Classification Level:
Business Owner:
Distribution List:
Technology Licensing for the Petrochemical Industry
Global E&C Solutions Communications
Budapest, 13/10/2015 l Dirk Burghardt l Sales Director Licensing and Technology, Downstream & Petrochemicals
CEE & Turkey Refining and Petrochemicals
13th-15th October 2015 I Sofitel Budapest, Hungary
Air Liquide, world leader in gases, technologies and services for Industry and Health 2 13/10/2015
■ Synthesis Gas Production
■ Air Separation Plants
■ Methanol & MTP
■ Natural gas conditioning
■ Petrochemicals
■ Oleochemicals, Biodiesel
■ Fischer-Tropsch GTL
The Air Liquide Group
Large Industries
Air gases and hydrogen 15-year contracts Pipeline networks Industrial basins
Electronics
Carrier gases Specialty gases Equipment and Installations
Healthcare
Hospitals Homecare Hygiene
Industrial Merchant Bulk and cylinder gases 80 countries Wide variety of sectors and customer sizes
Global E&C Solutions Design, Engineering & Construction
of leading-edge processing facilities Plants for AL Group and 3rd Party Clients
Other activities
Welding & Cutting Diving Specialty chemicals
Air Liquide, world leader in gases, technologies and services for Industry and Health 3 13/10/2015
Agenda
1. Petrochemistry – General
2. 1,3-Butadiene
3. Benzene (Distapex®)
4. Acrylic Acid
5. Melamine
Air Liquide, world leader in gases, technologies and services for Industry and Health 4 13/10/2015
Petrochemistry General – Technology Map
Products Intermediates
Acrylic Acid
Butadiene
Benzene
Urea
Propylene
C4-Cut
Aromatics
Melamine
MTP MeOH
Natural Gas
Syngas
(CO, H2)
Refinery /
Cracker
ASU
Acrylates
SAP
Synthetic
Rubber
Styrene,
Phenol, CH
Laminates
Adhesives
Poly-
propylene
Air Liquide E&C features special expertise in
■ Oxidation
■ Extraction
■ Hydrogenation
Air Liquide, world leader in gases, technologies and services for Industry and Health 5 13/10/2015
Technology Portfolio – Business Model
Proprietary
Technologies
Own Research &
Development
Alliances
Edgein
Aquisition
BP
(Semi-) Exclusive
Partnerships
Technology
Portfolio
Distapex®
Acrylic Acid
Butadiene
Acrylates
Melamine
Air Liquide, world leader in gases, technologies and services for Industry and Health 6 13/10/2015
1. Petrochemistry – General
2. 1,3-Butadiene
3. Benzene (Distapex®)
4. Acrylic Acid
5. Melamine
Agenda
Air Liquide, world leader in gases, technologies and services for Industry and Health 7 13/10/2015
Global Butadiene Demand - Outlook
■ Global Consumption 2013: 10.5 mio tons
■ Expected Average Annual Growth Rate 2013 – 2020: 3.2 %
driven by growth in demand for ABS, SBR, and Butadiene Rubber
Asia Pacific 55%
North America 17%
Western Europe
16%
Eastern Europe
5%
South America
3%
Central Europe
3%
Middle East & Africa
1%
BD Consumption 2013
-4%
-2%
0%
2%
4%
6%
8%
10%
12%
14%
16%
BD Consumption Growth2000 - 2013
BD Consumption Growth2013 - 2020
Source: Nexant, Mai 2014
Air Liquide, world leader in gases, technologies and services for Industry and Health 8 13/10/2015
Butadiene Experience and Partnership
NMP Process invented
by BASF
BASF
Technology Owner
First BASF Plant built by Lurgi
Lurgi
Sublisensor
for BASF NMP Process
Lurgi‘s First Butadiene Reference
Esso (CAA) Technology
Lurgi projects based on
Esso (CAA)
Shell (ACN)
Nippon Zeon (DMF)
BASF (NMP)
1958
1968
Since 1990
Continuous Improvements
Early
1960‘s
Air Liquide, world leader in gases, technologies and services for Industry and Health 9 13/10/2015
BASF NMP Technology Features
■ Worldwide recognized technology
Safe
Eco-Efficient
Reliable
Low environmental impact
■ 57 References in total
■ 30 since Y2000
Air Liquide, world leader in gases, technologies and services for Industry and Health 10 13/10/2015
Butadiene Extraction Technology - Challenges
■ Separation of Butadiene from a complex Mix of C4
■ C4 Mix is different in each individual project
■ Operational Difficulties
Popcorn Formation
Foaming
Fouling
C4 Acetylenes
Raffinate Propyne
Butadiene C4 Feed
C4 / C5
Extractive Distillation
Distillation
Air Liquide, world leader in gases, technologies and services for Industry and Health 11 13/10/2015
AL E&C - The Technology Partner of Choice
■ AL E&C has long-term competence in Hydrocarbon Extraction
■ Besides standard process concepts we offer tailor-made solutions to
meet the specific requirements of its clients
■ Active Contribution to continuous process improvements with regard to:
Popcorn Formation
Foaming
Fouling
Source:
Popcorn Issue Group (European
Ethylene Producers Committee)
Proven highest On-stream Efficiency
Air Liquide, world leader in gases, technologies and services for Industry and Health 12 13/10/2015
ONGC, Gutjarat
126,600 tpa (2009)
Russian Federation
105,000 tpa (2012)
10 References since 2005, 4 in 2012, 36 in total
EVONIK, Antwerp, Belgium
100,000 tpa (2012)
OMV, Schwechat, Austria
+ 12,000 tpa (2012)
Petrobras, Rio
+ 165,000 tpa (2008)
BASF, Ludwigshafen
+ 14,000 tpa (2008)
HALDIA, India
+ 25,000 tpa (2007)
Copesul, Triunfo
+ 103,500 tpa (2005)
OXENO, Marl
+ 36,000 tpa (2006)
MOL, Tiszaujvaros, Hungary
130,000 tpa (2012)
Air Liquide, world leader in gases, technologies and services for Industry and Health 13 13/10/2015
1. Petrochemistry – General
2. 1,3-Butadiene
3. Benzene (Distapex®)
4. Acrylic Acid
5. Melamine
Agenda
Air Liquide, world leader in gases, technologies and services for Industry and Health 14 13/10/2015
Global Benzene Demand - Outlook
■ Global Production 2014: 45 mio tons
■ Expected Average Annual Growth Rate 2015 – 2020: 3.5 %
driven by growth in demand Styrene, Phenol & Cyclohexane
0
10
20
30
40
50
60
2014 2015 2016 2017 2018 2019 2020
Millio
ns
Other Production Sorces
On-Purpose Production
Production from Petrochemicals
Producton from Refineries
Source: Platts
Air Liquide, world leader in gases, technologies and services for Industry and Health 15 13/10/2015
Distapex® Proprietary Technology - Challenges
■ Separation of Benzene from a complex Mix of Pyrolysis Gasoline
■ C6 Mix is different in each individual project
Pygas
C5
Benzene
Selective
Hydrogenation
Full Hydrogenation
and
Desulphurisation
Extractive
Distillation
C7+ to Gasoline Pool
C5- to Gasoline Pool
H2
Off-gas H2 Off-gas
C6
Raffinate
Air Liquide, world leader in gases, technologies and services for Industry and Health 16 13/10/2015
AL E&C Frankfurt - The Technology Partner of Choice
■ AL E&C has long-term competence in Hydrocarbon Extraction
■ Lurgi technology developed in 1960s and continuously improved
■ Reference capacities ranging from 20,000 tpa up to 400,000 tpa
■ Use of same solvent as in Butadiene Extraction (NMP)
Synergies for Cracker operators
Advanced competences available with AL E&C Frankfurt
■ Outstanding solution for Benzene production
High purity and high Benzene yield
Air Liquide, world leader in gases, technologies and services for Industry and Health 17 13/10/2015
OPaL, India
165,000 tpa (2009)
6 Aromatics References since 2003, 25 in total
Gexaro, France
252,000 tpa (2005)
OMV, Burghausen
+ 10,000 tpa (2003)
HALDIA, India
+ 77,000 tpa (2005)
Petrochimica Uniao, Brazil
+ 123,000 tpa (2007)
SABIC, The Netherlands
280,000 tpa (2005)
Air Liquide, world leader in gases, technologies and services for Industry and Health 18 13/10/2015
Agenda
1. Petrochemistry – General
2. 1,3-Butadiene
3. Benzene (Distapex®)
4. Acrylic Acid
5. Melamine
Air Liquide, world leader in gases, technologies and services for Industry and Health 19 13/10/2015
■ Global Consumption 2014: 5.2 mio tons
■ Expected Average Annual Growth Rate 2014 – 2019: 3.8 %
driven by growth in demand for SAP and Acrylic Esters
Global Acrylic Acid Demand - Outlook
0
1000
2000
3000
4000
5000
6000
7000
2011 2012 2013 2014 2015 2016 2017 2018 2019
Asia Pacific
Africa
Middle East
Eastern Europe
Central Europe
Western Europe
South America
North America
Source: Nexant
Air Liquide, world leader in gases, technologies and services for Industry and Health 20 13/10/2015
Hexion
Heavy Acrylates
Glacial
Acrylic
Acid
SAP
Lurgi /
Nippon
Kayaku
Ester
Grade
Acrylic
Acid
Hexion
Light Acrylates
Technologies licensed by AL E&C Frankfurt
Others
Acrylic Complex and Alliances
■ Single Line Responsibility for EAA, GAA and Acrylates
■ Proven Technologies
■ 30 Years Experience
■ Operational
Excellence
■ Licensing
■ Engineering
■ Marketing
■ Proprietary
Catalyst
Air Liquide, world leader in gases, technologies and services for Industry and Health 21 13/10/2015
Acrylic Acid Technology - Challenges
Solvent
Extraction
Crude AA
Recovery
Raffinate
Stripping
Acrylic Acid
Purification
Absorber Offgas to Incinerator
Demin Water
Absorber Offgas Recycle
Propylene
Air
Steam
Waste Water Organic Waste
EAA Product
Quench/
Absorber
Reaction
■ Complex Reactor System
■ Oxidation of Propylene: avoid flammable envelope
■ Potential Polymerization of Acrylic Acid
Air Liquide, world leader in gases, technologies and services for Industry and Health 22 13/10/2015
■ Reactor Design in Cooperation with a Reknown Manufacturer
■ Single train capacity up to 160 ktpa
Lowest CAPEX
■ Safety Standards for HC Oxidation fully mastered
■ Highest performance catalyst on the Market
Lowest OPEX
Feedstock: Refinery Grade Propylene (> 80 wt.%)
■ Technological Features to prevent Polymerization
Internal Thermoplate Heat Exchangers
Use of Baffle Trays in Columns
■ Minimum Health & Environmental Impact
Non-toxic Extraction Solvent
Minimized Waste Generation
Lurgi / NK Acrylic Acid – Features
Air Liquide, world leader in gases, technologies and services for Industry and Health 23 13/10/2015
BPCL, Kochi, Kerala, India
160,000 tpa
Start-up: 2012
CNOOC, Huizhou, Guangdong, China
140,000 tpa
Start-up: 2002
Hexion, Sokolov, Czech Republic
30,000 tpa
3 References, 2 World-scale, July 2015: BPCL, India
Air Liquide, world leader in gases, technologies and services for Industry and Health 24 13/10/2015
Agenda
1. Petrochemistry – General
2. 1,3-Butadiene
3. Benzene (Distapex®)
4. Acrylic Acid
5. Melamine N
NN
NH2H
2N
NH2
Air Liquide, world leader in gases, technologies and services for Industry and Health 25 13/10/2015
0
200
400
600
800
1000
1200
1400
1600
1800
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017
Mto
ns/y
ear
Year
US Japan Europe Asia Pacific Rest of the world
■ Global Consumption 2014: 1.6 mio tons
■ Expected Average Annual Growth Rate 2013 – 2017: 4.6 %
driven by growth in demand for Laminates and Adhesives
Global Melamine Demand - Outlook
Source: National Energy Corporation
Air Liquide, world leader in gases, technologies and services for Industry and Health 26 13/10/2015
Melamine – Alliance
Licensing and
Know-How
Package
ALLIANCE
■ Technology Owner
■ Vast Operation Experience
■ Reference Plants
■ Training at Site
■ Site Visits
■ Technical Assistance
Edgein Technology
Developer &
Producer
AL E&C Frankfurt Technology
Licensor &
Engineering
■ Technology Licensing
■ Value Engineering and
Process Optimization
■ Marketing
■ Engineering
■ Project Execution World Wide
Client
Advanced
Technology
Air Liquide, world leader in gases, technologies and services for Industry and Health 27 13/10/2015
Melamine Technology – Challenges
■ Complex Fluidized Bed Reactor
■ Efficient Solids Handling
■ Efficient Product Separation
■ Avoid Corrosion Problems
■ Gas Phase Crystallization
■ Handling of Desublimation and Solid Product
■ Prevention of Fouling
Reaction
& Filtration Gas Scrubbing
Crystallization
& Separation
Urea
Melt Melamine
Product
Air Liquide, world leader in gases, technologies and services for Industry and Health 28 13/10/2015
Start-up: 2012
NevAzot, Stavropol, Russia
50,000 tpa
Melamine References
Since 1993: 18 Plants
Golden Elephant, China
Total capacity: 400,000 tpa
Air Liquide, world leader in gases, technologies and services for Industry and Health 29 13/10/2015
■ Air Liquide E&C cultivates Competences in:
Hydrocarbon Processing
Technology Research & Development
Mangement of Industrial Alliances
Acquisition of Technologies
Technological Challenges
Safety
Reliability
Conceptional Solutions
Effective Project Execution
Conclusion
Air Liquide E&C is the Technology Partner of Choice