Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
Rev: Prepared By: Checked By: Approved By: Issued:0 Tony Fildes Tom Selkirk D Montagu-Smith 08/09/2015
Page 1 of 6
West Newton B WellsiteDrilling Products
Exploratory Operations
This document contains proprietary information belonging to Rathlin Energy (UK) Limited and shallbe used only for the purpose for which it was supplied. It shall not be copied, reproduced, disclosedor otherwise used, nor shall such information be furnished in whole or in part to third parties, exceptin accordance with the terms of any agreement under which it was supplied or with the priorconsent of Rathlin Energy (UK) Limited and shall be returned upon request.
© Copyright of Rathlin Energy (UK) Limited
Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
Rev: Prepared By: Checked By: Approved By: Issued:0 Tony Fildes Tom Selkirk D Montagu-Smith 08/09/2015
Page 2 of 6
*** Page Left Blank Intentionally ***
Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
Rev: Prepared By: Checked By: Approved By: Issued:0 Tony Fildes Tom Selkirk D Montagu-Smith 08/09/2015
Page 3 of 6
171/2” INTERVAL DRILLING FLUIDS INFORMATION
Mud Type Bentonite Polymer WBM Total Volume 184m3
Drill from 80m (TVD KB) Drill to 505m (TVD KB)
Proposed Drilling Fluid Composition
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
Concentration
(kg per M3)
Soda Ash 25 3 75 0.41
Caustic soda 12.5 5 62.5 0.34
POLYPAC UL 25 21 525 2.85
Drilling Starch 25 63 1,575 8.56
M–I GEL 25 210 5,250 28.53
Safe–cide 25 3 75 0.41
Contingency Drilling Products Held on Site
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
Soda Ash 25 6 150
Caustic soda 12.5 10 125
POLYPAC UL 25 42 1,050
Drilling Starch 25 126 3150
M–I GEL 25 420 10,500
M-I WATE 25 1,600 40,000
Safe–cide 25 5 125
NUTSHELLS (all grades) 25 20 500
DYNARED (all grades) 12 42 504
KWIK-SEAL (all grades) 18 28 504
SAFECARB (all grades) 25 40 1,000
Citric Acid 25 20 500
DEFOAM PLUS NS 25 8 200
Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
Rev: Prepared By: Checked By: Approved By: Issued:0 Tony Fildes Tom Selkirk D Montagu-Smith 08/09/2015
Page 4 of 6
121/4” INTERVAL DRILLING FLUIDS INFORMATION
Mud Type KCl Polymer WBM Total Volume 288m3
Drill from 505m (TVD KB) Drill to 1,510m (TVD KB)
Proposed Drilling Fluid Composition
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
Concentration
(kg per M3)
KCl Brine 1,000 78.3 78,300 271.88
Soda Ash 25 5 125 0.43
Caustic soda 12.5 10 125 0.43
DUO-VIS 25 33 825 2.86
POLYPAC UL 25 33 825 2.86
Drilling Starch 25 132 3,300 11.46
Safe–cide 25 4 100 0.35
M-I WATE 1,000 33 33,000 114.58
Contingency Drilling Products Held on Site
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
KCl Brine 1,000 156.6 156,600
Soda Ash 25 10 250
Caustic soda 12.5 19 237.5
DUO-VIS 25 66 1,650
POLYPAC UL 25 66 1,650
Drilling Starch 25 264 6,600
Safe–cide 25 8 200
M-I WATE 1,000 66 66,000
DEFOAM PLUS NS 25 12 300
NUTSHELLS (all grades) 25 20 500
DYNARED (all grades) 12 42 504
KWIK-SEAL (all grades) 18 28 504
Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
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Page 5 of 6
SAFECARB (all grades) 25 40 1,000
Citric Acid 25 20 500
KCl Salt 1,000 6 6,000
81/2” INTERVAL DRILLING FLUIDS INFORMATION
Mud Type Mixed Salt Saturated Polymer WBM Total Volume 168m3
Drill from 1,510m (TVD KB) Drill to 2,044m (TVD KB)
Proposed Drilling Fluid Composition
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
Concentration
(kg per M3)
KCL Salt 1,000 10 10,000 59.52
Soda Ash 25 3 75 0.45
Caustic soda 12.5 3 37.5 0.22
DUO-VIS 25 29 725 4.32
POLYPAC UL 25 29 725 4.32
Drilling Starch 25 58 1,450 8.63
Safe–cide 25 2 50 0.30
M-I WATE 1,000 27 27,000 160.71
Contingency Drilling Products Held on Site
Product Unit Size
(kg)
Quantity Total Quantity
(kg)
NaCl Brine 1,000 347.4 347,400
KCl Salt 1,000 20 20,000
Soda Ash 25 6 150
Caustic soda 25 3 75
DUO-VIS 25 58 1,450
POLYPAC UL 25 58 1,450
Drilling Starch 25 116 2,900
Safe–cide 25 4 100
Applies To: Rathlin Energy (UK) Limited RE-05-EPRA-WNB-DP-009
Prepared By: Tony Fildes Uncontrolled, If Printed Rev: 0
EPRA – WEST NEWTON B – EXPLORATORY OPERATIONS – DRILLING PRODUCTS
Rev: Prepared By: Checked By: Approved By: Issued:0 Tony Fildes Tom Selkirk D Montagu-Smith 08/09/2015
Page 6 of 6
M-I WATE 1,000 54 54,000
DEFOAM PLUS NS 25 12 300
NUTSHELLS (all grades) 25 20 500
DYNARED (all grades) 12 42 504
KWIK-SEAL (all grades) 18 28 504
SAFECARB (all grades) 25 40 1,000
Citric Acid 25 20 500
CONQOR 404 NS 25 36 900
REVISION DATE: 25-Sep-10 - Rev 06: 0656
SAFETY DATA SHEET
Caustic Soda
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME Caustic Soda
CHEMICAL NAME Sodium hydroxide
PRODUCT NO. CASOGEN, CASO004, CASO025
APPLICATION Unblocks drains and clears waste pipes.
BarrettineSUPPLIER
Barrettine Works
St Ivel Way
Warmley
Bristol
BS30 8TY
0117 960 0060
0117 935 2437
EMERGENCY TELEPHONE 0870 190 6777
2 HAZARDS IDENTIFICATION
CLASSIFICATION (1999/45) C;R35.
CLASSIFICATION (EC 1272/2008)
Physical Not classified.
Health Skin Corr. 1A - H314
Environmental Not classified.
LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008
SIGNAL WORD Danger
CONTAINS SODIUM HYDROXIDE
HAZARD STATEMENTS
H314 Causes severe skin burns and eye damage.
PRECAUTIONARY STATEMENTS
Store locked up. Keep out of reach of children.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303/361/353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing.
Rinse skin with water/shower.
P305/351/338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P301/330/331/313 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Get medical
advice/attention.
P501B Dispose of contents/container to hazardous waste collection point.
HUMAN HEALTH
Corrosive. Prolonged contact causes serious eye and tissue damage.
3 COMPOSITION/INFORMATION ON INGREDIENTS
51 /
REVISION DATE: 25-Sep-10 - Rev 06: 0656
Caustic Soda
SODIUM HYDROXIDE >98%
CAS-No.: 1310-73-2 EC No.: 215-185-5
CLASSIFICATION (67/548)
C;R35
CLASSIFICATION (EC 1272/2008)
Skin Corr. 1A - H314
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16
4 FIRST-AID MEASURES
GENERAL INFORMATION
Immediately remove affected person from source of exposure. Provide first-aid, rest, warmth and fresh air. First-aiders
should avoid direct contact with this product and should wear protective gloves, goggles and clothing. Get medical attention
immediately!
INHALATION
Keep the affected person warm and at rest. Get prompt medical attention.
INGESTION
NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Rinse mouth thoroughly. Get medical attention
immediately! Promptly get affected person to drink large volumes of water to dilute the swallowed chemical.
SKIN CONTACT
Remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention immediately!
EYE CONTACT
Check for contact lenses which must be removed from the eyes before rinsing.
Promptly rinse eyes with plenty of clean water while lifting the eyelids.
Continue to rinse for at least 15 minutes. Continue until the eyes are free of all traces of contamination.
Get immediate medical attention.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials. For large fires use: Water spray, fog or mist. Alcohol
resistant foam.
SPECIAL FIRE FIGHTING PROCEDURES
Contaminated fire water must not be allowed to contaminate ground or enter drains, sewers or water courses. Provide
bunding against fire water run-off.
UNUSUAL FIRE & EXPLOSION HAZARDS
Corrosive to metals. Liberates highly flammable hydrogen gas.
PROTECTIVE MEASURES IN FIRE
Wear self-contained breathing apparatus and full protective clothing. Keep all unnecessary people away. Fire water run-off
must not be allowed to contaminate ground or enter drains, sewers or water courses. Provide bunding against fire water
run-off.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing (see Section 8). Keep unnecessary people at a safe distance.
ENVIRONMENTAL PRECAUTIONS
Do not allow ANY environmental contamination. Cover all drains and sewers. Avoid spreading spilt material.
SPILL CLEAN UP METHODS
DO NOT TOUCH SPILLED MATERIAL! Stop leak if possible without risk. Avoid generation and spreading of dust.
Sweep-up and place into clearly labelled containers for recovery or disposal. (see section 13)
Cover and move the containers. Flush the area with water. Flushings must not be allowed to contaminate ground or enter
drains, sewers or water courses. Provide bunding against water run-off.
Clean-up personnel should wash contaminated skin thoroughly after dealing with spillage.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Prevent spilling, skin and eye contact. Avoid inhalation of dust. Use only with adequate ventilation.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place. Store away from: Acids. Stored containers
should be routinely inspected for damage and leakage.
52 /
REVISION DATE: 25-Sep-10 - Rev 06: 0656
Caustic SodaSUITABLE STORAGE MATERIALS
Keep in original container. Stainless steel. Most plastics
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Std STEL - 15 minTWA - 8 hrsName Notes
WEL 2 mg/m3SODIUM HYDROXIDE
WEL = Workplace Exposure Limit.
PROCESS CONDITIONS
Provide eyewash, quick drench.
ENGINEERING MEASURES
Handling should take place with controlled ventilation sufficient to remove dust arising from handling but which does not
itself lead to dust formation.
Operators should in any case wear RPE.
RESPIRATORY EQUIPMENT
If ventilation is insufficient suitable respiratory protection must be provided.
Seek recommendations and advice from equipment manufacturer or supplier.
HAND PROTECTION
Wear suitable protective gloves conforming to EN 374. Seek recommendations from manufacturer or supplier. After using
gloves the hands should be washed and dried thoroughly and a suitable moisturiser applied. Suitable gloves may include -
Neoprene.
EYE PROTECTION
Wear tightly fitting safety goggles conforming to EN166
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact.
HYGIENE MEASURES
DO NOT SMOKE IN WORK AREA! Wash at the end of each work shift and before eating, smoking and using the toilet.
Wash promptly if skin becomes wet or contaminated. Promptly remove any clothing that becomes contaminated. When
using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Granules, prills or pellets.
COLOUR White
SOLUBILITY Soluble in water.
MELTING POINT (°C) 318°C RELATIVE DENSITY 2.13
BULK DENSITY ~1175 kg/m3 pH-VALUE, DILUTED SOLUTION >11.5 1%
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal conditions of storage and use. See section 7. The substance is hygroscopic and will absorb water by
contact with the moisture in the air.
CONDITIONS TO AVOID
May attack light-alloy metals and liberate hydrogen gas. (e.g. aluminium, magnesium, zinc.)
MATERIALS TO AVOID
Reacts strongly with some metals, metal powders and metal alloys including aluminium (Al), copper (Cu), tin (Sn) and zinc
(Zn). to evolve Extremely flammable Hydrogen.
HAZARDOUS DECOMPOSITION PRODUCTS
Decomposition can lead to the formation of toxic gases or fumes, including Hydrogen.
11 TOXICOLOGICAL INFORMATION
GENERAL INFORMATION
Seek medical attention for all burns, regardless how minor they may seem.
INHALATION
May cause damage to mucous membranes in nose, throat, lungs and bronchial system.
INGESTION
Causes severe burns. May cause chemical burns in mouth and throat. Ingestion may result in perforation of the
oesophagus, accompanied by vomiting blood, diarrhoea, haemolysis, haemoglobinuria and shock.
53 /
REVISION DATE: 25-Sep-10 - Rev 06: 0656
Caustic SodaSKIN CONTACT
Causes severe burns.
EYE CONTACT
Strongly corrosive. Causes severe burns and serious eye damage. Immediate first aid is imperative.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Not regarded as dangerous for the environment.
MOBILITY
The product is soluble in water. Discharge of large amounts causes changes in pH which may affect effluent and sewage
treatment processes.
ACUTE FISH TOXICITY
Discharge of large quantities may kill fish and other aquatic life due to excessive changes in water pH.
WATER HAZARD CLASSIFICATION
WGK 1 ID = 142 Sodium hydroxide.
13 DISPOSAL CONSIDERATIONS
GENERAL INFORMATION
Empty but unlaundered containers must be treated in the same manner as when full; labels should not be removed.
DISPOSAL METHODS
Product is classified as hazardous waste. Disposal of waste material and empty containers must be by means of a licensed
waste contractor.
14 TRANSPORT INFORMATION
UK ROAD CLASS 8
PROPER SHIPPING NAME SODIUM HYDROXIDE, SOLID
1823UN NO. ROAD IIUK ROAD PACK GR.
8ADR CLASS NO. Class 8: Corrosive
substances.
ADR CLASS
IIADR PACK GROUP (E)TUNNEL RESTRICTION CODE
80HAZARD No. (ADR) 8ADR LABEL NO.
2WHAZCHEM CODE 80GC6-II+IIICEFIC TEC(R) NO.
8RID CLASS NO. IIRID PACK GROUP
1823UN NO. SEA 8IMDG CLASS
IIIMDG PACK GR. F-A, S-BEMS
1823UN NO. AIR 8AIR CLASS
IIAIR PACK GR.
15 REGULATORY INFORMATION
EU DIRECTIVES
EC Regulation 1907/2006 (as amended) : 'REACH'.
Dangerous Substances DIrective 67/548/EEC.
Dangerous Preparations Directive 1999/45/EC.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging for Supply) Regulations 2009 SI No 716. (CHIP4).
Control of Substances Hazardous to Health Regulations (as amended). (COSHH)
Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations 2007. (CDG 2009)
APPROVED CODE OF PRACTICE
The Control of Substances Hazardous to Health Regulations 2002 (as amended). Approved code of practice and guidance.
Fifth Edition 2005. HSE Books, or download at: http://www.hse.gov.uk/pubns/priced/l5.pdf
54 /
REVISION DATE: 25-Sep-10 - Rev 06: 0656
Caustic SodaApproved classification and labelling guide L131 (Sixth Edition - 2009)
GUIDANCE NOTES
CHIP for everyone HSG(108).
Workplace Exposure Limits EH40.
Introduction to Local Exhaust Ventilation HS(G)37.
16 OTHER INFORMATION
REVISION COMMENTS
New format SDS, including classification to CLP. (EC1272/2008)
REVISION DATE 25-Sep-10 - Rev 06: 0656
REV. NO./REPL. SDS
GENERATED
06 - replaces version 05 dated 21-04-2010
RISK PHRASES IN FULL
Causes severe burns.R35
HAZARD STATEMENTS IN FULL
Causes severe skin burns and eye damage.H314
DISCLAIMER
This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in
any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no
warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the
suitability of such information for his own particular use.
55 /
Revision Date 28-Feb-13
Revision 6
Supersedes date 14-Mar-08
SDS No. 11350
SAFETY DATA SHEET
CITRIC ACID
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name CITRIC ACID
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Oil well drilling fluid additive. pH modifier.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Eye Irrit. 2 - H319
Environment Not classified.
Classification (1999/45/EEC) Xi;R36.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
Signal Word Warning
Hazard Statements
H319 Causes serious eye irritation.
Precautionary Statements
P337+313 If eye irritation persists: Get medical advice/attention.
Supplementary Precautionary Statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash contaminated skin thoroughly after handling.
71 /
SDS No. 11350
CITRIC ACID
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
CITRIC ACID MONOHYDRATE 60-100%
CAS-No.: 5949-29-1 EC No.:
Classification (67/548/EEC)
Xi;R36.
Classification (EC 1272/2008)
Eye Irrit. 2 - H319
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes and get medical attention.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Fire or high temperatures create: Irritating gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
72 /
SDS No. 11350
CITRIC ACID
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Remove spillage with vacuum cleaner. If not possible, collect spillage with shovel, broom or the like.
Flush with plenty of water to clean spillage area. Do not let washing down water contaminate ponds or waterways.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Store separated from: Alkalis. Oxidising material.
Storage Class
Chemical storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Wear mask supplied with: Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. Polyvinyl chloride (PVC).
Eye protection
Wear approved safety goggles.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
73 /
SDS No. 11350
CITRIC ACID
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Crystals or crystalline
Colour White.
Odour Odourless.
Solubility Soluble in water.
Melting point (°C) 153°C
Relative density 1.542g/cm3 @ 20°C
Bulk Density 900 kg/m3
pH-Value, Diluted Solution 1.6 @ 100g/l
Solubility Value (G/100G
H2O@20°C)
60
Auto Ignition Temperature (°C) 1010°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
Violent reaction with: Strong alkalis. Strong oxidising agents.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
None known.
10.5. Incompatible materials
Materials To Avoid
Strong alkalis. Strong oxidising agents.
10.6. Hazardous decomposition products
Fire or high temperatures create: Irritating gases/vapours/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxic Dose 1 - LD 50
5040 mg/kg (oral-mouse)
Toxic Dose 2 - LD 50
3000 mg/kg (oral rat)
Acute toxicity:
Acute Toxicity (Oral LD50)
> 7000 mg/kg Rabbit
ATE (Oral)
3000 mg/kg
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
74 /
SDS No. 11350
CITRIC ACID
Ingestion
May irritate and cause stomach pain, vomiting and diarrhoea.
Skin contact
Skin irritation is not anticipated when used normally.
Eye contact
Causes serious eye irritation. Particles in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
LC 50, 96 Hrs, Fish mg/l 440 - 760
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
This product does not contain any PBT or vPvB substances.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
EWC-code: 06 01 06. 7134. Organic acids.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
75 /
SDS No. 11350
CITRIC ACID
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable. Please contact [email protected] for info regarding transport in Bulk.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
Water hazard classification
WGK 1
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision.
Issued By Sarah Malone
Revision Date 28-Feb-13
Revision 6
Supersedes date 14-Mar-08
SDS No. 11350
Signature Laura McDonald
Signature 2 Sandra McWilliam
Risk Phrases In Full
Irritating to eyes.R36
Hazard Statements In Full
Causes serious eye irritation.H319
76 /
SDS No. 11350
CITRIC ACID
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
77 /
Revision Date 15-Oct-12
Revision 0
SDS No. 15797
SAFETY DATA SHEET
DEFOAM PLUS NS*
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name DEFOAM PLUS NS*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Defoamer.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Not classified.
2.2. Label elements
Risk Phrases
NC Not classified.
Safety Phrases
NC Not classified.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
FATTY ACID DERIVATIVES 60-100%
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
61 /
SDS No. 15797
DEFOAM PLUS NS*
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel into
dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
62 /
SDS No. 15797
DEFOAM PLUS NS*
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Light amber
Odour Slight odour.
Solubility Insoluble in water
Relative density ~ 0.96 s.g
Flash point >130°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Not known.
63 /
SDS No. 15797
DEFOAM PLUS NS*
10.6. Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
> 2000 mg/kg Rat
*Based on components
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Toxicity - Fish
LC50 > 100 mg/l
*Aquatic species (calculated data following Dir. 1999/45/CE)
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is insoluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
64 /
SDS No. 15797
DEFOAM PLUS NS*
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), United States (TSCA).
SECTION 16: OTHER INFORMATION
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
This is first issue. Compiled or revised by Sandra McWilliam
Issued By Bill Cameron
Revision Date 15-Oct-12
Revision 0
SDS No. 15797
65 /
SDS No. 15797
DEFOAM PLUS NS*
Risk Phrases In Full
Not classified.NC
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
66 /
Page 1 of 2 Version: MSDS 001.01 Date of issue 05.1.12
MATERIAL SAFETY DATA SHEET According to Regulation (EC) Nr. 1907/2006
SECTION 1: IDENTIFICATION OF PREPARATION AND COMPANY Company:
Novidon Limited Coed Aben Road , Wrexham Industrial Estate WREXHAM, LL13 9UH Tel: +44 (0)1978 664384 Fax: +44 (0)1978 665979
Product Name: Drillamyl – Drilling Starch
SECTION 2: HAZARDS IDENTIFICATION The chemical nature of this product does not give occasion to
caution against hazards for adverse human health and environmental effects. Avoid dust creation, which could lead to a dust explosion.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS CAS NR EINECS NR Chemical Constitution Hazardous Components:
9005-84-9 see section 15 Cold water soluble modified potato starch None
SECTION 4: FIRST AID MEASURES SKIN: Wash the skin with soap and water EYES: Immediately wash out the eyes with plenty of water. Seek medical
attention if symptoms persist INGESTION: Wash out the mouth with water. Do not induce vomiting. Seek
medical attention if large amounts ingested INHALATION: Remove from exposure. Keep warm and rest.
SECTION 5: FIRE FIGHTING MEASURES Fumes containing carbon dioxide and carbon monoxide may be formed in large fires.
In case of fire use powder, foam, sand and water spray. Self contained breathing apparatus should be worn. The risk of a dust explosion should be considered.
SECTION 6: ACCIDENTAL RELEASE MEASURES Contain and collect the spillage. Shovel/vacuum up in a manner to minimise dust
generation. Wear impervious gloves, overalls, eye protection and a dust mask while clearing up the spillage. Do not wash with water - may make the floor very slippery. Do not wash into drains.
SECTION 7: HANDLING AND STORAGE Store in a cool dry area. External damage to the bags should be avoided. Seal bags
after use. Do not store next to strong oxidising agents that may aggravate any fire situation. Use in a well ventilated area. Avoid rough open handling which creates dust
SECTION 8: EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Controls: Provide good ventilation Respiratory Protection: Dust masks must be worn Hand Protection: Impervious gloves must be worn Eye Protection: Goggles must be worn in dusty conditions Skin Protection Protective overalls and shoes must be worn.
Page 2 of 2 Version: MSDS 001.01 Date of issue 05.1.12
MATERIAL SAFETY DATA SHEET According to Regulation (EC) Nr. 1907/2006 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Appearance: Free flowing, granular powder Odour: Almost odourless pH: 5.0-8.0 Solubility Soluble in water at ambient temperatures Bulk density 550-700kg/m3 Flash point >125ºC Other properties: None are relevant
SECTION 10: STABILITY AND REACTIVITY Stable. Avoid water damage in storage to prevent the product lumping. There is no
thermal decomposition if used as directed. In case of complete combustion the decomposition products carbon dioxide (CO2) and water (H2O) are formed.
SECTION 11: TOXICOLOGICAL INFORMATION This product is not toxic.
SECTION 12: ECOLOGICAL INFORMATION The base starch is not harmful to aquatic organisms and does not cause long-term
adverse effects in the aquatic environment.
SECTION 13: DISPOSAL INFORMATION Disposal will depend upon the actual mud system and the regulations governing drilling
muds in that part of the world where Drillamyl is intended for use. Existing EEC, National and Local Regulations must always be complied with.
SECTION 14: TRANSPORT INFORMATION Not classified as hazardous for transportation.
SECTION 15: REGULATORY INFORMATION Generally this product is not subjected to the regulations for mandatory marking; however
take into consideration the possible existence of local regulations. As a consequence of the classification rules, polymer products like derivates don’t have an EINECS of ELINCS number. Starch as product or raw material for derivates of starch has the EINECS number 232-679-6.
SECTION 16: OTHER INFORMATION Risk Phrases referred to in this safety data sheet: not applicable
Drillamyl is an additive for use in drilling mud systems. This information only concerns the above named product and may not be valid if used with other product(s) or in any process. This information is, to our best knowledge, correct and complete, but no guarantee can be given. It remains the responsibility of the user to make sure that the information is appropriate and complete for their particular use of the product. If you have purchased this product for supply to a third party for use at work, it is your duty to take all necessary steps to ensure that any person handling or using the product is provided with the information on this sheet. If you are an employer, it is your duty to tell employees and others who may be affected of any hazards described in this sheet and of any precautions that should be taken. Drillamyl is not obliged to be registered for REACH
Revision Date 08-Nov-2012
Revision 6
Supersedes date 18-May-2010
SDS No. 10216
SAFETY DATA SHEET
DUO-VIS*
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name DUO-VIS*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Viscosifier
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Contact Person [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East
and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Not classified.
2.2. Label elements
Risk Phrases
NC Not classified.
Safety Phrases
NC Not classified.
Australian statement of hazardous/dangerous nature
Classified as Non-Hazardous according to the criteria of NOHSC.
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
71 /
SDS No. 10216
DUO-VIS*
XANTHAN GUM 60-100%
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
GLYOXAL <1%
CAS-No.: 107-22-2 EC No.: 203-474-9
Classification (67/548/EEC)
Muta. Cat. 3;R68
Xn;R20
R43
Xi;R36/38
Classification (EC 1272/2008)
Acute Tox. 4 - H332
Skin Irrit. 2 - H315
Eye Irrit. 2 - H319
Skin Sens. 1 - H317
Muta. 2 - H341
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues. Do not induce vomiting.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop
as described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
72 /
SDS No. 10216
DUO-VIS*
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. In case of
spills, beware of slippery floors and surfaces.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Good personal hygiene is
necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Remove contaminated clothing. Do not
eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
No biological limit allocated.
GLYOXAL (CAS: 107-22-2)
DNEL
Dermal Long Term Systemic Effects 48 mg/kg
Inhalation. Long Term Systemic Effects 16.9 mg/m³
Inhalation. Long Term Local Effects 0.07 mg/m³
PNEC
Freshwater 0.319 mg/L
Marinewater 0.0319 mg/L
Intermittent release 1.1 mg/L
STP 4.1 mg/L
Sediment (Freshwater) 0.685 mg/kg
Sediment (Marinewater) 0.0685 mg/kg
Soil 4.06 mg/kg
8.2. Exposure controls
Protective equipment
73 /
SDS No. 10216
DUO-VIS*
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and
the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated
with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such
further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace
and should be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
In case of inadequate ventilation or risk of inhalation of dust, use suitable respiratory equipment with particle filter (type P2).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber or polyvinyl acetate.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Promptly remove
any clothing that becomes wet or contaminated.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Powder, dust
Colour Cream to Tan
Odour Characteristic.
Solubility Completely soluble in water
Relative density 1.5 s.g @ 20°C
Bulk Density 650-850 kg/m3
pH-Value, Diluted Solution 7 @ 1 %
Auto Ignition Temperature (°C) > 200°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Dust may form explosive mixture with air.
10.4. Conditions to avoid
Avoid dust formation. Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with strong oxidisers.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Carbon dioxide (CO2). Carbon monoxide (CO).
74 /
SDS No. 10216
DUO-VIS*
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxic Dose 1 - LD 50
45 mg/kg (oral rat)
Toxic Dose 2 - LD 50
20 mg/kg (oral-mouse)
Toxic Conc. - LC 50
21 ppm/1h (inh-rat)
Toxicological information
*Based on components
Aspiration hazard:
Based on available data the classification criteria are not met.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Particles in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Toxicity - Fish
LC50 96 hours 420 mg/l Onchorhynchus mykiss (Rainbow trout)
12.2. Persistence and degradability
Degradability
Readily biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
No bioaccumulation is expected.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
75 /
SDS No. 10216
DUO-VIS*
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID). and (ADG).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
Australian Standard for the Uniform Scheduling of Drugs and Poisons
No Poisons Schedule number allocated.
New Zealand Hazard Classification and HSNO Approval No.
Not Classified. HSNO Approval No. Not Required.
Name of Group Standard and Information on Conditions of Group Standard
Not applicable.
Australian Regulations
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)]. National Occupational
Health and Safety Commission’s Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004) 3rd Edition]. National
Occupational Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in the occupational Environment
[NOHSC:1003 (1995)]. Safe Work Australia. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). ADG Code – Australian
Dangerous Goods Code.
76 /
SDS No. 10216
DUO-VIS*
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 2 HMIS Flammability - 1 HMIS Physical Hazard - 0 E - Safety glasses, Gloves, Dust Respirator
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Updated according to REACH Annex II. Compiled or revised by Sarah Malone
Issued By Bill Cameron
Revision Date 08-Nov-2012
Revision 6
Supersedes date 18-May-2010
SDS No. 10216
Risk Phrases In Full
Harmful by inhalation.R20
Irritating to eyes and skin.R36/38
May cause sensitisation by skin contact.R43
Not classified.NC
Possible risk of irreversible effects.R68
Hazard Statements In Full
Causes serious eye irritation.H319
Causes skin irritation.H315
Harmful if inhaled.H332
May cause an allergic skin reaction.H317
Suspected of causing genetic defects.H341
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
77 /
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 1/6
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
Product information
Trade name : DYNARED™ (Seepage Control Fiber) Material : 1016830, 1016829, 1016828 Use : Drilling Fluid Additive Company : Chevron Phillips Chemical Company LP
Drilling Specialties Company 10001 Six Pines Drive The Woodlands, TX 77380
Local : Chevron Phillips Chemicals International N.V.
Brusselsesteenweg 355 B-3090 Overijse Belgium MSDS Requests: (800) 852-5530 Technical Information: (832) 813-4862 Responsible Party: Product Safety Group Email:[email protected]
Emergency telephone:
Health: 866.442.9628 (North America) 1.832.813.4984 (International) Transport: North America: CHEMTREC 800.424.9300 or 703.527.3887 ASIA: 800-CHEMICAL (2435 2255) CHINA: 0532.8388.9090 EUROPE: BIG +32.14.584545 (phone) or +32.14583516 (telefax) South America SOS-Cotec Inside Brazil: 0800.111.767 Outside Brazil: +55.19.3467.1600
Responsible Department : Product Safety and Toxicology Group E-mail address : [email protected] Website : www.CPChem.com
2. HAZARDS IDENTIFICATION
Risk advice to man and the environment
Not a hazardous substance or mixture according to EC-directives 67/548/EEC or 1999/45/EC. Labelling according to EC Directives
1999/45/EC
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 2/6
Further information : The product does not need to be labelled in accordance with EC directives or respective national laws.
GHS-Classification
Not a dangerous substance according to Globally Harmonized System of Classification and Labeling of Chemicals (GHS). GHS-Labeling
Not a dangerous substance according to Globally Harmonized System of Classification and Labeling of Chemicals (GHS).
3. COMPOSITION/INFORMATION ON INGREDIENTS
Synonyms : DYNARED™ Medium DYNARED™ Fine DYNARED™ Coarse
Molecular formula : Not Applicable Contains no hazardous ingredients according to GHS.
4. FIRST AID MEASURES
General advice : Do not leave the victim unattended. Inhalation : If unconscious place in recovery position and seek medical
advice. If symptoms persist, call a physician. Eye contact : Remove contact lenses. Protect unharmed eye. If eye
irritation persists, consult a specialist. Ingestion : Keep respiratory tract clear. Do not give milk or alcoholic
beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician.
5. FIRE-FIGHTING MEASURES
Flash point : Not applicable Autoignition temperature : Not applicable
Special protective equipment for fire-fighters
: Wear self contained breathing apparatus for fire fighting if necessary.
Further information : Standard procedure for chemical fires. Use extinguishing
measures that are appropriate to local circumstances and the surrounding environment.
Fire and explosion protection
: Provide appropriate exhaust ventilation at places where dust is formed.
Hazardous decomposition products
: None.
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 3/6
6. ACCIDENTAL RELEASE MEASURES
Personal precautions : Avoid dust formation. Methods for cleaning up : Pick up and arrange disposal without creating dust. Sweep up
and shovel. Keep in suitable, closed containers for disposal.
7. HANDLING AND STORAGE
Handling
Advice on safe handling : For personal protection see section 8. Smoking, eating and
drinking should be prohibited in the application area. Advice on protection against fire and explosion
: Provide appropriate exhaust ventilation at places where dust is formed.
Storage
Requirements for storage areas and containers
: Electrical installations / working materials must comply with the technological safety standards.
Advice on common storage : No materials to be especially mentioned.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Personal protective equipment
Respiratory protection : No personal respiratory protective equipment normally
required. Eye protection : Safety glasses. Skin and body protection : Protective suit. Hygiene measures : General industrial hygiene practice.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Physical state : Solid Color : reddish brown Odor : Mild, earthy Safety data
Flash point : Not applicable
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 4/6
Lower explosion limit : Not applicable
Upper explosion limit : Not applicable
Oxidizing properties : No
Autoignition temperature : Not applicable
Molecular formula : Not Applicable
Molecular Weight : Not applicable
pH : Not applicable
Pour point : Not applicable
Boiling point/boiling range : Not applicable
Vapor pressure : Not applicable
Water solubility : Slightly soluble
Partition coefficient: n-octanol/water
: No data available
Viscosity, kinematic : Not applicable
Relative vapor density : Not applicable
Evaporation rate : No data available
Percent volatile : No data available
10. STABILITY AND REACTIVITY
Conditions to avoid : Not applicable. Other data : This material is considered stable under normal ambient and
anticipated storage and handling conditions of temperature and pressure.
No decomposition if stored and applied as directed.
11. TOXICOLOGICAL INFORMATION
Product Acute oral toxicity : LD50: not known
Product Acute inhalation toxicity : LC50: not known Product Acute dermal toxicity : LD50: not known
Product
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 5/6
Skin irritation : No skin irritation Dust causes irritation to the eyes, skin and mucous membranes and may lead to toxic lung edemas.
Product Eye irritation : No eye irritation
Product Aspiration toxicity : No aspiration toxicity classification.
12. ECOLOGICAL INFORMATION
Elimination information (persistence and degradability) Biodegradability : Expected to be biodegradable
Further information on ecology
Additional ecological information
: No data available
13. DISPOSAL CONSIDERATIONS
Use material for its intended purpose or recycle if possible. This material, if it must be discarded, may meet the criteria of a hazardous waste as defined by US EPA under RCRA (40 CFR 261) or other State and local regulations. Measurement of certain physical properties and analysis for regulated components may be necessary to make a correct determination. If this material is classified as a hazardous waste, federal law requires disposal at a licensed hazardous waste disposal facility. Contaminated packaging : Empty containers should be taken to an approved waste
handling site for recycling or disposal.
14. TRANSPORT INFORMATION
The shipping descriptions shown here are for bulk shipments only, and may not apply to shipments in non-bulk packages (see regulatory definition). Consult the appropriate domestic or international mode-specific and quantity-specific Dangerous Goods Regulations for additional shipping description requirements (e.g., technical name or names, etc.) Therefore, the information shown here, may not always agree with the bill of lading shipping description for the material. Flashpoints for the material may vary slightly between the MSDS and the bill of lading.
USDOT NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IMO / IMDG NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
IATA NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
SAFETY DATA SHEET
DYNARED™ (Seepage Control Fiber)
Version 1.1 Revision Date 2010-07-13
MSDS Number:100000014030 6/6
ADR NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
RID NOT REGULATED AS A HAZARDOUS MATERIAL OR DANGEROUS GOODS FOR TRANSPORTATION BY THIS AGENCY.
15. REGULATORY INFORMATION
National legislation
Major Accident Hazard Legislation
: 96/82/EC Update: 2003 Directive 96/82/EC does not apply
Notification status Europe REACH : On the inventory, or in compliance with the inventory United States of America TSCA : On the inventory, or in compliance with the inventory Canada DSL : On the inventory, or in compliance with the inventory Australia AICS : On the inventory, or in compliance with the inventory New Zealand NZIoC : On the inventory, or in compliance with the inventory Japan ENCS : On the inventory, or in compliance with the inventory Korea KECI : On the inventory, or in compliance with the inventory Philippines PICCS : On the inventory, or in compliance with the inventory China IECSC : On the inventory, or in compliance with the inventory
16. OTHER INFORMATION
Further information
Legacy MSDS Number : 647920
Changes since the last version are highlighted in the margin. This version replaces all previous versions. The above information is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with which we may be unfamiliar and since data made available subsequent to the date hereof may suggest modifications of the information, we do not assume any responsibility for the results of its use. This information is furnished upon condition that the person receiving it shall make his own determination of the suitability of the material for his particular purpose.
Safety Data SheetAccording to (EC) No 1907/2006 (REACH)
(EU) No 453/2010
SECTION 1: Identification of the substance/mixture and of thecompany/undertaking
Product Name: Kwik-Seal® Fine, Medium, Coarse
Chemical Name Wood fiber blend
Product Use Lost circulation material
Company Kelco Oil Field GroupRegus House1 Berry StreetAberdeen, ScotlandAB25 1HFUK
Tel: +44 1224 843784
Emergency Telephone Number CHEMTREC: +1 800 424 9300 or International +1 703 527 3887In Asia Pacific: +65 6491 9100EU KOFG Phone: +44 (0) 1224 843 784 Aberdeen, Scotland
Internet www.kofg.com
Email [email protected]
SECTION 2: Hazards identificationClassification: EC 1272/2008: Not Classified
EC 1999/45: Not Classified
Label Element(s): None
Signal Word(s): None
SECTION 3: Composition/information on ingredientsChemical Name/CAS EC / REACH EU CLP Classification
Wood, wood fibers, ground hulls or shellsNot applicable
* Not Classified
Synthetic flakesNot applicable
* Not Classified
Regulation (EC) 1907/2006: *Exempt Contact KOFG*Exempt Regulation (EC) 1907/2006:
Issue Date: 24/Jan/2013 Revision Number: 1.1
Wood, wood fibers, ground hulls or shells - Not applicable
SECTION 4: First aid measuresGeneral Advice:Remove material from eyes, skin and clothing.In case of doubt or when symptoms persist, seek medical attention.Wash heavily contaminated clothing before reuse.
Eye contactFlush eye(s) immediately with plenty of water
Skin contactWash off with soap and plenty of water.
IngestionNo significant adverse health effects are expected to develop if only small amounts (less than a mouthful) are swallowed.
InhalationIf large quantities have been inhaled, keep airway open as necessary and seek medical attention
SECTION 5: Firefighting measuresGeneral AdviceTreat as "Class A" fire.. Product will burn when in contact with a flame. Tends to smolder.
Suitable Extinguishing MediaWaterDry chemicalFoam
Unsuitable Extinguishing MediaNone known
Hazardous Combustion ProductsCarbon dioxideCarbon monoxidealdehydesorganic acids
Dust Explosion HazardCan contain sufficient fines to cause a combustible dust explosion. Do not breathe smoke, gases or vapors generated.
Special Protective Equipment for Firefighters:Use personal protective equipment. If necessary, wear self contained breathing apparatus (SCBA) for fire fighting.Equiment should be thoroughly decontaminated after use.
SECTION 6: Accidental release measuresPersonal PrecautionsIn case of exposure to high levels of airborne dust, wear a personal respirator in compliance with national legislation.
Environmental PrecautionsNot expected to cause an environmental hazard as a result of its intended use, disposal, or incineration.
Methods for Cleaning upSweep or vacuum spilled material and repackage After cleaning, flush away traces with water Disposal information -Refer to Section 13.
Page 2 of 7
Revision Number: 1.1Kwik-Seal® Fine, Medium, CoarseCP KELCO Safety Data Sheet
Issue Date: 24/Jan/2013
Other Information:Personal Protection Equipment (PPE) - Refer to Section 8.Disposal - Refer to Section 13
SECTION 7: Handling and storageHandlingHandle in accordance with good industrial hygiene and safety practices.Avoid conditions that generate airborne dust in handling, transfer and clean up.Product may form combustible dust-air mixtures.Avoid contact with eyes and skin. Wear suitable personal protection equipment.Remove material from eyes, skin and clothing.
StorageDry storage.
Specific end uses:Oil field drilling fluid compound
SECTION 8: Exposure controls/personal protectionExposure Controls
Engineering ControlsProvide natural or mechanical ventilation to control exposure levels below airborne exposure limits indicated in thissection. The use of local mechanical exhaust ventilation is preferred at sources of air contamination such as openprocess equipment.
Personal Protective Equipment
Eye ProtectionProtect eyes from exposure.EU: P2 half masksHave eye flushing equipment available.
Skin and Body ProtectionWear appropriate protective clothing.Wash thoroughly after handling.Launder contaminated clothing and clean protective equipment before reuse.
Hand ProtectionGloves are recommended if extended exposure is anticipated.EN 420.
Respiratory ProtectionIf handling generates dust levels which cause irritation, or results in personal exposure exceeding the OccupationalExposure Standard (OES) of 10 mg M-3 (8 hr TWA reference period) for total inhalable dust, then suitableapproved dust respirator should be used.Personal exposure to dust should ideally be controlled to the lowest level possible below the OES. A respirator thatmeets Standard EN 149 type P2, such as 3M8810 or 8210 is recommended.
Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.
Control Parameters
Exposure Limit Values:
Page 3 of 7
Revision Number: 1.1Kwik-Seal® Fine, Medium, CoarseCP KELCO Safety Data Sheet
Issue Date: 24/Jan/2013
Nuisance particles/Nuisance dust:
If not specified dusts are:ACGIH: 10 m/g3 (total dust), 3 mg/m3 (respirable fraction)OSHA PEL: 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction)
SECTION 9: Physical and chemical propertiesAppearance Tan to brownPhysical State Blend of fibrous, flake and granular materialOdor Slight odor (Do not attempt to detect the odor)Odor Threshold No information availablepH Not applicableMelting Point / Range Not applicableBoiling Point Not applicableFreeze Point Not applicableFlash Point Not applicableEvaporation Rate Not applicableFlammability (solid, gas) CombustibleVapor Pressure Not applicableVapor Density Not applicableWater Solubility InsolubleAutoignition Temperature Not applicableOxidizing Properties Not ApplicableFat Solubility Not soluble in fats
SECTION 10: Stability and reactivity
StabilityStable
Conditions to AvoidDust formation.
Materials to avoid (Incompatible Materials)None known
Hazardous Decomposition ProductsCarbon monoxideCarbon dioxide (CO2)aldehydesorganic acidsNitrogen oxidescyanideother products of wood combustion
Wood, wood fibers, ground hulls or shells - Not applicableExposure limitsNot established The creation of aerosols should be avoided.
Revision Number: 1.1
Synthetic flakes - Not applicable
Kwik-Seal® Fine, Medium, Coarse
Exposure limitsNot established The creation of aerosols should be avoided.
CP KELCO Safety Data SheetIssue Date: 24/Jan/2013
Page 4 of 7
SECTION 11: Toxicological informationGeneralThis product contains wood fiber. Wood dust may be present. Toxicological properties include special health effect ofconstituents.
Toxicological Data SourcesData from material suppliers Data from regulations
Potential Health Effects:Eyes Wood dust can cause eye irritation
Skin Wood dust can cause contact dermatitis in sensitized individuals
Inhalation Wood dust is a respiratory irritant. Use approved respirators to avoid breathing wooddust. Avoid prolonged breathing of airborne wood dust.
Ingestion Not toxic if swallowed (less than a mouthful). Based on available information.
SECTION 12: Ecological informationAquatic toxicityThis product is not expected to pose an ecological hazard as a result of its intended use.
Ecotoxicity96-hr LC50 mysid shrimp, in standard drilling mud: >1,000,000 ppm suspended partiulate phase.
Microtox Toxicity: Photobacterium phosphoreum: Non-toxic.
Persistence / DegradabilityThis product is biodegradable.
Bioaccumulative PotentialNo data available
MobilityData not available
Potential environmental effects:Contains no substances known to be hazardous to the environment.
Other Adverse Effects:None known
Carcinogenicity Not listed as a carcinogen.
Revision Number: 1.1Kwik-Seal® Fine, Medium, Coarse
Wood, wood fibers, ground hulls or shells - Not applicable
CP KELCO Safety Data Sheet
Carcinogenicity None of the components of this product at concentrations greater than 0.1% arelisted by IARC, NTP, OSHA or ACGIH as a carcinogen
Issue Date: 24/Jan/2013
Reported Human Effects Repeated exposure over many years to uncontrolled wood dust increases the risk ofnasal cavity cancer. Inhalation of wood dust may also increase the risk of lungfibrosis (scarring). There are also increased risks of respiratory and skinsensitization from wood dust and resin resulting in asthma and dermatitis,respectively
Page 5 of 7
Synthetic flakes - Not applicable
SECTION 13: Disposal considerations
Waste treatment methodsDispose in accordance with local, state and national regulations.
SECTION 14: Transport informationIMDG / IMONot regulatedICAONot regulatedRID/ADRNot regulatedDOTNot regulated
General Information:The data provided in this section is for information only.Please apply the appropriate regulations to properly classify your shipment for transportation.
SECTION 15: Regulatory informationHealth, Safety, and Environmental regulations / legislation for the substance or mixture
Component(s) of the product are on the following Inventory lists:
ChemicalName/CAS
EC / REACH Australia(AICS)
Canada China (IECSC) Japan Korea (KECL) New Zealand(NZIoC)
Philippines(PICCS)
USA (TSCA) Taiwan(ECN)
Wood, woodfibers, groundhulls or shells -Not applicable
* Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt
Synthetic flakes -Not applicable
* Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt*
Exempt
Legend
Present: Listed-: Not Listed*:ExemptNominated
Regulatory and CompendiaRefer to Product Data Sheet
SECTION 16: Other information
Revision Number: 1.1Kwik-Seal® Fine, Medium, CoarseCP KELCO Safety Data Sheet
Issue Date: 24/Jan/2013Page 6 of 7
SECTION 16: Other informationTraining Advice:Personnel handling the substance(s) named in this Safety Data Sheet should be skilled and trained in areas associated with the keypoints named herein.
Personnel should have training and access to appropriate PPE for handling this product.
Personnel handling the substance(s) named in this Safety Data Sheet are responsible for ensuring that appropriate precautions aretaken and for satisfying themselves that the data are suitable and sufficient for the substance(s) intended purpose.
If additional information is required, please contact the supplier or an expert.
Sources of key data:Literature data and/or investigative reports are available through the manufacturer.
Acronym / Abbreviation:ACRONYMS:INTERNATIONAL:ADR: International Carriage of Dangerous Goods by RoadBOD: Biochemical Oxygen DemandCLP: Classification, Labeling and PackagingCOD: Chemical Oxygen DemandD.O.T.: U.S. Department of TransportationICAO International Civil Aviation OrganizationIATA: International Air Transport Association (IATA)IMO::International Maritime Organization.IMDG::International Maritime Dangerous GoodsINCI: International Nomenclature of Cosmetic IngredientsOES: Occupational Exposure StandardOR: EU REACH Only RepresentativePPE: Personal protection equipmentRID: International Carriage by RailSCBA: self contained breathing apparatusTLV-STEL: Threshold Limit Values - Short Term Exposure LimitsTWA: Time Weighted Averages
North America:CERCLA RQ: US EPA Comprehensive Environmental, Response, and Liability Act Reportable QuantityCERCLA: US EPA Comprehensive Environmental Response, Compensation, and Liability Act of 1980CONEG: Conference of North Eastern GovernorsNIOSH/MSHA - National Institute for Occupational Safety and Health/Mine Safety and Health AdministrationSARA: Superfund Amendments and Reauthorization Act (US EPA)TDG: Canada Transport of Dangerous GoodsWHMIS: Canada's Workplace Hazardous Materials Information System
Disclaimer:The information contained in this Safety Data Sheet to the best of CP Kelco's knowledge and belief as of the date indicated is believedto be accurate and reliable. However, no representation, warranty or guarantee is implied or expressed regarding the accuracy,reliability or completeness of this information or the use of the product. Nothing contained herein should be construed as arecommendation to use this product in conflict with National or local regulations or existing patents covering any material or its use. Incase of dispute, the English text governs.
Reason for version:Regulation (EC) 1907/2006: REACH(EU) No 453/2010
and Article 31 or 32
Prepared by:CP Kelco Global Regulatory AffairsEmail: [email protected]
END OF SAFETY DATA SHEET
Issue Date: 24/Jan/2013Page 7 of 7
Revision Number: 1.1Kwik-Seal® Fine, Medium, CoarseCP KELCO Safety Data Sheet
REVISION DATE 07-12-2010 SDS No. 11210
SAFETY DATA SHEET
M-I GEL
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME M-I GEL
APPLICATION Viscosifier
M-I SWACOSUPPLIER
A Schlumberger Company
Woodlands Drive,
Kirkhill Industrial Estate,
Dyce, Aberdeen AB21 0GW.
Scotland UK
T = +44 (0)1224-246600
F = +44 (0)1224-246699
E-mail = [email protected]
EMERGENCY TELEPHONE (24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44
(0) 1235 239 670, Middle East and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001
281 561 1600.
2 HAZARDS IDENTIFICATION
CLASSIFICATION (1999/45) Not classified.
CLASSIFICATION (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
LABEL IN ACCORDANCE WITH (EC) NO. 1272/2008
No pictogram required.
HUMAN HEALTH
This product contains a small quantity of quartz, crystalline silica. IARC Monographs, Vol 68, 1997, concludes that there is sufficient
evidence that inhaled crystalline silica in the form of quartz or crystobalite from occupational sources causes cancer in humans. IARC
classification Group 1. Because of quantity and composition, the health hazard is small.
3 COMPOSITION/INFORMATION ON INGREDIENTS
BENTONITE 60-100%
CAS-No.: 1302-78-9 EC No.: 215-108-5
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
QUARTZ, CRYSTALLINE SILICA 5-10%
CAS-No.: 14808-60-7 EC No.: 238-878-4
Classification (67/548/EEC)
Xn;R48/20.
Classification (EC 1272/2008)
STOT RE 2 - H373
The Full Text for all R-Phrases and Hazard Statements is Displayed in Section 16
COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives. This product contains a small quantity of quartz, crystalline silica. Prolonged
and repeated exposure to concentrations of crystalline silica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease
such as silicosis. Because of quantity and composition, the health hazard is small.
The Full Text for all R-Phrases is
Displayed in Section 16
41 /
REVISION DATE 07-12-2010 SDS No. 11210
M-I GEL
4 FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
INGESTION
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.
SPECIAL FIRE FIGHTING PROCEDURES
Containers close to fire should be removed immediately or cooled with water.
UNUSUAL FIRE & EXPLOSION HAZARDS
High concentrations of dust may form explosive mixture with air.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODS
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
STD STEL - 15 MinTWA - 8 HrsName Notes
0,1 mg/m3WELQUARTZ, CRYSTALLINE SILICA
WEL = Workplace Exposure Limit.
PROTECTIVE EQUIPMENT
PROCESS CONDITIONS
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
42 /
REVISION DATE 07-12-2010 SDS No. 11210
M-I GEL
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists.
HAND PROTECTION
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Powder, dust
COLOUR Cream. to Grey.
ODOUR Odourless.
SOLUBILITY Insoluble in water
RELATIVE DENSITY 2.3 - 2.6
pH-VALUE, CONC. SOLUTION 9 - 10
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
11 TOXICOLOGICAL INFORMATION
INHALATION
Dust in high concentrations may irritate the respiratory system.
INGESTION
May cause discomfort if swallowed.
SKIN CONTACT
Prolonged and frequent contact may cause redness and irritation.
EYE CONTACT
Particles in the eyes may cause irritation and smarting.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
15 REGULATORY INFORMATION
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
NATIONAL REGULATIONS
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
43 /
REVISION DATE 07-12-2010 SDS No. 11210
M-I GEL
INTERNATIONAL CHEMICAL INVENTORIES
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Korea (TCCL / ECL), New Zealand (NZIoC),
Phillipines (PICCS), United States (TSCA).
New Zealand Hazard Classification and HSNO Approval No.
Not Classified. HSNO Approval No. Not Required.
Name of Group Standard and Information on Conditions of Group Standard
Not applicable.
16 OTHER INFORMATION
INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
REVISION COMMENTS
Updated according to CLP. Compiled or Revised by Ewan MacLeod
ISSUED BY
Bill Cameron
REVISION DATE 07-12-2010
REV. NO./REPL. SDS
GENERATED
4
SDS NO. 11210
RISK PHRASES IN FULL
Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/20
Not classified.NC
HAZARD STATEMENTS IN FULL
May cause damage to organs <<Organs>> through prolonged or repeated exposure.H373
DISCLAIMER
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
44 /
Revision Date 27-Aug-12
Revision 1
Supersedes date 28-Feb-12
SDS No. 15397
SAFETY DATA SHEET
M-I WATE* (ALL GRADES)
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name M-I WATE* (ALL GRADES)
Synonyms, Trade Names M-I WATE*, M-I WATE* ULTRA FINE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Weighting agent.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive,
Kirkhill Industrial Estate,
Dyce, Aberdeen AB21 0GW.
Scotland UK
T = +44 (0)1224-246600
F = +44 (0)1224-246699
E-mail = [email protected]
Contact Person [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East
and Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (1999/45/EEC) Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Human health
This product contains a small quantity of quartz, crystalline silica. IARC Monographs, Vol 68, 1997, concludes that there is sufficient
evidence that inhaled crystalline silica in the form of quartz or crystobalite from occupational sources causes cancer in humans. IARC
classification Group 1. Because of quantity and composition, the health hazard is small.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
61 /
SDS No. 15397
M-I WATE* (ALL GRADES)
BARITE (Ba(SO4)) 60-100%
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
QUARTZ, CRYSTALLINE SILICA 5-10%
CAS-No.: 14808-60-7 EC No.: 238-878-4
Classification (67/548/EEC)
Xn;R48/20.
Classification (EC 1272/2008)
STOT RE 2 - H373
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives. Barite is a naturally occurring mineral. This product contains a small quantity
of quartz, crystalline silica. Prolonged and repeated exposure to concentrations of crystalline silica exceeding the workplace exposure limit
(WEL) may lead to chronic lung disease such as silicosis. Because of quantity and composition, the health hazard is small.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop
as described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
62 /
SDS No. 15397
M-I WATE* (ALL GRADES)
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
STD STEL - 15 MinTWA - 8 HrsName Notes
0,1 mg/m3WELQUARTZ, CRYSTALLINE SILICA
WEL = Workplace Exposure Limit.
QUARTZ, CRYSTALLINE SILICA (CAS: 14808-60-7)
DNEL
Inhalation. Short Term Local Effects 4 mg/m³
Inhalation. Long Term Local Effects 1 mg/m³
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and
the risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated
with this product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such
further assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace
and should be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
Respiratory protection must be used if air contamination exceeds acceptable level. Dust filter P3 (for especially fine dust/powder).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Nitrile. or Neoprene.
63 /
SDS No. 15397
M-I WATE* (ALL GRADES)
Eye protection
Wear dust resistant safety goggles where there is danger of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Promptly remove
any clothing that becomes wet or contaminated.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Powder, dust
Colour Tan to Grey.
Odour Odourless.
Solubility Insoluble in water
Melting point (°C) 1580°C
Relative density 4.1 s.g 20°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Avoid heat, flames and other sources of ignition.
10.5. Incompatible materials
Materials To Avoid
Not known.
10.6. Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Particles in the eyes may cause irritation and smarting.
64 /
SDS No. 15397
M-I WATE* (ALL GRADES)
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
OSPAR have defined this chemical as PLONOR. Contact M-I SWACO's QHSE Department for ecological information at
[email protected]. Barite is a naturally occurring mineral.
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is insoluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
65 /
SDS No. 15397
M-I WATE* (ALL GRADES)
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
Guidance Notes
REACH. With respect to minerals, Article 2 § 7(b) and Annex V point 7 explicitily exempt from registration and evaluation "minerals which
occur in nature, if they are not chemically modified." This product is exempt from registration.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
Not hazardous to Water.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health -1 HMIS Flammability - 0 HMIS Physical Hazard - 0 E - Safety glasses, Gloves, Dust Respirator
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or revised by Sandra McWilliam
Issued By Bill Cameron
Revision Date 27-Aug-12
Revision 1
Supersedes date 28-Feb-12
SDS No. 15397
Risk Phrases In Full
Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/20
Not classified.NC
Hazard Statements In Full
May cause damage to organs <<Organs>> through prolonged or repeated exposure.H373
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
66 /
REVISION DATE: 08-12-10 SDS NO.: 11128
SAFETY DATA SHEET
NUT SHELLS (All Grades)
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
PRODUCT NAME NUT SHELLS (All Grades)
APPLICATION Lost circulation material.
M-I SWACOSUPPLIER
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail =
EMERGENCY TELEPHONE (24 Hour) Europe +44 (0) 1235 239 670, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Middle
East and Africa +44 (0) 1235 239 671, Australia +61 2801 44558.
2 HAZARDS IDENTIFICATION
CLASSIFICATION (EC 1272/2008)
Physical Not classified.
Health Not classified.
Environmental Not classified.
3 COMPOSITION/INFORMATION ON INGREDIENTS
NUT SHELLS 60-100%
CAS-No.: EC No.:
CLASSIFICATION (67/548)
-
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16
COMPOSITION COMMENTS
The data shown is in accordance with the latest EC Directives.
4 FIRST-AID MEASURES
INHALATION
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
INGESTION
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues.
SKIN CONTACT
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
EYE CONTACT
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
Use fire-extinguishing media appropriate for surrounding materials.
41 /
REVISION DATE: 08-12-10 SDS NO.: 11128
NUT SHELLS (All Grades)
SPECIAL FIRE FIGHTING PROCEDURES
Containers close to fire should be removed immediately or cooled with water.
UNUSUAL FIRE & EXPLOSION HAZARDS
High concentrations of dust may form explosive mixture with air.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
ENVIRONMENTAL PRECAUTIONS
Do not allow to enter drains, sewers or watercourses.
SPILL CLEAN UP METHODS
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. In case of
spills, beware of slippery floors and surfaces.
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry, cool and well-ventilated place.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
INGREDIENT COMMENTS
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
PROTECTIVE EQUIPMENT
ENGINEERING MEASURES
Provide adequate general and local exhaust ventilation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection must be used if the general level exceeds the recommended occupational
exposure limit. Dust filter P3 (for especially fine dust/powder).
HAND PROTECTION
Gloves are recommended for prolonged use. Rubber or plastic.
EYE PROTECTION
Wear approved chemical safety goggles where eye exposure is reasonably probable.
OTHER PROTECTION
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Powder, dust Granular Solid
COLOUR Brown
ODOUR Odourless
SOLUBILITY Insoluble in water
BULK DENSITY 1200 - 1400 kg/m3 PARTICLE SIZE (Micron) 0 - 4000 μm
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions and recommended use.
CONDITIONS TO AVOID
Avoid heat, flames and other sources of ignition. Avoid contact with: Water, moisture.
42 /
REVISION DATE: 08-12-10 SDS NO.: 11128
NUT SHELLS (All Grades)
11 TOXICOLOGICAL INFORMATION
INHALATION
Dust in high concentrations may irritate the respiratory system.
INGESTION
May cause discomfort if swallowed.
SKIN CONTACT
Prolonged and frequent contact may cause redness and irritation.
EYE CONTACT
Particles in the eyes may cause irritation and smarting.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
WATER HAZARD CLASSIFICATION
WGK 1
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
GENERAL The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
15 REGULATORY INFORMATION
UK REGULATORY REFERENCES
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU DIRECTIVES
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
INTERNATIONAL CHEMICAL INVENTORIES
Contact [email protected] for REACH information.
16 OTHER INFORMATION
INFORMATION SOURCES
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
REVISION COMMENTS
Updated according to CLP. Compiled or Revised by Ewan MacLeod
ISSUED BY
Bill Cameron
REVISION DATE 08-12-10
REV. NO./REPL. SDS GENERATED 4
SDS NO. 11128
RISK PHRASES IN FULL
Not classified.NC
43 /
REVISION DATE: 08-12-10 SDS NO.: 11128
NUT SHELLS (All Grades)
DISCLAIMER
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
44 /
Revision Date 21-06-11
Revision 6
Supersedes date 03-07-09
SDS No. 10844
SAFETY DATA SHEET
POLYPAC* (All Grades)
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name POLYPAC* (All Grades)
Synonyms, Trade Names POLYPAC ELV, R, UL & POLYPAC SUPREME R, UL .
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Fluid loss control
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive,
Kirkhill Industrial Estate,
Dyce, Aberdeen AB21 0GW.
Scotland UK
T = +44 (0)1224-246600
F = +44 (0)1224-246699
E-mail = [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (67/548/EEC) Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
61 /
SDS No. 10844
POLYPAC* (All Grades)
POLYANIONIC CELLULOSE 60-100%
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
None known.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
62 /
SDS No. 10844
POLYPAC* (All Grades)
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water. In case of
spills, beware of slippery floors and surfaces.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Keep away from heat, sparks and open
flame.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Take precautionary measures against static discharges.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Granular Powder, dust
Colour White / off-white.
Odour Odourless.
63 /
SDS No. 10844
POLYPAC* (All Grades)
Solubility Soluble in water.
Relative density 1.5 - 1.6 @ 25 °C
Bulk Density 400 - 880 kg/m3
pH-Value, Diluted Solution 6.5 - 9.5 @ 1 %
Decomposition temperature (°C) > 230°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use. The substance is hygroscopic and will absorb water by contact with the
moisture in the air.
10.3. Possibility of hazardous reactions
Hazardous Polymerisation
Will not polymerise.
10.4. Conditions to avoid
The substance is hygroscopic and will absorb water by contact with the moisture in the air.
10.5. Incompatible materials
Materials To Avoid
Strong oxidising substances.
10.6. Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed. Fire or high temperatures create: Vapours/gases/fumes of: Carbon
monoxide (CO). Carbon dioxide (CO2). Na2O Na2CO3
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
27000 mg/kg Rat
Acute Toxicity (Dermal LD50)
2000 mg/kg Rabbit
Acute Toxicity (Inhalation LC50)
4 hours 5800 mg/l (dust/mist) Rat
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged contact may cause redness, irritation and dry skin.
Eye contact
Particles in the eyes may cause irritation and smarting.
64 /
SDS No. 10844
POLYPAC* (All Grades)
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability
The product is slowly degradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product is not bioaccumulating.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
EWC-Code: 16 03 06
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
65 /
SDS No. 10844
POLYPAC* (All Grades)
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
Water hazard classification
WGK 1
New Zealand Hazard Classification and HSNO Approval No.
Not Classified. HSNO Approval No. Not Required.
Name of Group Standard and Information on Conditions of Group Standard
Not applicable.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By Bill Cameron
Revision Date 21-06-11
Revision 6
Supersedes date 03-07-09
SDS No. 10844
Risk Phrases In Full
Not classified.NC
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
66 /
Revision Date 26-Feb-13
Revision 6
Supersedes date 10-Aug-10
SDS No. 10064
SAFETY DATA SHEET
POTASSIUM CHLORIDE BRINE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name POTASSIUM CHLORIDE BRINE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Drilling fluid additive Completion Brine
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Not classified.
2.2. Label elements
Risk Phrases
NC Not classified.
Safety Phrases
NC Not classified.
Australian statement of hazardous/dangerous nature
Classified as Non-Hazardous according to the criteria of NOHSC.
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
71 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
POTASSIUM CHLORIDE 5-30%
CAS-No.: 7447-40-7 EC No.: 231-211-8
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Fire or high temperatures create: Vapours/gases/fumes of: Chlorides.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
72 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel into
dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Good personal hygiene is necessary. Wash hands and
contaminated areas with water and soap before leaving the work site. Remove contaminated clothing. Do not eat, drink or smoke when using
the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Bulk storage:This product should be stored in a cool dry,
well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
No biological limit allocated.
POTASSIUM CHLORIDE (CAS: 7447-40-7)
DNEL
Industry Dermal Short Term Systemic Effects 910 mg/kg/day
Industry Inhalation. Short Term Systemic Effects 5320 mg/m3
Industry Dermal Long Term Systemic Effects 303 mg/kg/day
Industry Inhalation. Long Term Systemic Effects 1064 mg/m3
PNEC
Freshwater 0.1 mg/l
Marinewater 0.1 mg/l
Intermittent release 1 mg/l
STP 10 mg/l
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with inorganic vapour cartridge (Grey B).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Rubber gloves are recommended.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
73 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Colourless.
Odour Odourless.
Solubility Soluble in water.
Initial boiling point and boiling range
(°C)
102°C
Melting point (°C) -7°C
Relative density 1.08 - 1.57 s.g (8.33 - 9.7 lb/gal)
pH-Value, Conc. Solution ~7
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with: Strong oxidising substances. Strong acids. Strong alkalis.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Chlorides.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion
May cause discomfort if swallowed. Gastrointestinal symptoms, including upset stomach.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
74 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Toxicity - Fish
LC50 96 hours 1060 mg/l Lepomis macrochirus (Bluegill)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 825 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
EC50 72 hours 2500 mg/l
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
EWC-code: 06 03 14 Waste number: 7097. Inorganic solutions and liquids.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID). and (ADG).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
75 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
The product has been assessed and contained in Chapters 17 and 18 of the IBC Code and the latest MEPC.2/Circular and is permitted to be
carried under Annex II of MARPOL and resolution A.673 (16) Offshore Supply Vessel Code. Ship Type:- 3. Pollution Category:- Z. Please
contact [email protected] for info regarding transport in Bulk.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
Water hazard classification
WGK 1
Australian Standard for the Uniform Scheduling of Drugs and Poisons
No Poisons Schedule number allocated.
Australian Regulations
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)]. National Occupational Health
and Safety Commission’s Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004) 3rd Edition]. National Occupational
Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in the occupational Environment [NOHSC:1003 (1995)].
Safe Work Australia. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). ADG Code – Australian Dangerous Goods Code.
15.2. Chemical Safety Assessment
International Chemical Inventories
This product is exempt from REACH registration according to EC Regulation 1907/2006 Article 2 § 7 b and Annex V, point 7. Contact
[email protected] for REACH information. Complies with the following national/regional chemical inventory requirements: Australia
(AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New Zealand
(NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information). MARPOL 73/78. Marine Environment Protection Committee (MEPC) Circulars.
MEPC.2 MEPC 54/10/4. IBC Code. IMO Resolution A.673 (16), Guidelines for the Transport and Handling of Limited Amounts of Hazardous
and Noxious Liquid Substances in Bulk Offshore Support Vessels.
Revision Comments
General revision.
Issued By Sandra McWilliam
Revision Date 26-Feb-13
Revision 6
Supersedes date 10-Aug-10
SDS No. 10064
Safety Data Sheet Status Approved.
Date 26-Feb-13
Signature Kirsty Walker
Signature 2 Nina Øvrehus
Risk Phrases In Full
Not classified.NC
76 /
SDS No. 10064
POTASSIUM CHLORIDE BRINE
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
77 /
Revision Date 26-Feb-13
Revision 4
Supersedes date 06-Apr-11
SDS No. 10857
SAFETY DATA SHEET
POTASSIUM CHLORIDE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name POTASSIUM CHLORIDE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Oil well drilling fluid additive. Oil well completion fluid additive.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (67/548/EEC) Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
Australian statement of hazardous/dangerous nature
Classified as Non-Hazardous according to the criteria of NOHSC.
NON-HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
71 /
SDS No. 10857
POTASSIUM CHLORIDE
POTASSIUM CHLORIDE 60-100%
CAS-No.: 7447-40-7 EC No.: 231-211-8
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Fire or high temperatures create: Vapours/gases/fumes of: Chlorides.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
72 /
SDS No. 10857
POTASSIUM CHLORIDE
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Provide good ventilation. Good personal
hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site. Remove contaminated clothing.
Do not eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
No biological limit allocated.
POTASSIUM CHLORIDE (CAS: 7447-40-7)
DNEL
Industry Dermal Short Term Systemic Effects 910 mg/kg/day
Industry Inhalation. Short Term Systemic Effects 5320 mg/m3
Industry Dermal Long Term Systemic Effects 303 mg/kg/day
Industry Inhalation. Long Term Systemic Effects 1064 mg/m3
PNEC
Freshwater 0.1 mg/l
Marinewater 0.1 mg/l
Intermittent release 1 mg/l
STP 10 mg/l
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate ventilation. Observe occupational exposure limits and minimize the risk of inhalation of dust.
Respiratory equipment
If ventilation is insufficient, suitable respiratory protection must be provided. Use respiratory equipment with particle filter, type P2.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Rubber gloves are recommended.
Eye protection
Wear dust resistant safety goggles where there is danger of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
73 /
SDS No. 10857
POTASSIUM CHLORIDE
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Powder, dust
Colour White to Pale Pink.
Odour Odourless.
Solubility Soluble in water.
Initial boiling point and boiling range
(°C)
1406-1413°C
Melting point (°C) 768-773°C
Relative density 1.98 @ 20°C
pH-Value, Diluted Solution ~ 7 @ 1%
Solubility Value (G/100G
H2O@20°C)
37
Partition Coefficient
(N-Octanol/Water)
-3.0
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Avoid wet and humid conditions.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with: Strong oxidising substances. Strong acids. Strong alkalis.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Chlorides.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
2600 mg/kg Rat
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed. Gastrointestinal symptoms, including upset stomach.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
74 /
SDS No. 10857
POTASSIUM CHLORIDE
Eye contact
Particles in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected]. OSPAR have defined this chemical as
PLONOR. This is a naturally occurring mineral.
12.1. Toxicity
Acute Toxicity - Fish
LC50 96 hours 1060 mg/l Lepomis macrochirus (Bluegill)
Acute Toxicity - Aquatic Invertebrates
EC50 48 hours 825 mg/l Daphnia magna
Acute Toxicity - Aquatic Plants
EC50 72 hours 2500 mg/l
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
Partition coefficient -3.0
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
EWC-code: 06 03 14 Waste number: 7091 Inorganic salts and other solids.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID). and (ADG).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
75 /
SDS No. 10857
POTASSIUM CHLORIDE
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable. Please contact [email protected] for info regarding transport in Bulk.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
Water hazard classification
WGK 1
Australian Standard for the Uniform Scheduling of Drugs and Poisons
No Poisons Schedule number allocated.
New Zealand Hazard Classification and HSNO Approval No.
HSR003261
Name of Group Standard and Information on Conditions of Group Standard
Information such as HSNO number and group standard have been added to fulfill the requirements for NZ regulations. As this product conforms
to current EU regulations, it contains the required information to comply with the conditions of the stated group standard.
Australian Regulations
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)]. National Occupational Health
and Safety Commission’s Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004) 3rd Edition]. National Occupational
Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in the occupational Environment [NOHSC:1003 (1995)].
Safe Work Australia. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). ADG Code – Australian Dangerous Goods Code.
15.2. Chemical Safety Assessment
International Chemical Inventories
This product is exempt from REACH registration according to EC Regulation 1907/2006 Article 2 § 7 b and Annex V, point 7. Contact
[email protected] for REACH information. Complies with the following national/regional chemical inventory requirements: Australia
(AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New Zealand
(NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
General information
HMIS Health -1 HMIS Flammability - 0 HMIS Physical Hazard - 0 E - Safety glasses, Gloves, Dust Respirator
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision.
Issued By Sandra McWilliam
Revision Date 26-Feb-13
76 /
SDS No. 10857
POTASSIUM CHLORIDE
Revision 4
Supersedes date 06-Apr-11
SDS No. 10857
Safety Data Sheet Status Approved.
Date 26-Feb-13
Signature Sarah Malone
Signature 2 Nina Øvrehus
Risk Phrases In Full
Not classified.NC
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
77 /
Revision Date 11/01/2011
Revision 6
SDS No. 11713
SAFETY DATA SHEET
SAFE-CARB (All Grades)
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name SAFE-CARB (All Grades)
Synonyms, Trade Names SAFE-CARB 2, 10, 20, 25, 40, 250, 500, 600, 750, 1400 and 2500.
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Weighting agent. Lost circulation material. Bridging material.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (1999/45/EEC) Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Human health
This product contains a small quantity of quartz, crystalline silica. IARC Monographs, Vol 68, 1997, concludes that there is sufficient
evidence that inhaled crystalline silica in the form of quartz or crystobalite from occupational sources causes cancer in humans. IARC
classification Group 1. Because of quantity and composition, the health hazard is small.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
2.3. Other hazards
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
61 /
SDS No. 11713
SAFE-CARB (All Grades)
CALCIUM CARBONATE 60-100%
CAS-No.: 471-34-1 EC No.: 207-439-9
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
QUARTZ, CRYSTALLINE SILICA <1%
CAS-No.: 14808-60-7 EC No.: 238-878-4
Classification (67/548/EEC)
Xn;R48/20.
Classification (EC 1272/2008)
STOT RE 2 - H373
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives. This product contains a small quantity of quartz, crystalline silica. Prolonged
and repeated exposure to concentrations of crystalline silica exceeding the workplace exposure limit (WEL) may lead to chronic lung disease
such as silicosis. Because of quantity and composition, the health hazard is small.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
Specific hazards
During fire, toxic gases (CO, CO2) are formed.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
62 /
SDS No. 11713
SAFE-CARB (All Grades)
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
STD STEL - 15 MinTWA - 8 HrsName Notes
0,1 mg/m3WELQUARTZ, CRYSTALLINE SILICA
WEL = Workplace Exposure Limit.
CALCIUM CARBONATE (CAS: 471-34-1)
DNEL
Inhalation. Long Term Systemic Effects 10 mg/m3
PNEC
STP 100 mg/l
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Dust filter P3 (for especially fine dust/powder).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
63 /
SDS No. 11713
SAFE-CARB (All Grades)
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Promptly remove any
clothing that becomes wet or contaminated.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Powder, dust
Colour White / off-white.
Odour Odourless.
Solubility Insoluble in water
Relative density 2.7 - 2.9
pH-Value, Diluted Solution 8.5 - 9.5 @ 100g/l
Decomposition temperature (°C) 825°C
9.2. Other information
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
10.5. Incompatible materials
10.6. Hazardous decomposition products
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhalation
Dust in high concentrations may irritate the respiratory system.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Particles in the eyes may cause irritation and smarting.
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
12.2. Persistence and degradability
12.3. Bioaccumulative potential
12.4. Mobility in soil
64 /
SDS No. 11713
SAFE-CARB (All Grades)
12.5. Results of PBT and vPvB assessment
12.6. Other adverse effects
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
14.2. UN proper shipping name
14.3. Transport hazard class(es)
14.4. Packing group
14.5. Environmental hazards
14.6. Special precautions for user
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
Water hazard classification
WGK 0
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Updated according to CLP. Compiled or Revised by Ewan MacLeod
Issued By Bill Cameron
Revision Date 11/01/2011
Revision 6
SDS No. 11713
65 /
SDS No. 11713
SAFE-CARB (All Grades)
Risk Phrases In Full
Harmful: danger of serious damage to health by prolonged exposure through inhalation.R48/20
Not classified.NC
Hazard Statements In Full
May cause damage to organs <<Organs>> through prolonged or repeated exposure.H373
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
66 /
Revision Date 01-11-11
Revision 8
Supersedes date 13-07-11
SDS No. 10707
SAFETY DATA SHEET
SAFE-CIDE*
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name SAFE-CIDE*
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Biocide
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive,
Kirkhill Industrial Estate,
Dyce, Aberdeen AB21 0GW.
Scotland UK
T = +44 (0)1224-246600
F = +44 (0)1224-246699
E-mail = [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
National Emergency Telephone Number
+31 (0)30-2748888 Only for the purpose of informing medical personnel in cases of acute intoxications in the Netherlands.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Acute Tox. 4 - H302;Acute Tox. 2 - H330;Skin Sens. 1 - H317
Environment Not classified.
Classification (1999/45/EEC) T;R23. Xn;R22. R43.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Contains 2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL
Label In Accordance With (EC) No. 1272/2008
Signal Word Danger
Hazard Statements
H302 Harmful if swallowed.
H317 May cause an allergic skin reaction.
H330 Fatal if inhaled.
Precautionary Statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
81 /
SDS No. 10707
SAFE-CIDE*
P310 Immediately call a POISON CENTER or doctor/physician.
P501A Dispose of waste and residues in accordance with local authority requirements.
This material and its container must be disposed of as a hazardous waste.
Supplementary Precautionary Statements
P261 Avoid breathing vapour/spray.
P363 Wash contaminated clothing before reuse.
P405 Store locked up.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL 60-100%
CAS-No.: 4719-04-4 EC No.: 225-208-0
Classification (67/548/EEC)
T;R23.
Xn;R22.
R43.
Classification (EC 1272/2008)
Acute Tox. 4 - H302
Acute Tox. 2 - H330
Skin Sens. 1 - H317
2-AMINOETHANOL 1-5%
CAS-No.: 141-43-5 EC No.: 205-483-3
Classification (67/548/EEC)
C;R34
Xn;R20/21/22
Classification (EC 1272/2008)
Acute Tox. 4 - H302
Acute Tox. 4 - H312
Acute Tox. 4 - H332
Skin Corr. 1B - H314
STOT SE 3 - H335
ETHYLENDIAMINOTETRAACETIC ACID, TETRASODIUM SALT 1-5%
CAS-No.: 64-02-8 EC No.: 200-573-9
Classification (67/548/EEC)
Xn;R22.
Xi;R36.
Classification (EC 1272/2008)
Acute Tox. 4 - H302
Eye Irrit. 2 - H319
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention.
82 /
SDS No. 10707
SAFE-CIDE*
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
Inhalation
Toxic by inhalation.
Ingestion
Harmful if swallowed.
Skin contact
May cause sensitisation by skin contact.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Sulphurous gases (SOx).
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel into
dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
83 /
SDS No. 10707
SAFE-CIDE*
8.1. Control parameters
STD STEL - 15 MinTWA - 8 HrsName Notes
1 ppm 2,5 mg/m3WEL 3 ppm 7,6 mg/m32-AMINOETHANOL Sk
WEL = Workplace Exposure Limit.
Sk = Can be absorbed through skin.
2,2',2''-(HEXAHYDRO-1,3,5-TRIAZINE-1,3,5-TRIYL)TRIETHANOL (CAS: 4719-04-4)
DNEL
Inhalation. Long Term Systemic Effects 19 mg/m³
PNEC
Freshwater 0.006mg/L
Marinewater 0.00066mg/L
Soil 0.00219mg/kg
STP 5.5mg/L
Sediment (Freshwater) 0.0172mg/kg
Sediment (Marinewater) 0.00172mg/kg
Intermittent release 0.66mg/L
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
Wear suitable respiratory protection. A minimum of a chemical respirator with organic vapour cartridge should be worn. If there are conditions in
which this triazine containing product produces a vapor, a chemical respirator with A1 +Formaldehyde and P2 particulate pre-filter combination
would be required.
Hand protection
Chemical resistant gloves required for prolonged or repeated contact. Use protective gloves made of: Nitrile. or Neoprene.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash hands after handling. Promptly remove any
clothing that becomes wet or contaminated.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Colourless to pale yellow.
Odour Characteristic.
Solubility Miscible with water
Initial boiling point and boiling range
(°C)
>100°C
Relative density 1.14 - 1.18g/cm3 @ 20°C
Vapour pressure 14.8 hPa @ 20°C
pH-Value, Diluted Solution 9.5-11.5 @ 1%
Viscosity 1850mPas @ 20°C
84 /
SDS No. 10707
SAFE-CIDE*
Flash point (°C) 68°C
Auto Ignition Temperature (°C) >200°C
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Not known.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with acids. Avoid contact with strong oxidisers. Avoid contact with strong reducing agents.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Carbon monoxide (CO). Carbon dioxide (CO2). Nitrous gases (NOx).
Sulphurous gases (SOx).
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Toxicological information
This product may contain or release trace amounts of formaldehyde. The International Agency for Research on Cancer (IARC) has classified
formaldehyde as a Group 1carcinogen(limited evidence in humans, sufficient evidence in animals). exposure to formaldehyde has been linked
to adverse reproductive effects in some human and animal studies. In other reproductive studies, however, no adverse effects were noted.
(Meditext). Formaldehyde may also cause skin and respiratory sensitisation (allergic reaction).
Acute toxicity:
Acute Toxicity (Oral LD50)
1400 mg/kg Rat
Acute Toxicity (Inhalation LC50) 0.371
mg/l 4h. Method - Aerosol.
Aspiration hazard:
Toxic by inhalation.
Inhalation
Toxic by inhalation.
Ingestion
Harmful if swallowed.
Skin contact
May cause sensitisation by skin contact.
Eye contact
Irritating to eyes.
Route of entry
No route of entry noted.
85 /
SDS No. 10707
SAFE-CIDE*
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
Acute Toxicity - Fish
LC50 96 hours > 100 mg/l Brachydanio rerio (Zebra Fish)
EC 50, 48 Hrs, Daphnia, mg/l > 100 mg/l
IC 50, 72 Hrs, Algae, mg/l 10-100 mg/l
12.2. Persistence and degradability
Degradability
The product is biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
No data available.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements. This material and
its container must be disposed of as hazardous waste.
SECTION 14: TRANSPORT INFORMATION
14.1. UN number
UN No. (ADR/RID/ADN) 2810
UN No. (IMDG) 2810
UN No. (ICAO) 2810
14.2. UN proper shipping name
Proper Shipping Name TOXIC LIQUID, ORGANIC, N.O.S. (2, 2', 2"-(hexahydro -1, 3, 5-triazine -1, 3, 5-triyl) triethanol)
14.3. Transport hazard class(es)
ADR/RID/ADN Class 6.1
ADR/RID/ADN Class Class 6.1:Toxic substances.
IMDG Class 6.1
ICAO Class/Division 6.1
Transport Labels
86 /
SDS No. 10707
SAFE-CIDE*
6
TOXIC
14.4. Packing group
ADR/RID/ADN Packing group II
IMDG Packing group II
ICAO Packing group II
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
EMS F-A, S-A
Emergency Action Code 2X
Hazard No. (ADR) 60
Tunnel Restriction Code (D/E)
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
National Regulations
In accordance with Dutch Mining Regulation 9.2 and ARBO regulation Chapter 4.
New Zealand Hazard Classification and HSNO Approval No.
Classified. HSNO: 6.1B, 6.1D, 6.5B, HSR002625
Name of Group Standard and Information on Conditions of Group Standard
N.O.S. (Toxic [6.1, 6.7]) Group Standard 2006 Information such as HSNO number and group standard have been added to fulfill the
requirements for NZ regulations. As this product conforms to current EU regulations, it contains the required information to comply with the
conditions of the stated group standard.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
*a mark of M-I L.L.C.
General information
HMIS Health - 3 HMIS Flammability - 1 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour Respirator.
87 /
SDS No. 10707
SAFE-CIDE*
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
Classification updated. The following sections have been revised: 11, Compiled or revised by Sandra McWilliam
Issued By Bill Cameron
Revision Date 01-11-11
Revision 8
Supersedes date 13-07-11
SDS No. 10707
Risk Phrases In Full
Causes burns.R34
Harmful by inhalation, in contact with skin and if swallowed.R20/21/22
Harmful if swallowed.R22
Irritating to eyes.R36
Irritating to respiratory system.R37
May cause sensitisation by skin contact.R43
Toxic by inhalation.R23
Hazard Statements In Full
Causes serious eye irritation.H319
Causes severe skin burns and eye damage.H314
Fatal if inhaled.H330
Harmful if inhaled.H332
Harmful if swallowed.H302
Harmful in contact with skin.H312
May cause an allergic skin reaction.H317
May cause respiratory irritation.H335
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
88 /
Revision Date 21-03-13
Revision 4
Supersedes date 13-03-08
SDS No. 11693
SAFETY DATA SHEET
SODA ASH
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name SODA ASH
Synonyms, Trade Names SODIUM CARBONATE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses pH modifier.
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Eye Irrit. 2 - H319
Environment Not classified.
Classification (1999/45/EEC) Xi;R36.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Contains SODIUM CARBONATE
Label In Accordance With (EC) No. 1272/2008
Signal Word Warning
Hazard Statements
H319 Causes serious eye irritation.
Precautionary Statements
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P337+313 If eye irritation persists: Get medical advice/attention.
71 /
SDS No. 11693
SODA ASH
Supplementary Precautionary Statements
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P264 Wash contaminated skin thoroughly after handling.
Australian statement of hazardous/dangerous nature
Classified as Hazardous according to the criteria of NOHSC.
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
SODIUM CARBONATE 60-100%
CAS-No.: 497-19-8 EC No.: 207-838-8
Classification (67/548/EEC)
Xi;R36
Classification (EC 1272/2008)
Eye Irrit. 2 - H319
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. Place unconscious person on the side in the recovery position and ensure breathing can take
place. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort continues.
Ingestion
Do not induce vomiting. Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if
any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention immediately. Continue to rinse.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
Fire or high temperatures create: Carbon monoxide (CO). Carbon dioxide (CO2). Oxides of: Sodium.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
72 /
SDS No. 11693
SODA ASH
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid generating excess dust. Avoid contact with acids.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid inhalation of dust and contact with skin and eyes. Avoid handling which leads to dust formation. Avoid contact with water. Avoid contact
with acids. Good personal hygiene is necessary. Wash hands and contaminated areas with water and soap before leaving the work site.
Remove contaminated clothing. Do not eat, drink or smoke when using the product.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid contact with acids.
Storage Class
Chemical storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
No biological limit allocated.
SODIUM CARBONATE (CAS: 497-19-8)
DNEL
Inhalation. Long Term Local Effects 10 mg/m³
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
73 /
SDS No. 11693
SODA ASH
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Wear mask supplied with: Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Use protective gloves made of: Neoprene. or Rubber gloves are
recommended.
Eye protection
Wear dust resistant safety goggles where there is danger of eye contact.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Powder, dust
Colour White.
Odour Odourless.
Solubility Completely soluble in water
Melting point (°C) 851°C (1564°F)
Relative density 2.53 s.g @ 20°C
pH-Value, Conc. Solution > 12 @ 10g/l
Solubility Value (G/100G
H2O@20°C)
26g
Decomposition temperature (°C) > 400°C (752°F)
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
Reacts violently with strong acids. Carbon dioxide (CO2). may be formed.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
Avoid contact with: Water, moisture.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with acids.
10.6. Hazardous decomposition products
Thermal decomposition or combustion may liberate carbon oxides and other toxic gases or vapours.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
2800 mg/kg Rat
Acute Toxicity (Dermal LD50)
> 2000 mg/kg Rat
Acute Toxicity (Inhalation LC50)
2300 Rat
74 /
SDS No. 11693
SODA ASH
Serious eye damage/irritation:
Irritating to eyes.
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May irritate and cause stomach pain, vomiting and diarrhoea.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Irritating to eyes. Particles in the eyes may cause irritation and smarting.
Route of entry
Skin and/or eye contact.
Target Organs
Eyes
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected]. OSPAR have defined this chemical as
PLONOR.
12.1. Toxicity
LC 50, 96 Hrs, Fish mg/l 300
EC 50, 48 Hrs, Daphnia, mg/l 265
12.2. Persistence and degradability
Degradability
The product solely consists of inorganic compounds which are not biodegradable.
12.3. Bioaccumulative potential
Bioaccumulative potential
The product is not bioaccumulating.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
The definitive European Waste code for this product will depend upon the final use that is made of this material. EWC-code: 06 02 05 Waste
number: 7091 Inorganic salts and other solids.
SECTION 14: TRANSPORT INFORMATION
75 /
SDS No. 11693
SODA ASH
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID). and (ADG).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable. Please contact [email protected] for info regarding transport in Bulk.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
Australian Standard for the Uniform Scheduling of Drugs and Poisons
No Poisons Schedule number allocated.
Australian Regulations
National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011 (2003)]. National Occupational Health
and Safety Commission’s Approved Criteria for Classifying Hazardous Substances [NOHSC:1008 (2004) 3rd Edition]. National Occupational
Health and Safety Commission’s Exposure Standards for Atmospheric Contaminants in the occupational Environment [NOHSC:1003 (1995)].
Safe Work Australia. Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP). ADG Code – Australian Dangerous Goods Code.
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
General information
HMIS Health -1 HMIS Flammability - 1 HMIS Physical Hazard - 0 E - Safety glasses, Gloves, Dust Respirator
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
76 /
SDS No. 11693
SODA ASH
Revision Comments
General revision. Updated according to CLP. Updated according to REACH Annex II.
Issued By Sandra McWilliam
Revision Date 21-03-13
Revision 4
Supersedes date 13-03-08
SDS No. 11693
Safety Data Sheet Status Approved.
Date 22-03-13
Signature Laura McDonald
Signature 2 Nina Øvrehus
Risk Phrases In Full
Irritating to eyes.R36
Hazard Statements In Full
Causes serious eye irritation.H319
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
77 /
Sodium Acid Pyro PhosphateSafety Data Sheet
according to Regulation (EC) No. 1907/2006
Version:1Date: 11-03-2011
Supersedes: 20-08-2007
OA00058
13-05-2011 EN (English) 1/4
1. Identification of the substance/mixture and of the company/undertaking1.1. Product identifier
Product name - Trade name : Sodium Acid Pyro PhosphateCAS No. : 7758-16-9REACH registration No. : 01-2119489793-19
1.2. Relevant identified uses of the substance or mixture and uses advised against
1.2.1. Relevant identified usesNo additional information available
1.2.2. Uses advised againstNo additional information available
1.3. Details of the supplier of the safety data sheetUnivar Zwijndrecht N.V.Noordweg 33336 LH Zwijndrecht - NederlandT +31 (0)78 6250 000 - F +31 (0)78 6250 [email protected] - www.univareurope.com
1.4. Emergency telephone number
Country Official advisory body Address Emergency numberNETHERLANDS National Poisons Information Centre
National Institute for Public Health and the Environment, NB thisservice is only available to health professionals
P.O. Box 13720 BABilthoven
+31 30 274 88 88
2. Hazards identification2.1. Classification of the substance or mixture
2.1.1. Classification according to Regulation (EC) No. 1272/2008 [CLP]Eye Irrit. 2 H319Full text of H-phrases: see section 16.
2.1.2. Classification according to Directive 67/548/EEC or 1999/45/ECNot classified
2.1.3. Adverse physicochemical, human health and environmental effectsNo additional information available
2.2. Label elements
2.2.1. Labelling according to Regulation (EC) No. 1272/2008 [CLP]Hazard pictograms (CLP) :
GHS07
Signal word (CLP) : WarningH-Phrases : H319 - Causes serious eye irritationP-phrases : P280 - Wear eye protection, face protection.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minuts. Removecontact lenses, if present and easy to do. Continue rinsingP337+P313 - If eye irritation persists: Get medical advice/attention
2.2.2. Labelling according to Directive 67/548/EEC or 1999/45/ECNo labelling applicable
2.3. Other hazardsNo additional information available
3. Composition/information on ingredients3.1. Substances
Name Product identifier % Classification according toDirective 67/548/EEC
Disodium dihydrogenpyrophosphate (CAS No.)7758-16-9(EC no)231-835-0(REACH-no)01-2119489793-19
99 Not classified
Sodium Acid Pyro PhosphateSafety Data Sheet
according to Regulation (EC) No. 1907/2006
13-05-2011 EN (English) 2/4
Name Product identifier % Classification according toRegulation (EC) No.1272/2008 [CLP]
Disodium dihydrogenpyrophosphate (CAS No.)7758-16-9(EC no)231-835-0(REACH-no)01-2119489793-19
99 Eye Irrit. 2, H319
Full text of R-, H- and EUH-phrases: see section 16.
3.2. MixturesNot applicable
4. First aid measures4.1. Description of first aid measuresAfter inhalation : Remove the victim into fresh air. Allow the affected person to rest. Seek medical attention if ill
effect or irritation develops.After skin contact : Wash skin thoroughly with mild soap and water. Seek medical attention if ill effect or irritation
develops. Wash clothing before re-using.After eye contact : Flush with lukewarm water for 15 minutes. Seek medical attention immediately.After swallowing : Rinse mouth. Seek medical attention if ill effect or irritation develops. If victim completely
conscious/alert. slightly. Give water to drink. DO NOT INDUCE VOMITING. Never give anythingby mouth to an unconscious person.
4.2. Most important symptoms and effects, both acute and delayedInhalation : Not expected to be an irritant.Skin contact : Not expected to be an irritant.Eye contact : Severe eye irritant. Redness, pain. Tears. Eye irritation.Ingestion : Irritation of the linings of the mouth, throat, and gastrointestinal tract.
4.3. Indication of any immediate medical attention and special treatment neededTreat symptomatically.
5. Firefighting measures5.1. Extinguishing mediaSuitable extinguishing media : Use extinguishing media appropriate for surrounding fire.Unsuitable extinguishing media : None.
5.2. Special hazards arising from the substance or mixtureNo additional information available
5.3. Advice for firefightersFirefighting instructions : Clear the danger area.Protective equipment for firefighters : Wear suitable protective clothing. Use self-contained breathing apparatus.
6. Accidental release measures6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnelProtective equipment : Evacuate and limit access. Equip cleanup crew with proper protection. Use recommended
respiratory protection. Do not breathe dust. Avoid making dust. Ventilate area.
6.1.2. For emergency respondersProtective equipment : Reduce/avoid exposure and/or contact.
6.2. Environmental precautionsAvoid release to the environment. Notify authorities if product enters sewers or public waters.
6.3. Methods and material for containment and cleaning upMethods for cleaning up : Contain and collect as any solid. Prevent entry to sewers, ground and public waters.
6.4. Reference to other sectionsNo additional information available
7. Handling and storage7.1. Precautions for safe handlingPrecautions for safe handling : Reduce/avoid exposure and/or contact.
Sodium Acid Pyro PhosphateSafety Data Sheet
according to Regulation (EC) No. 1907/2006
13-05-2011 EN (English) 3/4
7.2. Conditions for safe storage, including any incompatibilitiesStorage : Store in dry, cool, well-ventilated area.
7.3. Specific end use(s)No additional information available
8. Exposure controls/personal protection8.1. Control parametersNo additional information available
8.2. Exposure controls- Hand protection : Wear gloves.- Eye protection : Safety glasses with side guards should be worn to prevent injury from airborne particles and/or
other eye contact with this product.- Skin protection : If skin contact or contamination of clothing is likely, protective clothing should be worn.- Respiratory protection : Approved dust or mist respirator should be used if airborne particles are generated when
handling this material.
9. Physical and chemical properties9.1. Information on basic physical and chemical propertiesAppearance : Powder.Physical state : SolidColour : White.Odour : Odourless.pH value : 3,7-5 (10 g/l)Relative density : 1-1,2Density : ≥ 0
9.2. Other informationNo additional information available
10. Stability and reactivity10.1. ReactivityNo additional information available
10.2. Chemical stabilityStable under normal conditions.
10.3. Possibility of hazardous reactionsNo additional information available
10.4. Conditions to avoidMoisture.
10.5. Incompatible materialsNo additional information available
10.6. Hazardous decomposition productsNo additional information available
11. Toxicological information11.1. Information on toxicological effectsSerious eye damage/irritation : Causes serious eye irritation.
12. Ecological information12.1. ToxicityNo additional information available
12.2. Persistence and degradabilityNo additional information available
12.3. Bioaccumulative potentialNo additional information available
Sodium Acid Pyro PhosphateSafety Data Sheet
according to Regulation (EC) No. 1907/2006
13-05-2011 EN (English) 4/4
12.4. Mobility in soilNo additional information available
12.5. Results of PBT and vPvB assessmentNo additional information available
12.6. Other adverse effectsNo additional information available
13. Disposal considerations13.1. Waste treatment methodsWaste treatment methods : Dispose in a safe manner in accordance with local/national regulations.Additional information : After last use, the packing should be totally empty and closed.
14. Transport informationNo dangerous good in sense of transport regulations.
15. Regulatory information15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
15.1.1. EU-RegulationsNo additional information available
15.1.2. National regulationsWater hazard class : 10 - Low toxicity to aquatic organisms, may cause long term adverse effects.Remediation Efforts : A - Basically, no discharge, if so, apply best available techniques
15.2. Chemical safety assessmentNo additional information available
16. Other informationFurther information : The contents and format of this MSDS are in accordance with regulation (EC) no. 1907/2006 of
the European Parliament and Council of 18 December 2006 concerning the registration,evaluation, authorisation and restriction of Chemicals (REACH). Appendix Of the raw materialsin chapter 3 at moment of reporting of this material safety data sheet, chemical safety reportshave not been registered in the scope of regulation (EC) no. 1907/2006.
Full text of R-, H- and EUH-phrases:------ Eye Irrit. 2 Serious Eye Damage/Irritation Category 2------ H319 Causes serious eye irritation
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore beconstrued as guaranteeing any specific property of the product.
Revision Date 03-04-13
Revision 6
Supersedes date 04-10-12
SDS No. 11368
SAFETY DATA SHEET
SODIUM BICARBONATE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name SODIUM BICARBONATE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Drilling fluid additive
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Woodlands Drive
Kirkhill Industrial Estate
Dyce, Aberdeen AB21 0GW
Scotland UK
T=+44(0)1224-246600
F=+11(0)1224-246699
Email - [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East and
Africa +44 (0) 1235 239 671, New Zealand +64 9929 1483, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (EC 1272/2008)
Physical and Chemical Hazards Not classified.
Human health Not classified.
Environment Not classified.
Classification (67/548/EEC) Not classified.
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
2.2. Label elements
Label In Accordance With (EC) No. 1272/2008
No pictogram required.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1. Substances
SODIUM BICARBONATE 60-100%
CAS-No.: 144-55-8 EC No.: 205-633-8
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
61 /
SDS No. 11368
SODIUM BICARBONATE
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
General information
The severity of the symptoms described will vary dependant of the concentration and the length of exposure. If adverse symptoms develop as
described the casualty should be transferred to hospital as soon as possible. For further information, please refer to section 11.
4.3. Indication of any immediate medical attention and special treatment needed
Treat Symptomatically.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Water spray, foam, dry powder or carbon dioxide.
Unsuitable extinguishing media
Do not use water jet as an extinguisher, as this will spread the fire.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Unusual Fire & Explosion Hazards
High concentrations of dust may form explosive mixture with air.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-fighters
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet. Avoid inhalation of dust and contact with skin and eyes. Avoid
spreading dust.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Avoid generation and spreading of dust. Shovel into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
For waste disposal, see section 13.
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SDS No. 11368
SODIUM BICARBONATE
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Observe good chemical hygiene practices. Avoid handling which leads to dust formation. Avoid inhalation of dust and contact with skin and
eyes. Avoid Water, moisture, acids and heating.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place. Avoid Contact with acids.
Storage Class
Chemical storage.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
NUI = Nuisance dust, WEL TWA 4mg/m3 Respirable Dust, 10 mg/m3 Total Dust.
8.2. Exposure controls
Protective equipment
Process conditions
All chemical Personal Protective Equipment (PPE) should be selected based on an assessment of both the chemical hazard present and the
risk of exposure to those hazards. The PPE recommendations below are based on an assessment of the chemical hazards associated with this
product. Where this product is used in a mixture with other products or fluids, additional hazards may be created and as such further
assessment of risk may be required. The risk of exposure and need of respiratory protection will vary from workplace to workplace and should
be assessed by the user in each situation.
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Dust filter P2 (for fine dust).
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. PVC gloves are recommended.
Eye protection
Use tight fitting goggles if dust is generated.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Solid
Colour White.
Odour Odourless.
Solubility Soluble in water.
Melting point (°C) 270°C
Relative density 2.21 - 2.23 s.g @ 20°C
Bulk Density 500 - 1150 kg/m3
pH-Value, Diluted Solution 8.1 - 8.4 @ 50g/l
Solubility Value (G/100G
H2O@20°C)
95 @ 20°C
Decomposition temperature (°C) > 60°C
63 /
SDS No. 11368
SODIUM BICARBONATE
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not relevant
10.4. Conditions to avoid
Avoid contact with: Moisture. Avoid heat.
10.5. Incompatible materials
Materials To Avoid
Avoid contact with acids.
10.6. Hazardous decomposition products
When heated, vapours/gases hazardous to health may be formed.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Acute toxicity:
Acute Toxicity (Oral LD50)
4220 mg/kg Rat
Acute Toxicity (Inhalation LC50)
4.74 mg/l (dust/mist) Rat
Aspiration hazard:
Not anticipated to present an aspiration hazard based on chemical structure.
Inhalation
Dust may irritate respiratory system or lungs.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Particles in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected]. OSPAR have defined this chemical as
PLONOR.
64 /
SDS No. 11368
SODIUM BICARBONATE
12.1. Toxicity
LC 50, 96 Hrs, Fish mg/l >7000
EC 50, 48 Hrs, Daphnia, mg/l >4000
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
Waste Class
The definitive European Waste code for this product will depend upon the final use that is made of this material. EWC-code: 06 03 14 7132.
Inorganic bases.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
Not applicable.
65 /
SDS No. 11368
SODIUM BICARBONATE
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation,
Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and
repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and
Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
Australia (AICS), Canada (DSL / NDSL), China (IECSC), Europe (EINECS / ELINCS), Japan (METI / ENCS), Korea (TCCL / ECL), New
Zealand (NZIoC), Phillipines (PICCS), United States (TSCA).
SECTION 16: OTHER INFORMATION
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information).
Revision Comments
General revision. Compiled or revised by Sarah Malone
Issued By Sarah Malone
Revision Date 03-04-13
Revision 6
Supersedes date 04-10-12
SDS No. 11368
Signature Sarah Malone
Signature 2 Nina Ovrehus
Risk Phrases In Full
Not classified.NC
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk. We
have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or situations. It
is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this product. Additional
information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any nature with respect to this
product or to the data herein is made or incurred hereunder.
66 /
Revision Date 14-03-11
Revision 3
Supersedes date 20-11-07
SDS No. 11115
SAFETY DATA SHEET
SODIUM CHLORIDE BRINE
SECTION 1: IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Product name SODIUM CHLORIDE BRINE
1.2. Relevant identified uses of the substance or mixture and uses advised against
Identified uses Oil well drilling fluid additive. Completion Brine
1.3. Details of the supplier of the safety data sheet
M-I SWACOSupplier
A Schlumberger Company
Endeavour Drive
Arnhall Business Park, Westhill
Aberdeen AB32 6UF
Scotland UK
T = +44 (0)1224-742200
F = +44 (0)1224-742288
E-mail = [email protected]
1.4. Emergency telephone number
(24 Hour) Australia +61 2801 44558, Asia Pacific +65 3158 1074, China +86 10 5100 3039, Europe +44 (0) 1235 239 670, Middle East
and Africa +44 (0) 1235 239 671, USA 001 281 561 1600.
SECTION 2: HAZARDS IDENTIFICATION
2.1. Classification of the substance or mixture
Classification (1999/45/EEC) Not classified.
2.2. Label elements
Risk Phrases
NC Not classified.
Safety Phrases
NC Not classified.
2.3. Other hazards
Not Classified as PBT/vPvB by current EU criteria.
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.2. Mixtures
WATER 60-100%
CAS-No.: 7732-18-5 EC No.: 231-791-2
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
SODIUM CHLORIDE 10-30%
CAS-No.: 7647-14-5 EC No.: 231-598-3
Classification (67/548/EEC)
Not classified.
Classification (EC 1272/2008)
Not classified.
61 /
SDS No. 11115
SODIUM CHLORIDE BRINE
The Full Text for all R-Phrases and Hazard Statements are Displayed in Section 16.
Composition Comments
The data shown is in accordance with the latest EC Directives.
SECTION 4: FIRST AID MEASURES
4.1. Description of first aid measures
Inhalation
Move the exposed person to fresh air at once. If respiratory problems, artificial respiration/oxygen. Get medical attention if any discomfort
continues.
Ingestion
Immediately give a couple of glasses of water or milk, provided the victim is fully conscious. Get medical attention if any discomfort
continues.
Skin contact
Remove contaminated clothing immediately and wash skin with soap and water. Get medical attention promptly if symptoms occur after
washing.
Eye contact
Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids.
Continue to rinse for at least 15 minutes. Get medical attention if any discomfort continues.
4.2. Most important symptoms and effects, both acute and delayed
Inhalation.
This is unlikely to occur but symptoms similar to those of ingestion may develop.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged skin contact may cause redness and irritation.
Eye contact
May cause temporary eye irritation.
4.3. Indication of any immediate medical attention and special treatment needed
Get medical attention if any discomfort continues.
SECTION 5: FIREFIGHTING MEASURES
5.1. Extinguishing media
Extinguishing media
Use fire-extinguishing media appropriate for surrounding materials.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products
When heated, vapours/gases hazardous to health may be formed.
Specific hazards
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Sodium. and Chlorides.
5.3. Advice for firefighters
Special Fire Fighting Procedures
Containers close to fire should be removed immediately or cooled with water.
Protective equipment for fire-figthers
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
SECTION 6: ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions, protective equipment and emergency procedures
Wear protective clothing as described in Section 8 of this safety data sheet.
6.2. Environmental precautions
Do not allow to enter drains, sewers or watercourses.
6.3. Methods and material for containment and cleaning up
Stop leak if possible without risk. Dike far ahead of larger spills for later disposal. Absorb spillage with suitable absorbent material. Shovel
into dry containers. Cover and move the containers. Flush the area with water.
6.4. Reference to other sections
Wear protective clothing as described in Section 8 of this safety data sheet.
62 /
SDS No. 11115
SODIUM CHLORIDE BRINE
SECTION 7: HANDLING AND STORAGE
7.1. Precautions for safe handling
Avoid spilling, skin and eye contact.
7.2. Conditions for safe storage, including any incompatibilities
Store in tightly closed original container in a dry, cool and well-ventilated place.
7.3. Specific end use(s)
The identified uses for this product are detailed in Section 1.2.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1. Control parameters
Ingredient Comments
No exposure limits noted for ingredient(s).
8.2. Exposure controls
Protective equipment
Engineering measures
Provide adequate general and local exhaust ventilation.
Respiratory equipment
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists. Chemical respirator with organic vapour cartridge.
Hand protection
For prolonged or repeated skin contact use suitable protective gloves. Butyl rubber. or PVC gloves are recommended.
Eye protection
Wear approved chemical safety goggles where eye exposure is reasonably probable.
Other Protection
Wear appropriate clothing to prevent any possibility of skin contact. Provide eyewash station.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
9.1. Information on basic physical and chemical properties
Appearance Liquid
Colour Colourless.
Odour Odourless.
Solubility Soluble in water.
Initial boiling point and boiling range 106°C
Melting point (°C) -5°C
Relative density 1.008 - 1.200 g/cm3 @ 20 °C
pH-Value, Conc. Solution 8.5
9.2. Other information
Not relevant
SECTION 10: STABILITY AND REACTIVITY
10.1. Reactivity
There are no known reactivity hazards associated with this product.
10.2. Chemical stability
Stable under normal temperature conditions and recommended use.
10.3. Possibility of hazardous reactions
Not known.
10.4. Conditions to avoid
63 /
SDS No. 11115
SODIUM CHLORIDE BRINE
Avoid contact with: Not known.
10.5. Incompatible materials
Materials To Avoid
Avoid Strong oxidising substances.
10.6. Hazardous decomposition products
Fire or high temperatures create: Vapours/gases/fumes of: Oxides of: Sodium. and Chlorides.
SECTION 11: TOXICOLOGICAL INFORMATION
11.1. Information on toxicological effects
Inhalation
Gas or vapour in high concentrations may irritate respiratory system.
Ingestion
May cause discomfort if swallowed.
Skin contact
Prolonged and frequent contact may cause redness and irritation.
Eye contact
Spray and vapour in the eyes may cause irritation and smarting.
Route of entry
No route of entry noted.
Target Organs
No specific target organs noted
SECTION 12: ECOLOGICAL INFORMATION
Ecotoxicity
Contact M-I SWACO's QHSE Department for ecological information at [email protected].
12.1. Toxicity
Acute Fish Toxicity
Not considered toxic to fish.
12.2. Persistence and degradability
Degradability
There are no data on the degradability of this product.
12.3. Bioaccumulative potential
Bioaccumulative potential
No data available on bioaccumulation.
12.4. Mobility in soil
Mobility:
The product is soluble in water.
12.5. Results of PBT and vPvB assessment
Not Classified as PBT/vPvB by current EU criteria.
12.6. Other adverse effects
None known.
SECTION 13: DISPOSAL CONSIDERATIONS
13.1. Waste treatment methods
Recover and reclaim or recycle, if practical. Dispose of waste and residues in accordance with local authority requirements.
SECTION 14: TRANSPORT INFORMATION
General The product is not covered by international regulation on the transport of dangerous goods (IMDG, IATA,
ADR/RID).
14.1. UN number
Not applicable.
14.2. UN proper shipping name
64 /
SDS No. 11115
SODIUM CHLORIDE BRINE
Not applicable.
14.3. Transport hazard class(es)
Not applicable.
14.4. Packing group
Not applicable.
14.5. Environmental hazards
Environmentally Hazardous Substance/Marine Pollutant
No.
14.6. Special precautions for user
Not applicable.
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
The product has been assessed and contained in Chapters 17 and 18 of the IBC Code and the latest MEPC.2/Circular and is permitted to
be carried under Annex II of MARPOL and resolution A.673 (16) Offshore Supply Vessel Code. Ship Type:- 3. Pollution Category:- Z.
SECTION 15: REGULATORY INFORMATION
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
Uk Regulatory References
Chemicals (Hazard Information & Packaging) Regulations. Control of Substances Hazardous to Health Regulations 2002 (as amended)
Workplace Exposure Limits EH40.
EU Legislation
Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive
1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive
76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC, including amendments.
Water hazard classification
WGK 1
15.2. Chemical Safety Assessment
International Chemical Inventories
Contact [email protected] for REACH information. Complies with the following national/regional chemical inventory requirements:
AICS, DSL / NDSL, IECSC, EINECS / ELINCS, METI ENCS, TCCL ECL, NZIoC, PICCS, TSCA,
SECTION 16: OTHER INFORMATION
Abbreviations and acronyms used in the safety data sheet
If M-I SWACO product use phrase: *a mark of M-I L.L.C.
General information
HMIS Health -1 HMIS Flammability - 0 HMIS Physical Hazard - 0 J - Splash Goggles, Gloves, Synthetic Apron, Dust and Vapour
Respirator.
Information Sources
Product information provided by the commercial vendor(s). Material Safety Data Sheet, Misc. manufacturers. LOLI. European Chemicals
Bureau - ESIS (European Chemical Substances Information). MARPOL 73/78. Marine Environment Protection Committee (MEPC)
Circulars. MEPC.2 MEPC 54/10/4. IBC Code. IMO Resolution A.673 (16), Guidelines for the Transport and Handling of Limited Amounts of
Hazardous and Noxious Liquid Substances in Bulk Offshore Support Vessels.
Revision Comments
General revision. Compiled or Revised by Ewan MacLeod
Issued By Bill Cameron
Revision Date 14-03-11
Revision 3
Supersedes date 20-11-07
SDS No. 11115
Risk Phrases In Full
Not classified.NC
65 /
SDS No. 11115
SODIUM CHLORIDE BRINE
Disclaimer
MSDS furnished independent of product sale. While every effort has been made to accurately describe this product, some of the data are obtained from
sources beyond our direct supervision. We cannot make any assertions as to its reliability or completeness; therefore, user may rely only at user's risk.
We have made no effort to censor or conceal deleterious aspects of this product. Since we cannot anticipate or control the conditions under which this
information and product may be used, we make no guarantee that the precautions we have suggested will be adequate for all individuals and/or
situations. It is the obligation of each user of this product to comply with the requirements of all applicable laws regarding use and disposal of this
product. Additional information will be furnished upon request to assist the user; however, no warranty, either expressed or implied, nor liability of any
nature with respect to this product or to the data herein is made or incurred hereunder.
66 /