[GROUNDWATER MONITORING REPORT - NOVEMBER 2000 FOR ... · 5599 San Felipe, Suite 700 Houston, TX...

N O V E M B E R 2000G R O U N D W A T E R M O N I T O R I N G REPORT

T E X A R K A N A WOOD P R E S E R V I N G C O . S U P E R F U N D S I T ET E X A R K A N A , B O W I E C O U N T Y , T X

T N R C C C O N T R A C T N O . 43000000002

Prepared forT e x a s Natural Resource Conservation Commission

P.O. Box 13087Aus t in , TX 78711

Prepared byRoy F. W e s t o n , Inc.

5599 San F e l i p e , S u i t e 700H o u s t o n , TX 77056

January 2001909480

000590

N O V E M B E R 2000G R O U N D W A T E R M O N I T O R I N G REPORT

T E X A R K A N A WOOD P R E S E R V I N G C O . S U P E R F U N D S I T ET E X A R K A N A , BOWIE C O U N T Y , T X

T N R C C C O N T R A C T N O . 43000000002

T A B I L E O F C O N T E N T S

S E C T I O N T I T L E PAGE

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INTRODUCTION............................................................................................................ 1-11.1 P U R P O S E AND SCOPE..................................................................................... 1-11.2 OBJECTIVES...................................................................................................... 1-1S A M P L I N G A N D A N A L Y S E S A C T I V I T I E S ............................................................... 2 - 12.1 O V E R V I E W . ....................................................................................................... 2-12.2 SAMPLING PROCEDURES .............................................................................. 2-12.3 ANALYTICAL PROCEDURES ......................................................................... 2-2ANALYTICAL RESULTS.............................................................................................. 3-13.1 DATA MANAGEMENT O V E R V I E W .............................................................. 3-13.2 G R O U N D W A T E R ANALYTICAL RESULTS ................................................. 3-1

W : \ T N R C O 2 4 4 4 0 6 ( M \ N O V 2 0 0 0 G W ( R E V _ 0 ) . D O C r l W 1 1 / 3 1 / 0 1

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II N O V E M B E R 2000. G R O U N D W A T E R M O N I T O R I N G REPORTI T E X A R K A N A WOOD P R E S E R V I N G C O . S U P E R F U N D S I T E

T E X A R K A N A , B O W I E C O U N T Y , T X• T N R C C C O N T R A C T NO. 43000000002

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m

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L I S T O F F I G U R E S

F I G U R E T I T L E P A G E

2-1 Moni tor ing W e l l Locations.................................................................................. 2-3

L I S T O F A T T A C H M E N T S

A T T A C H M E N T T I T L E

T A B L E ST a b l e 1 Groundwater Act ion Leve l s

I T a b l e 2 Summary of A n a l y s e s and MeasurementsT a b l e 3 Sumrnaiiy of W e l l MeasurementsT a b l e 4 G r o u n d A J v a t e r A n a l y t i c a l Summary

FIELD LOG BOOKR E G I O N A L D A T A W p V J E W REPORTA N A L Y T I C A L R E S U L T S

T a b l e 1 PAH/PCP and BAP Resul t sT I C ' R E S U L T S

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IIIIIIIIIIIIIIIIIII

S E C T I O N 1I N T R O D U C T I O N

1.1 P U R P O S E AND S C O P ERoy F. W e s t o n , Inc. (WESTON®) was contracted by the T e x a s Natural Resource ConservationCommiss ion (TNRCC) to p e r f o r m groundwater monitoring ac t iv i t i e s at the Texarkana WoodPreserving Company (TWPC) S u p e r f u n d site. The primary purpo s e o f th e groundwatermonitoring a c t iv i t i e s at the T W P C s i t e was to analyze groundwater f r o m on-site permanentmonitoring w e l l s to observe increases or decreases in concentrations of c on s t i tu en t s of concern(po lynuc l ear aromatic hydro carbons [PAHs] and pentach loropheno l [PCP]) and determine ifknown p l u m e s have migrated since the last s a m p l i n g and analysi s event conducted in July 1999.The groundwater monitoring ac t iv i t i e s inc luded evaluat ing analyt i ca l data obtained through thec o l l e c t i o n and analysi s of groundwater sample s from selected e x i s t i n g monitoring w e l l s at thesite.In a d d i t i o n to a c t i v i t i e s described above, the f o l l o w i n g a d d i t i o n a l s a m p l i n g a c t i v i ty wasp e r f o r m e d :

• Measure f i e l d parameters ( d i s s o l v e d oxygen, o x i d a t i o n / r e d u c t i o n p o t e n t i a l , pH,temperature, amd s p e c i f i c c onduc t iv i ty).

The s p e c i f i c Data Qual i ty O b j e c t i v e s (DQOs) for thi s e f f o r t are provided in the Proj e c t Qual i tyAssurance P r o j e c t Plan (QAPP) dated December 1997 in Element A, T a b l e A.1.2 O B J E C T I V E SThe o b j e c t i v e s o f WESTON's groundwater s a m p l i n g in November 2000 inc luded:

• Purge and s a m p l e s e l e c t ed sha l l ow monitoring w e l l s ( M W - 0 1 , MW-03, MW-04,MW-06, M W - 0 7 , MW-08, MW-09, M W - 1 3 , MW-14, M W - 2 7 , and MW-28).

• Purge and s a m p l e s e l e c t ed intermediate monitoring w e l l s ( M W - 1 7 , M W - 1 9 ,MW-20, and M W - 2 6 ) .

• Record f i e l d measurements (water l ev e l , d i s s o lv ed oxygen, o x i d a t i o n / r e d u c t i o np o t e n t i a l , pH, temperature, and s p e c i f i c c o n d u c t i v i t y ) f o r a l l w e l l s sampled .

• Analyze groundwater sampl e s for s e l e c t ed s e m i v o l a t i l e organic compound( S V O C ) cons t i tuent s using S W - 8 4 6 Method 8270C.

• Determine if s i te a t t r i bu tab l e contaminants are d e t e c t ed in monitoring w e l l s , andcompare contaminant concentrations to the site s p e c i f i c action l ev e l s presented inT a b l e 1 in Attachment 1.

W : \ T N R C O 2 4 4 4 0 6 0 4 \ N O V 2 0 0 0 G W ( R E V _ 0 ) . D O C r f w 1 - 1 1 / 3 1 / 0 1

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II_ • Record water l e v e l s in the above-mentioned monitoring w e l l s to compare to water• l e v e l s measured in previous s a m p l i n g events.

I

I

I

I

Compare c o l l e c t e d data to previous si te reports to i d e n t i f y p o t e n t i a l p lumemovements.

W : \ T N R C C U 4 4 4 0 6 0 4 \ N O V 2 0 0 0 G W ( R £ V _ 0 ) . D O C r f u - 1 - 2 1 / 3 1 / 0 1

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S E C T I O N 2S A M P L I N G A N D A N A L Y S E S A C T I V I T I E S

2.1 O V E R V I E WFour t e en monitoring w e l l s ( M W - 0 1 , MW-03, MW-06, M W - 0 7 , MW-08, MW-09, M W - 1 3 ,M W - 1 4 , M W - 1 7 , M W - 1 9 , MW-20, M W - 2 6 , MW-27, and M W - 2 8 ) were purged and sampledfor analys i s during the November 2000 Groundwater S a m p l i n g A c t i v i t i e s as well as c o l l e c t i n g awater level measurement at MW-04. Due to severe weather condit ions, a groundwater s a m p l efrom MW-04 was not c o l l e c t e d . Moni tor ing well locat ions are shown on Figur e 2-1. T h e s e tenshal low water-bearing zone w e l l s and f our intermediate water-bearing zone w e l l s were selected

j o i n t l y by WESTON and TNRCC, as presented in the Groundwater Moni tor ing Plan submittedby WESTON to TNRCC in October 2000. T h e s e w e l l s were se l ec t ed for ]?roundwater s a m p l i n gto observe increases or decreases in concentrations of cons t i tuent s of concern and to determine ifthe downgradient boundaries of known p lume s have migrated since the last monitoring event.A summary of the tasks p e r f o r m e d during the November 2000 s a m p l i n g event is as f o l l o w s :

• F i e l d measurements (water level, pH, temperature, d i s so lved oxygen, oxidat ion/reduction p o t e n t i a l , and s p e c i f i c c onduc t iv i ty); and

• Groundwater s s i m p l i n g for analysis of consti tuents of concern (PAHs and P C P ) .A summary of analyses and f i e l d measurements p er f ormed for each well is shown in T a b l e 2 ofAttachment 1. T a b l e 3 in Attachment 1 tabu la t e s the measurements recorded from each wel l . Allf i e l d a c t i v i t i e s were recorded in a site l ogbook by the W E S T O N f i e l d team, leader Monitor wellpurging and s a m p l i n g in format i on was recorded on Groundwater S a m p l i n g F i e l d Data Shee t s .Photo cop i e s of the logbook pages and groundwater s a m p l i n g data sheets are provided asAttachment 2.2 .2 SAMPLING PROCEDURESS a m p l i n g procedures were f o l l o w e d as d e t a i l e d in Attachment One of the Q A P P — S t a n d a r dOpera t ing Procedures (SOP's). P h o t o c o p i e s o f a l l f i e l d logbook pages are inc luded asAttachment 2 of thi s document. In summary, a l o w - f l o w (minimal drawdown) s a m p l i n gtechnique was used to purge and sample groundwater from the monitoring wells. S a m p l e tubingwas po s i t i oned to c o l l e c t groundwater from the midpo in t of the water column. N o n d i s p o s a b l es a m p l i n g equipment was decontaminated f o l l o w i n g ac t iv i t i e s at each well as ou t l ined in theQAPP. S a m p l e s were sent for analys i s by overnight de l ivery to an Environmental Prot e c t i onAgency (EPA) de s ignated Contract Laboratory Program (CLP) laboratory. S a m p l e s wereh a n d l e d , l a b e l e d , packed , and s h i p p e d in accordance with the site QAPP.

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2 . 3 A N A L Y T I C A L PROCEDURESGroundwater sampl e s were analyzed for PAHs and PCP by M i t k e m Corpora t i on in Warwick,Rhode I s l a n d , using U . S . EPA SW-846 Method 8270C. Q A / Q C sample s were c o l l e c t e d andanalyzed as part of the grounclwater s a m p l i n g ac t iv i t i e s as required by Element B5 of the QAPP.

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000596

MW-09

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M O N I T O R I N G W E L L S W H E R ES A M P L E S WERE C O L L E C T E D A N DA N A L Y Z E D D U R I N G T H E N O V E M B E R2000 S A M P L I N G E V E N T .M O N I T O R I N G W E L L S P R O P O S E D F O RS A M P L I N G D U R I N G T H E N O V E M B E R2000 S A M P L I N G E V E N T . H O W E V E R ,D U E T O F I E L D C O N D I T I O N S . N OS A M P L E W A S C O L L E C T E D .

O S H A L L O W W E L L® S H A L L O W E X T R A C T I O N W E L L0 AQUITARD WELL<D INTERMEDIATE WELL® DEEP WELL51 ABANDONED WELL

Q M W - 1 2O O N D S \ <D M W-19

F I G U R E 2 - 1T E X A R K A N A WOOD P R E S E R V I N G C O .N O V E M B E R 2000 G R O U N D W A T E RM O N I T O R I N G R E P O R TM O N I T O R I N G W E L LL O C A T I O N S

H : \ O W G \ T E X W O O D \ 0 1 2 9 0 1 1 4 4 S . G A G 01-29-01

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S E C T I Q N 3A N A L Y T I C A L R E S U L T S

3 . 1 D A T E M A N A G E M E N T O V E R V I E Wt

The s a m p l e s i c o l l e c t e d f rom each well were analyzed by M i t k e m Corporat ion for the c on s t i t u en t sl i s t e d in A t t a c h m e n t 1, T a b l e 2-1 in accordance with the QAPP. A f t e r s a m p l e c o l l e c t i o n , theassociated cha in-o f - cu s t ody forms and analyt ical r e su l t s were entered into WESTON On-Line, apropr i e tary data management system for ease in I t a b u l a t i n g and pre s en t ing data. WESTONOn-Line was also used to c a l c u l a t e b enzo(a)pyrene j (BAP) equivalent s , as s p e c i f i e d in the 1998ROD Amendment No. l , i t o determine if const i tuents were above the established action l eve l s fori i 1the site. The EPA Region 6 H o u s t o n Branch ES AT data review team compl e t ed a review of theCLP data package. A copy of the Regional Data Review Report is inc luded in Attachment 3.i3 . 2 G R O U N D W A T E R A N A L Y T I C A L R E S U L T SThe ana ly t i ca l r e su l t s for the November 2000 s a m p l i n g event revealed that one of the 14 w e l l shad one of the groundwater contaminants of concern, acenaphthene, above the laboratoryreport ing l i m i t s but below the site action l eve l s . A summary of the re su l t s is pre s ented in T a b l e 4of Attachment 1. Attachment 4 of th i s Groundwater Moni tor ing Report is the d e t a i l e d analyt icalr e su l t s for PAH/PCP and BAP analysis.TICs were de t e c t ed in MW-06 and in an equipment blank taken at M W - 1 7 . No TICs werede t e c t ed in s a m p l e s that were c o l l e c t e d using i the non-d i spo sab l e s a m p l i n g equipment.Attachment 5 i n c l u d e s r e su l t s f o r t e n t a t i v e l y i d e n t i f i e d compounds ( T I C s ) .No groundwater s a m p l e s c o l l e c t e d exceeded the action l e v e l s o f 0.01 m i l l i g r a m s per l i t e r ( m g / L )and 0.2 m g / L , e s tab l i shed for to tal carcinogenic PAHs (cPAHs), expressed as BAP equivalents ,and P C P , r e s p e c t i v e l y .

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000598

S E C T I O N 4C O N C L U S I O N S

Based on the a n a l y t i c a l data f rom the November 2000 Groundwater Moni t or ing A c t i v i t i e s , thef o l l o w i n g conc lu s ions maybe drawn:

• No d e t e c t a b l e concentrations of PAHs and PCP are present in downgradients h a l l o w monitoring w e l l s M W - 0 3 , MW-06, MW-07, MW-08, MW-09, M W - 1 3 ,M W - 1 4 , a r i d M W - 2 8 .

• No d e t e c t a b l e concentrations of PAHs and PCP are present in upgrad i en t s h a l l o wmonitoring wel l M W - 0 1 .

• No d e t e c t a b l e concentrations of PAHs and PCP are present in intermediatemonitoring w e l l s M W - 1 7 , M W - 1 9 , MW-20, and MW-26.

• Detected concentrat ions of groundwater contaminants of concern in MW-27 andMW-27 ( d u p l i c a t e ) have not increased since the 1998 and 1999 s a m p l i n g events.Acenaphthene was the only cons t i tuent of concern d e t e c t e d above the laboratoryreport ing l imi t in MW-27 at a concentration of 0.009 m g / L .

• One unknown TIC was de t e c t ed in MW-06 at an estimated concentration of0.014 mg/L.

• It appears that the general c o n f i g u r a t i o n s of the p l u m e s that were d e l i n e a t e dduring the 1989 PJ and the 1999 A d d i t i o n a l F i e l d S a m p l i n g Trip Report continueto represent the p l u m e s of contaminated groundwater.

• The concentrations o f total non-carcinogenic PAHs, carcinogenic PAHs(expre s s ed as BAP e q u i v a l e n t s ) , and PCP have not shown a s i g n i f i c a n t increase ordecrease f r om previous s a m p l i n g events ( N o v e m b e r 1997 - July 1 9 9 9 ) in thew e l l s s a m p l e d .

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000599

S E C T I O N 5R E C O M M E N D A T I O N S

Based on the conclusions prov ided in S e c t i o n 4, WESTON makes the f o l l o w i n grecommendati ons:

• Cont inue to s ampl e the eleven sha l l ow w e l l s i d e n t i f i e d as being downgradientw e l l s for analysi s of PAHs and PCP on an annual basis. T h e s e eleven w e l l s areM W - 0 3 , M W - 0 6 , MW-07, MW-08, MW-09, M W - 1 1 , M W - 1 3 , M W - 1 4 , M W - 2 2 ,M W - 2 7 , and M W - 2 8 .

• Continue annual s a m p l i n g of upgrad i en t monitoring w e l l s M W - 0 1 , MW-04 andM W - 2 3 to observe increases or decreases in concentrat ions of contaminants ofconcern and determine if the groundwater p l u m e has migrated to the north or ifo f f - s i t e sources are a t t r i bu tab l e .

• Discontinue s a m p l i n g of the intermediate monitoring we l l s .

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000600

A T T A C H M E N T S

000601

IIIIIIIA T T A C H M E N T 1I T A B L E SI

T A B L E 1 GROUND W A T E R A C T I O N L E V E L S• T A B L E 2 S U M M A R Y O F A N A L Y S E S A N D M E A S U R E M E N T S• T A B L E 3 SUMMARY OF W E L L MEASUREMENTS

T A B L E 4 GROUND W A T E R A N A L Y T I C A L S U M M A R Y

IIIIIII

000602

IIIIIIIIIIIIIIIIIII

T A B L E 1G R O U N D W A T E R A C T I O N L E V E L S 1

N O V E M B E R 2000 S A M P L I N G E V E N T

C O M P O U N DT o t a l carcinogenic PAHs ( e x p r e s s e d a sto ta l BAP e q u i v a l e n t s )T o t a l noncarcinogenic P A H sT o t a l carcinogenic d i i o x i n / f u r a r i s( e x p r e s s e d as 2 , 3 , 7 , 8 - T C D D equ iva l en t s)PCP

G R O U N D W A T E R A C T I O NLEVEL ( m g / L )

0.010N A

0.0010.2

Reference: Record of Decision for Texarkana W o o d Preserving Co. E P A , 1990.

000603

IIIIIIIIIIIIIIIIIII

T A B L E 2S U M M A R Y O F A N A L Y S E S A N D M E A S U R E M E N T S C O N D U C T E D


A N A L Y S E SM o n i t o r i n g

W e l l N u m b e r 1

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M W - 1 7 e

M W - 1 8M W - 1 9 e

M W - 2 0 e

M W - 2 2MW-23M W - 2 5

M W - 2 6 e

MW-27 !MW-28

W e l l Loca t i on 2

U p g r a d i e n tW i t h i n

DowngradientU p g r a d i e n t

W i t h i nDowngradientDowngradientDowngradientDowngradient

W i t h i nBetween

W i t h i nDowngradientDowngradient

W i t h i nDowngradient

W i t h i nW i t h i n

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1 W e l l s l i s t e d i n c l u d e n i l s h a l l o w a n d i n t e r m e d i a t e w e l l s .2 Well l o c a t i o n i n d i c a t e s the l o c a t i o n o f the w e l l w i t h respect to the two p l u m e boundaries that were d e l i n e a t e d in the 1999A d d i t i o n a l F i e l d S a m p l i n g T r i p Report3 F i e l d measurements i n c l u d e : water l e v e l , d i s s o l v e d oxygen, o x i d a t i o n / r e d u c t i o n p o t e n t i a l , p H , t emperature , a n d s p e c i f i cc o n d u c t i v i t y .4 T e n t a t i v e l y I d e n t i f i e d C o m p o u n d s .5 I n t e r m e d i a t e m o n i t o r i n g w e l l .

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T A B L E 3S U M M A R Y O F W E L L M E A S U R E M E N T S


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1 Static water l eve l measured f r o m the top of c a s i n g on 15 November 2000.2 O n l y water l eve l measurements were p er f ormed on these w e l l s .H / k d k / T e x w o o d / N o v O O t a b l e . x I s Page 2 o f4

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7.987.837.76

1 Static water l eve l measured f r o m the top of ca s ing on 15 November 2000.2 O n l y water l ev e l measurements were p e r f o r m e d on these w e l l s .H / k d k / T e x w o o d / N o v O O t a b l e . x l s Page 3 o f4

000607



M W - 2 7 1 1 / 1 7 / 0 0 3.56 375380379379377377

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4.073.142.452.302.021.73

180.3142.191.075.173.373.7

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62.9966.2666.2865.4364.8564.76

7.956.596.536.656.536.46

173.5178.4174.0172.2169.0166.7

7.026.546.506.486.496.49

1 Static water l ev e l measured f r o m the top of ca s ing on 15 N o v e m b e r 2000.2 O n l y water l ev e l measurement s were p e r f o r m e d on these w e l l s .H / k d k / T e x w o o d / N o v O O t a b l e . x l s Page 4 o f4

000608

T A B L E 4G R O U N D W A T E R A N A L Y T I C A L S U M M A R Y 1

N O V E M B E R 2000 S A M P L I N G E V E N T R E S U L T S ( m g / L ) 2

M o n i t c r W e l l Number ; h *. : - ' : V • - • " • . v ; ; * v v . ; - - { y ; ' .M W - 0 1MW-03MW-06MW-07MW-08MW-09M W - 1 3M W - 1 4M W - 1 7M W - 1 9MW-20MW-26MW-27

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O.0051 T h i s t a b l e i n c l u d e s o n l y those c o n s t i t u e n t s f o u n d t o b e above the labora tory r e p o r t i n g l i m i t .2 All a n a l y t i c a l r e s u l t s were f o u n d to be b e l ow s i t e a c t i on l e v e l s .

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A T T A C H M E N T 2F I E L D LOG BOOK

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"Rite in the Rain" - a unique a l l - w e a t h e r w r i t i n g s u r f a c e createdto shed water and to enhance the wr i t t en image. Makes itp o s s i b l e to write s h a r p , l e g i b l e f i e ld d a t a in any kind o f weather.A v a i l a b l e in a variety of standard and custom pr in t ed case-bound f i e ld books, loose l ea f , sp ira l and s t a p l e d notebooks,m u l t i - c o p y sets and copier paper s .

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1 GROUNDWA TER SAMPLING FIELD DA TA SHEET^Last W e l l I D N o . Last DateI w e l l I D N o .1 YY\ voi[ C a s i n g DiameterBcasing S t i c k u p ^-— T o t a l W e l l 1 D e p t h•(from T O C )

1 f t '[ s t a t i c W a t e rA_evel ( f r o m T O C )• ft .

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hos / cm a t 2 5 ° CT i m e

5 ° CT i m e

° CN A P L Present? Y e s N oE s t i m a t e d v o l u m e / t h i c k n e s s ( g a l / i n ) ?Descr ip t on:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :

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5 ° CT i m e

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Purge E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l No. __S a m p l e E q u i p m e n t :Geote ch P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level M e t e r :S o l i n s tP u r e l y - C o n t a i n e r i z e d ?

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______nmhos/cm a t 2 5 ° CT i m e_nmhos/cm at 2 5 ° C _ _ _ _ _ _

T i m e_mg/ l at

N A P L Present? Y e s N oEs t imat ed v o l u m e / t h i c k n e s s ( g a l / i n ) ? _D e s c r i p t i o n :S a m p l e c o l l e c t e d ? Y e s N oS a m p l e ID:___________G r o u n d w a t e r S a m p l e C o l l e c t e d ? ,G r o u n d w a t e r S a m p l e D e p t h ( f t . ) : _ \ _

N oG r o u n d w a t e r S a m p l e ID: fY)l*>0~}- 6)- A/- O 7

T i m eN u m b e r o f C a s i n g

V o l u m e sG a l l o n s

RemovedW a t e rLevel

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P u m pD e p t h f t .

V i s u a lD e s c r i p t i o n

0211

/ W . 22-n2,0 271

l a l y s e s Requested (see C O C ) F u l l S u i t e Par t ia l S u i t e ( e x p l a i n )| Q C S a m p l e s : G C / M S Rinse Blank F i e l d B l a n k T r i p Blank

IJ d i t i o n a l A n a l y s e s :

D H N u I n i t i a l Readings:D OVA TOC_____D M i c r o t i p BZ_____

Bkgnd____

S a m p l e Readings:TOC_____BZ______Bkgnd____

d d i t i o n a l Comment s: Qfl \Cj"

Protect ive Leve l:B C D

S E R I A L NO.__H S O S i g n a t u r e :

l o n d i t i o n o f W e l l , Remarks:

S a m p l e r ' s S i g n a t

000624

| GROUNDWATER SAMPLING FIELD DA YA SHEETEast W e l l I D N o . Last Date

Wffi$0$-£i-d-O7l e a s i n g Diameter /• H in•asing S t i c k u p I i1 I ' M i ni total W e l l 1 D e p t h L a s t T o t a l W e l l• r o m T D C J D e p t hP / £ * Z J f t . f tj S t a t i c W a t e r Las t S t a t i c W a t e r•evel ( f r o m T O C ) Levelj W a t e r T h i c k n e s sL /-^ ftH / e l l Diameter F a 6 t o r \

P Diameter 27 4" ) 6" 8"1 F a c t o r .16^j>5/ 1-47 2.61M a s i n g V o l u m e ^• g a l .•Screened I n t e r v a l ( f r o m G S )i _ f t .

I T i m e

i f l t f f

C^5<9p?^5• t f C DUOO?


' i r v VG a l l o n s

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Purge E q u i p m e n t :Geotech P e r i s t c i l t i c P u m pS e r i a l N o .S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tP u r g e - C o n t a i n e r i z e d ?

(Ygs^ N ' oDes t ina t i on:

O M ' ^ f - t f l DGrAQfW a t e rLevel

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T e m p ° £

65<oM5? St V / - ' 5 C "L>/-^

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S a m p j e r j s l n i t i a l sP — t T^"

Log Book #PC

T i m eage J of |

/ Dai le

( / / | 0 / Z ° o oMeter C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CC o n d u c t a n c e S t a n d a r d : urnMeasured V a l u e : umhos/ cm at 2Disso lved OxygenC a l i b r a t e d to mq/l at


5 ° CT i m e

° CN A P L Present? Yes. N oEstimated v o l u m e / t h i c k n e s s ( g a l / i n ) ?D e s c r i p t i o n :S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :

^—^G r o u n d w a t e r S a m p l e C o l l e c t e d ? Qfg^ N oG r o u n d w a t e r S a m p l e D e p t h ( f t . ) :G r o u n d w a t e r S a m p l e I D : Yf\(.PG>&' G \ ~ M " C f ?

PH6.23

Cy#$5.7 \<5not}.b$

Bnalyse s Requested (see C O C ) F u l l S u i t e P a r t i a l S u i t e ( e x p l a i n )I Q C S a m p l e s : G C / M S Rinse Blank F i e l d E H a n k T r i p Blank• j d i t i o n a l A n a l y s e s :

j f c d i t i o n a l Comments: / C j j 5 " CO^2^ SA**~f> ^- /^

1 î^cfi


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/ T / . " 7/ "- /in 4MAWA

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Protect ive Level:B C D

H S O S i g n a t u r e ; :C o n d i t i o n o f W e l l , Remarks:

J^4?m /S a m p l e r ' s S i g n a t u r e T l / ^ k_Jt/-^- 1 _ >' 1000625

| GROUNDWA TER SAMPLING FIELD DA 7 A SHEETpast W e l l I D N o . Last DateW e I J D N o .• OniA^ctf- fc'^t-crt•Casing Diameter, /• \ in

•asing S t i c k u p S~) /m>\a\ Wel l ! Depth Last Total W e l lMom TOC) D e p t hP nno f t . f tI s t a t i c W a t e r Last S t a t i c WaterBfevel ( f r o m T O C ) Level• | C ? . C D f t . f t( W a t e r T h i c k n e s s•ell Diameter Factor\IB Diameter 2" / 4 " ) 6" 8"

F a c t o r .16 165/7 1-47 2.61j t e s i n g V o l u m e ^~r(Screened I n t e r v a l ( f r o m G S )

I T i m e

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Purge E q u i p m e n t :Geotech P e r i s t a l t i c P u m pSerial No.S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c P u m pSerial No.A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level M e t e r :S o l i n s tP u r g e - C o n t a i n e r i z e d ?

/re s / N olt>>/

D e s t i n a t i o n j/ m - s r t x w\aW a t e rLevel

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E.G.^mhos/cm

/73n$\\t1

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Log Book #P£

me jge 1 of Ii Dê

I I I (£ f e c t>Meter Calibration Timep H = a t ° C

T i m ep H = a t ° CConductance Standard: ^mhos/cm at 25°CMeasured V a l u e :

T i m enmho s / cm a t 2 5 ° C

Dissolved OxygenC a l i b r a t e d to mq/l at

Time° C

N A P L Present? Y e s N oEs t imat ed v o l u m e / t h i c k n e s s ( g a l / i n ) ?Descr ip t i on:S a m p l e collected? Yes NoS a m p l e I D :Groundwater S a m p l e C o l l e c t e d ? < e NoGroundwat e r S a m p l e D e p t h ( f t . ) :G r o u n d w a t e r S a m p l e ID: Yf\ L O C f l ' G] - l^k O7

pH

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M a l y s e s Requested (see C O C ) F u l l S u i t e P a r t i a l S u i t e ( e x p l a i n )Q C S a m p l e s : G C / M S Rinse B l a n k F i e l d Blank T r i p B l a n k/Bdit ional Analyses: . M , I . , ,« lutM has a *d itf I'X^teterj f c i o n a l Comments: M 2 / 5 C&U£C>{ ^rrf?(S Gut~ Ml4S^ sw s:

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H S O Signature:C o n d i t i o n o f W e l l , Remarks:

S a m p l e r ' s Signali^-^Ô^tÎ000626

| GROUNDWA TER SAMPLING FIELD DA TA SHEETj L a s t W e l l I D N o . Last Date

• iTlUd^-fa-Kl-D"![ C a s i n g Diameter ' /• *-/ in

f t a s i n g S t i c k u p i î/~~ 1ôtal W e l l 1 D e p t h Las t Tota l W e l lBrom TOC) ^ D e p t hT fa 1 ^ « ft[ S t a t i c W a t e r Las t S t a t i c W a t e r•evel (from TOC) LevelI ^Jô ft. «( W a t e r T h i c k n e s s• f t'•Veil Diameter F a c t o T AP Diameter 2" / 4" J 6" 8"1 F a c t o r .16 \§5/ 1.47 2.61t ea s ing VolumeI g a l '"[Screened I n t e r v a l ( f r o m G S )J _ f t .

| T i m e

P / 4 F ?S < / 2 0r/^ 5

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Purge Equ ipmen t:Geotech P e r i s t a l t i c P u m pS e r i a l N o .S a m p l e E q u i p m e n t :Geote ch P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .Water Level Moter:S o l i n s tP u r p s - G o n t a i n e r i z e d ?

ss/ NoD e s t i n a t i o n : 1

W a t e rLevel

l\ Q c~iCJ.&^\D£7|!^

T e m p ° o f/

(&MbW£nMfff(fi,2((£.30

(imho s / cm

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Log Book #?> Pime 3 g e J _ o f _ JDate

l l J n l Z T O c sM e t e r C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CC o n d u c t a n c e S t a n d a r d : urnMeasured V a l u e : umhos/ cm at 2Dissolved OxygenC a l i b r a t e d to mq/l at

ho s/cm a t 2 5 ° CT i m e

5 ° CT i m e

° CN A P L Present? Y e s N oEs t imated v o l u m e / t h i c k n e s s ( g a l / n)?D e s c r i p t i o n :S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :G r o u n d w a t e r S a m p l e C o l l e c t e cG r o u n d w a t e r S a m p l e D e p t h ( f t . ) :G r o u n d w a t e r S a m p l e I D : /)OUI t t y

pH

k4

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•nalyses Requested (see C O C ) F u l l S u i t e P a r t i a l S u i t e ( e x p l a i n )J Q C S a m p l e s : G C / M S Rinse Blank F i e l d B l a n k T r i p BlankH j d i t i o n a l A n a l y s e s :

• j d i t i o n a l Comment s: I n i ^ C&AM 6f ' < Â'" v ~ | p'M' (c/ f t IV- 1 3


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I n i t i a l Readings: S a m p l e Readings:TOC TOCBZ BZBkqnd Bkqnd



S a m p l e r ' s Signatuf^v""^^^-^

000627

1 GROUNDWA TER SAMPLING FIELD DA TA SHEET[ L a s t W e l l I D N o . Last Date

• W e l l I D N o .1 ft fJ/Y- C>- K) -O~ll e a s i n g Diameterl ea s ing S t i c k u p

J T o t a l W e l l 1 D e p t hI f r a m J D C ^1 r?« (^ ft.( S t a t i c W a t e riLeveJ ( f r o m T O C )I w a t e r T h i c k n e s s

•Wel l Diameter Fac torT Diameter 2" /4"

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f tLast S t a t i c W a t e rLevel f t

f t] 6" 8"

1 F a c t o r .16 ( .65} 1.47 2.61•Casing Volume ^"^

g a l .(Scre ened I n t e r v a l ( f r o m G S ) .

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0

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M e t e r C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CConduc tanc e S t a n d a r d : urnMeasured V a l u e : umhos / cm at 2Disso lved OxygenC a l i b r a t e d to mq/l at

hos / cm a t 2 5 ° CT i m e

5 ° CT i m e

° CN A P L Present? Y e s N oEs t imat ed v o l u m e / t h i c k n e s s ( q a l / i n ) ?Descr ip t i on:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :G r o u n d w a t e r S a m p lG r o u n d w a t e r S a m p l eGroundwat er S a m p l e

pH

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•Analyses Requested (see C O C ) F u l l S u i t e Partial S u i t e ( e x p l a i n )l o C S a m p l e s : G C / M S Rinse B l a n k F i e l d B l a n k T r i p Blank• A d d i t i o n a l A n a l y s e s :

• A d d i t i o n a l Comments .! \3LIO Cd-MJic}"cj\i'^Qlf cJi n°)iOi^-^


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Protect ive Leve l:B



S a m p l e r ' s SignatureS^/^-^-^-^

000628

1 GROUNDWA TER SAMPLING HELD DA TA SHEET[ L a s t W e l l I D N o . Last Date

l / V e l l I D N o .[ C a s i n g Diameter . / /

K a s i n g S t i c k u pJ T o t a l W e l l 1 D e p t h Last T o t a l W e l l•from TOC) ^ Depth

[ s t a t i c W a t e r Last S t a t i c W a t e r•evel ( f r o m TOC) LevelT w a t e r T h i c k n e s s•Veil Diameter Factpi s .9 Diameter 2" / 4 " ) 6" 8"1 F a c t o r .16 CW 1.47 2.61

•Casing V o l u m e ^• 9 a'pcreened I n t e r v a l ( f r o m G S )

T T i m e

1/3001/30 z-f ( Mi ( & > v\w>\\wIr1

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Purge E q u i p m e n t :Geotech P e r i s t a l t i c PumpS e r i a l N o .S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c PumpS e r i a l N o .Anayl t i ca l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o ./ V a l e r Level Meter:S o l i n s tPuri j e Conta iner i z ed?

( Yes 7 NoD e s ' t i n a t i o n : i

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Log Book #Page 1 of 1T i m e y Date\(\\(l\C0Meter C a l i b r a t i o n T i m e

p H = a : ° CT i m e

p H = a t ° CConduc tance S t a n d a r d : urnMeasured Value: umhos/cm at 2Dissolved OxygenC a l i b r a t e d to mq/l at


5 ° CT i m e

° C_NAPL Present? Yes (ôjEst imated v o ! u m e / t h i c k n e s s 7 g a l / i n ) ?Description:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :

, — .,Groundwat er S a m p l e C o l l e c t e d ? (Yes-/ N oGroundwat er S a m p l e D e p t h ( f t . ) :Groundwater S a m p l e ID: ff\lO{ ""} - £j - /^/— QT~\

pH8.21/ 0 . < / f

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S a m p l e r ' s S i g n a t u r e : Î000629

| GROUNDWA TER SAMPLING FIELD DA TA SHEET[ L a s t W e l l I D N o . Last DateL rf)VdYy(-£l-l4-O(jp

•Veil I D N o .P/*7 iJ/J - (5 «*- /I/ ~ <9 /[ C a s i n g Diameter r• ^ V ' n

K a s i n g S t i c k u pT ini"otal Wel l 1 D e p t h Last Tota l Wel l•rom TOC) Depth| G?3-* 7^> ft- ftJ S t a t i c W a t e r Last S t a t i c W a t e r

•evel ( f r o m TOC) LevelI $.?/ f t- f t[ W a t e r Thickness^-well Diameter Factor sP Diameter 2"/ 4" ) 6" 8"1 F a c t o r .16( .65 / 1.47 2.61Basing V o l u m e \^£/• ga l .[Scre ened I n t e r v a l ( f r o m G S )

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Purge E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .S a m p l e Equ ipmen t:Geotech Per i s t a l t i c PumpS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tP u r a e - f x p n t a i n e r i z e d ?

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Log Book #P;

me age_i_of_|I Date

M e t e r C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CConduc tance S t a n d a r d : urrMeasured V a l u e : ^mhos/cm at 2Dissolved OxygenC a l i b r a t e d to ma/I at

i ho s / cm at 25°CT i m e

5°CT i m e

° C^ —— vNAPL Present? Yes; A\oJ

Est imated v o l u m e / t h i c k n e $ S r o a l / i n ) ?Descr ip t i on:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :Groundwat er S a m p l e C o l l e c t e dGroundwat e r S a m p l e D e p t h ( f t . ) :G r o u n d w a t e r S a m p l e I D : j Y ' ) \ j

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000630

1 GROUNDWA TER SAMPLING FIELD DA TA SHEET[ L a s t W e l l I D N o .1MU2O-&-1 / V e l l I D N o .T Al bJ£O-£>-fal e a s i n g Diameter

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T i m ep H = a t ° CConduc tance S t a n d a r d : urnMeasured V a l u e : umhos/ cm at 2Disso lved OxygenC a l i b r a t e d to mq/ l at

h o s / c m a t 2 5 ° CT i m e

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000631

GROUNDWA TER SAMPLING FIELD DA TA SHEET T a s k (CODLast W e l l I D N o . Last DateW e l l I D N o .ea s ing Diameter

ineas ing S t i c k u pl o t a l W e l l D e p t h( f r o m T O C )61/10 f t .S t a t i c W a t e r

evel ( f r o m T D C ) f t .

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Diameter T 4" ) 6" 8"F a c t o r .16 [ .65/ 1.47 2.61

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[ S c r e e n e d I n t e r v a l ( f r o m G S )f t

Log Book #_Job # . col

Purge E q u i p m e n t :Geote ch P e r i s t a l t i c P u m pS e r i a l No. ______S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .A r i a y l t i c a l Equipment:( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tP u r g e Con ta in er i z ed?

Y e s N oD e s t i n a t i o n :

S a m p l e r ' a I n i t i a l s•\m T i m eM e t e r C a l i b r a t i o nDH = at

at

T i m e

Page I of |[ / / S l o p

T i m ePH __Conduc tance S t a n d a r d : _nmhos/cm a t 2 5 ° C

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_Mmhos/cm a t 2 5 ° C _T i m e

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nalys e s Reques ted (see C O C ) F u l l S u i t e P a r t i a l S u i t e ( e x p l a i n )Q C S a m p l e s : G C / M S Rinse Blank F i e l d B l a n k T r i p B l a n k

d d i t i o n a l A n a l y s e s :

D H N u I n i t i a l Readings: S a m p l e Reading s:D OVA TOC______ TOC______D M i c r o t i p BZ______

B k g n d _BZB k g n d _

A d d i t i o n a l Comments: Collet- 'Protec t ive Level:

B C DS E R I A L NO.__H S O S i g n a t u r e :

o n d i t i o n o f Wel l , Remarks:

S a m p l e r ' s S i

000632

| GROUNDWA TER SAMPLING FIELD DA TA SHEET[ L a s t W e l l I D N o . Last Date

•Veil ID No. , , -| --7lea s ing Diameter

K a s i n g S t i c k u pi o t a l W e l l Depth•From TOC)f ltf.U'1 ft.J S t a t i c W a t e r•evd ( f r o m TOC)[ W a t e r Thicknes s

•Veil Diameter EactorP Diameter /2" ) 4"

^_ in£ in

Last T o t a l W e l lDepth

f tLast S t a t i c WaterLevel

f t .f t .

6" 8"1 F a c t o r (\fi/).65 1.47 2.61

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I Time1. l^2f^Ww2&ua?0M<^• t f j oD(^<5nb^b

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T a s k 1 OOP Log Book #Job $ c^^^"^ ' ' ^^ L? • C>O^ Paqe ' of /

Purge E q u i p m e n t :Geote ch P e r i s t a l t i c P u m pSerial N o .S a m p l e E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O / T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Meter:S o l i n s tPunm-Conta iner iz ed?

^(3S/ NO

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( 1 1 ( 7 / 2 0 ) 5Meter C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a l ° CC o n d u c t a n c e S t a n d a r d : umhos/ cm a t 2 5 ° CMeasured V a l u e :

Timeumhos/cm at 25°C

Disso lved OxygenC a l i b r a t e d to mq/ l at

T i m e° C

N A P L Present? Y e s N oEst imated v o l u m e / t h i c k n e s s ( g a l / i n ) ?D e s c r i p t i o n :S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :G r o u n d w a t e r S a m p l e C o l l e c t e d ? A ' e s ^ ) N oG r o u n d w a t e r S a m p l e D e p t h (ft.): ^^Groundwat er S a m p l e I D : iTil/O^"?-^ - N l ~ C T |

pH&.<&

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I n a l y s e s Requested (see C O C ) F u l l S u i t e Part ial S u i t e ( e x p l a i n )J Q C S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p BlankI d d i t i o n a l Analyses: (AjÂ/L T X / o r ^ j L / C Ôt' : Jt2/K, //~^cS j>(îliA| * QiAjLJlT'IB• j d i t i o n a l Comments:r ckkpitc&L• /\n(A> 2"?-F /-7 <5 a

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r / o i r f ^C ( C T ^ t X t ' >

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Protect ive L e v e l :B C D

S E R I A L N O .H S O S i g n a t u r e :C o n d i t i o n o f W e l l , Remarks:

S a m p l e r ' s S i g n a t u r e : (^P^L^r

000633

| GROUNDWA TER SAMPLING HELD DA TA SHEETJ L a s t W e l l I D N o . Last Date

f f f r W f e * - 6 - K - n - 7l e a s i n g Diameter -.• ' i — inRasing S t i c k u p ^ /

I C~- int f o t a l W e l l 1 D e p t h Las t T o t a l W e l l•rom T O C L , D e p t hI s t a t i c W a t e r L a s t S t a t i c W a t e r

B e v e l j f f r o m T O C ) LevelI .43 ft. ft[ W a t e r T h i c k n e s s• ft

•Veil Diameter^FactorT D i a m e t e r / 2 " ) 4" 6" 8"1 F a c t o r (.16^.65 1.47 2.61

Rasing V o l u m e '• gai.(Screened I n t e r v a l ( f r o m G S )* f t .

I T i m e

P f e ?L\(%&\9^>0mffrfimfi^G\\$&


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oon0, 5l-o1.2.|,q

Purge E q u i p m e n t :Geotech P e r i s t a l t i c P u m pS e r i a l N o .S a m p l e Equ ip imen t:Geotech P e r i s t a l t i c P u m pS e r i a l N o .A n a y l t i c a l E q u i p m e n t :( p H / c o n d / D O f T e m p )Y S I 3560XLS e r i a l N o .W a t e r Level Muter:S o l i n s tP u m p - C o n t a i n e r i z e d ?

D e s t i n a t i o n : - jOA.J<:5 tj2 TX^&W a t e rLevel

0.08g&lq.u^M6Q.(t

T e m p ^ 5ww(fte-TJj66-266«5. 36M^(fi\rk

n m h o s / c m

zzz^ 3Z Z 3ZZ325 iZ33

T a s k CODJob # 'Z^Cfy"! .OCL?. OCB


Loq Book #Page | of 1

T i m e DateMeter C a l i b r a t i o n T i m ep H = a t ° C

T i m ep H = a t ° CConduc tance S t a n d a r d : urrMeasured V a l u e : umhos/cm at 2Dissolved OxygenC a l i b r a t e d to mq/l at

ho s/cm a t 2 5 ° CT i m e

5 ° CT i m e

° CN A P L Present? Y e s N oEst imat ed v o l u m e / t h i c k n e s s ( q a l / i n ) ?Descr ipt ion:S a m p l e c o l l e c t e d ? Y e s N oS a m p l e I D :G r o u n d w a t e r S a m p lGroundwat e r S a m p l eG r o u n d w a t e r S a m p l ei / i h j

PH

7.02.fe^4

G » / 3 b/ (tg?i M ' ^ T4?.

Analyse s Requested ( s e e COC) Ful l S u i t e Partial S u i t e ( e x p l a i n )J Q C S a m p l e s : G C / M S Rinse Blank F i e l d Blank T r i p BlankA d d i t i o n a l A n a l y s e s :

B > d d i t i o n a l Comments: |\5\%? C^l ' l / l x 'CT ^ ( T ^ W X i V M ^ l^«T


1ASU3^( - 3 3U?y^$

t/&b, me


S E R I A L N O

e C o l l e c t e d ? ( Y e s , ) N oD e p t h (ft.): ^^Î D : m ( / 0 7 J 8 - 6 - A ( - o r 7QMPump'R a J e < G P M

1 "73/5I ' W . M

l " 7 W j Onz.2i ^ / o/ ( / ^ ^



D e s c r i p t i o n*•

d^'/i

C&x%s\ck^xL^CisvdLvi.

I n i t i a l Readings: S a m p l e Readings:T O C T O CBZ BZBkqnd Bkqnd

Protec t ive L e v e l :B C D

H S O S i g n a t u r e :C o n d i t i o n o f Wel l , Remarks:

A7&&1S a m p l e r ' s S i g n a t u f e r y ' /

000634

IIIIIIIII ATTACHMENT 3| R E G I O N A L DATA REVIEW REPORTIIIIIIIII

000635

U N I T E D S T A T E S E N V I R O N M E N T A L P R O T E C T I O N A G E N C YR E G I O N 6

H O U S T O N B R A N C H10625 F A L L S T O N E R D .

H O U S T O N , T E X A S 77099

M E M O R A N D U M

D a t e : December 11, 2000S u b j e c t : C o n t r a c t L a b o r a t o r y Program D a t a ReviewF r o m : M a r v e l y n V H i j m p h r f f i y , A l ^ t e r n g / t e E S A T RPO, 6 N D - H CT o : D . A b s h i r e , 6 S F - A T

S i t e : _ _ _ _ T E X A R K A N A WOOD P R E S E R V I N G CO._____

Case#:____28724_____________________________S D G # ; F05C1____________________________

The EPA Region 6 H o u s t o n Branch ESAT d a t a review team hasc o m p l e t e d a review of the s u b m i t t e d C o n t r a c t Laboratory Program( C L P ) d a t a pa ckage f o r the: r e f e r e n c e d s i t e . T h e s a m p l e s analyzedand reviewed are d e t a i l e d in the a t t a ch ed Regional da ta reviewrepor t .The d a t a package i s a i c c e p t a . b l e f or regional use. P r o b l e m s , i fany, are l i s t e d in the report narrative.If you have any ques t ions r egard ing the d a t a review r e p o r t ,p l e a s e ca l l me at ( 2 8 1 ) 983-2140 .A t t a c h m e n t scc: R. F l o r e s , Region 6 C L P / T P O

M. E l - F e k y , Region 6 Data C o o r d i n a t o rF i l e s ( 2 )

000636

L O C K H E E D M A R T I N S E R V I C E S GROUPF . S A T R E G I O N V I

10101 S O U T H W E S T F R E E W A Y , S U I T E 5 0 0H O U S T O N , T X 77074

M E M O R A N D U M

D A T E : December 11, 2000T O : M e l v i n R i t t e r / M a r v e l y n H u m p h r e y , E S A T R F C / A l t e r n a t e

RPO, R e g i o n VI „J , , M f .FROM: T o m C . H . C h i a n g , E S A T T e a m M e a g e r , Region V I

S U B J E C T : C L P D a t a ReviewR E F : T D F # 6-1071A E S A T # 0-2282E S A T C o n t r a c t N o . , 6 8 - D 6 - 0 0 0 5

A t t a c h e d i s t h e d a t a review summary f o r C a s e # _ _ 2 E I 7 2 4S D G # _ _ F 0 5 C 1S i t e T e x a r k a n a W o o dP r e s e r v i n g C o .

C O M M E N T S :

I . C O N T R A C T U A L A S S E S S M E N T O F T H E D A T A P A C K A G ET h e C C S r e p o r t w a s u n a v a i l a b l e a t t h e time t h i s d a t a reviewr e p o r t w a s p r e p a r e d . T h e reviewer f o u n d t h e h a r d c o p yp a c k a g e c o n t r a c t u a l l y c o m p l i a n t .

I I . T E C H N I C A L U S A B I L I T Y A S S E S S M E N T O F T H E D A T A P A C K A G ET h e t o t a l number o f r e s u l t s reviewed w a s 1 ,003 f o r t h i s d a t ap a c k a g e . A l l r e s u l t s a r e a c c e p t a b l e .

Page 1 of 17

000637

IIIIIIIIIIIIIIIIIII

U N I T E D S T A T E S E N V I R O N M E N T A L P R O T E C T I O N A G E N C YR E G I O N 6

H O U S T O N B R A N C H10625 FALLSTONE ROADH O U S T O N , T E X A S 77099

O R G A N I C R E G I O N A L D A T A A S S E S S M E N T

C A S E N O .L A B O R A T O R YC O N T R A C T SS D G #S O W *A C C T #S F #S A M P L E N O .

2 8 7 2 4M I T K E M6 8 - D 6 - 0 0 6 3F 0 5 C 1S O W O L C 0 2 . 11 5 0 1 0 2 D J N 1 35 0 1 0 2 D 9 1

F O - 5 C 1F O - 5 C 2F O - 5 C 3F O - 5 C 4

S I 1

N OM A 1

R E 'R E 'CO!

F O - 5 C 5F O - 5 C 6F O - 5 C 7F O - 5 C 8

S I T E T e x a r k a n a W o o d P r e s e r v i n g C o .N O . O F SAMPLES________17_________W a t e rE S A TR E V I E W E R ( I F N O T E S D ) .R E V I E W E R ' S N A M E Y i n a - P i n a H s i e hC O M P L E T I O N D A T E December 1 1 . 2000

F O - 5 C 9F O - 5 D OF O - 5 D 1F O - 5 D 2

D A T A A S S E S S M E N T S U M M A R Y

1.2.3.4.5.6.7.8.9.10.11.

H O L D I N G T I M E SG C / M S T U N E / I N S T R . P E R F O R M .C A L I B R A T I O N SB L A N K SS M C / S U R R O G A T E SL A B O R A T O R Y C O N T R O L S A M P L E S ( L C S ]O T H E R Q CI N T E R N A L S T A N D A R D SC O M P O U N D I D / Q U A N T I T A T I O NP E R F O R M A N C E / C O M P L E T E N E S SO V E R A L L A S S E S S M E N T

F O - 5 D 3F O - 5 D 4F O - 5 D 5F O - 5 D 6

B N A

0

F O - 5 D 7

0000000O

0 = D a t a had nc p r o b l e m s .M = D a t a q u a l i f i e d due toZ = D a t a u n a c c e p t a b l e .N A = N o t a p p l i c a b l e .m a j o r or minor p r o b l e m s ,

A C T I O N I T E M S :AREA OF C O N C E R N :N O T A B L E P E R F O R M A N C E : T h e d a t a p a c k a g e arr ived 3 c a l e n d a r d a y se a r l y f o r t h e c o n t r a c t u a l 1 4 - d a y t u r n a r o u n d t ime .

Page 2 of 17

000638

C O M M E N T S / C L A R I F I C A T I O N SR E G I O N VI CLP QA REVIEW

C A S E 2 8 7 2 4 S D G F 0 5 C 1 S I T E T e x a r k a n a W o o d P r e s e r v i n g C o . L A B M I T K E MThe f o l l o w i n g i s a summary o f s a m p l e q u a l i f i e r s used by R e g i o n 6i n r e p o r t i n g t h i s C L P d a t a : :

____No,___ A c c e p t a b l e _ P r o v i s i o n a l U n a c c e p t a b l eBNA _____17_____ ___________ ___________

C O M M E N T S : T h i s S D G c o n t a i n s 1 7 wa t e r s a m p l e s f o r l o wc o n c e n t r a t i o n B N A a n a l y s i s b y S O W O L C 0 2 . 1 . A c c o r d i n g t o t h eO T R / C O C r e c o r d s , s a m p l e s F O - 5 D 2 a n d F O - 5 D 3 were f i e l d d u p l i c a t e s ,s a m p l e F O - 5 D 4 w a s a f i e l d b l a n k , a n d s a m p l e F O - 5 C 3 w a s a r i n s a t e .T h e d a t a p a c k a g e arrived 3 c a l e n d a r d a y s e a r l y f o r t h ec o n t r a c t u a l 1 4 - d a y t u r n a r o u n d t i m e , and i t was c o n t r a c t u a l l yc o m p l i a n t . .The o n l y t a r g e t a n a l y t e r e p o r t e d a t a c o n c e n t r a t i o n above th eCRQL was a c e n a p h t h e n e in t h i s S D G , and i t was o n l y d e t e c t e d ins a m p l e s F O - 5 D 2 a n d F O - 5 D 3 . A l l r e s u l t s a r e a c c e p t a b l e . T h et e c h n i c a l u s a b i l i t y o f a l l r e p o r t e d s a m p l e r e s u l t s i s i n d i c a t e db y E S A T ' s f i n a l d a t a q u a l i f i e r s i n t h e D a t a S u m m a r y T a b l e . A nE v i d e n c e A u d i t w a s c o n d u c t e d f o r t h e C o m p l e t e S a m p l e D e l i v e r yG r o u p F i l e ( C S F ) , a n d t h e aud i t r e s u l t s were d o c u m e n t e d i n t h eE v i d e n c e I n v e n t o r y C h e c k l i s t .

N O T E : T H E F O L L O W I N G R E V I E W N A R R A T I V E A D D R E S S E S B O T H C O N T R A C T U A LI S S U E S ( B A S E D O N T H E S T A T E M E N T O F W O R K ) A N D T E C H N I C A L I S S U E S( B A S E D O N T H E N A T I O N A L F U N C T I O N A L G U I D E L I N E S ) . T H E A S S E S S M E N T

M A D E F O R E A C H Q C P A R A M E T E R I S S O L E L Y B A S E D O N T H E T E C H N I C A L D A T AU S A B I L I T Y , W H I C H M A Y N O T N E C E S S A R I L Y B E A F F E C T E D B Y C O N T R A C T U A LP R O B L E M S . T H E A S S E S S M E N T S A R E D E F I N E D B E L O W .A c c e p t a b l e = N o r e s u l t s were q u a l i f i e d f o r a n y p r o b l e ma s s o c i a t e d w i t h t h i s QC p a r a m e t e r .P r o v i s i o n a l = S o m e r e s u l t s were q u a l i f i e d because o f p r o b l e m sa s s o c i a t e d w i t h t h i s QC p a r a m e t e r .U n u s a b l e = A l l r e s u l t s a r e u n u s a b l e because o f m a j o r p r o b l e m sa s s o c i a t e d w i t h t h i s QC p a r a m e t e r .1 . H o l d i n g T i m e s : A c c e p t a b l e . A l l s a m p l e s m e t c o n t r a c t u a l a n dt e c h n i c a l ( 4 0 C F R P a r t 1 3 6 ) h o l d i n g t ime c r i t e r i a .2 . T u n i n g / P e r f o r m a n c e : A c c e p t a b l e . T h e D F T P P a n a l y s e s m e t G C / M St u n i n g c r i t e r i a .3 . C a l i b r a t i o n s : A c c e p t a b l e . T C L c o m p o u n d s m e t c o n t r a c t u a lc a l i b r a t i o n c r i t e r i a . T h e a n a l y t e 4 - c h l o r o a n i l i n e f a i l e dt e c h n i c a l % R S D a n d % D c a l i b r a t i o n c r i t e r i a . D a t a q u a l i f i c a t i o nwas u n n e c e s s a r y b e cau s e t h i s a n a l y t e was not d e t e c t e d in anys a m p l e .

Page 3 of 17

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O R G A N I C QA REVIEWC O N T I N U A T I O N PAGE

C A S E 2 8 7 2 4 S D G F 0 5 C 1 S I T E T e x a r k a n a W o o d P r e s e r v i n g C o . L A B M I T K E M4 . Blanks: A c c e p t a b l e . T h e m e t h o d b l a n k s m e t t h e c o n t r a c t u a lc r i t e r i a . No t a r g e t a n a l y t e s were d e t e c t e d in th e method b l a n k s .F i e l d Blank: N o t a r g e t a n a l y t e s were d e t e c t e d i n f i e l d b l a n ks a m p l e F O - 5 D 4 , d e m o n s t r a t i n g t h e r e w a s n o f i e l d c o n t a m i n a t i o n .Rinsat e: T h e a n a l y t e b i s ( 2 - e t h y l h e x y l ) p h t h a l a t e w a s d e t e c t e d a t ac o n c e n t r a t i o n b e l o w t h e C R Q L i n r i n s a t e s a m p l e F O - 5 C 3 .A s s e s s m e n t f o r s a m p l i n g e q u i p m e n t c o n t a m i n a t i o n can no t b ep e r f o r m e d because i n f o r m a t i o n a s s o c i a t i n g t h e s a m p l e s w i t h t h er i n s a t e i s n o t a v a i l a b l e . H o w e v e r , p l e a s e no t e t h a tb i s ( 2 - e t h y l h e x y l ) p h t h a l a t e wa s o n l y d e t e c t e d a t a c o n c e n t r a t i o nb e l o w t h e C R Q L i n s a m p l e F O - 5 C 7 i n t h i s S D G .5 . S y s t e m M o n i t o r i n g Compound s ( S M C 1 s ) / S u r r o g a t e s : A c c e p t a b l e .All s u r r o g a t e r e cover i e s met QC c r i t e r i a .6 . Laboratory Contro l S a m p l e s ( L C S ) : A c c e p t a b l e . T h e L C Sre cover i e s m e t c o n t r a c t u a l c r i t er ia . A l t h o u g h c o n t r a c t u a l l ya c c e p t a b l e , the recovery o:: 4 - c h l o r o a n i l i n e e x c e e d e d the QCl i m i t . S i n c e 4 - c h l o r o a n i l i n e wa s no t d e t e c t e d in any s a m p l e ,d a t a q u a l i f i c a t i o n w a s u n n e c e s s a r y .7. Other QC:F i e l d d u p l i c a t e s : A c c e p t a b l e . T h e r e s u l t s f o r t h e f i e l dd u p l i c a t e s were c o n s i s t e n t . ,8 . I n t e r n a l S t a n d a r d s ( I S ) : A c c e p t a b l e . I n t e r n a l s t a n d a r dp e r f o r m a n c e me t th e QC c r i t e r i a f or a l l s a m p l e s and s t a n d a r d s .9 . Compound I d e n t i t y / Q u a n t a . t a t i o n : A c c e p t a b l e . T h e o n l y t a r g e ta n a l y t e r e p o r t e d at a c o n c e n t r a t i o n above the C R Q L wasa c e n a p h t h e n e i n t h i s S D G , a n d i t w a s o n l y d e t e c t e d i n s a m p l e sF O - 5 D 2 a n d F O - 5 D 3 . T h e r e p o r t e d a n a l y t e s m e t compoundi d e n t i f i c a t i o n c r i t e r i a .1 0 . P e r f o r m a n c e / C o m p l e t e m s s s : A c c e p t a b l e . T h e d a t a p a c k a g e w a sc o m p l e t e but had one o m i s s i o n and some r e p o r t i n g errors. Thel a b o r a t o r y w a s c o n t a c t e d f o r t h e n e e d e d c o r r e c t i o n s a n dr e s u b m i s s i o n s ( s e e F A X Record L o g ) .11 . Overall A s s e s s m e n t : All r e s u l t s ar e a c c e p t a b l e .

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000640

O R G A N I C D A T A Q U A L I F I E R D E F I N I T I O N S

T h e f o l l o w i n g d e f i n i t i o n s p r o v i d e b r i e f e x p l a n a t i o n s o f t h eE S A T - R e g i o n 6 q u a l i f i e r s a s s i g n e d t o r e s u l t s i n t h e D a t a S u m m a r yT a b l e .

U Not d e t e c t e d a t r e p o r t e d q u a n t i t a t i o n l i m i t .N I d e n t i f i c a t i o n i s t e n t a t i v e .J E s t i m a t e d v a l u e .L R e p o r t e d c o n c e n t r a t i o n i s b e l o w the C R Q L .M R e p o r t e d c o n c e n t r a t i o n s h o u l d be used as a ra i s edq u a n t i t a t i o n l i m i t because o f i n t e r f e r e n c e s a n d / o rl a b o r a t o r y c on tamina t i on .R U n u s a b l e .

H i g h b i a s e d . A c t u a l c o n c e n t r a t i o n may b e l ower than th ec o n c e n t r a t i o n r e p o r t e d .V Low b i a s e d . A c t u a l c o n c e n t r a t i o n may be h i g h e r than thec o n c e n t r a t i o n r e p o r t e d .F + A f a l s e p o s i t i v e e x i s t s .F - A f a l s e n e g a t i v e e x i s t s .B T h i s r e s u l t may b e h i g h b i a s e d because o f l a b o r a t o r y / f i e l dc o n t a m i n a t i o n . The r e : p o r t e d c o n c e n t r a t i o n is above 5X or10X the c o n c e n t r a t i o n r e p o r t e d in th e m e t h o d / f i e l d b l a n k .U J E s t i m a t e d q u a n t i t a t i o n l i m i t .T I d e n t i f i c a t i o n i s q u e s t i o n a b l e because o f absence o f o thercommonly c o e x i s t i n g p e s t i c i d e s .* R e s u l t no t r e c o m m e n d e d , f o r u s e because o f a s s o c i a t e d Q A / Q Cp e r f o r m a n c e i n f e r i o r t o t h a t f r o m o t h e r a n a l y s i s .

Page 5 of 17

000641

Case N o . :Laboratory:

28724M I T K E M

O R G A N I C D A T A S U M M A R YS D G : F O S C 1M a t r i x : Water

Reviewer: Y. H s i e hU n i t s : ug /L

O C M I V U L A I I L CE R A S A M P L E N U M B E R : FO-5C1 F O - 5 C 2 F O - S C 3 I r i y M j I r L A t a| F O - S C 4 _____ | FO-5CS _____FO-5C6 | FO-SC7j R f i e -bi s(2~Chloroe thyl) ether ___ -_ ___________________i

M i l « i 8 5 B t i i H i » A U5 L I 5 U

2,4-Dimethylphenol2,4-Dichtorophenol

loro-3-methylpnenolHexachlorocyc iopentad i ene2,4,5-Tncnlorophenol

20 U 20 if4-Bromophenyt-phenyletherPentachlorophenolAnthraceneFluoranthene S U s u 5 U ^™"™ 5 U 5 U 5 U S U

'BiialB u t y l b e n z y l p h t h a l a t e

b i s ( 2 - E t h y l h e x y l ) p h t h a l a t e$msg&mm®gR—Benzo(b)f luoranthene

5 U S U0y-"!t*B!*f^^

Benzo(a)pyrene i a i f l.5 U 5 U..,__.._____Oibenzo(a.h)anthracehe 5 U 5 U 5 U v » a R A i ' £ ^ v ® a i t j 3 ^ " ^ y ' 7 w a % a a j : O . a u ^ ? ^ i t ' . ^ ^ a ' ! i - < o > t U g ^ ' A i5 4 ______ 5 u 5 U _____S U5SU tsfîef^^ssS^jj^^^s^taiîo^nh^âs^^ô^ffAK^j

S a m p l e Volume ( m L ) :Dilu t i on F a c t o r :

N u m b e r o f T I C ' s :

100010

100010

100014

100010

100010

100010

100010

N o t e : For the r e su l t s l i s t ed in the Data Summary T a b l e , ESAT has replaced the laboratory assigned f l a g s withESAT Organic Data Q u a l i f i e r s . The ESAT f l a g s indi ca t e the technical u sab i l i ty of the reported results.

P a g e 6 of 17

000642


28724M I T K E M

O R G A N I C D A T A S U M M A R YS D G : F 0 5 C 1Matrix: Water

Reviewer: Y. H s i e hU n i t s : ug/L

2,4-Dimethylphenol

& B m * « B > ^ T f l ' " f ^ ° ^ T ' H l T r i - . H K n l t4-Chloro-3-methyl phenolH exacfi l orocydopentadiene2,4 ,5-Tnchlorophenol

2 , 4 - O m i t r o p h e n o l '

«^W^t^ |V-*^Lttfji<Aa^JUl^^J5 U 5 U4,6-Dmitro-2-rnetnylpnenol

ntachloroohenol

Benzo(a)anthracener l M *** - - ^( 2 - E t h y l h e x y l ) p h t h a l a t e

B e n z o ( b ) f l u o r a n t t i e n e

Dibenzo(a.h)anthracene

S a m p l e Volume ( m l ) :D i l u t i o n F a c t o r :


Note: For the r e su l t s l i s t ed in the Data Summary T a b l e , ESAT has replaced the laboratory assigned f l a g s withESAT Organic Data Q u a l i f i e r s . The ESAT f l a g s indicate the technical u sab i l i ty of th<! reported results.

Page 7 of 17

000643

IIIIIIIIIIIIIIIIIII


28724M I T K E M

O R G A N I C D A T A S U M M A R YS D G : F 0 5 C 1M a t r i x : Water

Reviewer: Y. H s i e hU n i t s : ug/L

S t M I V U L A I I L tE R A S A M P L E N U M B E R FO-5D5 FO-5D6 FO-5D7

b i s ( 2 - C h l o r o e t h y l ) ether""2-Methyiphenol44S5thyiphenort t i L N i t r c s o B ? P j j p t _H e x a c h l o f o e t h a n el i ophorone2^Di"me*ylphenoT2r4-Dichloropr7ehbl

^^s: iU':F?gr:?T:^5TJ^^^

4 - C h l o r o a n i l i n e4-Chloro-3-methylphenolH e x a c h l o r o c y c l o p e n t a d i e n e

l2,4^tncriiorpp"heriol "" *2 - N i t r o a n i ' l i n e " " " * ' ' ' ' %

"Acenaphtriyiene"'3 - N i t f o a n i l i n e ~

______ _______________________________ _________5 ; ^________________________M^ ^

^j^^ _______

20 Ui5 U^20 U

~ U 20 U _..^;,. .•._.J,••,.. ._. _.„ ____________________5 U 5 U

2,4-DinitrophenolD i b e n z o ' f i i r a nD i e t h y l p h t h a l a t eF l u o r e r i e4 ' ^ D l r T i t ^ 2 ^ m e 9 i y i p h e n 6 r4-Brornbphenyl-phenyietherPeri tachiorophenol~AnthraceneD K £ ! 5 f f l S ^ i § i W g S S ? ! A v " s 'F l u o r a n t h e n eB u t y l b e n z y l p h t t i a l a t e3;3' :DichlpjiolJercB(line2^ "Ben20(a)aritliraceneC h r j p n f J l E S i S f M - ^ "b i s ( 2 - E t h y l h e x y l ) p h t h a l a t eD i ^ i o d y l p j y t e j a t e 3 J 3 ' y ^Ben26(b)fluoranth"eneBerji^)f1.uit»an*iehe]J],y^Benzb(a)pyrene "_" .Dibenzo(a.h)anthraceneBenzb(g,h;i)peryfer)e;~"~

S a m p l e V o l u m e ( m L ) :D i l u t i o n F a c t o r :


-.

^_____ _______________________

^ 5 U

^S^

^___^~-Tî^*<cy>^^Tirn"vJV*/7i?:^^-'t:?^- L; ; ^J^

100010

100010

100010

N o t e : For the r e s u l t s l i s t e d in trie Data Summary T a b l e . ESAT has replaced the laboratory assigned f l a g s withESAT Organic Data Q u a l i f i e r . The ESAT f l a g s i n d i c a t e th e technical u s a b i l i t y o f th e reported results.

P a g e 8 of 17

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• I N O R G A N I C / O R G A N I C C O M P L E T E S D G F I L E ( C S F ) I N V E N T O R Y C H E C K L I S TI f c a s e No. 28724 SDG No. F 0 5 C 1 SDG N o s . To F o l l o w SAS Mo. Date Rec 1 2 / 1 / 0 0

1 E P A L a b I D : M I T K E M• Lab Location- 175 Metro Center Blvd. Warwick. PA 02886P Region: 6 Audi t No.: 2 8 7 2 4 / F 0 5 C 1

I Re S u b m i t t e d CSF? Yes No X• ROT N o f s V 1¥ C O M M E N T S :• rtpm Descr ip t ionI 8. The C a s e / S D G numbers were entered incorrectly onT Form DC-1 (page 250). The auditor corrected them.

(Over for addi t ional comments.

O R I G I N A L SC U S T O D Y S E A L S1 . Present on package?2. Intact uoon receipt?FORM DC-23. Numbering scheme accurate?4. Are enclosed documents l i s t e d ?5. Are l i s t e d documents enclosed?FORM DC-16. Present?7. Compl e t e?8. Accurate?C H A I N - O F - C U S T O D YRECORD(s)9. Signed?10. Dated?

T R A F F I C REPORT(s)P A C K I N G L I S T ( s )11. Signed?12. Dated?A I R B I L L S / A I R B I L L S T I C K E R13. Present?14. S i e n e d ?15. Dated?S A M P L E T A G S16. Does DC-1 li s t tags as being included?17. Present?O T H E R D O C U M E N T S18. C o m p l e t e ?19. Legib l e?20. Original?20a. If "NO", does the copy indicatewhere original documents are located?

YES

XXXXXXX

XX

XX

XXX

XX

XX

X

NO

X

X

N / A

•Audit ed by:Audit ed by:Audited by:

Signature

Y i n g - P i n g Hsi eh/ESAT Data P.eviewer

Printed N a m e / T i t l e

Date 12/8 /00Date _____Date

Date Recvd by CEAT:Entered by:

Reviewed by:

TO BE C O M P L E T E D BY CEATDate Entered: Date Reviewed:

Signature Printed N a m e / T i t l e

IDC-2

Page 9 of 17

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P a g e 1 of 1I n R e f e r e n c e t o C a s e N o ( s ) :2 8 7 2 4 S D G : F 0 5 C 1 ( 0 - 2 2 8 2 )

Contract Laboratory ProgramR E G I O N A L / L A B O R A T O R Y C O M M U N I C A T I O N S Y S T E MFAX Record Log

Laboratory N a m e : ______MITKEM______________Lab Con ta c t : _____Agnes R. Ng_________Region: ______£__________________Regional C o n t a c t : _Mahmoud E l - F e k y - EPA______E S A T Reviewer: _ Y i n a - P i n g H s i e h - E S A T _ _ _ _ _FAX ini t iated by: ___Laboratory X Region

In re ference to data for the f o l l o w i n g f r a c t i o n s :C S F D e l i v e r a b l . e s B N A

Summary of Q u e s t i o n s / I s s u e s :A . C S F Deliverable s

The C a s e / S D G numbers were entered i n c o r r e c t l y on F o r m DC-1( p a g e 2 5 0 ) . P l e a s e revise a n d resubmit th i s p a g e .B. BNA

F o r m 8 ' s f o r t h e i n i t i a l c a l i b r a t i o n were omi t t ed ( O L C 0 2 . 1 ,p. B-18, sec. 2 . 6 . 4 . 1 . 5 ) . P l e a s e submit at t h i s time asp a g e s 18A and 1I3B.N O T E : Any l a b o r a t o r y r e sub tn i s s i on shou ld be s u b m i t t e d e i ther asan a d d e n d u m to the o r ig ina l CSF wi th a revised F o r m DC-2 ors u b m i t t e d as a new CSF wi th a new F o r m DC-2 ( O L C 0 2 . 1 , p. B-31,2 . 7 . 3 ) , e x c e p t tho s e c o n t a i n i n g o n l y r e p l a c e m e n t p a g e s . C u s t o d ys e a l s a r e required f o r a l l C S F r e submi s s i on s h i p m e n t s .P l e a s e r e s p o n d to the above i t ems within 7 days to:

M r . Mahmoud E l - F e k yU . . S . E P A Region 6 L a b o r a t o r y10625 F a l l s t o n e RoadH o u s t o n , T X 77099If you have any q u e s t i o n s , p l e a s e contact me a t ( 2 8 1 ) 983-2128.

S i g n a t u f f e " " ? D a t eDistribut ion: ( 1 ) L a b C o p y , ( 2 ) Region C o p y , a n d ( 3 ) E S A T CopyPage 10 of 17

000646

a n 5 f , i w l l& C h a i n Of C u s t o d y Record( F o r . Organic C L P A n a l y s i s )1. Project CodeAccount CodeS i l e N a m e

C i t f c S l a t e S i t e S p i l l I D Op Unit

2. Region No. Sampling Co.S a m p l e r (Name)S a m p l e S i g n a l u r e3. Purposele*T3 < S FPRPn0BZ

Eaif c ActionPA_ R E MRlis.

L o n g - T e r mActionI R I F S04M

4. Date Shipped CarrierA i r b i l l Number5. Ship To: -

/H<?/x>o C

A T T N :

6. Matiix(Enter inColumn A)1. Surface W a t e r2. Ground W a t e r3. Leacha t e4. Field QC '5. Soi i /SedimenI6. PE-waler7. PE-soil .8. Other (specify inColumn A)

7. Preservative(Enter inColumn D)1. HCI2. HN033. NaHSOJ4. H2S045. Ice on ly6. CH30H7. Other (specifyIn Column D)N . N o t Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o mBox 6)

Other

Bone.:

LowMed

CS a m p l eT y p e :C o m p . /Grab

DPreser-vat ive( f r o mB o x ? )Other:

T APR* 7 H 21

R A S A n a l y s i sTA(idea.)PR* r M 21

VOAPR* 7 14 21

B N A P e s t /PCB

Regional S p e c i f i cT r a c k i n g N u m b e ror Tag N u m b e r sG :Station 'Location .i d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o nC o r r e s p o n d i n gC L P I n o r g a n i cS a m p l e N o .

JS a m p l e rI n i t i a l sKReld QCQ u a l i f i e r

B ' B J j n k S ' R e M S p i ePE • Perionn Ent

2. u V2- y 102.0F.D5C3 2. \\l\\tloo II 00

S h i p m e n t f o r CaseC o m p l e t e ? ( Y / £ ) Page. L o f _ J _ VOA MS/MSP Required? Y/N S a m p l e #:U N A M S / M S P Required? Y f t Q S a m p l e f l :

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain o f C u s t o d y Seal N u m b e r ( s )Pest/PCB MSÎSD Required? Y/N S a m p l e #:

*PR. p r o v i d e s 7-day d a l a turnaround in a d d i t i o n t o p r e l i m i n a r y r e su l t s . Requests f or « i_ • r / • > i j« jp r e l i m i n a r y r e s u l t s w i l l increase a n a l y t i c a l costs. _____(-.Main 01 O U S t O d y K G C O r uR e l i n q u i s h e d by: (Signaluio)ffi^T&ffRel inqu i sh ed by: (Sigildture)

R e l i n q u i s h e d by: (Signature)

Dale / TimeIM<?I0Z>Da

Da

e / Time

e / Time

Receiygdby: (Signature)tidfXReceived by: (Signature)

Received lor Laboratory by:(Signature)

Relinqui shed by: (Signature)

Relinqui shed by: (Signature)tDale / T i m e

I

Dale / Time1Dale / T i m e1

Received by: (Signature) /

•Remarks: Is cu s tody seal intact? Y/N/none \ /

Diskibul ion: Blue • Region C o p y Pink -SMO C o p yWhile • Lab C o p y lot R e l u r n lo SMO Yellow • Lab C o p y for Return to Region ERA Form 9110-2 (2/99) *See Reverse for Purpo s e Code Def ini t ionsC L A S S - 9 9 - 0 0 1

396834000647

( F o r . Organic C L P A n a l y s i s )1. P r o j e c t CodeA c c o u n t CodeS i t e N a m e

C i t y , S t a l e S i t e S p i l l I D Op Unit

2. Region No. Sampling Co.S a m p l e r ( W a m e j

r Signalu3. Purposel e a i f S FPRP

S IF E D02

E a i l y Action

K E MRl_ S IJ £ E S I

L o n g - T e r m

4. Date Shipped CarnerA i r b i l l N u m b e r5. Ship To:

"' 02

6. MatrixlEnler'nColumn A)1. S u r f a c e Water2. Ground Water3. Leachate4. Field QC5. Soil/Sediment6. PE-water7. PE-soil8. Other (specify inColumn A)

A T T N :

7. PreservativeC o / u m n O J1. HCI2. HN033. NaHS044. H2S045. Ice on ly6. CH30H7. Olher (specify/n Column D)N. Not Preserved

C L PS a m p l eN u m b e r s/ f r r t m 1 - i K / i l My i i u n i I O U C I 3 J

AM a t r i x( f r o mBox 6)U D i e t :

BCone.:

LowW e d

cS a m p l eT y p e :C o m p . /Grab

DPreser-vative( f r o mBox 7)Olher:

(c» cio onejiPR* 7 14 21

R A S A n a l y s i s

V G A

T A( C H d S K a '

R* 7 14 21B N A

T A(di t t e CM!PR* 7 14 21

P e s t fPCB

Regional S p e c i f i cT r a c k i n g Numberor Tag N u m b e r sGStation 'Location ,I d e n t i f i e r

HM o / D a y /Y e a r f f i m eS a m p l eC o l l e c t i o n

1C o r r e s p o n d i n gCLP I n o r g a n i cS a m p l e ' N o .JS a m p l e rI n i t i a l s

KField QCQ u a l i f i e rB» Blank S » Fidd Spike) • Field DuplicateI ' R i n u t gP E - P o t o r m E v i

-6:

n_ &L VTFo^CJS •1 L. yL -^y-M-o 7

S h i p m e n t f or CaseC o m p l e l e ? ( Y N ) . Page_ L o f _ / _ V G A M S / M S D Requited? S a m p l e #:B N A M S / M S P Required? Y ^ N ^ S a m p l e # :

A d d i t i o n a l S a m p l e r Signa tur e s Chain of Cus t ody Seal Number(s)P e s t f f ' C B M S I M S D Required? Y / N S a m p l e f r

" P R . p r o v i d e s 7-day d a l a t u r n a r o u n d i n a d d i t i o n t o p r e l i m i n a r y r e s u l t s , , ' t op r e l i m i n a r y r e s u l t s w i l l increase a n a l y t i c a l costs. ques t s f o r C h a i n o f C u s t o d y RecordR e l i n q u i s h e d by: (Signature)^^ê"^^R e l i n q u i s h e d by: (Signature)


, i Dale / T i m e"•/Iffl8&Dale / T i m e

1Dale / TimeI

Received bv: (Signature)p?o(B^Received by: (Signature)

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Date / T i m eI

Date / Time1Dale / T i m e1


Received by: (Signature) /• •/'•'•'Remarks: Is cus tody seal intact? Y/N/none \ . /— — — — — — — — — — — — — — — — — — — — — — — — — — — — — — • — — - — — — — — • — — — — — — — — — — — " — — — — — \ T — — — — — — — — T - — — — — — — — — — ' — — — — — — — — — — — ' . — — —Diil/ ibul ion: Glue • Region Copy Pink • SMO C o p yWhile • Lab Copy lor Return la SMO Yellow • Lab C o p y loi Return la Region

ERA Form 9110-2 (2/99)See Reverse (or Addi t ional S t a n d a r d Ins truc t ions' S e e Rever sV(o[Purpo s e Code D e f i n i t i o n s

CLASS-99-001

3 9 6 8 3 5000648

O P cn PL.,;.. r t f r , , _ i _ j , . D _ _ _ _ J& C h a i n Of C u s t o d y Record( F o r Organic C L P A n a l y s i s )1. P r o j e c t C o d eA c c o u n l CodeS i t e N a m e . ALUoocJ/

i t y , S t a t e S i t e S p i l l I D Op Unit —

a l e S h i p p e d Carrier 6. Matrixi l l N u m b e r

5. Ship To: ./-7 ^ u /L r rt/ 4/VO /yidfrto C~iSAjfcy /Zlvcf.

/ / \ ~ ^( YO /) 7 32, ~* O Y£>£>A T T N :

1. Surf ace W a t e r2. Ground Water3. L e a c h a l e4. Field QC '5. Soil/Sediment6. PE-waler7. PE-soil8. Other (specify inColumn A)

Preservative(Enter inColumn D)1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Other (specifyIn Column D)N. Not Preserved

C L PS a m p l eNumber s( f r o m l a b e l s )AM a t r i x( f r o mBox 6)

O t f i e r

BCone.:

LowMed

Ca m p l eT y p e :Comp./Grab

Dreser-vativef i r o mBox 7)Other

R A S A n a l y s i sT Aj a ido ore)

IPR* 7 14 21V G A

TA TAisoPR* 7 14 21

B N A

Regional S p e c i f i cT r a c k i n g N u m b e ror Tag N u m b e r sPes t /PCB

6 ;Station 'Locat ion ,i d e n t i f i e rHM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o n

IC o r r e s p o n d i n gC L P I n o r g a n i cS a m p l e ' N o .JS a m p l e rI n i t i a l s

KField QC .Q u a l i f i e r8 ' B l a n k S ' F i e l d S f A e). Field DupiuteR ' R i n u l aP E ' P a t o m E v a L

&SCT7 L 6 .5"H/n oo

S h i p m e n t f o r CC o m p l e t e ? ( Y / PageJ _ o f _ L VOA MS/MSP Required? Y/N S a m p l e #:B N A M S / M S D Required? Y J S > S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain o f C u s t o d y Seal Number f s)P e s l / P C S M S / M S D Required? Y / N S a m p l e d z'PR p r o v i d e s 7-day d a t a turnaround in a d d i t i o n to p r e l i m i n a r y resul t s . Requests (or «i,-8_ -* ^,,«.*«/j., O~~~,Ap r e l i m i n a r y r e s u l t s W i l l increase a n a l y t i c a l costs. • C h a i n O f C U S I O d y ReCOra

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D a t e / Time \1 ADate / T i m e1

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• Remarks: Is cus tody seal intact? Y/N/none ^-^^

Dis l i i bu l i on: Blue • Regun Cop/ Pink - SMO C o p yWhile - Lab Copy lot Return to SMO Yellow • Lab C o p y (or Return la Region EPA F o r m 9110-2 (2/99)S e e Reverse f o r A d d i t i o n a l S t a n d a r d I n s t r u c t i o n s

See Reverse for Purpose Code D e f i n i t i o n sC L A S S - 9 9 - O O I

396836000649

A i r b i l l N u m b e r807/ZI/&0

s c m T o n m e m a T F r o l e c l i o n A g e n c yC o n t r a c t L a b o r a t o r y Program• O p l c T M i l R e& C h a i n of C u s t o d y Record( F o r Organic C L P A n a l y s i s )

1. P r o j e c t Code 6. Matrix(Enter inColumn A)1. S u r f a c e W a t e r2. Ground W a t e r3. L e a c h a l e4. Field QC5. Soi l/Sediment6. PE-waler7. PE-soil8. Other (specify inColumn A)

Preservative(Enter inColumn DJ1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Other (specifyin Column D)N . N o t Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )AM a t r i x( f r o m

D™ C\L J U A u ;Olher:

BCone.:

LowMed

CS a m p l eT y p e :C o m p . /Grab

DPreser-vat ive{ f r o mBox 7)Other:

T A3rdc ons!PR* 7 14

R A S A n a l y s i s

PRV G A

T A[drcis a*)PR*

B N A

TAi iClo ur»j

7 14 21P e s l /PCS

FRegional S p e c i f i cT r a c k i n q N u m b e ror Tag N u m b e r sGS t a t i o nLocat ioni d e n i i i i e r

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o n

IC o r r e s p o n d i n gC L P I n o r g a n i cS a m p l e N o .JS a m p l e ri n i t i a l s

KField QCQ u a l i f i e rB "Blank> > f f e l d O i j f i i c * eI ' R i n u l aP E ' P e r t o n n E v a l .

L It/n/ r*i "**_L .5"£30-

S h i p m e n t f o r C aC o m p l e t e ? ( Y / / Page V O A M S / M S D R e q u i r e d ? Y / N S a m p l e * :B N A M S / M S P Required? Y f N l J S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s C h a i n o f C u s t o d y S e a l N u m b e r ( s )P e s l / P C B M S / M S D Required? Y / N S a m p l e ! i :

*PR p r o v i d e s 7-day iâla t u r n a r o u n d in a d d i t i o n to p r e l i m i n a r y r e s u l t s . Reques t s for _. . .«.. . . , n .p r e l i m i n a r y r e s u l t s w i l l increase a n a l y t i c a l costs. C h a i n O f L U S t O d y RecordR e l i n o / i s h e d by'-fiigrialure) 4


R e l i n q u i s h e d by: (Signature) i

, D a l e / T i m em$ \<dvoDal

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Relinquished by: (Signature)*•. Dale / Time

1

Dale / T i m e1Dale / T i m e1


Received by: (Signature) // -.Remaiks: Is cus tody seal inlacl? Y/N/none \ /

\ : /Diil i i bu t ion: Blue - Region C o p y Pink - SMO C o p yWhile - Lab C o p y lor Return to SMO Yellow • Lab C o p y lor Return lo Region ERA F o r m 9110-2 (2/99)

S e e Reverse f o i A d d i t i o n a l S t a n d a r d I n s t r u c t i o n s' S e e Reverse f o r Purpo s e Code D e f i n i t i o n s

C L A S S - 9 9 - 0 0 1

000650

C o n t r a c t Labora tory Programa 0 » t ~ . _ I . . . •& C h a i n of C u s t o d y Record( F o r . Organic C L P A n a l y s i s )1. Pfoj e c lCode 6. Matrix

f E n / e r i f iColumn A)1. Surf ace Water2. Ground W a t e r3. Leachat e4. Field QC5. Soil/Sediment6. PE-water7. PE-soil8. Other (spec/'/y/nC o / o m n A J

7. Preservative(Enter inColumn D)1. HCI2. HN033. NaHS044. H2S045. Ice only6. CH30H7. Other (spea'ry//i Column D)N. Not Preserved

C L PS a m p l eN u m b e r s( f r o m i a b e l s j

AM a t r i x( f r o mBox 6)Other:

BCone.:

LowMed

cS a m p l eT y p e :omp./Grab

DPreser-vative( f r o mB o x ? )Other

RAS Analys i sT A

(ditto o*!IPR* 7 14 21

V G A

TA TA(act: D.TSJPR* 7 14 21

B H A PesVPCB

Regional S p e c i f i cT r a c k i n g N u m b e ror Tag N u m b e r sGStation 'Lxation (i d e n i i i l e r

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o nC o r r e s p o n d i n gC L P I n o r g a n i cS a m p l e N o .

1

JS a m p l e rI n i t i a l sKField QCQ u a l i f i e r

B » Blink S ' R e l i l S p i k t0 • Field DuplicateR ' R l n u KPE • Perform Enf.

U 6D*/ 2- L. &-

S h i p m e n t f o r CaseC o m p l e t e ? ( Y / f J ) PageL o f _ L VOA MS/MSD Required? Y/N S a m p l e 0:B N A M S / M S D Required? Y / t D S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s C h a i n o f C u s t o d y S e a l N u m b e r ( s )PesVPCB MSTMSD Required? Y/N S a m p l e #:: P R p r o v i d e s 7-day d a t a turnaround i r ) a d d i t i o n t o p r e l i m i n a r y re su l t s . Requests f o r / » • • * / » i j n j ' 'p r e l i m i n a r y r e s u l t s W i l l increase a n a l y t i c a l costs. C h a i n O f C u s t o d y Record . /

Relinquiêd by: (Signature)

R e l i n q u i s h e d by: '(Signaluli)


, Date / T i m e"A*t fctoD a t e / T i m e

1Date / T i m eI


Received by: (Signature)i i



Relinqu i sh ed by: (Signature)iDale / Time

• 1

Date / T i m e1Dale / T i m e1

Received by: (Signature) . .\ /\ /Received by: (Signature) •

\ /.Remarks: Is cus tody seal intact? Y/N/none \ /

D i s l n t i u l i o n : Dlue • Region C o p y P i n k - S M O CopyWhile - Lab Copy lui R e l u r n la SMO Yellow - Lab C o p y lor Reluin to Region EPA F o r m 9110-2 (2/99)See Reverse l or Addi t i ona l Standard Ins t ruc t i on s"See Reverse for Purpose Code Defini t ions

000651

( F o r Organic C L P A n a l y s i s )1 . P r o j e c t Code

Account CodeS i l e N a m e

Cc).C i l y , S t a l e S i l e S p i l l I D O p U n i t

2. N o . Sampl ing Co .Sampler (Name).

KtIFS a m p l e / S i g n a t u r e3. Purpose*l e a d E a r l y A c t i o n

PAREMRlI I• S I O J M

4. 6. Matrix(Enter inColumn A)1. S u r f a c e Water2. Ground Water3. Leacha t e4. Field QC5. S o i l / ^ d i r n e n t6. P E - w a l e r7. PE-soi l8. Other (specify inColumn A)

7. Preservative( E n l e / mCofumn DJ1. HCI2. HN033. NaHS044. H2S045. Ice o n l y6. CH30H7. Other (specifyin Column D)N. Not Preserved

C L PS a m p l eN u m b e r s( f r o m l a b e l s )

AM a t r i x( f r o mBox 6)Other:

BCone.:

LowM e d

CS a m p l eT y p e :omp./Grab

Dreser-vat ivei f i o r nB o x ? )Other:

RAS Analys sT A(orao one)

' R * 7 1 4 2 1V G A

TA(ode one)" 7TAI d r c t o one)

PR* 7 14 21B N A P e s l /PCB

Regional S p e c i f i cT r a c k i n g N u m b e ror Tag N u m b e r sG :Station 'Loca t i on ,I d e n t i f i e r

HM o / D a y /Y e a r / T i m eS a m p l eC o l l e c t i o nC o r r e s p o n d i n gC L P I n o r g a n i cS a m p i e ' N o .

S a m p l e rI n i t i a l sKField QCQ u a l i f i e r

B* Blank S = Fi*!Sple) • Field Dupl i ca t eRsRinut ePE • Perioon Evil.

2- L oils' \tof-•z, L 6-

S h i p m e n t f o r C aC o m p l e t e ? ( Y , P a g e ._ ! _ o f _ L V O A M S / M S D Required? S a m p l e #:B N A M S / M S D Required? Y t f J j S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s C h a i n o f C u s t o d y S e a l N u m b e r sPesl/PCB MSÎSD Required? Y/N_Sample #:

'PR p r o v i d e s 7-day (fata t u r n a r o u n d in a d d i t i o n t o p r e l i m i n a r y re su l t s . Requests for _. . •. - . , _ '• •. ' .p r e l i m i n a r y r e s u l t s w i l l increase a n a l y t i c a l costs. _________Unain O i U U S t O d y K e C P mR e l i n q u i s h e d byfr&tfl (Signature)/a?yR e l i n q u i s h e d by: (Signafure)

R e l i n q u i s h e d by (Signature)

. Dale / T i m e/ / / O T / t o 3Dat

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Relinqu i sh ed by: (Signature)

R e l i n q u i s h e d by: (Signature)ii Date /Time

' 1

D a l e /

Date

T i m e

Time i

Received by: (Signature) . .

(Signature)

. Remarks: Is cus tody seal intact? Y/hi/none /D i s u i b u l i o n : Blue - RcQion Com Pink - SMO CopyWhile • L ab C o p y for Return la SMO Yellow - Ub Copy lor Return to Region

ERA F o r m 9110-2 (2/99)SeeMReverse f o r A d d i t i o n a l S t a n d a r d I n s t r u c t i o n s' S e V R e v e r s e f o r Purpo s e Code D e f i n i t i o n s

C L A S S - 9 M 0 1

' 3 9 6 8 4 0000652

( F o r . Organic C L P A n a l y s i s )1. P r o j e c t C o d eA c c o u n t CodeS i t e N a m e

Co.C i l y , S t a l e S i t e S p i l l I D O p U n i l

2. Region No.•it Sampl ing Co.S a m p l e r (Name)S a r3. t e a . SFPRP

S TF E D82

Early ActionI APAREMRl

Il ong-TermActionI — [ R I F SL J R DL J R AC H O i M

5.

"732-3^30A T T N :

6. Matrix(Enter inColumn A)1. S u r f a c e W a t e r2. Ground W a t e r3. Leachate4. Field QC5. Soil/Sediment6. PE-waler7. PE-soil8. Other (specify inColumn A)

7. PreservativelEnler inColumn D)1. HCI2. HN033. NaHS044. H 2 S 0 45. Ice on ly6. CH30H7. Other (specifyin Column D)N . N o t Presetved

C L PS a m p l eN u m b e r s( I r o r n l a b e l s )

AM a t r i x( f r o mo~» c\U U A U fOther.

Bone.:

LowMed

ca m p l eT y p e :omp./Grab

Dreser-vat ive( f r o mBox 7)Other:

RAS Analy s i sT AI d f d o pi»l

H* 7 14 t\VOA

T A0

R / t f l / 2 1TAI r j r r U An*j

PR* 7 14 21

B N A Pes t /PCB

Regional S p e c i f i cT r a c k i n g Numberor Ta n N u m b e r sGStat ion 'Locat ion ,I d n i f l

HM o / D a y /Y e a r / T i m eC z i r r m j g

C o l l e c t i o n

iC o r r e s p o n d i n gC L P I n o r g a n i cO i m n l s s K l r tW U H l f l G I 1 U .

JS a m p l e rI n i t i a l sKField QCQ u a l i f i e r

!ksR ' R i n u f ca£ • Perform Evil.

y&fee-

L

9S h i p m e n t f o r CaseC o m p l e t e ? < f y / N ) P a g e_ L o f J _V O A M S / M S D Required? Y / N S a m p l e # :S N A M S / M S D Required? Y / f i ? S a m p l e # :

A d d i t i o n a l S a m p l e r S i g n a t u r e s Chain o f C u s t o d y Seal Number(s)Pesl/PCB M&MSD Required? Y/N S a m p l e #:

'"PR. p r o v i d e s 7-day da|a t u r n a r o u n d in a d d i t i o n to p r e l i m i n a r y resul t s . Requests forp r e l i m i n a r y r e s u l l s w i l l increase a n a l y t i c a l costs. ~t n.. *« ,. D/,^_^,JOf C u s t o d y RecordRelinquished by: (Signature)

R e l i n q u i s h e d by: (S'ignature^


Dale / T i m et o i l l / i f i i f e f l J 1Dal

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e / T i m e




Relinquished by: (Signature)

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' 1

Dale / Time1Dale /Time ...1 ' •

Received by: (Signature) /' ,/••'Received by: (Signature}' ' \

\ 1 /: Remarks: Is cus tody seal in la c l? Y/N/none \ /

D i s l i i b u t i o n : Blue • Region Copy Pink -SMO C o p yWhite • Lab C o p y for R e t u r n to SMO Y o i l o w - lab C o p y lor Return to Region EPA F o r m 9110-2 (2/99)See Reverse for Addi t ional Standard Ins truc t i ons"See Reverse iot Purpos e Code Definitions

^ CLASS-99-001'

3 9 6 8 3 9000653

IIIIIIIII ATTACHMENT 4| A N A L Y T I C A L R E S U L T SIIIIIIIII

T A B L E 1 PAH/PCP and BAP R E S U L T S

000654

IA N A L Y T I C A L R E S U L T S N O T E S P A G E

I1. The BAP Equivalent c a l c u l a t i o n in c lud e s the f o l l o w i n g cons t i tuent s:

benzo(a)anthracene; b enzo(a)pyrene; b e n z o ( b ) f l u o r a n t h e mchrysene; dibenzo(a,h)anthracene; and i n d e n o ( l , 2 , 3 - c d ) p y r e n e .

• benzo(a)anthracene; b enzo(a)pyrene; b e n z o ( b ) f l u o r a n t h e n e ; b e n z o ( k ) f l u o r a n t h e n e ;

1 2. The T o t a l N o n - C a r c i n o g e n i c PAH c a l c u l a t i o n inc lude s the f o l l o w i n g cons t i tu ent s:acenaphthene , acenaphthylene. , anthracene, d i b enzo furan , f l u o r a n t h e n e , f l u o r e n e ,n a p h t h a l e n e , phenanthrene, and pyrene.

3. D e f i n i t i o n of q u a l i f i e r s :

I J E s t ima t ed value;L Reported concentration is below the contract required quanti sat ion l i m i t ( C R Q L ) ;

andI U Not d e t e c t ed at reported qu .mt i t ia t i on l i m i t .

IIIIIIIIIII

000655

T a b l e 1G r o u n d w a t e r M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resu l t s , N o v e m b e r 2000 ( m g / 1 )

T e x a r k a n a Wood Preserving C o m p a n y

S t a t i o n I DS a m p l e I D

L a b I DDate

A n a l y t e QC-Mienolb i s [ 2 - C h l o r o e t h y l ] ether2 - C h l o r o p h e n o l2 - M e t h y l p h e n o I2 , 2 ' - O x y b i s ( 1 - c h l o r o p r o p a n e )4 - i v i e t h y i p h e n o iN - N i t r o s o - d i - n - p r o p y ! a m i n eH e x a c h l o r o e t h a n eN i t r o b e n z e n eI s o p h o r o n e2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lb i s [ 2 - C h l o r o e t h o x y ] methane2 , 4 - D i c h l o r o p h e n o lN a p h t h a l e n e4 - C h l o r o a n i l i n eH e x a c h l o r o b u t a d i e n e4 ÛI —— 1 h^^*U..1«U —— ~l- v ^ i n u i w - ^ - l v i w l l l J ' l p i l ^ i i u l

2 - M e t h y l n a p h t h a l e n eM e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h c n o l2 , 4 , 5 - T r i c h l o r o p h e n o l2 - C h l o r o n a p h t h a l e n e2 - N i t r o a n i l i n eD i m e t h y l p h t h a l a t e

MW-01M W O i - G - N - 0 7

FO-5C61 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 un r>r><v j . w v j * ' L )

0.005 u0.005 u0.005 u

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MW-07MW07-G-N-07

FO-5D51 1 / 1 8 / 2 0 0 0

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MW-08MW08-G-N-07

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MW-09MW09-G-N-07

FO-5D711/18/2000

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S e e notes page f o r q u a l i f i e r a n d e q u i v a l e n t c a l c u l a t i o n i n f o r m a t i o n-1

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000656

T a b l e 1 ( C o n t i n u e d )Groundwater M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )

T e x a r k a n a W o o d Pres erving C o m p a n y


L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 .6-Dini t ro t oIuene3 - N i t r o a n i i i n eA c e n a p h t h e n e2 , 4 - D i n i t r o p h e n o l4 - N i i r o p h e n o iD i b e n z o f u r a n2 , 4 - D i n i t r o t o l u e n eD i e t h y l p h t h a l a t e4 - C h l o r o p h e n y l - p h e n y l e therF l u o r e n e4 - N i t r o a n i I i n e4 , 6 - D i n i t r o - 2 - m e t h y l p h e n o lN - N i t r o s o d i p h e n y l a m i n e4-Bromophenyl-phenyle therH e x a c h l o r o b e n z e n eP e n t a c h l o r o p h e n o !P h ^ n o n t h r c n p

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M V V - 0 1M W O i - G - N - 0 7

FO-5C611/16/2000

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MW-07M W 0 7 - G - N - 0 7

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FO-5D711/18/2000

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T a b l e 1 ( C o n t i n u e d )G r o u n d w a t e r M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics R e s u l t s , N o v e m b e r 2000 ( m g / 1 )

T e x a r k a n a Wood Pre s erv ing C o m p a n y


L a b I DDate

A n a l y t e QCChryseneb i s ( 2 - E t h y l h e x y l ) p h t h a l a t eD i - n - o c t y l p h t h a i a t eB c n z o ( b ) f l u o r a n t h e n eB e n z o ( k ) f l u o r a n t h e n eB c i i i O w p y i c i i cI n d c n o ( l , 2 , 3 - c d ) p y r e n eD i b e n z ( a , h ) a n t h r a c e n eB e n z o ( g , h , i ) p e r y l e n eB A P E q u i v a l e n tT o t a l N o n - C a r c i n o g e n i c P A H s

MW-01M W O I - G - N - 0 7

FO-5C61 1 / 1 6 / 2 0 0 0

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MW-03MW03-G-N-07

FO-5C71 1 / 1 7 / 2 0 0 0

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0.01155 u0.045 u

MW-06MW06-G-N-07

FO-5C81 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u

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MW-07MW07-G-N-07

FO-5D51 1 / 1 8 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

0 . 0 1 1 5 5 u0.045 u

MW-08MW08-G-N-07

FO-5D61 1/18/2000


0.01155 u0.045 u

MW-09MW09-G-N-07

FO-5D71 1 / 1 8 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 U0.005 U0.005 U0.005 u0.005 U0.005 U0.005 u

0.01155 U0.045 u

dala8050frx 0 1 / 3 1 / 2 0 0 1


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T a b l e 1 ( C o n t i n u e d )Groundwater Moni tor ing S a m p l i n g S e m i - V o l a t i l e Organics Resul t s , November 2000 ( m g / 1 )



L a b I DDate

A n a l y t e QCP h e n o lb i s [ 2 - C h l o r o e t h y l ] e ther2 - C h i o r o p h e n o i2 - M e t h y ! p h e n o l2 , 2 ' - O x y b i s ( 1 - c h l o r o p r o p a n e )4 - f v i e i i i y i p h e n o iN - N i t r o s o - d i - n - p r o p y l a m i n eH e x a c h l o r o e t h a n eN i t r o b e n z e n eI s o p h o r o n e2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lb i s [ 2 - C h I o r o e t h o x y ] methane2 , 4 - D i c h l o r o p h e n o lN a p h t h a l e n e4-Chloroan i l in eH e x a c h l o r o b u t a d i e n e4 - P h l A r n . ^ - M p t h v l n h p n n lj r2 - M e t h y l n a p h t h a l e n eH e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h e n o l2 , 4 , 5 - T r i c h I o r o p h e n o l2 - C h l o r o n a p h t h a l e n e2 - N i t r o a n i l i n eD i m e t h y l p h t h a l a t e

M V V - 1 3M\vi3-G-N-o7FO-5DO

1 1 / 1 7 / 2 0 0 0N o r m a l

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M W - 1 4M W 1 4 - G - N - 0 7

FO-5C91 1 / 1 7 / 2 0 0 0

N o r m a l0.005 U0.005 u0.005 U0.005 U0.005 U0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 Un nns n0.005 U0.005 U0.005 U

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000659

T a b l e 1 ( C o n t i n u e d )G r o u n d w a t e r M o n i t o r i n g S a m p l i n g S e m i - V o l a t i l e Organics Resu l t s , N o v e m b e r 2000 ( m g / 1 )


S t a t i o n !0S a m p l e I D

L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 , 6 - D i n i t r o t o l u e n e3 - N l i r o a n i i i n eA c e n a p h t h e n e2 , 4 - D i n i t r o p h e n o I,1 M:(-^«U«.««I- T ~ l l l t l u L / I I V I I V y l

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MW-13MW13-G-N-07

FO-5DO1 1 / 1 7 / 2 0 0 0

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T e x a r k a n a Wood Pres erving C o m p a n y


L a b I DDate

A n a l y t e QCChrys eneb i s ( 2 - E t h y l h e x y l ) p h t h a l a t eD i - n - o c t y i p h t h a i a t eB c n z o ( b ) f l u o r a n t h e n eB e n z o ( k ) f l u o r a n t h e n eI 3 c n / . u \ a 7 p ^ i c n cI n d e n o ( 1 , 2 , 3 - c d ) p y r e n eDibenz(a ,h)anthrac eneB e n z o ( g , h , i ) p e r y l e n eB A P E q u i v a l e n tT o t a l N o n - C a r c i n o g e n i c P A H s

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S t a t i o n I DS a m p l e i D

L a b I DDate

A n a l y t e QCPheno lb i s [ 2 - C h l o r o e t h y l ] ether2 - C ' h l o r o p h e n o l2 - M e t h y l p h e n o l2 , 2 ' - O x y b i s ( 1 - c h l o r o p r o p a n e )4 - M e i h y i p h e n o iN - N i t r o s o - d i - n - p r o p y l a m i n eHexach loroe thaneN i t r o b e n z e n eI s o p h o r o n e2 - N i t r o p h e n o l2 , 4 - D i m e t h y l p h e n o lb i s [ 2 - C h l o r o e t h o x y ] methane2 , 4 - D i c h l o r o p h e n o lN a p h t h a l e n e4 - C h l o r o a n i l i n eH e x a c h l o r o b u t a d i e n e4 - P M n r n - ' J - M f > t h r < l n 1 i r . r , r . lJ K2 - M e t h y l n a p h t h a l e n eM e x a c h l o r o c y c l o p e n t a d i e n e2 , 4 , 6 - T r i c h l o r o p h e n o l2 , 4 , 5 - T r i c h l o r o p h e n o i2 - C ' h l o r o n a p h t h a l e n e2 - N i l r o a n i l i n eD i m e t h y l p h t h a l a t e

M V V - 2 6MW26-G-N-07

FO-5C51 1 / 1 6 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 uG.005 u0.005 u0=005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 un nn^0.005 u0.005 u0.005 u

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FO-5D41 1 / 1 7 / 2 0 0 0

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0.005 u0.005 u0.005 u

0.02 u0.005 u

0.02 u0.005 u

L e f tB l a n k On

P u r p o s e

See notes page for q u a l i f i e r and equivalent c a l c u l a t i o n i n f o r m a t i o n-7

data8050.frx 0 1 / 3 1 / 2 0 0 1

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T e x a r k a n a Wood Pres erving C o m p a n y


L a b I DDate

A n a l y t e QCA c e n a p h t h y l e n e2 . 6 - D i n i t r o t o I u e n e3 - N i t r o a n i l i n eA c c n a p h t h e n e2 , 4 - D i n i t r o p h e n o l4 - N i u u p l i e n u iD i b e n z o f u r a n2 , 4 - D i n i t r o t o l u e n eD i e t h y l p h t h a l a t e4 - C h l o r o p h e n y l - p h e n y l etherF l u o r e n e4 - N i t r o a n i l i n e4 , 6 - D i n i t r o - 2 - m e t h y l p h e n o lN - N i t r o s o d i p h e n y l a m i n e4 - B r o m o p h e n y l - p h e n y l e t h e rH e x a c h l o r o b e n z e n eP e n t a c h l o r o p h e n o lP h p n a n t h r * * n pA n t h r a c e n eD i - n - b u t y l p h t h a l a t eF l u o r a n t h e n ePyreneB u t y l b e n z y l p h t h a l a t e3 , 3 ' - D i c h l o r o b e n z i d i n eB e n z o ( a ) a n t h r a c e n e

MW-26MW26-G-N-07

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0.02 un nns0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

MW-27G W 2 7 - G - N - 0 7

FO-5D41 1 / 1 7 / 2 0 0 0

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M W - 2 7MW27-G-D-07

FO-5D31 1 / 1 7 / 2 0 0 0D u p l i c a t e

0.005 U0.005 u

0.02 u0.009

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0.005 u0.005 u0.005 u0.005 U0.003 u

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0.005 U0.005 U0.005 U

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MW-27M W 2 7 - G - N - 0 7

FO-5D21 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.006

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.002 u

0.02 U0.02 u

0.005 u0.005 u0.005 U

0.02 u0.005 u0.005 U0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U

MW-28MW28-G-N-07

FO-5D11 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u

0.02 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u0.005 u0.005 u

0.02 u0.02 u

0.005 u0.005 u0.005 u

0.02 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u

L e f tB l a n k OnP u r p o s e


data8050.frx 0 1 / 3 1 / 2 0 0 1

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Texarkana Wood Preserving Company


L a b I DDate

A n a l y t e QCChrys eneb i s ( 2 - E t h y l h c x y l ) p h t h a l a t eD i - n - o c t y l p h t h a l a t cB e n z o ( b ) f l u o r a n t h e n eB c n z o ( k ) f l u o r a n t h e n eBcnzo^2^nvrcncI n d c n o ( 1 , 2 , 3 - c d ) p y r e n eD i b e n z ( a , h ) a n t h r a c e n eB c n z o ( g , h , i ) p e r y l e n eB A P E q u i v a l e n tT o t a l N o n - C a r c i n o g e n i c P A H s

MW-26M W 2 6 - G - N - 0 7

FO-5C51 1 / 1 6 / 2 0 0 0


0.01155 u0.045 u

MW-27G W 2 7 - G - N - 0 7

FO-5D411/17/2000

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0.01155 U0.045 u

M W - 2 7MW27-G-D-07

FO-5D31 1 / 1 7 / 2 0 0 0D u p l i c a t e

0.005 U0.005 U0.005 u0.005 U0.005 U0.005 li0.005 U0.005 U0.005 U

0.01155 U0.047

MW-27M W 2 7 - G - N - 0 7

FO-5D21 1 / 1 7 / 2 0 0 0

N o r m a l0.005 u0.005 u0.005 u0.005 u0.005 u0.005 u0.005 U0.005 u0.005 u

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MW-28MW28-G-N-07

FO-5D11 1 / 1 7 / 2 0 0 0


0.01155 u0.045 u

L e f tB l a n k OnP u r p o s e

dalaSOSO.frx 0 1 / 3 1 / 2 0 0 1


000664

A T T A C H M E N T 5T I C R E S U L T S

000665

MW-06

000666

IIIIIIIIIIIIIIIIIII

1LCBL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Ca.£36 N O . : 28724 SAS No. : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881013L a b F i l e H ) : S 3 A 6 6 8 3S a m p l e Volvime: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

CAS NO. COMPOUND

Date Received: 1 1 / 1 8 / 0 0Date Extracted: 1 1 / 1 8 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0

1 0 0 0 ( u L ) Dilution Fac t or: 1.0

C O N C E N T R A T I O N( u g / L )

1 0 8 - 9 5 - 2 — — — — — P h e n o l _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _111-44-4--------bis ( - 2 ' - C h l o r o e t h y l ) Ether95-57-8-- — — ---2-Chlorophenol_______________95-48-7---- — — - 2 - M e t h y l p h e n o l _ _ _ _ _ _ _ _ _ _ _ _108-60-1- — — — - 2 , 2 ' - o x y b i s ( 1 - C h l o r o p r o p a n e )106-44-5- -------4-Methylphenol________621-64-7--------N-Nitroso-di-n-propylamine67-72-1— — — — -Hexachloroe thane_____________98-95-3-- —— -- -Nitrobenzene___________________78-59-l---------Isophorone_______________________88-75-5-- — — — — -2-Nitrophenol________________105-67-9- — — — -2,4 -Dimethylphenol1 1 1 - 9 1 - 1 — — — — - b i s (- 2 -Chloroethoxy) methane_1 2 0 - 8 3 - 2 — — — — — 2 , 4 - D i c h l o r o p h e n o l _ _ _ _ _ _ _ _ _ _ _ _91-20-3-- —— ---Naphthalene______________106-47-8 — — — — — -4 -Chloroaniline87-68-3 — — — — -Hexachlorobutadiene5 9 - 5 0 - 7 — — — — — - 4 - C h l o r o - 3 - M e t h y l p h e n o l _ _ _91-57-6— — — — — - 2 - M e t h y l n a p h t h a l e n e _ _ _ _ _ _7 7 - 4 7 - 4 - - — — — - H e x a c h l o r o c y c l o p e n t a d i e n e8 8 - 0 6 - 2 — — — — - 2 , 4 , 6 - T r i c h l o r o p h e n o l _ _ _ _ _ _9 5 - 9 5 - 4 — — — — — - 2 , 4 , 5 - T r i c h l o r o p h e n o l _ _ _ _ _9 1 - 5 8 - 7 — — — — — - 2 - C h l o r o n a p h t h a l e n e _ _ _ _ _ _ _ _88-74-4 — — — — — — -2-Nitroaniline___________1 3 1 - 1 1 - 3 — — — — - D i m e t h y l p h t h a l a t e _ _ _ _ _ _ _ _ _ _2 0 8 - 9 6 - 8 — — — — - A c e n a p h t h y l e n e _ _ _ _ _ _ _ _ _ _ _ _ _6 0 6 - 2 0 - 2 — — — - - - 2 , 6 - D i n i t r o t o l u e n e _ _ _ _ _ _ _ _ _ _9 9 - 0 9 - 2 — — — — — - 3 - N i t r o a n i l i n e _ _ _ _ _ _ _ _ _ _ _ _ _ _ _8 3 - 3 2 - 9 — — — — — - A c e n a p h t h e n e _ _ _ _ _ _ _ _ _ _ _ _

FORM I L C S V - 1

555555555555555555555

2052055520

UUUUUUUUUUUUUUUUUUUUUUUUUUUUU

OLC02 . 10

000667

I:LCCL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E 1 3 T EPA S A M P L E NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N O . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881013L a b F i l e I D : S 3 A 6 6 8 3S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

CAS NO. COMPOUND


1 0 0 0 ( u L ) Dilution Fac tor: 1.0


51-28-5 — — — -100-02-7----132-64-9 —— -191-1 4-9----.LÛ. _1. £M84-66-2 — — — -700^-79-3---OC "71 "7100-01-6 —— -534-52-1 —— -86-30-6 — — — -101-55-3----1 1 O *7A TQ"7 OC CQ c m Q1 90-1 9-7----.A.AI/ .L. « /R4-74-9-----U " / X A206-44-0 —— -129-00-0 — — —DC CQ "791-94-1 -----56-55-3 — — — -01 H m Q_1 -I "7 m «7_117-84-0 — — —0/1*7 no oK f\ •} O O193-39-5 — — —53-70-3 — — — —1 <51 -94 9- --

- - — -2,4 -Dinitrophenol- - — - 4 -Nit rophenol- - - - -Dibenzof uran-----2,4 -Dinitrotoluene—— - Die thy lph tha la t e- — -4 -Chlorophenyl -phenyl ether _- — -Fluorene- — -4-Nitroanil ine----4,6 -Dinitro- 2 -methylphenol _- — - N-nitrosodiphenylamine ( 1 )- — - 4 -Bromophenyl -phenylether- — - Pentaclilorophenol

> y^4-V|-y»*^ fifvr^ <a/ u l L X JJL Q.\ f tJ It.- — -Di-n-butylphthalate- — - Fluoranthene- — -Pyrene- — - Butylb«mzylphthalate- — - 3 , 3 ' -Dichlorobenzidine- - - - Benzo ( a ) anthracene- — -Chrysene—— bi s ( 2 - K t h y l h e x y l ) p h t h a l a t e _- - - -Di -n-oc:tylphthalate— -Benzo (1>) f luoranthene- — -Benzo (k) f luoranthene- - - -Benzo (a) pyrene- — -Indeno ( 1 , 2 , 3 -cd) pyrene- — -Dibenzo (a , h) anthracene--- -Benzo (g, h, i) perylene

2020c55520205552055555555555555555

UUUUUUUUUUUUUUUUUUUUUUUUUUUUUU

(1) - Cannot be separated f rom Diphenylamine

FORM I L C S V - 2 OLC02.1073000668

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E TT E N T A T P / E L Y I D E N T I F I E D COMPOUNDS

EPA S A M P L E NO.

F 0 5 C 8Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e 3D: 71881013L a b F i l e I D : S 3 A 6 6 8 3S a m p l e Volume.- 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 8 / 0 0Date Extracted: 11 /18/00Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

Number TICs f ound: 1CAS NUMBER1.2.3.4.5.6.7.8.9.10.

11.12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

COM1POUND NAMEU N K N O W N

RT12.63

E S T . C O N C .( u g / L )14

QJ

FORM I L C S V - T I C OLC02.1

073000669

Data F i l e : \ \ A V O G A D R O S U S E R D A T A S O r g a n i c S s v o a \ s 3 , i S 0 0 1 1 2 8 . B \ S 3 A 6 6 8 3 . DDate ; 28-NOV-aoOO 09:29 'C l i e n t ID: F 0 5 C 8 ••S a m p 1 e I n f o ; 71881013,F05C8,S1118-BU2, C S , , F 0 5 C 1V o l u m e I n j e c t e d <uL>: 1.0C o l u m n phase: DB-5HS

Instrument: s3.i

Operator: CSC o l u m n diameter: 0.25

3.4-i3.3-13.2-i3.1-;3.0-i2.9-i2.8-!2.7-i2 ' 6 1Z.5\2*4i?;3-|2.2^2.1-i2.0-i

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,l— > 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38—— e»4 ——— . ._.... . H i nO

000670

Data F i l e : S 3 A 6 6 8 3 . DReport Date: 2 9 - N O V - 2 0 0 0 10:54

Data f i l eLab Smp IdI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eOil F a c t o rI n t e g r a t o r

M i t k e m Corpora t i onC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 8 . B \ S 3 A 6 6 8 3 . D

71881013 C l i e n t S m p I D : F 0 5 C 8 '2 8 - N O V - 2 0 0 0 0 9 : 2 9 'C S I n s t I D : S 3 . i7 1 8 8 1 0 1 3 , F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 8 - N O V - 0 0 , 1 8 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 8 . B \ s 3 _ c l p _ l o w . m2 8 - N O V - 2 0 0 0 13:58 m t l Quant T y p e : I S T D2 8 - N O V - 2 0 0 C ) 04:45 C a l F i l e : S 3 A 6 6 7 7 . D2 9 ~ — — — — — "1.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03P r o c e s s i n g H o s t : T A R G E T 7

Concen tra t i on F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name V a l u e D e s c r i p t i o n

DFU fVtVOVi

1.0001.0001000.0001000.0001.000

Dilut ion F a c t o rng unit correc t ion f a c t o rVolume o f f i n a l extract ( u L )Volume o f s a m p l e e x trac t ed ( m L )V o l u m e i n j e c t e d ( u L )

CompoundsQ U A N T S I G

M A S S

$ 1 2-Fluoropheno l$ 2 P h e n o l - d 5* 6 1, 4-Dichlorobenzene-d4$ 12 N i t r o b e n z e n e - d 5* 19 N a p h t h a l e n e - d a$ 28 2 - F l u o r o b i p h e n y l* 35 A c e n a p h t h e n e - d l O$ 47 2 , 4 , 6 - T r i b r o m o p h e n o l* 51 Phenanthrene-d lO$ 57 T e r p h e n y l - d l 4* 61 Chrys ene-d ia* 68 Peryl ene-d l2

RT EXP RT REL RT R E S P O N S E

11299

15282

136172164330188244240264

101213141518192122252831

sss.050.400.180.387.910.175.569.199.641.937.090.172

cs:10121314I S181 9 ,21.2 2 .25.28.31.

= S = R

.047

.403

.178

.390

.913

.178.572.207.644.940.093.181

(0.( 0 .( 1 .( 0 .( 1 .(0.( 1 -( 0 .( 1 .( 0 .(1.(1.

762)9 4 1 )0 0 0 )9 0 4 )0 0 0 )9 2 9 )0 0 0 )9 3 6 )0 0 0 )9 2 3 )000)000)

4718726 8 0 2 0 83 5 3 3 9 7801353

14084421489840

816179477800

1310228175820711933261135402

101020282027203720292020

.7896

.9494

.0000

.0185

.0000

.4400

.0000

.0807

.0000

.6736

.0000

.0000

C O N C E N T R A T I O N SC N - C O L U M N F I N A L

( ng) ( u g / L )

111128

081

000671

1111111111111111111


Data f i l eLab Smp idin j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eD i l F a c t o r

M i t k e m C o r p o r a t i o nC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i\001128 . B \ S 3 A 6 6 8 3 .D

71881013 C l i e n t S m p I D : F 0 5 C 82 8 - N O V - 2 0 0 0 0 9 : 2 9C S I n s t I D : s3.i71881013, F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 8 - N O V - O O f 1 8 - N O V - 0 0

\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i\001128 . B \ s 3 _ c l p _ l o w . m2 8 - N O V - 2 0 0 0 1 3 : 5 8 m t l Quant T y p e : I S T D2 8 - N O V - 2 0 0 C ) 04:45 C a l F i l e : S 3 A 6 6 7 7 . D291.00000I n t e g r a t o r H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03P r o c e s s i n g H o s t : T A R G E T ?

C o n c e n t r a t i o n F o r m u l a : Amt * DF * Uf * Vt/ (Vo * Vi)Name

DFU fVtvoVi

I S T D

V a l u e D e s c r i p t i o n1.000 D i l u t i o n F a c t o r1.000 ng unit correc t ion f a c t o r1000.000 V o l u m e o f f i n a l extract ( u L )1000.000 Volume o f s a m p l e ex trac t ed ( m L )1.000 Volume i n j e c t e d ( u L )

RT AREA A M O U N T

* 6 l , 4 - D i c h l o r o b e n z e n e - d 4 13.180 2 1 3 9 8 7 0 20.000

RT AREA

Unknown1 2 . 6 3 0 1507508

C O N C E N T R A T I O N S Q U A N TO N - C O L ( n g ) F I K A L C u g / L ) QUAL L I B R A R Y L I B E N T R Y C P N D f r

C A S f t :14.0897157 1 4 0 0 6

082

000672

Data F i l e : S N A V C I G A D R O S U S E R D A T A S O r g a n i c S s v o a S s 3 . i S001128. B S S 3 A 6 6 8 3 . BDate : 28-NOV-2000 09:29C l i e n t I D : F 0 5 C 8 I n s t r u m e n t : s3.iS a m p l e I n f o : 7 1 8 8 1 0 1 3 , F 0 5 C 8 , S 1 1 1 8 - B W 2 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L > : 1 .0 Operator: CSC o l u m n phase: DB-5MS C o l u m n d iame t e r; 0.25

L i b r a r y Search Compound H a t c hUnknown1,4-Dioxane, d i m e t h y l -Ethane, i s o t h i o c y a n a t o -1,3-Dioxolane, 2-e thyl-4-methyl-

C A S N u m b e r L i b r a r y Entry

25136-55-4 N B S 7 5 K . L 3278542-85-8 NBS75K.L 628764359-46-0 N B S 7 5 K . L 3247

Q u a l i t y F o r m u l a H e i g h t

64 C6H120264 C3H5NS50 C6H1202

11687116

10.0

8.0no 6.0X~ 4'°n8 2.0z

0.0

10.08.0

n<o 6.0X\rf-- <•«•10o 2.0z

0.0

10.0

8.0n<o 6.0T*X\x_ 4-°i»o 2.0

0.0-

10.08.0

ro 6.0« 4.0b 2.0z

0.0

59s,

{

\

,.., L . .

Scan 1599 (12.630 m i n ) o f S 3 A 6 6 8 3 . D ( S u b t r a c t e d ) ( S C A L C D )-67

127\, /0-56 i99\ 23&N^ 28*. x25'6 427^S434.... . . .. k .. .1. . ..1, . . . . . . /^

20 40 60 80 100 120 140 163 180 200 220 240 260 280 300 320 340 360 380 400 420m / z

X 5 9

/ 3 1

n jl I . . .1.. ..

. Entry »3278, 1,4-Dioxane, d i m e t h y l - ( f r o m N B S 7 5 K . L ) ( S C A L E D )' ^ 6 7

-1161. , IT

20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420m / z87 "

/29

ill 1 1 1 . .i i

Entry # 62876, Ethiane, i sothiocyanato- ( f r o m N B S 7 5 K . L ) (SCALED)

120 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420m / z

El>

3N

l l , 1J... Jl.. .J, J. ... i ...... .... ...

/*"

.1. .

•(try #3247, 1 , 3 - D i o x o l a n e , 2 - e t h y l - 4 - m e t h y l - ( f r o m N B S 7 5 K . L ) ( S C A L E D )

.1.20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380 400 420m / z

083000673

E Q U I P M E N T B L A N K A T M W - 1 7

000674

1LCBL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N o . : 28724 S A S N o . : S D G N O . : F 0 5 C 1Lab S a m p l e ID: 71881006L a b F i l e I D : S 3 A 6 6 7 2S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilution Fac tor: 1.0

CAS NO. COMPOUNDC O N C E N T R A T I O N( u g / L )

1 0 8 - 9 5 - 2 — — — — — - P h e n o l _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _1 1 1 - 4 4 - 4 — — — • — - b i s ( - 2 - - C h l o r o e t h y l ) Ether ~95-57-8 — -- — ---2-Chlorophenol______________95-48-7 — — — — — — -2-Methylphenol108-60-1--- — — - 2 , 2 ' -oxybis (1-Chloropropane)1 0 6 - 4 4 - 5 — — — - - - 4 - M e t h y l p h e n o l _ _ _ _ _ _ '621-64-7- — — — - N - N i t r o s o - d i - n - p r o p y l a m i n e67-72-1— — — — - H e x a c h l o r o e thane___________98-95-3 — — — ---Nitrobenzene________________78-59-1— — — ---Isophorone_________________88-75-5 — — — ---2-Nitrophenol____________105 -67-9- — — ---2,4 -Dimethylphenol _______1 1 1 - 9 1 - 1 — — — — - b i s ( - 2 - Chloroe thoxy) methane_1 2 0 - 8 3 - 2 — — — —-2 ,4-Dich l oropheno l__________91-20-3 — — — — -Naphtha l ene ______________1 0 6 - 4 7 - 8 — — — - - -4-Chloroaniline87-68-3 — — — — -Hexachl orobutadiene5 9 - 5 0 - 7 — — — — — - 4 - C h l o r o - 3 - M e t h y l p h e n o l _ _9 1 - 5 7 - 6 — — — — — - 2 -Methylnaphthalene__)_____7 7 - 4 7 - 4 — - - — - - - H e x a c h l o r o c y c l o p e n t a d i e n e88-06-2 — —— — -2,4, 6-Trichlorophenol____9 5 - 9 5 - 4 — — — — -2 ,4 ,5 -Trichlorophenol9 1 - 5 8 - 7 — — — — — - - 2 - C h l o r o n a p h t h a l e n e _ _ _ _ _ _ _88-74-4 — — — — — — -2-Nitre aniline____________1 3 1 - 1 1 - 3 — — — — - D i m e t h y I p h t h a l a t e________208-96-8- — — — — -Acenaphthylene____________606-20-2- — — ---2, 6-Dinitrotoluene_______99-09-2 — — — — -• 3 -Nitro aniline________________83-32-9— — —— -Acenaphthene___________

555555555555555555555

20520555205


FORM I L C S V - 1 OLC02.1035000675

1LCCL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N ! C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Ceise N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881006L a b F i l e I D : S 3 A 6 6 7 2S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilution Factor: 1.0

CAS NO. C O M P O U N DC O N C E N T R A T I O N

( u g / L )

-2,4 -Diiiitrotoluene~Die thylph tha la t e_

5 1 - 2 8 - 5 — — - - - - - 2 , 4 - D i n i t r o p h e n o l _100-02-7- — — ----4-Nitrophenol___~132-64-9---—---Dibenzo furan121-14-2-----84-66-2 ——— - _________7 0 0 5 - 7 2 - 3 — - - — - 4 - C h l o r o p h e n y l - p h e n y l e t h e r _86-73-7 —— — ---Fluorene1 0 0 - 0 1 - 6 - — - - — - 4 - N i t r o a n i l i n e534-52-1-----8 6 - 3 0 - 6 — — — —101-55-3 —— --1 1 8 - 7 4 - 1 — — —87-86-5------

4,6-Dini tro-2-methylpheno l_N-nitrosodiphenylamine (1) ~4 -Bromophenyl -phenylether_JHexachlorobenzene_________Pentaclilorophenol_______

-Di-n-butylphthalate_- Fluoranthene______-Pyrene__

85-01-8 — — — — -Phenanthrene120-12-7- — — — -Anthracene84-74-2 ——— -•206-44-0 —— -•1 2 9 - 0 0 - 0 — — — • ________^__8 5 - 6 8 - 7 — — — — — - Butylbenzylphthalate9 1 - 9 4 - 1 - - - - - - — - 3 , 3 ' - D i c h l o r o b e n z i d i n e5 6 - 5 5 - 3 — — — -2 1 8 - 0 1 - 9 — — — -1 1 7 - 8 1 - 7 — — — -1 1 7 - 8 4 - 0 — — — -2 0 5 - 9 9 - 2 — — — -2 0 7 - 0 8 - 9 — — — -50-32-8------1 9 3 - 3 9 - 5 — — — -53-70-3 — — — — -1 9 1 - 2 4 - 2 — — — -

-Benzo (a) anthracene-Chrysene_b i s ( 2 - K t h y l h e x y l ) p h t h a l a t e .-Di-n-octylphthalate________-Benzo (b) fluoranthene_______-Benzo(k)fluoranthene_____-Benzo (at) pyrene_-Indeno ( 1 , 2 , 3 -cd)pyrene_-Dibenzo (a, h) anthracene"- B e n z o ( g , h , i ) p e r y l e n e(1) - Cannot be separated f r om Diphenylamine

20205555

20205

5520555555555


t>FORM I L C S V - 2 OLC02.1

000676

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E 1 2 T

T E N T A T I V E L Y I H S N T I F I E D COMPOUNDSEPA S A M P L E NO.

F 0 5 C 3Lab Name: MITKEM CORPORATION Contract: 68-D6-0063Lab Code: MITKEM Case N O . : 28724 SAS No. : SDG No. : F 0 5 C 1Lab S a m p l e ID: 71881006L a b F i l e I D : S 3 A 6 6 7 2S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )


Number TICs found: 4CAS NUMBER1. 630-01-32. 629-94-73. 638-67-54. 630-03-55.6.7.8.9.10.11.12.13.14.

15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

C O M I ? O U N D N A M EH E X A C O S A N EH E N E I C O S A N ET R I C O S A N EN O N A C O S A N E

RT28.5229.1629.8230.57

E S T . C O N C .( u g / L )2322

QN JN JN JN J

FORM I L C S V - T I C037

OLC02.1

000677

Data F i l e : S N A V O G A D R O S U S E R D A T A S O r g a n i c \ svoaSs3.i S 0 0 1 1 2 7 A . B X S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22 'C l i e n t I D : F 0 5 C 3 ,S a m p l e I n f o ; 71881006,F05C3,S1117-BW4,CS,,F05C1V o l u m e I n j e c t e d <uDi 1.0C o l u m n phase: D B - 5 H S

I n s t r u m e n t : s3.i

Operator: CSC o l u m n d i a m e t e r : 0.25

SXAVOCADROXUSERDATASOrgan i c\svoa\s3 . i S001127A . B X S 3 A 6 6 7 2 . D3.5; g g_ . : a &34- c jC3.3-i 3 iO O3 , 2 - j &: 33.1-13.0-:

2.8-j2.7-i2.6-i2.5; 0>2.4; ?

U>2.3, g

^ f Ii^ 1 ! f

> 1 ' 8 1 m ? Nx 1.7-: ? o |> 1.6^ 1o °• - f a - *1.5- o £ i ^»i !

i **•* " (VIi.o-i

<\ a •

0.8-i0.7-i0.6-10.5-i0.40.3-j0.2-i

i

i _ iI

u!(VJ

^

Ol1"a.

'

J5.-«iV

K

sT J1Olt.C"racOlit

"D13)C01££•1-

fv-, 6 8 10 12 14 16 18 20 22 24 26**"' Hin

CM01c01I / I1

28J

(VIi

J i1

L j , / . „ , , , . „ , . „ „ „ , , ,30 32 34 36 38

000678

11111

Data F i l e : S 3 A 6 6 7 2 . DReport Date: 2 9 - N o v - 2 0 0 0 11:24

M i t k e m C o r p o r a t i o nC L P O L C 0 2 Q U A N T I T A T I O N REPORTData f i l e \ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . DL a b S m p I d 71881006 C l i e n t S m p I D : F 0 5 C 3 -

i n j Date 2 8 - N O V - 2 0 0 0 0 1 : 2 2 'Operator CS I n s t ID: s3.iS m p I n f o 71881006 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1M i s c I n f o , , ,1, , , , , , , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0CommentM e t h o d \ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 c l p l ow.m

1111111111_1

111

M e t h Date 2 9 - N o v - 2 0 0 ( ) 11:05 m t l Quant T y p e : I S T DC a l Date 2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . DA l s b o t t l e 1 9 — — — — — *Oil F a c t o r 1.00000I n t e g r a t o r H P R T E Compound S u b l i s t : a l l . s u bT a r g e t Ver s ion: 4.03Proc e s s ing H o s t : T A R G E T 7

Concentra t i on F o r m u l a : Amt * DF * Uf * Vt/ (Vo * Vi)Name V a l u e D e s c r i p t i o n

DF 1.000 D i l u t i o n F a c t o rUf 1.000 ng unit correct ion f a c t o rVt 1000.000 Volume o f f i n a l extract ( u L )Vo 1000.000 Volume o f s a m p l e e x t rac t ed (mL)V i 1.000 Volume i n j e c t e d ( u L )

C O N C E N T R A T I O N SQ U A N T S I Q O N - C O L U M N F I N A L

Compounds MASS RT EXP RT REL RT R E S P O N S E ( ng) ( u g / L )

$ 1 2 - F l u o r o p h e n o l 112 10.047 10.052 ( 0 . 7 6 2 ) 570090 13.1411 13$ 2 P h a n o l - d 5 99 12.397 12.408 ( 0 . 9 4 1 ) B13831 13.1850 13* 6 l , 4 - D i c h l o r o b e n z e n e - d 4 152 13.177 13.183 ( 1 . 0 0 0 ) 344992 20.0000S 12 Nitrobenzene-d5 82 14.384 14.390 ( 0 . 9 0 4 ) 763684 29.1206 29* 19 N a p h t h a l e n e - d B 136 15.912 15.912 ( 1 . 0 0 0 ) 1332338 20.0000$ 28 2 - F l u o r o b i p h e n y l 172 18.177 18.178 ( 0 . 9 2 9 ) 1 5 3 3 9 6 8 2 9 . 2 7 3 0 29* 35 A c e n a p h t h e n e - d l O 164 19.566 19.577 ( 1 . 0 0 0 ) 774834 20.0000$ 47 2 , 4 , 6 - T r i b r o m o p h e n o l 330 21.201 21.212 ( 0 . 9 3 6 ) 568421 44.6054 45* 51 Phenanthrene-dlO 188 2 2 . 6 4 3 2 2 . 6 4 9 ( 1 . 0 0 0 ) 1 2 5 8 9 9 2 20.0000v _. __ r __ ,, _ . „, _ . __ _ .„_ ,.. __ , - . _ . . _ _ _ - . _ _ . . 30* 61 C h r y s e n e - d l 2 240 2 8 . 0 9 2 2 8 . 0 9 8 ( 1 . 0 0 0 ) 1228817 20.0000

62 b i s ( 2 - E t n y l h e x y l ) p h t h a l a t e 149 28.124^28.130 ( 1 . 0 0 1 ) 104219 1 . 7 9 5 5 5 2 (a)* 68 P e r y l e n e - d l 2 264 31.175 31.186 ( 1 . 0 0 0 ) 1207003 20.0000 «/£•f / >>i*>

039

000679


QC F l a g Legend• a - T a r g e t compound d e t e c t e d but , quant i ta t ed amount• Below Limit Of Q u a i i t i t a t i o n ( B L O Q ) .

I

040

000680

IIIIIII


Data f i l eL a b S m p I dI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eD i l F a c t o rI n t e g r a t o r

M i t k e m C o r p o r a t i o nC L P O L C 0 2 Q U A N T I T A T I O N REPORT\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 2 . D

71881006 C l i e n t S m p I D : F 0 5 C 32 8 - N O V - 2 0 0 0 01:22C S I n s t I D : S 3 . i7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 C I 16:41 C a l F i l e : S 3 A 6 6 6 1 . D191.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03P r o c e s s i n g H o s t : T A R G E T 7

Concen tra t i on F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name V a l u e D e s c r i p t i o n

I S T D

* 61* 68

RT

DF 1.000U f 1.000Vt 1000.000Vo 1000.000Vi 1.000

D i l u t i o n F a c t o rng unit correc t ion f a c t o rVolume o f f i n a l extract ( u L )V o l u m e o f s a m p l e ex trac t ed ( m L )Volume i n j e c t e d ( u L )

RT AREA A M O U N T

C h r y s e n e - d l 2P e r y l e n e - d l 2

C O N C E N T R A T I O N S

2 8 . 0 9 2 4073449 20.31.175 4 0 0 6 6 6 8 20.

Q U A N T

000000

AREA O N - C O M n g ) F I N A L ( u g / L ) OUAL L I B R A R Y L I B E K T R Y C P N D ( t

Hexaco sane2 8 . 5 2 0 5 1 6 3 6 7 2 . 5 3 5 2 S 1 5 3

CAS #: 630-01-39 5 N B S 7 5 K . L 73943 6 1 ( L )

H e n e i c o s a n e29.155 546171 2 . 6 8 1 6 1 6 4 4

CAS #: 6 2 9 - 9 4 - 79 0 N B S 7 5 K . L 42201 6 1 ( M L )

041

000681

I Data F i l e : S 3 A 6 6 7 2 . D .Report Date: 2 9 - N O V - 2 0 0 0 11:24| C O N C E N T R A T I O N S Q U A N T

R T AREA O N - C O L ( n g ) F I N A L ( u g / L ) QUAL L I B R A R Y L I B E N T R Y C P N D

T r i c o s a n e CAS #: 6 3 8 - 6 7 - 529.818 499170 2 . 4 9 1 6 9 6 3 4 2 9 3 N B S 7 5 K . L 73318 6 £ : ( L )

Nonacosane CAS t t : 630-03-530.571 420137 2.09718899 2 94 N B S 7 5 K . L 54526 6 £ : ( L )

I

I

I QC F l a g LegendI M - Compound re sponse manual ly i n t e g r a t e d .L - Operator s e l e c t e d an a l t e r n a t e l i brary search match.

042

000682

Data F i l e : \ S A V O G A D R O S U S E R D A T A \ O r g a n i c \ svoaSs3. i S 0 0 1 1 2 7 A . B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 I n s t r u m e n t : s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1 .0 Operator: CSColumn phase: DB-5HS Column diameter: 0.25

62 b i s ( 2 - E t h a l h e x a l ) p h t h a l a t e C o n c e n t r a t i o n : 2 u g / LScan 4499 (28.124 m i n ) of S3A6672.D II Ion 149.00149 II 7.5-7.0

6.05.0

f 4.0ox 3.0>- 2.0

1.00.0

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7.06.05.0

? 4.03 •, «x 3.0-»- 2.0

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~ 6.0> 5.0i .. «,5 4.0> 3.0

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l..k.,l. J.... J l . l . U l . ..!.. .75 100 125 150

1 7lC^6.5ÎI 6>0i

A&7

-240207s X 2 4 ° /279\ i / 338.... .... ..i..... ..J.... ... .L. . . x

175 200 225 250 275 300 325m/zScan 4499 (28.124 m i n ) o f S 3 A 6 6 7 2 . D ( S u b t r a c t e d )149-

"N. . l .J. .J.... ll .Lib. ..1

A&7

75 100 125 150

J.

/ 2 4 ° /279212s 1 / 3 3 8...... A.. ..,1... . . .1. . . >175 200 225 250 275 300 325m / z

6 2 b i s ( 2 - E t h a l h e j a l > F > " t h a l a t e ( R e f e r e n c e S p e c t r u m )

113v

.L.Li...LJ.,IL..i......

y240/167

1 / 2 7 9228\ . /

................,....AJ:..... ....... I.75 100 125 150 175 200 225 250 275 300 325m / z

Scan 4499 (28.124 m i n ) o f S 3 A 6 6 7 2 . D (* DIFFERENCE)

3 ^ r~"75 100 125 150 175 200 225 250 275 300 325m / z

5.5^5,0-i4..5Hj^, :f 4..0-:s 3..5^:^ 3,0-:

" 2..5\2..Q\1..5^'1..00..5-;O..0^~^r~. —— r-r r-r — , - . - . -- . . . ,J — — — — — , — — — — — —

27.8 28.0 28.2 28.4 28.6H i nIon 167.009 ?-**4:^

2..01 Q I

1,61.4

I i<2O [s 1<0

> 0.80.60.4-0,2-0 ^ _- i>»- . iÂ._>f _V ____

27.8 28.0 28.2 28.4 28.6H i n

043

000683

Data F i l e : S S A V O G A D R O M J S E R D A T A S O r g a n i c S s v o a S s S . i \ 0 0 1 1 2 7 A . B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 I n s t r u m e n t : s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B U 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1 . 0 Operator: C SC o l u m n phase: DB-5MS C o l u m n d i a m e t e r : 0.25L i b r a r y Search Compound H a t c h

Hexaco saneH e p t a d e c a n e , 2 ,6,10,15-te tramethy1-Octadecane



Q u a l i t y F o r m u l a W e i g h t

95 C 2 6 H 5 493 C 2 1 H 4 493 C18H38

366296254

10.08.0

£>$> 6.0vHX

1b 2.0z0.0

10.08.0

f oS 6.0X

£b 2.0z0.0

10.08.0

f oo 6.0X

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/^ /-141 / X183 225 253 ,295 36^ ,368

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100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/zEntry »42196, H e p t a d e c a n e , 2 ,6 ,10,15- t e tramethyl- ( f r o m N B S 7 5 K . L ) ( S C A L E D )

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Entry #71559, Octadecane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

/ € 5

X 1 2 7 / L 6 S 254v. _ jL.....jL _ Ji. _j. .j. .*. .t. ». .* „ . ,.

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000684

Data F i l e t \ S A V O G A D R O \ U S E R D A T A S C I r s a n i c \ s v o a S s 3 . i \ 0 0 1 1 2 7 A . B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 I n s t r u m e n t : s3.iS a m p l e I n f o * 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1 . 0 Operator: C SC o l u m n phase: DB-5MS C o l u m n d i a m e t e r : 0.25L i b r a r y Search Compound H a t c h C A S N u m b e r L i b r a r y Entry Q u a l i t y F o r m u l a W e i g h t

H e n e i c o s a n e 629-94-7 N B S 7 5 K . L 42201 90 C 2 1 H 4 4 296Heptacosane 593-49-7 N B S 7 5 K . L 74082 - 89 C27H56 380Tetraco sane 646-31-1 NBS75K.L 73543 87 C 2 4 H 5 0 338

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1 x^27 A55 A97 /239 /267 338x^1 ,1 i , ' ' ' ' ^

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045

000685

Data F i l e : S S A V O G A D R O N U S E R D A T A S O r g a n i c\svoaXs3. iS001127A. B S S 3 A 6 6 7 2 . DDate : 28-NOV-2000 01:22C l i e n t I D : F 0 5 C 3 I n s t r u m e n t : s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d C u t ) : 1 .0 Opera t or: CSColumn phase; DB-5HS Column diameter: 0.25Library Search Compound M a t c h

T r i o o s a n eH e n e i c o s a n e , l l - ( l - e t h y l p r o p y l ) -N o n a d e c a n e




93 C 2 3 H 4 8 32487 C 2 6 H 5 4 36687 C 1 9 H 4 0 268

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0.0

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71

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Entry «51002, H e n e i c o s a n e , l l - ( l - e t h y l p r o p y l ) - ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 7 1

— qSyyi i / / L 4 1 îgg ^97 y225 ,253 29E\ 337v

80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380m / zEntry #7194".?, N o n a d e c a n e ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 7 1

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illi .11. . i l l . i l l . il n .1 .1 „ . i.80 100 120 140 1£.0 180 200 220 240 260 280 300 320 340 360 380m / z

046

000686

Data F i l e : \ \ A V O G A D R O S U S E R D A T A \ O r g a n i cSsvoa\s3. i \001127A.BSS3A6672.DDate ; 28-NOV-2000 01:22C l i e n t ID: F05C3 Instrument: s3.iS a m p l e I n f o : 7 1 8 8 1 0 0 6 , F 0 5 C 3 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d ( u L ) : 1 .0 Operator: CSC o l u m n phase: DB-5MS C o l u m n d i a m e t e r : 0.25

Library Search Compound H a t c h

N o n a c o s a n eEicosaneT r i c o s a n e

CAS N u m b e r L i b r a r y

630-03-5112-95-8638-67-5

N B S 7 5 K . LN B S 7 5 K . LN B S 7 5 K . L

Entry

545263986273318


94 C 2 9 H 6 0 40890 C 2 0 H 4 2 28290 C 2 3 H 4 8 324

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1 i ,1 I X 1 2 ' x155 ::1<\ X 2 3 7 295\ X 3 0 9 X 3 5 5 409\ X 4 3 0 49C\li I . . | J | . . , k L l l . l l J j | . . « j l . . . j l . l . l l . . .i ,,!«.. M l « . I . I . . . . ( 1 11 1 .. , ... . 1 . 1 . . . . . . . . ... . .

75 100 125 150 175 200 225 250 275 300 325 35O 375 400 425 450 475f H / Z

Entry #54526, Nonacosane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

1 OKX 6 5

, X 1 1 3 X 1 5 5 X 1 9 7 X 2 2 5 X 2 6 7 X 3 0 9 X 3 3 ' 40&\1....II ...JI....jL....ll....J......(......l......L..........-.i............. ____ .......... ..... ... ..... .... .... .... .... .... . ....75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m/z

Entry #398>»2, Eicosane ( f r o m N B S 7 5 K . L ) ( S C A L E D )

X 7 1

1/"3 /d41 ^3 /2±1 ZS2^

....ill. „«. ...jl... ..it. .J. .1. ..j ..ji . i. . ..i. ..i. .... .. .. ..I.75 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475m / z

Entry #73318, T r i c o s a n e ( f r o w N B S 7 5 K . L ) ( S C A L E D )

X 6 5

X 1 2 7 X-69 X^11 x2 5 3 324\ /3 2«J ...1.....L....1....J,....,. ...... .L ........./.... ... / ... .. . ...V'5 100 125 150 175 200 225 250 275 300 325 350 375 400 425 450 475

M / Z 04V

000687

1LCBL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E E T

E P A S A M P L E N O .

F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0053L a b Code: M I T K E M Ca.se N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilution Fac t or: 1.0

GAS NO. C O M P O U N DC O N C E N T R A T I O N( u g / L ) Q

J-U O _7_/ £*111-44-4 ——n C E T * 7 O95-57-8----95-48-7 — — —108-60-1 ——106-44-5---621-64-7----£ T *"71 "167-72-1-----98-95-3 — — — -•70 C Q 1Q£ 77^ — f^ — — — — -T n C C*7 Q111-91-1----i on ni o __._L^sU OJ /. — — — -91-20 3------/ -1> £^\J *J

106-47-8 —— -Q «7 C Q OO / DO~ J — — — -59-50-7 — — — -Q1 C T * 7 C.77-47-4 — — — —Q Q f\C O

yD — yo "± — ~91-58-7 — — — —88-74-4 — — — —131-11-3- ——o n Q QC ocf\c on oD U O — îU — ^ — — — —qq n q _ o _ _ _ _ _;73 \Jy — A — — — — —Q O - j o _ q _ _ _ _oj— jz — 17 — — — —

—— -bis ( - 2 - Chloroethyl ) Ether __- - — - 2 - Chlorophenol. _ _ _ .. 2 -Methylphenol-- — -2,2' -oxybis (1-Chloropropane)- - — - 4 -Methylphenol- - — -N-Nitro so-d i-n-propylamine _TTy~ iT^'a /~» V* 1 f~\ Y*^~\d ^ Tn ^ n oXT^ ^ •V^^T*^("\T1 T r t T I rt

- - - - -Isophorone- - — - 2 -Ni t rophenol-----2,4 -Dimethylphenol- - - - -bis ( - 2 -Chloroethoxy) methane_- - — 2,4 -Dichlorophenol- - — -Naphthia l ene•- — -4-Chloroaniline• - - - -HexachLorobutadiene- — -4 -Chloro- 3 -Methylphenol ___- — -2 -Methylnaphthalene- - - -Hexachlorocyclopentadiene-----2,4,6 -Tri chlorophenol- — - 2 , 4 , 5 - Tri chlorophenol—— 2 -Chloronaphthalene- — -2 -Nitroanil ine- — -Dimethylphthalate-----2,6 -Dinitrotoluene- -- -3 -Nitroaniline

555555555555555555555

20520555205


FORM I L C S V - 1 O L C 0 2 . 1

000688

1LCCL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E J 3 T E P A S A M P L E N O .

F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a n p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )


CAS NO. COMPOOflDC O N C E N T R A T I O N

( u g / L ) Q

5 1 - 2 8 - 5 - - — - - - - - 2 , 4 - D i n i t r o p h e n o l _100-02-7-—-----4-Nitropheno l___132-64-9--------Dibenzofuran1 2 1 - 1 4 - 2 — — - — -2,4-Dinitrotoluene_________8 4 - 6 6 - 2 — — — — — — D i e t h y l p h t h a l a t e _ _ _ _ _ _ _ _7005-72-3------- 4-Chlorophenyl-phenylether_86-73-7— — -- — -Fluorene __ ____1 0 0 - 0 1 - 6 — — — ---4-Nitroamline534-52-1-----8 6 - 3 0 - 6 — — — —1 0 1 - 5 5 - 3 — — — —118-74-1-----87-86-5------8 5 - 0 1 - 8 — — — - - - P h e n a n t h r e n e120-12-7- — - —— -Anthracene84-74-2 — — — -2 0 6 - 4 4 - 0 — — — -1 2 9 - 0 0 - 0 — — — -8 5 - 6 8 - 7 — — — —

•4,6-Dinitro-2-methylphenol_N-nitrosodiphenylamine ( 1 ) ]4 -Bromophenyl -phenylether__Hexachlorobenzene_________Pentaclilorophenol_______Di - n- bu ty lph tha la t e_Fluoranthene_____~Pyrene__- Butylbenzylphthala t e_91-94-1— — — — -3,3 ' -Dichlorobenzidine______56-55-3 — — — — — B e n z o (a) anthracene_________2 1 8 - 0 1 - 9 — — — - - - C h r y s e n e1 1 7 - 8 1 - 7 — — — — b i s (2 - K t h y l h e x y l ) phthalat e1 1 7 - 8 4 - 0 — — — — — D i - n - o c t y l p h t h a l a t e _ _ _ _ _ _ _ _2 0 5 - 9 9 - 2 - - - — — — B e n z o ( b ) fluoranthene______

2 0 7 - 0 8 - 9 — — — -50-32-8 — — — — -1 9 3 - 3 9 - 5 — — — -5 3 - 7 0 - 3 — — — — -1 9 1 - 2 4 - 2 — — — -

-Benzo(k)f luoran th ene_-Benzo(a)pyrene_- I n d e n o ( 1 , 2 , 3 - c d ) p y r e n e _-Dibenzo(a,h)anthracene_-Benzo(g , h, i ) p e r y l e n e _

20205555520205552055555555555555555


( 1 ) - Cannot b e separated f r om Diphenylamine

FORM I L C S V - 2 .1

000689

1LCFL O W C O N C . W A T E R S E M I V O L A T I L E O R G A N I C S A N A L Y S I S D A T A S H E I S TT E N T A T I V E L Y I D E N T I F I E D COMPOUNDS

EPA S A M P L E NO.

F 0 5 C 4Lab Name: MITKEM CORPORATION Contract: 68-D6-0063L a b Code: M I T K E M ' Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881001L a b F i l e I D : S 3 A 6 6 7 5S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1 0 0 0 ( u L )

Date Received: 1 1 / 1 7 / 0 0Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 8 / 0 0Dilut ion F a c t o r : 1.0

Number TICs f ound: 0

GAS NUMBER1.2.3.4.5.6.7.8.9.10.11.

12.13.14.15.16.17.18.19.20.21.22.23.24.25.26.27.28.29.30.

C O M P O U N D N A M E RT E S T . C O N C .( u g / L ) Q

_

FORM I L C S V - T I C OLC02.1

000690

Data F i l e : \ S A V O G A D R O S U S E R D f t T A \ O r g a n i c S s v o a S s 3 . i \ 0 0 1 1 2 7 f l . B N S 3 A 6 6 7 5 , DDate J 28-NOV-2000 03;43C l i e n t I D : F05C4S a m p l e I n f o ; 7 1 8 8 1 0 0 1 , F 0 5 C 4 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1V o l u m e I n j e c t e d <uL>: 1 .0C o l u m n phase: D B - 5 H S

Instrument: s3.i

Operator: CSC o l u m n d i a m e t e r : 0.25

\SfiVOCfiDROSUSERDATflSOrgan i cSsvoa\s3 . i \001127ft . B N S 3 f t 6 6 7 5 . D3.9-i ~3.BJ £ |3,7-; o t.3 g, : a.3:«»] !3.4H §3.3-i £3.2^ 73.1-^3.0-:2.9-i2.8-i2.7-!- - i 002.6- -o2.5-i *2.4- j S: 2 "2.3-i ? £: 01 ^

2;J I ! i^ : Oi c^ 2 - °^ » f S3 -1 <» • TJ 5; Cx " i 2 ^" i ° •§ I*" i.?^ g 5 S .U1.5-: g1.4 8

12^ w

0.8-i0.7-j0.6-i0.5-10.4-i0.3-j0.2 .

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(VI•H7J1HiCOP

5CM701Ef

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V^ \ • • • \ •' • • T^ " ^^ • - . — - - — — ; — ; — : — : — ; — .- —. — :~ ,- -. — r — : — - — : — — ; — : —— - — - ——— r—. — ^-. — : — r , . . . , . . . , . . . , . . . , . . . , . . . , . .i . 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38^ " H i n

000691

IIIIIIIIIIIIIIII

Data F i l e : S 3 A 6 6 7 5 . DReport Date: 2 9 - N o v - 2 0 ( ) 0 11:24

Data f i l eL a b S m p I dI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eD i l F a c t o rI n t e g r a t o r

M i t k e m C o r p o r a t i o nC L P O L C 0 2 Q U A N T I T A T I O N REPORT

\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ S v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 5 . D71881001 C l i e n t S m p I D : F 0 5 C 4 /2 8 - N O V - 2 0 0 0 03:43 'C S I n s t I D : S 3 . L7 1 8 8 1 0 0 1 , F 0 5 C 4 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1, , , ! , , , , , , , 1 7 - N O V - O O , 1 7 - N O V - O O\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 j 6 6 _ U D221.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03P r o c e s s i n g H o s t : T A R G E T 7

C o n c e n t r a t i o n F o r m u l a : Amt * DF * Uf * V t / ( V o * Vi)Name V a l u e D e s c r i p t i o n

DFU fvtVoVi

1.000 D i l u t i o n F a c t o r1.000 ng unit correct ion f a c t o r1000.000 V o l u m e o f f i n a l extract ( u L )1000.000 Volume o f s a m p l e e x t rac t ed ( m L )1.000 Volume i n j e c t e d ( u L )

Compounds

$ 1 2 - F l u o r o p h e n o l$ 2 P h e n o l - d 5* 6 1 ,4-Dich lorob enzene-d4$ 12 N i t r o b e n z e n e - d 5* 19 N a p h t h a l e n e - d S$ 28 2 - F l u o r o b i p h e n y l* 35 A c e n a p h t h e n e - d l O$ 47 2 , 4 , 6 - T r i b r o m o p h e n o l* 51 Phenanthrene-d lO$ 57 T e r p h e n y l - d l 4* 61 C h r y s e n e - d l 2* 68 P e r y l e n e - d l 2

Q U A N T S I GM A S S

11299

15282

136172164330188244240264

RT EXP RT REL RT

101213141518192122252831

.047

.398.183.385.913.178.567.201.639.940.087.175

101213141518192122252831

.052.408.183.390.912.178.577.212.649.940.098.186

( 0( 0( 1( 0( 1( 0( 1( 0( 1( 0( 1(1

= = = = =. 7 6 2 ). 9 4 0 ). 0 0 0 ). 9 0 4 ). 0 0 0 ). 9 2 9 ). 0 0 0 ). 9 3 7 ). 0 0 0 ). 9 2 4 ). 0 0 0 ). 0 0 0 )

6 5 2 6 4 99004813 6 4 0 6 6813712

14399521557809

8412066 3 7 2 4 9

13340701 9 6 6 1 4 21 2 2 8 0 9 21177497

141320282027204720322020

S = !3= =

. 2 5 6 0

.8245

.0000

.7093

.0000

.3824

.0000

.1923

.0000.0613.0000.0000

C O N C E N T R A T I O N SO N - C O L U M N F I N A L

R E S P O N S E ( n g ) ( u g / L )

1414

29

27

47

32

052

000692


Data f i l eL a b S m p I dI n j DateOperatorS m p I n f oM i s c I n f oCommentM e t h o dM e t h DateCal DateA l s b o t t l eDil F a c t o rI n t e g r a t o r

M i t k e m C o r p o r a t i o nC L P O L C 0 2 Q U A N T I T A T I O N REPORT

\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ S 3 A 6 6 7 5 .D71881001 C l i e n t S m p I D : F 0 5 C 42 8 - N O V - 2 0 0 0 03:43C S I n s t I D : S 3 . i7 1 8 8 1 0 0 1 , F 0 5 C 4 , S 1 1 1 7 - B W 4 , C S , , F 0 5 C 1, , , ! , , , , , , , , 1 7 - N O V - 0 0 , 1 7 - N O V - 0 0\ \ A V O G A D R O \ U S E R D A T A \ O r g a n i c \ s v o a \ s 3 . i \ 0 0 1 1 2 7 A . B \ s 3 _ _ c l p _ l o w . m2 9 - N O V - 2 0 0 0 11:05 m t l Quant T y p e : I S T D2 7 - N O V - 2 0 0 0 16:41 C a l F i l e : S 3 A 6 6 6 1 . D221.00000H P R T E Compound S u b l i s t : a l l . s u bT a r g e t V e r s i o n : 4.03Proce s s ing H o s t : T A R G E T ?

- N O T E N T A T I V E L Y I D E N T I F I E D C O M P O U N D S -

053000693

IIIIIIIIIIIIIIIIIII

1LCBL O W C O N C . W A T E R S E M I V O L A T I L E ORGAN!CS A N A L Y S I S D A T A S H E E T EPA S A M P L E MO.

F 0 5 C 5Lab Name: MITKEM CORPORATION Contract: 68-D6-0063 _________L a b Code: M I T K E M Case N o . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881002L a b F i l e I D : S 3 A 6 6 7 0S a m p l e Volume: 1000.00 (mL)Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

CAS NO. C O M P O U N D


1 0 0 0 ( u L ) Dilut ion F a c t o r : 1.0


108-95-2- — — ---Phenol____________________1 1 1 - 4 4 - 4 — — — — - - b i s ( - 2 - C h l o r o e t h y l ) E t h e r95-57-8——-----2-Chloropheno l__________9 5 - 4 8 - 7 - - - - — — - 2 - M e t h y l p h e n o l _ _ _ _ _ _ _ _ _ _ _ _1 0 8 - 6 0 - 1 — — — — 2 , 2 ' -oxybis (1-Chloropropane)1 0 6 - 4 4 - 5 — — — — — 4 - M e t h y l p h e n o l _ _ _ _ _ _ _ _6 2 1 - 6 4 - 7 — — - - - - -N-Nitro so-d i-n-propylamine98-95-3----—---Nitrob enz ene7 8 - 5 9 - 1 — - - — ---Isophorone___________________88-75-5— — — - - -2-Nitrophenol ____________105-67-9- — — — -2,4 -Dimethylphenol1 1 1 - 9 1 - 1 — — - - — b i s (-2 -Chloroe thoxy) methane_120-83-2--------2,4-Dichlorophenol________91-20-3---- — -- -Naphthalene_______________1 0 6 - 4 7 - 8 - — - - — - 4 - C h l o r o a n i l i n e87-68-3 — — — — -Hexachlorobutadiene59-50-7— — -- — -4-Cnloro-3 -Methylphenol___9 1 - 5 7 - 6 — — — — — 2 - M e t h y l n a p h t h a l e n e _ _ i _ _ _ _ _ _7 7 - 4 7 - 4 — - - — — -Hexachiorocyclopentadiene88-06-2---------2,4,6-Trichlorophenol______9 5 - 9 5 - 4 — — — — — 2 , 4 , 5 -Tri Chlorophenol_____9 1 - 5 8 - 7 — — — — — — 2 - C h l o r o n a p h t h a l e n e _ _ _ _ _ _ _ _ _88-74-4— — — — — 2 - N i t r o a n i l i n e _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _131-11-3 — — — — — D i m e t h y l p h t h a l a t e _ _ _ _ _ _ _ _ _ _ _208-96-8- — — — -Acenaphthylene_______________606-20-2--------2, 6-Dinitrotoluene____________9 9 - 0 9 - 2 — - - — — -3-Nitroaniline_____________83-32-9----—---Acenaphthene____________

5555555555555555555552052055520


FORM I L C S V - 1 O L C 0 2 . 1054

000694

1LCCL O W C O N C . W A T E R S E M I V O L A T T L E O R G A N I C S A N A L Y S I S D A T A S H E E T EPA S A M P L E NO.

F 0 5 C 5Lab Name: MITKEM C O R P O R A T I O N Contract: 68-D6-0063L a b Code: M I T K E M Ccise N O . : 28724 S A S N o . : S D G N o . : F 0 5 C 1Lab S a m p l e ID: 71881002L a b F i l e I D : S 3 A 6 6 7 0S a m p l e Volume: 1000.00 ( m L )Concentrated Extract Volume:I n j e c t i o n Volume: 1 ( u L )

1000 ( u L )

Date Received: 11/17/00Date Extracted: 1 1 / 1 7 / 0 0Date Analyzed: 1 1 / 2 7 / 0 0Dilution Fac t or: l .0

CAS NO. C O M P O U N DC O N C E N T R A T I O N

( u g / L ) Q

-2,4 -Diiii trotoluene_-Die thy lph tha la t e_

5 1 - 2 8 - 5 — — - - — - 2 , 4 - D i n i t r o p h e n o l100-02-7- -------4-Nitrophenol___~1 3 2 - 6 4 - 9 - - - - - — - D i b e n z o f u r a n121-14-2-----84-66-2------ ________7005-72-3 — -----4-Chlorophenyl-phenyle ther_8 6 - 7 3 - 7 — — - - - - - F l u o r e n e1 0 0 - 0 1 - 6 - — - - — - 4 - N i t r o a n i l i n e5 3 4 - 5 2 - 1 — — - -86-30-6 — —— -101-55-3 —— --

- - — - 4 , 6 - D i n i t r o - 2 - m e t h y l p h e n o l _-----N-nitrosodiphenylamine ( 1 ) _-----4-Bromophenyl-phenylether__118-74-1- - - - - — -Hexachlorobenzene_________87-86-5-- — -----Pentachlorophenol_______85- 01-8 - - — ---- -Phenanthrene_______________120-12-7- — ----Anthracene______________84-74-2-- — ----Di-n-butylphthalate_____206 -44-0- - ------Fluorarithene1 2 9 - 0 0 - 0 — — —8 5 - 6 8 - 7 — — — _ _9 1 - 9 4 - 1 - - — - - - - - 3 , 3 ' - D i c h l o r o b e n z i d i n e56-55-3-----2 1 8 - 0 1 - 9 - — —1 1 7 - 8 1 - 7 — — —1 1 7 - 8 4 - 0 — — —2 0 5 - 9 9 - 2 — — —2 0 7 - 0 8 - 9 - — —5 0 - 3 2 - 8 — — — —1 9 3 - 3 9 - 5 — — —5 3 - 7 0 - 3 — — — —191-24-2- ——

- Pyrene________________-Butylbe.nzylphthalate_-Benzo ( a i ) anthracene-Chrysene_b i s ( 2 - E t h y l h e x y l ) p h t h a l a t e _-Di - n- oc ty lph tha la t e_________-Benzo (b) f luoranthene______-Benzo (k) f luoranthene________-Benzo (a.) pyrene_--Indeno ( 1 , 2 , 3 - c d ) p y r e n e _-Dibenzo (a, h) anthracene"-Benzo (g, h , i) perylene_

2020555552020

5552055555555555555555


(1) -Cannot be separated from Diphenylamine

FORM I L C S V - 2 OLCQ2 ,1U J O

000695

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