holes equal the number of electrons since Eg is

1.12eV. Now comparing these energies to the thermal energy:

= 8.62 ∙ 10−5

∙  

= 300 

= 0.02586  

This means that Thermal Energy represents the energy above and below the band edges for

both electrons and holes (approximately).

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10. How do the maximum concentrations of electrons and holes compare? (give their values)

From what we learned so far of intrinsic semiconductors, we know that if the amount of 

electrons and holes equal each other, then the maximum concentration of electrons and holes

must be the same. The maximum concentration for electrons and holes are the same at

1.62e+11 eV/cm3

11. If you were to integrate DOS for electrons and DOS for holes over all energies in each band,

what would be the relationship between these two values? Explain in terms of what is

physically happening in the material.

.

If we were to integrate the DOS for both, electrons and holes over all energies in each band,

then we would get the same area under the curve for each band, because as we stated earlier,

n=p, thus we would have the same area under the curve. This means that the electrical

conductivity is due to crystals defects since we are dealing with a pure silicon. Also because of 

thermal excitation, an electron can jump into the Conduction Band, yet at the same moment it

 jumps to this band it would leave behind a hole. Hence n=p for intrinsic semiconductors.

These are trends that you should investigate and try to understand: 

12. In an intrinsic material, what happens to the occupation function as temperature is

changed? (hint: you can sweep the temperature)

As temperature is changed, we can see that when the temperature is cold we can see that the

occupation function looks like a step function (square wave), as we increase the temperature

the occupation function soon starts to curve.

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13. What happens to the Fermi energy under different doping levels? Run the simulation at

300K for several doping levels between 10 and 10E20. Compare these graphs and describe how

Ef changes.

 At 10/cm3: At 10e12/cm

3

 

:

 At 10e17/cm3:  At 10e18/cm

3

  :

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As you can see, when changing the doping levels between 10 and 10E20 the Fermi energy

slightly increases. This is because we no longer have an intrinsic semiconductor, and the

amount of electrons does not equal the amount of holes anymore.

14. What happens to the densities of electrons and holes as doping levels change?

By running the simulations above for different doping levels, I came to the conclusion that the

densities of electrons increase as doping levels increase. Yet as the doping levels increase the

densities of holes decrease.

15. What happens to the densities of electrons and holes as Temperature changes?

This is a really interesting part of the simulation, since we have to use temperature sweep.

After running the simulation for an intrinsic semiconductor, you can change the results to

"Electron density with energy" and then below the graph there is a play button where you cansee what happens to electron density as we change the temperature:

This means that as temperature increases, then the electron density increases. Similarly, since

we are dealing with an intrinsic semiconductor, then the number of electrons must equal the

number of holes, and since electron density increases as temperature increase, then hole

density must increases as well.


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