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Section1 1 Yilian LI

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    Evaluation on CO2geological

    utilization technologies

    CO2

    1 3

    45

    2

    Li YilianChina University of Geosciences

    April, 2012

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    PRESENTATION OUTLINE 1. Background

    2. CO2Geological Utilization R&D Activities

    CO23. Integrated CO2Geological Utilization System

    CO24. Prospect Evaluation on CO2Geological Utilization

    CO2

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    1. Background

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    Climate Change Compromises the Whole World

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    CCUS provides important technical options for

    Addressing Climate Change

    CO2Geological Utilization

    CO2CO2Chemical Utilization

    CO2

    CO2Biological Utilization

    CO2

    CCUS provides

    importanttechnical options

    for Addressing

    Climate Change

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    Role of CO2Geological UtilizationTechnology

    Why CO2

    GeologicalUtilization ?

    Time scale

    - Long time

    - Security

    Spatial scales

    - Underground space

    - Large reduction potential

    Environmental benefits

    - CO2reduction

    -Address climate change

    Economic benefits

    - Cost-effective

    -Additional output

    value

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    2. CO2Geological Utilization R&D ActivitiesCO2

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    Schematic diagram of possible CCUS systems

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    CO2Geological Utilization and Storage

    CO2Geological Utilization and Storage

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    CO2Geological Utilization Technologies

    CO2

    1.CO2 Enhanced oil recoveryCO2-EOR)2.CO2 Enhanced coal bed methane recovery

    (ECBM)

    3.CO2 Enhanced gas recovery(EGR)4.CO2 Assisting joint exploration of

    liquid mineral

    5.CO2 Enhanced geothermal system6.CO2 Enhanced exploration of

    shale gas

    7.CO2 Basalt storage8.CO2 Bauxite residue treatment9. Manufacturing rock cavity10.CO

    2

    Geological carbon sink

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    CO2geological utilization technologies

    CO2

    1.Enhanced oil recoveryCO2-EOR) CO2

    3.Enhanced gas recovery(EGR)CO2

    5.Enhanced geothermal system

    CO2

    1 3

    4

    5

    2

    CO2

    2. Enhanced coal bed methane recovery (ECBM)

    CO2

    4. Assisting joint exploration of liquid mineral

    CO2

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    1.CO2-EOR

    CO2

    CO2

    CO2

    Inject compressedCO2into depleted

    oil fields

    CO2mixture with theresidual oil and

    decrease its viscosity

    Through decrease thecrude oils viscosity,

    enhanced the oilrecovery

    13

    4

    5

    2

    EOR

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    Zama,canada EOR locationzamaCO2

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    Cross section map

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    CO2-EOR technology roadmap CO2

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    Injecting schematic

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    CO2-EOR

    230 28316.86m3/ 2006.12~2011

    25,000 100/ 2006.12~2009.8.30

    10%~15% CO2

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    PetroChinas CO2EOR Research and pilot Injection,

    Jilin Oilfield

    Goal: 0.8-1.0 million tons storage of CO2annually (Phase II)

    Site: Jilin Oil Field

    Technologies: Separation of CO2from natural gas + EORStatus: Phase I has been completed and phase II is in progress

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    3

    4

    5

    ECBM

    12

    2.CO2

    Enhanced coal bed methane recovery (ECBM)

    CO2

    CO2

    CO2

    CO2

    ECBM

    Displacing and releasing

    CO2 absorbs onto the coal

    CO2 injection into coal seams

    CO2 storage

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    Schematic of an ECBM operation, where captured CO2 from a power

    plant is injected into the coal seam and CH4 is produced

    Schematic of an ECBM operation, where captured CO2 from a power

    plant is injected into the coal seam and CH4 is produced

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    Simplified schematic for the storage mechanism in a conventional

    gas reservoir (a) and in a coal seam (b).

    Simplified schematic for the storage mechanism in a conventional

    gas reservoir (a) and in a coal seam (b).

    The injected gas fills the

    available pore volume as a

    compressed fluid

    The gas is additionally

    adsorbed and absorbed

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    CO2-ECBMCO2-ECBM

    Production and injection rates of multi well pilot test in the Ishikari Coal

    Basin of Japan in 2004

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    China United Coalbed Methane Co. ECBM Pilot Project

    Project Entity: China UnitedCoalbed Methane Company(CUCBM)

    Goal: Studying and developingECBM and CO2storagetechnology, testing safety andpermanence of CO2

    sequestration.Location: Shizhuang, Qinshui

    County, Shanxi Province

    Technique: CO2Storage for

    ECBM

    Current Status: Ongoing,injection test started since

    April 2010

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    3.EGRCO2

    CO2

    CO2

    13

    4

    5

    2

    EGR

    2

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    13

    4

    5

    2

    4.CO2

    Assisting joint exploration of liquid mineral

    Inject CO2 into

    the deep

    saline aquifers

    CO2

    The max

    utilization of

    the subsurfacespace

    Promote the

    production of

    brine

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    5.Enhanced geothermal system(EGS)

    CO2

    Relative place

    Product well

    Sequestration site

    Inject well

    usage of heat

    Hot CO2flow out

    Heat exchange by density

    Cold CO2inject in

    CO2

    CO2

    CO2

    13

    4

    5

    2

    EGS

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    6 8

    9

    10

    7

    CO2

    6.CO2

    Enhanced exploration of shale gas

    7.CO2

    Basalt storage

    8.CO2 Bauxite residue treatment

    9.Manufacturing rock cavity

    10.Geological carbon sink

    CO2

    6 7

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    68

    9

    10

    7

    Enhanced

    shale gas

    Injection of CO2

    and the reaction

    between CO2

    and basalt

    Make the

    silicate

    carbonatation

    Stable

    carbonates

    decrease the

    risk of CO2leakage

    6.CO2

    Enhanced exploration of shale gas

    7

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    68

    9

    10

    7

    Basalt

    storage

    7.CO2

    Basalt storage

    CO2

    CO2

    Injection of CO2

    and the reaction

    between CO2

    and basalt

    Make the

    silicate

    carbonatation

    Stable

    carbonates

    decrease the

    risk of CO2leakage

    6 7

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    68

    9

    10

    7

    CO2

    8.CO2

    Bauxite residue treatment

    CO2

    CO2

    CO2 can be injected into the highly alkaline bauxite residue

    CO2 can partially neutralize the product and then

    is converted to mineral form

    Reducing the disposal costs and limiting the

    potential environmental impacts

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    9&10.Manufacturing rock cavity and as carbon sink

    CO2

    CO2

    CO2CO2

    CO l i l ti li ti d St

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    Nagaoka

    Hokkaido

    Qinshui Basin

    Snohvit

    Sleipner

    In Salah

    Key

    ECBM projects

    EOR projects

    Gas production Fields

    Saline aquifier

    Sibilla

    RECOPOLCO2SINK

    K-12B

    Cerro Fortunoso

    Frio

    West Pearl Queen

    Mountaineer

    Weyburn

    Penn WestAlberta ECBM

    Teapot DomeRangely

    Burlington

    4 New CO2-EOR Pilots in

    Canada

    50 Acid Gas

    injection sites in

    North America

    70 CO2-EOR

    projects in U.S.A.

    GorgonDepleted Oil Field

    Otway Basin

    How to use this

    Presentation

    Zama

    Carson

    Kwinana

    COCO22geological utilizationgeological utilization and Storageand Storage

    ActivitiesActivities

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    Qinshui Basin

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    Comparison of Built CO2geological utilization

    Demonstration Projects in China and Other Countries

    Technology chain Project # Largest Project Longest

    ExperienceAbroad Home Abroad Home Abroad Home

    Geological

    Utilization

    and

    Storage

    CO2EOR Technology >100 10 1.2 MT/a100,000

    T/a

    Nearly 40

    Years6 Years

    CO2ECBM Technology

    >5 1 >200,000 s 192 s 7 Years 4 Years

    Onshore Saline aquifer

    Storage >2 1 1 MT/a100,000

    T/a7 Years

    0.5

    Year

    Offshore Saline aquifer

    Storage2 - 1 MT/a - 15 Years -

    Depleted Oil and Gas

    Field Storage 1 -about 10,000

    T/a- 7 Years -

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    3. Integrated CO2Geological Utilization SystemO

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    Integrated CO2Geological Utilization System

    CO2

    1.CO2Enhanced oilrecoveryCO2-EOR)

    2.CO2Enhanced gas

    recovery(EGR)

    3.CO2

    Assisting jointexploration of liquid

    mineral

    4.CO2

    Enhanced geothermalsystem

    CO2

    I d CO G l i l U il i i S

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    Integrated CO2Geological Util ization SystemO

    CO2CO2CO2

    CO2-EORCCSCCSCCUSCO2

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    4. Prospect Evaluation on CO2Geological Utilization O

    Prospect Evaluation on CO Geological Utilization

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    Prospect Evaluation on CO2Geological Utilization

    OPrimary Index Secondary Index

    Emission ReductionsPotential

    Overall Potential for Effective CO2Emission Reduction

    Maximum Annual Volume of CO2Capture

    Maximum Annual Volume of CO2StorageOther Environmental Benefits

    Cost CO2 Capture and Compression Cost (t/CO2)

    Transportation, Storage and Additional Revenue Summation (t/CO2)

    Risk Technological Perfection

    Leakage and Security Risk

    Future Resource Conflicts

    Development Decline Magnitude of Overall Costs after Large-scale Promotion

    Decline Magnitude of Risk after Putting into Practice

    Future Changes in Emission Sources

    Degree of Future Public Recognition

    Goal

    Congruence

    Consistent with the Vision of Technological Development and Goals in Every

    Stage

    Coverage Demonstration Project Should Cover All the Critical Technological Elements

    Reality CCUS Systems Having Been or to Be Demonstrated by Enterprises

    Prospect Evaluation on CO Geological Utilization

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    Prospect Evaluation on CO2Geological Utilization

    O

    CO2

    CO2

    CO2

    CO2

    CO2

    EOR

    EGR

    ECBM

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    Thank You !


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