IXM MANUFACTURING PROCESS E2 STACK EMISSIONS TEST … · IASDATA\CHEMOURS\15418.002.018\E2 STACK...

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IASDATACHEMOURS15418002018E2 STACK REPORT 12 2019-AMD 1212020

IXM MANUFACTURING PROCESS E2 STACK EMISSIONS TEST REPORT

TEST DATES 4-5 DECEMBER 2019

THE CHEMOURS COMPANY FAYETTEVILLE NORTH CAROLINA

Prepared for

THE CHEMOURS COMPANY 22828 NC Hwy 87 W

Fayetteville North Carolina 28306

Prepared by

WESTON SOLUTIONS INC 1400 Weston Way

PO Box 2653 West Chester Pennsylvania 19380

January 2020

WO No 15418002018

THE CHEMOURS COMPANY

TEST DATES 4-5 December 2019

Weston Solutions Inc (WESTONreg) is a commercial laboratory operating within full accreditation of the Louisiana Environmental Laboratory Accreditation Program under Certificate Number 03024 The qualifications to provide defensible quality data as a certified commercial environmental testing firm as Agency Interest No 30815 was granted by the Louisiana Department of Environmental Quality under the Louisiana Administrative Code of LAC 331 Chapter 45 et al

I certify that I have personally examined and am familiar with the information contained herein Based on my information and belief formed after reasonable inquiry the statements and information in the document are true accurate and complete

Paul M Meeter Weston Solutions Inc

IASDATACHEMOURS15418002018E2 STACK REPORT 12 2019-AMD 1212020 i

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

11 FACILITY AND BACKGROUND INFORMATION 1

12 TEST OBJECTIVES 1

13 TEST PROGRAM OVERVIEW 1

2 SUMMARY OF TEST RESULTS 4

3 PROCESS DESCRIPTIONS 5

31 E-2 5

32 PROCESS OPERATIONS AND PARAMETERS 5

4 DESCRIPTION OF TEST LOCATIONS 6

41 E2 STACK 6

5 SAMPLING AND ANALYTICAL METHODS 8

51 STACK GAS SAMPLING PROCEDURES 8

511 Pre-Test Determinations 8

52 STACK PARAMETERS 8

521 EPA Method 00108 522 EPA Method 0010 Sample Recovery 10 523 EPA Method 0010 Sample Analysis12

53 GAS COMPOSITION 14

6 DETAILED TEST RESULTS AND DISCUSSION 15 APPENDIX A PROCESS OPERATIONS DATA

APPENDIX B RAW AND REDUCED TEST DATA

APPENDIX C LABORATORY ANALYTICAL REPORT

APPENDIX D SAMPLE CALCULATIONS

APPENDIX E EQUIPMENT CALIBRATION RECORDS

APPENDIX F LIST OF PROJECT PARTICIPANTS

IASDATACHEMOURS15418002018E2 STACK REPORT 12 2019-AMD 1212020 ii

LIST OF FIGURES

Title Page

Figure 4-1 E2 Stack Test Port and Traverse Point Location 7

Figure 5-1 EPA Method 0010 Sampling Train 9

Figure 5-2 HFPO Dimer Acid Sample Recovery Procedures for Method 0010 13

IASDATACHEMOURS15418002018E2 STACK REPORT 12 2019-AMD 1212020 iii

LIST OF TABLES

Title Page

Table 1-1 Sampling Plan for E2 Stack 3

Table 2-1 Summary of HFPO Dimer Acid E2 Stack Test Results 4

Table 6-1 Summary of HFPO Dimer Acid Test Data and Test Results E2 Stack ndash Runs 1 2 and

3 16

IASDATACHEMOURS15418002018E2 STACK REPORT 12 2019-AMD 1212020 1

1 INTRODUCTION

11 FACILITY AND BACKGROUND INFORMATION

The Chemours Fayetteville Works (Chemours) is located in Bladen County North Carolina

approximately 10 miles south of the city of Fayetteville Chemours operating areas on the site

include the Fluoromonomers IXM and Polymers Processing Aid (PPA) manufacturing areas

Wastewater Treatment and Powerhouse

Chemours contracted Weston Solutions Inc (Weston) to perform HFPO Dimer Acid Fluoride

captured as HFPO Dimer Acid emission testing on the E2 stack at the facility Testing was

performed on 4-5 December 2019 and generally followed the ldquoEmission Test Protocolrdquo reviewed

and approved by the North Carolina Department of Environmental Quality (NCDEQ) This

report provides the results from the emission test program

12 TEST OBJECTIVES

The specific objectives for this test program were as follows

Measure the emissions concentrations and mass emissions rates of HFPO Dimer Acid Fluoride from the E2 stack which is located in the IXM process area

Monitor and record process and emissions control data in conjunction with the test program

Provide representative emissions data

13 TEST PROGRAM OVERVIEW

During the emissions test program the concentrations and mass emissions rates of HFPO Dimer

Acid were measured at the test location

Table 1-1 provides a summary of the test locations and the parameters that were measured along

with the samplinganalytical procedures that were followed

Section 2 provides a summary of test results A description of the processes is provided in

Section 3 Section 4 provides a description of the test locations The sampling and analytical

procedures are provided in Section 5 Detailed test results and discussion are provided in

Section 6

Appendix C includes the summary reports for the laboratory analytical results The full

laboratory data packages are provided in electronic format

Table 1-1 Sampling Plan for E2 Stack

Sampling Point amp Location E2 Stack Number of Tests 3 Parameters To Be Tested HFPO Dimer

Acid

(HFPO-DA)

Volumetric Flow Rate and Gas Velocity

Carbon Dioxide

Oxygen Water Content

Sampling or Monitoring Method EPA M-0010 EPA M1 and M2 in

conjunction with M-0010

tests

EPA M33A EPA M4 in conjunction

with M-0010 tests

Sample Extraction Analysis Method(s) LCMSMS NA6 NA NA Sample Size ge 15m3 NA NA NA NA Total Number of Samples Collected1 3 3 3 3 3 Reagent Blanks (Solvents Resins)1 1 set 0 0 0 0 Field Blank Trains1 1 per source 0 0 0 0 Proof Blanks1 1 per train 0 0 0 0 Trip Blanks12 0 set 0 0 0 0 Lab Blanks 1 per fraction3 0 0 0 0 Laboratory or Batch Control Spike Samples (LCS)

1 per fraction3 0 0 0 0

Laboratory or Batch Control Spike Sample Duplicate (LCSD)

Media Blanks 1 set4 0 0 0 0 Isotope Dilution Internal Standard Spikes Each sample 0 0 0 0 Total No of Samples 65 3 3 3 3

Key 1 Sample collected in field 2 Trip blanks include one XAD-2 resin module and one methanol sample per sample shipment 3 Lab blank and LCSLCSD includes one set per analytical fraction (front half back half and condensate) 4 One set of media blank archived at laboratory at media preparation 5 Actual number of samples collected in field 6 Not applicable

2 SUMMARY OF TEST RESULTS

A total of three test runs were performed on the E2 stack Table 2-1 provides a summary of the

HFPO Dimer Acid emissions test results Detailed test results summaries are provided in

Section 6

It is important to note that emphasis is being placed on the characterization of the emissions

based on the stack test results Research conducted in developing the protocol for stack testing

HFPO Dimer Acid Fluoride HFPO Dimer Acid Ammonium Salt and HFPO Dimer Acid

realized that the resulting testing including collection of the air samples and extraction of the

various fraction of the sampling train would result in all three compounds being expressed as

simply the HFPO Dimer Acid However it should be understood that the total HFPO Dimer

Acid results provided in Table 2-1 and in this report include a percentage of each of the three

compounds

Table 2-1 Summary of HFPO Dimer Acid E2 Stack Test Results

E2 Stack gsec lbhr

R1 111E-05 880E-05 R2 134E-06 106E-05 R3 200E-06 159E-05 Average 481E-06 382E-05

3 PROCESS DESCRIPTIONS

The IXM area is included in the scope of this test program

31 E-2

Freon E-2reg is a compound used in Nafiontrade polymerization processes to promote heat

dissipation

32 PROCESS OPERATIONS AND PARAMETERS

The following table is a summary of the operation and products from the specific areas tested

Source OperationProduct Batch or Continuous E2 Stack E-2 Batch

During the test program the following parameters were monitored by Chemours and are

included in Appendix A

IXM Process o E2 Reactor o Decanting o Drying

4 DESCRIPTION OF TEST LOCATIONS

41 E2 STACK

Two 3-inch ID test ports were installed on the 18-inch ID steel stack as shown below

Per EPA Method 1 a total of 12 traverse points (six per axis) were used for M-0010 isokinetic

sampling Figure 4-1 provides a schematic of the test ports and traverse point locations

Location Distance from Flow Disturbance Downstream (B) Upstream (A)

E2 Stack 125 feet gt 8 duct diameters

4 feet gt 26 diameters

DRAWING NOT TO SCALE

4

125

FIGURE 4-1E2 STACK

TEST PORT AND TRAVERSE POINT LOCATION

IASDATACHEMOURS15418002018FIGURE 4-1 E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

DISTANCE FROMINSIDE NEAR

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

5 SAMPLING AND ANALYTICAL METHODS

51 STACK GAS SAMPLING PROCEDURES

The purpose of this section is to describe the stack gas emissions sampling trains and to provide

details of the stack sampling and analytical procedures utilized during the emissions test

program

511 Pre-Test Determinations

Preliminary test data were obtained at the test location Stack geometry measurements were

measured and recorded and traverse point distances verified A preliminary velocity traverse

was performed utilizing a calibrated S-type pitot tube and an inclined manometer to determine

velocity profiles Flue gas temperatures were observed with a calibrated direct readout panel

meter equipped with a chromel-alumel thermocouple Preliminary water vapor content was

estimated by wet bulbdry bulb temperature measurements

A check for the presence or absence of cyclonic flow was conducted at the test location The

cyclonic flow check was negative (lt 20deg) verifying that the test location was acceptable for

testing

Preliminary test data was used for nozzle sizing and sampling rate determinations for isokinetic

sampling procedures

Calibration of probe nozzles pitot tubes metering systems and temperature measurement

devices was performed as specified in Section 5 of EPA Method 5 test procedures

52 STACK PARAMETERS

521 EPA Method 0010

The sampling train utilized to perform the HFPO Dimer Acid sampling at the location was an

EPA Method 0010 train (see Figure 5-1) The Method 0010 consisted of a borosilicate nozzle

that attached directly to a heated borosilicate probe In order to minimize possible thermal

degradation of the HFPO Dimer Acid the probe and particulate filter were heated above stack

temperature to minimize water vapor condensation before the filter The probe was connected

directly to a heated borosilicate filter holder containing a solvent extracted glass fiber filter

6

9

A section of borosilicate glass or flexible polyethylene tubing connected the filter holder exit to a

Grahm (spiral) type ice water-cooled condenser an ice water-jacketed sorbent module containing

approximately 40 grams of XAD-2 resin The XAD-2 resin tube was equipped with an inlet

temperature sensor The XAD-2 resin trap was followed by a condensate knockout impinger and

a series of two impingers that contained 100 mL of high-purity distilled water The train also

included a second XAD-2 resin trap behind the impinger section to evaluate possible sampling

train breakthrough Each XAD-2 resin trap was connected to a 1-liter condensate knockout trap

The final impinger contained 300 grams of dry pre-weighed silica gel All impingers and the

condensate traps were maintained in an ice bath Ice water was continuously circulated in the

condenser and the XAD-2 module to maintain method-required temperature A control console

with a leakless vacuum pump a calibrated orifice and dual inclined manometers was connected

to the final impinger via an umbilical cord to complete the sample train

HFPO Dimer Acid Fluoride (CAS No 2062-98-8) that is present in the stack gas is expected to

be captured in the sampling train along with HFPO Dimer Acid (CAS No 13252-13-6) HFPO

Dimer Acid Fluoride underwent hydrolysis instantaneously in water in the sampling train and

during the sample recovery step and was converted to HFPO Dimer Acid such that the amount

of HFPO Dimer Acid emissions represented a combination of both HFPO Dimer Acid Fluoride

and HFPO Dimer Acid

During sampling gas stream velocities were measured by attaching a calibrated S-type pitot tube

into the gas stream adjacent to the sampling nozzle The velocity pressure differential was

observed immediately after positioning the nozzle at each traverse point and the sampling rate

adjusted to maintain isokineticity at 100 plusmn 10 Flue gas temperature was monitored at each

point with a calibrated panel meter and thermocouple Isokinetic test data was recorded at each

traverse point during all test periods as appropriate Leak checks were performed on the

sampling apparatus according to reference method instructions prior to and following each run

component change (if required) or during midpoint port changes

522 EPA Method 0010 Sample Recovery

At the conclusion of each test the sampling train was dismantled the openings sealed and the

components transported to the field laboratory trailer for recovery

A consistent procedure was employed for sample recovery

1 The two XAD-2 covered (to minimize light degradation) sorbent modules (1 and 2) were sealed and labeled

2 The glass fiber filter(s) were removed from the holder with tweezers and placed in a

polyethylene container along with any loose particulate and filter fragments

3 The particulate adhering to the internal surfaces of the nozzle probe and front half of the filter holder were rinsed with a solution of methanol and ammonium hydroxide into a polyethylene container while brushing a minimum of three times until no visible particulate remained Particulate adhering to the brush was rinsed with methanol ammonium hydroxide into the same container The container was sealed

4 The volume of liquid collected in the first condensate trap was measured the value

recorded and the contents poured into a polyethylene container

5 All train components between the filter exit and the first condensate trap were rinsed with methanolammonium hydroxide The solvent rinse was placed in a separate polyethylene container and sealed

6 The volume of liquid in impingers one and two and the second condensate trap were

measured the values recorded and the sample was placed in the same container as Step 4 above then sealed

7 The two impingers condensate trap and connectors were rinsed with methanol ammonium hydroxide The solvent sample was placed in a separate polyethylene container and sealed

8 The silica gel in the final impinger was weighed and the weight gain value recorded

9 Site (reagent) blank samples of the methanolammonium hydroxide XAD resin filter

and distilled water were retained for analysis Each container was labeled to clearly identify its contents All samples were maintained cool

Following sample recovery all samples were transported to TestAmerica Laboratories Inc

(TestAmerica) for sample extraction and analysis

See Figure 5-2 for a schematic of the Method 0010 sample recovery process

523 EPA Method 0010 Sample Analysis

Method 0010 sampling trains resulted in four separate analytical fractions for HFPO Dimer Acid

analysis according to SW-846 Method 3542

Front-half Compositemdashcomprised of the particulate filter and the probe nozzle and

front-half of the filter holder solvent rinses

Back-half Compositemdashcomprised of the first XAD-2 resin material and the back-half of

the filter holder with connecting glassware solvent rinses

Condensate Compositemdashcomprised of the aqueous condensates and the contents of

impingers one and two with solvent rinses

Breakthrough XAD-2 Resin Tubemdashcomprised of the resin tube behind the series of

impingers

The second XAD-2 resin material was analyzed separately to evaluate any possible sampling

train HFPO-DA breakthrough

The front-half and back-half composites and the second XAD-2 resin material were placed in

polypropylene wide-mouth bottles and tumbled with methanol containing 5 NH4OH for 18

hours Portions of the extracts were processed analytically for the HFPO dimer acid by liquid

chromatography and duel mass spectroscopy (HPLCMSMS) The condensate composite was

concentrated onto a solid phase extraction (SPE) cartridge followed by desorption from the

cartridge using methanol Portions of those extracts were also processed analytically by

HPLCMSMS

8

3

13

Samples were spiked with isotope dilution internal standard (IDA) at the commencement of their

preparation to provide accurate assessments of the analytical recoveries Final data was corrected

for IDA standard recoveries

TestAmerica developed detailed procedures for the sample extraction and analysis for HFPO

Dimer Acid These procedures were incorporated into the test protocol

53 GAS COMPOSITION

The Weston mobile laboratory equipped with instrumental analyzers was used to measure carbon

dioxide (CO2) and oxygen (O2) concentrations

For the E2 stack test campaign the sample bag was collected at the exhaust of the Method 0010

sampling system

Each analyzer was set up and calibrated internally by introduction of calibration gas standards

directly to the analyzer from a calibration manifold The calibration manifold is designed with an

atmospheric vent to release excess calibration gas and maintained the calibration at ambient

pressure The direct calibration sequence consisted of alternate injections of zero and mid-range

gases with appropriate adjustments until the desired responses were obtained The high-range

standards were then introduced in sequence without further adjustment

The oxygen and carbon dioxide content of the stack gas was measured according to EPA Method

3A procedures which incorporate the latest updates of EPA Method 7E A Servomex Model

4900 analyzer (or equivalent) was used to measure oxygen content A Servomex Model 4900

analyzer (or equivalent) was used to measure carbon dioxide content of the stack gas Both

analyzers were calibrated with EPA Protocol gases prior to the start of the test program

6 DETAILED TEST RESULTS AND DISCUSSION

Each test was a minimum of 96 minutes in duration A total of three test runs were performed at

the test location

Table 6-1 provides detailed test data and test results for E2 stack

The Method 33A sampling indicated that the O2 and CO2 concentrations were at ambient air

levels (209 O2 0 CO2) therefore 209 O2 and 0 CO2 values were used in all

calculations

12302019 237 PM

16

Dec E2 Stack

TABLE 6-1CHEMOURS - FAYETTEVILLE NC

SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTSE2 STACK

Test DataRun number 1 2 3Location E2 Stack E2 Stack E2 StackDate 120419 120519 120519Time period 1416-1556 0817-0959 1025-1207

SAMPLING DATASampling duration min 960 960 960Nozzle diameter in 0280 0280 0280Cross sectional nozzle area sqft 0000428 0000428 0000428Barometric pressure in Hg 2970 3007 3007Avg orifice press diff in H2O 166 147 183Avg dry gas meter temp deg F 616 516 658Avg abs dry gas meter temp deg R 522 512 526Total liquid collected by train ml 203 336 236Std vol of H2O vapor coll cuft 10 16 111Dry gas meter calibration factor 09972 09972 09972Sample vol at meter cond dcf 68630 63724 71248

Sample vol at std cond dscf (1) 69025 66123 71992Percent of isokinetic sampling 1015 1024 995

GAS STREAM COMPOSITION DATACO2 by volume dry basis 02 02 02O2 by volume dry basis 209 208 208 N2 by volume dry basis 789 790 790 Molecular wt of dry gas lblb mole 2887 2886 2886H20 vapor in gas stream prop by vol 0014 0023 0015Mole fraction of dry gas 0986 0977 0985Molecular wt of wet gas lblb mole 2872 2861 2870

GAS STREAM VELOCITY AND VOLUMETRIC FLOW DATAStatic pressure in H2O 010 030 036Absolute pressure in Hg 2971 3009 3010Avg temperature deg F 66 51 59Avg absolute temperature degR 526 511 519Pitot tube coefficient 084 084 084Total number of traverse points 12 12 12Avg gas stream velocity ftsec 281 259 292Stackduct cross sectional area sqft 176 176 176Avg gas stream volumetric flow wacfmin 2969 2731 3079Avg gas stream volumetric flow dscfmin 2916 2770 3101

(1) Standard conditions = 68 deg F (20 deg C) and 2992 in Hg (760 mm Hg)

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Run number 1 2 3 Location E2 Stack E2 Stack E2 Stack Date 120419 120519 120519

Time period 1416-1556 0817-0959 1025-1207

LABORATORY REPORT DATA ug

HFPO Dimer Acid 1575 192 279

EMISSION RESULTS ugdscm

EMISSION RESULTS lbdscf

HFPO Dimer Acid 503E-10 639E-11 853E-11

EMISSION RESULTS lbhr

EMISSION RESULTS gsec

TABLE 6-1 (cont)

CHEMOURS - FAYETTEVILLE NC

SUMMARY OF HFPO DIMER ACID TEST DATA AND TEST RESULTS

E2 STACK

APPENDIX A PROCESS OPERATIONS DATA

18

E2 StackDate 12419TimeStack Testing

Date 12519TimeStack Testing

1200

1400 1500 1600RUN 1 - 1416-1556

E2 Reactor Cook Step

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

Decanting Drying eeding Trime Drying

1919

20

Sample and Velocity Traverse Point Data Sheet -Method 1

Client ~rrC~~ (rv~ Operator ~

LoactionPlant ~~ ~`l)~~~~ 1 ~~ Date ~~ ~~~SoutCe~~ WO Number ~j~~jsj~~ Crj~ p~j

Duct Type Circular Rectangular Duct Indicate appropriate type

Traverse Type Particulate Traverse p Velocity Traverse ~ CEM Traverse

Distance from far wail to outside of ort in = C ~~-

Port De th in = D

De th of Duct diameter in = C-D t Area of Duct ft2 ~ i Total Traverse Points ~ ~- Total Traverse Points er Port f Port Diameter in --- Flan e-Threaded-Hole

Monorail Len th

Rectan ular Ducts Onl Width of Duct rectan ular duct oni in

Total Ports rectan ular duct onl

E uivalent Diameter = 2LW l+W

Traverse Point Locations

Traverse Point of Duct

Distance from Inside Duct

Wall in Distance from Outside of

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

CEM 3 Point(Long Maasurmont Linos Stratificaton Point Locations

1 0167

2 050

3 0833 tvote it stacK aia lt ~z mcn use crH Memoo ~H

(Sample port upstream of pitot port) Note If stack dia gt24 then adjust traverse point to 1 inch from wall

If stack dia lt24 then adjust traverse point to 05 inch from wall

T r

v t ec r lt 5 ce t

P c o r i

Traverse Point Location Percent ofStack -Circular Num er o raverse Points

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

3 75 29G 19-4 IdG 118 q 933 70A 32i ~_6 177 5 RSd G77 ]4_ 25 6 9G s0o t~sa iSG 7 ~~~ ~ i7 t 644 ~ - -- - ~ - p6R Si4 75 ~ - ~ns xz3 10 974 ti ft2

Flow Disturbances

U stream - A ft

Downstream - B ft (~ S

U stream - A duct diameters ~ Downstream - B duct diameters ~` ~

Diagram of Stack

Duct Diameters Upstream from Flow Disturbance (Distance A)

05 10 t5 2A 25 50

40

30

zo

io

Stack Diametergt 24 inches o~wma~o T A

MOaBulliiCM Minimum Number of e sno

Particulate Traverse Points o~~~ma~o

24 (circular) 25 (rcentctan~ular ducts )

20 _ I- ~-

Traverse Points for Velocity ~ 6

12

8 (circular) 9 (rcentcinrqular) (DisWrbance =Bend Expansion Contraction etc)

SL ck OLD w EquNalunl Dk = 12 - 24 Yxhns

0 2

T

a v l e ~ r i s cent i

P~ of i

3 4 5 6 7 8 9 10

Duct Diameters Downstream from Flow Disturbance (Distance B)

Traverse Point Location Percent of Stack ~RecWn ular Number of Traverse Points

2 3 4 5 G 7 8 9 10 Ii 12 1 250 I67 I25 100 N3 7l 63 5G SA 45 42 2 750 X00 37S 3UQ 250 2t4 I INS IC7 ISO 136 12iS 3 X33 625 500 417 357 313 278 250 27 20R 4 875 7pn 583 SO0 A38 389 350 31amp 292 5 7n ~) 75A G43 5G3 SO0 450 409 375 fi X17 iR~~ 6$8 6tt SiA SQO 458 7 `L 9 2SI3 722 G50 591 542

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

CHEMOURS - FAYETTEVILLE NCINPUTS FOR HFPO DIMER ACID CALCULATIONS

E2 STACK

Test DataRun number 1 2 3Location E2 Stack E2 Stack E2 StackDate 120419 120519 120519Time period 1416-1556 0817-0959 1025-1207Operator JVBBKS JVKS JVBB

Inputs For CalcsSq rt delta P 049854 046742 052373Delta H 16579 14658 18342Stack temp (degF) 663 512 590Meter temp (degF) 616 516 658Sample volume (act) 68630 63724 71248Barometric press (inHg) 2970 3007 3007Volume H2O imp (ml) 70 220 80Weight change sil gel (g) 133 116 156 CO2 02 02 02

O2 209 208 208

N2 789 790 790Area of stack (sqft) 1760 1760 1760Sample time (min) 960 960 960Static pressure (inH2O) 010 030 036Nozzle dia (in) 0280 0280 0280Meter box cal 09972 09972 09972Cp of pitot tube 084 084 084Traverse points 12 12 12

2222

ISOHINETIC FIELD DATA SHEET client cnemours Stack Conditions wo 15418002018 Assumed Project ID Chemours Moisture ModelSource ID E2 Impinger Voi (ml)

Samp Loc ID STK Silica gel (g) Run NoID 1 CO2 by Vol ~ ~~ Test Method ID M0010 02 by Voi ~~i Date ID NOV2019 Temperature (degF) ~ JC SourceLocation E2 St2ck Meter Temp (F)

EPA Method 0010 - HFPO Diener Acid Page ~ or 2 Meter Box ID ~ n

Actual Meter Box Y Q~ c9 7~ K Factor~~~~ 1~7

Meter Box Dei H ~ Initial Mid-Point Final ~ Probe ID Length P7(f~j ~ Sample Train (ft3)

~~Probe Material Boro Leak Check (in Hg) Z Pitot Thermocouple ID jYJ~$ Pitot leak check good

C5 ` Pitot Coefficient 084 Pitot Inspectlon good Noale ID Method 3 System good

~ - ~+~~~--~~~l~~

~~ Noale Measurements 2 ~ o tg~ a z fsv Temp Check re- i es e os - ~ se ~be~

Sample Date ~1 y ~ ~ Static Press (in HZO) p ( J ~ Avg Noale Dia (in) ~~~ J Meter Box Temp Baro Press (In Hg) Q Area of Stack (ft2) ~ ~ ~p Reference Temp ~Jbull z L Operator ~ Ambient Temp (degF) S ~ Sample Time ~ 6 PassFail (+- 2deg) Fail s Fait

Total Traverse Pts ~ Z J Temp Change Response ~ no e no

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~a~r~ z~ y ~nrraquo~s~~~

~~~~~~~ ~ r~~~ ~~~~~~

~~a~~~~~~~~~~~~~~~ ~~~~~~~r~~r~~~r~~ ~~~~~~ ~~~~~~~~laquo~~~ _ ~~r~~r~~~ ~~~~~~~r~r~~~~~~ ~rsraquo~~~~ ~~~~~~~ bull ~A~ ~ ~~ ~~~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

Avg Defta H Total Volume

~ 1 6 )9 ~ b~63 ~ a ~ Avg Sgrt Del F Comments

~ 2~5 9 ~

Avg Ts t Avg Tm MinMax MinMax Max Max Vac MinMax

~ 25v 6bull S~ X091 ~n i~91~~~ S3 bbullS 6 ~0 EPA Method 0010 from EPA SW-846

2323

ISOHINETIC FIELD DATA SHEET EPA Method 0010 - HFPO Dimer Acid Page I or_ Client Chemours Stack Conditions Meter eox iD 3 ~ K Factor wo ~sa~s002o~a Assumed Actual nnetereox r Q ~g~a ~ ~ 6 7 Project ID cnemours io Moisture -~ ^Meter Box Del H ( g~ 5 Initial Mid-Point Final ModeSource ID E2 Impinger Vol (m~) ~ Probe ID Length (~7d p ~ t-~ ~ Sample Train (ft) o D 1 Samp Loc ID STK Silica gel (g) ~ ~ 1p Probe Material Boro Leak Check (in Hg) Run NoID 2 CO2 by Vol 1r Pitot Thermocouple ID P~ p~ Pitot leak check good

_Lrj

e no s no e no Test Method ID M0010 02 by Vol 2~J ~ -~~) ~ Pitot Coefficient 084 Pitot Inspection good e no s no 1 no Date ID NOV2019 Temperature (degF) Noale ID ~ z~D

---~ Method 3 System good yes no yes no yes no

SourcelLocahon E2 Stack Meter Temp (F) Noale Measurements z $CJ ~ ~Q ~ ~Q Temp Check re- est f Post- est Set Sample Date ~ _ ( f Static Press (in H2O) ~ j ~j ~ Avg Nome Dia (in) ~ ~ ~ Meter Box Temp Jy ~t~ Baro Press (in Hg) Area of Stack (ftz) J ~ ~ Reference Temp ~~ Operator ~~Ambient Temp (degF) vD Sample Time 9b ~ PassFail (+- 2deg) a Fail a~~ Fail

Total Traverse Pts ~~ Temp Change Response i (yea no y no

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

-~ ~ ~ ~~~ii101~1~~~r ~~~~~-1 r~vy cua r r~vy versa n

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

UtGi VUIUIIIe HV I J HV I III MINMBX MINMBX MH M8X V8C MINMBX

~~1~~ s~ ~b s s~ ~o~~~o iocenti~~r s~ 7 ~ SSl bo Comments EPA Method 0010 from EPA SW-846

~~~

2424

ISOHINETIC FIELD DATA SHEET Client Chemours Stack Conditions wo isa~a0020~8 Assumed Project ID Chemours Moisture Z ModeSource ID E2 Impinger Vol (mi) Samp Loc ID STK Silica gel (g) Run NoID 3 CO2 by Vol Z Test Method ID M0010 02 deg by Vol Z ~

c Date ID NOV2019 Temperature (degF) b 5 SourceLocation E2 Stack Meter Temp (F) ~ S

Sample Date ~ ~ S ~ 9 Static Press (In Hz0) i- 3 (oBaro Press (in Hg) ~ ~ 7 Operator )V ~ ~~AmbientTemp(degF)

EPA Method 0010 - HFPO Dimer Acid Page ~ or_ Meter Box ID ~j O MeterBox Y Q qc~ ~~ ~ K Factor 6 -7

l~ Meter Box Del H ~ ~ ~ 1 S Initial Mid-Point Finai Probe ID Length `~~j~R ~~ Sample Train (ft) Probe Material Boro Leak Check (in Hg) Pitot Thermocouple ID ~Q~j Pitot leak check good Pitot Coefficient 084 Pitot Inspection good Noale ID (~ Method 3 System good

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

Noale Measurements ~ -~ (~ ~ ~ ~Q Temp Check ~f se t ~e os - eS e Avg Noaie Dia (in) 2 A p ~ Meter Box Temp

Area of Stack (ft2) ( 7 (~ Reference Temp Sample Time J PassFail (+- 2deg) Pass Fail Pass Fail Total Traverse Pts ~ 2 ~ Temp Change Response 5 yes ra yes no

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

Avg Delta P ~ Avg Delta H~

2 1 ~6 `i Avg Sgrt Delta F~ Avg Sgrt Del H

5~~7~~ I3~15~

Total Volume Av Ts J Av Tm 1 MiNMax MinMax Max Max Vac MinMau 9 9

5K95 b5 Ss3 v cosi~2 ia~ r26 ~O ~5 SIf~65 EPA Method 0010 from EPA SW-846

~ 2525

SAMPLE RECOVERY FIELD DATA EPA Method 0010 - HFPO Dimer Acid

Client LocationPlant

Chemours Fayetteville NC

WO Source ampLocation

15418002018 E2 Stack

Run No 1 Sample Date ~~ ~ Recovery Date ~ ~ ` f

Sample ID Chemours - E2 - STK - 1 - M0010 - Analyst V ~- Filter Number ~~

Impin er 1 2 3 4 5 6 7 ImpTotal 8 Total

Contents Empty HPLC H2O HPLC H2O ` Silica Gel

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Initial ~ goo goo ~ v0~ soo

Gain i ~ ~ 2 -~ ~ ~~~

Impinger Color ~~n Labeled (

Silica Gel Condition Sealed

Run No 2 Sample Date ~ `j ~ Recovery Date ~ 2 ~j

Sample ID Chemours - E2 - STK - 2 - M0010 - Analyst G Filter Number

Contents Empty HPLC H2O HPLC H2O Silica Gel

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Initial (~ ioo goo ~ ~ soo

Gain )Co ~ Z `~ ~~ ~ lv

Impinger Color ~~ Labeled

Silica Gel Condition ~~3 p~ Sealed

QRun No 3 Sample Date (Z `j Recovery Date Z ~ ~

Sample ID Chemours - E2 - STK - 3 - M0010 - Analyst K$ Filter Number

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

Gain I 3 ~ 2- ~ ~~ ~ Impinger Color ~ ~~C_r Labeled ~1

Silica Gel Condition 6~ ~ Sealed ~

Check COC for Sample IDs of Media Blanks

2626

Source Gas Analysis Data Sheet -Modified Method 33A

Client ~~ ~1~`-~ Analyst ~l

LocationPlant C4~~ ~~~~ V~+ ~~ t~ Date f Z ft ` ) ~

Source f-- Z- Analyzer Make ampModel ~ ~emdash ~~ ~~ ~ U

WO Number

Calibration

Calibration Gas Calibration Gas Analyzer Analyzer Analysis Value Value Response Response Number Span O~ (deglol COQ (1 O~ (dego) COQ ()

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

Analyzer Analyzer Run Response Response

Number Analysis Time O~ () COQ (1

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

Number Analysis Time O () CO (

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

Report alI values to the nearest 01 percent

2727

Determination of Stack Gas Velocity -Method 2 Client Operetor ~ Pitot Coefi (Cp)C~

LocationPlant Date ~ 2-~ ~9 Stack Area ftZ(As)~

Source WO Number Pitot Tube7hermo ID

Run Number

Tlme

Barometric Press In Hg (Pb)

Static Press In H2O (Pstatic)

Source Moisture (BWS)

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

CyCIOnIC FIOW Determination Traverse Location

Leak Chack good 7 YIN

Leak Check good YIN

Leak Check good 7 Y N

Delta P at 0deg

Angle yeilding zero

Detta P Port Point Defla P

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

Avg Angle Avg Delta P 8 Temp

avg e~aP Average gas stream velocity ftlsec

Vol flow rate ~ actual conditions wacfmin

Vol flow rate at standard conditions dscfmin

y

4

MWd = (032Qz~+~044~pZ~+~028~100-~~QZ+Q2~~~ MWd =Dry molecular weight source gas Ibllb-mole

MWs = ~FMVd ~1- ~BW5100~~~+ ~18 ~BW51100~~ MWs =Wet molecular weight source gas IbIb-mole

Tsa = Ts+ 460 Tsa =Source Temperature absolute(oR) Ps =Absolute stack static pressure inches Hg

Pa = Pb+ (Pstntid136~ Vs =Average gas stream vebcity fUsec

Vs = 8549 Cpavg DeltaP Tsa Ps MWs Qs(act) =Volumetric flow rate of wet stack gas at actual wacflmin

Qs(act~m 80 Vs As Qs(std) = Volumetric fbw rate of dry stack gas at standard conditions dscUmin

cas(~rd) _ ~ ~sa bull (~ mdash (ewsi i oo)) (PslTsa )- o(apt) Note Micromanometer (s required if (A) The average Della P readings are less than 005 Inches of water

(B) For Vaverses of 12 or more po(nts more than 10 of the Defla P readings are bebw 005 Inches of water (C) For traverses of less than 12 points more than one Delta P readings is bebw 005 Inches of water

~-~~ _ice=-

method2xls

The Chemours CompanyFayetteville15418002018

2828

29

ANALYTICAL REPORTJob Number 140-17552-1

Job Description E2 Stack - M0010

Contract Number LBIO-67048

ForChemours Company FC LLC The

co AECOMSabre Building Suite 300

4051 Ogletown RoadNewark DE 19713

Attention Michael Aucoin

_____________________________________________

Approved for releaseCourtney M AdkinsProject Manager II12172019 142 PM

Courtney M Adkins Project Manager II5815 Middlebrook Pike Knoxville TN 37921

(865)291-3000 courtneyadkinstestamericainccom

12172019

This report may not be reproduced except in full and with written approval from the laboratory For questions please contact the Project Manager atthe e-mail address or telephone number listed on this page

The test results in this report relate only to the samples as received by the laboratory and will meet all requirements of the methodology with anyexceptions noted This report shall not be reproduced except in full without the express written approval of the laboratory All questions should bedirected to the Eurofins TestAmerica Project Manager

This report has been electronically signed and authorized by the signatory Electronic signature is intended to be the legally binding equivalent of atraditionally handwritten signature

Eurofins TestAmerica Knoxville

5815 Middlebrook Pike Knoxville TN 37921

Tel (865) 291-3000 Fax (865) 584-4315 wwwtestamericainccom

12172019Page 1 of 2443030

Table of ContentsCover Title Page 1

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Client Sample Results 10

Default Detection Limits 13

Surrogate Summary 14

QC Sample Results 15

Chronicle 17

Certification Summary 22

Manual Integration Summary 24

Organic Sample Data 26

LCMS 26

8321A_HFPO_Du 268321A_HFPO_Du QC Summary 278321A_HFPO_Du Sample Data 31Standards Data 43

8321A_HFPO_Du ICAL Data 438321A_HFPO_Du CCAL Data 66

Raw QC Data 728321A_HFPO_Du Blank Data 728321A_HFPO_Du LCSLCSD Data 76

8321A_HFPO_Du Run Logs 84

12172019Page 2 of 2443131

Table of Contents8321A_HFPO_Du Prep Data 86

Method DV-LC-0012 90Method DV-LC-0012 QC Summary 91Method DV-LC-0012 Sample Data 99Standards Data 135

Method DV-LC-0012 ICAL Data 135Method DV-LC-0012 CCAL Data 159

Raw QC Data 180Method DV-LC-0012 Tune Data 180Method DV-LC-0012 Blank Data 190Method DV-LC-0012 LCSLCSD Data 202

Method DV-LC-0012 Run Logs 223Method DV-LC-0012 Prep Data 227

Shipping and Receiving Documents 237

Client Chain of Custody 238

12172019Page 3 of 2443232

DefinitionsGlossaryJob ID 140-17552-1Client Chemours Company FC LLC The

ProjectSite E2 Stack - M0010

Qualifiers

LCMSQualifier Description

J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value

Qualifier

GlossaryThese commonly used abbreviations may or may not be present in this report

curren Listed under the D column to designate that the result is reported on a dry weight basis

Abbreviation

R Percent Recovery

CFL Contains Free Liquid

CNF Contains No Free Liquid

DER Duplicate Error Ratio (normalized absolute difference)

Dil Fac Dilution Factor

DL Detection Limit (DoDDOE)

DL RA RE IN Indicates a Dilution Re-analysis Re-extraction or additional Initial metalsanion analysis of the sample

DLC Decision Level Concentration (Radiochemistry)

EDL Estimated Detection Limit (Dioxin)

LOD Limit of Detection (DoDDOE)

LOQ Limit of Quantitation (DoDDOE)

MDA Minimum Detectable Activity (Radiochemistry)

MDC Minimum Detectable Concentration (Radiochemistry)

MDL Method Detection Limit

ML Minimum Level (Dioxin)

NC Not Calculated

ND Not Detected at the reporting limit (or MDL or EDL if shown)

PQL Practical Quantitation Limit

QC Quality Control

RER Relative Error Ratio (Radiochemistry)

RL Reporting Limit or Requested Limit (Radiochemistry)

RPD Relative Percent Difference a measure of the relative difference between two points

TEF Toxicity Equivalent Factor (Dioxin)

TEQ Toxicity Equivalent Quotient (Dioxin)

12172019Page 4 of 2443333

Method SummaryJob ID 140-17552-1Client Chemours Company FC LLC The

Method Method Description LaboratoryProtocol

SW8468321A HFPO-DA TAL DEN

SW8468321A PFOA and PFOS TAL DEN

TAL SOPNone Leaching Procedure TAL DEN

TAL SOPNone Leaching Procedure for Condensate TAL DEN

TAL SOPNone Leaching Procedure for XAD TAL DEN

Protocol References

SW846 = Test Methods For Evaluating Solid Waste PhysicalChemical Methods Third Edition November 1986 And Its Updates

TAL SOP = TestAmerica Laboratories Standard Operating Procedure

Laboratory References

TAL DEN = Eurofins TestAmerica Denver 4955 Yarrow Street Arvada CO 80002 TEL (303)736-0100

12172019Page 5 of 2443434

Sample SummaryJob ID 140-17552-1Client Chemours Company FC LLC The

Lab Sample ID Client Sample ID ReceivedCollectedMatrix Asset ID

140-17552-1 GF-25012502 R1 M0010 E2 STACK FH Air 120419 0000 120719 0800

140-17552-2 GF-250325042506 R1 M0010 E2 STACK BH Air 120419 0000 120719 0800

140-17552-3 GF-2505 R1 M0010 E2 STACK IMPINGER 12amp3

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

BREAKTHROUGH XAD-2 RESIN TUBE

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Job Narrative140-17552-1

Sample Receipt

The samples were received on December 7 2019 at 800 AM in good condition and properly preserved The temperatures of the 2 coolers at receipt time were 09ordm C and 14ordm C

Quality Control and Data Interpretation

Unless otherwise noted all holding times and QC criteria were met and the test results shown in this report meet all applicable NELAC requirements

Method 0010Method 3542 Sampling Train Preparation

Train fractions were extracted and prepared for analysis in TestAmericarsquos Knoxville laboratory Extracts and condensate samples were forwarded to the Denver laboratory for HFPO-DA analysis All results are reported in ldquoTotal ugrdquo per sample

LCMS

No analytical or quality issues were noted other than those described in the DefinitionsGlossary page

Organic Prep

12172019Page 7 of 2443636

QC Association SummaryJob ID 140-17552-1Client Chemours Company FC LLC The

LCMS

Analysis Batch 464589

Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch

Air 8321ADLCK 280-46458913 Lab Control Sample TotalNA

Prep Batch 479940

Air None140-17552-2 GF-250325042506 R1 M0010 E2 STACK BH TotalNA

Air None140-17552-4 GF-2507 R1 M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBETotalNA

Air NoneMB 280-4799401-A Method Blank TotalNA

Air NoneLCS 280-4799402-A Lab Control Sample TotalNA

Air NoneLCSD 280-4799403-A Lab Control Sample Dup TotalNA

Prep Batch 480027

Air None140-17552-1 GF-25012502 R1 M0010 E2 STACK FH TotalNA

Prep Batch 480114

Air None140-17552-3 GF-2505 R1 M0010 E2 STACK IMPINGER 12amp3 CONDTotalNA

Air 8321A 480027140-17552-1 GF-25012502 R1 M0010 E2 STACK FH TotalNA

Air 8321A 480027MB 280-4800271-A Method Blank TotalNA

Air 8321A 480027LCS 280-4800272-A Lab Control Sample TotalNA

Air 8321A 480027LCSD 280-4800273-A Lab Control Sample Dup TotalNA

Air 8321A 480114140-17552-3 GF-2505 R1 M0010 E2 STACK IMPINGER 12amp3 CONDTotalNA

12172019Page 8 of 2443737

LCMS

Air 8321A 479940140-17552-2 GF-250325042506 R1 M0010 E2 STACK BH TotalNA

Air 8321A 479940140-17552-4 GF-2507 R1 M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBETotalNA

12172019Page 9 of 2443838

Client Sample ResultsJob ID 140-17552-1Client Chemours Company FC LLC The

Lab Sample ID 140-17552-1Client Sample ID GF-25012502 R1 M0010 E2 STACK FHMatrix AirDate Collected 120419 0000

Date Received 120719 0800Sample Container Air Train

Method 8321A - PFOA and PFOSRL MDL

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

Surrogate Dil FacAnalyzedPreparedQualifier LimitsRecovery

Lab Sample ID 140-17552-2Client Sample ID GF-250325042506 R1 M0010 E2 STACK BHMatrix AirDate Collected 120419 0000

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

Lab Sample ID 140-17552-3Client Sample ID GF-2505 R1 M0010 E2 STACK IMPINGER 12amp3 COND

Matrix AirDate Collected 120419 0000Date Received 120719 0800Sample Container Air Train

Method 8321A - HFPO-DARL MDL

HFPO-DA ND 0201 00102 ugSample 121019 1115 121219 1044 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

Lab Sample ID 140-17552-4Client Sample ID GF-2507 R1 M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBE

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

HFPO-DA 0103 J 0200 00400 ugSample 120919 1420 121619 1059 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Default Detection LimitsClient Chemours Company FC LLC The Job ID 140-17552-1ProjectSite E2 Stack - M0010

Method 8321A - HFPO-DAPrep None

000250HFPO-DA ugSample

Analyte UnitsMDLRL

000128

Method 8321A - PFOA and PFOSPrep None

Analyte UnitsMDLRL

000270

0100HFPO-DA ugSample00200

12172019Page 13 of 2444242

Job Description E2 Field QC - M0010

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

ProjectSite E2 Field QC - M0010

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

140-17554-1 A-66226623 QC M0010 E2 STACK FH BT Air 120519 0000 120719 0800

140-17554-2 A-662466256627 QC M0010 E2 STACK BH BT Air 120519 0000 120719 0800

140-17554-3 A-6626 QC M0010 E2 STACK IMPINGERS 12amp3

COND BT

Air 120519 0000 120719 0800

140-17554-4 A-6628 QC M0010 E2 STACK BREAKTHROUGH

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

140-17554-5 A-6629 QC M0010 E2 STACK DI WATER RB Air 120519 0000 120719 0800

140-17554-6 A-6630 QC M0010 E2 STACK MEOH WITH 5

NH4OH RB

Air 120519 0000 120719 0800

140-17554-7 A-6631 QC M0010 E2 STACK COMBINED

GLASSWARE RINSES (MEOH5 NH4OH) PB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Air None140-17554-2 A-662466256627 QC M0010 E2 STACK BH BT TotalNA

Air None140-17554-4 A-6628 QC M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBE BTTotalNA

Air None140-17554-6 A-6630 QC M0010 E2 STACK MEOH WITH 5 NH4OH RBTotalNA

Air None140-17554-7 A-6631 QC M0010 E2 STACK COMBINED GLASSWARE RINSES (MEOH5 NH4OH) PBTotalNA

Prep Batch 480027

Air None140-17554-1 A-66226623 QC M0010 E2 STACK FH BT TotalNA

Prep Batch 480114

Air None140-17554-3 A-6626 QC M0010 E2 STACK IMPINGERS 12amp3 COND BTTotalNA

Air None140-17554-5 A-6629 QC M0010 E2 STACK DI WATER RB TotalNA

Air 8321A 480027140-17554-1 A-66226623 QC M0010 E2 STACK FH BT TotalNA

Air 8321A 480114140-17554-3 A-6626 QC M0010 E2 STACK IMPINGERS 12amp3 COND BTTotalNA

Air 8321A 480114140-17554-5 A-6629 QC M0010 E2 STACK DI WATER RB TotalNA

Air 8321A 479940140-17554-2 A-662466256627 QC M0010 E2 STACK BH BT TotalNA

Air 8321A 479940140-17554-4 A-6628 QC M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBE BTTotalNA

Air 8321A 479940140-17554-6 A-6630 QC M0010 E2 STACK MEOH WITH 5 NH4OH RBTotalNA

Air 8321A 479940140-17554-7 A-6631 QC M0010 E2 STACK COMBINED GLASSWARE RINSES (MEOH5 NH4OH) PBTotalNA

12172019Page 8 of 2195050

Lab Sample ID 140-17554-1Client Sample ID A-66226623 QC M0010 E2 STACK FH BTMatrix AirDate Collected 120519 0000

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

Lab Sample ID 140-17554-2Client Sample ID A-662466256627 QC M0010 E2 STACK BH BT

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

Lab Sample ID 140-17554-3Client Sample ID A-6626 QC M0010 E2 STACK IMPINGERS 12amp3 COND BT

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

Lab Sample ID 140-17554-4Client Sample ID A-6628 QC M0010 E2 STACK BREAKTHROUGH XAD-2 RESIN TUBE BT

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

Lab Sample ID 140-17554-5Client Sample ID A-6629 QC M0010 E2 STACK DI WATER RBMatrix AirDate Collected 120519 0000

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

Lab Sample ID 140-17554-6Client Sample ID A-6630 QC M0010 E2 STACK MEOH WITH 5 NH4OH RB

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

Lab Sample ID 140-17554-7Client Sample ID A-6631 QC M0010 E2 STACK COMBINED GLASSWARE RINSES (MEOH5 NH4OH) PB

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Default Detection LimitsClient Chemours Company FC LLC The Job ID 140-17554-1ProjectSite E2 Field QC - M0010

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

12302019238 PM Dec E2 Stack

SAMPLE CALCULATIONS FORHFPO DIMER ACID (METHOD 0010)

Client Chemours Plant Fayetteville NCTest Number Run 3 Test Date 120519Test Location E2 Stack Test Period 1025-1207

1 HFPO Dimer Acid concentration lbsdscf

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

W = Weight of HFPO Dimer Acid collected in sample in ug

Conc1 = Division Stack HFPO Dimer Acid concentration lbsdscf

22046x10-9 = Conversion factor from ug to lbs

2 HFPO Dimer Acid concentration ugdscm

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

Conc2 = Division Stack HFPO Dimer Acid concentration ugdscm

002832 = Conversion factor from cubic feet to cubic meters

5555

3 HFPO Dimer Acid mass emission rate lbshr

MR1(Outlet) = Conc1 x Qs(std) x 60 minhr

MR1(Outlet) = 853E-11 x 3101 x 60

MR1(Outlet) = 159E-05

Where

MR1(Outlet) = Division Stack HFPO Dimer Acid mass emission rate lbshr

4 HFPO Dimer Acid mass emission rate gsec

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

MR2(Outlet) = Division Stack HFPO Dimer Acid mass emission rate gsec

4536 = Conversion factor from pounds to grams

3600 = Conversion factor from hours to seconds

5656

EXAMPLE CALCULATIONS FORVOLUMETRIC FLOW AND MOISTURE AND ISOKINETICS

Client Chemours Facility Fayetteville NCTest Number Run 3 Test Date 120519Test Location E2 Stack Test Period 1025-1207

1 Volume of dry gas sampled at standard conditions (68 deg F 2992 in Hg) dscf

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vm(std) = Volume of gas sample measured by the dry gas metercorrected to standard conditions dscf

Vm = Volume of gas sample measured by the dry gas meterat meter conditions dcf

Pb = Barometric Pressure in Hgdelt H = Average pressure drop across the orifice meter in H2O

Tm = Average dry gas meter temperature deg FY = Dry gas meter calibration factor

1764 = Factor that includes ratio of standard temperature (528 deg R)to standard pressure (2992 in Hg) deg Rin Hg

136 = Specific gravity of mercury

2 Volume of water vapor in the gas sample corrected to standard conditions scf

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

Vw(std) = Volume of water vapor in the gas sample corrected tostandard conditions scf

Vwc = Volume of liquid condensed in impingers mlWwsg = Weight of water vapor collected in silica gel g

004707 = Factor which includes the density of water(0002201 lbml) the molecular weight of water(180 lblb-mole) the ideal gas constant

2185 (in Hg) (ft3)lb-mole)(deg R) absolute

temperature at standard conditions (528 deg R) absolute

pressure at standard conditions (2992 in Hg) ft3ml

004715 = Factor which includes the molecular weight of water(180 lblb-mole) the ideal gas constant

temperature at standard conditions (528 deg R) absolutepressure at standard conditions (2992 in Hg) and

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

bws = Proportion of water vapor by volume in the gasstream dimensionless

4 Mole fraction of dry gas

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

Md = Mole fraction of dry gas dimensionless

5 Dry molecular weight of gas stream lblb-mole

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

MWd = Dry molecular weight lblb-mole CO2 = Percent carbon dioxide by volume dry basis

O2 = Percent oxygen by volume dry basis N2 = Percent nitrogen by volume dry basis

CO = Percent carbon monoxide by volume dry basis0440 = Molecular weight of carbon dioxide divided by 1000320 = Molecular weight of oxygen divided by 1000280 = Molecular weight of nitrogen or carbon monoxide

divided by 100

6 Actual molecular weight of gas stream (wet basis) lblb-mole

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

MWs = Molecular weight of wet gas lblb-mole18 = Molecular weight of water lblb-mole

5858

7 Average velocity of gas stream at actual conditions ftsec

Ts (avg)

Vs = 8549 x Cp x ((delt p)12)avg x ( ---------------- )12

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Vs = Average gas stream velocity ftsec

(lblb-mole)(in Hg)12

8549 = Pitot tube constant ftsec x ------------------------------------ (deg R)(in H2O)

Cp = Pitot tube coefficient dimensionlessTs = Absolute gas stream temperature deg R = Ts deg F + 460

P(static)Ps = Absolute gas stack pressure in Hg = Pb + --------------

136delt p = Velocity head of stack in H2O

8 Average gas stream volumetric flow rate at actual conditions wacfmin

Qs(act) = 60 x Vs x As

Qs(act) = 60 x 292 x 176 = 3079

Where

Qs(act) = Volumetric flow rate of wet stack gas at actualconditions wacfmin

As = Cross-sectional area of stack ft2

60 = Conversion factor from seconds to minutes

9 Average gas stream dry volumetric flow rate at standard conditions dscfmin

PsQs(std) = 1764 x Md x ----- x Qs(act)

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

Qs(std) = Volumetric flow rate of dry stack gas at standardconditions dscfmin

5959

10 Isokinetic variation calculated from intermediate values percent

17327 x Ts x Vm(std)I = -----------------------------------

Vs x O x Ps x Md x (Dn)2

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

I = Percent of isokinetic samplingO = Total sampling time minutes

Dn = Diameter of nozzle inches17327 = Factor which includes standard temperature (528 deg R)

standard pressure (2992 in Hg) the formula for

calculating area of circle D24 conversion of square

feet to square inches (144) conversion of secondsto minutes (60) and conversion to percent (100)

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

Interference Check 2014xlsO2-Servomex 4900 7172019

Date 12414-12514Analyzer Type Servomex - O2

Model No 4900Serial No 49000-652921Calibration Span 2109 Pollutant 2109 O2 - CC418692

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

NO2 (2378 ppm CC500749) NA NA NA

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

CH4 (4531 ppm SG901795) NA NA NA

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

(a) The larger of the absolute values obtained for the interferent tested with and without the pollutant present was used in summing the interferences

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

ANALYZER RESPONSE OF CALIBRATION

SPAN(a)

TOTAL INTERFERENCE RESPONSE

METHOD SPECIFICATION

INTERFERENT GAS RESPONSE WITH BACKGROUND POLLUTANT ()

INTERFERENT GAS RESPONSE ()

6262

Interference Check 2014xlsCO2-Servomex 4900 7172019

Date 12414-12514Analyzer Type Servomex - CO2

Model No 4900Serial No 49000-652921Calibration Span 1665Pollutant 1665 CO2 - CC418692

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Long Cal Box_30 2-21-19

Calibrator MDW Meter Box Number 30 Ambient Temp 72

Date 21-Feb-19 Wet Test Meter Number P-2952 Temp Reference Source

Dry Gas Meter Number 17485131

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

Vw - Gas Volume passing through the wet test meter 0 - Time of calibration runVd - Gas Volume passing through the dry gas meter Pb - Barometric PressureTw - Temp of gas in the wet test meterTdi - Temp of the inlet gas of the dry gas meterTdo - Temp of the outlet gas of the dry gas meterTd - Average temp of the gas in the dry gas meter

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

1832 1832 1832 1832 1832 18320 001 - Channel Temps must agree with +- 5oF or 3oC

2 - Acceptable Temperature Difference less than 15

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Long Cal and Temperature Cal Datasheet for Standard Dry Gas Meter Console

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

Y - Ratio of accuracy of wet test meter to dry gas meter

∆H - Pressure differential across orifice

30 100 700

TemperaturesWet Test

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Reference Temperature

Select Temperature

oC oF

21232

Average Temperature

Reading

Thermocouple Simulator

(Accuracy +- 1oF)

Temp

Difference 2

()

Temperature Reading from Individual Thermocouple Input 1

Channel Number

19103

Calibration Results

Baro Press in Hg ( Pb)

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

460FTempTest460FTempferenceReDiffTemp

o

oo

6464

Y Factor Calibration Check CalculationMODIFIED METHOD 0010 TEST TRAIN

E2 STACKMETER BOX NO 301242019 + 1252019

Run 1 Run 2 Run 3

MWd = Dry molecular weight source gas lblb-mole032 = Molecular weight of oxygen divided by 100044 = Molecular weight of carbon dioxide divided by 100028 = Molecular weight of nitrogen or carbon monoxide divided by 100

CO2 = Percent carbon dioxide by volume dry basis 02 02 02

O2 = Percent oxygen by volume dry basis 209 208 208

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Source Temperature absolute(oR)Tm = Average dry gas meter temperature deg F 616 516 658

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Ps = Absolute meter pressure inches Hg1360 = Specific gravity of mercury

delta H = Avg pressure drop across the orifice meter during sampling in H2O 166 147 183Pb = Barometric Pressure in Hg 2970 3007 3007

Pm = Pb + (delta H 136)

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = dry gas meter calibration check value dimensionless003 = (2992528)(075)2 (in HgdegR) cfm2

2900 = dry molecular weight of air lblb-moleVm = Volume of gas sample measured by the dry gas meter at meter conditions dcf 68630 63724 71248

Y = Dry gas meter calibration factor (based on full calibration) 09972 09972 09972Delta H = Dry Gas meter orifice calibration coefficient in H2O 18715 18715 18715

avg SQRT Delta H = Avg SQRT press drop across the orifice meter during sampling in H2O 12860 12053 13516O = Total sampling time minutes 96 96 96

Yqa = (O Vm ) SQRT ( 00319 Tma 29 ) ( Delta H Pm MWd ) avg SQRT Delta H

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = Absolute difference between Yqa and Y 128 190 028

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

Pitot Tube Identification Number

Inspection Date 61518 Individual Conducting Inspection

Distance to A Plane (PA) - inches 0436 PASSDistance to B Plane (PB) - inches 0436 PASS

Pitot OD (Dt) - inches 0375105 Dt lt P lt 15 Dt PA must Equal PB

Q1 and Q2 must be lt 10o

B1 or B2 must be lt 5o

Z must be lt 0125 inches

W must be lt 003125 inches

X must be gt 075 inches

Thermocouple meets the Distance Criteria in the adjacent figure

Impact Pressure Opening Plane is above the Nozzle Entry Plane

NO

NA

NO

NA

PASS

Distance between Sample Nozzle and Pitot (X) - inches

YES

PASS

NO YES

NA

0

Angle of B1 from vertical A Tube- degrees (absolute) 0

0

09

Horizontal offset between A and B Tubes (Z) - inches

Vertical offset between A and B Tubes (W) - inches

001

0014

PASSFAIL

Angle of B1 from vertical B Tube- degrees (absolute)

PASS

P-708

KS

Angle of Q1 from vertical A Tube- degrees (absolute)

Angle of Q2 from vertical B Tube- degrees (absolute)

Type S Pitot Tube Inspection Data Form

Are Open Faces Aligned Perpendicular to the Tube Axis

YES NOPASS

If all Criteria PASS Cp is equal to 084

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Impact Pressure Opening Plane

Nozzle Entry Plane

W

B

A

B

A

Z

6666

CERTIFICATE OF ANALYSISGrade of Product EPA Protocol

Part Number E03NI62E15A0224 Reference Number 82-401196512-1Cylinder Number CC112489 Cylinder Volume 1572 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date May 12 2018

Expiration Date May 12 2026

Certification performed in accordance with ldquoEPA Traceability Protocol for Assay and Certification of Gaseous Calibration Standards (May 2012)rdquo document EPA600R-12531 using the assay procedures listed Analytical Methodology does not require correction for analytical interference This cylinder has a total analytical

uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on avolumevolume basis unless otherwise noted

Do Not Use This Cylinder below 100 psig ie 07 megapascals

ANALYTICAL RESULTSComponent Requested Actual Protocol Total Relative Assay

Concentration Concentration Method Uncertainty Dates

CARBON DIOXIDE 1700 1705 G1 +- 07 NIST Traceable 05122018OXYGEN 2100 2098 G1 +- 05 NIST Traceable 05122018NITROGEN Balance -

CALIBRATION STANDARDSType Lot ID Cylinder No Concentration Uncertainty Expiration Date

NTRM 13060731 CC413777 16939 CARBON DIOXIDENITROGEN +- 06 May 08 2019NTRM 09061420 CC273671 2253 OXYGENNITROGEN +- 04 Mar 08 2019

ANALYTICAL EQUIPMENTInstrumentMakeModel Analytical Principle Last Multipoint Calibration

Horiba VIA 510-CO2-19GYCXEG NDIR Apr 19 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Apr 19 2018

Triad Data Available Upon Request

Airgas Specialty GasesAirgas USA LLC600 Union Landing RoadCinnaminson NJ 08077-0000Airgascom

Signature on file

Approved for Release Page 1 of 82-401196512-16767

Part Number E03NI79E15A00E4 Reference Number 82-401356855-1Cylinder Number ALM009044 Cylinder Volume 1505 CFLaboratory 124 - Riverton (SAP) - NJ Cylinder Pressure 2015 PSIGPGVP Number B52018 Valve Outlet 590Gas Code CO2O2BALN Certification Date Nov 26 2018

Expiration Date Nov 26 2026

uncertainty as stated below with a confidence level of 95 There are no significant impurities which affect the use of this calibration mixture All concentrations are on amolemole basis unless otherwise noted

NTRM 09060236 CC263114 9961 OXYGENNITROGEN +- 03 Nov 05 2024

Horiba VIA 510-CO2-19GYCXEG NDIR Nov 06 2018Horiba MPA 510-O2-7TWMJ041 Paramagnetic Nov 07 2018

Signature on file

69

The following WESTON employees participated in this project

Paul Meeter Senior Project Manager

Johnnie Vitello Team Member

Brandon Berger Team Member

Kyle Schweitzer Team Member

Chris Hartsky Team Member

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
  - - FIELD DATA CALCS
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        Interference Check 2014pdf
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

THE CHEMOURS COMPANY

TEST DATES 4-5 December 2019

Weston Solutions Inc (WESTONreg) is a commercial laboratory operating within full accreditation of the Louisiana Environmental Laboratory Accreditation Program under Certificate Number 03024 The qualifications to provide defensible quality data as a certified commercial environmental testing firm as Agency Interest No 30815 was granted by the Louisiana Department of Environmental Quality under the Louisiana Administrative Code of LAC 331 Chapter 45 et al

I certify that I have personally examined and am familiar with the information contained herein Based on my information and belief formed after reasonable inquiry the statements and information in the document are true accurate and complete

Paul M Meeter Weston Solutions Inc

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

31 E-2 5

41 E2 STACK 6

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

3 16

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

TABLE OF CONTENTS

Section Page

1 INTRODUCTION1

31 E-2 5

41 E2 STACK 6

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

3 16

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

LIST OF FIGURES

Title Page

LIST OF TABLES

Title Page

3 16

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

LIST OF TABLES

Title Page

3 16

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

1 INTRODUCTION

12 TEST OBJECTIVES

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Section 6

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Acid

(HFPO-DA)

Carbon Dioxide

tests

with M-0010 tests

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Section 6

compounds

E2 Stack gsec lbhr

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

31 E-2

dissipation

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

41 E2 STACK

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

4

125

FIGURE 4-1E2 STACK

TRAVERSEPOINT

NUMBER

123456

18

7

WALL (INCHES)

12 585 3812 5815 38

17

E2BLDG

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

program

testing

sampling procedures

52 STACK PARAMETERS

521 EPA Method 0010

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

6

9

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

and HFPO Dimer Acid

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

impingers

HPLCMSMS

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

8

3

13

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

53 GAS COMPOSITION

sampling system

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

the test location

calculations

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

12302019 237 PM

16

Dec E2 Stack

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

12302019 237 PM

17

Dec E2 Stack

TEST DATA

Time period 1416-1556 0817-0959 1025-1207

TABLE 6-1 (cont)

E2 STACK

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

18

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

1200

1400 1500 1600RUN 1 - 1416-1556

800 900 1000 1100RUN 2 - 0817-0959 RUN 3 - 1025-1207

1919

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

20

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Port De th in = D

Monorail Len th

Port in

~ `~a~ ~

2 ~~ ~ ~ 7~~ ~ti ~~~b

3 Lbdquo~~ ~j ~ ~ ~ ( ~

4 i~~ 1 ~ ~~ ~ i--~ `~ 5 ~~~ ~7 ~ ~ ~~ cT ~ ~ ~ ~

7

8

9

10

11

12

1 0167

2 050

T r

v t ec r lt 5 ce t

P c o r i

1 2 3 A 5 G 7 K 9 10 11 12 14Cgt 67 44 32 26 21

2 Hi4 ~ G 105 ~ G9

Flow Disturbances

U stream - A ft

Diagram of Stack

05 10 t5 2A 25 50

40

30

zo

io

20 _ I- ~-

12

0 2

T

P~ of i

3 4 5 6 7 8 9 10

938 ata 7yA G82 625 9 944 850 773 708 2121

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

12302019 236 PM Dec E2 Stack

E2 STACK

O2 209 208 208

2222

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

~ - ~+~~~--~~~l~~

bull

-~I~-~~~~~~~~~ I ~~~~~rl~~ir~~~~~~~~-~-

~~~~~~~ ~ r~~~ ~~~~~~

-~-~~ I A ~ ~~[wi~~~~~~~-

vg eta

a49i Avn Snrt Melt

y9fs5

~ 2~5 9 ~

2323

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

_Lrj

~~~~ i ~ ~ ~ ~~~~~~~~-~

~~~~~~~~~ ~ ~~~~~ ~ ~~~i~~~~~~ti~~~

Avg Sgrt Delta

~ Avg Sgrt Del

~Ib~` ~ `Lo~3

~~~

2424

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

1 A ~I ~

r~r~~ ~ ~~~ ~~-~~ ~

0

~~~~ I

~~~

~i1~7C~~~ i R ~~~7~

~

~1~~- r

-~~-~I A I ~ALLI~~_~~~~~~~~-

-~-~r~~~~~~~~Sf~~~~- V ~~[~l~~~~~- ~~

-~-~ Ir~l~l-~~ ~ i ~~~~~-

-~-~~l~~~~~~~i7l~~ ~ ~ 1~[i~~~~~-

5~~7~~ I3~15~

~ 2525

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

15418002018 E2 Stack

Final ~ ~~ C~ ~ F ~~ ~~ 20 3 l~~

Gain i ~ ~ 2 -~ ~ ~~~

Final ~ ~ ~ rp (~~ ~ ~Z ~~ ( (o

Gain )Co ~ Z `~ ~~ ~ lv

Final ~ I ~ ~ C7 2 Z Z(~~ ~ Cs~

Initial ~ 100 100 v ~~~ 300

2626

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

WO Number

Calibration

1 Zero ~ ~ ~ ~ `-

2 Mid ~ ~ ~ 7 J~ `1 ~~ ~~_1~~ lt ~mdash ~~~ --~~

_ Average ___ __ _

~~~m ~1~~ IZ~S--t~

1 i E~ ~ ~ ~- r -~ mdash~-- ~~

2 ~ _1 ~ i ~ Q ~t ~ ~

Average _

1

2

3

Average

Snan Cvlinriar Itl

Mid ~ ( ~lfl t ir- `~ ~ i ~i -~( --

Hi h

-- ---------------- i lt ~-- ~- I ~ ~ ~1 C~

2727

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Run Number

Tlme

02 COQ

~ s (y mdash ~~ d

~

2 ~ 7 e ~ ~

j--~

Leak Check good YIN

Delta P at 0deg

Angle yeilding zero

Source

Temp Fdegs Deka P

Source

Temp FdegTs Delta P

Source Temp Fdeg

s

~ z ~ ~ 2

0 3 ~ ~ U q

~ 4 5

b U

O

~ 6 6 t L

CJ ~ o b S

y

4

~-~~ _ice=-

method2xls

2828

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

29

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

_____________________________________________

12172019

12172019Page 1 of 2443030

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 17

LCMS 26

12172019Page 2 of 2443131

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

12172019Page 3 of 2443232

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2443333

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Protocol References

12172019Page 5 of 2443434

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

COND

Air 120419 0000 120719 0800

140-17552-4 GF-2507 R1 M0010 E2 STACK

Air 120419 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-8 GF-2514 R2 M0010 E2 STACK

Air 120519 0000 120719 0800

COND

Air 120519 0000 120719 0800

140-17552-12 GF-2521 R3 M0010 E2 STACK

Air 120519 0000 120719 0800

12172019Page 6 of 2443535

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2443636

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2443737

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

LCMS

12172019Page 9 of 2443838

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

HFPO-DA 793 0100 00108 ugSample 120919 1420 121219 1018 1

13C3 HFPO-DA 120 50 - 200 120919 1420 121219 1018 1

HFPO-DA 755 0200 00400 ugSample 120919 1420 121619 1039 1

13C3 HFPO-DA 84 50 - 200 120919 1420 121619 1039 1

13C3 HFPO-DA 108 50 - 200 121019 1115 121219 1044 1

HFPO-DA 0267 0200 00400 ugSample 120919 1420 121619 1042 1

13C3 HFPO-DA 100 50 - 200 120919 1420 121619 1042 1

HFPO-DA 0556 0150 00162 ugSample 120919 1420 121219 1021 1

12172019Page 10 of 2443939

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

13C3 HFPO-DA 133 50 - 200 120919 1420 121219 1021 1

HFPO-DA 136 0325 00650 ugSample 120919 1420 121619 1046 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121619 1046 1

13C3 HFPO-DA 110 50 - 200 121019 1115 121219 1047 1

13C3 HFPO-DA 102 50 - 200 120919 1420 121619 1049 1

HFPO-DA 202 0150 00162 ugSample 120919 1420 121219 1024 1

13C3 HFPO-DA 127 50 - 200 120919 1420 121219 1024 1

12172019Page 11 of 2444040

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

HFPO-DA 0664 0325 00650 ugSample 120919 1420 121619 1052 1

13C3 HFPO-DA 131 50 - 200 120919 1420 121619 1052 1

13C3 HFPO-DA 116 50 - 200 121019 1115 121219 1050 1

13C3 HFPO-DA 101 50 - 200 120919 1420 121619 1059 1

12172019Page 12 of 2444141

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 13 of 2444242

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

_____________________________________________

12172019

12172019Page 1 of 2194343

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Data Summaries 4

Definitions 4

Method Summary 5

Sample Summary 6

Case Narrative 7

QC Association 8

Chronicle 15

LCMS 23

12172019Page 2 of 2194444

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

12172019Page 3 of 2194545

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Qualifiers

Qualifier

Abbreviation

R Percent Recovery

NC Not Calculated

QC Quality Control

12172019Page 4 of 2194646

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Protocol References

12172019Page 5 of 2194747

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

COND BT

Air 120519 0000 120719 0800

XAD-2 RESIN TUBE BT

Air 120519 0000 120719 0800

NH4OH RB

Air 120519 0000 120719 0800

12172019Page 6 of 2194848

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Sample Receipt

LCMS

Organic Prep

12172019Page 7 of 2194949

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

LCMS

Prep Batch 479940

Prep Batch 480027

Prep Batch 480114

12172019Page 8 of 2195050

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

HFPO-DA 00437 00250 000270 ugSample 120919 1420 121219 1027 1

13C3 HFPO-DA 128 50 - 200 120919 1420 121219 1027 1

HFPO-DA 0264 0200 00400 ugSample 120919 1420 121619 1102 1

13C3 HFPO-DA 98 50 - 200 120919 1420 121619 1102 1

13C3 HFPO-DA 124 50 - 200 121019 1115 121219 1053 1

13C3 HFPO-DA 111 50 - 200 120919 1420 121619 1105 1

12172019Page 9 of 2195151

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

13C3 HFPO-DA 139 50 - 200 121019 1115 121219 1057 1

13C3 HFPO-DA 147 50 - 200 120919 1420 121619 1108 1

13C3 HFPO-DA 143 50 - 200 120919 1420 121619 1112 1

12172019Page 10 of 2195252

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Analyte UnitsMDLRL

000128

Analyte UnitsMDLRL

000270

12172019Page 11 of 2195353

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

54

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

W x 22046 x 10-9

Conc1 = ------------------------------ Vm(std)

28 x 22046 x 10-9Conc1 = ------------------------------

71992

Conc1 = 853E-11

Where

Conc2 = W ( Vm(std) x 002832)

Conc2 = 28 ( 71992 x 002832 )

Conc2 = 137

Where

5555

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

MR1(Outlet) = 853E-11 x 3101 x 60

Where

MR2(Outlet) = PMR1 x 45359 3600

MR2(Outlet) = 159E-05 x 45359 3600

Where

5656

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

delta H 1764 x Y x Vm x ( Pb + ------------ )

136Vm(std) = --------------------------------------------

(Tm + 460)

18341764 x 09972 x 71248 x ( 3007 + --------------------- )

136

Vm(std) = ------------------------------------------------------------ = 71992 6583 + 460

Where

Vw(std) = (004707 x Vwc) + (004715 x Wwsg)

Vw(std) = ( 004707 x 80 ) + ( 004715 x 156 ) = 111

Where

4536 glb ft3g

5757

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

3 Moisture content

Vw(std)bws = -------------------------

Vw(std) + Vm(std)

111bws = ------------------------- = 0015

111 + 71992

Where

Md = 1 - bws

Md = 1 - 0015 = 0985

Where

MWd = ( 0440 x CO2 ) + ( 0320 x O2 ) + ( 0280 x ( N2 + CO) )

MWd = ( 0440 x 02 ) + ( 0320 x 208 ) + (0280 x ( 790 + 000 ))

MWd = 2886

Where

divided by 100

MWs = ( MWd x Md ) + ( 18 x ( 1 - Md ))

MWs = ( 2886 x 0985 ) +( 18 ( 1 - 0985 )) = 2870

Where

5858

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Ts (avg)

Ps x MWs

519Vs = 8549 x 084 x 052373 x ( -------------------- )^12 = 292

3010 x 2870Where

Qs(act) = 60 x 292 x 176 = 3079

Where

Ts

3010Qs(std) = 1764 x 0985 x -------------------- x 3079

5190

Qs(std) = 3101

Where

5959

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

17327 x Ts x Vm(std)I = -----------------------------------

17327 x 519 x 71992I = -------------------------------------------------- = 995

292 x 96 x 3010 x 0985 x (0280)^2Where

(in Hg)(in2)(min)

(deg R)(ft2)(sec)

6060

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

61

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

CO2 (3017 CC199689) 000 -001 000

NO (445 ppm CC346681) 000 002 011

N2O (904 ppm CC352661) 000 005 024

CO (4615 ppm XC006064B) 000 002 000

SO2 (4512 ppm CC409079) 000 005 023

H2 (552 ppm ALM048043) 000 009 044

HCl (451 ppm CC17830) 000 003 014

NH3 (969 ppm CC58181) 000 001 003

120

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6262

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

CO2 (3017 CC199689) NA NA NA

NO (445 ppm CC346681) 000 002 010

NO2 (2378 ppm CC500749) 000 000 002

N2O (904 ppm CC352661) 000 001 004

CO (4615 ppm XC006064B) 000 001 000

SO2 (4512 ppm CC409079) 000 011 064

CH4 (4531 ppm SG901795) 000 007 044

H2 (552 ppm ALM048043) 000 004 022

HCl (451 ppm CC17830) 010 006 060

NH3 (969 ppm CC58181) 000 002 014

219

lt 25

Chad Walker

INTERFERENCE CHECK

INTERFERENT GAS

SPAN(a)

6363

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Setting

in H20

(∆H) ft3

(Vw)ft3

(Vd)

oF (Tw)

Outlet oF (Tdo)

Inlet oF (Tdi)

Average oF (Td)

Time min (O)

Y ∆H

905750 7000 7000910724 7000 7000

4974 7000 7000911701 7100 7100916685 7100 7100

4984 7100 7100917680 7200 7200927695 7400 740010015 7300 7300

928690 7400 7400938780 7500 750010090 7450 7450

939800 7600 7600949930 7700 770010130 7650 7650

Average 09972 18715

1 2 3 4 5 632 32 32 32 32 320 00

212 213 213 212 212 2124 -01932 933 933 932 932 9324 00

20 100

18501128 10002

Dry Gas Meter

700

05 700

10

Orifice Manometer

Wet Test Meter

Dry gas Meter

Gas Volume

1822450 700 700 90

30 100 700

Meter

680

15 100

10007

50

700

107 09910

725

745

18894

18851130 09946

150 09995

9321832

Select Temperature

oC oF

21232

Average Temperature

Reading

(Accuracy +- 1oF)

Temp

Difference 2

()

Channel Number

19103

Calibration Results

2987

760

( ) ( )

( )( ) 2

Vw

O460tw

460tdPb

H03170H

460tw613

HPbVd

)460td(PbVwY

lowast+

lowast

+lowast

∆lowast=∆

+lowast

∆

+lowast

+lowastlowast=

( )( ) ( )( )( )

+

+minus+=

460FTempferenceRe

o

oo

6464

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Run 1 Run 2 Run 3

MWd = ( 032 O2 ) + ( 044 CO2 ) + ( 028 ( 100 - ( CO2 + O2 )))

MWd = ( 032 209 ) + ( 044 02 ) + ( 028 ( 100 - ( 02 + 209 )))

MWd = ( 669 ) + ( 009 ) + ( 2209 )

MWd = 2887 2886 2886

Tma = Ts + 460

Tma = 6158 + 460

Tma = 52158 51158 52583

Pm = 297 + ( 165791666666667 136)

Pm = 2982 3018 3020

Yqa = ( 9600 6863 ) SQRT ( 00319 52158 29 ) ( 187 2982 2887 ) 129

Yqa = 1399 SQRT 482517 1611069 129

Yqa = 09844 09783 09944

Diff = (( Y - Yqa ) Y ) 100

Diff = (( 09972 - 0984 ) 09972 ) 100

Average Diff = 115

Allowable = 50

1172020404 PM Dec E2 Stack6565

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

P-708 all in oneMOD

NO

NA

NO

NA

PASS

YES

PASS

NO YES

NA

0

09

001

0014

PASSFAIL

PASS

P-708

KS

YES NOPASS

Sample Probe

Type S Pitot Tube

Temperature Sensor

Dt

2 inch

Sample Probe

Temperature Sensor

DtType S Pitot Tube

3 inch

34 inch

A B

Face Opening Planes

A

BA

BQ1 Q1 Q2

B B

B

A A

A

FlowFlow

B1(+)B1(-)

B2(+ or -)

B1(+ or -)

B-Side Plane

AB

PA

PB

A-Side PlaneDt

X

Sampling D

Nozzle Entry Plane

W

B

A

B

A

Z

6666

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Signature on file

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

69

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

70

ADP6AAFtmp
- FIELD DATA INPUT
- - ADP4775tmp
    - SemiVol Results
    - - ADPBB2Btmp
      - SEMIVOLCALC
        
        Flow_Moist_ISO_Calc
        
        ADPE835tmp
        
        Calibration
        
        ADPC4BCtmp
        
        BLANK
        
        
        O2-Servomex 4900
        
        CO2-Servomex 4900
        
        CO-Servomex 4900
        
        NOx-42i
        
        ADPF759tmp
        
        Sheet1

Date post:	04-Sep-2020
Category:	Documents
Upload:	others
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