DRINKING WATER CHEMICAL COMPLIANCE MONITORING …...MONITORING TRAINING Presented by the: Safe...

DRINKING WATERCHEMICAL COMPLIANCEMONITORING TRAINING

DRINKING WATERCHEMICAL COMPLIANCEMONITORING TRAINING

Presented by the: Safe Drinking Water BranchHawaii Department of Health

MAY-JUNE 2017MAY-JUNE 2017

TRAINING OBJECTIVES

● Increase water system personnel understanding of drinking water monitoring requirements

. ● Improve the drinking water monitoring p g gsystem through education and training.

● Ensure public water system compliance● Ensure public water system compliance with drinking water monitoring requirementsrequirements.

SAMPLING TRAINING COURSE CHEMICAL COMPLIANCE MONITORING/SAMPLING

May-June 2017 (6 hours)

INTRODUCTION Course Objectives/Goals Course Content Department of Health – Safe Drinking Water Staff/Contact Information/Responsibilities Summary Department of Health – State Laboratories Division Staff Introduction of Participants BACKGROUND INFORMATION Hydrologic Cycle – How Do We Get Water (GW/SW)? Source of Potential Drinking Water Contamination Hawaii Groundwater/Drinking Water Contamination Maps PUBLIC DRINKING WATER SYSTEMS Definition of a Public Water System (PWS) What Are the Types of Public Water Systems? Community Non-Community Non-Transient, Non-Community Transient, Non-Community Consecutive CHEMICAL COMPLIANCE MONITORING REQUIREMENTS Drinking Water Monitoring Rules and Parameters/Analytes Federal Drinking Water Regulations State Drinking Water Regulations Drinking Water Sampling Points Drinking Water Sampling Frequencies (initial, routine, increased/decreased) Standardized Monitoring Framework Distribution System Sampling (D/DBPR, Pb/Cu) THE SAMPLER AND QA/QC IN SAMPLE COLLECTION Water System’s Responsibilities for Monitoring Collecting Quality Samples -- QA and Samplers as Key Components LABORATORY SESSION Use of Certified Laboratories and Approved Analytical Methods List of Approved Methods and Certified Laboratories Invalidation of Sample(s) Collected Analysis Performed by the DOH-SLD Analysis Not Performed by the DOH-SLD

SAMPLES FOR ANALYSIS BY THE STATE LABORATORY Information on SCRS Schedule/Initiate Sampling Find Samples Review State Laboratory Calendar Sampling Instructions/Resources SDWIS Viewer Scheduling Samples on SCRS Chemical Printing Chain of Custody Forms Chemical Obtaining the Necessary Sampling Supplies and Documents Sampling Bottles/Containers, Labels, Blue Ice, and Coolers Sampling Instructions and Chain of Custody Forms COLLECTING SAMPLES FOR ANALYSIS BY THE STATE LABORATORY (SAMPLING) Sample Collection and Handling Sample Documentation SAMPLE PACKING AND TRANSPORT TO THE LABORATORY Packing Samples to Ensure Proper Sample Temperature Transporting Samples to Laboratory to Meet Temperature and Holding Time Requirements TRACKING AND REVIEWING SAMPLING RESULTS (SCRS) Tracking Status of Samples Collected Reviewing Status of Chemical Compliance Monitoring RESPONDING TO POSITIVE RESULT(S) OTHER MONITORING REQUIREMENTS Phase II/V Parameters/Analytes not Analyzed by the DOH Laboratory Determining Phase II/V Sampling Requirements For More Information on Phase II/V Monitoring Requirements Radiological UCMR4 Applicable to all Large Water Systems (>10,000) and selected Medium & Small Systems UCMR3 – (PFOA/PFOS) To be sampled by SDWB and analyzed by DOH Laboratory WRAP-UP SESSION Questions and Answers Training Evaluation

SAFE DRINKING WATER BRANCH STAFF

Here is a current listing of SDWB staff with their primary responsibilities:

Joanna Seto Branch ChiefDoug Nguyen Data Processing System Analyst, SDWISAlan Dillion General Professional (Contracts)

CLERICALMaryHelen Cathcart SecretarySeila Aroni ClericalClaire Brown ClericalAmy Higa ClericalChantyll Westbrook ClericalNorma Polendy Clerical

COMPLIANCEAnn Zane Compliance SupervisorVACANT (General - Administration, Budget/Grants)Zhaohui Wang Consumer Confidence Reports, Phase II/Phase V monitoringJodi Yamami Operator Certification, SDWB Newsletter

ENGINEERINGMichael Miyahira Engineering SupervisorJoan Corrigan DWSRF Michael Cummings DWSRF, Cross-Connection, Groundwater RuleAlain Carey Lead & Copper, Capacity Development, Circuit Rider ProgramJennifer Nikaido Surface Water Treatment Rule, Disinfectant/Disinfection By-Product Rule

GROUNDWATER POLLUTION CONTROL (GWPC) SECTIONNorris Uehara SupervisorJaime Rimando Underground Injection ControlMark Frazier Underground Injection ControlRobert Whittier Source Water

MONITORINGDaniel Chang Monitoring Supervisor, Quality Assurance, Groundwater ProtectionDavid Kawahara Monitoring, SCRS Melvin Tokuda Monitoring, SCRS Steven Matsuda Monitoring, SCRSVACANT Groundwater Protection

NEIGHBOR ISLAND STAFFTheresa McGeehan-Takiue SDWB - East Hawaii

SAFE DRINKING WATER BRANCHCONTACT INFORMATION

The SDWB may be contacted as follows:

OFFICE LOCATIONS

HONOLULU OFFICE HILO OFFICESafe Drinking Water Branch Department of Health919 Ala Moana Boulevard, #308 Environmental Health FacilityHonolulu, Hawaii 96814 1582 Kamehameha Avenue Phone: (808) 586-4258 Hilo, Hawaii 96720Fax: (808) 586-4351 Phone: (808) 933-0401

Fax: (808) 933-0400

TO CONTACT THE HONOLULU OFFICE FROM THE NEIGHBOR ISLANDS

From the Island of: Telephone Number:

KAUAI (Toll-free) 274-3141, x64258

MAUI (Toll-free) 984-2400, x64258

HAWAII (Toll-free) 974-4000, x64258

MOLOKAI/LANAI (Toll-free) (800) 468-4644, x64258

TO CONTACT SAFE DRINKING WATER BRANCH STAFF BY EMAIL

SDWB Staff Email: To contact SDWB staff by email:

[email protected]

General Email: [email protected]

SEE MORE INFORMATION ON THE SAFE DRINKING WATER BRANCH ON THE WEBSITE:

http://www.hawaii.gov/health/environmental/water/sdwb

DEPARTMENT OF HEALTHSTATE LABORATORIES DIVISION

2725 WAIMANO HOME ROADPEARL CITY, HAWAII 96782

ENVIRONMENTAL HEALTH ANALYTICAL SERVICES BRANCH

Administration

Wanda Chang Branch ChiefJoanna Cook Secretary

Drinking Water Chemistry Section

Richard Saiki Section Supervisor

Robert Pineda Chemist QA Officer

Elsie Chun Chemist Inorganics (Metals) (EPA 200.8 , EPA 200.9, EPA 245.1, SM 3111B & SM 3113B)

Vilma Fermin Chemist Inorganics (Anions) (EPA 300.0)Glyphosate (EPA 547)

Vianney Kang Chemist EDB/DBCP/TCP (EPA 504.1) Carbamates (EPA 531.1)

Wendy Oyadomari Chemist VOCs (EPA 502.2)THMs (EPA 502.2)

Beverly Taira Chemist Herbicides (EPA 515.3)HAAs (SM 6251B)

Guomin Yao Chemist SOCs (EPA 508.1)

Groundwater

Salty Water Dike Complex

Sediments

Transition Zone

BACKGROUND

INFORMATION

BACKGROUND

INFORMATION

Table 5-1 PCA INVENTORY LIST

* PCAs associated with (but not necessarily limited to) microbiological contamination FILE:DRY/C:\JOBS\SWAPLAN\TABLE5-2.DOC

The potential for contamination is based on the nature of the activities, contaminants associated with those activities, and past record of groundwater and/or surface water contamination regardless of whether any environmental standards were exceeded. The potential for contamination does not reflect toxicity of the contaminant and should not be utilized as a means of assessing risk. These rankings do not take into account any site-specific practices such as pollution prevention or protection measures such as best management practices (BMPs). PCAs utilizing BMPs that may mitigate potential contamination will be acknowledged in the assessment summary. Very High • RCRA sites • CERCLA sites • Large Quantity Hazardous Waste Generators • RCRA TSD sites • Gas stations • Chemical/petroleum processing/storage • Chemical/petroleum pipeline • Dry cleaners/processing • Metal plating/finishing/fabricating • Plastics/synthetic fabricators • Pesticides/herbicides mixing and loading sites • Airports – maintenance fueling areas • Landfills/dumps/historic dumps • Cesspools – High density >1/acre (VH in Zone A

and B, M in Zone C)* • Wastewater treatment plants (VH in Zone A and

B, otherwise H)* • Underground injection of commercial/industrial

discharges • Injection wells/dry wells/sumps • Military installations • Leaking underground storage tanks • Confined animal feeding facilities (VH in Zone

A, otherwise H) >25 head/acre beef cattle, dairy cattle, pigs, horses, others >200 fowl/acre*

• Pineapple cultivation • Sugar cane cultivation • Feral animals including rats, pigs, goats, and

birds (surface water sources)* • Improperly abandoned wells • Wood treatment facilities • Power plants • Illegal activities/unauthorized dumping • Recorded spills • Other crops using soil fumigants (direct

application into soil)

High • Small Quantity Hazardous Waste

Generators • Auto body shops • Automobile repair shops • Boat services/repair/refinishing • Fleet/trucking/bus terminals • Furniture repair/manufacturing • Junk/scrap/salvage yards • Machine shops • Photo processing/printing • Research laboratories • Sewer lines (H in Zones A and B, M in

Zone C)* • Utility stations/maintenance areas • Wastewater treatment plants (VH in

Zones A and B, otherwise H)* • Confined animal feeding operations (VH

in Zones A and B, otherwise H)* • Pesticide distributors/professional

applicators • Construction or farm machinery

repair/maintenance • Septic systems (H in Zones A and B, M in

Zone C)* • Lagoons/liquid wastes* • Wells- geothermal (production and

injection) • Reclaimed water irrigation (R2 Water)* • Grazing – surface water source* • Underground storage tanks (non-

regulated, not yet upgraded or registered) • Cultivated agricultural land (crops not

using fumigants) • Golf courses • Diversified agriculture (orchards,

silviculture)

Medium • Car washes • Parking lots/malls (>50 spaces) • Cement/concrete plants • Food processing* • Funeral services/graveyards • Hardware/lumber/parts stores • Residential parcels • Sewer lines (H, in Zones A and B,

otherwise M)* • Motor pools • Parks • Waste transfer /recycling stations • Sewage sludge (biosolids) land

applications* • Reclaimed wastewater irrigation (R1

Water)* • Above ground storage tanks • Wells – improperly maintained

water supply, monitoring, and test holes

• Contractor or government agency equipment storage yards

• Transportation corridors (freeways, state highways, road right-of-ways)

• Hospitals • Storm drain discharge points • Storm water detention facilities • Storm water drainage - dry wells • Artificial recharge projects (non-

potable water) • Schools (high school and higher) • Campgrounds

Low • Office buildings/complexes • Equipment rental yards • Apartments and condominiums • Fire stations • Schools (pre- up to

intermediate/middle) • Underground storage tanks

(decommissioned-inactive) • Roads/streets • Veterinary offices/clinics • Medical/dental clinics • Storm drains (concrete lined)

3

4 10

Kunia

Nui

Hickam

38

57

21

25

26

6

12

2027

31

4544

13

22

9

8

30

17

11

16

50

48

51 47

15

49

43

42

40

36

24

39

46

18

37

1921

3533

34

41

32

14

2329 28

Ewa

Laìe

AieaMaìli

Heèia

Waimea

Makaha

Kawela

Kalihi

Kailua

Kahuku

Kahana

Kahala

Kaààwa

Hauùla

Waikiki

Waikane

Waiànae

Waialua

Waialeè

Waiàlae

Wahiawa

LanikaiKaneòhe

Kahaluù

Haleìwa

Waiàhole

Hawaiì Kai

Nanakuli

Mokuleìa

Honolulu

Waimanalo

Ewa Beach

Sunset Beach

Pacific Palisades

ISLAND OF OÀHU2005 GROUNDWATER CONTAMINATION

0 3 6 9 121.5Miles

Hawaiì State Department of HealthJuly 2006

Legend

Current Information

Historical Monitoring Data

Major Roads

13

11

15 13

12

17

18

2423

2022

32

21

14

31 302928

27

25

1916

10

98

7

6

54

3

2 1

26

Hilo

Hawi

Puako

Pahoa

Keaàu

Kalapana

Haina

Haèna

Waipiò

Waikui

Waihou

Waimea

Pahala

Makapala

Ninole

Laupahoehoe

Kiholo

KehenaKealia

Kapoho

Kalaòa

Kailua

Honomu

Volcano

Paàuillo

Naàlehu

Miloliì

Òòkala

Kahaluù

Hoòkena

Hakalau

Waiohinu

Piìhonua

Mahukona

Keawaiki

Kawaihae

Honaunau

Honomakaù

Honokohau

Kurtistown

Captain Cook

Mountain View

ISLAND OF HAWAIÌ2005 GROUNDWATER CONTAMINATION

0 6 12 18 243Miles


Legend

Current Information


Major Roads

Current Spring Information

Historical Spring Monitoring Data

17

20 21

1918

16

1514

13 1211

10

9 8

6

75

43

2

1

Mala

Kuàu

HanaKihei

Kaupo

Kakio

HueloHaìku

Wailua

Waiheè

Waièhu

Makena

Keànae

Kailua

Kahana

Wailuku

Waikapu

Waiàkoa

Ulumalu

Pauwela

Olowalu

Makawao

Maàlaea

Honolua

Kipahulu

Kahakuloa

Kaànapali

Ùlupalakua

Paìa

Launiupoko

Kaupakulua

Lahaina

Honokahau

0 3 6 9 121.5Miles


Legend

Current Information


Major Roads

ISLAND OF MAUI2005 GROUNDWATER CONTAMINATION

78

6

54

3

2

1

Puhi

Mana

Poìpu

Lihuè

LawaìKoloa

Kapaà

Waimea

Wailua

Kekaha

Kealia

Èleèle

Kilauea

Kalaheo

Hanalei

Anahola

Waipouli

Hanapepe

Kalihiwai

Hanamaulu

Port Allen

0 3 6 9 121.5Miles


Legend

Current Information


Major Roads

ISLAND OF KAUAÌ2005 GROUNDWATER CONTAMINATION

TYPES OF PUBLIC WATER SYSTEMS

A public water system has 15 or more service connections or regularly serves at least 25 people 60 or more days a year. A system that serves water 60 or more days a year is considered to “regularly serve” water. Public water systems can be publicly or privately owned. Public water systems can be subdivided by regulations into two major categories: community and non-community water systems. This division is based on the type of consumer served and the frequency the consumer uses the water. Basically, a community system serves water to a residential population, whereas a non-community system served water to a non-residential population. The non-community category is further broken down into two categories: non-transient non-community water systems and transient non-community water systems.

1

Community Water System

15 SERVICECONNECTIONS

OR

25 PERSONS

FOR

YEAR-ROUND (365 days)

HOMES APARTMENT’ MULTI-FAMILY CONDOMINIUMS HOUSING COMPLEX

A public water system that pipes water for human consumption to at least 15 service connections used by year-round residents, or one that regularly serves at least 25 year-round residents (e.g., municipality, subdivision, mobile home park).

Community Water SystemsMunicipal systems and public water utiitiesMobile home parksCondominiumResidential institutions and schools (including hospitals, nursing homes, colleges, homes for the aged, …)Housing developments (public and proivate)Multi-family housing complexes

Non-Community Water System

15 SERVICECONNECTIONS

OR

25 PERSONS

FOR

60 DAYS/YEAR

CHURCHES SCHOOL GAS STATION/ STORE/REST STOP

A public water system that pipes water for human consumption to at least 15 service connections used by individuals other than year-round residents for at least 60 days a year (e.g., school, factories, rest stops)

NON-TRANSIENT NON-COMMUNITY WATER SYSTEM:A non-community water system that serves at least 25 of the same persons over six months per year (e.g., schools, factories, industrial parks, office buildings).

TRANSIENT NON-COMMUNITY WATER SYSTEM:A non-community water system that does not meet the definition of a non-transient non-community water system (e.g., highway rest stops, restaurants, motels, golf courses, parks).

Hotels-Motels-Resort areas Restaurants-Food Service EstablishmentsSchools (non-residents) MarinasCampgrounds Gasoline Service StationsAirports Shopping Centers/MallsParks and Recreation Areas Office and Commercial BuildingsChurches Public Buildings/Public Assembly facilitiesHighway Rest Areas Medical Care Facilities

Consecutive Water System

CuCuPb

Pb

CuCuPb

Pb

APARTMENTWATER SYSTEM

SCHOOLWATER SYSTEM

Exists when one public water system (PWS) supplies water to one or more other public water systems (PWSs). This type of water system must either be a Community Water System, Non-Transient Non-Community, or a Transient Non-Community Water System.

Number of People Served

Very Small water system: 25-500 peopleSmall water system: 501-3,300 peopleMedium water system: 3,301-10,000 peopleLarge water system: 10,001-100,000 peopleVery Large water system: 100,001+ people

Contact the Safe Drinking Water Branch if you are note sure what category you are in. The public notification regulations apply based on whether you are a community, non-transient non-community or a transient non-community water system.

WHEN IN DOUBT, ASK!!!

COMPLIANCEMONITORING

REQUIREMENTS

40 CFR 141

Chapter 20

SAFE DRINKING WATER ACT

1974

amended 1986 1996

1

MONITORING REQUIREMENTS

FEDERAL: 40 CFR 141

STATE: CHAPTER 20

Plus: EPA FactSheets

MONITORING REQUIREMENTS

LIST OF CONTAMINANTS TO BE ANALYZED FOR NEW SOURCES

LIST OF MCL for REGULATEDLIST OF MCL for REGULATED CONTAMINANTS

The SDWB reserves the right to require additional testing for specific contaminants due to potential contaminating activities near the source or due to past history of contamination of the source or nearby sources.

CONTAMINANTS TO BE TESTED PRIOR TO REACTIVATING SOURCES OF DRINKING WATER Water systems shall provide Safe Drinking Water Branch with water quality results for all of the below contaminants taken within the last five (5) years. The water quality results may include compliance monitoring taken at the entry-point-to-distribution system or at the wellhead or special sampling at the wellhead prior to any treatment.

MICROBIOLOGICAL* SYNTHETIC ORGANIC CHEMICALS Total Coliform 1,2-Dibromo-3-Chloropropane (DBCP) E. Coli Ethylene Dibromide (EDB) 1,2,3-Trichloropropane (TCP) WATER QUALITY PARAMETERS* 2,4,5-TP Chlorine residual 2,4-D Alachlor (Lasso) INORGANIC CHEMICALS Atrazine Antimony Benzo(a)pyrene Arsenic Carbofuran Asbestos Chlordane Barium Dalapon Beryllium Di(2-ethylhexyl)adipate Cadmium Di(2-ethylhexyl)phthalate Chromium Dieldrin Copper Dinoseb Cyanide Dioxin (2,3,7,8-TCDD) Fluoride Diquat Lead Endothall Mercury Endrin Nickel Gamma-BHC (Lindane) Nitrate (as N) Glyphosate Nitrite (as N) Heptachlor Selenium Heptachlor Epoxide Thallium Hexachlorobenzene Hexachlorocyclopentadiene VOLATILE ORGANIC CHEMICALS Methoxychlor 1,1,1-Trichloroethane (TCA) Oxamyl (Vydate) 1,1,2-Trichloroethane Pentachlorophenol 1,1-Dichloroethylene Picloram 1,2,4-Trichlorobenzene Polychlorinated biphenyls (PCBs) 1,2-Dichloroethane (EDC) Simazine 1,2-Dichloropropane (DCP) Toxaphene Benzene Carbon Tetrachloride (CTC) RADIONUCLIDES Chlorobenzene Gross alpha particle activity Cis-1,2-Dichloroethylene Gross beta particle activity Dichloromethane Radium 226 Ethylbenzene Radium 228 o-Dichlorobenzene Uranium p-Dichlorobenzene Styrene * Microbiological samples shall be taken after all well

rehabilitation is completed, regardless of the five (5) year timeline. The chlorine residual must be taken at the same time as the Microbiological sample and shall be not detected. Microbiological data without non-detect chlorine residual will be considered invalid.

Tetrachloroethylene Toulene Trans-1,2-Dichloroethylene Trichloroethylene (TCE) Vinyl Chloride Xylenes (total)

MCL fact 2014-07-10.xls

CONTAMINANTS REGULATED BY THE SAFE DRINKING WATER BRANCH (updated 7/10/14)

MICROBIOLOGICAL CONTAMINANT MCL, (mg/l)Total Coliform Bacteria: ORGANIC CHEMICALS - 40 or more samples per month: Volatile Organic Chemicals No more than 5.0% of the samples may be total Benzene 0.005 coliform positive Carbon Tetrachloride 0.005 - Less than 40 samples/month: Chlorobenzene 0.1 No more than 1 sample/month may be total coliform o-Dichlorobenzene 0.6 positive. para-Dichlorobenzene 0.075

1,2-Dichloroethane 0.005E. coli or Fecal Coliform Bacteria: 1,1-Dichloroethylene 0.007An acute violation occurs when: cis-1,2-Dichloroethylene 0.07 - A total coliform positive routine is followed by an E. coli trans-1,2-Dichloroethylene 0.1 or fecal coliform positive repeat, OR DCP (1,2-Dichloropropane) 0.005 - An E. coli or fecal coliform positive routine is followed by Ethylbenzene 0.7 a total coliform positive repeat. Styrene 0.1

Tetrachloroethylene 0.005CONTAMINANT MCL (mg/l) Toluene 1INORGANIC CHEMICALS 1,1,1-Trichloroethane 0.2 Arsenic 0.01 Trichloroethylene 0.005Asbestos 7 million fibers per liter TCP (1,2,3-Trichloropropane) 0.0006 (longer than 10 µm) Vinyl Chloride 0.002 Barium 2 Xylenes (total) 10 Cadmium 0.005 Dichloromethane 0.005Chromium 0.1 1,2,4-Trichlorobenzene 0.07 Copper (Action Level) 1.3 1,1,2-Trichloroethane 0.005Lead (Action Level) 0.015 Synthetic Organic ChemicalsMercury 0.002 Alachlor 0.002Nitrate (as Nitrogen) 10 Atrazine 0.003Nitrite (as Nitrogen) 1 Carbofuran 0.04 Total Nitrate & Nitrite (as Nitrogen) 10 Chlordane 0.002Selenium 0.05 DBCP (Dibromochloropropane) 0.00004Antimony 0.006 2,4-D 0.07 Beryllium 0.004 EDB (Ethylene Dibromide) 0.00004Cyanide (as free Cyanide) 0.2 Heptachlor 0.0004 Thallium 0.002 Heptachlor Epoxide 0.0002Fluoride 4.0 Lindane 0.0002

Methoxychlor 0.04 DISINFECTION BYPRODUCTS Polychlorinated biphenyls (PCB) 0.0005Total trihalomethanes (TTHM) (sum of chloroform, 0.080 Pentachlorophenol 0.001 bromoform, bromodichloromethane, and Toxaphene 0.003 dibromochloromethane). 2,4,5-TP (Silvex) 0.05

Benzo(a)pyrene 0.0002Total Haloacetic acids (five) (HAA5) (sum of mono-, 0.060 Dalapon 0.2 di-, trichloroacetic acids and mono- and Di(2-ethylhexyl) adipate 0.4 dibromoacetic acids). Di(2-ethylhexyl) phthalate 0.006

Dinoseb 0.007Bromate 0.010 Diquat 0.02 Chlorite 1.0 Endothall 0.1

Endrin 0.002RADIONUCLIDES Glyphosate 0.7 (applies to all community water systems) Hexachlorobenzene 0.001 Gross alpha particle 15 pCi/l Hexachlorocyclopentadiene 0.05 Combined radium 226/228 5 pCi/l Oxamyl (Vydate) 0.2 Uranium 30 µg/L Picloram 0.5 Beta particle and photon radioactivity 4 mrem/yr Simazine 0.004 (applies only to water systems designated as 2,3,7,8-TCDD (Dioxin) 3 X 10 -8

vulnerable by the state) Unregulated Contaminant MRL, (mg/l)Dieldrin 0.00001

CONTAMINANTS TO BE TESTED WITH INITIAL QUARTERLY MONITORING (IQM) FOR NEW SOURCES

Effective 1/1/10revised 7/1/14

Contaminants to be Tested with IQM 2014.xlsx

These monitoring requirements pertain to a NEW source that has been approved through new source monitoring, and has been activated.

INORGANIC CHEMICALS (1 sample) Synthetic Organic ChemicalsContam Contaminant 2931 1,2-Dibromo-3-Chloropropane (DBCP)code 2946 Ethylene Dibromide (EDB)1074 Antimony 2414 1,2,3-Trichloropropane (TCP)1005 Arsenic 2110 2,4,5-TP1094 Asbestos a 2105 2,4-D1010 Barium 2051 Alachlor (Lasso)1075 Beryllium 2050 Atrazine1015 Cadmium 2306 Benzo(a)pyrene1020 Chromium 2046 Carbofuran1022 Copper 2959 Chlordane1024 Cyanide 2031 Dalapon1025 Fluoride 2035 Di(2-ethylhexyl)adipate1030 Lead 2039 Di(2-ethylhexyl)phthalate1035 Mercury 2070 Dieldrin1036 Nickel 2041 Dinoseb1040 Nitrate (as N) 2063 Dioxin (2,3,7,8-TCDD)1041 Nitrite (as N) 2032 Diquat1045 Selenium 2033 Endothall1085 Thallium 2005 Endrin

a One sample must be collected in the distribution system, 2010 Gamma-BHC (Lindane) at a tap served by asbestos-cement pipe. 2034 Glyphosate

2065 Heptachlor2067 Heptachlor Epoxide

ORGANIC CHEMICALS (2 consecutive quarterly samples) 2274 Hexachlorobenzene2042 Hexachlorocyclopentadiene

Volatile Organic Chemicals 2015 Methoxychlor2036 Oxamyl (Vydate)

2981 1,1,1-Trichloroethane (TCA) 2326 Pentachlorophenol2985 1,1,2-Trichloroethane 2040 Picloram2977 1,1-Dichloroethylene 2383 Polychlorinated biphenyls (PCBs)2378 1,2,4-Trichlorobenzene 2037 Simazine2980 1,2-Dichloroethane (EDC) 2020 Toxaphene2983 1,2-Dichloropropane (DCP)2990 Benzene RADIONUCLIDES (4 consec. quarterly samples)2982 Carbon Tetrachloride (CTC) 4109 Gross alpha particle activity2989 Chlorobenzene 4100 Gross beta particle activity2380 cis-1,2-Dichloroethylene 4020 Radium 2262964 Dichloromethane 4030 Radium 2282992 Ethylbenzene 4006 Uranium2968 o-Dichlorobenzene Notes:2969 p-Dichlorobenzene -Unless otherwise stated, samples must be collected2996 Styrene at the entry-point-to the distribution system, after source2987 Tetrachloroethylene treatment.2991 Toulene - All analyses must be performed by a lab certified or2979 trans-1,2-Dichloroethylene approved by the Hawaii Department of Health, State 2984 Trichloroethylene (TCE) Laboratories Division.2976 Vinyl Chloride -All analyses must be performed using EPA approved 2955 Xylenes (total) methods for drinking water analysis. The EPA method

& detection levels must be clearly stated for each contaminant tested.

April 24, 2014 1

CONTAMINANTS TO BE TESTED IN ALL NEW SOURCES OF DRINKING WATER (Based on Chapter 11-20, effective November 28, 2011 and Code of Federal Regulations Title 40, Part 141 of July 1, 2011, the Phase I and Phase II Rule effective January 1, 1993, and the Phase V Rule effective January 17, 1994)

MICROBIOLOGICAL Total Coliform Fecal Coliform (MPN) or E. Coli Microscopic Particulate Analysis (surface water sources, springs, shafts, tunnels, and wells with less than 50 feet of solid grouting - by EPA Consensus Method, EPA 910/0-92-029, October 1992)

WATER QUALITY PARAMETERS

Alkalinity Calcium Chlorine residual Conductivity pH (field measurement) Temperature (field measurement) Turbidity

INORGANIC CHEMICALS

Antimony Arsenic Asbestos Barium Beryllium Cadmium Chromium Copper Cyanide Fluoride Lead Mercury Nickel Nitrate (as nitrogen) Nitrite (as nitrogen) Selenium Thallium

ORGANIC CHEMICALS Volatile Organic Chemicals

Benzene Carbon Tetrachloride Chlorobenzene o-Dichlorobenzene p-Dichlorobenzene 1,2-Dichloroethane 1,1-Dichloroethylene cis-1,2-Dichloroethylene trans-1,2-Dichloroethylene Dichloromethane 1,2-Dichloropropane (DCP) Ethylbenzene

Volatile Organic Chemicals (cont.) Styrene

Tetrachloroethylene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane 1,2,4-Trichlorobenzene Trichloroethylene Vinyl Chloride Xylenes (total)

Synthetic Organic Chemicals

2,4-D Alachlor Aldicarb Aldicarb Sulfone Aldicarb Sulfoxide Atrazine Benzo(a)Pyrene Carbofuran Chlordane Dalapon Dibromochloropropane (DBCP) Di(2-ethylhexyl)adipate Di(2-ethylhexyl)phthalate Dinoseb Diquat Dioxin (2,3,7,8-TCDD) Endothall Endrin Ethylene Dibromide (EDB) Glyphosate Heptachlor Heptachlor epoxide Hexachlorobenzene Hexachlorocyclopentadiene Lindane Methoxychlor Oxamyl (Vydate) Pentachlorophenol Picloram Polychlorinated biphenyls (PCBs) 2,4,5-TP (Silvex) Simazine Toxaphene 1,2,3-Trichloropropane (TCP)

RADIONUCLIDES

Beta/photon emitters Gross alpha particle Combined radium 226/228 Uranium

2

NOTES: (1) With the exception of turbidity and water quality parameters, all analyses must be performed by a

laboratory certified or approved by the Hawaii Department of Health, State Laboratories Division. However, turbidity and water quality parameters must be done using EPA approved methods.

(2) Please consult with the Safe Drinking Water Branch for acceptable laboratories to perform Microscopic Particulate Analysis.

(3) All laboratory reports must be submitted to allow the Department of Health to verify that the analyses were performed by an approved laboratory, using EPA approved methods for drinking water analysis. The EPA method and detection levels must be clearly stated for each chemical contaminant tested.

The Director of Health may require additional analyses whenever appropriate to evaluate the new source.

SURFACE WATER AND GROUNDWATER UNDER THE DIRECT INFLUENCE OF SURFACE WATER (GWUDI) SOURCES ONLY: The following additional water quality parameters may be required by the State at its discretion:

• Wet and dry weather Microscopic Particulate Analyses (MPA) using Consensus Method for

Determining Groundwaters Under the Direct Influence of Surface Water Using Microscopic Particulate Analysis (MPA), EPA 910/9 29-029 EPA (October 1992)

• MPA analyses shall be accompanied by a particle sizing analysis (down to 2 um) with the tabular

results segregated by size in bins reflective of Cryptosporidium and Giardia sized particles, as well as those particles smaller and larger in size, e.g. <2 um, 2-5 um, 5-15 um, 15-30 um, 30-50 um, 50-100 um, >100 um.

• Total Suspended Solids (TSS) • Color (True and Apparent) • Total Organic Carbon (TOC) • Dissolved Organic Carbon (DOC) fraction • Total Trihalomethane Formation Potential (TTHM FP) • Five Haloacetic Acid Formation Potential (HAA5 FP)

The State reserves the right to require pilot testing of all alternative filtration technologies, applicable under HAR 11-20-46(c)(2)(D), on all surface water or GWUDI sources proposed for use in a regulated public water system. Water quality parameters not listed here may be added to the pilot testing protocol at State discretion.

2

Sampling Points

• Every sample must be linked to a sampling point

• Sampling points are linked to a specific water system facility (e.g. treatment plant, well distribution system)well, distribution system)

• Generic sampling points can be used for TCR

Sampling Points

Sampling Point Type Applicable RulesDistribution System TCR L&C TTHMs Residual Disinfectant

Entry Point Chemicals Radionuclides

First Consumer DBP (Chlorite/Chlorine Dioxide)

Lowest Disinfectant Residual SWTR IESWTR MRDLs

Midpoint in Distr. System Old TTHMs

Point of Maximum Retention Old and New TTHMs

Raw Water Source SWTR IESWTR Presursor Monitoring DBP

3

Sampling Points

Raw Water SourceStage 1 DBP

Alkalinity

TOC

Bromide

LT2LT2

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eColi

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Turbidity

Stage 1 DBP

TOC

4

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IOC

VOC

SOC

Nitrate

Nitrite

Radionuclides

Stage 1 DBP

CLO2

Chlorite

Bromate

IESWTR, LT1, LT2

Residual Disinfectant

1st Consumer in DSStage 1 DBP

Chlorite

5

Distribution System (General)

TCR

L&C

Asbestos

IESWTR, LT1, LT2

Chlorine

Chloramine

Point of AveragePoint of Average Residence TimeStage 1 DBP

TTHM

HAA5

Chlorite

6

Point of Maximum Residence TimeStage 1 DBP

TTHM

HAA5HAA5

Chlorite

The Standardized Monitoring Framework:A Quick Reference Guide

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See 40 CFR 141.23 regardingIOCs; 40 CFR 141.24regarding VOCs and SOCs;and 40 CFR 141.26 regardingRadionuclides.

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02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19

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STANDARDIZED MONITORING FRAMEWORK

1Until January 22, 2006 the maximum contaminant level (MCL) for arsenic is 50 µg/L; on January 23, 2006 the MCL for arsenic becomes 10 µg/L.2Based on 3 rounds of monitoring at each EPTDS with all analytical results below the MCL. Waivers are not permitted under the current arsenicrequirements, however systems are eligible for arsenic waivers after January 23, 2006.3A system with a sampling point result above the MCL must collect quarterly samples, at that sampling point, until the system is determined by theprimacy agency to be reliably and consistently below the MCL.4Samples must be taken during the quarter which previously resulted in the highest analytical result. Systems can apply for a waiver after 3consecutive annual sampling results are below the detection limit.5Groundwater systems must update their vulnerability assessments during the time the waiver is effective. Primacy agencies must re-confirm thatthe system is non-vulnerable within 3 years of the initial determination or the system must return to annual sampling.6If all monitoring results during initial quarterly monitoring are less than the detection limit, the system can take annual samples. If after a minimumof 3 years of annual sampling with all analytical results less than the detection limit, the primacy agency can allow a system to take 1 sampleduring each compliance period. Systems are also eligible for a waiver.7Primacy agencies must determine that a surface water system is non-vulnerable based on a vulnerability assessment during each complianceperiod or the system must return to annual sampling.8If all monitoring results during initial quarterly monitoring are less than the detection limit, the system can take annual samples. Systems are alsoeligible for a waiver.9Samples must be taken during the quarter which previously resulted in the highest analytical result.10Systems are required to monitor for asbestos during the first 3-year compliance period of each 9-year compliance cycle. A system vulnerable toasbestos contamination due solely to corrosion of asbestos-cement pipe must take 1 sample at a tap served by that pipe. A system vulnerable toasbestos contamination at the source must sample at each EPTDS.

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02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19

02 03 04 05 06 07 08 09 10 11 12 13 14 15 16 17 18 19

2002

2003

2004

2005

2006

2007

2008

2009

2010

2011

2012

2013

2014

2015

2016

2017

2018

2019

EXCEPTIONS

5/4/2017

1

D/DBPRSAMPLING

D/DBPR

SDWB STAFF CONTACT:

Jennifer Nikaido(808) [email protected]

See Table 2.

Regulated under Stage 1 DBPR1

Regulated under Stage 1 DBPR



Comprehensive Disinfectants and Disinfection Byproducts Rules (Stage 1 and Stage 2): Quick Reference GuideOverview of the RulesTitles* ►

►

Stage 1 Disinfectants and Disinfection Byproducts Rule (Stage 1 DBPR) 63 FR 69390, December 16, 1998, Vol. 63, No. 241Stage 2 Disinfectants and Disinfection Byproducts Rule (Stage 2 DBPR) 71 FR 388, January 4, 2006, Vol. 71, No. 2

Purpose Improve public health protection by reducing exposure to disinfection byproducts. Some disinfectants and disinfection byproducts (DBPs) have been shown to cause cancer and reproductive effects in lab animals and suggested bladder cancer and reproductive effects in humans.

General Description

The DBPRs require public water systems (PWSs) to: ► Comply with established maximum contaminant levels (MCLs) and operational evaluation

levels (OELs) for DBPs, and maximum residual disinfection levels (MRDLs) for disinfectant residuals.

► Conduct an initial evaluation of their distribution system. Inaddition,PWSsusingconventionalfiltrationarerequiredtoremovespecificpercentagesoforganic material that may react to form DBPs through the implementation of a treatment technique.

Utilities Covered

The DBPRs apply to all sizes of community water systems (CWSs) and nontransient noncommunity water systems (NTNCWSs) that add a disinfectant other than ultraviolet (UV) light or deliver disinfected water, and transient noncommunity water systems (TNCWSs) that add chlorine dioxide.

*This document provides a summary of federal drinking water requirements; to ensure full compliance, please consult the federal regulations at 40 CFR 141 and any approved state requirements.

1. A new analytical method for bromate was approved with the Stage 2 DBPR.

Overview of RequirementsThis table shows how the requirements for the Stage 2 DBPR build on the existing requirements established in the Stage 1 DBPR. For more information on changes in monitoring requirements, see Table 1.

Stage 1 DBPR

Stage 2 DBPR

For More Info:

Coverage

All CWSs and NTNCWSs that add disinfectant other than UV light and TNCWSs that treat with chlorine dioxide.Consecutive systems that deliver water treated with a disinfectant other than UV light.

TTHM & HAA5 MCL Compliance

MCL compliance is calculated using the running annual average (RAA) of all samples from all monitoring locations across the system. See Table 3

and Table 4.MCL compliance is calculated using the locational RAA (LRAA) for each monitoring location in the distribution system.

Regulated Contaminants & Disinfectants

Contaminants

Total Trihalomethanes (TTHM)

5 Haloacetic Acids (HAA5)

Bromate

Chlorite

Disinfectants

Chlorine/chloramines

Chlorine dioxide

Operational Evaluation

If an operational evaluation level (OEL) is exceeded, systems must evaluate practices and identify DBP mitigation actions.

See Table 5.

10,000 must have at least 25 percent of samples at the location of maximum residence time; the remaining samples must be representative of average residence time.

Table 1. Changes in Monitoring RequirementsStage 1 DBPR Stage 2 DBPR

TTH

M/

HA

A5

Ro

utin

e M

oni

tori

ng Number of Samples Based on source water type, population, and number of treatment plants or wells. Based on source water type and population.

Sample Locations At location of maximum residence time.1 Based on Initial Distribution System Evaluation (IDSE) requirements.2

Compliance Calculation RAA must not exceed the MCL for TTHM or HAA5. LRAA must not exceed the MCL for TTHM or HAA5.

Red

uced

Mo

nito

ring

Eligibility

TTHM/HAA5

All systems need TTHM RAA < 0.040 mg/L and HAA5 < 0.030 mg/L. Subpart H systems also need source water TOC RAA at location prior to treatment < 4.0 mg/L .3, 4

The Stage 2 DBPR left eligibility unchanged but specifiesthatSubpartHsystemsmusttakesourcewater TOC samples every 30 days. Subpart H systems on reduced monitoring must take source water TOC samples every 90 days to qualify for reduced monitoring.

Bromate5Source water bromide RAA < 0.05 mg/L. WiththeStage2DBPRspecifiedentrypointtodistribution system bromate RAA < 0.0025 mg/L.

>1Subpart H systems serving

2All systems are required to satisfy their IDSE requirement by July 10, 2010.3SubpartHsystemsarewatersystemsthatusesurfacewaterorgroundwaterunderthedirectinfluenceofsurfacewater(GWUDI).

< 0.020 mg/L and a HAA5 RAA < 0.015 mg/L for 1 year.4Ground water systems serving < 10,000 must meet these RAA for 2 years; can also qualify for reduced monitoring if the TTHM RAA is

5A new analytical method for bromate was established with the Stage 2 DBPR.

MRDL3 (mg/L) MRDLG3 (mg/L) MRDL (mg/L) MRDLG (mg/L)

Table 2. Regulated Contaminants and DisinfectantsStage 1 DBPR Stage 2 DBPR

Regulated Contaminants MCL (mg/L) MCLG (mg/L) MCL (mg/L) MCLG (mg/L)TTHM 0.080 Unchanged2

Chloroform - 0.07Bromodichloromethane Zero Unchanged2

2

2

Dibromochloromethane 0.06 UnchangedBromoform Zero Unchanged

HAA5 0.060 Unchanged2

Monochloroacetic acid - 0.07Dichloroacetic acid Zero Unchanged2

Trichloroacetic acid 0.3 0.2Bromoacetic acid - -Dibromoacetic acid - -

Bromate (plants that use ozone)1 0.010 Zero Unchanged2

2

Unchanged2

2Chlorite (plants that use chlorine dioxide) 1.0 0.8 Unchanged Unchanged

Regulated DisinfectantsChlorine 4.0 as Cl2

2

4 Unchanged2

2

2

Unchanged2

2

2

Chloramines 4.0 as Cl 4 Unchanged UnchangedChlorine dioxide 0.8 0.8 Unchanged Unchanged1

2

3

A new analytical method for bromate was established with the Stage 2 DBPR.

Stage 2 DBPR did not revise the MCL or MRDL for this contaminant/disinfectant.

Stage 1 DBPR included MRDLs and MRDLGs for disinfectants, which are similar to MCLs and MCLGs.

Table 4. Compliance with MCLs and MRDLs (Routine Monitoring)

Contaminant/Disinfectant

Coverage Stage 1 DBPR Stage 2 DBPR

Source Water Population Monitoring

Frequency

Total Distribution System Monitoring

Locations

Monitoring Frequency1

Total Distribution System Monitoring

Locations

TTHM/HAA5

Subpart H

< 500 Per year2 1 per treatment plant Per year2 2

500 - 3,300

Per quarter

1 per treatment plant

Per quarter

2

4

8

12

16

20

2

4

6

8

3,301 - 9,999

10,000 - 49,000


50,000 - 249,999

250,000 - 999,999

1,000,000 - 4,999,999

> 5,000,000

Ground water

< 500Per year2


Per year2

Per quarter

500 - 9,999

10,000 - 99,999

Per quarter100,000 - 499,999

> 500,000

Bromate3 Systems that use ozone as a disinfectant Monthly 1 at entry point to

distribution system Unchanged4

Chlorite Systems that use chlorine dioxide as a disinfectant

Daily (at entrance to distribution system);monthly (in distribution system)

1 at entry point to distribution system; 3 in distribution system

Unchanged4

4

4

4

Chlorine dixoide Systems that use chlorine dioxide as a disinfectant Daily 1 at entry point to

distribution system Unchanged

Chorine/Chloramines All systems Same location and frequency as Total

Coliform Rule (TCR) sampling Unchanged

DBP precursors (TOC sample set)*

Systems that use conventional filtration Monthly 1 per source water

source Unchanged

1All systems must monitor during the month of highest DBP concentrations. Systems on quarterly monitoring, except Subpart H systems serving 500 - 3,300, must take dual sample sets every 90 days at each monitoring location. Systems on annual monitoring and Subpart H systems serving 500 - 3,300 are required to take individual TTHM and HAA5 samples (instead of a dual sample set) at the locations with the highest TTHM and HAA5 concentrations, respectively. If monitoring annually, only one location with a dual sample set per monitoring period is needed if the highest TTHM and HAA5 concentrations occur at the same location and in the same month.2Ground water systems serving < 10,000 and Subpart H systems serving < 500 must increase monitoring to quarterly if an MCL is exceeded.3A new analytical method for bromate was established with the Stage 2 DBPR.4Stage 2 DBPR did not revise the monitoring frequency or location requirements for this contaminant/disinfectant.

1

2

*

Table 3. Compliance DeterminationStage 1 DBPR Stage 2 DBPR

TTHM/HAA5 RAA LRAA

Bromate1 RAA Unchanged2

2

2

2

Chlorite Daily/follow-up monitoring UnchangedChorine dioxide Daily/follow-up monitoring UnchangedChlorine/chloramines RAA UnchangedDBP precursors (TOC sample set)* Monthly for TOC and alkalinity Every 30 days for TOC and alkalinity

A new analytical method for bromate was established with the Stage 2 DBPR.Stage 2 DBPR did not change the compliance requirements for this contaminant/disinfectant.TOC sample set is comprised of source water alkalinity, source water TOC, and treated TOC.

*TOC sample set is comprised of source water alkalinity, source water TOC, and treated TOC.

http://water.epa.gov/drink August 2010EPA 816-F-10-080OfficeofWater(4606M)

For additional information on the DBPRs:

Call the Safe Drinking Water Hotline at 1-800-426-4791; visit the EPA web site at http://water.epa.gov/drink; or contact your state drinking water representative.

Table 5. Operational Evaluation Levels (OELs)Applies to: All systems subject to Stage 2 DBPR monitoring requirements that conduct compliance

monitoring and collect samples quarterly.Purpose of establishing OELs: To reduce peaks in DBP levels and exposure to high DBP levels.

OEL calculations: Calculated for both TTHMs and HAA5s at each monitoring location using Stage 2 ►DBPR compliance monitoring results. OEL is determined by the sum of the two previous quarter’s TTHM or HAA5 result ►

►plus twice the current quarter’s TTHM or HAA5 result at that location, divided by four. OEL = (Q1 + Q2 + 2Q3) / 4

OELs are exceeded: During any quarter in which the OEL is greater than the TTHM or HAA5 MCL.If an OEL is exceeded, a system must:

Conduct an operational evaluation.►►

►

Submit a written report of the evaluation to the state no later than 90 days after being notifiedoftheanalyticalresultsthatcausedtheexceedance(s).Keep a copy of the operational evaluation report and make it publically available upon request.

The operational evaluation must include:

An examination of the treatment and distribution systems’ operational practices that ►may contribute to TTHM and HAA5 formation.Steps to minimize future exceedances.►

OEL requirements take effect: When the system begins compliance monitoring for the Stage 2 DBPR.

Table 6. Standard Monitoring Compliance Dates

If You are a System Serving: Schedule1 Begin LRAA TTHM & HAA5 Monitoring By:

At least 100,000 people or part of a combined distribution system (CDS) serving at least 100,000 people.

1

2

3

4

April 1, 2012

50,000 to 99,999 people or part of a CDS serving 50,000 to 99,999 people. October 1, 2012

10,000 to 49,999 people or part of a CDS serving 10,000 to 49,999 people. October 1, 2013

Less than 10,000 people or part of a CDS serving less than 10,000 people. October 1, 20132

1Your schedule is determined by the largest system in your CDS.2Systems not conducting Cryptosporidium monitoring under Long Term 2 Enhanced Surface Water Treatment Rule (LT2ESWTR) must begin LRAA TTHM/HAA5 monitoring by this date. Systems conducting Cryptosporidium monitoring under LT2ESWTR must begin LRAA TTHM/HAA5 monitoring by October 1, 2014.

Table 7. TOC RemovalSubpart H systems that use conventional filtration treatment are required to remove specific percentages of organic materials, measured as total organic carbon (TOC), that may react with disinfectants to form DBPs. Removal must be achieved through a treatment technique (enhanced coagulation or enhanced softening) unless a system meets alternative criteria. Systems practicing softening must meet TOC removal requirements for source water alkalinity greater than 120 mg/L CaC03.

Source Water TOC (mg/L)

Source Water Alkalinity, mg/L as CaCO3

0 - 60 > 60 to 120 > 120> 2.0 to 4.0 35.0% 25.0% 15.0%

> 4.0 to 8.0 45.0% 35.0% 25.0%> 8.0 50.0% 40.0% 30.0%

http://water.epa.gov/drink



5/4/2017

1

LEAD and COPPERSAMPLING

LEAD and COPPER

SDWB STAFF CONTACT:

Alain Carey(808) [email protected]

1This document provides a summary of federal drinking water requirements; to ensure full compliance, please consult the federal regulations at 40 CFR 141 and any approved state requirements.2 The June 1991 LCR was revised with the following Technical Amendments: 56 FR 32112, July 15, 1991; 57 FR 28785, June 29, 1992; 59 FR 33860, June 30, 1994.

It was subsequently revised by: the LCR Minor Revisions, 65 FR 1950, January 12, 2000; and the LCR Short-Term Revisions, 72 FR 57782, October 10, 2007.

Lead and Copper Rule: A Quick Reference Guide

Public Health Benefits Implementation ► Reduction in risk of exposure to Pb that can cause damage to brain, red blood cells, and kidneys,

of the LCR has especially for young children and pregnant women. resulted in ► Reduction in risk of exposure to Cu that can cause stomach and intestinal distress, liver or kidney damage, and complications of Wilson’s disease in genetically predisposed people.

Major Monitoring ProvisionsLead and Copper TapApplicability All CWSs and NTNCWSs. ►

Standard CWSs and NTNCWSs must collect first-draw samples at taps in homes/buildings that are at high risk of ►Pb/Cu contamination as identified in 40 CFR 141.86(a). Number of samples is based on system size (see Table 1). ►Systems must conduct monitoring every 6 months unless they qualify for reduced monitoring. ►

Reduced See Table 1 for sample number and Table 2 for criteria. ►

Water Quality Parameter (WQP)Applicability Systems serving > 50,000 people. ►

Systems serving ≤ 50,000 during monitoring periods in which either AL is exceeded. ►

Standard WQP samples at taps are collected every 6 months. ►WQPs at entry points to distribution system (EPTDS) are collected every 6 months prior to CCT ►installation, then every 2 weeks.

Reduced See Table 1 for sample number and page 2 for criteria. Does not apply to EPTDS WQP monitoring. ►

Overview of the RuleTitle1 Lead and Copper Rule (LCR)2, 56 FR 26460 - 26564, June 7, 1991

Purpose Protect public health by minimizing lead (Pb) and copper (Cu) levels in drinking water, primarily by reducing water corrosivity. Pb and Cu enter drinking water mainly from corrosion of Pb and Cu containing plumbing materials.

General Description

Establishes action level (AL) of 0.015 mg/L for Pb and 1.3 mg/L for Cu based on 90th percentile level of tap water samples. An AL exceedance is not a violation but can trigger other requirements that include water quality parameter (WQP) monitoring, corrosion control treatment (CCT), source water monitoring/treatment, public education, and lead service line replacement (LSLR).

Utilities Covered

All community water systems (CWSs) and non-transient non-community water systems (NTNCWSs) are subject to the LCR requirements.

Table 1: Lead and Copper Tap and WQP Tap Monitoring

Size Category System SizeNumber of Pb/Cu Tap Sample Sites3 Number of WQP Tap Sample Sites4

Standard Reduced Standard Reduced

Large> 100K 100 50 25 10

50,001 - 100K 60 30 10 7

Medium10,001 - 50K 60 30 10 7

3,301 - 10K 40 20 3 3

Small

501 - 3,300 20 10 2 2

101 - 500 10 5 1 1

≤ 100 5 5 1 13 With written State approval, PWSs can collect < 5 samples if all taps used for human consumption are sampled.4 Two WQP tap samples are collected at each sampling site.

Table 2: Criteria for Reduced Pb/Cu Tap Monitoring

Annual PWS serves ≤ 50,000 people and is ≤ both ALs for 2 consecutive 6-month monitoring periods; or1. Any PWS that meets optimal WQPs (OWQPs) and is ≤ Pb AL for 2 consecutive 6-month monitoring 2. periods.

Triennial PWS serves ≤ 50,000 people and is ≤ both ALs for 3 consecutive years of monitoring; or1. Any PWS that meets OWQP specifications and is ≤ Pb AL for 3 consecutive years of monitoring; or2. Any PWS with 903. th percentile Pb and Cu levels ≤ 0.005 mg/L and ≤ 0.65 mg/L, respectively, for 2 consecutive 6-month monitoring periods (i.e., accelerated reduced Pb/Cu tap monitoring).

Every 9 years PWS serves ≤ 3,300 people and meets monitoring waiver criteria found at 40 CFR 141.86(g).

Lead Consumer NoticeWithin 30 days of learning the results, all systems must provide individual Pb tap results to people who receive water from sites that were sampled, regardless of whether the results exceed the Pb AL, as required by 40 CFR 141.85(d).

Consumer Confidence Report (CCR)All CWSs, irrespective of their lead levels, must provide an educational statement about lead in drinking water in their CCRs as required by 40 CFR 141.154. Must be in 2008 CCR (due July 1, 2009) if EPA is Primacy Agency, State adopts the rule by reference automatically, or adopts during 2008. Otherwise, this statement is required in the 2009 CCR (due July 1, 2010).

Office of Water (4606M) http://water.epa.gov/drink June 2008EPA 816-F-08-018

For additional information on the LCR

Call the Safe Drinking Water Hotline at 1-800-426-4791; visit the EPA Web site at http://water.epa.gov/drink; or contact your State drinking water representative.

Treatment Technique and Sampling Requirements if the AL is Exceeded5

5 Based on 90th percentile level. Multiply number of valid samples by 0.9 (e.g., 10 samples x 0.9 = 9; thus, use 9th highest Pb and Cu test result to compare to AL). For 5 samples, average 4th and 5th highest results. For < 5 samples, use highest result.

Water Quality Parameter (WQP)Applicability Refer to page 1.Parameters ► pH, alkalinity, calcium (initial only, unless calcium carbonate stabilization is used), conductivity (initial

monitoring only), orthophosphate (if inhibitor is phosphate-based); silica (if inhibitor is silicate-based), and temperature (initial monitoring only).

Frequency ► Systems installing CCT, must conduct follow-up monitoring for 2 consecutive 6-month periods. ► WQP tap monitoring is conducted every 6 months, EPTDS monitoring increases to every 2 weeks. ► After follow-up monitoring, State sets OWQP specifications that define optimal CCT.

Reduced Tap Monitoring

► Collect reduced number of sampling sites (see Table 1) if meet OWQPs for 2 consecutive 6-month periods.

► Collect reduced number of sampling sites at reduced frequency if meet OWQPs for: - 6 consecutive 6-month monitoring periods can monitor annually; - 3 consecutive years of annual monitoring can monitor triennially.

Public Education (PE)Applicability ► Systems that exceed the Pb AL (not required if only the Cu AL is exceeded). Purpose ► Educates consumers about lead health effects, sources, and steps to minimize exposure. Delivery Method ► CWSs: deliver materials to bill-paying customers and post lead information on water bills, work in

concert with local health agencies to reach at-risk populations (children, pregnant woman), deliver to other organizations serving “at-risk” populations, provide press releases, include new outreach activities from list in 40 CFR 141.85(a)(2)(vi), and post to Web site (CWSs serving > 100,000 only).

► NTNCWSs: posting and distribution to all consumers (can be electronic with State permission). Can apply to CWSs such as hospitals and prisons where population cannot make improvements.

Timing ► Within 60 days after end of monitoring period in which Pb AL was exceeded if not already delivering PE.6

► Repeat annually except: water bill inserts - quarterly; press releases - 2x/year, and Web posting - continuous.

► Can discontinue whenever ≤ Pb AL but must recommence if subsequently exceed Pb AL.6State may allow extension in some situations. Also, State may require approval of message content prior to delivery.

Source Water Monitoring and Source Water Treatment (SOWT)Applicability ► Systems that exceed Pb or Cu AL. Purpose ► Determine contribution from source water to total tap water Pb and Cu levels and need for SOWT. Timing ► One set of samples at each EPTDS is due within 6 months of first AL exceedance.

► System has 24 months to install any required SOWT. ► State sets maximum permissible levels (MPLs) for Pb and Cu in source water based on initial and

follow-up source water monitoring.Standard ► Ground water PWSs monitor once during 3-year compliance periods; surface water PWSs monitor

annually.Reduced ► Monitor every 9 years if MPLs are not exceeded during 3 consecutive compliance periods for ground

water PWSs or 3 consecutive years for surface water PWSs.

Corrosion Control Treatment (CCT)Applicability ► All large systems except those meeting requirements of 40 CFR 141.81(b)(2) or (b)(3).

► Medium and small systems that exceed either AL; may stop CCT steps if ≤ both ALs for 2 consecutive 6-month periods but must recommence CCT if subsequently exceed either AL.

Study ► All large systems except as noted above. ► If State requires study for small or medium systems, it must be completed within 18 months.

Treatment ► Once State determines type of CCT to be installed, PWS has 24 months to install. ► Systems installing CCT must conduct 2 consecutive 6 months of follow-up tap and WQP monitoring.

OWQPs ► After follow-up Pb/Cu tap and WQP monitoring, State sets OWQPs. Refer to WQP section above.

Lead Service Line Replacement (LSLR)Applicability ► Systems that continue to exceed the Pb AL after installing CCT and/or SOWT.

► Can discontinue LSLR whenever ≤ Pb AL in tap samples for 2 consecutive 6-month monitoring periods; must recommence if subsequently exceed.

Monitoring ► Optional: Sample from LSL to determine if line must be replaced. If all samples are ≤ 0.015 mg/L, line is considered “replaced through testing”; must reconsider these lines if Pb AL is subsequently exceeded.

► Required: Sample from any LSLs not completely replaced to determine impact on Pb levels.Replacement ► Must replace at least 7% of LSLs annually; State can require accelerated schedule.

► If only portion of LSL is replaced, PWS must: - Notify customers at least 45 days prior to replacement about potential for increased Pb levels. - Collect samples within 72 hours of replacement and provide results within 3 days of receipt.


1

DRINKING WATER MONITORING SYSTEM

CONSIST OF:

(1) SAMPLE COLLECTION

(2) LABORATORY ANALYSES

(3) DATA ANALYSES, INTERPRETATION, MANAGEMENT, AND REPORTING

STATE’S RESPONSIBILITIES

It is the responsibility of the State Safe Drinking Water Program to ensure that the public watersystems are tested for the listed contaminants on regular basis and that the levels meet therequired drinking water standards.

PUBLIC WATER SYSTEM’S RESPONSIBILITIES

It is the responsibility of the Public Water System to monitor their public water supplies for thelisted contaminants at the required frequencies and that the levels meet the required standards forproviding safe drinking water to its customers.

With respect to monitoring of their public water systems, water purveyors are required to collectdrinking water samples for analysis, reporting the results and contaminants, provide publicnotification of contaminant detection, and for keeping monitoring records.

ANALYTES OF INTEREST

SAMPLING LOCATION/FREQUENCY

SAMPLE COLLECTION

SAMPLE PRESERVATION/HANDLING

FIELD DETERMINATIONS

SAMPLE DOCUMENTATION

SAMPLE STORAGE & TRANSPORT

SAMPLE ANALYSES

2

VERIFICATION OF CONTAINERS

SAMPLE COLLECTION

SAMPLE PRESERVATION

FIELD TESTING/MEASUREMENTS

DOCUMENTATION

STORAGE AND TRANSPORT

3

COMMON CONTAMINANTS AND SOURCES

Contaminant Source

Phthalate ester plasticizers PlasticsA t L b S l tAcetone Lab SolventMethylene Chloride Lab SolventVinyl Chloride PVC pipesToluene Electrical tape, marking penOils Lubricated surfacesM t l M t l fMetals Metal surfacesFreon Refrigerated units, compressed gases Nitrate, sulfate, chloride Nitric-, Sulfuric-, & Hydrochloric acidsPAHs Cigarette smokeOther contaminants (ambient) Chemicals present in the air due to

acti ities in s rro nding area

4

activities in surrounding area

5

PHYSICAL CHANGES

▪ Volatilization

▪ Absorption/Adsorption

▪ Diffusion

6

CHEMICAL CHANGES

▪ Chemical reaction

▪ Photochemical reaction

▪ Microbiological degradation

▪ Precipitation

7

USE OF SAMPLE CONTAINERS FOR PRESERVATION

Container Use/Benefit

Glass Inert surface (No adsorption of organics, no introduction of organic contaminants, Adsorption of metals)

Plastic Cheap, less prone to breakage (diffusion or adsorption of organics, potential contamination by organics)

Plastic, sterile No bacteriological contaminants

Pl ti l th l Mi i i d ti f t lPlastic, polyethylene Minimize adsorption of metals

Amber Glass Minimize photochemical reactions

Teflon Expensive, inert surface

8

Metal Potential contamination by metals and organis

USE OF CHEMICAL REAGENTS AS PRESERVATIVES

Chemical Use

Sulfuric acid Reduce pH no chloride interferenceSulfuric acid Reduce pH, no chloride interference

Hydrochloric acid Reduce pH (possible chloride interference)

Nitric acid Reduce pH, create nitrate ion to solubilize metals

Sodium hydroxide Raise pH, stabilize cyanide and sulfide ion

Sodium thiosulfate Remove free chlorine, prevent chlorination reaction

9

10

USE OF SAMPLING PRACTICES FOR PRESERVATION

Practice Benefit

Minimize handling Reduce exposure to air, minimize chemical reaction

Zero headspace Reduce partitioning of volatiles into headspace(for Volatiles)

Maintain sterile Eliminate introduction of bacteriological contaminantsConditions

Filtration Focus on dissolved species

11

SAMPLE LABELSAMPLE LABEL

▪ Securely and clearly attached to sample container▪ Ink should be permanent, waterproof and non-smearing▪ Writing should be legible and large enough to read▪ Contain sufficient information to identify sample

CHAIN OF CUSTODY FORM

▪ Should have same basic information as label▪ Should accompany sample at all times▪ Ink should be permanent, waterproof and non-smearingp , p g▪ Writing should be legible and large enough to read ▪ Contain sufficient information to identify sample▪ Properly signed, dated, timed by all personnel handling sample. To ensure

transfer and custody of sample▪ Chain of Custody forms are legal documents and records. There should be no

discrepancies on the form.

12

p

13

Should comply with general requirements of 49 Code of Federal Regulations 173.24(a).

1. Limit sample volume to amount required by lab.

2. Use Plastic or Glass specified by the analytical method and sample collection details.

3. Use screw-type lids/covers – avoid stoppers, corks or other friction-type closures.

4. Provide suitable cushioning for all glass containers and protect plastic ones from punctures by sharp objects.

5. Use ice substitute or ice in sealed plastic bags.

14

6. Secure in sturdy shipping containers.

▪ Sturdy Shipping Containers ▪ Bottle labels

- waterproof ink- legible

▪ Coolant - wet ice – not usually used- blue ice- dry ice – not usually used (may freeze sample & shipping restrictions

▪ Insulation- maintain 4oC- prevent breakage

▪ Custodiy Seals- Prevent tampering- maintain integrity of shipping

▪ Length of Time in Transit- holding time

▪ Transport/Carriers- schedule (pick-up, and drop off)- documentation (shipping label, airbill, special labels)

15

- DOT regulations

5/2/2017

1

QA INFORMATION(Dechlorination & Temperature)

DW Monitoring Updates & Regulatory Changes

NOTES TO SAMPLE COLLECTORSFROM THE SLD (DOH)

• Sample dechlorination and preservationSample dechlorination and preservation• Temperature Requirements

5/2/2017

2

• DW Sample Dechlorination and Preservation is a 2-step Process.

Notes to Sample Collection

– Add dechlorinating agent (if needed) and fill to top (convex meniscus). Wait until dissolved (solid) or well mixed (liquid). Applies to 40 mL VOA vials.

– Add the preservative (if required) cap the– Add the preservative (if required), cap the vials (no bubbles) then cool to 4°C.

• Which Dechlorinating Agent to use?Depends on the Analysis. Not all use S di Thi lf t

Dechlorinating Agents

Sodium Thiosulfate:– VOCs uses Ascorbic Acid– SOCs uses Sodium Sulfite– HAAs uses Ammonium Chloride– Some Samples Do Not Require

D hl i tiDechlorination.(metals and nitrates)

• Some Sample Containers are Preloaded.– VOCs, SOCs, HAAs, and Herbicides

5/2/2017

3

• Using Wrong Sequence Invalidates S l

Dechlorinating Agents

Sample– Dechlorinate First, Then Add Preservative.

• Adding Wrong Amount May InvalidateAdding Wrong Amount May Invalidate Sample– You Can Add Too Much or Too Little.

Sodium Thiosulfate

Single Uncrushed Crystals (100-200 mg range)Finely Crushed Crystals ( 50-75 mg range per full scoop)

For 40 mL vials that require Thiosulfate add 3-4 mg½ scoop is too much.

Use only enough crystals to barely cover the bottom of the scoop

5/2/2017

4

What Happens When Samples Improperly Collected?

• Temperature Requirement:

Notes to Sample Collection

– Less than 6°C but not frozen if held for more 24 hrs after sample collection.

– If less than 24 hrs, only need to showIf less than 24 hrs, only need to show evidence of sample cooling. (Ice or Frozen Blue Ice Packs)

Drinking Water Monitoring ProgramQuality Assurance Program Plan

Section No. Appendix A Revision No. 0.0

Date: April 1, 2016 Page: A -1 of A - 5

APPENDIX A

CONTAINERS, PRESERVATION, AND HOLDING TIMES

I. Containers, Preservation, and Holding Times for Potable Water Samples.

TABLE 1A - Bacterial Tests

MaximumParameter No./Name Container1 Preservation2,3 Holding Time4

______________________________________________________________________________

Coliform, fecal and total and E. Coli............................... P,Pa,G Cool, 4°C, NTE 6 hours

Na2S2O35 for samples

delivereddirectly tolab bysampler

NTE 30 hoursfor samplesshipped via mail,freightor couriers. (See 4a)

TABLE 1B - Inorganic Tests


______________________________________________________________________________

Chloride ................................ P,G None required 28 days

Chlorine, total residual ............................... P,G None required Analyze

immediately

Fluoride ................................. P None required 28 days

Hydrogen ion (pH) ............... P,G None required Analyze immediately

Inorganic Metals ................... P Cool, 4°C 6 months HNO3 to pH<2




TABLE 1B - Inorganic Tests (continued)


______________________________________________________________________________

Lead and Copper ....... P Cool, 4°C 6 months HNO3 to pH<2

Chromium VI ...... P,G Cool, 4°C 24 hours

Mercury .......... P,G HNO3 to pH<2 28 days

Nitrate .......... P,G Cool, 4°C 48 hours

Nitrate-Nitrite .. P,G Cool, 4°C, 48 hours H2SO4 to pH<2

Turbidity ........ P,G Cool, 4°C 48 hours

TABLE 1C - Organic Tests:6,7 Maximum

Parameter No./Name Container1 Preservation2,3 Holding Time4

______________________________________________________________________________

Synthetic Organic G,Compounds ............... Teflon- Cool, 4°C 7 days

lined Na2S2O35

septum

Volatile Organic G,Compounds ............... Teflon- Cool, 4°C 14 days

lined Na2S2O35

septum Adjust pH with HCl

Trihalomethanes ......... G, Cool, 4°C, 14 days Teflon- Na2S2O3

5 lined septum

Haloacetic Acids.......... G, Cool, 4°C, 14 days Teflon- Na2S2O3

5 lined septum




TABLE 1C - Organic Tests:6,7 (continued) Maximum

Parameter No./Name Container1 Preservation2,3 Holding Time4

______________________________________________________________________________

DBCP/EDB/TCP ......... G, Cool, 4°C, 28 days Teflon- Na2S2O3

5

lined septum

TABLE 1D - Pesticides Tests:


______________________________________________________________________________

Glyphosate .............. G, Teflon- Cool, 4°C 28 days lined Na2S2O3

5

septum

Herbicides .............. G, Cool, 4°C 14 days Teflon- Na2S2O3

5

lined septum

Carbamates .............. G Cool, 4°C 28 days Teflon Na2S2O3

5

lined Monchloro- septum acetic acid

TABLE 1E - Radiological Tests:


______________________________________________________________________________

Alpha, beta, andradium ................ P,G HNO3 to pH 2




NOTES

1 Polyethylene (P) or Polypropylene or other autoclavable plastic (Pa) or Glass (G).

2 Sample preservation should be performed immediately upon sample collection. For compositechemical samples each aliquot should be preserved at the time of collection. When use of anautomated sampler makes it impossible to preserve each aliquot, then chemical samples may bepreserved by maintaining at 4°C until compositing and sample splitting is completed.

3 When any sample is to be shipped by common carrier or sent through the United States Mails, itmust comply with Department of Transportation Hazardous Materials Regulations (49 CFR Part172). The person offering such material for transportation is responsible for ensuring suchcompliance. For the preservation requirements of the above table, the Office of HazardousMaterials, Materials Transportation Bureau, Department of Transportation has determined that theHazardous Materials Regulations generally do not apply to the following materials: Hydrochloricacid (HCl) in water solutions at concentrations of 0.04% by weight or less (pH about 1.96 orgreater); Nitric acid (HNO3) in water solutions at concentrations of 0.15% by weight or less (pHabout 1.62 or greater); Sulfuric acid (H2SO4) in water solutions at concentrations of 0.35% byweight or less (pH about 1.15 or greater); and Sodium hydroxide (NaOH) in water solutions atconcentrations of 0.080% by weight or less (pH about 12.30 or less).

4 Samples should be analyzed as soon as possible after collection. The times listed are themaximum times that samples may be held before analysis and still be considered valid. Samples may be held for longer periods only if the laboratory has data on file to show that thespecific types of samples under study are stable for the longer time, and has received a variancefrom the Regional Administrator under Section 136.3(e). Some samples may not be stable for themaximum time period given in the table. The monitoring laboratory should hold the sample for ashorter time if knowledge exists to show that this is necessary to maintain sample stability.

4a Preservation: Current Manual for the Certification of Laboratories Analyzing Drinking WaterEPA/570/9-90/008 states: "Holding/travel time between sampling and analysis is not to exceed 30hours. If the laboratory is required by State regulation to analyze samples after 30 hours and upto 48 hours, the laboratory is to indicate that the data may be invalid because if excessive delaybefore sample processing. No samples received after 48 hours are to be analyzed forcompliance. All samples received in the laboratory are to be analyzed on the day of receipt." State requirements (Hawaii Administrative Rules Title 11 Chapter 115, Potable WaterLaboratories Exhibit A, Environmental Microbiology Reference Guide) will state: "Holding/traveltime between sampling and analysis is not to exceed six hours for those samples delivereddirectly to the laboratory by the sampler and is not to exceed 30 hours for those samples whichare shipped via mail or public transportation. Samples received after 30 hours are not analyzedfor compliance purposes. All samples received in the laboratory are to be analyzed within twohours of receipt."

5 Should be used in the presence or potential presence of residual chlorine.

6 Guidance applies to samples to be analyzed by GC, LC, or GC/MS for specific compounds.




NOTES (continued)

7 When the extractable analytes of concern fall within a single chemical category, the specificpreservative and maximum holding times should be observed for optimum safeguard of sampleintegrity. When the analytes of concerns fall within two or more chemical categories, the samplemay be preserved by cooling to 4°C, reducing residual chlorine with 0.008% sodium thiosulfate(Na2S2O3), storing in the dark, and adjusting the pH; samples preserved in this matter may be heldfor seven days before extraction and for forty days after extraction. Exceptions to this optionalpreservation and holding time procedure are noted in footnote 5 (re the requirement for thiosulfatereduction of residual chlorine).

LABORATORY

SESSION

LABORATORY

SESSION

LABORATORY CERTIFICATION

The regulations covered under 40 C.F.R. 141.28 requires that all testing for drinking watercompliance purposes, except for turbidity, free chlorine residual, temperature and pH beperformed by laboratories approved by either the U.S. Environmental Protection Agency (EPA)or those States with primary enforcement responsibility.

In order for the State to obtain and maintain primary enforcement responsibilities of he safedrinking water program, it is required to conform with the provisions of 40 C.F.R. 142.10(b)(3). The establishment and maintenance of a State program for the certification of laboratoriesconducting analytical measurements of drinking water contaminants pursuant to therequirements of the State primary drinking water regulations including the designation by theState of a laboratory officer, or officers, certified by the Administrator, as the official(s)responsible for the State’s certification program. Until such time as the EPA establishes aNational quality assurance program for laboratory certification, the State shall maintain aninterim program for the purpose of approving those laboratories from which the requiredanalytical measurements will be accepted.

Primacy States with certification programs are responsible for certifying local laboratories. Regional laboratories and principal State laboratories must successfully analyze a complete setof unknown performance evaluation (PE) samples annually and pass an on-site evaluation everythree years.

The following State Laboratories Division , State Department of Health personnel are qualifiedas Laboratory Certification Officers:

Richard Saiki (EHASB)Robert Pineda (EHASB)

and are responsible for conducting drinking water laboratory certification activities.

THE DRINKING WATER LABORATORIES LISTED ON THE FOLLOWING PAGES HAVEBEEN CERTIFIED OR APPROVED BY THE DEPARTMENT OF HEALTH STATELABORATORIES DIVISION. THE LISTING ALSO IDENTIFY THE PARAMETERS THATEACH OF THE LABORATORIES ARE CERTIFIED TO ANALYZE AND THE DATE THATCERTIFICATION EXPIRES.

rev. Nov 30, 2016

DIRECTORY OF DRINKING WATER LABORATORIES

CERTIFIED OR APPROVED BY THE HAWAII DEPARTMENT OF HEALTH, STATE LABORATORIES DIVISION

ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, Colorado 80487 (970) 879-6590 x531 (800) 334-5493 AECOS Laboratory, Inc. 45-939 Kamehameha Highway, Suite 104 Kaneohe, Hawaii 96744

(808) 234-7770 Agriculture & Priority Pollutants Laboratories, Inc. 908 N. Temperance Avenue Clovis, California 93611 (559) 275-2175 Alloway Marion Laboratory 1776 Marion-Waldo Road Marion, Ohio 43302

(419) 223-1362 ALS Environmental, Houston 19408 Park Row, Suite 320 Houston, Texas 77084-4949 (800) 695-7222 ALS Environmental, Kelso 1317 South 13th Avenue Kelso, Washington 98626 (360) 577-7222 Associated Laboratories 806 North Batavia Orange, California 92868-1225

(714) 771-6900 BSK Analytical Laboratories 1414 Stanislaus Street Fresno, California 93706 (559) 497-2888 Bureau Veritas North America, Inc. 3380 Chastain Meadows Parkway, Suite 300 Kennesaw, Georgia 30144

(770) 499-7500 Eurofins Calscience Environmental Laboratories, Inc. 7440 Lincoln Way Garden Grove, California 92841

(714) 895-5494

Eberline Analytical Corp, Richmond 2030 Wright Avenue Richmond, California 94804 (510) 235-2633 Edge Analytical, Incorporated 1620 South Walnut Street Burlington, Washington 98233 (360) 757-1400 EMAX Laboratories, Inc. 1835 W, 205th Street Torrance, California 90501

(310) 618-8889

EMSL Analytical, Inc. - California 2235 Polvorosa Avenue, Suite 230 San Leandro, California 94577

(510) 895-3675

EMSL Analytical, Inc. – New Jersey 200 Route 130 North Cinnaminson, New Jersey 08077 (800) 220-3675 EnviroMatrix Analytical, Inc. 4340 Viewridge Ave., Suite A San Diego, California 92123 (858) 560-7717 Eurofins Eaton Analytical, Inc. (f.k.a. MWH Laboratories, Inc.) 750 Royal Oaks Drive, Suite 100 Monrovia, California 91016-3629

(626) 386-1100 (626) 386-1125 Eurofins Lancaster, PA 2425 New Holland Pike Lancaster, Pennsylvania 17601 (717) 656-2681

Eurofins Analtyical, South Bend, IN (formerly Underwriters Laboratories, Inc.) 110 South Hill Street South Bend, Indiana 46617 (574) 233-4777 (800) 332-4345

rev. Nov 30, 2016

FGL Environmental 853 Corporation Street Santa Paula, California 93060

(805) 392-2024 Food Quality Analysts, LLC 3170-A Ualena Street Honolulu, Hawaii 96819

(808) 839-9444 GEL Laboratories, LLC 2040 Savage Road Charleston, South Carolina 29407

(843) 556-8171 County of Hawaii Department of Water Supply Microbiology Laboratory 25 Aupuni Street Hilo, Hawaii 96720 Honolulu Board of Water Supply 630 S. Beretania St. Honolulu, HI 96843

(808)748-5841 Hawaii Food & Water Testing, LLC 2688 B Kilihau Street Honolulu, Hawaii 96819 (808) 836-5558 HECO Chemistry Laboratory Environmental Department P.O. Box 2750 Honolulu, Hawaii 96840

(808) 543-4297 Honolulu Board of Water Supply Chemistry Laboratory 630 Beretania Street Honolulu, Hawaii 96813 (808) 748-5840 Kauai Department of Water 4398 Pua Loke Street Lihue, Hawaii 96766 LABCOR, Inc. 7619 Sixth Avenue NW Seattle, Washington 98117-4037 (206) 781-0155 Maui Department of Water Supply 614 Palapala Drive Kahului, Hawaii 96732 (808) 270-7816

Maxxam Analytics International Corp. 6740 Campobello Road Mississauga, Ontario L5N2L8 (905) 817-5700 McCampbell Analytical, Inc. 1534 Willow Pass Road Pittsburg, CA 94565-1701 (925) 252-9262

National Testing Laboratories, Ltd. 556 South Mansfield Street Ypsilanti, Michigan 48197 (734) 483-8333 Naval Facilities Engineering Command Hawaii Environmental Services Laboratory EV11 (NAVSAC PAC) 400 Marshall Road Pearl Harbor, Hawaii 96860-3139 (808) 471-0768 NSF International 789 N. Dixboro Road Ann Arbor, Michigan 48105-9723

(734) 827-6837 Pace Analytical Services, Inc., Florida 8 East Tower Circle Ormond Beach, Florida 32174 (386) 672-5668 Pace Analytical Services, Inc., Minnesota 1700 Elm Street, Suite 200 Minneapolis, Minnesota 55414 (612) 607-6352 Pace Analytical Services, Inc., Pittsburgh 1638 Roseytown Road, Suites 2, 3, & 4 Greensburg, Pennsylvania 15601 (724) 850-5600 Radiation Safety Engineering, Inc. 3245 N. Washington St. Chandler, Arizona 85225-1121

(480) 897-9459 TestAmerica Laboratories, Inc., Chicago 2417 Bond Street University Park, Illinois 60484 (708) 534-5200

rev. Nov 30, 2016

TestAmerica Honolulu 4429 Malaai St., Suite 104 Honolulu, HI 96818 (808) 486-5227 TestAmerica Laboratories, Inc., Irvine 17461 Derian Avenue, Suite 100 Irvine, California 92614 (949) 261-1022 TestAmerica Laboratories, Inc., Knoxville 5815 Middlebrook Pike Knoxville, Tennessee 37921-5947 (865) 291-3000

TestAmerica Laboratories, Inc. – Richland 2800 George Washington Way Richland, WA 99354 (509) 375-3131 TestAmerica Laboratories, Savannah 5102 LaRoche Avenue Savannah, Georgia 31404 (912) 354-7858 TestAmerica Laboratories, Inc., West Sacramento 880 Riverside Parkway West Sacramento, California 95605

Tripler Army Medical Center Preventive Medicine Services Env. Laboratory Attn: MCHK-PV (Maj. Stacy Mosko) CDR TAMC 1 Jarrett White Road Tripler Army Medical Center, Hawaii 96859-5000 Vista Analytical Laboratory 1104 Windfield Way El Dorado Hills, CA 95762

(916) 673-1520 Weck Laboratories, Inc. 14859 East Clark Avenue City of Industry, California 91745-1396 (626) 336-2139

(916) 374-4308 *NOTE: The above listings are for informational purposes only. It does not imply that any laboratory on the list will perform analyses for any other party. Water systems or their authorized representative ("applicant") are responsible for contracting with any of the certified or approved laboratories, listed above, to perform all of the analyses required for a new source approval. It is also the "applicant's" responsibility to verify that the contracted laboratory or laboratories are currently certified when the analyses are performed. Please note that the Department of Health does not perform analyses for prospective sources of drinking water.

Certified or Approved Drinking Water Laboratories(Hawaii Department of Health, State Laboratories Division)

INORGANIC CHEMICALS

CONTAMINANTA

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Pollu

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*

ALS

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CONTAMINANT

Antimony 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8, SM3113B 200.8 200.8 200.8 200.8 200.8 200.8 200.8 Antimony

Arsenic 200.8 200.8 200.8200.9 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 SM3113B 200.9 200.8 200.8,

SM3113B 200.8 200.8 200.8 200.8 200.8 200.8 200.8 Arsenic

Barium 200.8200.7

200.7200.8

200.7200.8

200.7200.8 200.7, 200.8 200.7

200.8200.7200.8

200.8200.7

200.8200.7 200.8 200.8 200.8 200.7

200.8200.7200.8 200.8 200.7 200.8 200.7 200.8 200.8 200.7, 200.8 200.7, 200.8 200.7

200.8200.7200.8 Barium

Beryllium 200.8200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7200.8

200.7200.8

200.8200.7

200.8200.7 200.8 200.8 200.8 200.7

200.8200.7200.8 200.8 200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7, 200.8 200.7200.8 200.8 Beryllium

Cadmium 200.8 200.7200.8

200.8 200.7, 200.8 200.8200.7

200.7200.8

200.8200.7

200.8200.7 200.8 200.8 200.8 200.7

200.8200.7200.8 200.8 200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7, 200.8 200.7200.8

200.7200.8 Cadmium

Chromium 200.8200.7

200.8200.7

200.7200.8

200.8200.7 200.7, 200.8 200.8

200.7200.7200.8

200.8200.7

200.8200.7 200.8 200.8 200.8 200.7

200.8200.7200.8 200.8 200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7, 200.8 200.7200.8

200.7200.8 Chromium

Copper 200.8200.7 200.8 200.7 200.7, 200.8,

200.9200.8200.7 200.7, 200.8 200.8

200.7200.7200.8

200.8200.7

200.8200.7 200.8 200.8

200.7 200.8 200.7200.8 SM3113B 200.7 SM3113B,

200.9200.7200.8 200.8 200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7, 200.8 200.7200.8

200.7200.8 Copper

Lead 200.8 200.8 200.8200.9 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 SM3113B 200.9 SM3113B,

200.9 200.8 200.8, SM3113B 200.8 200.8 200.8 200.8 200.8 200.8 200.8 Lead

Mercury 245.1 245.1 245.1 200.8 245.1 200.8, 245.1 245.1 245.1 245.1 245.1 245.1 200.8 245.1 245.2, 200.8 200.8 200.8 245.1 200.8 245.1 245.1 200.8, 245.1 245.1 Mercury

Nickel 200.8 200.8 200.7 200.7200.8

200.8200.7 200.7, 200.8 200.8

200.7200.7200.8

200.8200.7

200.8200.7 200.8 200.8 200.8 200.7

200.8200.7200.8 200.8 200.7 200.8 200.7

200.8 200.8 200.7, 200.8 200.7, 200.8 200.7200.8

200.7200.8 Nickel

Selenium 200.8 200.8 200.8200.9 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8,

SM3113B 200.8 200.8 200.8 200.8 200.8 200.8 200.8 Selenium

Thallium 200.8 200.8 200.8200.9 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 200.8 Thallium

Asbestos 100.1 100.2 100.2 100.2 100.2 Asbestos

Cyanide 335.4 335.4 SM4500 CN E F

SM4500 CN F

335.4SM4500 CN

E

SM4500 CN E

SM4500CN F,

335.4335.4 335.4, Lachat 10-

204-00-1-XSM4500

CN ESM4500

CN E 335.4 335.4 SM4500 CN-CE

SM4500 CN E

335.4,SM 4500

CN E335.4 Cyanide

Fluoride 300.0 SM 4500F C 300.0,SM 4500F C

300.0,SM 4500F C 300.0 300.0

300.0,SM

4500F C

300.0,SM 4500F C

300.0,SM 4500F C

300.0,SM 4500F C

Technicon 380-75WE,

SM4500FC, 300.0300.0 Hach 10225 300.0 SM 4500F C 300.0 300.0, 300.1 300.0 SM 4500F C SM 4500F C 300.0 300.0,

SM 4500F C300.0,

SM 4500F C300.0,

SM 4500F C 300.0 Fluoride

Nitrate 353.2300.0

353.2, SM4500 NO3F

353.2300.0 300.0 300.0, SM4500

NO3F 300.0 353.2300.0

353.2300.0

300.0353.2 calc

300.0353.2 calc

300.0353.2 300.0 Hach 10206 300.0 353.2 300.0 300.0, 300.1 300.0 300.0 300.0

353.2

SM4500 NO3 F,

300.0, 353.2300.0 300.0

353.2300.0353.2 Nitrate

Nitrite 353.2300.0

353.2, SM4500 NO3F

353.2300.0 300.0 300.0, SM4500

NO3F 300.0 353.2300.0

353.2300.0,

SM4500 NO2 B

300.0353.2

300.0353.2 353.2

300.0,SM4500 NO2 B

353.2 300.0 353.2 300.0 300.0, 300.1 300.0 300.0 300.0353.2

SM4500 NO2 B,300.0

300.0 300.0353.2

300.0353.2 Nitrite

CertificationExpiration Date

09/3

0/17

04/0

1/17

02/1

0/17

01/2

9/17

04/0

1/17

01/1

8/17

06/3

0/17

09/3

0/16

06/3

0/17

10/3

1/17

01/2

9/17

01/2

9/17

01/3

1/17

09/1

6/17

08/0

1/16

10/3

1/17

10/3

1/17

05/3

1/17

04/3

0/17

03/2

8/17

10/3

1/17

12/3

1/16

03/3

1/17

11/0

3/17

06/3

0/17

12/3

1/16

04/3

0/17

01/2

9/17

06/3

0/17

01/2

9/17 Certification

Expiration Date

* Laboratories located on the continental U.S. that are approved by the Department of Health, State Laboratories Division.

November 30, 2016


EPA REGULATED ORGANIC COMPOUNDS

CONTAMINANT

Agr

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CONTAMINANT

Alachlor 525.2 525.2 525.2 525.2 525.2, 505 525.2, 507 525.2 505 525.2, 505 508.1, 525.2 525.2 508.1 . 525.2, 505 525.2 . 525.2 AlachlorAtrazine 525.2 525.2 525.2 525.2 525.2 525.2, 507 525.2 507 525.2, 505 508.1, 525.2 525.2 508.1 . 525.2 525.2 . 525.2 AtrazineChlordane 508 508.1 505 508.1 525.2, 505 505 505 525.2, 505 505 505, 508.1 508.1 . 505 508 . 508 ChlordaneDieldrin 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 505, 525.2 525.2 508.1 525.2 508, 525.2 508, 525.2 DieldrinEndrin 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 525.2, 505 525.20 525.2 508.1 . 505 508, 525.2 . 508, 525.2 EndrinHeptachlor 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 . 505 508, 525.2 . 508, 525.2 HeptachlorHeptachlor Epoxide 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 . 505 508, 525.2 . 508, 525.2 Heptachlor EpoxideHexachlorobenzene 508 508, 525.2 525.2 505 525.2 525.2 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 525.2, 505 525.2 508 HexachlorobenzeneHexachlorocyclopentadiene 508, 525.2 525.2 505 525.2 525.2 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 525.2, 505 525.2 508 HexachlorocyclopentadieneLindane 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 505 508, 525.2 508, 525.2 LindaneMethoxychlor 508 508 508.1 505 508.1, 525.2 525.2, 505 525.2 525.2 505 525.2, 505 505, 525.2 525.2 508.1 525.2, 505 508, 525.2 508, 525.2 MethoxychlorSimazine 525.2 525.2 525.2 525.2 525.2 525.2 525.2 507 525.2, 505 508.1, 525.2 525.2 508.1 525.2 525.2 525.2 SimazineToxaphene 508 508 508.1 505 508.1 505 505 505 525.2, 505 505 505, 508.1 508.1 505 508 508 Toxaphene

Polychlorinated Biphenyls (PCB) Screen aroclor screen 508

aroclor screen 508.1

aroclor screen

505

aroclor screen 508.1 aroclor screen 505 aroclor screen 505 aroclor

screen 505 aroclor screen 505 aroclor screen 505 505

aroclor screen 508.1

aroclor screen 505

aroclor screen 508 508 Polychlorinated Biphenyls (PCB) Screen

Polychlorinated Biphenyls (PCB) as Decachlorobiphenyl 508A Polychlorinated Biphenyls (PCB) as Decachlorobiphenyl

Aldicarb 531.1 531.1 531.1 531.2 531.2 531.1 531.1, 531.2 531.1 531.2 531.2 531.2 531.1 531.1 531.1 531.1 AldicarbAldicarb Sulfone 531.1 531.1 531.1 531.2 531.2 531.1 531.1, 531.2 531.1 531.2 531.2 531.2 531.1 531.1 531.1 531.1 Aldicarb SulfoneAldicarb Sulfoxide 531.1 531.1 531.1 531.2 531.2 531.1 531.1, 531.2 531.1 531.2 531.2 531.2 531.1 531.1 531.1 531.1 Aldicarb SulfoxideCarbofuran 531.1 531.1 531.1 531.2 531.2 531.1 531.1, 531.2 531.1 531.2 531.2 531.2 531.1 . 531.1 531.1 . 531.1 CarbofuranOxamyl 531.1 531.1 531.1 531.2 531.2 531.1 531.1, 531.2 531.1 531.2 531.2 531.2 531.1 531.1 531.1 531.1 Oxamyl

Benzo(a)Pyrene 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 . 525.2 525.2 . 525.2 Benzo(a)PyreneDi(2-ethylhexyl)Adipate 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 . 525.2 525.2 . 525.2 Di(2-ethylhexyl)-AdipateBis(2-ethylhexyl)Phthalate 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 525.2 . 525.2 525.2 . 525.2 Bis(2-ethylhexyl)-Phthalate

Dalapon 515.1 515.1 515.4 515.3 515.1, 515.4 515.4, 552.3 515.1 515.3 515.3 515.3, 552.2 552.2 515.3 515.3 . 515.4 515.1 . 515.3 Dalapon2,4-D 515.1 515.1 515.4 515.3 515.1, 515.4 515.4 515.1 515.3 515.3 515.3 515.2 515.3 515.3 . 515.4 515.1 . 515.3 2,4-DDinoseb 515.1 515.1 515.4 515.3 515.1, 515.4 515.4 515.1 515.3 515.3 515.3 515.2 515.3 515.3 . 515.4 515.1 . 515.3 DinosebPentachlorophenol 515.1 515.1 515.4 515.3 515.1, 515.4 515.4, 525.2 515.1 515.3 515.3 515.3 515.2 515.3 515.3 515.4 515.1 515.3 PentachlorophenolPicloram 515.1 515.1 515.4 515.3 515.1, 515.4 515.4 515.1 515.3 515.3 515.3 515.2 515.3 515.3 515.4 515.1 515.3 Picloram2,4,5-TP (Silvex) 515.1 515.1 515.4 515.3 515.1, 515.4 515.4 515.1 515.3 515.3 515.3 515.2 515.3 515.3 515.4 515.1 515.3 2,4,5-TP (Silvex)

Diquat 549.2 549.2 549.2 549.2 549.2 549.2 549.2 549.2 549.2 549.2 549.2 . 549.2 549.2 . 549.2 Diquat

Endothall 548.1 548.1 548.1 548.1 548.1 548.1 548.1 548.1 548.1 548.1 548.1 . 548.1 548.1 . 548.1 Endothall

Glyphosate 547 547 547 547 547 547 547 547 547 547 547 . 547 547 . 547 Glyphosate

1,2-dibromo-3-chloropropane (DBCP) 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1, 551.1, 524.3 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 . 504.1 504.1 . 504.1 1,2-dibromo-3-chloropropane (DBCP)1,2-dibromoethane (EDB) 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1, 551.1, 524.3 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 . 504.1 504.1 . 504.1 1,2-dibromoethane (EDB)1,2,3-Trichloropropane (TCP) 504.1 504.1 504.1 504.1 504.1 504.1 504.1 504.1 1,2,3-Trichloropropane (TCP)

Regulated Volatile Organic Compounds 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2, 524.3 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 Regulated Volatile Organic CompoundsVinyl Chloride 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2, 524.3 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 524.2 Vinyl Chloride

Trihalomethanes 524.2 524.2 524.2 524.2 524.2 524.2 524.2, 551.1, 524.3 524.2 524.2 524.2,

551.1 524.2 544.2 524.2 524.2 524.2 524.2 524.2 524.2 Trihalomethanes

Haloacetic Acids 552.2 552.2 552.2 552.3 SM6251B, 552.3 552.2 552.2 552.2 552.2 552.2 552.2 552.2 552.2 552.2 Haloacetic Acids

2,3,7,8-Tetrachlorodibenzo-p-dioxin (Dioxin) 1613 1613 1613 1613 1613 1613 1613 1613 1613 2,3,7,8-Tetrachlorodibenzo-p-dioxin (Dioxin)

CertificationExpiration Date

09/3

0/17

04/0

1/17

04/3

0/17

02/1

0/17

01/2

9/17

01/1

8/17

06/3

0/17

10/3

1/17

01/2

9/17

01/2

9/17

01/3

1/17

09/1

6/17

08/0

1/16

10/3

1/17

05/3

1/17

11/2

2/16

10/3

1/17

12/3

1/16

11/0

3/17

06/3

0/17

12/3

1/17

04/1

3/17

01/2

9/17

06/3

0/17

01/2

9/17

02/0

7/17

01/2

9/17 Certification

Expiration Date

* Laboratories located on the continental U.S. that are approved by the Department of Health, State Laboratories Division.

November 30, 2016


RADIOCHEMISTRY MONITORINGC

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CO

NTA

MIN

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Gross Alpha 900.0 900.0 SM 7110 B SM 7110 C 900.0 900.0 900.0,

SM 7110 C900.0,

EPA 00-02 900.0, EPA 00-02

900.0, SM 7110 C Gross Alpha

Gross Beta 900.0 900.0 SM 7110 B 900.0 900.0 900.0 900.0 900.0 900.0 Gross Beta

Radium - 226 903.1 Georgia Inst. Tech Rev1,2

SM 7500-Ra B 903.1 903.1 903.1 903.1, GA 903.0

903.1 Radium - 226

Radium - 228 904.0 Georgia Inst. Tech Rev1,2

SM 7500-Ra D

EPA Ra-05 904.0 904.0 904.0, GA 904.0 Radium - 228

Uranium 200.8 200.8 200.8 200.8 200.8, 908.0

ASTM D5174-97 200.8

908.0, ASTM

D5174-97

ASTM D6239-09,

SM 7500-UC200.8 ASTM

D5174-97 200.8 Uranium

Certification Expiration

Date 08/3

1/17

01/1

8/17

01/2

9/17

09/1

6/17

08/0

1/16

10/3

1/17

12/3

1/20

17

03/3

1/17

02/2

8/15

01/2

9/17

01/2

9/17

01/2

9/17 Certification

Expiration Date

*Laboratories located on the continental U.S. that are approved by the Department of Health, State Laboratories Division.

November 30, 2016

TOTAL COLIFORMS E-COLI HETEROTROPHIC BACTERIA

County of Hawaii, Dept. of Water Supply Microbiology Laboratory 8/31/17

SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration SM 9223

Colilert-18 (Vessel) Presence/Absence

SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration SM 9223 Colilert-

18 (Vessel) Presence/Absence IDEXX SimPlate Enumeration

County of Maui, Department of Water Supply 3/31/17SM 9223 Colisure (vessel) Presence/Absence

SM 9223 Colilert-18 (vessel) Presence/Absence SM 9223 Colilert-18 (Quantitray) Enumeration

SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colilert-18 (vessel) Presence/Absence SM 9223 Colilert-18 (Quantitray) Enumeration

SM 9215B HPC (Pour Plate) Enumeration IDEXX SimPlate Enumeration

DOH Hawaii District Health Laboratory - Hilo 9/30/17 SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colisure (vessel) Presence/Absence

DOH Kauai District Health Laboratory - Lihue 5/30/17 SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colisure (vessel) Presence/Absence

DOH Maui District Health Laboratory 6/30/17 SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colisure (vessel) Presence/Absence SM 9215B HPC (Pour Plate) Enumeration

Honolulu Board of Water Supply 8/31/18 SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colilert-18 (vessel) Presence/Absence

SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colilert-18 (vessel) Presence/Absence


Tripler Army Medical Center 10/31/17 SM 9223 Colilert (vessel) Presence/Absence SM 9223 Colilert (vessel) Presence/Absence

AECOS 12/31/17 SM 9223 Colilert (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration

SM 9223 Colilert (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration


PROVISIONAL CERTIFICATION*

County of Kauai, Department of Water 5/30/17 SM 9223 Colisure (vessel) Presence/Absence SM 9223 Colisure (vessel) Presence/Absence IDEXX SimPlate Enumeration

CERTIFICATION HAS LAPSED

Hawaii Food & Water Testing, LLC 4/30/16 SM 9223 Colilert (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration

SM 9223 Colilert (vessel) Presence/Absence SM 9223 Colilert (Quantitray) Enumeration SM 9215 HPC (Pour Plate) Enumeration

REVOKED

FQLabs, LLC

Revoked 10/17/15; Earliest

reapplication allowed: 3/17/16

SM 9223 Colilert (Quantitray) Presence/Absence SM 9223 Colilert (Quantitray) Presence/Absence SM 9215 HPC (Pour Plate) Enumeration IDEXX SimPlate Enumeration

* A provisionally certified laboratory may analyze drinking water samples for compliance purposes only if the clients are notified of its status in writing on any report.

Hawaii Department of Health Certified Drinking Water Laboratories

MICROBIOLOGICAL ANALYSIS

As of 5/24/2016

FULL CERTIFICATION CERTIFICATE EXPIRATION

CERTIFIED LABORATORY METHOD

8−1

APPROVED METHODS FOR DRINKING WATER ANALYSIS

APPROVED METHODS FOR MICROBIOLOGICAL (COLIFORM) SAMPLING To comply with the provisions of the Total Coliform Rule, public water systems must conduct analyses in accordance with one of the analytical methods in the following table. Total coliform methods, except for the Colisure Test, are contained in the 18th edition of Standard Methods for the Examination of Water and Wastewater, 1992, American Public Health Association, 1015 Fifteenth Street NW, Washington, D.C. 20005. Preparation of the EC medium and the nutrient agar are described in Standard Methods, p. 9-52, para. la, and pp. 9-47 to 9-48, respectively. A description of the Colisure Test may be obtained form the Millipore Corporation, Technical Services Department, 80 Ashby Road, Bedford, MA 01730. The phone number is (800)645-5746.

Organism Methodology Citation Total Coliforms1

Total Coliform Fermentation Technique2,3,4

9221A, B

Total Coliform Membrane Filter Technique

9222A, B, C

Presence-Absence (P-A) Coliform Test4,5

9221D

ONPG-MUG Test6

9223

Colisure Test7,8

E*Colite® Test9

m-ColiBlue24® Test10

Footnotes 1The time from sample collection to initiation of analysis may not exceed 30 hours. 2Lactose broth, as commercially available, may be used in lieu of lauryl tryptose broth, if the system conducts at least 25 parallel tests between this medium and lauryl tryptose broth using the water normally tested, and this comparison demonstrates that the false-positive rate for total coliforms, using lactose broth, is less than 10 percent. 3If inverted tubes are use to detect gas production, the media should cover these tubes at least one-half to two-thirds after the sample is added. 4No requirement exists to run the completed phase on 10 percent of all total coliform-positive confirmed tubes. 5Six-times formulation strength may be used if the medium is filter-sterilized rather than autoclaved. 6The ONPG-MUG Test is also known as the Autoanalysis Colilert System. 7The Colisure Test must be incubated for 28 hours before examining the results. If examination at 28 hours is not convenient, the results may be examined at any time between 28 hours and 48 hours. 8A description of the Colisure Test, Feb 28, 1994, may be obtained from IDEXX Laboratories, Inc., One IDEXX Drive, Westbrook, Maine 04092. The Colisure Test may be read after an incubation time of 24 hours.

9A description of the E*Colite®Test, “Presence/Absence for Coliforms and E. Coli in Water,” Dec 21, 1997, is available from Charm Sciences, Inc., 36 Franklin Street, Malden, MA 02148–4120.

10A description of the m-ColiBlue24®Test, Aug 17, 1999, is available from the Hach Company, 100 Dayton Avenue, Ames, IA 50010.

8−2

APPROVED METHODS FOR INORGANIC CHEMICALS AND OTHER PARAMETERS Analysis for the following contaminants shall be conducted in accordance with the methods in the following Table, or their equivalent as determined by EPA. The monitoring requirements for these contaminants are specified at Sections 141.23, 141.41, and 141.80 - 141.91. Criteria for analyzing arsenic, barium, beryllium, cadmium, calcium, chromium, copper, lead, nickel, selenium and thallium with digestion or directly without digestion, and other mandatory procedures are contained in Section IV of this Technical Notes document. Guidance on conducting asbestos analysis is described in Section V of Technical Notes. Contaminant Methodology EPA ASTM1 SM2 Other Antimony ICP-Mass Spectrometry 200.83

Hydride-Atomic Absorption D-3697-92 Atomic Absorption; Platform 200.93 Atomic Absorption; Furnace 3113B

Arsenic Inductively Coupled Plasma 200.73 3120B

ICP-Mass Spectrometry 200.83

Atomic Absorption, Platform 200.93 Atomic Absorption, Furnace D2972-93C 3113B Hydride Atomic Absorption D-2972-93B 3114B

Asbestos Transmission Electron Microscopy 100.14

Transmission Electron Microscopy 100.25 Barium Inductively Coupled Plasma 200.73 3120B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Direct 3111D Atomic Absorption; Furnace 3113B

Beryllium Inductively Coupled Plasma 200.73 3120B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93 Atomic Absorption; Furnace D-3645-93B 3113B

Cadmium Inductively Coupled Plasma 200.73

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93 Atomic Absorption; Furnace 3113B

Chromium Inductively Coupled Plasma 200.73 3120B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93 Atomic Absorption; Furnace 3113B

Cyanide Manual Distillation followed by 4500CN-C

Spectrophotometric, Amenable D2036-91B 4500-CN-G Spectrophotometric Manual D2036-91A 4500-CN-E I-300-856

Semi-automated 335.47 Selective Electrode 4500-CN-F

8−3

Contaminant Methodology EPA ASTM SM2 Other Fluoride Ion Chromatography 300.07 D4327-91 4110B

Manual Distill.; Color. SPADNS 4500F-B,D Manual Electrode D1179-93B 4500F-C

Automated Electrode 380-75WE8 Automated Alizarin 4500F-E 129-71W8

Mercury Manual, Cold Vapor 245.13 D3223-91 3112B

Automated, Cold Vapor 245.29

ICP-Mass Spectrometry 200.83 Nickel Inductively Coupled Plasma 200.73 3120B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93 Atomic Absorption; Direct 3111B Atomic Absorption; Furnace 3113B

Nitrate Ion Chromatography 300.07 D4327-91 4110B B-101110

Automated Cadmium Reduction 353.27 D3867-90A 4500-NO3-F Ion Selective Electrode 4500-NO3-D 60111 Manual Cadmium Reduction D3867-90B 4500-NO3-E

Nitrate Ion Chromatography 300.07 D4327-91 4110B B-101110

Automated Cadmium Reduction 353.27 D3867-90A 4500-NO3-F Manual Cadmium Reduction D3867-90B 4500-NO3-E Spectrophotometric 4500-NO2-B

Selenium Hydride-Atomic Absorption D3859-93A 3114B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93 Atomic Absorption; Furnace D3859-93B 3113B

Thallium ICP-Mass Spectrometry 200.83

Atomic Absorption; Platform 200.93 Lead Atomic Absorption; Furnace D3559-90D 3113B

ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93

Copper Atomic Absorption; Furnace D1688-90C 3113B

Atomic Absorption; Direct Aspiration D1688-90A 3111B ICP 200.73 3120B ICP-Mass Spectrometry 200.83 Atomic Absorption; Platform 200.93

pH Electrometric 150.19 D1293-84 4500-H+-B

150.29 Conductivity Conductance D1125-91A 2510B

8−4

Contaminant Methodology EPA ASTM1 SM2 Other Calcium EDTA titrimetric D511-93A 3500-Ca-D

Atomic Absorption, Direct Aspiration D511-93B 3111B Inductively-coupled plasma 200.73 3120B

Alkalinity Titrimetric D1067-92B 2320B

Electrometric Titration I-1030-856 Ortho- Colorimetric, automated, ascorbic acid 365.17 4500-P-F phosphate unfiltered, Colorimetric, ascorbic acid, single D515-88A 4500-P-E no digestion reagent or hydrolysis Colorimetric, phosphomolybdate; I-1601-856

automated-segmented flow; I-2601-906 automated discrete I-2598-856 Ion Chromatography 300.07 D4327-91 4110

Silica Colorimetric, molybdate blue; I-1700-856

automated-segmented flow I-2700-856 Colorimetric D859-88 Molybdosilicate 4500-Si-D Heteropoly blue 4500-Si-E Automated method for molybdate-reactive silica 4500-Si-F Inductively-coupled plasma 200.73 3120B

Temperature Thermometric 2550B Sodium Inductively-coupled plasma 200.73

Atomic absorption; direct aspiration 3111B

Footnotes 1 Annual Book of ASTM Standards, Vols. 11.01 and 11.02, American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103. 2 18th edition of Standard Methods for the Examination of Water and Wastewater, 1992, American Public Health Association, 1015 Fifteenth Street NW, Washington, D.C. 20005. 3 “Methods for Determination of Metals in Environmental Samples - Supplement I”, EPA-600/R-94/111, May 1994. Available at NTIS, PB94-184942. 4 Method 100.1, “Analytical Method for Determination of Asbestos Fibers in Water,” EPA-600/4-83-043, September 1983. Available at NTIS, PB83-260471. 5 Method 100.2, “Determination of Asbestos Structures Over 10 μm in Length in Drinking Water,” EPA-600/R-94/134, June 1994. Available at NTIS, PB94-201902. 6 Available from Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, CO 80225-0425. 7 "Methods for the Determination of Inorganic Substances in Environmental Samples,” EPA-600/R-93/100, August 1993. Available at NTIS, PB94-121811.

8−5

8 Industrial Method No. 129-71W, “Fluoride in Water and Wastewater,” December 1972, and Method No. 380-75WE, “Fluoride in Water and Wastewater,” February 1976, Technicon Industrial Systems, Tarrytown, NY 10591. 9 Methods 150.1, 150.2 and 245.2 are available from USEPA, EMSL-Cincinnati, OH 45268. The identical methods are also in “Methods for Chemical Analysis of Water and Wastes,” EPA-600/4-79/020, March 1983. 10Method B-1011, “Waters Test Method for Determination of Nitrite/Nitrate in Water Using Single Column Ion Chromatography,” Millipore Corporation, Waters Chromatography Division, 34 Maple Street, Milford, MA 01757. 11Technical Bulletin 601 “Standard Method of Test for Nitrate in Drinking Water, “July 1994, PN 221890- 001, ATI Orion, 529 Main Street, Boston, MA 02129. This method is identical to Orion WeWWG/5880, which is approved for nitrate analysis. ATI Orion republished the method in 1994, and renumbered it as 601, because the 1985 manual “Orion Guide to Water and Wastewater Analysis,” which contained WeWWG/5880, is no longer available. APPROVED METHODS FOR ORGANIC CHEMICALS Analyses for regulated organic contaminants under the monitoring requirements specified at Sections 141.24 and 141.30 shall be conducted using the following EPA methods or their equivalent as approved by EPA. Other mandatory and optional procedures for conducting these methods are described in Sections IV and V, respectively, of the document. Contaminant Method Benzene 502.2, 524.2 Carbon tetrachloride 502.2, 524.2, 551 Chlorobenzene 502.2, 524.2 1,2-Dichlorobenzene 502.2, 524.2 1,4-Dichlorobenzene 502.2, 524.2 1,2-Dichloroethane 502.2, 524.2 cis-Dichloroethylene 502.2, 524.2 trans-Dichloroethylene 502.2, 524.2 Dichloromethane 502.2, 524.2 1,2-Dichloropropane 502.2, 524.2 Ethylbenzene 502.2, 524.2 Styrene 502.2, 524.2 Tetrachloroethylene 502.2, 524.2, 551 1,1,1-Trichloroethane 502.2, 524.2, 551 Trichloroethylene 502.2, 524.2, 551 Toluene 502.2, 524.2 1,2,4-Trichlorobenzene 502.2, 524.2 1,1-Dichloroethylene 502.2, 524.2 1,1,2-Trichloroethane 502.2, 524.2 Vinyl chloride 502.2, 524.2 Xylenes (total) 502.2, 524.2 2,3,7,8-TCDD (dioxin) 1613 2,4-D 515.2, 555, 515.1 2,4,5-TP (Silvex) 515.2, 555, 515.1 Alachlor 5051, 507, 525.2, 508.1 Atrazine 5051, 506, 525.2, 508.1

8−6

Contaminant Method Benzo(a)pyrene 525.2, 550, 550.1 Carbofuran 531.1, 6610 Chlordane 505, 508, 525.2, 508.1 Dalapon 552.1, 515.1 Di(2-ethylhexy)adipate 506, 525.2 Di(2-ethylhexy)phthalate 506, 525.2 Dibromochloropropane (DBCP) 504.1, 551 Dinoseb 515.2, 555, 515.1 Diquat 549.1 Endothall 548.1 Endrin 505, 508, 525.2, 508.1 Ethylene dibromide (EDB) 504.1, 551 Glyphosate 547, 6651 Heptachlor 505, 508, 525.2, 508.1 Heptachlor Epoxide 505, 508, 525.2, 508.1 Hexachlorobenzene 505, 508, 525.2, 508.1 Hexachlorocyclopentadiene 505, 525.2, 508, 508.1 Lindane 505, 508, 525.2, 508.1 Methoxychlor 505, 508, 525.2, 508.1 Oxamyl 531.1, 6610 PCBs (as decachlorobiphenyl)2 508A

(as Aroclors) 505, 508 Pentachlorophenol 515.2, 525.2, 555, 515.1 Picloram 515.2, 555, 515.1 Simazine 5051, 507, 525.2, 508.1 Toxaphene 505, 508, 525.2 Footnotes 1 A nitrogen-phosphorous detector should be substituted for the electron capture detector in Method 505 (or another approved method should be used) to determine alachlor, atrazine and simazine, if lower detection limits are required. 2 PCBs are qualitatively identified as Aroclors and measured for compliance purposes as decachlorobiphenyl using Method 508A. Methods 502.2, 505, 507, 508, 508A, 515.1 and 531.1 are in Methods for the Determination of Organic Compounds in Drinking Water, EPA-600/4-88-039, December 1988, Revised, July 1991. Methods 506, 547, 550, 550.1 and 551 are in Methods for the Determination of Organic Compounds in Drinking Water - Supplement I, EPA-600-4-90/020, July 1990. Methods 515.2, 524.2, 548.1, 549.1, 552.1 and 555 are in Methods for the Determination of Organic Compounds in Drinking Water - Supplement II, EPA-600/R-92/129, August 1992. Method 1613 is titled, “Tetra-Through Octa-Chlorinated Dioxins and Furans by Isotope Dilution HRGC/HRMS,” EPA-821-B-94-005, October 1994. These documents are available from the National Technical Information Service (NTIS), PB91-231480, PB91-146027, PB92-207703 and PB95-104774, U.S. Department of Commerce, 5285 Port Royal Road, Springfield, Virginia 22161. The toll-free number is (800)553-6487. EPA Methods 504.1,508.1, and 525.2 are available for USEPA EMSL- Cincinnati, Cincinnati, OH 45268. The phone number is (513)569-7856. Method 6651 is contained in the 18th edition of Standard Method for Examination of Water and Wastewater, 1992, and Method 6610 is contained in the Supplement to the 18th Edition of Standard Methods for the Examination of Water and Wastewater, 1994, American Public Health Association, 1015 Fifteenth Street NW, Washington, D.C. 20005.

8−7

APPROVED METHODS FOR UNREGULATED CONTAMINANTS Regulation specified in Section 141.40 require monitoring for certain contaminants to which maximum contaminant levels do not apply. These chemicals are called “unregulated” contaminants, and presently include sulfate, 34 volatile organic chemicals (VOCs) and 13 synthetic organic chemicals (SOCs). 1. Analysis for the 34 unregulated VOC. listed under paragraphs(e) and (j) of Section 141.40 shall be

conducted using the following recommended methods, or their equivalent as determined by EPA.

VOC Contaminants Method Chloroform 502.2, 524.2, 551 Bromodichloromethane 502.2, 524.2, 551 Bromoform 502.2, 524.2, 551 Chlorodibromomethane 502.2, 524.2, 551 Bromobenzene 502.2, 524.2 Bromochloromethane 502.2, 524.2 Bromomethane 502.2, 524.2 n-Butylbenzene 502.2, 524.2 sec-Butylbenzene 502.2, 524.2 tert-Butylbenzene 502.2, 524.2 Chloroethane 502.2, 524.2 0-Chlorotoluene 502.2, 524.2 p-Chlorotoluene 502.2, 524.2 Dibromomethane 502.2, 524.2 M-Dichlorobenzene 502.2, 524.2 Dichlorodifluoromethane 502.2, 524.2 1,1-Dichloroethane 502.2, 524.2 1,3-Dichloropropane 502.2, 524.2 2,2-Dichloropropane 502.2, 524.2 1,1-Dichloropropene 502.2, 524.2 1,3-Dichloropropene 502.2, 524.2 Fluorotrichloromethane 502.2, 524.2 Hexachlorobutadiene 502.2, 524.2 Isopropylbenzene 502.2, 524.2 p-Isopropyltoluene 502.2, 524.2 Napthalene 502.2, 524.2 n-Propylbenzene 502.2, 524.2 1,1,2,2-Tetrachloroethane 502.2, 524.2 1,1,1,2-Tetrachloroethane 502.2, 524.2 1,2,3-Trichlorobenzene 502.2, 524.2 1,2,3-Trichloropropane 502.2, 524.2, 504.1 1,2,4-Trimethylbenzene 502.2, 524.2 1,3,5-Trimethylbenzene 502.2, 524.2

2. Analysis for the 13 unregulated SOCs listed under paragraph (n)(11) of Section 141.40 shall be

conducted using the following recommended methods.

SOC Contaminants Method Aldicarb 531.1, 6610 Aldicarb sulfone 531.1, 6610 Aldicarb sulfoxide 531.1, 6610

8−8

SOC Contaminants Method Aldrin 505, 508, 525.2, 508.1 Butachlor 507, 525.2 Carbaryl 531.1, 6610 Dicamba 515.1, 515.2, 555 Dieldrin 505, 508, 525.2, 508.1 3-Hydroxycarbofuran 531.1, 6610 Methomyl 531.1, 6610 Metolachlor 507, 525.2, 508.1 Metribuzin 507, 525.2, 508.1 Propachlor 508, 525.2, 508.1

Other mandatory and optional procedures for conducting analyses of unregulated VOC. and SOCs are described in Section IV and V, respectively, of this Technical Notes document. Sources for EPA Methods 502.2, 504.1, 505, 507, 508, 508.1, 515.1, 515.2, 524.2, 525.2, 531.1, 551 and Standard Method 6610 are referenced above under methods for organic chemicals.

3. Analysis for the unregulated inorganic contaminant listed under paragraph (n)(12) of Section

141.40 shall be conducted using the following recommended methods.

Analytical Method1 Contaminant EPA ASTM SM

Sulfate 300.0 D4327-91 4110

375.2 D516-90 4500-S04-F 4500-S04-E

Sources for the Standard Methods and ASTM sulfate methods are reference above under methods for inorganic chemicals. The EPA methods are contained in “Methods for the Determination of Inorganic Substances in Environmental Samples,” EPA-600/R-93/100, August 1993, which is available at NTIS, PB94-121811.

APPROVED METHODS FOR FILTRATION AND DISINFECTION 1. Microbiological, pH, and Turbidity Methods

To comply with provisions of the Surface Water Treatment Rule monitoring under Subpart H of 40 CFR Part 141, public water systems must conduct analyses of total coliforms, fecal coliforms, heterotrophic bacteria, turbidity, and temperature in accordance with one of the following analytical methods, and by using mandatory procedures for turbidimeter calibration, which are specified in Section IV of this Technical Notes document. Approved methods for pH are described above under “Methods for Inorganic Contaminants.”

8−9

Organism Methodology Citation1

Total Coliforms2

Total Coliform Fermentation Technique3,4,5

9221A, B, C

Total Coliform Membrane Filter Technique

9222A, B, C

ONPG-MUG Test6

9223

Fecal Coliforms2

Fecal Coliform MPN Procedure7

9221E

Fecal Coliform Membrane Filter Procedure

9222D

Heterotrophic bacteria2

Pour Plate Method

9215B

Turbidity

Nephelometric Method

2130B

Nephelometric Method

180.18

Great Lakes Instruments

Method 29

Temperature

2550

Footnotes 1Except where noted, all methods refer to the 18th edition of Standard Methods for the Examination of Water and Wastewater, 1992, American Public Health Association, 1015 Fifteenth Street NW, Washington D.C, 2005. 2The time from sample collection to initiation of analysis may not exceed 8 hours. 3Lactose broth, as commercially available, may be used in lieu of lauryl tryptose broth, if the systems conducts at least 25 parallel tests between this medium and lauryl tryptose broth using the water normally tested, and this comparison demonstrates that the false-positive rate for total coliforms, using lactose broth, is less than 10%. 4Media should cover inverted tubes at least one-half to two- thirds after the sample is added. 5No requirement exists to run the completed phase on 10 percent of all total coliform-positive confirmed tubes. 6The ONPG-MUG Test is also known as the Autoanalysis Colilert System. 7A-1 Broth may be held up to 3 months in a tightly closed screwcap tube at 4°C. 8"Methods for the Determination of Inorganic Substances in Environmental Samples,” EPA-600/R-93-100, August 1993. Available at NTIS, PB94-121811. 9GLI Method 2, “Turbidity,” November 2, 1992, Great Lakes Instruments, Inc., 8855 North 55th Street, Milwaukee, Wisconsin 53223. 2. Disinfectant Residual Methods

Public water systems must measure residual disinfectant concentrations with one of the analytical methods in the following table. The methods are contained in the 18th edition of Standard Methods. Corrections to SM-4500-Cl-E and 4500-Cl-G, and procedures for conducting continuous measurements of chlorine residuals are described in the Technical Notes in Section IV of this document.

8−10

Residual1 Methodology Methods Free Chlorine2

Amperometric Titration DPD Ferrous Titrimetric DPD Colorimetric Syringaldazine (FACTS)

4500-Cl D 4500-Cl F 4500-Cl G 4500-Cl H

Total Chlorine2

Amperometric Titration Amperometric Titration (low level measurement) DPD Ferrous Titrimetric DPD Colorimetric Iodometric Electrode

4500-Cl D 4500-Cl E 4500-Cl F 4500-Cl G 4500-Cl I

Chlorine Dioxide

Amperometric Titration DPD Method Amperometric Titration

4500-Cl02 C 4500-Cl02 D 4500-Cl02 E

Ozone

Indigo Method 4500-03 B

Footnotes 1If approved by the State, residual disinfectant concentrations for free chlorine and combined chlorine also may be measured by using DPD colorimetric test kits. 2Free and total chlorine residuals may be measure continuously by adapting a specified chlorine residual method for use with a continuous monitoring instrument provided the chemistry, accuracy, and precision of the measurement remain same. Instruments use for continuous monitoring must be calibrated with a grab sample measurement at least every 5 days, or with a protocol approved by the State. RECOMMENDED METHODS FOR SECONDARY DRINKING WATER CONTAMINANTS Analysis of aluminum, chloride, copper, fluoride, foaming agents, iron, manganese, odor, silver, sulfate, total dissolved solids (TDS) and zinc to determine compliance under Section 143.3 may be conducted with the methods in the following Table. Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other mandatory procedures are contained in the Technical Notes in Section IV of this document. Measurement of pH may be conducted with one of the methods listed above in Section I under “Methods for Inorganic Chemicals.” Contaminant EPA ASTM1 SM2 Other Aluminum 200.73 3120B

200.83 3113B 200.93 3111D

Chloride 300.04 D4327-91 4110

4500-Cl-D Color 2120B Copper 200.73 D1688-90A 3120B

200.83 D1688-90C 3111B 200.93 3113B

8−11

Contaminant EPA ASTM1 SM2 Other Fluoride 300.04 D4327-91 4110 129-71W5

D1179-93A 4500F-B,D 380-75WE5 D1179-93B 4500F-C

4500F-E Foaming Agents 5540C Iron 200.73 3120B

200.93 3111B 3113B

Manganese 200.73 3120B

200.83 3111B 200.93 3113B

Odor 2150B Silver 200.73 3120B I-3720-856

200.83 3111B 200.93 3113B

Sulfate 300.04 D4327-91 4110

375.24 4500-S04-F 4500-S04-C,D

TDS 3120C Zinc 200.73 3120B

200.83 3111B Footnotes 1Annual Book of ASTM Standards, Vols. 11.01 and 11.02, American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103. 218th edition of Standard Methods for the Examination of Water and Wastewater, 1992, American Public Health Association, 1015 Fifteenth Street NW, Washington, D.C. 20005. 3“Methods for the Determination of Metals in Environmental Samples - Supplement I,” EPA-600/R-94-111, May 1994. Available at NTIS, PB94-184942. 4“Methods for the Determination of Inorganic Substances in Environmental Samples,” EPA-600/R-93-100, August 1993. Available at NTIS, PB94-121811. 5Industrial Method No. 129-71W, “Fluoride in Water and Wastewater,” December 1972, and Method No. 380-75WE, “Fluoride in Water and Wastewater,” February 1976, Technicon Industrial Systems, Tarrytown, NY 0591. 6Available from Books and Open-File Reports Section, U.S. Geological Survey, Federal Center, Box 25425, Denver, CO 80225-0425.

8−12

APPROVED METHODS FOR TRIHALOMETHANES AND HALOACETIC ACIDS Sampling and analyses for trihalomethanes and haloacetic acids shall be conducted by one of the following EPA approved methods:

Contaminant Methodology Methods TTHM (Sum of chloroform, bromochloromethane dibromochloromethane bromoform) ,

EPA 502.2 EPA 524.2 EPA 551.1

HAA5 (Sum of monochloroacetic acid dichloroacetic acid trichloroacetic acid monobromoacetic acid diibromoacetic acid)

EPA 552.1

EPA 552.2 SM 6251B

APPROVED METHODS FOR RADIOACTIVITY (40 C.F.R. 141.25(a)) Sampling and analyses for radioactivity shall be conducted by one of the following EPA approved methods: (1) Gross Alpha and Beta -- Method 302 “Gross Alpha and Beta Radioactivity in Water” Standard

Methods for the Examination of Water and Wastewater, 13th Edition, American Public Health Association, New York, N.Y., 1971.

(2) Total Radium -- Method 304 “Radium in Water by Precipitation” Ibid. (3) Radium 226 -- Method 305 “Radium-226 by Radon in Water” Ibid. (4) Strontium-89,90 -- Method 303 “Total Strontium and Strontium-90 in Water” Ibid. (5) Tritium -- Method 306 “Tritium in Water” Ibid. (6) Cesium-134 -- ASTM D-2459 “Gamma Spectrometry in Water,” 1975 Annual Book of ASTM

Standards, Water and Atmospheric Analysis, Part 31, American Society for Testing and Materials, Philadelphia, PA. (1975)

(7) Uranium -- ASTM D-2907 “Microquantities of Uranium in Water by Fluorometry,” Ibid.

U.S. EPA’s Methods and Minimum Detection Limits List taken from the 2007 version of 40 CFR 141.23 to 141.25

Note: These detection limits are for your information. They are U.S. EPA’s Minimum Detection Limits, codified at 40 CFR 141.23-141.25. Your state may have different detection limits that take precedence. If you are uncertain about the inclusion of certain data, talk to your primacy agency. Some contaminants, such as lead and copper, are not listed below. If you cannot find a contaminant listed below and your lab analysis provides a detected value for that contaminants, report it in your CCR. If you are uncertain, always provide too much data rather than too little.

Contaminant Method Detection limit (mg/L) Inorganic Contaminants [40 CFR 141.23(a)(4)]

Atomic Absorption; Furnace 0.003 Atomic Absorption; Platform 0.0008 ICP-Mass Spectrometry 0.0004

Antimony

Hydride-Atomic Adsorption 0.001 Atomic Absorption; Furnace 0.001 Atomic Absorption; Platform-Stabilized Temperature

0.0005

Atomic Absorption; Gaseous Hydride 0.001

Arsenic

ICP-Mass Spectrometry 0.0014 Asbestos Transmission Electron Microscopy 0.01 MFL

Atomic Adsorption; furnace technique 0.002 Atomic Adsorption; direct aspiration 0.1

Barium

Inductively Coupled Plasma 0.002 (0.001) Atomic Adsorption; Furnace 0.0002 Atomic Adsorption; Platform 0.00002

Beryllium

Inductively Coupled Plasma 0.0003

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(s), report it in your CCR. If you are uncertain, always provide

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too much data rather than too little.

Contaminant Method Detection limit (mg/L) ICP-Mass Spectrometry 0.0003 Atomic Adsorption; furnace technique 0.0001 Cadmium Inductively Coupled Plasma 0.0001 Atomic Adsorption; furnace technique 0.001 Chromium Inductively Coupled Plasma 0.007 (0.001) Distillation, Spectrophotometric 0.02 Distillation, Automated, Spectrophotometric 0.005 Distillation, Selective Electrode 0.05 Distillation, Amenable, Spectrophotometric 0.02 UV, Distillation, Spectophotometric 0.0005 Micro Distillation, Flow Injection, Spectrophometric

0.0006

Cyanide

Ligand Exchange with Amperometry 0.0005 Manual Cold Vapor Technique 0.0002 Mercury Automated Cold Vapor Technique 0.0002 Atomic Absorption; Furnace 0.001 Atomic Absorption; Platform 0.0006 Inductively Coupled Plasma 0.005

Nickel

ICP-Mass Spectrometry 0.0005 Manual Cadmium Reduction 0.01 Automated Hydrazine Reduction 0.01 Automated Cadmium Reduction 0.05 Ion Selective Electrode 1

Nitrate

Ion Chromatography 0.01

Contaminant Method Detection limit (mg/L) Capillary Ion Electrophoresis 0.076 Spectrophotometric 0.01 Automated Cadmium Reduction 0.05 Manual Cadmium Reduction 0.01 Ion Chromatography 0.004

Nitrite

Capillary Ion Electrophoresis 0.103 Atomic Absorption; furnace 0.002 Selenium Atomic Absorption; gaseous hydride 0.002 Atomic Absorption; Furnace 0.001 Atomic Absorption; Platform 0.0007

Thallium

ICP-Mass Spectrometry 0.0003 Volatile Organic Contaminants [40 CFR 141.24] Benzene 502.2; 524.2 0.0005 Carbon tetrachloride 502.2; 524.2; 551.1 0.0005 Chlorobenzene 502.2; 524.2 0.0005 1,2-Dichlorobenzene 502.2; 524.2 0.0005 1,4-Dichlorobenzene 502.2; 524.2 0.0005 1,2-Dichloroethane 502.2; 524.2 0.0005 1,1-Dichloroethylene 502.2; 524.2 0.0005 cis-Dichloroethylene 502.2; 524.2 0.0005 trans-Dichloroethylene 502.2; 524.2 0.0005 Dichloromethane 502.2; 524.2 0.0005 1,2-Dichloropropane 502.2; 524.2 0.0005 Ethylbenzene 502.2; 524.2 0.0005

Contaminant Method Detection limit (mg/L) Styrene 502.2; 524.2 0.0005 Tetrachloroethylene 502.2; 524.2; 551.1 0.0005 1,1,1-Trichloroethane 502.2; 524.2; 551.1 0.0005 Trichloroethylene 502.2; 524.2; 551.1 0.0005 Toluene 502.2; 524.2 0.0005 1,2,4-Trichlorobenzene 502.2; 524.2 0.0005 1,1,2-Trichloroethane 502.2; 524.2; 551.1 0.0005 Vinyl chloride 502.2; 524.2 0.0005 Xylenes (total) 502.2; 524.2 0.0005 Sythentic Organize Contaminents and Herbicides [40 CFR141.24] 2,3,7,8-TCDD (Dioxin) 1613 0.000000005 2,4-D (as acids, salts, and esters) 515.2; 555; 515.1; 515.3; 515.4 0.0001 2,4,5-TP (Silvex) 515.2; 555; 515.1; 515.3; 515.4 0.0002 Alachlor 505; 507; 525.2; 508.1; 551.1 0.0002 Aldicarb 531.1; 6610 .0005 Aldicarb sulfoxide 531.1; 6610 .0005 Aldicarb sulfone 531.1; 6610 .0008 Atrazine 505; 507; 525.2; 508.1; 551.1 0.0001 Benzo(a)pyrene 525.5; 550; 550.1 0.00002 Carbofuran 531.1; 531.2; 6610 0.0009 Chlordane 505; 508; 525.2; 508.1 0.0002 Dalapon 552.1; 515.1; 515.3; 515.4; 552.2; 552.3 0.001 Di(2-thylhexyl) adipate 506; 525.2 0.0006 Di(2-ethylhexyl) phthalate 506; 525.2 0.0006

Contaminant Method Detection limit (mg/L) Dibromo-chloropropane (DBCP) 504.1; 551 0.00002 Dinoseb 515.2; 555; 515.1; 515.3; 515.4 0.0002 Diquat 549.2 0.0004 Endothall 548.1 0.009 Endrin 505; 508; 525.2; 508.1; 515.1 0.00001 Ethylene dibromide (EDB) 504.1; 551 0.00001 Glyphosate 547; 6651 0.006 Heptachlor 505; 508; 525.2; 508.1; 551.1 0.00004 Heptaclor epoxide 505; 508; 525.2; 508.1; 551.1 0.00002 Hexachlorobenzene 505; 508; 525.2; 508.1; 551.1 0.0001 Hexachlorocyclopentadiene 505; 525.2; 508; 508.1; 551.1 0.0001 Lindane 505; 508; 525.2; 508.1; 551.1 0.00002 Methoxyclor 505; 508; 525.2; 508.1; 551.1 0.0001 Oxamyl 531.1; 531.2; 6610 0.002 Polychlorindated biphenyls (PCBs) (as decachlorophenyl)

508A 0.0001

Pentachlorophenol 515.2; 525.2; 555; 515.1; 515.3; 515.4 0.00004 Picloram 515.2; 555; 515.1; 515.3; 515.4 0.0001 Simazine 505; 507; 525.2; 508.1; 515.1 0.00007 Toxaphene 505; 508; 525.2; 508.1 0.001 Radioactive Contaminants [40 CFR141.25] Gross alpha particle activity Co-precipitation 3 pCi/L Radium 226 Radio emanation; radiochemical 1 pCi/L Radium 228 Radiochemical 1 pCi/L

Contaminant Method Detection limit (mg/L) Uranium Radiochemical; fluorometric; ICP-MS; alpha

spectrometry; laser phosphorimetry 1 μg/L

Tritium Liquid Scintillation 1,000 pCi/L Strontium-89 Radiochemical 10 pCi/L Strontium-90 Radiochemical 2 pCi/L Iodine-131 Radiochemical; gamma ray spectrometry 1 pCi/L Cesium-134 Radiochemical; gamma ray spectrometry 10 pCi/L Gross beta Evaporation 4 pCi/L Other radionuclides 1/10 of the applicable limit

5/2/2017

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SAMPLE INVALIDATION OR REJECTION

CHEMISTRYLab will invalidate samples when:● QC checks are not acceptable (ie., out of

control % recoveries).● Samples may be contaminated (vial, poor

sampling,...)● Obtain detections that have never been seen

before. (May void and request new sample.)● Samples exceeded acceptable holding time

before analysis.

SAMPLE INVALIDATION OR REJECTION

CHEMISTRYLab will invalidate samples when:● Samples received at lab warm or not properly

cooled.● COC form has not been properly/completely

fill d t tl fill d t i ilfilled out correctly – filled out in pencil, cross outs are not initialed and dated. No signature for change of custody, incompleted form, etc …

DRINKING WATER CHEMICAL COMPLIANCE MONITORING/SAMPLING

SAMPLES FOR ANALYSIS BY THE DOH LAB

USING THE SAMPLE COLLECTION &&

RESERVATION SYSTEM (SCRS)

5/2/2017

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USING THE SAMPLE COLLECTION & RESERVATION SYSTEM (SCRS)

CHEMICAL COMPLIANCE SAMPLING

▪ Determining Chemical Compliance Monitoring/Sampling Required

▪ Scheduling Chemical Compliance Samples

▪ Printing Chain of Custody Forms

▪ Reviewing Sample Status and ResultsReviewing Sample Status and Results

▪ Sampling Resources (Sample Collection Instructions)

5/2/2017

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COMPUTER DEMONSTRATION

▪ SCHEDULING SAMPLES ON SCRS

▪ PRINTING CHAIN OF CUSTODY FORMS


CHEMICAL SAMPLES FOR ANALYSIS BY THE DOH LAB

OBTAINING SAMPLING MATERIALS:

The SDWB will automatically send water purveyors enough sampling supplies (coolers, blue ice, bottles, labels, sample preservatives, …) after water systems have scheduled their sampling.

Should you need additional sampling supplies, due to use of your supply for special sampling or repeat samples due to a detected positive result, please contact the SDWB – Monitoring Section.

You must have a courier account (such as FedEx), which the SDWB will charge for shipping.

SAMPLECOLLECTION

andDOCUMENTATION

CARBAMATE SAMPLING This sample uses a clear vial with no lettering on the cap and a small amount of liquid acid preservative (PLEASE DO NOT USE A CLEAR SAMPLING VIAL WITH "6N SOC HCL" LETTERING ON THE CAP). The clear vial with no lettering on the cap contains a liquid acid preservative, so be careful not to spill it on yourself.

Fill the clear vial to 3/4 full with your water sample.

Add a half a scoop of the sodium thiosulfate to each of the ¾ full vials using the small plastic scooper.

Fill the rest of the vial to the rim (FORMING A MENISCUS) with your water sample.

Place the cap on the vial being sure that the septa is teflon-side down (towards the sample). Avoid trapping air bubbles within the vial.

Check vial to ensure that there are no air bubbles trapped in the vial.

CARBAMATESCARBAMATES

EDB/DBCP/TCP SAMPLING This sample uses TWO clear vials.

Add a half a scoop of the sodium thiosulfate to each of the vials using the small plastic scooper.

Fill both of the clear vials to the rim (forming a meniscus) with your water sample.

Place the caps on both vials being sure that the septa is teflon-lined side down (towards the sample). Avoid trapping air bubbles within the vials.

Check to ensure that there are no air bubbles trapped in the vials.

EDB/DBCP/TCPEDB/DBCP/TCP

GLYPHOSATE SAMPLING

This sample uses ONE amber vial.

Add one small grain of the sodium thiosulfate to the vial using the small plastic scooper.

Fill the amber vial to the rim (forming a meniscus) with your water sample.

Place the caps on the vial being sure that the septa is teflon-lined sidedown (towards the sample). Avoid trapping air bubbles within the vials.

Check vial to ensure that there are no air bubbles trapped in thevial

GLYPHOSATEGLYPHOSATE

HERBICIDE (CHLORINATED ACIDS) SAMPLING

This sample uses TWO amber vials, the vials should have stickers attached to the cap saying “HERB”. Sodium thiosulfate has been pre-added to the vials by the laboratory.

Fill both of the clear vials to the rim (forming a meniscus) with your water sample.


Check vials to ensure that there are no air bubbles trapped in thevials.

Try to make sure the "HERB" stickers stay attached to the vial caps.

CHLORINATED ACIDS(HERBICIDES)

INORGANIC METALS SAMPLING

This sample uses one 500ml plastic bottle. The bottle may look like one of the bottles shown at the right. No preservative is added to the sample.

Fill the plastic bottle to the rim with your water sample.

Place the cap on the bottle.

INORGANICS(METALS)

INORGANIC (ANIONS - NITRATE) SAMPLING

This sample uses a 125ml plastic bottle. No preservative is added to the sample.

Rinse out the plastic bottle and the cap 3 times with the water you are sampling.

Fill the plastic bottle to the rim with your water sample.

Place the cap on the bottle.

INORGANICS(ANIONS)

SYNTHETIC ORGANIC CHEMICALS (SOC8) SAMPLING This sample uses an amber liter bottle and a clear vial with "6N SOC HCL" on the cap (PLEASE DO NOT USE A CLEAR VIAL WITH NO LETTERING ON THE CAP). Sodium Sulfite has been pre-added to the amber liter bottle. The vial with "6N SOC HCL" lettering on the cap contains a liquid acid preservative, so be careful not to spill it on yourself.

Fill the amber liter bottle to 3/4 full with your water sample, cap and mix the sodium sulfite with your sample.

Pour the contents of the vial with "6N SOC HCL" lettering on the cap into the amber liter bottle.

Fill the rest of the amber liter bottle to the rim with your water sample. Place the cap on the amber liter bottle.

Rinse out the vial that you poured into the amber liter bottle and return with your sample.

SYNTHETIC ORGANICS(SOC)

VOLATILE ORGANIC CHEMICALS (VOC) SAMPLING This sample uses TWO amber vials with a VOC label on the caps. These 2 vials already contain a powder acid preservative so be careful not to spill it on yourself. This sample also uses another type of acid in a small squeeze bottle labeled “1:1 HCL”. DO NOT ADD THIS “1:1 HCL” ACID TO THE 2 VIALS UNTIL YOU HAVE READ THE NEXT STEP BELOW. ADDING IT NOW WILL INVALIDATE YOUR SAMPLES.

Fill both of the amber vials with your water sample until the water is close to the rim of the vials. Use the “1:1 HCL” squeeze bottle to add 2 drops of the acid (be careful not to spill it on yourself) to each of the amber vials.

Carefully fill the rest of the amber vials to the rim with your water sample forming a meniscus at to the top.

Place the caps on the vials being sure that the septa is teflon-lined side down (towards the sample). Avoid trapping air bubbles within the vials. Try to make sure that the VOC labels stay attached to the vial caps.


VOC

TRIHALOMETHANES (THM) SAMPLING This sample uses TWO amber vials.

Add a half a scoop of the sodium thiosulfate to each of the vials using the small plastic scooper.

Fill both of the amber vials to the rim (forming a meniscus) with your water sample.

Place the caps on the vials being sure that the septa is teflon-lined side down (towards the sample). Avoid trapping air bubbles within the vials.


THMsTHMs

HALOACETIC ACID (HAA) SAMPLING This sample uses TWO amber vials, the vials should have stickers attached to the cap saying “HAA”. Sodium thiosulfate has been pre-added to the vials by the laboratory.

Fill both of the amber vials to the rim (forming a meniscus) with your water sample.



Try to make sure the "HAA" stickers stay attached to the vial caps.

HAA5HAA5

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For each Chemistry/DBP sample that has an SCRS ID, the Sampler needs to write in the same SCRS ID on this line of the label.

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Typewritten Text

For each sample, the Sampler needs to write in the corresponding Sample Date and Time on this line of the label.

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For each sample, the Sampler needs to write in (print) his/her name on this line label.

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For each Chemistry/DBP sample collected that has an SCRS ID, the Sampler needs to circle the corresponding 3 letter heading on the label. Note: The "HER" designation on the label is the same as the "CHL-Chlorinated Acids" designation on the Chain of Custody form.

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SAMPLER

Relinquished by Sampler:

Received by:

Relinquished by:

Received by:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Method of Shipping:

Delivered to Lab by:

Date/Time:

Delivered to Courier (Fedex/UPS/Other) by:

[FEDEX] [UPS] [Other]

Date/Time:

Received by:

Relinquished by: Date/Time:

Date/Time:

LABORATORY Use Only

Received in Laboratory by:

Sample Temperature on Receipt at Laboratory:

Samples Received Day Of Collection OR T<6ºC:

Date/Time:

Cooler #

[Yes] [No] [Yes] [No][Yes] [No][Yes] [No]

Cooler # Cooler # Cooler #



Cooler #



Samples Checked Against COC by:

Sampler Signature:

331-HNL-WINDWARD-PEARL HARBORWater System:□ Non-Compliance Sample

Erwin Kawata

Page 1 of 1331-1304-001COC ID:

Sampler Name:

Sample Date: 5/8/2013Sample Point ID: 331-212Facility: TP001 - KALIHI SHAFT CHLORINATOR

Sample Point Location:

KALIHI SHFT CHLOR,HB OFF BOOSTR PMP PIPE

Sample Time:

Chlorine Residual [Free] [Total] [Free] [Total] [Free] [Total]NIT - Nitrate & Anions (1 bottle/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

GLY - Glyphosate (1 vial/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

CAR - Carbamate Pestacides(1 vial/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

EDB/DBCP/TCP (2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SOC - Synthetic Org. Chemicals(1 bottle/sample)

SCRS ID: 331-212-1304-001(+Dup)

Cooler #/SATS ID:

SCRS ID: (+Dup)

Cooler #/SATS ID:

SCRS ID: (+Dup)

Cooler #/SATS ID:

CHL - Chlorinated Acids(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

HAA5 (DBP) - Haloacetic Acids(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

THM (DBP)-Trihalomethane(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

VOC - Volatile Org. Compounds (2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

INO - Inorganic Chemicals/Metals (1 bottle/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

Sampler Comments:

Lab Comments:

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Sampler needs to sign here.

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#1 - If the sampler who collected the sample(s) is able to deliver the sample(s) to the Courier, he/she does not need to sign off on line #1, but must sign off on the "Delivered to Courier by:" line #5 when reaching the Courier. If the sampler is not able to deliver the sample(s) to the Courier, he/she must sign off on line #1 and read #2 below. #2 - The person receiving the sample(s) from the sampler from line #1 above must sign off on line #2. If the person from line #2 is going to deliver the sample(s) to the Courier, then he/she must also sign off on the "Delivered to Courier by:" line #5 when reaching the Courier. If the person from line #2 is unable to deliver the sample(s) to the Courier, then he/she must sign off on line #3 and read #4 below. #4 -The person receiving the sample(s) from the person from line #3 must sign off on line #4, then he/she must also sign off on the "Delivered to Courier by:" line #5 when reaching the Courier.

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For each Sample Point Location you are sampling at (in this case - KALIHI SHFT CHLOR, HB OFF BOOSTR PMP PIPE) you will need to write in the Sample Time, the Chlorine Residual, and circle whether it's a Free or Total Chlorine reading when collecting your samples.

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Each cell that has a corresponding SCRS ID number, means that you will be collecting that corresponding Chemistry parameter (in this case - SOC) at that corresponding Sample Point Location (in this case - KALIHI SHFT CHLOR, HB OFF BOOSTR PMP PIPE). After you have collected all your samples, for each sample on the Chain of Custody form you will need to write in the "Cooler #" that the corresponding sample will be delivered to the lab in. The sampling coolers that you receive from SDWB have a "Cooler #" written in black ink on the top right hand corner of the cooler lid. The "Cooler #" will either start with a "L" or an "S" and will be followed by a number (example - L1 or S1). It is this number that you need to write in the "Cooler #" box (example L1) to verify which cooler your sample(s) are located in.

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Also for SOC sampling, SDWB may send you and extra bottle and request that you collect an extra "Duplicate" sample for Laboratory purposes. If you are sampling for SOC from just 1 Sample Point Location, please collect a "Duplicate" sample and circle the (+Dup) for the corresponding "Duplicate" SOC sample on the Chain of Custody form (also write "Duplicate" on the sample label for this sample). If you are sampling for SOC from more than 1 Sample Point Location, you can collect a "Duplicate" SOC from any one of the Sample Point Locations, but make sure you circle the (+Dup) for the corresponding "Duplicate" SOC sample on the Chain of Custody form (also write "Duplicate" on the sample label for this sample).

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#1

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#2

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#3

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#4

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#5

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SAMPLER

Relinquished by Sampler:

Received by:

Relinquished by:

Received by:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Method of Shipping:

Delivered to Lab by:

Date/Time:

Delivered to Courier (Fedex/UPS/Other) by:

[FEDEX] [UPS] [Other]

Date/Time:

Received by:

Relinquished by: Date/Time:

Date/Time:

LABORATORY Use Only




Date/Time:

Cooler #





Cooler #




Sampler Signature:

331-HNL-WINDWARD-PEARL HARBORWater System:□ Non-Compliance Sample

Erwin Kawata

Page 1 of 1331-1304-001COC ID:

Sampler Name:

Sample Date: 5/8/2013Sample Point ID: 331-212Facility: TP001 - KALIHI SHAFT CHLORINATOR

Sample Point Location:

KALIHI SHFT CHLOR,HB OFF BOOSTR PMP PIPE

Sample Time:

Chlorine Residual [Free] [Total] [Free] [Total] [Free] [Total]NIT - Nitrate & Anions (1 bottle/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

GLY - Glyphosate (1 vial/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

CAR - Carbamate Pestacides(1 vial/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

EDB/DBCP/TCP (2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SOC - Synthetic Org. Chemicals(1 bottle/sample)

SCRS ID: 331-212-1304-001(+Dup)

Cooler #/SATS ID:

SCRS ID: (+Dup)

Cooler #/SATS ID:

SCRS ID: (+Dup)

Cooler #/SATS ID:

CHL - Chlorinated Acids(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

HAA5 (DBP) - Haloacetic Acids(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

THM (DBP)-Trihalomethane(2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

VOC - Volatile Org. Compounds (2 vials/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

INO - Inorganic Chemicals/Metals (1 bottle/sample)

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

SCRS ID:

Cooler #/SATS ID:

Sampler Comments:

Lab Comments:

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Sampler needs to sign here.

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#1 - If the sampler who collected the sample(s) is able to deliver the sample(s) to the State Laboratory, he/she does not need to sign off on line #1, but must sign off on the "Delivered to Lab by:" line #5 when reaching the State Laboratory. If the sampler is not able to deliver the sample(s) to the State Laboratory, he/she must sign off on line #1 and read #2 below. #2 - The person receiving the sample(s) from the sampler from line #1 above must sign off on line #2. If the person from line #2 is going to deliver the sample(s) to the State Laboratory, then he/she must also sign off on the "Delivered to Lab by:" line #5 when reaching the State Laboratory. If the person from line #2 is unable to deliver the sample(s) to the State Laboratory then he/she must sign off on line #3 and read #4 below. #4 -The person receiving the sample(s) from the person from line #3 must sign off on line #4, then he/she must also sign off on the "Delivered to Lab by:" line #5 when reaching the State Laboratory.

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For each Sample Point Location you are sampling at (in this case - KALIHI SHFT CHLOR, HB OFF BOOSTR PMP PIPE) you will need to write in the Sample Time, the Chlorine Residual, and circle whether it's a Free or Total Chlorine reading when collecting your samples.

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Each cell that has a corresponding SCRS ID number, means that you will be collecting that corresponding Chemistry parameter (in this case - SOC) at that corresponding Sample Point Location (in this case - KALIHI SHFT CHLOR, HB OFF BOOSTR PMP PIPE). After you have collected all your samples, for each sample on the Chain of Custody form you will need to write in the "Cooler #" that the corresponding sample will be delivered to the lab in. The sampling coolers that you receive from SDWB have a "Cooler #" written in black ink on the top right hand corner of the cooler lid. The "Cooler #" will either start with a "L" or an "S" and will be followed by a number (example - L1 or S1). It is this number that you need to write in the "Cooler #" box (example L1) to verify which cooler your sample(s) are located in.

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Also for SOC sampling, SDWB may send you and extra bottle and request that you collect an extra "Duplicate" sample for Laboratory purposes. If you are sampling for SOC from just 1 Sample Point Location, please collect a "Duplicate" sample and circle the (+Dup) for the corresponding "Duplicate" SOC sample on the Chain of Custody form (also write "Duplicate" on the sample label for this sample). If you are sampling for SOC from more than 1 Sample Point Location, you can collect a "Duplicate" SOC from any one of the Sample Point Locations, but make sure you circle the (+Dup) for the corresponding "Duplicate" SOC sample on the Chain of Custody form (also write "Duplicate" on the sample label for this sample).

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For each Lead/Copper sample, the Sampler needs to write in the corresponding SCRS ID/SATS ID on this line of the label.

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For each Lead/Copper sample, the Sampler needs to write in the corresponding Sample Collection Date and Time on this line of the label.

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For each Lead/Copper sample, the Sampler needs to write in (print) his/her name on this line of the label.

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For each Lead/Copper sample, the Sampler needs to circle the LC heading on the label.

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SAMPLER

Received by Sample Collector:

Received by:

Relinquished by Sample Collector:

LABORATORY USE ONLY

Relinquished by:

Received by:

Method of Shipping: [FEDEX] [UPS] [Other]

Date/Time: <See Below>

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:



Samples Logged into SATS by:Delivered to Courier (Fedex/UPS/Other) by:

Received by:

Relinquished by:

Delivered to Laboratory by:

Date/Time:

133-KUKUIHAELE

Sample Collector's Signature:

□ Non-Compliance Sample Flushed SampleMae Kise

First DrawPage 1 of 2133-1304-001COC ID:

Sampler Name:

Water System:

SCRS ID / SATS IDSamplePoint ID

Sample PointLocation

SampleCollection

Date

SampleCollection

Time

DateReceived

From

TimeReceived

From

Cold WaterTap in Kitchenor Bathroom?

WaterPurification

Device Installed? Sampler Comments(Laboratory Use Only)Laboratory Comments

133-LC001-1305-001 LC001 47-4588 WAIPIO RD.

5/2/2013 Yes No Yes No

133-LC005-1305-001 LC005 47-4614 HONOKAA-WAIPIO RD.






133-LC009-1305-001 LC009 47-4726B HONOKAA-WAIPIO RD




133-LC012-1305-001 LC012 48-5172 HONOKAA-WAIPIO RD


133-LC016-1305-001 LC016 48-5364 GOVT. MAIN RD.


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#1 - Sampler needs to sign off on line #1 and then read #2 below. . #2 - If the sampler is able to deliver the sample(s) to the Courier, he/she does not need to sign off on line #2, but must sign off on the "Delivered to Courier by:" line #6 when reaching the Courier. If the sampler is not able to deliver the sample(s) to the Courier, he/she must sign off on line #2 and read #3 below. . #3 - The person receiving the sample(s) from the sampler from line #2 above must sign off on line #3. If the person from line #3 is going to deliver the sample(s) to the Courier, then he/she must also sign off on the "Delivered to Courier by:" line #6 when reaching the Courier. If the person from line #3 is unable to deliver the sample(s) to the Courier, then he/she must sign off on line #4 and read #5 below. . #5 -The person receiving the sample(s) from the person from line #4 must sign off on line #5, then he/she must also sign off on the "Delivered to Courier by:" line #6 when reaching the Courier.

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For each Lead and Copper sample, you need to fill in the following: the "Sample Collection Date" and the "Sample Collection Time" that the homeowner has written down on their Lead and Copper sample collection sheet; fill in the "Time Received From" with the time that you received the Lead and Copper sample from the homeowner; circle the homeowners "Yes" or "No" responses that they circled on their Lead and Copper sample collection sheet.

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SAMPLER

Received by Sample Collector:

Received by:

Relinquished by Sample Collector:

LABORATORY USE ONLY

Relinquished by:

Received by:

Method of Shipping: [FEDEX] [UPS] [Other]

Date/Time: <See Below>

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:

Date/Time:



Samples Logged into SATS by:Delivered to Courier (Fedex/UPS/Other) by:

Received by:

Relinquished by:

Delivered to Laboratory by:

Date/Time:

133-KUKUIHAELE

Sample Collector's Signature:

□ Non-Compliance Sample Flushed SampleMae Kise

First DrawPage 1 of 2133-1304-001COC ID:

Sampler Name:

Water System:

SCRS ID / SATS IDSamplePoint ID

Sample PointLocation

SampleCollection

Date

SampleCollection

Time

DateReceived

From

TimeReceived

From

Cold WaterTap in Kitchenor Bathroom?

WaterPurification

Device Installed? Sampler Comments(Laboratory Use Only)Laboratory Comments

133-LC001-1305-001 LC001 47-4588 WAIPIO RD.








133-LC009-1305-001 LC009 47-4726B HONOKAA-WAIPIO RD




133-LC012-1305-001 LC012 48-5172 HONOKAA-WAIPIO RD


133-LC016-1305-001 LC016 48-5364 GOVT. MAIN RD.


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#1 - Sampler needs to sign off on line #1 and then read #2 below. . #2 - If the sampler is able to deliver the sample(s) to the State Laboratory, he/she does not need to sign off on line #2, but must sign off on the "Delivered to Laboratory by:" line #6 when reaching the State Laboratory. If the sampler is not able to deliver the sample(s) to the State Laboratory, he/she must sign off on line #2 and read #3 below. . #3 - The person receiving the sample(s) from the sampler from line #2 above must sign off on line #3. If the person from line #3 is going to deliver the sample(s) to the State Laboratory, then he/she must also sign off on the "Delivered to Laboratory by:" line #6 when reaching the State Laboratory. If the person from line #3 is unable to deliver the sample(s) to the State Laboratory then he/she must sign off on line #4 and read #5 below. . #5 -The person receiving the sample(s) from the person from line #4 must sign off on line #5, then he/she must also sign off on the "Delivered to Laboratory by:" line #6 when reaching the State Laboratory.

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For each Lead and Copper sample, you need to fill in the following: the "Sample Collection Date" and the "Sample Collection Time" that the homeowner has written down on their Lead and Copper sample collection sheet; fill in the "Time Received From" with the time that you received the Lead and Copper sample from the homeowner; circle the homeowners "Yes" or "No" responses that they circled on their Lead and Copper sample collection sheet.

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SAMPLEPACKING

andTRANSPORT



SAMPLE PACKING and TRANSPORT

▪ PACKING SAMPLES TO ENSURE PROPER TEMPERATURE

▪ TRANSPORTING SAMPLES TO MEET TEMPERATURE AND

HOLDING TIME REQUIREMENTS

14

SAMPLE STORAGE AND PACKAGING

Should comply with general requirements of 49 Code of Federal Regulations 173.24(a).

1. Limit sample volume to amount required by lab.

2. Use Plastic or Glass specified by the analytical method and sample collection details.

3. Use screw-type lids/covers – avoid stoppers, corks or other friction-type closures.

4. Provide suitable cushioning for all glass containers and protect plastic ones from punctures by sharp objects.

5. Use ice substitute or ice in sealed plastic bags.

6. Secure in sturdy shipping containers.

15

SAMPLE TRANSPORT

▪ Sturdy Shipping Containers ▪ Bottle labels

- waterproof ink- legible

▪ Coolant - wet ice – not usually used- blue ice- dry ice – not usually used (may freeze sample & shipping restrictions

▪ Insulation- maintain 4oC- prevent breakage

▪ Custodiy Seals- Prevent tampering- maintain integrity of shipping

▪ Length of Time in Transit- holding time

▪ Transport/Carriers- schedule (pick-up, and drop off)- documentation (shipping label, airbill, special labels)- DOT regulations

1

ASK COURIER/SHIPPER WHEN SAMPLES WILL BE PICKED UP OR WHEN SAMPLES MUST BE DROPPED OFF. This will assist you in determining when you need to collect your sample, and when to pack your samples for shipping (you do not want to pack the samples too early).

SAMPLES NEED TO BE DELIVERED TO THE DOH LABORATORY BEFORE 4:00pm THE NEXT/FOLLOWING DAY. Please be aware of the sample temperature and the holding time requirements. Lab procedures that they check the temperature inside the cooler and that the temperature is within the acceptable range or 2 to 6 degrees Celsius. Samples may be rejected by the Lab if it is not within the temperature range or the sample exceeds the holding time.

2

BE SURE TO FREEZE YOUR BLUE ICE AS SOON AS YOU RECEIVE YOUR SAMPLING SUPPLIES OR AT LEAST 72 HOURS PRIOR TO SAMPLING. PARTITIALLY FROZEN BLUE ICE WILL BE INSUFFICIENT TO COOL THE SAMPLES TO THE REQUIRED TEMPERATURE.

WHEN PACKING THE SAMPLES, BE SURE THAT THE BLUE ICE IS COMPLETELY FROZEN TO ENSURE THAT IT WILL BE COLD ENOUGH TO KEEP THE SAMPLE AT THE REQUIRED TEMPERATURE WHEN IT REACHES THE LABORATORY.

SAMPLES THAT ARE NOT WITHIN THE REQUIRED TEMPERATURE RANGE WILL BE REJECTED BY THE LABORATORY REQUIRING THAT YOU RESAMPLE.

3

AVOID PLACING THE BLUE ICE ON THE BOTTOM OF THE COOLER AND SETTING YOUR SAMPLES ON TOP OF THE BLUE ICE. THE DIRECT CONTACT WITH THE BLUE ICE MAY CAUSE THE SAMPLE TO FREEZE OR THE BOTTLE TO BREAK.

WHEN PACKING THE VIALS AND BOTTLES, BE SURE TO USE THE VIAL HOLDERS AND BOTTLE RACK TO HOLD YOUR SAMPLES. THIS WILL HELD TO PREVENT DIRECT CONTACT OF THE BLUE ICE WITH THE VIAL OR BOTTLE.

BUBBLE WRAP MAY BE USED TO PREVENT DIRECT CONTACT.

FROZEN SAMPLES WILL BE REJECTED BY THE LABORATORY REQUIRING THAT YOU RESAMPLERESAMPLE.

4

PROPERLY PACK SAMPLES TO PREVENT POSSIBLE CONTACT AND BREAKAGE.

BROKEN SAMPLES WILL BE REJECTED BY THE LABORATORY REQUIRING THAT YOU RESAMPLE.

5

PROPERLY PACK SAMPLES TO PREVENT POSSIBLE CONTACT AND BREAKAGE.

BROKEN SAMPLES WILL BE REJECTED BY THE LABORATORY REQUIRING THAT YOU RESAMPLE.

6

HAWAII DEPARTMENT OF HEALTH SAFE DRINKING WATER BRANCH

JULY 22 2011JULY 22, 2011

THE FOLLOWING INSTRUCTIONS ARE PROVIDED TO ASSIST YOU DURING THE COLLECTION OF DRINKING WATER SAMPLES THAT WILL BE SHIPPED TO THE STATE LAB FOR CHEMICAL ANALYSIS THE ISSUE ADDRESSEDLAB FOR CHEMICAL ANALYSIS. THE ISSUE ADDRESSED IN THIS INSTRUCTIONS IS THE MAINTENANCE OF PROPER SAMPLE TEMPERATURE.

RECOMMENDED METHOD TO PACKING SAMPLE COOLERWHEN USING LARGE BLUE ICE

During sample collection , used one set of blue ice or wet ice to chill samples. When you pack the sample for shipment to the lab, use a new set of blue ice taken from the freezer. Make sure the ice has been in the freezer for at least 3 days.

Place 2 large blocks of blue ice on top of the samples. Place chain of custodies on the top of the cooler. Secure the cooler shut with duct or masking tape. Proper sample temperature must be maintained in order for the lab to

Place the large block of blue ice on the sides of the cooler, Place sample in the center.

temperature must be maintained in order for the lab to accept the samples.

RECOMMENDED METHOD TO PACKING SAMPLE COOLERWHEN USING SMALL BLUE ICE

During sample collection , used one set of blue ice or wet ice to chill samples. When you pack the sample for shipment to the lab, use a new set of blue ice taken from the freezer. Make sure the ice has been in the freezer for at least 3 days

Place 6 small blocks of blue ice on top of the samples. Place chain of custodies on the top of the cooler. Secure the cooler shut with duct or masking tape. Proper sample temperature must be maintained in order for the lab toMake sure the ice has been in the freezer for at least 3 days.

Place the blocks of blue ice on the sides of the cooler. Place samples in the center.

temperature must be maintained in order for the lab to accept the samples.

Send Lead & Copper and

Chemistry sampling coolers to:

DRINKING WATER CHEMISTRY LAB

2725 WAIMANO HOME RD.

PEARL CITY, HI 96782

PHONE: (808) 453-6679

SAFE DRINKING WATER BRANCH LEAD AND COPPER RESULTS DELIVERY CERTIFICATION

Public Water System Name: PWS #: I certify that occupants of each residence/building from where lead and copper water samples were collected, have been informed of the lead and copper analyses results of the water sample provided. The following information was also provided:

An explanation of the health effects of lead, steps consumers can take to reduce exposure to lead in drinking water, the Maximum Contaminant Level Goal (MCLG) and the action level for lead. The definitions for the terms MCLG and action level for lead, and the contact information for the water system were also provided.

A sample copy of the letter to the participating residents/building occupants is attached to this delivery certification. DELIVERY METHOD & DATE NOTIFIED Community Water System (Single or Multi-Family Residences):

Residents were notified by U.S. Mail on .

Residents were notified by hand/direct-delivery on .

Non-transient Non-Community Water Systems (Schools, Correctional Facilities, Parks, or Businesses)

Occupants of the building were notified by U.S. Mail on .

Occupants of the building were notified by posting on . The posting will remain until replaced with the posting reporting the results of the subsequent lead and copper monitoring period.

Occupants of the building were notified by hand/direct delivery on .

Signature: Title: Print Name: Phone: Date: This form must be completed and returned to the Safe Drinking Water Branch within three (3) months from the end of the lead and copper monitoring period (September 30 for annual and triennial monitoring).

Instructions for Returning Lead & Copper Samples to the State Laboratory (Oahu) The water system must drop-off the lead and copper samples to the State Laboratory for analysis.

1. Ensure that all chain of custody forms and bottle labels are filled out completely, accurately and legibly. Failure to complete the chain of custody forms and bottle labels may result in the lab rejecting the lead and copper samples.

2. The chain of custodies should be placed in a separate zip-top (water-proof) bag and then into the shipping container/box.

3. The bottles should be placed into a plastic garbage-type bag and then into the shipping container/box with enough packing material to ensure the bottles do not rattle in the box. Make sure that the caps on the sample containers are secure. The laboratory will not accept leaking sample containers or take delivery of wet/damaged boxes.

4. The samples should be dropped off directly to the State Laboratory at: State Laboratory Division Attention: Chemistry Section-Pb/Cu 2725 Waimano Home Road Pearl City, HI 96782 (808) 453-6679

5. Please be aware that there are new security measures in effect. Security may deny you entry if you are not on the facility’s list of chem/micro samplers. Samples will be accepted at the lab only on regular state business days, from 9-11 a.m. and from 1-3 p.m.

6. Samples should be received by the lab within 7 days of the earliest sample taken. (e.g. If you sample on a Monday, Tuesday and Wednesday, the samples must be received by the lab by the following Monday.)

7. No samples will be accepted by the lab after the following to allow the lab adequate time to analyze the samples before the reporting deadlines.

Monitoring Period Deadline to Submit Samples to Lab Reporting Deadline

January 1 – June 30 June 15 July 10 June 1 – September 30 September 15 October 10 July 1 – December 31 December 1 January 10

8. Lead and copper results will be provided to the water system through the Sample

Collection and Reservation System (SCRS) following lab analysis.

Instructions for Shipping Lead & Copper Samples to the State Laboratory (Neighbor Islands) The water system must ship the lead and copper samples to the State Laboratory via a courier service (e.g. FedEx or UPS) for analysis.

1. Ensure that all chain of custody forms and bottle labels are filled out completely, accurately and legibly. Failure to complete the chain of custody forms and bottle labels may result in the lab rejecting the lead and copper samples.

2. The chain of custodies should be placed in a separate zip-top (water-proof) bag and then into the shipping container/box.

3. The bottles should be placed into a plastic garbage-type bag and then into the shipping container/box with enough packing material to ensure the bottles do not rattle in the box. Make sure that the caps on the sample containers are secure. The laboratory will not accept leaking sample containers or take delivery of wet/damaged shipping boxes.

4. The samples should be shipped directly to the State Laboratory at: State Laboratory Division Attention: Chemistry Section-Pb/Cu 2725 Waimano Home Road Pearl City, HI 96782 (808) 453-6679

5. Samples should be received by the lab within 7 days of the earliest sample taken. (e.g. If you sample on a Monday, Tuesday and Wednesday, the samples must be received by the lab by the following Monday.)

6. No samples will be accepted by the lab after the following to allow the lab adequate time to analyze the samples before the reporting deadlines.

Monitoring Period Deadline to Submit Samples to Lab Reporting Deadline

January 1 – June 30 June 15 July 10 June 1 – September 30 September 15 October 10 July 1 – December 31 December 1 January 10

7. Lead and copper results will be provided to the water system through the Sample

Collection and Reservation System (SCRS) following lab analysis.




CO O S OCOMPUTER DEMONSTRATION

▪ TRACKING STATUS OF SAMPLES COLLECTEDTRACKING STATUS OF SAMPLES COLLECTED

▪ REVIEWING CHEMICAL COMPLIANCE MONITORING

RESULTS

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OTHERCOMPLIANCEMONITORING

REQUIREMENTS

40 CFR 141

Chapter 20

SAFE DRINKING WATER ACT

1974

amended 1986 1996

5/4/2017

1

PHASE II/VSAMPLING

PHASE II/V

SDWB STAFF CONTACT:

Zhaohui Wang(808) [email protected]

Summary of Phase II and Phase V Contaminants

Required to be Monitored for by Water Purveyor

(cannot be run by the DOH Laboratories Division)

FOR SYSTEMS SERVING LESS THAN OR EQUAL TO 3300 PERSONS

(GROUP 1)

Systems which qualify for reduced monitoring (no detections of contaminants in the previous four quarterly samples) must collect one sample in the January 2017 to December 2019 monitoring period.

Phase II and Phase V contaminants (2017 ‐ 2019)

Contaminant EPA Method NumbersContaminant EPA Method Numbers

Benzo(a)pyrene 525.2, 550, or 550.1

Di(2‐ethylhexyl)adipate 525.2, or 506

Di(2‐ethylhexyl)phthalate 525.2, or 506

Dioxin 1613

Diquat 549.2

Endothall 548.1

Cyanide (one sample*) 335.4 or SM4500 CN – C, E, F, or G

*For groundwater systems, one sample is required in the three year compliance period.

For surface water or groundwater under the direct influence of surface water systems, an annual sample is required.

Asbestos 100.1 or 100.2.

Systems do not have to perform asbestos monitoring if they certify in a letter to the DOH that

they do not have asbestos‐cement piping in the distribution system.



(can not be run by the DOH Laboratories Division)

FOR SYSTEMS SERVING GREATER THAN 3300 PERSONS AND

LESS THAN OR EQUAL TO 10,000 PERSONS

(GROUP 2)

Systems which qualify for reduced monitoring (no detections of contaminants in the previous four quarterly samples) must collect two samples in two different quarters of a 12 month period during the January 2017 to December 2019 monitoring period.

Organic and Inorganic contaminants (2017 2019)Organic and Inorganic contaminants (2017 ‐ 2019)

Contaminant EPA Method Numbers


Di(2‐ethylhexyl)adipate 525.2, or 506 i( ethylhexyl)adipate 5 5. , or 506


Dioxin 1613

Diquat 549.2

Endothall 548.1

Cyanide (one sample*) 335.4 or SM4500 CN – C, E, F, or G.

*For groundwater systems, one sample is required in the three year compliance period. For surface water or groundwater under the direct influence of surface water systems, an annual sample is required.


Systems do not have to period no perform asbestos monitoring if they certify in a letter to the DOH thatSystems do not have to period, no perform asbestos monitoring if they certify in a letter to the DOH that

they do not have asbestos‐cement piping in the distribution system.



(can not be run by the DOH Laboratories Division)

FOR SYSTEMS SERVING GREATER THAN 10,000 PERSONS

(GROUP 3)

Systems which qualify for reduced monitoring (no detections of contaminants in the previous four quarterly samples) must collect two samples in two different quarters of a 12 month period during the January 2017 to December 2019 monitoring period.

Organic and Inorganic contaminants (2017 ‐ 2019)

Contaminant EPA Method Numbers

2,4‐D; 2,4,5‐TP 515.1, 515.2, 515.3, 515.4, or 555

Dinoseb; Picloram 515.1, 515.2, 515.3, 515.4, or 555

Dalapon; 515.1, 515.3, 515.4, 552.1, or 552.2

Pentachlorophenol 515.1, 515.2, 515.3, 515.4, 525.2, or 555


Di(2‐ethylhexyl)adipate 525.2, or 506


Dioxin 1613

Diquat 549.2

Endothall 548.1

Cyanide (one sample*) 335.4 or SM4500 CN – C, E, F, or G.

*For groundwater systems, one sample is required in the three year compliance period. For surface water or groundwater under the direct influence of surface water systems, an annual sample is required.


Systems do not have to perform asbestos monitoring if they certify in a letter to the DOH that they do not have asbestos‐cement piping in the distribution system. This letter must be submitted once for each three‐year compliance period (2017 ‐ 2019).

5/4/2017

1

RADIOLOGICALSAMPLING

RADIOLOGICAL SAMPLING

SDWB STAFF CONTACT:Zhaohui Wang(808) [email protected]

United StatesEnvironmental ProtectionAgency

Office of Water(4606)

EPA 816-F-01-003June 2001

Radionuclides Rule:A Quick Reference GuideOverv i ew o f the Ru leTitle Radionuclides Rule

66 FR 76708December 7, 2000Vol. 65, No. 236

Purpose Reducing the exposure toradionuclides in drinking waterwill reduce the risk of cancer.This rule will also improvepublic health protection byreducing exposure to allradionuclides.

GeneralDescription

The rule retains the existingMCLs for combined radium-226and radium-228, gross alphaparticle radioactivity, and betaparticle and photon activity.The rule regulates uranium forthe first time.

UtilitiesCovered

Community water systems, allsize categories.

Publ i c Hea l th Benef i t sImplementation ofthe RadionuclidesRule will result in . . .

Reduced uraniumexposure for 620,000persons, protection fromtoxic kidney effects ofuranium, and a reducedrisk of cancer.

Estimated impacts ofthe RadionuclidesRule include . . .

Annual compliance costsof $81 million.

Only 795 systems willhave to install treatment.

Crit ical Deadlines & Requirements

For Drinking Water SystemsJune 2000 - December 8, 2003 When allowed by the State, data collected between these

dates may be eligible for use as grandfathered data(excluding beta particle and photon emitters).

December 8, 2003 Systems begin initial monitoring under State-specifiedmonitoring plan unless the State permits use ofgrandfathered data.

December 31, 2007 All systems must complete initial monitoring.

For StatesDecember 2000 - December 2003 States work with systems to establish monitoring

schedules.

December 8, 2000 States should begin to update vulnerability assessmentsfor beta photon and particle emitters and notify systemsof monitoring requirements.

Spring 2001 EPA meets and works with States to explain new rulesand requirements and to initiate adoption andimplementation activities.

December 8, 2002 State submits primacy revision application to EPA. (EPAapproves within 90 days.)

Regulated ContaminantsRegulatedRadionuclide MCL MCLGBeta/photon emitters* 4 mrem/yr 0

Gross alpha particle 15 pCi/L 0

Combined radium-226/228

5 pCi/L 0

Uranium 30 µg/L 0

*A total of 168 individual beta particle andphoton emitters may be used to calculatecompliance with the MCL.

Initial Monitoring Results

< Detection Limit

> 1/2 the MCL but < theMCL

> MCL

> Detection Limit but ≤ 1/2 the MCL

2008 2009 2010 2011 2012 2013 2014 2015 2016

First Compliance Cycle

KEY

One sampling event.

4 consecutive quarterly samples. Systems with MCL violations must continue to take quarterly samples until 4 consecutive samples are at or below the MCL.

When allowed by the State, data collected between 6/00 and 12/08/03 may be used as grandfathered data to satisfy the initial monitoring requirements.

06/00 12/08/03

Grandfathered Data Collected between

Final Rule12/07/00

Initial Monitoring Begins unless State Permits the

Use of Grandfathered Data

2004 2005 2006 2007

Initial Compliance Monitoring

Initial Monitoring Completed12/31/07

For additional informationon the Radionuclides Rule

Call the Safe Drinking WaterHotline at 1-800-426-4791;visit the EPA Web site atwww.epa.gov/safewater; orcontact your State drinkingwater representative. EPAwill provide radionuclidetraining over the next year.

Applicability of the Standardized Monitoring Framework to Radionuclides(Excluding the Beta Particle and Photon Emitters)

Moni to r ing Requ i r ement sGross Alpha, Combined Radium-226/228, and

Uranium (1)Beta Particle and Photon

Radioactivity (1)

Initial Monitoring

Four consecutive quarters of monitoring. No monitoring required for most CWSs.Vulnerable CWSs (2) must sample for: • Gross beta: quarterly samples. • Tritium and Strontium-90: annual samples.

Reduced Monitoring

If the average of the initial monitoring results foreach contaminant is below the detection limit: Onesample every 9 years.

If the average of the initial monitoring results foreach contaminant is greater than or equal to thedetection limit, but less than or equal to one-halfthe MCL: One sample every 6 years.

If the average of the initial monitoring results foreach contaminant is greater than one-half the MCL,but less than or equal to the MCL: One sampleevery 3 years.

If the running annual average of the grossbeta particle activity minus the naturallyoccurring potassium-40 activity is less than orequal to 50 pCi/L: One sample every 3 years.

Increased Monitoring

A system with an entry point result above the MCLmust return to quarterly sampling until 4consecutive quarterly samples are below the MCL.

If gross beta particle activity minus thenaturally occurring potassium-40 activityexceeds 50 pCi/L, the system must: • Speciate as required by the State. • Sample at the initial monitoring frequency.

(1) All samples must be collected at each entry point to the distribution system.(2) The rule also contains requirements for CWSs using waters contaminated by effluents from nuclear facilities.

Grandfa ther ing o f Da taWhen allowed by the State, data collected between June, 2000 and December 8, 2003 may be usedto satisfy the initial monitoring requirements if samples have been collected from: • Each entry point to the distribution system (EPTDS). • The distribution system, provided the system has a single EPTDS. • The distribution system, provided the State makes a written justification explaining why the sample is representative of all EPTDS.

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UCMR4


UCMR4• 1996 SDWAA require EPA to issue a new of no more than 30 unregulated contaminants to be monitored by PWSs (once every 5 years)

• UCMR4 proposed on 12/11/15.• 30 chemical contaminants to be monitored for between 2018 and 2020.

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• Use analytical methods by EPA & consensus organizations.

• Provides the basis for future regulatory determinations and, as warranted, actions to protect public health.

• Assessment Monitoring (List 1 contaminants)

‐ Additional Chemicals (20)‐ Cyanotoxins (10)

DW Monitoring Updates & Regulatory Changes• Assessment Monitoring (List 1Assessment Monitoring (List 1 contaminants)

‐ Additional Chemicals (20)

Two Metals

(Germanium, Manganese)

Ei ht P ti id & O P ti id M f t i B P d tEight Pesticides & One Pesticide Manufacturing ByProducts

(alpha‐hexachlorocyclohexane, Chlopyrifos, Dimethipin, Ethoprop,

Oxyfluorfen, Profenofos, tebuconazole, total permethrin (cis‐ &

trans‐), Tribufos)

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DW Monitoring Updates & Regulatory Changes• Assessment Monitoring (List 1 contaminants)Assessment Monitoring (List 1 contaminants)

‐ Additional Chemicals (20) continued….

Three Brominated Haloacetic Acid (HAA) Groups

(HA5, HAA6Br, HAA9)

Three Alcohols

(1‐butanol 2‐methoxyethonol 2‐propen‐1‐ol)(1‐butanol, 2‐methoxyethonol, 2‐propen‐1‐ol)

Three Other Semivolatile Chemicals

(butylated hydroxyanisole, o‐toluidine, Quinoline)

DW Monitoring Updates & Regulatory Changes• Assessment Monitoring (List 1 contaminants)

C i (10)‐ Cyanotoxins (10)

total microcystin microcystin‐RRmicrocystin‐LA microcystin‐YRmicrocystin‐LF Nodularinmicrocystin‐LR anatoxin‐amicrocystin‐LY cylindrospertopsin

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• National Sample Assessment Monitoring Design

System Size List 1 – Cyanotoxins List 1 ‐ Chemicals

Small Systems(25‐10,000)

800 randomly selected SW & GWUDI systems

800 randomly selected SW, GWUDI, & GW systems

Large Systems(10,001 & over)

All SW & GWUDI systems All SW, GWUDI, & GW systems


• Draft Hawaii State Monitoring Plan (SMP)

System Size List 1 – Cyanotoxins List 1 – Chemicals


01 randomly selected SW & GWUDI systems

03 randomly selected SW,GWUDI, & GW systems

Large Systems(10,001 & over)

All SW & GWUDI systems (4)

All SW, GWUDI, & GW systems (17)

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• Draft Hawaii State Monitoring Plan (SMP)Groundwater


List 1 –Cyanotoxins

List 1 ‐Chemicals

Primary System (501‐3,300)

108 – Waiohinu‐Naalehu X

Replacement Systems (500‐3,300)

230 – Hoolehua X

238 – Manele Bay X

425 – Kokee State Park X425 – Kokee State Park X

• Draft Hawaii State Monitoring Plan (SMP)Groundwater



List 1 ‐Chemicals

Primary System (3,301‐10,000)

129 – North Kohala X

406 – Kekaha‐Waimea X

Replacement Systems (3,301‐10,000)

357 – NCTAMS East Pac X

365 – Kahuku X

117 – Hawaiian Beaches X

204 – Kapalua X

205 – Kaanapali X

112 – Olaa‐Mountain View X

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Surface Water & GWUDISmall Systems(25‐10,000)


List 1 ‐Chemicals

Primary System (3,301‐10,000)

215 – Upper Kula X

Replacement System (3,301‐10,000)

130 – South Kohala X

DW Monitoring Updates & Regulatory ChangesUCMR4 (Small Systems)UC (S a Syste s)• PWS sample for either cyanotoxins or chemicals.

• Cost to be covered by USEPA. Cyanotoxins Monitoring Schedule• Collect 2 samples per month for 4 consecutive months (March through November), for a total of 8 sample eventsNovember), for a total of 8 sample events (SEs).

• No sampling scheduled for January, February and December.

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DW Monitoring Updates & Regulatory ChangesAdd’l Chemicals Monitoring ScheduleAdd l Chemicals Monitoring Schedule

• Groundwater PWSs:Sample twice, 5 to 7 months apart. For a total of 2 SEs.

• Surface Water PWSs:Surface Water PWSs: Sample once every 3 months. For a total of 4 SEs.

• Draft Hawaii State Monitoring Plan (SMP)GroundwaterLarge Systems(10,001 & over )


List 1 ‐Chemicals

101 – Hilo X

131 – North Kona X

135 – Waikoloa X

331 – Honolulu‐Windward‐PH X

332 – Waialua‐Haleiwa X

333 – Wahiawa X

334 – Waipio Heights X

335 – Waipahu‐Ewa‐Waianae X

345 – Schofield Barracks X

356 – Marine Corps Base Hawaii X

360 – Joint Base Pearl Harbor‐Hickam X

367 – Mililani X

434 – Kalaheo‐Koloa X

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Surface Water & GWUDILarge Systems(10,001 & over)

List 1 – Cyanotoxins List 1 – Chemicals

212 ‐Wailuku X X

213 ‐Makawao X X

214 – Lahaina X X

400 – Lihue‐Kapaa X X

DW Monitoring Updates & Regulatory ChangesUCMR4 (Large Systems)UC ( a ge Syste s)• All large applicable SW PWSSs are required to monitor for cyanotoxins.

• Cost to be covered by PWSs. Cyanotoxins Monitoring Schedule• Collect 2 samples per month for 4 consecutive months (March through November), for a total of 8 sample events (SEs).of 8 sample events (SEs).

(Same rules as small PWSs for add’l chemical monitoring)

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DW Monitoring Updates & Regulatory ChangesAdd’l Chemicals Monitoring Scheduleg• Groundwater PWSs:

Sample twice, 5 to 7 months apart. For a total of 2 SEs.

• Surface Water PWSs: Sample once every 3 months. For a total of 4 SEs.

(Same rules as small PWSs for cyanotoxinsmonitoring)

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UCMR3UCMR3(PFOA/PFOS)

DW/GW Monitoring ProjectsPFOA/PFOS Monitoring • What is PFOA/PFOS?

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DW/GW Monitoring ProjectsPFOA/PFOS Monitoring

• Why are weWhy are we looking for it?

PFOA/PFOS MONITORINGEPA has also launched a concerted, strategic engagement with key partners and stakeholders – including state, tribal and local governments, drinking water utilities, and public health, environmental and community t k h ld t d l d i l t ti l ti l t dd th iti l d i ki tstakeholders – to develop and implement a national action plan to address the critical drinking water challenges and opportunities before us. The focus of that engagement will include:

Emerging and Unregulated Contaminant Strategies: Develop and implement improved approaches through which EPA, state, tribal and local governments, utilities and other stakeholders can work together to prioritize and address the challenges posed by emerging and unregulated contaminants such as algal toxins and perfluorinated compounds (PFCs).

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