Highly Dispersible Precipitated Amorphous Silicon Dioxide (BET) (CTAB) Huber's highly dispersible silica can be used to reinforce all rubber compounds Zeopol 8745 Granule N/A 7 180 140 • Superior dispersion over conventional silica, particle size < 1 micron in compounded rubber Zeopol 8755 Granule N/A 7 195 153 • Lower viscosity and improved processibility at equal mixing energy compared with conventional silica Zeopol 8755LS Granule N/A 7 160 155 • Low surface area viscosity and improved processibility at equal mixing energy compared with conventional silica • Superior tear, fatigue and abrasion resistance vs. conventional silica • Significantly reduced hysteresis and heat build-up vs. carbon black under dynamic conditions Synthetic Sodium Aluminosilicate (BET) Zeolex products offer an excellent cost/performance because they are semi-reinforcing fillers and lower in cost than silica Zeolex ® 23 Powder 6 10 75 • Low surface area Zeolex products are used in extruded goods such as hose, gaskets and floor molding where surface smoothness and moderate reinforcement are needed Zeolex 80 Powder 6 7 115 • High surface area Zeolex products have more reinforcing capability, and can replace silica in some applications Synthetic Sodium Magnesium Aluminosilicate (BET) Hydrex ® R Powder 5 10 60 • Hydrex products improve UV resistance and extend titanium dioxide in white and colored rubber Kaolin Clay - Water Washed (BET) Brightness Water-washed kaolin clays offer good reinforcement, neutral pH, and extremely low crystalline silica and salt content Polyfil ® 35 Powder 4 6.5 9 82 • Coarse kaolin with the lowest oil absorption, for extending without reinforcement Polyfil DL Spray dried bead 1 6.5 13 83 • Large, platy delaminated clay that reduces gas permeability Polyfil DLX Spray dried bead 1.3 6.5 14 87 • Large, platy delaminated clay with a higher aspect ratio than Polyfil DL to reduce gas permeability Polyfil XB Spray dried bead 0.7 6.5 14 87 • Cost effective, kaolin extender offering improved consistency vs. air floated clays Polyfil X Powder 0.7 6.5 14 87 • Pulverized powder form of Polyfil XB Polyfil HG-90 Spray dried bead 0.2 6.5 21 91 • High brightness, ultrafine kaolin extender for white or bright colored rubber Polygloss ® 90 Powder 0.2 6.5 21 91 • Specially milled, high brightness ultrafine particle size kalin clay Silane treated clays mix-in quicker and may allow the formulator to reduce the amount of added silane Kaolin Clay - Treated The treatment aids dispersion in soft, low shear compounds such as stoppers, tubing, printing blankets Nucap ® 100G Powder 0.2 7 22 88 • Cost effective, moderate brightness, silane treated clay for partial carbon black replacement Nucap 190W Powder 0.2 5.8 22 91 • Sulfur-functional, siliane-treated, high brightness kaolin, for white roofing membranes and white sidewalls Nucap 290W Powder 0.2 5.8 22 91 • Highest silane surface treatment, for the best mechanical properties and water resistance Nulok ® 390 Powder 0.2 8.5 22 91 • Amino silane treated, high brightness water-washed kaolin clay, designed for peroxide cure systems Calcined clays are brighter than most water-washed clays, offering excellent processing and limited reinforcement Kaolin Clay - Calcined (BET) Brightness Outstanding wet/dry electrical properties due to the elimination of bound water during the calcined process Compounding with calcined clays results in smooth extrusions and reduced stickiness on mills Polyfil ® 70 Powder 1.4 5.5 8 91 • High brightness, workhorse calcined kaolin clay, Polyfil 80 Powder 1.4 5.5 8 92 • Higher brightness, medium particle size, calcined kaolin clay Polyfil 90 Powder 0.7 5.5 15 93 • Highest brightness, smallest particle size, calcined kaolin clay Polyfil WC Powder 1.4 5.5 8 91 • Organo-functional calcined clay for outstanding wet electrical properties and long term stability in W&C applications Polyfil WC-426 Powder 0.7 5.5 15 93 • Fine particle size organo-functional calcined clay for outstanding wet electrical properties and long term stability Nylok ® 170 Powder 1.4 8 8 91 • Aminosilane treated calcined kaolin reinforces polyamide resin systems Brightness reported as % reflectance, Technodyne These are typical properties - not specifications Product Physical Form Average Particle Size (µm) pH Surface Area (m 2 /g) Surface Area (m 2 /g) Huber Solutions… a broad array of performance additives for rubber products Huber proudly offers a broad product assortment to satisfy the needs of rubber compounders and producers. From Silicas and Silicates to Kaolin Clays, Alumina Trihydrate (ATH), Magnesium Hydroxide, Calcium Carbonate and Barium Sulfate, Huber products meet the demanding needs of its global and regional customers. Over a Century… of making products and processes better Since 1883, the J.M. Huber Corporation has provided a broad range of mineral and chemical solutions for industry. Focused on developing “best-in class” products, Huber has become a recognized leader in its field. Always persistent in understanding customer needs, Huber organizes its approach to effectively transform needs into innovative products that solve customer problems. Today, Huber has over 70 sites in 20 countries, and is one of the largest privately held family businesses in the United States. With a customer base ranging from large global multi-national companies to domestic regional businesses, Huber satisfies the needs of its customers, daily. Markets Served Huber materials are formulated in compounds for an endless array of rubber products, in a broad range of end-use markets. From tires, gaskets, belts, plugs, and mats, to thousands of unique molded, extruded and fabricated parts, Huber has the mix of products and applications expertise to meet the demanding needs of its broad customer base. Sample end-use markets include: o Automotive o Aerospace o Construction o Agriculture o Telecommunications o Medical Molded rubber parts, like these gaskets and liners, are formulated with a variety of performance-enhancing ingredients like the inorganic materials innovated by Huber.
Transcript
Highly Dispersible Precipitated Amorphous Silicon Dioxide (BET) (CTAB) Huber's highly dispersible silica can be used to reinforce all rubber compoundsZeopol 8745 Granule N/A 7 180 140 • Superior dispersion over conventional silica, particle size < 1 micron in compounded rubberZeopol 8755 Granule N/A 7 195 153 • Lower viscosity and improved processibility at equal mixing energy compared with conventional silicaZeopol 8755LS Granule N/A 7 160 155 • Low surface area viscosity and improved processibility at equal mixing energy compared with conventional silica
• Superior tear, fatigue and abrasion resistance vs. conventional silica• Significantly reduced hysteresis and heat build-up vs. carbon black under dynamic conditions
Synthetic Sodium Aluminosilicate (BET) Zeolex products offer an excellent cost/performance because they are semi-reinforcing fillers and lower in cost than silicaZeolex® 23 Powder 6 10 75 • Low surface area Zeolex products are used in extruded goods such as hose, gaskets and floor molding
where surface smoothness and moderate reinforcement are neededZeolex 80 Powder 6 7 115 • High surface area Zeolex products have more reinforcing capability, and can replace silica in some applications
Synthetic Sodium Magnesium Aluminosilicate (BET)Hydrex® R Powder 5 10 60 • Hydrex products improve UV resistance and extend titanium dioxide in white and colored rubber
Kaolin Clay - Water Washed (BET) Brightness Water-washed kaolin clays offer good reinforcement, neutral pH, and extremely low crystalline silica and salt contentPolyfil® 35 Powder 4 6.5 9 82 • Coarse kaolin with the lowest oil absorption, for extending without reinforcementPolyfil DL Spray dried bead 1 6.5 13 83 • Large, platy delaminated clay that reduces gas permeabilityPolyfil DLX Spray dried bead 1.3 6.5 14 87 • Large, platy delaminated clay with a higher aspect ratio than Polyfil DL to reduce gas permeabilityPolyfil XB Spray dried bead 0.7 6.5 14 87 • Cost effective, kaolin extender offering improved consistency vs. air floated claysPolyfil X Powder 0.7 6.5 14 87 • Pulverized powder form of Polyfil XBPolyfil HG-90 Spray dried bead 0.2 6.5 21 91 • High brightness, ultrafine kaolin extender for white or bright colored rubberPolygloss® 90 Powder 0.2 6.5 21 91 • Specially milled, high brightness ultrafine particle size kalin clay
Silane treated clays mix-in quicker and may allow the formulator to reduce the amount of added silaneKaolin Clay - Treated The treatment aids dispersion in soft, low shear compounds such as stoppers, tubing, printing blanketsNucap® 100G Powder 0.2 7 22 88 • Cost effective, moderate brightness, silane treated clay for partial carbon black replacementNucap 190W Powder 0.2 5.8 22 91 • Sulfur-functional, siliane-treated, high brightness kaolin, for white roofing membranes and white sidewallsNucap 290W Powder 0.2 5.8 22 91 • Highest silane surface treatment, for the best mechanical properties and water resistanceNulok® 390 Powder 0.2 8.5 22 91 • Amino silane treated, high brightness water-washed kaolin clay, designed for peroxide cure systems
Calcined clays are brighter than most water-washed clays, offering excellent processing and limited reinforcementKaolin Clay - Calcined (BET) Brightness Outstanding wet/dry electrical properties due to the elimination of bound water during the calcined process
Compounding with calcined clays results in smooth extrusions and reduced stickiness on millsPolyfil® 70 Powder 1.4 5.5 8 91 • High brightness, workhorse calcined kaolin clay,Polyfil 80 Powder 1.4 5.5 8 92 • Higher brightness, medium particle size, calcined kaolin clayPolyfil 90 Powder 0.7 5.5 15 93 • Highest brightness, smallest particle size, calcined kaolin clayPolyfil WC Powder 1.4 5.5 8 91 • Organo-functional calcined clay for outstanding wet electrical properties and long term stability in W&C applicationsPolyfil WC-426 Powder 0.7 5.5 15 93 • Fine particle size organo-functional calcined clay for outstanding wet electrical properties and long term stability Nylok® 170 Powder 1.4 8 8 91 • Aminosilane treated calcined kaolin reinforces polyamide resin systems
Brightness reported as % reflectance, Technodyne
These are typical properties - not specifications
ProductPhysical
Form
AverageParticle
Size (µm) pH
SurfaceArea(m2/g)
SurfaceArea(m2/g)
Huber Solutions…a broad array of performance
additives for rubber
products
Huber proudly offers a broad product assortment to satisfy the needs of rubbercompounders and producers. From Silicasand Silicates to Kaolin Clays, AluminaTrihydrate (ATH), Magnesium Hydroxide,Calcium Carbonate and Barium Sulfate,Huber products meet the demanding needsof its global and regional customers.
Over a Century… of making products and
processes better
Since 1883, the J.M. Huber Corporation hasprovided a broad range of mineral andchemical solutions for industry. Focused ondeveloping “best-in class” products, Huberhas become a recognized leader in its field.Always persistent in understanding customerneeds, Huber organizes its approach to effectively transform needs into innovativeproducts that solve customer problems.
Today, Huber has over 70 sites in 20 countries, and is one of the largest privatelyheld family businesses in the United States.With a customer base ranging from largeglobal multi-national companies to domesticregional businesses, Huber satisfies theneeds of its customers, daily.
Markets Served
Huber materials are formulated in compounds for an endless array of rubber products, in abroad range of end-use markets. From tires, gaskets, belts, plugs, and mats, to thousands ofunique molded, extruded and fabricated parts,Huber has the mix of products and applicationsexpertise to meet the demanding needs of itsbroad customer base. Sample end-use marketsinclude:
o Automotive
o Aerospace
o Construction
o Agriculture
o Telecommunications
o Medical
Molded rubber parts, likethese gaskets and liners, areformulated with a variety ofperformance-enhancingingredients like the inorganicmaterials innovated by Huber.
www.hubermaterials.com
For more information about these and other Huber products,contact the Huber office in your region.
CORPORATE HEADQUARTERSHuber Engineered MaterialsJ.M. Huber Corporation1000 Parkwood Circle, Suite 1000Atlanta, GA 30339Phone - 1-866-JM [email protected]
Alumina Trihydrate - Untreated (BET)SB-30 Off white powder 50 9 0.3 80 Alumina trihydrate is an extremely cost effective flame retardant and smoke suppressantSB-36 Off white powder 25 9 1 84 • Ground untreated grades are the most economical and are differentiated based on their particle sizeSB-222 Off white powder 14 9 1.3 87 • Alumina trihydrate contains no halogens or heavy metals, and hence it offers improved environmental compliance vs.SB-332 Off white powder 11 9 1.8 88 other flame retardantsSB-432 Off white powder 9 9 2.1 89 • Mechanism: At ~440 degrees F, the 3 water molecules in ATH are released in an endothermic reaction.Micral® 632 White Powder 5 9 4 95 The released water molecules quench the surface of the surrounding materials, thus imparting flame retardance.Micral 932 White Powder 2 9 13 98 High surface area improves flame retardant efficiencyMicral 9400D White Powder 1 9 4 98 Ultrafine, precipitated ATH with very low electrolyte content and high brightness
Alumina Trihydrate - Treated (BET) Huber applies a variety of surface treatments to ATH to speed up mixing, increase water resistance,Hymod® SB-432SP Powder 9* - 2.1* 89 and in some cases, enable the ATH to crosslink with the elastomerHymod SB-632SP Powder 5* - 4* 95 • SP reactive silane surface treatment improves mechanical properties, increases water resistance and is
compatible with silicone elastomersHymod SB-432CM Powder 9* - 2.1* 89 • CM surface treatments enable faster mixing times, but contain no crosslinking functionalityHymod M9400 SP Powder 1* - 4* 98 • SP surface treatment on 1 micron precipitated ATH makes this ideal for elastomer-based applicationsHymod M9401 Powder 1* - 4* 98 • Proprietary silane treatment on Hymod M9401 is designed for platinum cured silicone rubber
* indicates values of the base mineral
Magnesium Hydroxide (BET) Magnesium hydroxide is an excellent flame retardant for systems requiring compounding between 400º and 500º FVertexTM 60HST Powder 1.5* - 13* • Fine particle size, surface-treated magnesium hydroxide for applications such as thermoplastic and elastomeric
roofing membranes.Zerogen® 50SP Powder 1* - 7* • High purity, surface treated magnesium hydroxide for elastomer-based applicationsVertex 100HST Powder 0.8 - 14 • Fine particle size with uniform particle-size distribution for enhanced fire performance and mechanical properties.
* Indicates values of the base mineral** Untreated “base” magnesium hydroxide as well as other treated grades are also available.
Calcium Carbonate Oil Absorption Huber supplies a full line of calcium carbonate productsASTM D-281 The items below represent products commonly used in rubber
Hubercarb® W3 Powder 4 9.4 15 92 • Extremely low crystalline silica content (<0.1%) with low moisture pick-up and rounded particle shapeHubercarb W4 Powder 6 9.4 13 92 which improve surface finish and reduce equipment abrasion. W series products are produced in Quincy, IL
Hubercarb Q 3 Powder 3 9.4 18 89 • Fine particle size ground calcium carbonate produced in Quincy, ILHubercarb Q325 Powder 13 9.4 14 86 • Medium particle size ground calcium carbonate produced in Quincy, IL
Hubercarb G3 Powder 3 9.4 18 95 • High brightness, fine particle size calcium carbonate produced in Marble Hill, GAHubercarb G325 Powder 11 9.4 15 93 • High brightness, medium particle size calcium carbonate produced in Marble Hill, GA
Hubercarb M4 Powder 4 9.4 17 89 • Fine particle size ground calcium carbonate produced in Quincy, ILHubercarb M300 Powder 8 9.4 13 84 • Fine particle size ground calcium carbonate produced in Quincy, IL
Hubercarb Q1T Powder 1 9.4 21 90 • Stearic acid treated, very fine particle size ground calcium carbonate produced in Quincy, ILHubercarb G2T Powder 2 9.4 17 95 • Stearic acid treated, very fine particle size ground calcium carbonate produced in Marble Hill, GA
Barium Sulfate Oil AbsorptionASTM D-281 Barium sulfate is inert, insoluble in water and very dense
Huberbrite® 1 Powder 1 - 13 94 • High specific gravity (4.4) for dampening applications, used in white and bright colorsHuberbrite 7 Powder 7 - 10 94 • Available in 1, 3, 7 and 10 microns, low oil absorption allows high loadings
Brightness reported as % reflectance, Hunter
These are typical properties - not specifications
ProductPhysical
Form
AverageParticle
Size (µm) pH
SurfaceArea
(m2/g) Brightness
THERE ARE NO IMPLIED WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. Refer to Huber's StandardConditions of Sale for the only express warranties applicable to the Huberproducts. Products incorporating Huber products are not warranted by Huber. In no event is Huber liable for consequential damages.
Huberbrite® is a registered trademark of J.M. Huber Corporation for barium sulfate. Hubercarb® is a registered trademark of J.M. Huber Corporation for calcium carbonate.Huberpol® is a registered trademark of J.M. Huber Corporation for silicon dioxide.Hubersil® is a registered trademark of J.M. Huber Corporation for silicon dioxide.Hydrex® is a registered trademark of J.M. Huber Corporation for sodium aluminosilicate.Hymod® is a registered trademark of J.M. Huber Corporation for alumina trihydrate.Micral® is a registered trademark of J.M. Huber Corporation for alumina trihydrate.Nucap® is a registered trademark of J.M. Huber Corporation for kaolin clay.Nulok® is a registered trademark of J.M. Huber Corporation for kaolin clay.
Nylok® is a registered trademark of J.M. Huber Corporation for kaolin clay.Onyx Elite® is a registered trademark of J.M. Huber Corporation for alumina trihydrate.Polyfil® is a registered trademark of J.M. Huber Corporation for kaolin clay.Polygloss® is a registered trademark of J.M. Huber Corporation for kaolin clay.Vertex® is a registered trademark of J.M. Huber Corporation for magnesium hydroxide.Zeolex®is a registered trademark of J.M. Huber Corporation for sodium aluminosilicate.Zeopol® is a registered trademark of J.M. Huber Corporation for silicon dioxide.Zerogen® is a registered trademark of J.M. Huber Corporation for magnesium hydroxide.
