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The Costs and Benefits of Carbon Capture and Storage
Khosrow BiglarbigiHitesh Mohan
Marshall Carolus
INTEK
July 16, 2009Calgary, Canada
CO2 Emissions from Energy Consumption
2.0
3.0
4.0
5.0
6.0
7.01
99
0
19
91
19
92
19
93
19
94
19
95
19
96
19
97
19
98
19
99
20
00
20
01
20
02
20
03
20
04
20
05
20
06
20
07
20
08
Billion Tons of CO2
Year
20% Increase
Source: US EIA
United States
So, What Do We Do With It?
Transport
Use
Capture
Potential Uses of CO2
CO2
Sequestration
Industrial Grade
Food Grade
Options with Environmental and Economic Benefits
Options with Environmental
Benefits
CO2 Capture TechnologyAmine Absorber
Amine Absorber
Flue Gas without
CO2
Feed Gas Lean Solution
PumpLean/Rich Exchanger
Amine Stripper
Acid Gas Condenser CO2
Make-Up Water
Lean Solution
Cooler
Source: UOP, “Amine GuardTM FS Process” 2000. Amine Reboiler
Variations of Technology(Proprietary Licenses)
• Amine with SO2 removal – Kerr McGee/ABB Lummus
• Costain Oil Gas and Process Limited (natural gas)
• Amine Guard and Amine Guard II – UOP
• Econamine FG – Fluor Daniel, Inc.
• Hindered Amine – Flexsorb HP (Exxon) and Giammarco-
Vetrocoke
CO2 Capture Technology (Cont.)
• Cold Methanol
• Pressure Swing Adsorption
• Hot Potassium Carbonate
• Membrane (unproven)
• Amine/membrane combination
Cost of Capturing Industrial CO2
Capture Cost Sources: Global Energy Technology Strategy Program, NETL, and others
low high low high average
Fossil Fuel Power Plants 38 63 2.11 3.50 2.81
Refineries 35 55 1.95 3.06 2.50
Cement Plant 35 55 1.95 3.06 2.50
Hydrogen Plants 6 12 0.33 0.67 0.50
Ammonia Plants 6 12 0.33 0.67 0.50
Ethanol Plants 6 12 0.33 0.67 0.50
New IGCC Plants 25 40 1.39 2.22 1.81
Source$/Ton CO2 $/mcf CO2
low high low high average
Fossil Fuel Power Plants 38 63 2.11 3.50 2.81
Refineries 35 55 1.95 3.06 2.50
Cement Plant 35 55 1.95 3.06 2.50
Hydrogen Plants 6 12 0.33 0.67 0.50
Ammonia Plants 6 12 0.33 0.67 0.50
Ethanol Plants 6 12 0.33 0.67 0.50
New IGCC Plants 25 40 1.39 2.22 1.81
Source$/Ton CO2 $/mcf CO2
• Pipeline
– CO2 must be dried
– High compression required for transport (2000-3000 psig)
– Drying and compression cost is estimated at $9 per ton
• Truck, Barge, Ship
– CO2 is transported as a liquid
– Liquefaction infrastructure is required
– Additional loading and unloading activities
– Liquefaction cost is estimated at $10 per ton
– Shipping cost is estimated at $1-$10 per ton
CO2 Transportation
Options with Environmental Benefits
Brine Aquifer
Ocean Bed Storage
Ocean BedCO2 Ocean BedCO2
Brine Aquifer
CO2
Brine Aquifer
CO2
Depleted Oil & Gas Reservoirs
CO2
Oil & Gas Reservoirs
Depleted Oil & Gas Reservoirs
CO2
Oil & Gas Reservoirs
Options with Environmental and Economic Benefits
EOR Coal Bed Methane
Gas Bearing Shale
Gas Storage
Gas Bearing Sandstone
CH4
Top Gas (CH4)
Natural Gas Well
CO2 CH4
Top Gas (CH4)
Natural Gas Well
CO2
Natural Gas Well
CO2
Fluidized Bed Unit
Injection Separation
CO2 Capture
CO2 N2 N2
CH4 to Sales
Coalbed CO2 CH4 N2 CH4
Fluidized Bed UnitFluidized Bed Unit
Injection Separation
CO2 Capture
CO2 N2 N2
CH4 to Sales
Coalbed CO2 CH4 N2 CH4
C O 2P ro d u c e d M e th a n e C O 2P ro d u c e d M e th a n e CO2
Produced Natural Gas
CO2
Produced Natural Gas
Costs and Benefits of SequestrationDollar per Ton of CO2
Oil & Gas Res.
Brine Aquifer
Ocean Bed
CO2
Sequestration
Gas Bearing Sandstone
Gas Bearing Shale
Coal Bed Methane
Gas Storage (Base Gas)
EOR
($31-55)
$36
- 10
6
($1-10)
($1-10)
($1-10)
($7- 41)
$4 -
41($
33-7
5)($
39-1
06)
0
20
40
60
80
100
120
Year
No. o
f Pro
jects
0
50
100
150
200
250
1982 1984 1986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008Year
Pro
du
ctio
n (
MB
bl/D
ay)
Example Application in the United StatesCO2 Enhanced Oil Recovery
Proven Technology 100 Projects in 2008 (USA) Production of 240 MBbl/Day
Pro
du
ctio
n M
Bb
l/D
Source: Oil & Gas Journal
Year
Nu
mb
er o
f P
roje
cts
Year
Projects Using CO2 from Natural Sources(61 Million Ton/Year)
Source: Oil and Gas Journal
Industrial Sources of CO2
(2 Billion Tons of CO2 in 2007)
CO2 EOR Candidate Fields(1,700 Reservoirs, 20 Billion Barrels)
Proximity of the Sources to the Fields
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power Plants
Candidate CO2 EOR Fields
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power Plants
Candidate CO2 EOR Fields
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
RefineriesAmmonia PlantsCement PlantsHydrogen Plants
Ethanol Plants > 50 Bcf/YrEthanol Plants > 1 Bcf/Yr
Fossil Fuel Power PlantsOther Industrial Sources
Incremental ProductionDaily Oil Production from Additional CO2 EOR
0
200
400
600
800
1,000
1,200
Year
Daily
Oil
Pro
duct
ion (
MB
bl)
Total of4.7 Billion Bbl
Dai
ly O
il P
rod
uct
ion
(M
Bb
l)
Year
Additional Benefit: CO2 Storage(Cumulative Over 25 Years)
0
5
10
15
20
25
30
2008
2010
2012
2014
2016
2018
2020
2022
2024
2026
2028
2030
Year
CO
2 S
tore
d (
MM
cf/D
ay)
CO
2 S
tore
d (
Tri
llio
n C
ub
ic F
eet
)
25 Trillion Cubic Feet
Summary
• Capture Technologies are Advancing Rapidly
• Sequestration Options are Widely Available
• The Process is Both Site and Project Specific
• Both Environmental and Economic Benefits can be Realized