J. of Supercritical Fluids 79 ( 2013 ) iii – xiv

doi:10.1016/S0896-8446(13)00211-8

Contents

Contents lists available at ScienceDirect

The Journal of Supercritical Fluids

journal homepage: www.elsevier .com/locate/supf lu

Special issue—10th International Symposium on Supercritical Fluids (Keith W. Hutchenson, Guest Editor, The Journal of Supercritical Fluids)

Jerry W. King, Ram B. Gupta, Keith W. Hutchenson, Mark A. McHugh, Feral Temelli

University of Arkansas, Fayetteville, AK, USA

Auburn University, Auburn, AL, USA

DuPont CR&D, Wilmington, DE, USA

Virginia Commonwealth University, Richmond, VA, USA

University of Alberta, Edmonton, Alberta, Canada

The Journal of Supercritical Fluids, 79 (2013) 1

Preface

Phase behavior measurement for poly(isobornyl acrylate) � cosolvent systems in supercritical solvents at high pressure

Dong-Sun Yang, Sang-Ha Cho, Soon-Do Yoon, Hyeon-Ho Jeong, Hun-Soo Byun

Department of Chemical and Biomolecular Engineering, Chonnam National University, Yeosu, Jeonnam 550-749, South Korea


Experimental determination and activity coeffi cient based models for mixture solubilities of nitrophenol isomers in supercritical carbon dioxide

Sivamohan N. Reddy, Giridhar Madras

Department of Chemical Engineering, Indian Institute of Science, Bangalore 560012, India


Thermodynamics, Phase Equilibria, Solubility

iv Contents

SCFs-Ionic Liquids Coupled Media

Separation Processes

High pressure phase equilibria of ethyl esters in supercritical ethane and propane

C.E. Schwarz, C. Schlechter, J.H. Knoetze

Department of Process Engineering, University of Stellenbosch, Private Bag X1, Matieland, South Africa

High-pressure phase equilibrium data for the L-lactic acid � (propane � ethanol) and the L-lactic acid � (carbon dioxide � ethanol) systems

Isabel C.N. Debiena, Aline A. Rigob, Marcio A. Mazuttic, J. Vladimir Oliveirad, M. Angela A. Meirelesa

aDEA/FEA (School of Food Engineering)/UNICAMP, Campinas, 13083-862 SP, Brazil bDepartment of Food Engineering, URI – Erechim Campus, Erechim, RS 99700-000, Brazil cDepartment of Chemical Engineering, UFSM, Santa Maria, RS 97105-900, Brazil dDepartment of Chemical and Food Engineering, UFSC, Florianópolis, SC 88040-900, Brazil


Partition coeffi cients of furan derivative compounds in 1-n-butyl-3-methylimidazolium chloride ([bmim][Cl])–supercritical CO2 biphasic systems and their correlation and prediction with the LSER-� model

Yuya Hiragaa, Atsushi Hayasakaa, Yoshiyuki Satob, Masaru Watanabeb, Richard L. Smith Jr.a,b

aGraduate School of Environmental Studies, Tohoku University, Aramaki Aza Aoba 6-6-11, Aoba-ku, Sendai 980-8579, Japan

bResearch Center of Supercritical Fluid Technology, Tohoku University, Aramaki Aza Aoba 6-6-11, Aoba-ku, Sendai 980-8579, Japan


Adsorption of 2-phenylethyl alcohol on silica aerogel from saturated solution in supercritical CO2

Xiaohui Hua, Shengxuan Zhenga, Linjing Zhua, Ako Rajour Tanyia, Hongqiao Lanb, Yanzhen Honga, Yuzhong Sua, Hongtao Wanga, Jun Lia

aDepartment of Chemical and Biochemical Engineering, College of Chemistry and Chemical Engineering, National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, Xiamen University, Xiamen 361005, PR China

bTechnology Center of China Tobacco Fujian Industry Corporation, Xiamen 361022, PR China



Contents v

Biomass and Energy-Related Conversions

Semi-preparative supercritical chromatography scale plant for polyunsaturated fatty acids purifi cation

Fernando Montañés, Owen J. Catchpole, Stephen Tallon, Kevin Mitchell, Kirill Lagutin

Integrated Bioactive Technologies, Industrial Research Limited, 69 Gracefi eld Road, 5040 Lower Hutt, New Zealand

Liquid and supercritical CO2 extraction of fat from rendered materials

Jose Luis Orellana, Tyler D. Smith, Christopher L. Kitchens

Clemson University, Department of Chemical and Biomolecular Engineering, 206 S. Palmetto Boulevard, Clemson, SC 29634, USA


Fatty acids recovery from vegetable oil wet sludge by supercritical alcoholysis

G. Soto, A. Velez, P. Hegel, G. Mabe, S. Pereda

PLAPIQUI, Universidad Nacional del Sur - CONICET, CC 717, 8000 Bahía Blanca, Argentina


Microwave-mediated non-catalytic transesterifi cation of algal biomass under supercritical ethanol conditions

Prafulla D. Patila, Harvind Reddya, Tapaswy Muppanenia, Sundaravadivelnathan Ponnusamya, Peter Cookeb, Tanner Schuabc, Shuguang Denga

aChemical Engineering Department, New Mexico State University, Las Cruces, NM 88003, USA

bElectron Microscopy Laboratory, New Mexico State University, Las Cruces, NM 88003, USA

cChemical Analysis and Instrumentation Laboratory, New Mexico State University, Las Cruces, NM 88003, USA



vi Contents

Production of feruloylated arabino-oligosaccharides (FA-AOs) from beet fi ber by hydrothermal treatment

Nobuaki Satoa, Yohei Takanoa, Masahiro Mizunoa, Kouichi Nozakia, Shingo Umemuraa, Tsunetomo Matsuzawaa, Yoshihiko Amanoa, Satoshi Makishimaa,b

aDepartment of Chemistry and Material Engineering, Faculty of Engineering, Shinshu University, 4-17-1 Wakasato, Nagano 380-8553, Japan

bB Food Science Co. Ltd., Chiyoda-ku 101-0054, Tokyo, Japan


Natural Products, Nutraceuticals, and Food-Related Materials

Hydrothermal conversion of glucose in multiscale batch processes. Analysis of the gas, liquid and solid residues

Qian Michelle Yu-Wu, Elsa Weiss-Hortala, Radu Barna

Université de Toulouse, Mines Albi, CNRS UMR 5302, Centre RAPSODEE, Campus Jarlard, F-81013 Albi Cedex 09, France


Infl uence of impurities on biodiesel production from Jatropha curcas L. by supercritical methyl acetate process

Noorzalila Muhammad Nizaa, Kok Tat Tanb, Keat Teong Leec, Zainal Ahmadc

aFaculty of Chemical Engineering, UiTM Pulau Pinang, 13500 Permatang Pauh, Pulau Pinang, Malaysia

bDepartment of Petrochemical Engineering, Faculty of Engineering and Green Technology, Universiti Tunku Abdul Rahman, Jalan Universiti, Bandar Barat, 31900 Kampar, Perak, Malaysia

cSchool of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, Seri Ampangan, 14300 Nibong Tebal, Pulau Pinang, Malaysia


High pressure carbon dioxide pasteurization of fresh-cut carrot

Sara Spilimbergoa, Drazenka Komesb, Aleksandra Vojvodicb, Branka Levajb, Giovanna Ferrentinoa

aUniversity of Trento, Department of Industrial Engineering, via Mesiano 77, Trento, Italy

bFaculty of Food Technology and Biotechnology, University of Zagreb, Pierottijeva 6, Zagreb, Croatia


Contents vii

Supercritical rosemary extracts, their antioxidant activity and effect on hepatic tumor progression

Gonzalo Vicentea, Susana Molinab, Margarita González-Vallinasb, Mónica R. García-Riscoa, Tiziana Fornaria, Guillermo Regleroa,b, Ana Ramírez de Molinab

aInstituto de Investigación en Ciencias de la Alimentación (CIAL), CEI UAM�CSIC, C/Nicolás Cabrera 9, Universidad Autónoma de Madrid, 28049 Madrid, Spain

bIMDEA-Food Institute, CEI UAM�CSIC, C/Faraday 7, 28049 Madrid, Spain


Extraction and solubility evaluation of functional seed oil in supercritical carbon dioxide

Karin Tomitaa, Siti Machmudahb, Armando T. Quitaina, Mitsuru Sasakia, Ryuichi Fukuzatoc, Motonobu Gotob

aGraduate School of Science and Technology, Kumamoto University, Kumamoto 860-8555, Japan

bDepartment of Chemical Engineering, Nagoya University, Nagoya 464-8603, Japan

cSCF Techno-Link, Inc., Ashiya 659-0033, Japan


Phase equilibrium engineering of jojoba oil extraction with mixed-CO2 � propane solvent

Pablo Hegel, Guillermo Mabe, Esteban A. Brignole, Selva Pereda

Planta Piloto de Ingeniería Química, PLAPIQUI Universidad Nacional del Sur, CONICET Camino La Carrindanga Km 7, CC 717, 8000 Bahía Blanca, Argentina


Extraction of rotundifuran and casticin from chaste tree fruits by near critical liquid carbon dioxide

Altin Melea, Harro Lentzb, Ardita Melea, Elisabeth Feizlmayrc, Sokol Abazia, Rudolf Bauerc

aUniversity of Tirana, Faculty of Natural Sciences, Department of Chemistry, Bulevardi “Zogu i parë”, Nr. 2, Tirana, Albania

bGro�beeren Stra�e 72, D-10963 Berlin, Germany

cInstitute of Pharmaceutical Science, Karl Franzens University Graz, Universitätsplatz 4, 8010 Graz, Austria


viii Contents

Fundamental mechanisms of cell nucleation in polypropylene foaming with supercritical carbon dioxide—Effects of extensional stresses and crystals

Anson Wonga, Yanting Guob,a, Chul B. Parka

aDepartment of Mechanical and Industrial Engineering, University of Toronto, Ontario, Canada

bNational Engineering Research Center of Novel Equipment for Polymer Processing, South China University of Technology, Guangdong, China


Polymers, Materials Applications, and Processes

Enzymatic synthesis of poly(�-caprolactone) in supercritical carbon dioxide medium by means of a variable-volume view reactor

Sibele R. Comim Rossoa, Emanuel Bianchinb, Débora de Oliveiraa, J. Vladimir Oliveiraa, Sandra R.S. Ferreiraa

aEQA-CTC/UFSC, Chemical and Food Engineering Department, Federal University of Santa Catarina, C.P. 476, CEP 88040-900, Florianópolis, SC, Brazil

bDepartment of Food Engineering, URI – Campus de Erechim, Av. Sete de Setembro, 1621, Erechim, RS 99700-000, Brazil


Kinetic enzymatic resolution in scCO2 – Design of continuous reactor based on batch experiments

E. Székely, M. Utczás, B. Simándi

Department of Chemical and Environmental Process Engineering, Budapest University of Technology and Eco-nomics, H-1111 Budapest, Budafoki út 6-8, Hungary


Reactions in Critical Fluids

Use of supercritical fl uid technology for the production of tailor-made aerogel particles for delivery systems

C.A. García-González, I. Smirnova

Institute of Thermal Separation Processes, Hamburg University of Technology, Eißendorferstraße 38, D-21073 Hamburg, Germany


Contents ix

Lysozyme encapsulation within PLGA and CaCO3 microparticles using supercritical CO2 medium

M.-K. Trana,b, L.N. Hassania,b, B. Calvignaca,b, T. Beuvierc, F. Hindréa,b, F. Bourya,b

aLUNAM Université, Angers, France

bINSERM U1066, Micro et Nanomedécines Biomimétiques, IBS, 4 rue Larrey, F-49933 Angers Cedex 9, France

cUniversité du Maine, CNRS UMR 6087-Laboratoire de Physique de l’Etat Condensé, 72085 Le Mans Cedex 9, France


Fractionation of an oligomeric pyrene pitch via supercritical extraction

David F. Esguerraa, Wesley P. Hoffmanb, Mark C. Thiesa

aDepartment of Chemical and Biomolecular Engineering, Center for Advanced Engineering Fibers and Films, Clemson University, Clemson, SC 29634-0909, USA

bAir Force Research Laboratory, AFRL/RQRC, 10 E. Saturn Blvd., Edwards, CA 93524-7680, USA


Unleashing the potential of supercritical fl uids for polymer processing in tissue engineering and regenerative medicine

Ana Rita C. Duartea,b, Vitor E. Santoa,b, Anabela Alvesa,b, Simone S. Silvaa,b, Joana Moreira-Silvaa,b, Tiago H. Silvaa,b, Alexandra P. Marquesa,b, Rui A. Sousaa,b, Manuela E. Gomesa,b, João F. Manoa,b, Rui L. Reisa,b

a3B’s Research Group – Biomaterials, Biodegradables and Biomimetics, University of Minho, Headquarters of the European Institute of Excellence on Tissue Engineering and Regenerative Medicine, AvePark, 4806-909 Taipas, Guimarães, Portugal

bICVS/3B’s – PT Government Associate Laboratory, Braga, Guimarães, Portugal


Comparison of the physical stability and physicochemical properties of amorphous indomethacin prepared by co-milling and supercritical anti-solvent co-precipitation

Ron Tau Yee Lima,b, Wai Kiong Nga, Effendi Widjajaa, Reginald B.H. Tana,b

aInstitute of Chemical and Engineering Sciences (ICES), Agency for Science Technology and Research (A*STAR), 1, Pesek Road, Jurong Island, Singapore 627833, Singapore

bNational University of Singapore, Department of Chemical & Biomolecular Engineering, 4 Engineering Drive 4, Blk E5 #02-09, Singapore 117576, Singapore


x Contents

Encapsulation of nanoparticles using CO2-expanded liquids

M. Vinjamur, M. Javed, M. Mukhopadhyay

Department of Chemical Engineering, IIT Bombay, Powai, Mumbai 400 076, India


Preparation of multi-membrane alginate aerogels used for drug delivery

Anja Veronovski, Zeljko Knez, Zoran Novak

University of Maribor, Faculty of Chemistry and Chemical Engineering, Smetanova 17, SI-2000 Maribor, Slovenia


Pharmaceutical Applications

Superabsorbent alginate aerogels

Rajendar R. Mallepallya,c, Ian Bernarda, Michael A. Marina, Kevin R. Wardb,d, Mark A. McHugha,c

aDepartment of Chemical and Life Science Engineering, Virginia Commonwealth University, Richmond, VA 23284, USA bDepartment of Emergency Medicine, University of Michigan, Ann Arbor, MI 48109, USA cMaterial Science Division, VCU Reanimation Engineering Science Center, Virginia Commonwealth University Medical Center, Richmond, VA 23298-0614, USA

dMichigan Center for Integrative Research in Critical Care, University of Michigan, Ann Arbor, MI 48109, USA


Modeling of precipitation of ultra-fi ne particles by pressure reduction over CO2-expanded liquids

K. Arjun Kumar, Rajarshi Chattaraj, Umesh Dhumal, Mamata Mukhopadhyay, Madhu Vinjamur, Sameer V. Dalvi

aChemical Engineering, IIT Gandhinagar, Ahmedabad 382 424, India

bChemical Engineering, IIT Bombay, Powai, Mumbai 400 076, India


Contents xi

Hydrothermal Processing

Reverse micelle synthesis of silver nanoparticles in gas expanded liquids

Ashley E. Hart, David B. Akers, Samuel Gorosh, Christopher L. Kitchens

Clemson University, Department of Chemical and Biomolecular Engineering, 206 South Palmetto Boulevard, Clemson, SC 29631, United States


Strontium ruthenium oxide deposition in supercritical carbon dioxide using a closed reactor system

Kyubong Jung, Takeshi Momose, Yukihiro Shimogaki

Department of Materials Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan


Hydrothermal processing and in situ surface modifi cation of metal oxide nanomaterials

K. Namratha, K. Byrappa

Center for Materials Science, University of Mysore, P.B. No. 21, NCHS Bldg., Manasagangothri, Mysore 570006, India


SCF Particle / Film Technology

A theoretical study of factors affecting corrosion in supercritical water reaction vessels

Simon James Halstead

Department of Chemical Engineering, Xi Da Zhi Street, Harbin, Heilong Jiang, China 150001


xii Contents

Supercritical water oxidation—Current status of full-scale commercial activity for waste destruction

Philip A. Marrone

Science Applications International Corporation (SAIC), Newton, MA 02459, USA


Reprint of: Application of subcritical water liquefaction as pretreatment for supercritical water gasifi cation system in domestic waste water treatment plant

Osamu Sawai, Teppei Nunoura, Kazuo Yamamoto

Environmental Science Center, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan


Controlled morphology and size of ZnO nanocrystals using the continuous hot compressed water technique

Zhiqiang Mao, Sining Li, Yuanpeng Leng, Yaping Zhao

School of Chemistry and Chemical Engineering, Shanghai Jiaotong University, 800 Dong Chuan Road, Minhang District, Shanghai 200240, China


The applicability of subcritical fl uids to the conservation of actively corroding iron artifacts of cultural signifi cance

Liisa M.E. Näsänena, Néstor G. González-Pereyraa, Stéphanie A. Crettéa, Philippe DeViviésb

aClemson University Restoration Institute, Warren Lasch Conservation Center, 1250 Supply Street, Bldg 255, North Charleston, SC 29405, USA

bA-CORROS Expertises, 23 Chemin des Moines, 13200 Arles, France


Archeological Applications

Contents xiii

Industrial Applications

Conservation of waterlogged archaeological corks using supercritical CO2 and treatment monitoring using structured-light 3D scanning

Stéphanie A. Cretté, Liisa M. Näsänen, Néstor G. González-Pereyra, Benjamin Rennison

Clemson University Restoration Institute, Warren Lasch Conservation Center, 1250 Supply Street, North Charleston, SC 29405, USA


Application of supercritical carbon dioxide–co-solvent mixtures for removal of organic material from archeological artifacts for radiocarbon datingMarvin W. Rowea, Jenny Phomakayb, Jackson O. Layc, Oscar Guevarad, Keerthi Srinivasb, W. Kirk Hollise, Karen L. Steelmanf, Thomas Guildersong, Thomas W. Stafford Jr.h, Sarah L. Chapmani, Jerry W. Kingb

aTexas A&M University, Doha, QATAR/Conservation Laboratory - Museum of New Mexico, Santa Fe, NM 87505, USA bDepartment of Chemical Engineering, University of Arkansas, Fayetteville, AR 72701, USA cDepartment of Chemistry, University of Arkansas, Fayetteville, AR 72701, USA dDepartment of Biological and Agricultural Engineering, Fayetteville, AR 72701, USA eLos Alamos National Laboratory, Los Alamos, NM 87544, USA fDepartment of Chemistry, University of Central Arkansas, Conway, AR 72035, USA gCenter for AMS, Lawrence Livermore National Laboratory L-397, 7000 East Avenue, Livermore, CA 94551, USA hStafford Research Laboratories, Inc., 200 Acadia Avenue, Lafayette, CO 80026, USA iDepartment of Anthropology, University of Arkansas, Fayetteville, AR 72701, USA


Metal extraction of a spiked solid with supercritical carbon dioxide

Ming-Tsai Lianga, Ru-Chien Lianga, Chih-Hsiung Lina, Ping-Jui Hsua, Li-Yu Wua, Hong-Fa Chena, Yuh-Wern Wua, Wen-Chen Leeb

aDepartment of Chemical Engineering, I-Shou University, Kaohsiung City 84001, Taiwan, ROC

bInstitute of Nuclear Energy Research, Atomic Energy Council, Taoyuan County 32546, Taiwan, ROC


Demonstration of NIR inline monitoring for hops extraction and micronization of benzoic acid in supercritical CO2

D. Böhma, T. Graua, N. Igl-Schmidc, S. Johnsena, E. Kaczowkaa, A. Klotza,b, J. Schulmeyrc, M. Türkb, G. Wieganda, A. Wuzikc, B. Zehnderd

aKarlsruhe Institute of Technology (KIT), Institute of Catalytical Research and Technology (IKFT), P.O.B. 3640, D-76021 Karlsruhe, Germany

bKarlsruhe Institute of Technology (KIT), Institute for Technical Thermodynamics and Refrigeration (ITTK), Kaiserstrasse 12, D-76133 Karlsruhe, Germany

cNATECO2 GmbH & Co. KG, Auenstrasse 18-20, 85283 Wolnzach, Germany

dSITEC-Sieber Engineering AG, Maur b. Zürich, Switzerland


xiv Contents

New considerations in the economic evaluation of supercritical processes: Separation of bioactive compounds from multicomponent mixtures

María P. Fernández-Ronco, Antonio de Lucas, Juan F. Rodríguez, M.T. García, Ignacio Gracia

Departamento de Ingeniería Química, Facultad de C.C. Químicas, Universidad de Castilla-La Man-cha, Avda. Camilo José Cela 12, 13071 Ciudad Real, Spain


Infl uence of pretreatment on supercritical CO2 extraction from Nannochloropsis oculata

Christelle Crampona, Adil Mouahida, Sid-Ali Amine Toudjia, Olivier Lépineb, Elisabeth Badensa

aAix-Marseille Université, M2P2 UMR CNRS 7340, Europole de l’Arbois, BP80, Pavillon Laennec, Hall C, Aix en Provence Cedex 04, FR 13545,

bAlpha Biotech, Le Frostidié, Asserac, FR 44410, France


Process Design and Economics

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