ANALYTICAL REPORTEurofins TestAmerica, Tampa6712 Benjamin RoadSuite 100Tampa, FL 33634Tel: (813)885-7427
Laboratory Job ID: 660-96392-1Client Project/Site: CCR
For:Waste Connections, Inc.5135 Madison AveTampa, Florida 33619
Attn: Kirk Wills
Authorized for release by:8/13/2019 10:05:04 AM
Willie Hallmon, Project Manager I(813)[email protected]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Waste Connections, Inc.Project/Site: CCR
Laboratory Job ID: 660-96392-1
Page 2 of 14Eurofins TestAmerica, Tampa
8/13/2019
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Definitions/Glossary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8
QC Association Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Lab Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
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Sample SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID
660-96392-1 8/15/19 CCR Solid 08/05/19 08:50 08/05/19 11:29
Eurofins TestAmerica, Tampa
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Case NarrativeClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR
Job ID: 660-96392-1
Laboratory: Eurofins TestAmerica, Tampa
Narrative
Job Narrative660-96392-1
Comments
No additional comments.
Receipt
The sample was received on 8/5/2019 11:29 AM; the sample arrived in good condition, properly preserved and, where required, on ice.
The temperature of the cooler at receipt was 4.7º C.
Metals No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Eurofins TestAmerica, TampaPage 4 of 14 8/13/2019
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Definitions/GlossaryJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Qualifiers
MetalsQualifier Description
U Indicates that the compound was analyzed for but not detected.
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Tampa
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Detection SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Client Sample ID: 8/15/19 CCR Lab Sample ID: 660-96392-1
Barium
PQL
0.050 mg/L
MDL
0.0046
Analyte Result Qualifier Unit Dil Fac D Method Prep Type
TCLP10.11 6010D
Selenium 0.10 mg/L0.025 TCLP10.13 6010D
Eurofins TestAmerica, Tampa
This Detection Summary does not include radiochemical test results.
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Client Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Lab Sample ID: 660-96392-1Client Sample ID: 8/15/19 CCRMatrix: SolidDate Collected: 08/05/19 08:50
Date Received: 08/05/19 11:29
Method: 6010D - Metals (ICP) - TCLPPQL MDL
Silver 0.0073 U 0.050 0.0073 mg/L 08/08/19 14:05 08/09/19 10:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
0.050 0.0093 mg/L 08/08/19 14:05 08/09/19 10:10 1Arsenic 0.0093 U
0.050 0.0046 mg/L 08/08/19 14:05 08/09/19 10:10 1Barium 0.11
0.020 0.0023 mg/L 08/08/19 14:05 08/09/19 10:10 1Cadmium 0.0023 U
0.050 0.0055 mg/L 08/08/19 14:05 08/09/19 10:10 1Chromium 0.0055 U
0.050 0.010 mg/L 08/08/19 14:05 08/09/19 10:10 1Lead 0.010 U
0.10 0.025 mg/L 08/08/19 14:05 08/09/19 10:10 1Selenium 0.13
Method: 7470A - Mercury (CVAA) - TCLPPQL MDL
Mercury 0.00050 U 0.00070 0.00050 mg/L 08/09/19 01:00 08/09/19 18:03 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Tampa
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QC Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Method: 6010D - Metals (ICP)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 660-214114/2-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214171 Prep Batch: 214114
Silver 5.00 4.86 mg/L 97 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Arsenic 5.00 4.91 mg/L 98 80 - 120
Barium 5.00 5.11 mg/L 102 80 - 120
Cadmium 5.00 4.95 mg/L 99 80 - 120
Chromium 5.00 5.16 mg/L 103 80 - 120
Lead 5.00 5.05 mg/L 101 80 - 120
Selenium 5.00 4.92 mg/L 98 80 - 120
Client Sample ID: Method BlankLab Sample ID: LB 660-214108/1-BMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114
PQL MDL
Silver 0.0073 U 0.050 0.0073 mg/L 08/08/19 14:05 08/09/19 10:01 1
LB LB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
0.0093 U 0.00930.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Arsenic
0.0046 U 0.00460.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Barium
0.0023 U 0.00230.020 mg/L 08/08/19 14:05 08/09/19 10:01 1Cadmium
0.0055 U 0.00550.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Chromium
0.010 U 0.0100.050 mg/L 08/08/19 14:05 08/09/19 10:01 1Lead
0.025 U 0.0250.10 mg/L 08/08/19 14:05 08/09/19 10:01 1Selenium
Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114
Silver 0.0073 U 5.00 4.98 mg/L 100 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Arsenic 0.0093 U 5.00 5.10 mg/L 102 75 - 125
Barium 0.11 5.00 5.12 mg/L 100 75 - 125
Cadmium 0.0023 U 5.00 5.08 mg/L 102 75 - 125
Chromium 0.0055 U 5.00 4.99 mg/L 100 75 - 125
Lead 0.010 U 5.00 4.80 mg/L 96 75 - 125
Selenium 0.13 5.00 5.21 mg/L 102 75 - 125
Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSDMatrix: Solid Prep Type: TCLPAnalysis Batch: 214171 Prep Batch: 214114
Silver 0.0073 U 5.00 4.96 mg/L 99 75 - 125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Arsenic 0.0093 U 5.00 5.04 mg/L 101 75 - 125 1 20
Barium 0.11 5.00 5.05 mg/L 99 75 - 125 1 20
Cadmium 0.0023 U 5.00 5.03 mg/L 101 75 - 125 1 20
Chromium 0.0055 U 5.00 4.97 mg/L 99 75 - 125 0 20
Lead 0.010 U 5.00 4.76 mg/L 95 75 - 125 1 20
Selenium 0.13 5.00 5.17 mg/L 101 75 - 125 1 20
Eurofins TestAmerica, Tampa
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QC Sample ResultsJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Method: 7470A - Mercury (CVAA)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 660-214190/14-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214198 Prep Batch: 214190
Mercury 0.00140 0.00150 mg/L 107 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Lab Control Sample DupLab Sample ID: LCSD 660-214190/15-AMatrix: Solid Prep Type: Total/NAAnalysis Batch: 214198 Prep Batch: 214190
Mercury 0.00140 0.00153 mg/L 109 80 - 120 2 20
Analyte
LCSD LCSD
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: LB 660-214108/1-CMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190
PQL MDL
Mercury 0.00050 U 0.00070 0.00050 mg/L 08/09/19 01:00 08/09/19 17:56 1
LB LB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190
Mercury 0.00050 U 0.00140 0.00138 mg/L 99 80 - 120
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: 8/15/19 CCRLab Sample ID: 660-96392-1 MSDMatrix: Solid Prep Type: TCLPAnalysis Batch: 214198 Prep Batch: 214190
Mercury 0.00050 U 0.00140 0.00124 mg/L 88 80 - 120 11 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Eurofins TestAmerica, Tampa
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QC Association SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Metals
Leach Batch: 214108
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 1311660-96392-1 8/15/19 CCR TCLP
Solid 1311LB 660-214108/1-B Method Blank TCLP
Solid 1311LB 660-214108/1-C Method Blank TCLP
Solid 1311660-96392-1 MS 8/15/19 CCR TCLP
Solid 1311660-96392-1 MSD 8/15/19 CCR TCLP
Prep Batch: 214114
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 3010A 214108660-96392-1 8/15/19 CCR TCLP
Solid 3010A 214108LB 660-214108/1-B Method Blank TCLP
Solid 3010ALCS 660-214114/2-A Lab Control Sample Total/NA
Solid 3010A 214108660-96392-1 MS 8/15/19 CCR TCLP
Solid 3010A 214108660-96392-1 MSD 8/15/19 CCR TCLP
Analysis Batch: 214171
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 6010D 214114660-96392-1 8/15/19 CCR TCLP
Solid 6010D 214114LB 660-214108/1-B Method Blank TCLP
Solid 6010D 214114LCS 660-214114/2-A Lab Control Sample Total/NA
Solid 6010D 214114660-96392-1 MS 8/15/19 CCR TCLP
Solid 6010D 214114660-96392-1 MSD 8/15/19 CCR TCLP
Prep Batch: 214190
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 7470A 214108660-96392-1 8/15/19 CCR TCLP
Solid 7470A 214108LB 660-214108/1-C Method Blank TCLP
Solid 7470ALCS 660-214190/14-A Lab Control Sample Total/NA
Solid 7470ALCSD 660-214190/15-A Lab Control Sample Dup Total/NA
Solid 7470A 214108660-96392-1 MS 8/15/19 CCR TCLP
Solid 7470A 214108660-96392-1 MSD 8/15/19 CCR TCLP
Analysis Batch: 214198
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Solid 7470A 214190660-96392-1 8/15/19 CCR TCLP
Solid 7470A 214190LB 660-214108/1-C Method Blank TCLP
Solid 7470A 214190LCS 660-214190/14-A Lab Control Sample Total/NA
Solid 7470A 214190LCSD 660-214190/15-A Lab Control Sample Dup Total/NA
Solid 7470A 214190660-96392-1 MS 8/15/19 CCR TCLP
Solid 7470A 214190660-96392-1 MSD 8/15/19 CCR TCLP
Eurofins TestAmerica, Tampa
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Lab ChronicleClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR
Client Sample ID: 8/15/19 CCR Lab Sample ID: 660-96392-1Matrix: SolidDate Collected: 08/05/19 08:50
Date Received: 08/05/19 11:29
Leach 1311 08/07/19 19:30 GH1214108 TAL TAM
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
TCLP
Prep 3010A 214114 08/08/19 14:05 GH1 TAL TAMTCLP
Analysis 6010D 1 214171 08/09/19 10:10 GAF TAL TAMTCLP
Leach 1311 214108 08/07/19 19:30 GH1 TAL TAMTCLP
Prep 7470A 214190 08/09/19 01:00 GH1 TAL TAMTCLP
Analysis 7470A 1 214198 08/09/19 18:03 GH1 TAL TAMTCLP
Laboratory References:
TAL TAM = Eurofins TestAmerica, Tampa, 6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL (813)885-7427
Eurofins TestAmerica, Tampa
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Method SummaryJob ID: 660-96392-1Client: Waste Connections, Inc.
Project/Site: CCR
Method Method Description LaboratoryProtocol
SW8466010D Metals (ICP) TAL TAM
SW8467470A Mercury (CVAA) TAL TAM
SW8461311 TCLP Extraction TAL TAM
SW8463010A Preparation, Total Metals TAL TAM
SW8467470A Preparation, Mercury TAL TAM
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL TAM = Eurofins TestAmerica, Tampa, 6712 Benjamin Road, Suite 100, Tampa, FL 33634, TEL (813)885-7427
Eurofins TestAmerica, Tampa
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Accreditation/Certification SummaryClient: Waste Connections, Inc. Job ID: 660-96392-1Project/Site: CCR
Laboratory: Eurofins TestAmerica, TampaUnless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program EPA Region Identification Number Expiration Date
Florida E842824NELAP 06-30-20
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
Eurofins TestAmerica, Tampa
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Login Sample Receipt Checklist
Client: Waste Connections, Inc. Job Number: 660-96392-1
Login Number: 96392
Question Answer Comment
Creator: Fullwood, Kierston R
List Source: Eurofins TestAmerica, Tampa
List Number: 1
N/ARadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded.
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
TrueContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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